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Hypothetical Thresholds for Effects of Platinum Group Elements 铂族元素影响的假设阈值
Pub Date : 2019-03-31 DOI: 10.5539/EP.V8N1P39
G. Bengtsson
The platinum-group elements are rhodium, ruthenium, palladium, osmium, iridium, and platinum. Together with rhenium and gold they form the highly siderophilic (“iron-loving”) elements. These are poorly known with respect to toxicity and ecotoxicity. The mobilization by man of the eight metals is about 100 times to 1 million times the natural mobilization. Mean soil concentrations in Europe may now be more than doubled for gold, rhenium and rhodium. The objective of the current work was to enable a preliminary assessment of the consequences of such high environmental levels. Thresholds for ecological effects found in the literature were divided by the element’s mean soil concentration and plotted against group and period in the periodic system. Thresholds for health effects were correspondingly divided by the mean dietary intake of the element over large population groups. For health effects, an upper limit of intake is commonly used. This was shown to be about 4 times the mean normal intake for most period 4 elements. For other periods, occupational exposure thresholds entail upper limits of intake in µg/day of: Ru 18, Rh 8, Pd 17, Re 60, Os 15, Ir 4, Pt 20 and Au 160. For ecological effects, the no effect thresholds for period 4 were 1-5 times the soil concentrations. Very scarce data suggest higher relative thresholds for periods 5 and 6. The current high contaminations of European soil by Rh and possibly Pd may be of concern. Since the estimates of risks are uncertain, further research is warranted.
铂族元素有铑、钌、钯、锇、铱和铂。它们与铼和金一起形成了高度亲铁(“亲铁”)的元素。它们在毒性和生态毒性方面鲜为人知。人类对这八种金属的动员作用是自然动员作用的100到100万倍。欧洲土壤中金、铼和铑的平均浓度现在可能增加了一倍以上。目前工作的目标是能够初步评估这种高环境水平的后果。在文献中发现的生态效应阈值除以元素的平均土壤浓度,并根据周期系统中的组和周期绘制。健康影响的阈值相应地除以该元素在大量人群中的平均膳食摄入量。考虑到对健康的影响,通常会设定摄入量的上限。这被证明是大多数时期4元素平均正常摄入量的4倍。在其他时期,职业暴露阈值规定了以微克/天为单位摄入Ru 18、Rh 8、Pd 17、Re 60、Os 15、Ir 4、Pt 20和Au 160的上限。对于生态效应,第4期的无效应阈值为土壤浓度的1 ~ 5倍。很少有数据表明,第5和第6期的相对阈值较高。目前欧洲土壤中Rh和Pd的高污染值得关注。由于对风险的估计是不确定的,因此需要进一步的研究。
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引用次数: 3
Exploring the Nexus among Environmental Pollution, Economic Growth Energy Use and Foreign Direct Investment in Sub Sahara Africa 探讨撒哈拉以南非洲地区环境污染、经济增长、能源利用和外国直接投资之间的关系
Pub Date : 2019-03-31 DOI: 10.5539/EP.V8N1P54
Max William Ssali, Jianguo Du, I. A. Mensah, Duncan O. Hongo
This research seeks to enhance the current literature by exploring the nexus among environmental contamination, economic growth, energy use and foreign direct investment in 6 Selected Sub-Saharan-African-nations for a time of 34 years (1980-2014). By applying, panel unit root (CADF and CIPS, Cross-sectional independence test), panel cointegration (Pedroni and Kao cointegration test, Panel PP, Panel ADF), Hausman poolability test and an auto-regressive distributed lag procedure in view of the pooled mean group estimation (ARDL/PMG), experimental findings discloses that alluding to the related probability values, the null hypothesis of cross-sectional independence for all variables is rejected because they are not stationary at levels but rather stationary at their first difference. The variables are altogether integrated at the same order I(1). Findings revealed that there is a confirmation of a bi-directional causality between energy use and CO2 in the short-run as well as one-way causality running from energy use to CO2 in the long run. There is additionally a significant positive outcome and uni-directional causality from CO2 to foreign direct investment in the long-run yet no causal relationship in the short-run. An increase in energy use by 1% causes an increase in CO2 by 49%. An increase in economic growth by 1% causes an increment in CO2 by 16% and an increase in economic growth squared by 1% diminish CO2 by 46%. The positive and negative impact of economic growth and its square approve the EKC theory. To guarantee sustainable economic development Goal, more strict laws like sequestration ought to be worked out, use of sustainable power source ought to be stressed. GDP ought to be multiplied to diminish CO2 by the utilization of eco-technology for instance carbon capturing, to save lives and also to maintain a green environment.
