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IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-31 DOI: 10.1002/ep.14423
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引用次数: 0
Issue Information - Cover and Table of Contents 发行信息 - 封面和目录
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-31 DOI: 10.1002/ep.14180
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引用次数: 0
Investigation of physical properties of microalgae-pectin-based bio-composite with addition of pine needle for environmental application 添加松针的微藻-pectin 生物复合材料在环境应用中的物理性质研究
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-29 DOI: 10.1002/ep.14463
Carlos Munoz-Cupa, Kristine Lee, Anuradha Krishnan, Amarjeet Bassi

Polymers and biopolymers have gained significance due to their applicability and use in industry reducing the negative impact of polymers based on petroleum. A possible solution for the conventional polymer's biodegradability is bio-composites, which contain natural fibers or aggregates such as microalgae. Hence, microalgae biomass has a promising application to address the biodegradability issue of conventional polymers. In this study, Chlorella vulgaris biomass was mixed with pectin for control samples with glycerol as plasticizer. The mixture microalgae-pectin-glycerol, and the addition of pine needles was used to evaluate the tensile strength and compression of the bio-composite. This bio-composite showed a higher Young's modulus of 95.66 MPa for blend C2 and a higher strength with 20% of pectin concentration in the mixture. Additionally, the pine needle addition did not have a low effect between the compression results. On the other hand, analysis on elasticity showed that the full recovery of the bio-composite happened after 10 min in all the blends. Also, the bio-composite showed a slow release of nitrogen and phosphorous after 5 days of water addition, indicating an effective slow release for blend B for both nutrients. Water uptake capacity and loss of soluble material was studied using pullulan, chitosan, and cetyltrimethylammonium bromide additives. These cationic surfactants demonstrated their potential for reduction of water solubility of the bio-composite.

聚合物和生物聚合物由于其适用性和在工业中的应用,减少了以石油为基础的聚合物所带来的负面影响,因而变得越来越重要。生物复合材料是解决传统聚合物生物降解性问题的一个可行方案,它含有天然纤维或微藻等聚合体。因此,微藻生物质在解决传统聚合物的生物降解性问题方面具有广阔的应用前景。在这项研究中,对照样品中的小球藻生物质与果胶混合,甘油作为增塑剂。微藻-果胶-甘油混合物和松针被用来评估生物复合材料的拉伸强度和压缩性。这种生物复合材料显示,混合物 C2 的杨氏模量较高,为 95.66 兆帕,混合物中果胶浓度为 20% 时,强度较高。此外,松针添加量对压缩结果的影响并不明显。另一方面,弹性分析表明,在所有混合物中,生物复合材料在 10 分钟后完全恢复。此外,在加水 5 天后,生物复合材料显示出氮和磷的缓慢释放,这表明混合物 B 能有效地缓慢释放这两种养分。使用拉毛聚糖、壳聚糖和十六烷基三甲基溴化铵添加剂对吸水能力和可溶性物质的损失进行了研究。这些阳离子表面活性剂证明了它们在降低生物复合材料水溶性方面的潜力。
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引用次数: 0
Preparation of porous plate from municipal solid waste incineration fly ash and its application in a biofilm batch reactor 利用城市固体废物焚烧飞灰制备多孔板并将其应用于生物膜批式反应器
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-24 DOI: 10.1002/ep.14459
Jing Wang, Han Liu, Chang-Jung Sun, Weicheng Fang

The reutilization of municipal solid waste incineration (MSWI) fly ash is a prominent area of research. This study focused on creating fly ash porous plate filler (FAPPF) by using techniques, such as water extraction, milling, component adjustment, and sintering. The produced FAPPF was then used to cultivate a biofilm for wastewater treatment. The key parameters included a two-stage water extraction process with a 5:1 liquid-to-solid ratio; milling for 1, 2, and 4 h; component adjustment using waste glass powder, milled fly ash, palygorskite powder, and peanut shell powder at a 7:1:1:1 mass ratio; and sintering temperatures ranging from 700 to 1000°C. For the biofilm cultivation and treatment, this study employed semisimulated sewage in a sequencing biofilm batch reactor system. The results revealed the FAPPF had no heavy metal leaching, with a porosity of 48.53%–54.68%. Approximately 90% of its composition was derived from waste materials. Furthermore, scanning electron microscopy microanalysis revealed an internally stable liquid-phase sintering structure. Finally, a mature biofilm developed in 21 days, achieving maximum removal rates of 95.48% for chemical oxygen demand and 78.4% for ammonia nitrogen. This article confirms the sustainable recycling potential of MSWI fly ash.

