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Fixation of BiOI/BiOBr/MoS2 Powders on Fiber Cloths for Photocatalytic Degradation of Ammonia Nitrogen from Aqueous Solution BiOI/BiOBr/MoS2粉末在纤维布上固定光催化降解水溶液中氨氮
Pub Date : 2020-03-31 DOI: 10.5539/ep.v9n1p14
Yi Wei, P. Tang, Minfeng Huang, Yongzhang Pan
A novel photocatalyst powder, BiOI/BiOBr/MoS2, was synthesized by a simple solvothermal method. X-ray diffraction (XRD), specific surface area and pore size analyses, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray energy spectrometry (EDS) were utilized to characterize the prepared samples. After evaluating the photocatalytic performance of the catalyst, it was loaded on the glass fiber and carbon fiber by polyvinylidene fluoride (PVDF) and N-methylpyrrolidone, respectively. The photocatalytic activity of the composite was investigated by the degradation of ammonia nitrogen wastewater. The fiber cloth solved the problem of separation of powder from solution after reaction, and the presence of the binder reduces the agglomeration of the nanoparticles in the water. After four times repeated experiments, the degradation of simulate ammonia nitrogen wastewater by loaded glass fiber and loaded carbon fiber are 74.1% and 60.58%. Fixation of BiOI/BiOBr/MoS2 powders on fiber cloth solve the problem of difficult recovery of powder photocatalytic materials and it can be recycled, which has economic valuable.
采用简单的溶剂热法合成了一种新型光催化剂BiOI/BiOBr/MoS2粉末。利用x射线衍射(XRD)、比表面积和孔径分析、扫描电镜(SEM)、透射电镜(TEM)和x射线能谱(EDS)对制备的样品进行表征。在评价了催化剂的光催化性能后,将其分别用聚偏氟乙烯(PVDF)和n -甲基吡咯烷酮负载在玻璃纤维和碳纤维上。通过对氨氮废水的降解研究了复合材料的光催化活性。纤维布解决了反应后粉末与溶液分离的问题,粘结剂的存在减少了纳米颗粒在水中的团聚。经过4次重复实验,加载玻璃纤维和加载碳纤维对模拟氨氮废水的降解效果分别为74.1%和60.58%。将BiOI/BiOBr/MoS2粉末固定在纤维布上,解决了粉末光催化材料难回收的问题,可循环利用,具有经济价值。
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引用次数: 1
Contamination and Potential Ecological Risk Factors of Potentially Toxic Elements Present in the Soil of Shooting Range: Comparison with the Global Soils 射击场土壤中潜在有毒元素的污染及潜在生态风险因素:与全球土壤的比较
Pub Date : 2020-03-31 DOI: 10.5539/ep.v9n1p37
Saba Shoukat, S. Nazneen, S. Khan, U. Zafar
This study was carried out to determine potentially toxic element (PTE) contamination and their potential ecological risk factors in shooting range soil. For this purpose soil samples were collected from different locations (left side, right side, shooting point, middle, and stop-butt) from the shooting range of Frontier Corps Training Centre (FCTC) present in Warsak, Peshawar. The soil samples were analyzed for pH, electrical conductivity (EC) and potentially toxic elements including Cd, Cr, Ni, Pb, and Zn. The strong acids digested extracts were analyzed using atomic absorption spectrophotometry to determine the concentrations of selected PTEs. The concentration of Pb was found to be maximum at stop-butt i.e. 2049 mg/kg and exceeded the United States Environmental Protection Agency (US-EPA) critical value of 400 mg/kg, while its concentrations at left, right, shooting point and middle were 14.0 mg/kg, 18.8 mg/kg, 47.4 mg/kg, and 18.2 mg/kg, respectively and exceeded the background level of normal soils which is 10 mg/kg for Pb. This study revealed that the shooting range soil was highly contaminated with Pb, and very high contamination factor and potential ecological risk for Pb was observed at stop-butt, very high contamination factor and potential ecological risk for Cd, while moderate contamination factor for Zn was observed at all locations of the shooting range. In Pakistan, the environmental perspective of shooting range soils is overlooked and there is a need to take steps to avoid such contamination of soils with Pb and other PTEs that can enter into food chains and can also leach to contaminate the aquifer. Replacement of vegetation of shooting range with PTE tolerant species, addition of soil conditioners and uncontaminated soil would reduce the mobility of these contaminants into aerial portions of plants and protect the groundwater contamination.