本研究旨在通过探索环境污染、经济增长、能源使用和外国直接投资在撒哈拉以南非洲6个国家34年(1980-2014)之间的关系来加强现有文献。通过应用面板单位根(CADF和CIPS,横截面独立性检验)、面板协整(Pedroni和Kao协整检验,panel PP, panel ADF)、Hausman poolability检验和针对混合平均组估计(ARDL/PMG)的自回归分布滞后程序,实验结果表明,针对相关概率值,所有变量的横截面独立性的原假设被拒绝,因为它们在水平上不是平稳的,而是在它们的第一个差处是平稳的。所有变量都以相同的I(1)阶积分。研究结果表明,在短期内,能源使用与二氧化碳之间存在双向因果关系,而从长期来看,能源使用与二氧化碳之间存在单向因果关系。此外,二氧化碳与外国直接投资在长期内存在显著的正向结果和单向因果关系,但在短期内没有因果关系。能源使用量每增加1%,二氧化碳排放量就会增加49%。经济增长每增加1%,二氧化碳就会增加16%,经济增长每增加1%的平方,二氧化碳就会减少46%。经济增长的正负影响及其平方验证了EKC理论。为了实现可持续的经济发展目标,应该制定更严格的法律,如封存,强调可持续能源的使用。国内生产总值应该成倍增长,通过利用生态技术(例如碳捕获)来减少二氧化碳,以拯救生命,并保持绿色环境。
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引用次数: 2
Reply to the Readership regarding Ilgren & Hoskins (2018) Anthophyllite Mesothelioma Articles 回复读者对Ilgren & Hoskins(2018)花青体间皮瘤文章的意见
Pub Date : 2019-02-11 DOI: 10.5539/EP.V8N1P32
E. Ilgren
Reply to the Readership regarding Ilgren & Hoskins (2018) Anthophyllite Mesothelioma Articles.
回复读者对Ilgren & Hoskins(2018)花青体间皮瘤文章的意见。
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引用次数: 0
Anthophyllite Asbestos: The Role of Fiber Width in Mesothelioma Induction. Part 4: Mechanistic Considerations regarding the Failure to Observe Anthophyllite Asbestos Mesotheliomas in Humans 花青石石棉:纤维宽度在间皮瘤诱导中的作用。第4部分:关于未能观察到人类花石石棉间皮瘤的机制考虑
Pub Date : 2018-12-11 DOI: 10.5539/ep.v8n1p18
E. Ilgren, J. Hoskins
Anthophyllite is an amphibole mineral formed through a prograde metamorphism of magnesium-rich ultramafic talcose rocks through increasing pressure and temperature and dehydration. The talc and anthophyllite are in phase equilibrium. Anthophyllite asbestos is therefore not a ‘contaminant’ of talc but a product derived from it. Fibrous talc, or so-called transitional fibers, are anthophyllite fibers undergoing retrograde degeneration. In its fibrous asbestiform state, anthophyllite differs in several fundamental ways from other commercially exploited forms of amphibole asbestos of which there are two broad families: monoclinic and orthorhombic. The more common forms of commercial amphibole asbestos such as crocidolite and amosite are monoclinic. The anthophyllites are orthorhombic. The differences between the two crystal systems are reflected at the level of the basic amphibole-structure in a greater overall fiber width dimensional profile and a significant reduction in microstructural strength. Strength reduction most probably arises at the cellular level and is particularly pronounced within the thinner population of fibers. Here microstructural differences, due in significant part to stacking defects in the basic amphibole structure, can account for these observations. The lack of an observed attendant mesothelioma risk following exposure to anthophyllite and transitional fibers in humans is a consequencel of these microstructural features that appear to differentiate them from the equidimensional monoclinic forms of amphibole asbestos such as South African crocidolite and amosite.
