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Removal of methylene blue by hydrochar modified from hydrothermal carbonization technique 利用热液碳化技术改性的水炭去除亚甲基蓝
IF 2.8 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-09-11 DOI: 10.1002/ep.14469
Mohammad W. Amer, Eman M. Khdeir, Francesco Barzagli, Mustafa A. Taha, Heba M. Alsalti, Elias N. Ibrahim, Rahaf A. Almassi, Ahmad R. Hasoneh, Mohammed T. Rasheed, Raid Al‐Jawasrah
This study explores the adsorption potential of hydrothermally treated waste derived algal biomass for removing methylene blue (MB) dye. Synthesizing a modified hydrochar through hydrothermal carbonization (150°C, 35 bar) followed by NaOH modification, we observed enhanced thermal stability and distinctive chemical changes. Optimal conditions were determined at pH 6 and 1 h contact time. Soluble salts with cations were identified as impacting adsorption efficiency, with increased interference for higher cation charges. Thermodynamic parameters (ΔG, ΔH, and ΔS) indicated a spontaneous and exothermic process, the calculated values (−5.417 to −6.907 kJ mol−1, −29.0 kJ mol−1, −73.8 J K−1 mol−1) aligned with this behavior. Adsorption isotherms favored the Freundlich model, revealing heterogeneous multilayer adsorption, with a maximum capacity of 97%. Kinetic studies supported the pseudo‐first‐order model. This detailed exploration provides insights into thermodynamics, kinetics, and the impact of adsorption parameters on MB removal, emphasizing the practicality of alkaline‐modified hydrochar as an effective, sustainable adsorbent.
本研究探讨了经水热处理的废物衍生藻类生物质去除亚甲基蓝(MB)染料的吸附潜力。通过水热碳化(150°C,35 巴)合成改性水炭,然后进行 NaOH 改性,我们观察到其热稳定性增强,化学变化明显。最佳条件是 pH 值为 6,接触时间为 1 小时。结果表明,带有阳离子的可溶性盐会影响吸附效率,阳离子电荷越高,干扰越大。热力学参数(ΔG、ΔH 和 ΔS)表明这是一个自发的放热过程,计算值(-5.417 至 -6.907 kJ mol-1、-29.0 kJ mol-1、-73.8 J K-1 mol-1)与这一行为一致。吸附等温线倾向于 Freundlich 模型,显示了异质多层吸附,最大吸附容量为 97%。动力学研究支持伪一阶模型。这项详细的研究深入探讨了热力学、动力学以及吸附参数对甲基溴去除的影响,强调了碱改性水炭作为一种有效、可持续吸附剂的实用性。
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引用次数: 0
Energy analysis of standalone hybrid active solar room heating system 独立式混合主动太阳能室内供暖系统的能耗分析
IF 2.8 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-09-09 DOI: 10.1002/ep.14471
Amit Shrivastava, M. K. Gaur
In winter, offices use heat pumps, electric heaters, and blowers to stay warm, but these use traditional energy that is not sustainable or eco‐friendly. To meet the requirements of thermal comfort, an environmentally friendly and self‐sustainable system was developed at Madhav Institute of Technology and Science in Gwalior, India. This system includes a heat exchanger, a flat plate collector, an evacuated tube collector, and a pump. Two versions of the system were tested: one with a heat exchanger and an evacuated tube collector (HEWETC) and another with a heat exchanger and a flat plate collector (HEWFPC). The results showed that the HEWETC system is better at heating the room and has higher efficiency compared to the HEWFPC system. The HEWFPC system is 12% efficient, while the HEWETC system is 21% efficient. The room stayed at a constant temperature of 26.3°C all day. The HEWETC and HEWFPC systems provided 0.46 and 0.55 MJ of heat to the room, respectively. During the heating season, the solar heat collected was 8030.38 kWh, and electricity used was 5229.7 kWh. The HEWETC system proved to be effective and suitable for heating the building.
冬季,办公室使用热泵、电暖器和鼓风机来取暖,但这些设备使用的都是不可持续或不环保的传统能源。为了满足热舒适度的要求,印度瓜里奥尔的马达夫技术与科学学院开发了一套环保且可自我维持的系统。该系统包括一个热交换器、一个平板集热器、一个抽真空管集热器和一个泵。对该系统的两个版本进行了测试:一个是热交换器和真空管集热器(HEWETC),另一个是热交换器和平板集热器(HEWFPC)。结果表明,与 HEWFPC 系统相比,HEWETC 系统的房间加热效果更好,效率更高。HEWFPC 系统的效率为 12%,而 HEWETC 系统的效率为 21%。房间全天恒温 26.3°C。HEWETC 和 HEWFPC 系统分别为房间提供了 0.46 兆焦耳和 0.55 兆焦耳的热量。在供暖季节,收集的太阳能热量为 8030.38 千瓦时,用电量为 5229.7 千瓦时。事实证明, HEWETC 系统可以有效地为建筑物供暖。
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引用次数: 0
Performance estimation of a two‐body wave energy converter for the East Coast of India 印度东海岸双体波浪能转换器性能评估