本研究旨在确定靶场土壤中潜在有毒元素(PTE)污染及其潜在生态危险因素。为此目的,从白沙瓦瓦尔萨克边境部队训练中心(FCTC)射击场的不同位置(左侧、右侧、射击点、中间和停靶)收集土壤样本。分析了土壤样品的pH值、电导率(EC)和潜在有毒元素Cd、Cr、Ni、Pb和Zn。采用原子吸收分光光度法对强酸消化的提取物进行分析,以确定所选pte的浓度。停靶处铅浓度最高,为2049 mg/kg,超过美国环境保护署(US-EPA)的临界值400 mg/kg,而左、右、射击点和中间的铅浓度分别为14.0 mg/kg、18.8 mg/kg、47.4 mg/kg和18.2 mg/kg,超过了正常土壤的背景水平(10 mg/kg)。研究结果表明,射击场土壤Pb污染程度较高,停靶处Pb污染系数和潜在生态风险较高,Cd污染系数和潜在生态风险较高,射击场土壤Zn污染系数中等。在巴基斯坦,人们忽视了射击场土壤的环境前景,有必要采取措施,避免铅和其他pte污染土壤,因为它们可能进入食物链,也可能浸出污染含水层。用耐PTE植物替代靶场植被,添加土壤调节剂和未受污染的土壤,可以减少这些污染物向植物空中部分的迁移,保护地下水污染。
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引用次数: 0
Reviewer acknowledgements for Environment and Pollution, Vol. 9, No. 1 环境与污染》第 9 卷第 1 期审稿人致谢
Pub Date : 2020-03-31 DOI: 10.5539/ep.v9n1p54
A. John
Reviewer acknowledgements for Environment and Pollution, Vol. 9, No. 1, 2020.
环境与污染》,第 9 卷第 1 期,2020 年,审稿人致谢。
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引用次数: 0
Aliphatic Hydrocarbons in Recent Dated Sediment Cores of Imo River, SE Nigeria: Environmental/Historical Implications 尼日利亚东南部伊莫河沉积物岩心中脂肪烃的环境/历史意义
Pub Date : 2020-03-31 DOI: 10.5539/ep.v9n1p26
I. Oyo-Ita, U. Umoh, Ugim S. Ugim, E. Oyo-ita, O. Oyo-ita
Four recent sediment cores (0-30 cm long) from Afam (AF), Mangrove (MG), Estuary (ES) and illegal Petroleum refinery (PT) sites of the Imo River, Southeastern Nigeria were analyzed to characterize the sources and distribution of organic matter (OM), as well as examine their historical trends of deposition and assess human-induced changes in the last ca. 5 decades using biomarker approach. Radionuclides 210Pb and 137Cs were used to assign approximate dates to each section of the cores. Evaluation of proxy parameters such as carbon preference index (CPI, 2.01 - 2.19), carbon number maximum (Cmax, 29, 31) and atomic C/N (16.51-31.32) for the most recent top layers (0-5 cm) revealed greater wash-in of land-derived organic matter (OM), attributable to the recent rise in water height. The bottom layer (PT1, 25-30 cm,) of the PT core deposited ca. 1964-1972 exhibited a CPI of 0.97 and pristane/phytane (Pr/Ph, 3.75), suggesting that oil bunkering/illegal refinery activity had begun in the region ca. 8 years after the first commercial discovery of oil in Nigeria in 1956. The occurrence in high abundance of heptadecane in the middle layer (ES4, 10-15 cm) of the ES almost corresponded with the period of eutrophication that blocked the waterway in the late 1980s. Measurement of a marked unresolved complex mixture at the near-top layer (AF5, 5-10 cm) of the AF indicated that the heaviest contamination by petroleum hydrocarbons occurred at ca. 1997-2005. This time frame coincided with the period of intensive bunkering and oil pipeline vandalism by Niger Delta militant groups.