花青石是一种角闪孔矿物,是富镁超镁质滑石岩石在增温增压和脱水作用下渐进变质而形成的。滑石和花青石处于相平衡状态。因此,花青石石棉不是滑石的“污染物”,而是滑石的衍生产品。纤维滑石,或所谓的过渡纤维,是逆行变性的花青石纤维。在纤维石棉状态下,花青石在几个基本方面不同于其他商业开发的角孔石棉形式,其中有两大类:单斜和正交。更常见的商业角闪孔石棉形式,如鳄鱼石和阿莫石是单斜的。花青体是正交的。两种晶体体系之间的差异反映在基本角闪石结构水平上,其总体纤维宽度尺寸剖面更大,微观结构强度显著降低。强度降低最有可能发生在细胞水平,在纤维较薄的群体中尤其明显。在这里,微观结构的差异,在很大程度上是由于基本角闪洞结构中的堆积缺陷,可以解释这些观察结果。人类暴露于花青石和过渡纤维后,未观察到间皮瘤风险,这是这些微观结构特征的结果,这些特征似乎将它们与等维单斜角闪孔石棉(如南非青橄榄石和阿莫子石)区分开来。
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引用次数: 1
Anthophyllite Asbestos: The Role of Fiber Width in Mesothelioma Induction. Part 3: Studies of American and Japanese Anthophyllite Asbestos – Additional Supportive Evidence 花青石石棉:纤维宽度在间皮瘤诱导中的作用。第3部分:美国和日本花青石石棉的研究-额外的支持性证据
Pub Date : 2018-12-11 DOI: 10.5539/EP.V8N1P1
E. Ilgren, J. Hoskins
The largest anthopyllite deposits in the world are found in Finland and it is from here that most of the commercial anthophyllite derives. However, other large deposits exist in both North America and Japan. Commercial production has existed in both these countries although not on a scale which matches the Finnish mines. Small deposits are known from several other countries but, apart from minor exploitation in India no significant mining has taken place. The North American deposits are primarily in the Eastern US states, mostly Maryland, Georgia and North Carolina although there was also extensive exploration in Alabama. In Japan, the major mining site was at Matsubase on the southermost island of Kyushu. Although these mines and attendant commercial concerns operated for decades and under conditions of high dust exposure no mesothelioma clusters are known from the mining areas.
世界上最大的花青石矿床是在芬兰发现的,这里是大多数商业花青石的产地。然而,北美和日本都有其他大型矿床。这两个国家都有商业生产,尽管其规模比不上芬兰的矿山。在其他几个国家也发现了少量矿藏,但除了印度的少量开采外,没有进行大规模开采。北美的矿床主要在美国东部各州,主要是马里兰州、佐治亚州和北卡罗来纳州,尽管在阿拉巴马州也有广泛的勘探。在日本,主要的采矿地点位于九州岛最南端的松濑。虽然这些矿山和伴随的商业公司在高粉尘暴露的条件下经营了几十年,但在矿区没有发现间皮瘤集群。
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引用次数: 6
Characteristics of Organophosphate Ester Formation during Smoking 吸烟过程中有机磷酸酯形成的特征
Pub Date : 2018-09-29 DOI: 10.5539/EP.V7N2P32
H. Shimazu
This study examines the occurrence of organophosphate esters (OPEs) in cigarettes and sidestream cigarette smoke and to see the OPE formation characteristics during smoking. All seven OPEs in both gas and particulate phases were measured in sidestream cigarette smoke for four brands of cigarettes. Tributyl phosphate (TBP), tris(2-butoxyethyl) phosphate (TBEP), tris(2-chloroethyl) phosphate (TCEP), and triphenyl phosphate (TPP) were found frequently. Median total OPE increases in the air samples during smoking were 56.2 ng per cigarette for gas-phase OPEs and 2360 ng per cigarette for particulate-phase OPEs. TBP and TCEP could be absorbed to particles in air more readily than alkans as seen from the correlation line between gas–particle partition coefficients (Kp) and the subcooled liquid vapor pressures (PLº) for alkans. Furthermore, TBP was determined in the cigarettes. Median total OPE decreases in the cigarette samples during smoking were 1200 ng per cigarette. The combustion reaction increased TBP and TBEP levels in cigarettes, and particulate-phase TBEP in air appeared to influence the production of TBP, TCEP, and TPP. TBP and TBEP in cigarettes likely affect the production of TBP, TBEP, TCEP, and TPP in air during smoking.