IF 2.8 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-09-06 DOI: 10.1002/ep.14468
Devesh Singh, Akshoy Ranjan Paul, Abdus Samad
The study aims to assess the feasibility of harnessing wave energy from the low‐energy waves prevalent along the east coast of India, where wave energy converters (WECs) may not produce sufficient power economically. Vishakhapatnam port, located on the east coast, experiences such waves (period, Tp = 5 to 10 s, and wave height, Hs = 0.07 to 2.61 m). This study analyzes the performance of a two‐body point absorber WEC and estimates the wave power using the parameters Hs and Tp. The hydrodynamic parameters were assessed in the frequency domain using the boundary element method, while the output power was estimated in the time domain using the open‐source code WEC‐Sim. The harvested power initially increased with the wave period, peaked at Tp = 7 s and Hs = 2 m, and subsequently decreased. This study highlights the potential of wave energy as a renewable resource for India, given its extensive coastline and untapped wave energy potential. It suggests that green energy firms should explore opportunities in regions abundant with wave energy to promote sustainable energy production and drive innovation in wave energy technology, thereby indicating avenues for future research in this domain.
这项研究旨在评估从印度东海岸盛行的低能量波浪中利用波浪能的可行性,因为波浪能转换器(WEC)可能无法在经济上产生足够的电能。位于东海岸的维沙卡帕特南港就有这样的波浪(周期 Tp = 5 到 10 秒,波高 Hs = 0.07 到 2.61 米)。本研究分析了双体点吸收式水力发电装置的性能,并利用 Hs 和 Tp 参数估算了波功率。使用边界元法在频域评估了流体力学参数,同时使用开源代码 WEC-Sim 在时域估算了输出功率。收获功率最初随波浪周期增加,在 Tp = 7 s 和 Hs = 2 m 时达到峰值,随后下降。鉴于印度广阔的海岸线和尚未开发的波浪能潜力,本研究强调了波浪能作为可再生资源的潜力。研究建议,绿色能源公司应在波浪能丰富的地区寻找机会,促进可持续能源生产,推动波浪能技术创新,从而为这一领域的未来研究指明方向。
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引用次数: 0
Photoactivation of nano MgO anchored g‐C3N4 enhances biodiesel production in Chlorella sorokiniana: A sustainable approach 纳米氧化镁锚定 g-C3N4 的光活化提高了小球藻生物柴油的产量:一种可持续的方法
IF 2.8 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-09-05 DOI: 10.1002/ep.14470
Amany Khalifa, Maryam Faried, Essam M. Abdelsalam, Mohamed Samer, Mohamed A. Moselhy, Hassan Elsayed, Yasser A. Attia
Investigating the potential of magnesium oxide (MgO), graphitic carbon nitride (g‐C3N4), and their composite nanoparticles as nutrient sources for enhanced microalgae biodiesel production formed the core of this study. Supplementing the growth medium with g‐C3N4 and MgO/g‐C3N4 nanoparticles significantly increased microalgae (Chlorella sorokiniana) growth and lipid accumulation, culminating in a 58 mg/L lipid concentration. Interestingly, while MgO nanoparticles alone led to the highest biodiesel yield, the synergistic effect of MgO and g‐C3N4 in the composite nanoparticles improved nutrient availability and facilitated optimal microalgae growth and lipid accumulation. These findings pave the way for further research and development of nanoparticle‐based strategies to optimize microalgae‐based biodiesel production, offering a promising avenue for a more sustainable and efficient future of biofuel generation. The results showed that the addition of 15 mg/L of MgO NPs produced the maximum biodiesel yield which reached 61.5 mg/L.
本研究的核心是调查氧化镁(MgO)、氮化石墨碳(g-C3N4)及其复合纳米颗粒作为营养源用于提高微藻生物柴油生产的潜力。在生长培养基中添加 g-C3N4 和 MgO/g-C3N4 纳米粒子可显著提高微藻(小球藻)的生长和脂质积累,最终达到 58 mg/L 的脂质浓度。有趣的是,虽然单独使用氧化镁纳米颗粒可获得最高的生物柴油产量,但氧化镁和 g-C3N4 在复合纳米颗粒中的协同效应提高了营养物质的可用性,促进了微藻的最佳生长和脂质积累。这些发现为进一步研究和开发基于纳米颗粒的优化微藻生物柴油生产的策略铺平了道路,为未来更可持续、更高效地生产生物燃料提供了一条前景广阔的途径。结果表明,添加 15 毫克/升氧化镁 NPs 产生的生物柴油产量最高,达到 61.5 毫克/升。
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引用次数: 0
Optimizing the performance of solar evacuated tube collector systems for seawater desalination 优化用于海水淡化的太阳能真空管集热器系统的性能
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-09-05 DOI: 10.1002/ep.14467
Nitesh Patel, Unnati Joshi, Vijay Patel, Anand Joshi, Ankit D. Oza, Abhinav Kumar, Vladimir Ivanovich Velkin