本文分析了尼日利亚东南部伊莫河阿法姆(Afam)、红树林(MG)、河口(ES)和非法炼油厂(PT)的四个沉积物岩心(0-30厘米长),以表征有机质(OM)的来源和分布,并研究了它们的沉积历史趋势,并利用生物标志物方法评估了近50年来人类活动引起的变化。放射性核素210Pb和137Cs被用于确定每个岩心剖面的大致日期。最近的表层(0 ~ 5 cm)碳偏好指数(CPI, 2.01 ~ 2.19)、最大碳数(Cmax, 29、31)和原子C/N(16.51 ~ 31.32)等代理参数的评价表明,由于近期水位上升,陆源有机质(OM)被冲入较多。沉积于1964-1972年的PT岩心底层(PT1, 25-30 cm) CPI为0.97,柱甾/植烷(Pr/Ph)为3.75,表明该地区在1956年尼日利亚首次商业发现石油后约8年就开始了石油加注/非法炼油活动。在ES中层(ES4, 10-15 cm)出现的高丰度十七烷几乎与20世纪80年代后期富营养化阻塞水道的时期相对应。在近表层(AF5, 5-10 cm)测量了一个明显的未溶解的复杂混合物,表明石油烃污染最严重的时间大约在1997-2005年。这段时间恰逢尼日尔三角洲武装组织密集加油和破坏石油管道的时期。
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引用次数: 1
Africa’s Urban Waste Management and Sanitation Challenges: Are Transfer Stations the Solution? 非洲城市垃圾管理和卫生挑战:中转站是解决方案吗?
Pub Date : 2019-11-29 DOI: 10.5539/ep.v9n1p1
Bob O. Manteaw, Johannes Boachie
Africa’s urbanization processes are seen as both a challenge and an opportunity for sustainable development. While these processes unfold differently in diverse countries across the continent, it has become increasingly apparent that surge urbanization, population growth and the lack of effective planning for an efficient waste management system have brought in its wake other challenges that have significant implications for public health and sustainable development. Thus, much as urbanization has the potential to drive Africa’s growth and sustainable development agenda, current happenings in most of Africa’s cities, in particular, also signal the negative impact of rapid and unplanned urbanization on sustainable development processes. Waste and sanitation management have become an enduring urban challenge across Africa. They come with significant cost to people and governments and as the search for lasting solutions continue, Waste Transfer Stations have emerged as an efficient management technology which has been embraced and deployed in some countries. While it has received praises in some quarters as an innovative technology, there is concern that such praises have muted critical issues of pollution, odor nuisance, cultural incompatibility and public health challenges, which, for the most part, are unrecognized or underestimated. The question then becomes: are Waste Transfer Stations the solution to Africa’s urban waste and sanitation challenges?
非洲的城市化进程被视为可持续发展的挑战和机遇。虽然这些进程在非洲大陆不同国家的发展情况不同,但越来越明显的是,城市化的迅速发展、人口增长和缺乏有效的废物管理系统规划,带来了对公共卫生和可持续发展具有重大影响的其他挑战。因此,尽管城市化有可能推动非洲的增长和可持续发展议程,但非洲大多数城市目前发生的情况也表明,快速和无计划的城市化对可持续发展进程产生了负面影响。废物和卫生管理已成为整个非洲城市面临的一项持久挑战。它们给人民和政府带来了巨大的成本,随着寻求持久解决办法的继续,废物转运站已成为一种有效的管理技术,已在一些国家得到接受和部署。虽然它在某些方面被称赞为一种创新技术,但有人担心,这种赞扬掩盖了污染、气味骚扰、文化不相容和公共卫生挑战等关键问题,这些问题在很大程度上没有得到承认或低估。那么问题就变成了:垃圾转运站能解决非洲城市垃圾和卫生问题吗?
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引用次数: 3
Does Knowledge about Earthquake Vary with Respondent’s Socio-Demographic Dimensions? A Study in Sylhet City of Bangladesh 地震知识是否随受访者的社会人口维度而变化?在孟加拉国锡尔赫特市的研究
Pub Date : 2019-09-29 DOI: 10.5539/ep.v8n2p8
M. Ahmed
The prime and foremost purpose of this study was to explore climate change perception among indigenous people living in Sylhet, Bangladesh. This study also tried to investigate the nexus between some socio-demographic dimensions of the respondents and their perception regarding climate change. The present study followed descriptive-explanative research design where survey method used to collect necessary data. In case of survey method, a self-developed semi structured questionnaire was provided to the respondents for collecting relevant data. Total number of population was 75 and 63 respondents has been interviewed following the sample size estimation of Nurul Islam (2011). Findings of this study revealed that, there is a statistically significant difference between some socio-demographic dimensions (like; Age, Family type, Education and Income) and climate change perception. Furthermore, no statistically significant relationship found between Gender, Religion, Savings and climate c...