本研究考察了有机磷酸酯(OPEs)在卷烟和侧流卷烟烟雾中的发生情况,并观察了OPEs在吸烟过程中的形成特征。在四种香烟的侧流烟雾中测量了气体和颗粒相的所有七种OPEs。磷酸三丁酯(TBP)、磷酸三(2-丁氧乙基)磷酸(TBEP)、磷酸三(2-氯乙基)磷酸(TCEP)和磷酸三苯基(TPP)是常见的化合物。在吸烟过程中,空气样本中总OPE的中位数增加是:气相OPEs每支烟56.2 ng,颗粒相OPEs每支烟2360 ng。从气粒分配系数Kp与气液过冷蒸汽压PLº的相关曲线可以看出,TBP和TCEP比烷烃更容易被空气中的颗粒吸收。此外,还测定了香烟中的TBP。吸烟期间,香烟样本中总OPE的中位数下降为每支1200纳克。燃烧反应增加了卷烟中TBP和TBEP的含量,空气中颗粒相TBEP似乎影响了TBP、TCEP和TPP的产生。香烟中的TBP和TBEP可能影响吸烟过程中空气中TBP、TBEP、TCEP和TPP的产生。
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引用次数: 0
Hypothetical Strategies to Reduce the Greenhouse Gas Emissions from Mobile Sources on the Orizaba Valley 减少Orizaba山谷移动源温室气体排放的假设策略
Pub Date : 2018-09-29 DOI: 10.5539/ep.v7n2p42
Joaquín Pinto-Espinoza, Adán Reyes-Pavón, Marco A. Benítez-Espíndola, Gustavo Alvarado-Kinnell, A. Bello-ramírez
The Intergovernmental Panel on Climate Change established clear and solids conclusions on the 2013 report, it says that has been scientifically demonstrated with 95% of certainty, that human activities are the main cause of the global warming, observed since the middle of the XX century. The Orizaba Valley is a Mexican region, located at the geographic center of Veracruz State, having Orizaba City as the main demographic population surrounded by other municipalities, becoming the fourth metropolitan populated area of Veracruz State. This region has the third position on economic, historic and cultural relevance at Veracruz State, just after the Veracruz Port and Xalapa City. It was one of the main places with a vast economic growing during the Viceroyalty of the New Spain, being an obligatory passing route and resting place between Veracruz Port and Mexico City. This project estimates the magnitude of the Greenhouse Gas emissions coming from mobile sources at the Orizaba Valley. It includes the urban region of the municipalities of Ixtaczoquitlan, Orizaba, Río Blanco, Camerino de Mendoza and Nogales. The collected data was processed according to the Intergovernmental Panel on Climate Change methodology and it was possible to make the following projections: 1) One baseline scenario and 2) Three scenarios under hypothetical mitigation strategies that promise to achieve a reduction of GHG emission of 30 % from the year 2020 to 2050. Beyond this, also there is a significant reduction in fossil fuels consumption due to the efficient use of energy. All projections were made by using the Long-range Energy Alternatives Planning system software. In addition of the achievement on the GHG emissions reduction goal, it is possible to glimpse an economic recovery, if and only if, the decision makers of the governments decide to participate in the international trade of carbon market.