城市固体废物焚烧(MSWI)飞灰的再利用是一个突出的研究领域。本研究的重点是利用水提取、研磨、成分调整和烧结等技术制造粉煤灰多孔板填料(FAPPF)。然后利用生产出的 FAPPF 培养生物膜,用于废水处理。关键参数包括:两阶段水提取过程,液固比为 5:1;研磨时间为 1、2 和 4 小时;成分调整使用废玻璃粉、研磨粉煤灰、白云石粉和花生壳粉,质量比为 7:1:1:1;烧结温度为 700 至 1000°C。在生物膜的培养和处理方面,本研究采用了半模拟污水的序批式生物膜反应器系统。结果显示,FAPPF 没有重金属浸出,孔隙率为 48.53%-54.68%。其中约 90% 的成分来自废料。此外,扫描电子显微镜显微分析显示了内部稳定的液相烧结结构。最后,在 21 天内形成了成熟的生物膜,化学需氧量和氨氮的最大去除率分别达到 95.48% 和 78.4%。这篇文章证实了 MSWI 粉煤灰的可持续循环利用潜力。
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引用次数: 0
Experimental comparison of solar-powered adsorption-based atmospheric water harvesting using air-to-air & water-to-air heat exchanger for condensation 利用空气-空气和水-空气热交换器冷凝的太阳能吸附式大气集水实验比较
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-23 DOI: 10.1002/ep.14458
Anshu Agrawal, Amit Kumar

Adsorption-focused technologies for atmospheric water harvesting is of great importance. Most of the available systems in the literature use glass as a condenser, which gets heated up. This restricts vapor condensation to harvest less water and hampers the system's scalability. The effectiveness of the proposed solar atmospheric water harvesting system, which uses an air-to-air fin-tube heat exchanger to condense the vapors, is experimentally evaluated in this work. In order to assess the system's effectiveness using a water-to-air fin-tube heat exchanger, a comparison study is also carried out. The experimental setup consists of evacuated tube solar air heater having 8.46 m2 area and 15 kg silica gel adsorbent. The performance metrics for comparison include adsorption & regeneration rate, thermal, overall and exergy efficiency, along with economic analyses. The system harvests 1890 mL/day of water using air-to-air heat exchanger at cost of 0.19 $/l, achieving thermal, overall & exergy efficiencies of 21.66%, 2.24%, and 6.51%, respectively. On the other hand, the water-to-air heat exchanger based system harvests maximum of 2680 mL/day of water at a cost of 0.14 $/l, achieving thermal, overall & exergy efficiencies of 25.65%, 3.34%, and 9.13%, respectively. Moreover, the produced water is confirmed to be safe for consumption.

以吸附为重点的大气水收集技术非常重要。现有文献中的大多数系统都使用玻璃作为冷凝器,玻璃会被加热。这就限制了水汽的凝结,从而减少了水的收集量,并妨碍了系统的可扩展性。拟议的太阳能大气集水系统使用空气-空气翅片管热交换器来冷凝蒸汽,本作品对该系统的有效性进行了实验评估。为了评估使用水-空气翅片管热交换器的系统效果,还进行了对比研究。实验装置包括面积为 8.46 平方米的排空管式太阳能空气加热器和 15 公斤硅胶吸附剂。比较的性能指标包括吸附&;再生率;热效率、总效率和能效,以及经济分析。该系统利用空气-空气热交换器每天收集 1890 毫升水,成本为 0.19 美元/升,热效率、总效率和放能效分别为 21.66%、2.24% 和 6.51%。另一方面,基于水-空气热交换器的系统每天最多可获得 2680 毫升水,成本为 0.14 美元/升,热效率、总效率和放能效分别为 25.65%、3.34% 和 9.13%。此外,生产出的水可安全饮用。
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引用次数: 0
Evaluating the influence of working parameters on the efficiency of a solid oxide fuel cell by conducting sensitivity analysis using electrochemical and thermodynamic modeling 利用电化学和热力学模型进行敏感性分析,评估工作参数对固体氧化物燃料电池效率的影响
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-18 DOI: 10.1002/ep.14457
Ahmed Mouissi, Rabah Touaibi, Hasan Köten

