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Ecological Risk Assessment of Heavy Metals in Sediments from the Soubeira Reservoir, a Small-Scale Reservoir in North Central Burkina Faso, West Africa 西非布基纳法索中北部小型水库Soubeira水库沉积物重金属生态风险评价
Pub Date : 2018-03-30 DOI: 10.5539/EP.V7N1P66
Souleymane Pelede, A. Sako, O. Bamba
Small-scale reservoirs play a central role in socio-economic development of Burkina Faso. In the absence of a best environmental management plan, these reservoirs can be potential factors of water pollution and ecological deterioration. In the present study, we investigated ecological status of sediments from the Soubeira reservoir, using concentrations of a series of heavy metals. Concentrations of the metals ranked as follows: Fe> Mn> Cr> Zn> Cu> Pb> As ~ Co> Hg ~Mo> Cd. Based on the correlation analysis, Fe, with weaker relationships with other metals, may be derived from the local ferruginous soil, whereas Cd, Cu and Cr could be mainly originated from anthropogenic sources and carried by clay minerals into the reservoir. In contrast, Hg and As abundance could be related to artisanal gold mining in the surrounding environment. Negative correlations between heavy metals (except As) with pH were consistent with desorption and mobility of the majority of heavy metals under low pH values. The significant negative correlations were also observed between CEC and As (r = - 0.75) and between clay and As (r = -0.64). This could be an indication of As mobility under the physico-chemical conditions of the reservoir. Both potential ecological risk and adverse effect indices suggested that the reservoir sediments were highly polluted. Five heavy metals (As, Cd, Cu, Cr and Hg) could cause adverse effect to biota, whilst only Hg and Cd appeared to show high and moderate potential ecological risk indices, respectively. The study demonstrated that the Soubeira reservoir requires a heavy metal pollution control program.
小型水库在布基纳法索的社会经济发展中发挥着核心作用。在缺乏最佳环境管理计划的情况下,这些水库可能成为水污染和生态恶化的潜在因素。在本研究中,我们利用一系列重金属浓度研究了Soubeira水库沉积物的生态状况。各金属的富集程度依次为Fe> Mn> Cr> Zn> Cu> Pb> as ~ Co> Hg ~Mo> Cd。相关性分析表明,Fe可能来源于当地含铁土壤,与其他金属的相关性较弱,而Cd、Cu和Cr可能主要来源于人为来源,并由粘土矿物携带进入储层。汞和砷的丰度可能与周围环境的手工采金有关。重金属(As除外)与pH呈负相关,与低pH条件下大多数重金属的解吸和迁移率一致。CEC与As呈负相关(r = - 0.75),粘土与As呈负相关(r = -0.64)。这可能是储层物理化学条件下砷迁移率的指示。潜在生态风险指标和不利影响指标均表明水库沉积物污染严重。5种重金属(As、Cd、Cu、Cr和Hg)均对生物区系产生不利影响,其中Hg和Cd分别表现出高、中潜在生态风险指数。研究表明,苏贝拉水库需要制定重金属污染控制方案。
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引用次数: 1
Coupled Flow Modelling for a Geothermally Facilitated Bioreactor 地热促进生物反应器的耦合流动模型
Pub Date : 2018-03-30 DOI: 10.5539/ep.v7n1p81
Lucila B. Dunnington, M. Nakagawa
Abandoned mines across the world leak contaminated waters into precious water resources, threatening human populations and natural environments alike. The primary demand from the industry for addressing the contamination is a passive system that utilizes locally available and cheap material, with little energy or maintenance requirement. Passive treatment systems can operate in remote regions, using diverse, inexpensive, and locally available material with low waste production, but are subject to ambient conditions and are often space intensive. The geothermal gradient available at abandoned mines is a viable heat energy source that can provide advantageous temperature conditions for established remediation techniques, namely bioremediation.Currently, the primary models used for testing new passive designs are either largely empirically based, or limit the scope of modelling parameters, making it difficult to incorporate innovative design aspects into the existing modelling framework. The following paper presents a model, based on kinetic parameters from a column experiment, which couples mechanics, thermodynamics, hydrodynamics, and microbial kinetics. The modelling results show the effect of an imposed temperature gradient on the permeability and microbially driven reactions of a bioreactor. The model reflects evolving thermal and mass transfer in the multiphase system. The addition of geothermal energy to a bioreactor is shown to improve long-term permeability, enhance reactions and precipitation kinetics, and decrease the necessary spatial expanse of designed bioreactor systems.