Solar thermal collectors, such as evacuated tube collectors (ETCs), are essential for harnessing renewable energy, yet their efficiency is often hindered by thermal losses and limited heat transfer. This study focuses on enhancing ETC performance for seawater desalination by using nanofluids as heat transfer fluids. These modifications aim to improve heat transfer rates, reduce thermal losses, increase the maximum temperature attainable, and minimize the collector area required. An experimental setup has been developed at Parul University in Vadodara, Gujarat, India. Key parameters such as air mass flow rate, inclination angle, water mass flow rate, nanofluid volume percentage, and screw conveyor speed were optimized to achieve ideal temperature levels. Results indicate that the optimal configuration for steam generation includes a high air mass flow rate and a 40° inclination angle for the ETC. Additionally, a water mass flow rate of 10 LPH and a screw conveyor speed of 30 rpm are crucial for optimal performance. Data collected showed the highest solar energy levels between 12 PM and 1 PM, which significant decreases post this peak period. These findings highlight the potential of nanomaterial-based enhancements in improving the efficiency and cost-effectiveness of solar thermal systems for renewable energy applications.

真空管集热器(ETC)等太阳能集热器对利用可再生能源至关重要,但其效率往往受到热损失和有限传热的阻碍。本研究的重点是通过使用纳米流体作为传热液体,提高 ETC 在海水淡化方面的性能。这些改进旨在提高传热率,减少热损失,提高可达到的最高温度,并最大限度地减少所需的集热器面积。在印度古吉拉特邦瓦多达拉的帕鲁尔大学开发了一套实验装置。对空气质量流量、倾斜角度、水质量流量、纳米流体体积百分比和螺旋输送机速度等关键参数进行了优化,以达到理想的温度水平。结果表明,产生蒸汽的最佳配置包括高空气质量流量和 40° 的 ETC 倾斜角。此外,10 LPH 的水流量和 30 rpm 的螺旋输送机速度也是实现最佳性能的关键。收集到的数据显示,中午 12 点到下午 1 点之间的太阳能水平最高,高峰期过后太阳能水平显著下降。这些发现凸显了纳米材料在提高可再生能源应用中太阳能热系统的效率和成本效益方面的潜力。
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引用次数: 0
Grid-connected PV system in air cooled double-stage ORC geothermal power plant performance evaluation, case study: Sultanhisar GPP-2 空气冷却双级 ORC 地热发电站性能评估中的并网光伏系统,案例研究:苏丹希萨尔 GPP-2
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-27 DOI: 10.1002/ep.14460
Şeyma Kaçmaz, Havva Demirpolat