This research article presents an investigation conducted through a numerical model to analyze the influence of various operational parameters on the performance of solid oxide fuel cells (SOFCs). The parameters studied include operating temperature, current density, pressure, steam-to-carbon ratio, and fuel utilization. The electrochemical model employed the Butler-Volmer equation, Fick's model, and Ohm's law to calculate concentration, activation, and ohmic losses. The primary focus was on evaluating the generated power and electrical efficiency as performance metrics. The study revealed that increasing operating temperature and pressure resulted in higher power generation and specific optimum points were identified for optimal SOFC operation. Notably, the highest power generated was 812 kW, achieved at an operating temperature of 950 K and a current density of 18100 A/m2. Additionally, decreasing the fuel utilization factor to 55% at 15250 A/m2 led to a power output of 706 kW. Similarly, at a current density of 17150 A/m2 and a pressure of 400 kPa, the fuel cell generated about 780 kW of power. Furthermore, the research demonstrated that reducing the steam-to-carbon ratio increased power generation, with an optimum power output of 704 kW achieved at a current density of 16000 A/m2 and a low steam-to-carbon ratio. Notably, this point also showcased the improved electrical efficiency of the solid oxide fuel cell. Overall, this study underscores the significance of specific operational factors that significantly impact SOFC performance. By comprehending these parameters, it becomes possible to enhance the utilization of solid oxide fuel cells across various applications.

本研究文章介绍了通过数值模型进行的一项调查,旨在分析各种运行参数对固体氧化物燃料电池(SOFC)性能的影响。研究的参数包括工作温度、电流密度、压力、蒸汽碳比和燃料利用率。电化学模型采用巴特勒-沃尔默方程、菲克模型和欧姆定律来计算浓度、活化和欧姆损失。主要重点是评估作为性能指标的发电功率和电气效率。研究表明,提高工作温度和压力可提高发电量,并确定了 SOFC 最佳运行的特定最佳点。值得注意的是,在工作温度为 950 K、电流密度为 18100 A/m2 时,最高发电功率为 812 kW。此外,在 15250 A/m2 条件下,将燃料利用系数降至 55%,可输出 706 kW 的功率。同样,在电流密度为 17150 A/m2 和压力为 400 千帕时,燃料电池可产生约 780 千瓦的功率。此外,研究还表明,降低蒸汽与碳的比例可增加发电量,在电流密度为 16000 A/m2 和蒸汽与碳比例较低的情况下,最佳发电量为 704 kW。值得注意的是,这一点还显示出固体氧化物燃料电池的电气效率有所提高。总之,这项研究强调了对 SOFC 性能有重大影响的特定运行因素的重要性。通过了解这些参数,可以提高固体氧化物燃料电池在各种应用中的利用率。
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引用次数: 0
Comparative energy metrics and annual efficiency analyses of CPC-ETC integrated single slope solar desalting unit CPC-ETC 一体化单坡太阳能脱盐装置的能源指标比较和年效率分析
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-17 DOI: 10.1002/ep.14452
Ajay Raj Singh, Alka Bani Agarwal, Desh Bandhu Singh

This paper deals with the investigation of N identical compound parabolic concentrator evacuated tubular collector included single slope solar desalting unit (N-CPC-ETC-SSU) by incorporating energy metrics for solving contemporary issue of water scarcity in the society. It will contribute to the sustainable development of society and recede the dependency on fossil fuels, too. The energy metrics investigation is important for energy system because it talks about the feasibility of the system. The methodology consists of getting fundamental equations from energy balance equations. All fundamental equations with relevant data are fed to the code developed in MATLAB followed by the computation of overall energy and exergy. All types of climatic situations have been considered for the analysis. Data required for the same are accessed from IMD, Pune, India. The energy payback period, energy production factor, and life cycle conversion efficiency for N-CPC-ETC-SSU have been calculated at eight number of collectors, 0.012 mass flow rate and 0.14 m water depth. Results of N-CPC-ETC-SSU have been compared with results of SSU included with ETCs. Concludingly, energy payback period is lower by 6.41%, energy production factor is higher by 6.25% and exergy-based life cycle conversion efficiency is higher by 96.39% for N-CPC-ETC-SSU than N-ETC-SSU.