世界各地的废弃矿井将受污染的水泄漏到宝贵的水资源中,威胁着人类和自然环境。工业对解决污染的主要需求是一种被动系统,利用当地可用的廉价材料,几乎没有能源或维护需求。被动处理系统可以在偏远地区运行,使用各种廉价的、当地可获得的材料,废物产生量低,但受环境条件的限制,往往占用大量空间。废弃矿山可利用的地热梯度是一种可行的热能来源,可以为已建立的修复技术,即生物修复提供有利的温度条件。目前,用于测试新被动设计的主要模型要么主要基于经验,要么限制了建模参数的范围,这使得很难将创新设计方面纳入现有的建模框架。本文提出了一个基于柱实验动力学参数的模型,该模型结合了力学、热力学、流体力学和微生物动力学。模拟结果显示了施加温度梯度对生物反应器的渗透性和微生物驱动反应的影响。该模型反映了多相系统中不断变化的传热传质过程。在生物反应器中添加地热能可以改善长期渗透性,增强反应和沉淀动力学,并减少设计的生物反应器系统所需的空间扩展。
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引用次数: 0
How a Taxonomically-Ambiguous Cyanobiont and Vanadate Assist in the Phytoremediation of Cadmium by Azolla pinnata: Implications for CKDu 分类上不明确的蓝藻和钒酸盐如何协助植物修复羽状杜鹃中的镉:对CKDu的影响
Pub Date : 2018-03-30 DOI: 10.5539/EP.V7N1P53
D. R. A. M. T. R. Atugoda, L. Mandakini, N. Bandara, D. Gunawardana
We employed scientific tools to investigate the ex situ phytoremediation of cadmium by Azolla pinnata. Azolla pinnata was capable of efficient sequestration of cadmium up to a concentration of 1 ppm, though with a visibly high “physiological cost”. The sequestration of cadmium (1 ppm) was strongly reduced after 24 hours, in Azolla plants pre-treated with the gram-negative antibiotic erythromycin (60 µg/l), suggesting that the cyanobacterial population was important for phytoremediation. Only the co-treatment of 1 ppm cadmium with 1 ppm vanadate, showed significantly higher phytoremediation (P<0.05) compared to the “cadmium+erythromycin” treatment. The phytoremediation of Cadmium by the Azolla-Nostoc symbiosis was significantly (p<0.05) improved by the addition of citrate at 10 ppm in the presence of 1 ppm vanadate, compared to the 1 ppm cadmium only treatment. We hypothesize that citrate acting either as “vanadophores” or working as a cofactor in the Homocitrate Synthase enzyme, facilitates remediation of cadmium. When phylogeny was inferred using Homocitrate Synthases, the cyanobiont was approximated to a taxonomical twilight zone between Nostoc and Anabaena, although showing more proximity to the Anabaena cluster. It is proposed here that the cyanobacterial contribution appears to be crucial for the ability of Azolla pinnata to efficiently remediate cadmium and a “helping hand” appears to be provided by a vanadate dependent mechanism, which is likely to be nitrogen fixation. The association between vanadate-assisted phytoremediation by Azolla pinnata and the heightened bioavailability of vanadium in CKDu endemic areas, could serve as a vital stepping stone in developing a biological solution to CKDu.