Many factors determine the percentage of parasitic load of the geothermal power plant. Domestic consumption accounts for about 20–25 per cent of total production in low-temperature geothermal power plants. As a case study, the ratio of a 1 MW grid-connected PV system to the internal consumption of the Sultanhisar GPP-2 and its effect on increasing the efficiency of the system have been examined. The current production of the power plant has been modeled thermodynamically with the parameters taken from the plant, and the efficiency of the system has been calculated. Sultanhisar GPP-2, which operates at a geothermal well temperature of 140.2°C and a net efficiency of 6.28%, has a domestic consumption to production ratio of around 25%. The installation of a 1 MW PV system is expected to produce 2140MWh per year, equivalent to 7% of the internal energy consumption.

决定地热发电厂寄生负载比例的因素很多。在低温地热发电厂,国内消耗约占总产量的 20%-25%。作为一项案例研究,我们考察了 1 兆瓦并网光伏系统与苏尔坦希萨尔 GPP-2 内部消耗的比例及其对提高系统效率的影响。利用电厂的参数对电厂当前的发电量进行了热力学建模,并计算了系统的效率。Sultanhisar GPP-2 的地热井温度为 140.2°C,净效率为 6.28%,其国内消费与生产比率约为 25%。安装 1 兆瓦光伏系统后,预计每年可生产 2140 兆瓦时,相当于内部能源消耗的 7%。
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引用次数: 0
Occurrence and eco-toxicological risk assessment of primary aromatic amines in hookah wastewater 水烟废水中芳香族伯胺的存在及其生态毒理学风险评估
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-26 DOI: 10.1002/ep.14466
Gholamreza Heydari, Mahbubeh Tangestani, Farshid Soleimani, Bahman Ramavandi, Farshad Bahrami Asl, Roshana Rashidi, Hossein Arfaeinia

This study was conducted for the first time to discern the levels of primary aromatic amines (PAAs) in hookah wastewater resulting from the consumption of fruit-flavored and traditional tobacco. The ecological risk of PAAs laden hookah wastewater and its toxic effects on crustaceans and fish have also been evaluated. The mean concentrations of PAAs in hookah wastewater resulting from consumption of Al-Mahmoud, Al-Ayan, Al-Fakher, and Mazaya brands were 1075.56, 1033.25, 986.94, and 946.58 ng/L, respectively, while it was determined as 355.91 ng/L in traditional tobacco. The concentration of PAAs in the hookah wastewater of fruit-flavored tobacco was significantly higher than the traditional one (p < 0.05). Aniline (ANL) had the maximum level in hookah wastewater from fruit-flavored (679.83–802.50 ng/L) and traditional (316.53 ng/L) tobacco consumption. The RQ value of the mean concentration of PAAs in hookah wastewater for all samples was in the range of medium to low-risk (RQ < 1). In addition to PAAs, other dangerous chemicals in hookah wastewater can increase its ecological and health risk, so it is necessary to manage such wastewater before discharging it into the environment.

这项研究首次发现了因吸食果味烟草和传统烟草而产生的水烟废水中芳香族伯胺(PAA)的含量。研究还评估了含有 PAAs 的水烟废水的生态风险及其对甲壳类动物和鱼类的毒性影响。食用 Al-Mahmoud、Al-Ayan、Al-Fakher 和 Mazaya 品牌烟草所产生的水烟废水中 PAAs 的平均浓度分别为 1075.56、1033.25、986.94 和 946.58 ng/L,而传统烟草中的 PAAs 浓度为 355.91 ng/L。果味烟草勾兑废水中 PAAs 的浓度明显高于传统烟草(p < 0.05)。苯胺(ANL)在果味烟草(679.83-802.50 ng/L)和传统烟草(316.53 ng/L)的水烟废水中含量最高。所有样品的水烟废水中 PAAs 平均浓度的 RQ 值均在中低风险范围内(RQ < 1)。除 PAAs 外,水烟废水中的其他危险化学品也会增加其生态和健康风险,因此有必要在将这些废水排放到环境中之前对其进行管理。
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引用次数: 0
A review of the use of rice husk silica as a sustainable alternative to traditional silica sources in various applications 稻壳白炭黑作为传统白炭黑来源的可持续替代品在各种应用中的使用综述
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-22 DOI: 10.1002/ep.14451
Mustapha Abdullateef Taiye, Wahia Hafida, Fangong Kong, Cunshan Zhou