本文探讨了 N 个相同的复合抛物面聚光疏散管式集热器(包括单坡太阳能脱盐装置)的研究,通过纳入能源指标来解决当代社会的水资源短缺问题。这将有助于社会的可持续发展,并减少对化石燃料的依赖。能源指标调查对能源系统非常重要,因为它关系到系统的可行性。该方法包括从能量平衡方程中获取基本方程。所有基本方程和相关数据都被输入到用 MATLAB 开发的代码中,然后计算总能量和放能。分析中考虑了所有类型的气候条件。所需数据来自印度浦那的 IMD。在 8 个集热器、0.012 质量流量和 0.14 米水深条件下,计算了 N-CPC-ETC-SSU 的能源回收期、能源生产系数和生命周期转换效率。N-CPC-ETC-SSU 的结果与包含 ETC 的 SSU 的结果进行了比较。结论是,与 N-ETC-SSU 相比,N-CPC-ETC-SSU 的能源投资回收期缩短了 6.41%,能源生产系数提高了 6.25%,基于放能的生命周期转换效率提高了 96.39%。
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引用次数: 0
Optimal configuration of low-grade waste heat driven seawater desalination using data envelopment analysis: A case study of industrial application 利用数据包络分析法优化低品位余热驱动海水淡化配置:工业应用案例研究
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-17 DOI: 10.1002/ep.14438
Paria Yousefi, Akram Avami

Water supply challenges are caused by population growth, industrialization, as well as the scarcity of freshwater resources. Low-grade waste heat-driven seawater desalination technologies may improve the water-energy nexus issues of desalination systems by different configurations. The data envelopment analysis is used to determine the best final decision to achieve a better comparison of different parameters. The optimal configuration of low-grade waste heat driven seawater desalination is studied using flue gas waste heat in heat recovery boilers of an industrial oil refinery. Nine different types of multistage flash and multi-effect distillation (MED) desalination plants have been considered. The results show that the multistage flash brine recirculation may produce more desalinated water while the multi-effect distillation with three stages (3-stage MED) has the best payback period. Using 3-stage MED with a production of approximately 19,630 kg/h of water from 5.3 MW exhaust gas is more suitable for this design. Thus, the proposed strategy guides us toward the best decisions to configure low-grade waste heat-driven desalination plants for better design considering rigorous simulations for the plants. Moreover, this framework enables us to consider different criteria of technical, economic, and environmental issues for optimal configuration.

人口增长、工业化以及淡水资源稀缺是造成供水挑战的原因。低品位余热驱动海水淡化技术可以通过不同的配置改善海水淡化系统的水能关系问题。数据包络分析用于确定最佳最终决策,以更好地比较不同参数。利用工业炼油厂热回收锅炉的烟气余热,研究了低品位余热驱动海水淡化的最佳配置。考虑了九种不同类型的多级闪蒸和多效蒸馏(MED)海水淡化设备。结果表明,多级闪蒸盐水再循环可生产更多淡化水,而三级多效蒸馏(3 级 MED)的投资回收期最短。使用 3 级 MED,5.3 兆瓦废气的产水量约为 19,630 公斤/小时,更适合本设计。因此,建议的策略指导我们做出最佳决策,配置低品位废热驱动的海水淡化设备,并对设备进行严格模拟,以实现更好的设计。此外,该框架还能让我们考虑技术、经济和环境问题的不同标准,以实现最佳配置。
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引用次数: 0
Drying behavior and nutritional quality of bitter-gourd slices dried in a solar dryer with tray and skewer arrangement 在太阳能干燥器中用托盘和扦子干燥苦瓜片的干燥行为和营养质量
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-16 DOI: 10.1002/ep.14445
Sudarshan M. Borse, Manpreet Singh, Preetinder Kaur, Sukhmeet Singh, Ruchika Zalpouri