采用科学手段研究了凤尾花对镉的迁地修复作用。尽管具有明显的高“生理成本”,但凤尾花能够有效地隔离浓度高达1ppm的镉。经革兰氏阴性抗生素红霉素(60µg/l)预处理后,24小时后,绿藻种群对镉(1 ppm)的固存显著降低,表明蓝藻种群对植物修复具有重要作用。仅1 ppm镉与1 ppm钒酸盐共处理的植物修复效果显著高于“镉+红霉素”处理(P<0.05)。在钒酸盐浓度为1 ppm的情况下,添加10 ppm柠檬酸盐比只添加1 ppm镉的情况下,Azolla-Nostoc共生对镉的修复能力显著提高(p<0.05)。我们假设柠檬酸盐要么作为“钒吸收剂”,要么作为高柠檬酸合酶的辅助因子,促进镉的修复。当使用同柠檬酸合成酶推断系统发育时,蓝藻被近似于Nostoc和Anabaena之间的分类模糊区,尽管显示出更接近Anabaena集群。本文提出,蓝藻的贡献似乎对红豆菜有效修复镉的能力至关重要,而钒酸盐依赖机制似乎提供了“援助之手”,这可能是固氮机制。研究了钒酸盐辅助植物修复与高钒生物利用度之间的关系,为开发生物解决方案提供了重要的基础。
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引用次数: 2
Region EKC for Air Pollution: Evidence from China 空气污染的区域EKC:来自中国的证据
Pub Date : 2018-03-30 DOI: 10.5539/EP.V7N1P46
Wenzhong Wang
In recent years, with the increasing care of environmental issues, the relationship between air quality and the level of economic development has been widely studied. In the present paper, a traditional EKC model and two improved model are built to analyze the relationship between the air quality index and the per capita GDP with the panel data of 41 major cities during 2000 and 2015 of China. By the co-integration analysis, the results show that under the three-square EKC model, the relationship between the AQI and GDP per capita satisfies the N-shaped environment Kuznets curve and there exist two turning points. In the form of the traditional two-square EKC model, the two variables are satisfied with the U-shaped relationship. The results of the growth rate model also show that the two variables are satisfied with the U-shaped relationship, but there are differences among the turning points.
近年来,随着人们对环境问题的日益关注,空气质量与经济发展水平之间的关系得到了广泛的研究。本文利用2000年至2015年中国41个主要城市的面板数据,构建了传统EKC模型和两个改进模型,分析了空气质量指数与人均GDP的关系。协整分析结果表明,在三平方EKC模型下,AQI与人均GDP的关系满足n型环境库兹涅茨曲线,存在两个拐点。在传统的二平方EKC模型形式中,两个变量满足u型关系。增长率模型的结果也表明,两个变量满足u型关系,但拐点之间存在差异。
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引用次数: 4
Effects of Seasonal Variation on Informal Waste Collection in Ibadan, South-west Nigeria 季节变化对尼日利亚西南部伊巴丹非正式废物收集的影响
Pub Date : 2018-03-30 DOI: 10.5539/EP.V7N1P36
B. Wahab, B. Ola
Despite the active participation of informal waste collectors (IWCs) in waste management in Ibadan, south-west Nigeria, a major observed challenge to effective operation of this group of workers is the variation in the seasons of the year and their accompanying weather futures. This study investigated the effects of seasonal changes on the types and volume of waste handled by the informal waste collectors, level of patronage and income earned in the five municipal local government areas of Ibadan. A cross-sectional survey approach was adopted and both primary and secondary data were sourced. Through questionnaire survey and field observations, data were collected from 253 informal waste collectors operating in the study area. Descriptive statistics (frequencies and percentages) and inferential statistics (ANOVA) were used in analysing the data obtained from the field work. The study established that the types and volume of waste collected and income earned by the informal waste collectors varied from season to season. Patronage of the informal waste collectors was found to be reduced by about 25% in the dry season owing to less volume of waste generated and increased burning. The low patronage reduced the income by about 25% on average. The implications of this are that the job security of IWCs is threatened and increased burning of waste increases the atmospheric carbon content, which depletes the ozone layer and consequently results in global warming. The study, therefore, recommended financial and technical assistance to the waste collectors by either government or non-governmental organisations to establish small waste merchandising business to cater for the period of low patronage.