Rice husk silica (RHS) has emerged as a sustainable alternative to traditional sources of silica in various applications, offering eco-friendly attributes, cost-effectiveness, and versatility. This review explores the potential of RHS as a substitute for conventional silica sources, highlighting its alignment with sustainable development objectives and its appeal to industries seeking environmental responsibility. Among the extraction methods, acid leaching is identified as yielding higher purity silica. In contrast, among the novel techniques, the hydrothermobaric process stands out for producing high purity and yielding nanosilica. Despite challenges like limited access to high-quality rice husks and variations in silica content, RHS extraction methods show promising avenues for sustainable silica production, addressing waste management, and environmental concerns. Further development and optimization of extraction techniques are essential for widespread acceptance, with future research focusing on nanoparticle synthesis and incorporating green chemistry principles. This comprehensive review of RHS provides a valuable resource for researchers seeking to explore sustainable alternatives in their respective fields, aiming to foster adopting more sustainable practices and materials across various industries.

稻壳白炭黑(RHS)已成为各种应用中传统白炭黑来源的可持续替代品,具有生态友好、成本效益高和用途广泛等特点。本综述探讨了稻壳白炭黑作为传统白炭黑来源替代品的潜力,强调了它与可持续发展目标的一致性及其对寻求环境责任的行业的吸引力。在各种萃取方法中,酸浸法被认为能产生纯度更高的二氧化硅。相比之下,在新型技术中,水热法因其纯度高、产量大而脱颖而出。尽管存在诸如获取优质稻壳的途径有限和二氧化硅含量差异等挑战,但稻壳萃取方法为可持续二氧化硅生产、解决废物管理和环境问题提供了前景广阔的途径。萃取技术的进一步发展和优化对其被广泛接受至关重要,未来的研究重点将放在纳米粒子合成和绿色化学原理上。这篇关于 RHS 的全面综述为寻求在各自领域探索可持续替代品的研究人员提供了宝贵的资源,旨在促进各行各业采用更具可持续性的实践和材料。
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引用次数: 0
Comprehensive effects of ammonia substitution rate, compression ratio, and ignition timing on knock, NOx emissions and indicated thermal efficiency in a hydrogen fuel engine 氨替代率、压缩比和点火正时对氢燃料发动机爆震、氮氧化物排放和指示热效率的综合影响
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-15 DOI: 10.1002/ep.14465
Junquan Li, Chengfei Zhao, Zhangjun Tu, Shanxu Cheng, Yuanli Xu

To reduce knock and keeping low NOx emissions and high indicated thermal efficiency (ITE) in a hydrogen fuel engine, the comprehensive effects of ammonia substitution rate (ASR), compression ratio (CR), and ignition timing (IT) on its combustion and its NOx emissions were studied numerically. Based on a four-cylinder gasoline direct injection (GDI) engine, it was modified into an ammonia/hydrogen dual-fuel (AHDF) spark ignition (SI) engine. The simulation was conducted by GT-Power software, and simulation data were validated through experiments. 2500 rpm_50% load was selected for the research. ASR, CR and IT vary from 0% to 20%, 10.5 to 8.5, and −24 to 0°CA ATDC, respectively. The findings indicate that increasing ASR decreases the maximum pressure rise rate (MPRR) and the knock index (KI), improving the ITE, but increasing NOx emissions. Based on 20% ASR, CR was optimized. The findings indicate that decreasing CR reduces the MPRR and KI, but increasing NOx emissions and decreasing the ITE. Finally, based on CR of 9, IT was optimized. The findings indicate that delaying IT reduces the MPRR and KI, but also has a certain impact on NOx emissions and ITE. After compromise consideration, the optimal IT in this study was selected as −9°CA ATDC.