本研究的主要目的是探讨居住在孟加拉国锡尔赫特的土著居民对气候变化的看法。本研究还试图调查受访者的一些社会人口因素与他们对气候变化的看法之间的关系。本研究采用描述性-解释性研究设计,采用调查方法收集必要的数据。在调查方法方面,我们向受访者提供了一份自行开发的半结构化问卷,以收集相关数据。人口总数为75人,根据Nurul Islam(2011)的样本量估计,采访了63名受访者。本研究的结果显示,在一些社会人口统计学维度(如;年龄、家庭类型、教育和收入)和气候变化感知。此外,性别、宗教、储蓄与气候变化之间没有统计学上的显著关系。
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引用次数: 0
The Comparison of Acute Toxicity (96h) of Copper (CuSO4) in Cyprinus Carpio and Rutilus Rutilus 铜(CuSO4)对鲤鱼(Cyprinus Carpio)和贻贝(Rutilus Rutilus) 96h急性毒性的比较
Pub Date : 2019-09-29 DOI: 10.5539/ep.v8n2p21
M. Farhangi, H. Jafaryan
The experiments were conducted to study of the acute toxicity of Cyprinus carpio and Rutilus rutilus by added copper salt in basins. 13 fishes with average weight of 2±0.5g to Rutilus rutilus and 20±2.2g Cyprinus carpio were exposed to different concentrations of copper salt respectively. The experiments were done by Static Method during 96 hours. A group of fish was considered as control samples. The different concentrations of copper such as 0, 0.1, and 0.2, 0.3, 0.4, 0.45 and 5mgL-1 were used to Rutilus rutilus and Cyprinus carpio fishes. Under stable condition (TOC and pH), the lethal concentration of copper was measured of 0.4mgL-1 and 0.45mgL-1 to Rutilus rutilus and Cyprinus carpio respectively during of 96 hours. The results indicated the significant differences were observed between treatments of fish with each other and also with the control samples. With increasing of copper in each treatment, the mortality rate of fish significantly was increased. Histopathological findings showed that major lesions were hemorrhage, hyperemia, hyperplasia and epithelial cells necrosis in total fish. Also in the lesion fish were observed degenerated tubules of their kidney, expansion of Bowman's capsule and hepatocytes necrosis.
在盆地中添加铜盐,研究了鲤鱼(Cyprinus carpio)和贻贝(Rutilus Rutilus)的急性毒性。将13条平均体重为2±0.5g的Rutilus Rutilus和20±2.2g的Cyprinus carpio鱼分别暴露于不同浓度的铜盐中。实验时间为96小时,采用静力法。一组鱼作为对照样本。分别用0、0.1、0.2、0.3、0.4、0.45、5mg -1不同浓度的铜对Rutilus Rutilus和Cyprinus carpio鱼进行处理。在TOC和pH稳定的条件下,测定了96 h内铜的致死浓度分别为0.4mg -1和0.45mg -1。结果表明,不同处理的鱼之间以及与对照样品之间存在显著差异。随着各处理铜含量的增加,鱼的死亡率显著升高。组织病理学结果显示,全鱼的主要病变为出血、充血、增生和上皮细胞坏死。病变鱼的肾小管变性,鲍曼囊膨大,肝细胞坏死。
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引用次数: 5
The Influence of Social Interaction Learning Model, Learning Motivation, Social Attitude on the Student Learning Result of Geographic Subject in Public Senior High Schools in Aceh Province 社会互动学习模式、学习动机、社会态度对亚齐省公立高中学生地理学科学习效果的影响
Pub Date : 2019-09-29 DOI: 10.5539/ep.v8n2p41
T. Sahudra, M. Murniati, Deny Setiawan, Alamsyah Taher
Purpose – The aim of this research is to test the difference of sudents learning outcome of Geographic subject taught with social inquiry learning model, social simulation and students’ social investigation, social behavior, learning motivation of SMA in Aceh Province. Design/methodology/approach – The research methodology employed in his research was quasi-experimental with the design using a Non-equivalent Control Group Design method. The experimental class and the control of this research are selected randomly. The subject of this research is ninth grade student of public SMA in Aceh Province, Indonesia. Based on the early observation that the researcher conducts, total public SMA in Aceh is 344 schools. This study took 3 (three) study group of every SMA to be managed as a research subject, which was a class taught using a group investigation, social inquiry, and social simulation learning method. Data analysis technique is inferential analysis intended to test the research hypothesis conducted by using varians analysis technique (ANAVA). Findings – The findings that there are no differences in student learning outcomes of Geography subject taught with social inquiry learning models (A1), social simulation learning models (A2) and group investigative learning models (A3). There are differences in the learning outcome of geography subject and different social attitude, which is a high social attitude (B1) and social attitude (B2). There is an interaction between the learning model (A), social attitudes (B) and learning motivation (C). There is an interaction between learning models (A) and social attitudes (B). There is an interaction between learning model (A) and learning motivation (C). There is an interaction between learning model (A) and learning motivation (C). Originality/value – The research on the application of social interaction learning model to improve learning motivation, social attitude, and students learning outcome at the geographic subject of SMA in Aceh Province, Indonesia.
目的:本研究的目的是检验亚齐省采用社会探究学习模式、社会模拟教学的地理学科学生学习成果与SMA学生的社会调查、社会行为、学习动机的差异。设计/方法/方法-他的研究采用的研究方法是准实验的设计,使用非等效对照组设计方法。本研究的实验班和对照组是随机选取的。本研究以印尼亚齐省公共SMA九年级学生为研究对象。根据研究人员进行的早期观察,亚齐的公共SMA总数为344所学校。本研究以每个SMA管理的3(3)个学习小组为研究对象,采用小组调查、社会探究、社会模拟学习法进行授课。数据分析技术是运用方差分析技术(ANAVA)对研究假设进行检验的推论分析。研究发现:采用社会探究性学习模式(A1)、社会模拟学习模式(A2)和小组调查性学习模式(A3)教学的地理学科学生的学习成果没有差异。地理学科的学习结果与不同的社会态度存在差异,社会态度(B1)和社会态度(B2)较高。学习模式(A)、社会态度(B)和学习动机(C)之间存在交互作用,学习模式(A)和社会态度(B)之间存在交互作用,学习模式(A)和学习动机(C)之间存在交互作用,学习模式(A)和学习动机(C)之间存在交互作用。原创性/价值——应用社会互动学习模式提高学习动机、社会态度、以及印度尼西亚亚齐省SMA地理学科的学生学习成果。
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引用次数: 0
The Environmental Impact of Sturgeon Pen Culture on Diversity and Spatial Distribution Patterns of the Benthic Macro Fauna Communities in Gorgan Bay 鲟池养殖对高根湾底栖大型动物群落多样性及空间分布格局的环境影响
Pub Date : 2019-09-29 DOI: 10.5539/ep.v8n2p31
Farhangi Mohammad, Hosseini Seyyed Abbas, Jafaryan Hojatollah, Ghorbani Rasoul, Harsij Mohammad, S. Mohammad
Community structure and biodiversity of benthic macro fauna in around pen culture of Sturgeon fish in Gorgan Bay were studied for period of one year from August 2015 to July 2016. Seasonal samplings were carried out at 5 stations in 3 transects. In addition, depth (D), water temperature (Toc), dissolved oxygen (DO); pH, total dissolved solid (TDS), biological oxygen demand (BOD5), chemical oxygen demand (COD), phosphorus (PO4-3), nitrite (NO2-) and total ammonia (NH3+) were measured in each station. Results of season variations of Physico – chemical factors of water showed that, there were no significant differences between PO4-3 (p>0.05). However, there were significant differences between BOD5, COD, NO2-, NH3+ and TDS (p<0.05). Totally, 11 genus's and 10 families belong to 3 phyla as Mollusks, Arthropods and Annelids were identified. The results showed, there were the maximum abundance percent belong to Hydrobiidae and Cochliopidae with 33.83% and 26.25% and the minimum abundance percent belong to Gammaridae with 0.05% respectively. However, the maximum abundance belongs to Pyrgohydrobia sp., from Hydrobiidae with 3410 n/m2. The results showed, there were the maximum and minimum abundance percent in autumn and spring with 1.07 and 0.88 % respectively. The results of distance-based redundancy analysis (db.-RDA) revealed that environmental factors such as depth, DO and TDS are all important in determining the distribution of macro benthic species in Gorgan Gulf. However, there were significant differences between abundance, species number (S), diversity (as Shannon–Wiener’s, H´), species richness (as Margalef’s, D), and evenness (as Pielou’s, J) (p<0.05). There were the most diversity species in 2 and 5 stations.