尽管尼日利亚西南部伊巴丹的非正式废物收集者积极参与废物管理,但这组工人有效运作的一个主要挑战是一年中的季节变化及其伴随的天气未来。这项研究调查了季节变化对伊巴丹五个城市地方政府地区非正规废物收集者处理的废物种类和数量、赞助水平和收入的影响。采用了横断面调查方法,并获得了第一手和第二手数据。通过问卷调查和实地观察,收集了研究地区253名非正式废物收集者的数据。描述性统计(频率和百分比)和推理统计(方差分析)用于分析从实地工作中获得的数据。这项研究确定,收集的废物种类和数量以及非正式废物收集者的收入因季节而异。由于产生的废物量减少和燃烧增加,发现在旱季,非正式废物收集商的光顾减少了约25%。低赞助使收入平均减少了约25%。这意味着iwc的工作保障受到威胁,废物燃烧的增加增加了大气中的碳含量,这消耗了臭氧层,从而导致全球变暖。因此,研究建议政府或非政府机构向废物收集商提供财政和技术援助,以建立小型废物售卖业务,以应付顾客少的时期。
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引用次数: 5
Anthophyllite Asbestos: The Role of Fiber Width in Mesothelioma Induction Part 2: Further Epidemiological Studies of Occupational, Domestic and Environmental Exposure to Finnish Anthophyllite Asbestos 花石石棉:纤维宽度在间皮瘤诱发中的作用。第二部分:芬兰花石石棉职业、家庭和环境暴露的进一步流行病学研究
Pub Date : 2018-03-19 DOI: 10.5539/EP.V7N1P24
E. Ilgren, J. Hoskins
Although people in all sectors of the Finnish anthophyllite industry, including their families, have been heavily exposed to anthophyllite there is no evidence for even a single proven case of attributable mesothelioma. A few cases have been claimed but the evidence either, that they were mesotheliomas or that amphibole exposure was solely to anthophyllite is, in every case examined, insufficient. Even among the population who lived in Karelia in Central Finland who were exposed domestically or enviromentally to anthophyllite released during agricultural and various domestic activities and during transport from the mines, Finnish epidemiology found no risk of mesothelioma. There is also an absence of mesotheliomas reported in the earlier Finnish literature. This anomaly compared to the effects of exposure to other amphiboles is strong support for the role of fiber width in mesothelioma production. Anthophyllite, though, is not without clinical effect. As screening techniques improved it was discovered that of every person over the age of 65 years, one third living in Karelia had bilateral pleural plaques. The area was henceforth called the Endemic Pleural Plaque (EPP) zone. Radiographic analysis of the residents living in the district of Kuusjarvi led to suggestions that the cases resulted from asbestos blown from the Paakila facility via fiber drift as far away as 30 km. Later studies showed that ‘fiber drift’ was very unlikely to be a factor in the radiological findings thus observed.
尽管芬兰花青石行业所有部门的人,包括他们的家庭,都大量暴露于花青石中,但没有证据表明,甚至没有一例可归因于间皮瘤的病例。有一些病例被证实,但证据表明,它们是间皮瘤或角闪孔暴露仅仅是花青石,在每一个病例中,都是不足的。即使居住在芬兰中部卡累利阿的人口在农业和各种家庭活动以及从矿山运输过程中暴露于家庭或环境中释放的花青石,芬兰流行病学也没有发现间皮瘤的风险。在早期芬兰文献中也没有间皮瘤的报道。与暴露于其他角闪石的影响相比,这种异常现象有力地支持了纤维宽度在间皮瘤产生中的作用。然而,花青石并非没有临床效果。随着筛查技术的改进,人们发现,生活在卡累利阿的每65岁以上的人中,有三分之一患有双侧胸膜斑块。这一地区从此被称为地方性胸膜斑块区。对Kuusjarvi地区居民的放射学分析表明,这些病例是由Paakila工厂的石棉通过纤维飘流吹到30公里外造成的。后来的研究表明,“纤维漂移”不太可能是观察到的放射学结果的一个因素。
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引用次数: 1
Anthophyllite Asbestos: The Role of Fiber Width in Mesothelioma Induction Part 1: Epidemiological Studies of Finnish Anthophyllite Asbestos 石棉:纤维宽度在间皮瘤诱导中的作用。第一部分:芬兰石棉的流行病学研究
Pub Date : 2017-11-15 DOI: 10.5539/EP.V7N1P9
E. Ilgren, J. Hoskins