政府间气候变化专门委员会(Intergovernmental Panel on Climate Change, ipcc)在2013年的报告中得出了明确而确凿的结论,该报告称,自20世纪中叶以来,人类活动是全球变暖的主要原因,这一结论已得到95%的科学证实。奥里萨巴山谷是墨西哥的一个地区,位于韦拉克鲁斯州的地理中心,奥里萨巴市是主要的人口人口,被其他城市包围,成为韦拉克鲁斯州的第四个大都市人口区域。该地区在韦拉克鲁斯州的经济、历史和文化意义上排名第三,仅次于韦拉克鲁斯港和哈拉帕市。在新西班牙总督统治时期,它是经济发展迅速的主要地区之一,是韦拉克鲁斯港和墨西哥城之间的必经之路和休息之地。该项目估计了奥里萨巴河谷移动源产生的温室气体排放量的大小。它包括Ixtaczoquitlan, Orizaba, Río Blanco, Camerino de Mendoza和Nogales等市的市区。根据政府间气候变化专门委员会的方法对收集到的数据进行了处理,可以作出以下预测:1)一个基线情景和2)假设缓解战略下的三个情景,承诺从2020年到2050年实现温室气体排放量减少30%。除此之外,由于能源的有效利用,化石燃料的消耗也显著减少。所有预测都是使用长期能源替代规划系统软件进行的。除了温室气体减排目标的实现之外,当且仅当政府决策者决定参与碳市场的国际贸易时,才有可能看到经济复苏。
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引用次数: 0
Polycyclic Aromatic Hydrocarbons in Different Varieties of Rice (Oryza sativa) from Yobe State, Nigeria 尼日利亚约贝州不同品种水稻(Oryza sativa)中的多环芳烃
Pub Date : 2018-09-24 DOI: 10.5539/EP.V7N2P21
J. Akan, Joshua Yohanna Dawa, L. I. Bukar, Z. Muhammed
The present study determined the levels of sixteen polycyclic aromatic hydrocarbons (PAHs) in rice (Oryza Sativa) samples from six agricultural locations in Bade and Karasuwa Local Government Areas, Yobe State, Nigeria. Four varieties of rice (FARO 42, 44, 45 and 52) were collected for this study. The concentrations of PAHs in the study rice samples were lower than the maximum allowable concentration (MAC), average daily dose (ADD) of PAHs in the different variety of rice from the six agricultural locations shows that FARO 44 had the highest ADD (5.84 x1011 mg/kg), while FARO 52 shows the lowest ADD (1.20 x1015 mg/kg). The potential for non-carcinogenic PAHs in this study revealed that FARO 42 has the highest hazard index (2.04 x1011 mg/kg). Result from incremental lifetime expectancy cancer risk shows that FARO 44 from Jawa had the highest value (4.19 x1010 mg/kg), while the lowest value (7.61 x1015 mg/kg) was recorded for FARO 52 from Rina Kuna agricultural location. Results from the present study shows that the rice samples from the study locations are safe for human consumption and not significantly contaminated by PAHs.
本研究确定了来自尼日利亚约贝州Bade和Karasuwa地方政府区的六个农业地点的水稻(Oryza Sativa)样品中16种多环芳烃(PAHs)的水平。本研究收集了4个水稻品种(FARO 42、44、45和52)。研究水稻样品中多环芳烃的浓度均低于最大允许浓度(MAC), 6个农业地点不同品种水稻中多环芳烃的平均日剂量(ADD)显示,FARO 44的ADD最高(5.84 × 1011 mg/kg), FARO 52的ADD最低(1.20 × 1015 mg/kg)。本研究非致癌性多环芳烃的潜在含量显示,FARO 42的危害指数最高(2.04 × 1011 mg/kg)。预期寿命癌症风险增量结果显示,爪哇地区的FARO 44最高(4.19 x1010 mg/kg),而里纳库纳地区的FARO 52最低(7.61 x1015 mg/kg)。本研究结果表明,研究地点的大米样品可供人类食用是安全的,没有明显的多环芳烃污染。
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引用次数: 2
Assessment of a Woodstove Changeout Program on PM2.5 Levels in Keene, New Hampshire, U.S.A. 美国新罕布夏州基恩市柴火炉更换计划对PM2.5浓度的评估
Pub Date : 2018-09-13 DOI: 10.5539/EP.V7N2P11
T. Garceau
In local airsheds, wood smoke from residential woodstoves is a major source of PM2.5 pollution. Exposure to PM2.5 can cause a variety of health problems and complications. Communities situated in valleys that experience cold winters are especially susceptible to poor air quality during inversion events on calm winter nights. Keene, New Hampshire, USA is one such community where the widespread use of outdated residential woodstoves frequently resulted in PM2.5 exceeding national standards. Seeking to improve air quality, the City of Keene partnered with the New Hampshire Department of Environmental Services from 2009-2010 to facilitate a woodstove changeout program which replaced 86 inefficient woodstoves with newer or alternate heating appliances. Despite the fact that many U.S. communities have enacted similar programs, research on their effectiveness is limited. This research assessed Keene’s program and determined that Keene has experienced a significant reduction in PM2.5 on calm winter nights. When winds are below 2 miles per hour (3.22 kilometers per hour), PM2.5 dropped 7% to 52% (1.28 to 7.30 µg/m3) after the woodstove changeout; a mean decrease of 23%. It therefore appears that Keene’s woodstove changeout program successfully improved air quality on the nights that are most likely to violate national air quality standards. This provides evidence that such programs can be an effective means to moderating the effects of wood heating in communities susceptible to inversions.