In this investigation, we assessed the efficacy of an indirect-type solar drying system that utilized skewers and rack arrangements, comparing it to a conventional drying cabinet equipped with trays for dehydrating bitter gourd slices. We examined the influence of pretreatment methods and loading quantities on the solar drying process for bitter gourd slices in both configurations. The drying behavior of various combinations was scrutinized, and the physicochemical attributes of the dried bitter gourd samples, including total phenolic content, total flavonoid content, total chlorophyll content, antioxidant capacity, ascorbic acid content, and color, were analyzed. Rehydration characteristics, such as rehydration ratio, coefficient of rehydration, percent water in the rehydrated sample, and hardness of the rehydrated sample, were also determined. The bitter gourd slices achieved a final moisture content of 6.84%–8.27% wb after drying from an initial range of 88%–90% wb, within a total elapsed time of 28–55 h. The solar drying cabinet utilizing skewers exhibited enhanced efficiency, featuring reduced drying time and superior product quality compared to the tray-equipped drying cabinet. This improved performance is ascribed to enhanced hot air circulation over the produce surface, facilitated by the uniform spacing between skewers on racks within the drying chamber.

在这项研究中,我们评估了间接型太阳能干燥系统的功效,该系统采用串条和架式排列,并将其与装有托盘的传统干燥柜进行比较,以对苦瓜片进行脱水。我们研究了预处理方法和装载量对两种配置下苦瓜片太阳能干燥过程的影响。我们仔细研究了各种组合的干燥行为,并分析了干燥苦瓜样品的理化属性,包括总酚含量、总黄酮含量、总叶绿素含量、抗氧化能力、抗坏血酸含量和色泽。此外,还测定了复水特性,如复水率、复水系数、复水样品的水分百分比和复水样品的硬度。与配备托盘的干燥箱相比,使用串条的太阳能干燥箱效率更高,干燥时间更短,产品质量更好。这种性能的提高归功于烘干室内架子上的串条之间均匀的间距促进了产品表面的热空气循环。
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引用次数: 0
Ultrasound-assisted synthesis of biodiesel in the presence of a novel catalyst recovered from waste effluent/water: A mini-review 在从废水中回收的新型催化剂存在下超声辅助合成生物柴油:微型综述
IF 2.1 4区 环境科学与生态学 Q3 ENGINEERING, CHEMICAL Pub Date : 2024-07-12 DOI: 10.1002/ep.14450
A. V. S. L. Sai Bharadwaj, Athithyan Ilangovan, K. Sri Bala Kameswari, Dipesh Shikchand Patle, Suantak Kamsonlian

The government of India has mainly focused on waste management, environment protection acts, and control of energy demand, which will lead to the development of a clean and green India. Nowadays most of the drinking water is getting polluted due to the harmful gases released by well-renowned industries mining operations, alloy industries, and dye industries. The presence of more amounts of heavy metals in drinking water leads to a rise in chemical levels than the constrained level in the environment, inside a human body, and any living being. Protection of the environment through the recovery of heavy metals from waste effluents through a chemical activation process using bio-derived activated carbons as adsorbents is one of the known strategies in the current decade that can be adopted. The application of these heavy metals as catalysts in the synthesis of biodiesel from nonedible oils through an ultrasound (US)-assisted process is one of the emerging strategies that will help in the reduction of energy demand. In the current review, the recovery of heavy metals from the waste effluents through a conventional chemical activation process and their applications as catalysts in the US-assisted synthesis of biodiesel from nonedible oils is discussed.

印度政府主要关注废物管理、环境保护法案和能源需求控制,这将促进印度清洁绿色的发展。如今,由于知名的采矿业、合金工业和染料工业释放的有害气体,大部分饮用水都受到了污染。饮用水中含有更多的重金属,导致环境、人体和任何生物体内的化学含量超过了限制水平。利用生物活性炭作为吸附剂,通过化学活化过程从废水中回收重金属,从而保护环境,是当前可采用的已知策略之一。将这些重金属用作催化剂,通过超声(US)辅助工艺从非食用油中合成生物柴油,是有助于减少能源需求的新兴战略之一。在本综述中,讨论了通过传统化学活化工艺从废水中回收重金属,并将其作为催化剂应用于 US 辅助工艺从非食用油中合成生物柴油的问题。
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引用次数: 0
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Environmental Progress & Sustainable Energy
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