Anthophyllite asbestos only occurs in a few parts of the world in sufficient quantities to be mined. The largest deposits of anthophyllite asbestos occur in Finland where it was mined for more than 75 years and very extensively used and distributed, anciently, for more than six millennia. Anthophyllite is one of the five minerals known collectively as amphibole asbestos. Studies of the effect of these five mineral fibre types when inhaled have shown that fibre width is an important determinant of mesothelioma induction. Only the “thinner” fibres or those with fiber diameter dimensional profiles predominantly less than 0.25 – 0.30 µm, are clearly mesotheliogenic. The “thicker” ones or those whose predominant widths are greater than these diameters do not appear to show an observable attendant risk of mesothelioma. Observations based on studies of at least, two “thick” forms of amphibole asbestos support these hypotheses. The one is Bolivian crocidolite; the other Finnish anthophyllite. The Finnish anthophyllite industry presents an important opportunity to study the robustness of the theory that fibre width is key to mesothelioma genesis as vast numbers of people in all sectors of the Finnish industry and their families have historically incurred massive fiber exposures sufficient to cause a gross excess of asbestosis. Nonetheless, in spite of these long term, high dose exposures clear evidence for a mesothelioma risk due to anthophyllite asbestos is still lacking.
anthophylite石棉只在世界上少数几个地方有足够的开采量。最大的花青石石棉矿床位于芬兰,在那里它被开采了75年以上,并且在古代被广泛使用和分布了6000多年。花青石是五种矿物之一,统称为角闪孔石棉。对吸入这五种矿物纤维的影响的研究表明,纤维宽度是诱导间皮瘤的重要决定因素。只有“较薄”的纤维或那些纤维直径尺寸轮廓主要小于0.25 - 0.30µm的纤维才明显是间皮瘤。“较厚”的或那些主要宽度大于这些直径的似乎没有显示出可观察到的间皮瘤伴随风险。基于对至少两种“厚”形式的角闪孔石棉的研究的观察支持了这些假设。一个是玻利维亚的鳄鱼石;另一种芬兰花青石。芬兰的花青石行业提供了一个重要的机会来研究纤维宽度是间皮瘤发生的关键这一理论的稳健性,因为在芬兰工业的所有部门中,大量的人及其家庭在历史上遭受了大量的纤维暴露,足以导致石棉肺的严重过剩。然而,尽管存在这些长期、高剂量的暴露,仍然缺乏明确的证据表明花石石棉有间皮瘤风险。
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引用次数: 2
Treatment of Wastewater from Bean Sprout Production for Reuse 豆芽生产废水的回用处理
Pub Date : 2017-11-03 DOI: 10.5539/EP.V7N1P1
Inés Burgos-Luján, A. Tong
Bean sprout production consumes a significant volume of municipal water and generates a similar amount of wastewater. Water costs become a serious concern for this food industry, therefore wastewater reuse is highly desired by many sprout producers. Bean sprout wastewater has a relatively low level of contamination, which gives a great potential for reuse. The objective of this study was to exam the treatment feasibility of sprout production wastewater using a membrane bioreactor. Real-world wastewater from a sprout producer was treated continuously for 35 days. Important water quality parameters were monitored closely including chemical oxygen demand (COD), ammonia, tannins, pH, total suspended solids (TSS), etc. Once the biological system was stabilized, the MBR’s effluent showed very low level of COD, ammonia, TSS and bacteria, which demonstrated that the reuse of sprout wastewater is achievable.