本文于2015年8月至2016年7月对戈尔根湾鲟鱼围场周围底栖大型动物群落结构和生物多样性进行了为期1年的研究。在3个样带的5个站点进行了季节性采样。此外,深度(D)、水温(Toc)、溶解氧(DO);测定各监测站pH、总溶解固溶体(TDS)、生物需氧量(BOD5)、化学需氧量(COD)、磷(PO4-3)、亚硝酸盐(NO2-)和总氨(NH3+)。水体理化因子的季节变化结果显示,PO4-3与PO4-3之间无显著差异(p>0.05)。而BOD5、COD、NO2-、NH3+、TDS之间差异有统计学意义(p<0.05)。共鉴定出软体动物、节肢动物和环节动物3门11属10科。结果表明:水蠓科和蜗蠓科的丰度最高,分别为33.83%和26.25%;伽马蠓科的丰度最低,分别为0.05%;然而,丰度最高的是Pyrgohydrobia sp.,来自Hydrobiidae,为3410 n/m2。结果表明:秋季丰度最大,春季丰度最小,分别为1.07和0.88%;基于距离的冗余分析(db.-RDA)结果表明,深度、DO和TDS等环境因子对戈尔根湾大型底栖生物的分布都有重要影响。丰度、物种数量(S)、多样性(Shannon-Wiener’S, H’S)、物种丰富度(Margalef’S, D)和均匀度(Pielou’S, J)之间存在显著差异(p<0.05)。2和5个站点的物种多样性最大。
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引用次数: 0
Production and Characterization of Rice Husk Biosorbent from Far North Cameroon 喀麦隆远北稻壳生物吸附剂的生产与性能研究
Pub Date : 2019-09-03 DOI: 10.5539/ep.v8n2p1
Elie Kolwa Doboy, H. Z. Adjia, R. Kamga
The objective of this study is the production and the characterization of rice husk biosorbent. In fact, the biosorbent has been obtained by phosphoric acid treatment; its physicochemicals characteristics such as point of zero charge, specific surface, iodine number and chemicals functions have been determined. The analysis indicaded that, the point of zero charge is 8.7; for the pH value less than 8.7, the biosorbent surface is posotively charged and for pH value higher than 8.7, the biosorbent surface is negatively charged. The biosorbent iodine number is 1560.87±1 mg/g, it means that, the biosorbent is constituted in majority of microspores. Furthermore, the specific surface of biosorbent is 104.45±1m2/g, it is five times as big than untreated rice husk obtained by Dada and al., (2012). Acid treatment improve the porosity of biosorbent. Infrarouge spectrum present ether and aromatic functions.
对稻壳生物吸附剂的制备及性能进行了研究。事实上,生物吸附剂已通过磷酸处理获得;测定了其零电荷点、比表面、碘值和化学功能等理化特性。分析表明,零电荷点为8.7;pH值小于8.7时,生物吸附剂表面带正电;pH值大于8.7时,生物吸附剂表面带负电。生物吸附剂碘值为1560.87±1 mg/g,说明该生物吸附剂主要由小孢子组成。此外,生物吸附剂的比表面积为104.45±1m2/g,是Dada等(2012)获得的未经处理稻壳的5倍。酸处理提高了生物吸附剂的孔隙率。红外光谱中存在醚和芳香族功能。
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引用次数: 6
期刊
Environment and Pollution
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