为了减少爆震,保持氢燃料发动机的低氮氧化物排放和高指示热效率(ITE),对氨替代率(ASR)、压缩比(CR)和点火正时(IT)对其燃烧和氮氧化物排放的综合影响进行了数值研究。以四缸汽油直喷(GDI)发动机为基础,将其改进为氨氢双燃料(AHDF)火花点火(SI)发动机。模拟由 GT-Power 软件进行,模拟数据通过实验验证。研究选取 2500 rpm_50% 负载进行。ASR、CR 和 IT 分别在 0% 至 20%、10.5 至 8.5 和 -24 至 0°CA ATDC 之间变化。研究结果表明,增加 ASR 会降低最大压力上升率(MPRR)和爆震指数(KI),改善 ITE,但会增加氮氧化物排放量。在 20% ASR 的基础上,对 CR 进行了优化。研究结果表明,降低 CR 会降低 MPRR 和 KI,但会增加氮氧化物排放量,降低 ITE。最后,在 CR 为 9 的基础上,对 IT 进行了优化。结果表明,延迟 IT 可降低 MPRR 和 KI,但对 NOx 排放和 ITE 也有一定影响。经过折中考虑,本研究选择的最佳 IT 为 -9°CA ATDC。
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引用次数: 0
Electrocoating of polyaniline on graphite carbon and activated carbon cloth surfaces as an anode and its effect on performance of microbial fuel cell 在石墨碳和活性碳布表面电镀聚苯胺作为阳极及其对微生物燃料电池性能的影响
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-08-15 DOI: 10.1002/ep.14448
Andika Wahyu Afrianto, Paiboon Sreearunothai, Korakot Sombatmankhong, Sandhya Babel

Microbial fuel cell (MFC) is a bioelectrochemical-based reactor that can generate electrical energy directly from wastewater by utilizing microbial activity that oxidizes the waste organic matter. This study aims to synthesize polyaniline (PANI) and deposit on a graphite carbon electrode (GCE) and activated carbon cloth (ACC) surface to use as an anode material for MFCs. The MFC performance was evaluated using oxygen and ferricyanide as electron acceptors. PANI was electropolymerized from its aniline monomer and deposited using an electrophoretic deposition method onto the electrode surface. A PANI thin film was characterized using FTIR, field emission scanning electron microscopy (FESEM), BET, and electrochemical analysis. The analysis results show the characteristic peaks of PANI at 1557 cm−1, demonstratinjg the existence of quinoid rings (NQN), while the peaks at 1479 and 1400 cm−1 corresponding to the benzenoid (NBN) stretching in the PANI structure. The FESEM analysis confirmed that PANI appeared to have a porous structure on modified electrodes. It was found that the best system was MFC with ferricyanide as the electron acceptor. The highest power density produced is 254 mWm−2 from GCE-PANI and 16.47 mWm−2 from ACC-PANI. The normalized energy recovery of GCE-PANI and ACC-PANI in ferricyanide is 0.115 kWh kgCOD−1 and 5.67 × 10−3 kWh kgCOD−1, respectively. The COD removal was observed to be 88.8% for GCE-PANI and 87.2% for ACC-PANI from 1000 mg/L COD.

微生物燃料电池(MFC)是一种基于生物电化学的反应器,可利用微生物氧化废水中有机物的活性直接从废水中产生电能。本研究旨在合成聚苯胺(PANI),并将其沉积在石墨碳电极(GCE)和活性碳布(ACC)表面,作为 MFC 的阳极材料。使用氧气和铁氰化物作为电子受体对 MFC 的性能进行了评估。PANI 由苯胺单体电聚合而成,采用电泳沉积法沉积在电极表面。利用傅立叶变换红外光谱、场发射扫描电子显微镜(FESEM)、BET 和电化学分析对 PANI 薄膜进行了表征。分析结果显示,PANI 的特征峰位于 1557 cm-1,表明存在醌环 (NQN),而 1479 和 1400 cm-1 的峰则对应于 PANI 结构中的苯环 (NBN) 伸展。FESEM 分析证实,改性电极上的 PANI 似乎具有多孔结构。研究发现,最好的系统是以铁氰化物为电子受体的 MFC。GCE-PANI 产生的最高功率密度为 254 mWm-2,ACC-PANI 产生的最高功率密度为 16.47 mWm-2。在铁氰化物中,GCE-PANI 和 ACC-PANI 的归一化能量回收率分别为 0.115 kWh kgCOD-1 和 5.67 × 10-3 kWh kgCOD-1。从 1000 mg/L COD 的去除率来看,GCE-PANI 为 88.8%,ACC-PANI 为 87.2%。
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引用次数: 0
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