豆芽生产消耗了大量的市政用水,并产生了类似数量的废水。水成本成为这个食品工业的一个严重问题,因此废水回用是许多芽菜生产商高度期望的。豆芽废水的污染程度相对较低,具有很大的再利用潜力。研究了膜生物反应器处理芽苗菜生产废水的可行性。实际废水从发芽生产者连续处理了35天。密切监测重要水质参数,包括化学需氧量(COD)、氨、单宁、pH、总悬浮物(TSS)等。生物系统稳定后,MBR出水COD、氨、TSS和细菌含量均很低,表明发芽废水回用是可以实现的。
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引用次数: 2
Analysis of an Authentic Historical Italian Cosmetic Talc Sample – Further Evidence for the Lack of Cancer Risk 正宗的意大利历史化妆品滑石粉样品分析-进一步证明缺乏癌症风险
Pub Date : 2017-09-29 DOI: 10.5539/ep.v6n2p6
E. Ilgren, C. Sartorio, J. Hoskins
Italian talc from the Pinerolo Mines in North West Italy is known for its extreme purity. Several historical investigations of these mines have demonstrated very small amounts of tremolite in the host rock that occasionally found their way into the mined ore. However, more than sixty years of epidemiological studies of the Pinerolo miners and millers have failed to demonstrate any attendant cancer risk and show that this trace tremolite contamination is of no biological significance.Claims made that the Pinerolo Italian cosmetic talc produced prior to 1975 were contaminated with asbestos, principally tremolite, have been difficult to refute given the lack of authentic historical samples of commercial products. We now describe the analytical findings of a recently discovered authentic historical sample.Sample analyses of this material showed only a few non-asbestiform tremolite fibres - a finding discussed in the light of the historical (pre-1975) studies of this talc deposit: no serpentine (chrysotile) or amphibole fibres were detected.The numerical concentration of tremolite fibres in the talc sample was 3.687 x 106 fibres/gram, corresponding to a mass concentration of 0.722 parts per million.
来自意大利西北部皮涅罗罗矿的意大利滑石粉以其极高的纯度而闻名。对这些矿山进行的几项历史调查表明,寄主岩石中有极少量的透闪石偶尔会进入开采的矿石中。然而,对皮涅罗罗矿工和磨坊主进行的60多年的流行病学研究未能证明有任何伴随的癌症风险,并表明这种微量透闪石污染没有生物学意义。关于1975年以前生产的意大利Pinerolo化妆品滑石粉被石棉(主要是透闪石)污染的说法很难反驳,因为缺乏商业产品的真实历史样本。我们现在描述最近发现的一个真实的历史样本的分析结果。对该材料的样品分析显示,只有少数非石棉类型的透闪石纤维——根据对该滑石矿床的历史(1975年以前)研究讨论了这一发现:没有检测到蛇纹石(温石棉)或角闪石纤维。滑石样品中透闪石纤维的数值浓度为3.687 x 106纤维/克,对应的质量浓度为0.722百万分之一。
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引用次数: 8
PCDD/PCDF and pl-PCBs Concentration in Ambient Atmosphere in the City of Tulkarm Using Passive Air Sampler 利用被动空气采样器测定图尔卡姆市环境大气中PCDD/PCDF和多氯联苯浓度
Pub Date : 2017-09-29 DOI: 10.5539/EP.V6N2P34
N. Shahin, Amjad I. A. Hussein, Jakob Reiman, S. Al-khalil, M. Salman
This study investigates the presence of highly toxic and carcinogenic compounds such as dioxins, furans and dioxin-like polychlorinated biphenyls, which may have evolved as a result of many industrial and burning processes, in Tulkarm ambient atmosphere. The measured concentrations were compared to values found in other studies undertaken in other sites globally. PCB 118, PCB 104 and PCB 77 were the main congeners making the ambient air profile of Tulkarm city, Palestine. While PCDFs were detected in about 40% of air samples no PCDDs were recorded. The contribution of Gishori complex area to air pollution was considered.
本研究调查了在图尔卡姆周围大气中存在的高毒性和致癌化合物,如二恶英、呋喃和二恶英样多氯联苯,这些化合物可能是许多工业和燃烧过程的结果。测量的浓度与在全球其他地点进行的其他研究中发现的值进行了比较。PCB 118、PCB 104和PCB 77是构成巴勒斯坦Tulkarm市环境空气剖面的主要同系物。虽然在约40%的空气样本中检测到PCDFs,但没有记录到PCDDs。考虑了吉县综合园区对大气污染的贡献。
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引用次数: 0
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Environment and Pollution
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