在当地的大气中,住宅柴炉产生的木材烟雾是PM2.5污染的主要来源。暴露在PM2.5中会导致各种健康问题和并发症。在平静的冬夜逆温事件期间,位于冬季寒冷的山谷中的社区特别容易受到空气质量差的影响。美国新罕布什尔州基恩市就是这样一个社区,在那里广泛使用过时的住宅柴炉经常导致PM2.5超过国家标准。为了改善空气质量,基恩市在2009年至2010年期间与新罕布什尔州环境服务部合作,推动了一项柴炉更换计划,用更新或替代的加热设备取代了86个低效的柴炉。尽管美国许多社区已经制定了类似的计划,但对其有效性的研究却很有限。这项研究评估了基恩的计划,并确定基恩在平静的冬夜经历了PM2.5的显著减少。当风速低于每小时2英里(每小时3.22公里)时,更换了柴炉后,PM2.5下降了7%至52%(1.28至7.30微克/立方米);平均减少23%。因此,基恩的柴炉更换计划似乎成功地改善了最可能违反国家空气质量标准的夜晚的空气质量。这提供了证据,表明此类计划可以有效地缓解易受逆温影响的社区中木材加热的影响。
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引用次数: 0
Stability and Maturity of Different Poultry Manures and Potential Utilization for Horticultural Production 不同禽粪的稳定性、成熟度及其在园艺生产中的潜在利用
Pub Date : 2018-07-16 DOI: 10.5539/EP.V7N2P1
M. Mataa, Namakau Manzi, K. Munyinda
This study evaluated stability, maturity and the efficacy of different poultry litter for possible use in container plant production. Three types of poultry manure- Battery cage (BC), Deep litter (DL) and Free range (FR) were used, with Kraal manure (KM) as a comparison. The experiment was set up as a Split- split design with 6 replications. Composting period was main plot, poultry manure type the split plot and mixing ratio as the split- split plot. The litter was mixed with garden soil in 2 ratios (3:1 and 1:1 soil: manure ratio) and tested for up to 12 weeks. Rape (Brassica napus) was used as a bioassay for maturity, which was determined at 1 month, 2 months and 3 months. The pH declined slightly from 7 to about 6 for all treatments except for the kraal manure. Respiration trends were similar to electrical conductivity. Within 2 weeks of curing the respiration rate for all manures declined to below 4 mg CO2- C/ kg. At the end of 12 weeks curing Battery cage had highest total nitrogen (2.32 %), followed by Free range (1.25 %), Deep litter (0.73 %) and Kraal manure was lowest at 0.35 %). Maturity (rape survival) increased with compositing time. After 3 months of curing Kraal manure had highest survivability of rape. The DL at 1:1 ratio had the lowest survival of 67%. At 12 weeks except for BC at 3:1 all treatments had 100 % survival. The results showed that nitrogen rich manures (DL and BC) needed longer curing in order for them to reach maturity.
本研究评估了不同家禽产仔的稳定性、成熟度和功效,以供集装箱工厂生产之用。试验采用3种类型的鸡粪(BC)、深窝粪(DL)和散养粪(FR),并以克拉尔粪(KM)为对照。试验设6个重复,采用裂-裂设计。堆肥期为主要小区,禽粪类型为分块小区,混合比例为分块-分块小区。将凋落物与花园土壤按3:1和1:1的土粪比混合,试验长达12周。以油菜(Brassica napus)为研究对象,分别在1个月、2个月和3个月进行成熟度测定。除粪肥外,其余处理的pH值均从7下降到6左右。呼吸趋势与电导率相似。在养护2周内,所有肥料的呼吸速率降至4 mg CO2- C/ kg以下。12周养护结束时,蓄电池笼总氮最高(2.32%),散养笼次之(1.25%),深层凋落物最低(0.73%),Kraal粪肥最低(0.35%)。成熟度(油菜存活率)随合成时间的延长而增加。处理3个月后,油菜成活率最高。1:1比例的DL生存率最低,为67%。在12周时,除3:1的BC外,所有治疗的存活率均为100%。结果表明,富氮肥料(DL和BC)需要较长的养护时间才能达到成熟。
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引用次数: 4
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Environment and Pollution
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