Pub Date : 2022-12-08DOI: 10.20961/equilibrium.v6i2.67249
Regna Tri Jayanti, Annisa Aulia Furqana Ramzi, Muhammad Hanif Alfitra
Pertumbuhan industri pabrik kelapa sawit masih cukup potensial di Indonesia, kajian produk samping hasil produksi pabrik kelapa sawit ini masih belum diolah dengan optimal. Pemanfaatan fly ash sebagai salah satu produk samping masih sangat perlu dikembangkan. Silika merupakan komposisi penyusun fly ash kelapa sawit yang sangat diminati saat ini karena memiliki potensi aplikasi dalam berbagai tujuan seperti pengolahan limbah, material semikonduktor, dan bahan aditif pertanian. Penelitian pengolahan silika dari abu hasil proses pembakaran tidak terlepas dari metode ektraksi yang sangat bergantung dari karakteristik kelarutan silika terhadap pelarutnya. Penelitian ini bertujuan untuk memberikan informasi karakteritik kelarutan silika yang berasal dari fly ash pabrik kelapa sawit dalam larutan berupa basa kuat (NaOH) dan asam lemah (C6H8O7). Aktivitas kelarutan silika dalam pelarut asam dan basa dilakukan dengan memvariasikan konsentrasi pelarut yaitu 1 M, 2 M, dan 3 M. Proses pelarutan silika dilakukan pada temperatur 60oC dalam waktu 60 menit. Karaketrisasi fly ash dilakukan dengan menggunakan instrumen XRD, XRF, dan SEM yang menunjukkan bahwa senyawa penyusun utama fly ash adalah CaO 68,894% dan SiO2 19,189 % yang terkandung dalam mineral kalsit, portlandite, dan kuarsa dengan morfologi yang heterogen serta ukuran partikel diantara 200 μm – 300 μm. Hasil pelarutan menunjukkan bahwa kelarutan silika tertinggi diperoleh dalam pelarut asam sitrat 2 M yaitu sebesar 26,35 %.
{"title":"Karakterisasi Kelarutan Silika dari Fly Ash Kelapa Sawit dalam Larutan Basa Kuat (NaOH) dan Asam Lemah (C6H8O7)","authors":"Regna Tri Jayanti, Annisa Aulia Furqana Ramzi, Muhammad Hanif Alfitra","doi":"10.20961/equilibrium.v6i2.67249","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i2.67249","url":null,"abstract":"Pertumbuhan industri pabrik kelapa sawit masih cukup potensial di Indonesia, kajian produk samping hasil produksi pabrik kelapa sawit ini masih belum diolah dengan optimal. Pemanfaatan fly ash sebagai salah satu produk samping masih sangat perlu dikembangkan. Silika merupakan komposisi penyusun fly ash kelapa sawit yang sangat diminati saat ini karena memiliki potensi aplikasi dalam berbagai tujuan seperti pengolahan limbah, material semikonduktor, dan bahan aditif pertanian. Penelitian pengolahan silika dari abu hasil proses pembakaran tidak terlepas dari metode ektraksi yang sangat bergantung dari karakteristik kelarutan silika terhadap pelarutnya. Penelitian ini bertujuan untuk memberikan informasi karakteritik kelarutan silika yang berasal dari fly ash pabrik kelapa sawit dalam larutan berupa basa kuat (NaOH) dan asam lemah (C6H8O7). Aktivitas kelarutan silika dalam pelarut asam dan basa dilakukan dengan memvariasikan konsentrasi pelarut yaitu 1 M, 2 M, dan 3 M. Proses pelarutan silika dilakukan pada temperatur 60oC dalam waktu 60 menit. Karaketrisasi fly ash dilakukan dengan menggunakan instrumen XRD, XRF, dan SEM yang menunjukkan bahwa senyawa penyusun utama fly ash adalah CaO 68,894% dan SiO2 19,189 % yang terkandung dalam mineral kalsit, portlandite, dan kuarsa dengan morfologi yang heterogen serta ukuran partikel diantara 200 μm – 300 μm. Hasil pelarutan menunjukkan bahwa kelarutan silika tertinggi diperoleh dalam pelarut asam sitrat 2 M yaitu sebesar 26,35 %.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86814461","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRAK. Mikroalga Nannochlopsis sp merupakan alternatif bahan baku yang digunakan untuk pembuatan biodiesel karena memiliki kandungan asam lemak dan lipid yang tinggi serta pertumbuhannya yang begitu cepat. Metode yang digunakan yaitu transesterifikasi in situ dimana proses ekstraksi dan transesterifikasi berlangsung secara bersamaan yang terdiri dari 2 tahap, proses transestrifikasi in situ dan pemurnian biodiesel. Proses transeserifikasi in situ berlangsung selama 8 jam setelah itu, dilanjutkan dengan proses distilasi untuk menghilangkan kandungan n-heksana dan di oven selama 2 jam untuk menguapkan air yang tersisa. Penelitian ini memiliki tujuan yaitu untuk mengetahui pengaruh rasio molar minyak mikroalga : metanol dengan variasi katalis yang dimana rasio 1:6 memiliki tingkat kesetimbangan yang tinggi sehingga dapat menghasilkan %yield yang besar. Rasio molar minyak mikroalga : metanol 1:6 dengan variasi katalis KOH 2; 2,5; 3; 3,5; dan 4%w/w, dengan pelarut n-heksana 70%v/v terhadap yield crude dan kandungan FFA. Hasil yield crude biodiesel yang didapatkan pada penelitian ini sebesar 7%, kadar FFA sebesar 0,74 mg NaOH/gr. ABSTRACT. Microalgae Nannochloropsis sp is an alternative raw material which is used for biodiesel production because it has a high content of fatty acids and increased lipid and its growth is so fast. The method was in situ transesterification in which extraction and transesterification processes took place simultaneously and consisted of 2 steps; in situ transesterification process and biodiesel purification. The in-situ transesterification process lasted for 8 hours after that, followed by a distillation process to remove the n-hexane content and in the oven for 2 hours to evaporate the remaining air. The aim of this study was to determine the effect of the molar ratio from microalgae oil: methanol with variations of catalyst where the ratio of 1:6 has a high equilibrium level so that it can produce a large % yield. the molar ratio from microalgae oil: methanol 1:6 with variations of KOH catalysts 2; 2.5; 3; 3.5; and 4%w/w, with solvent n-hexane is 70%v/v to the yield of crude and FFA biodiesel. The variable used was the molar ratio variation of microalgae oil: methanol 1:6. The yield of biodiesel crude obtained was 7%, and FFA content was 0.74 mg NaOH/gr.
{"title":"Proses Pembuatan Biodiesel Dari Mikroalga Nannochloropsis sp. Menggunakan Metode Transesterifikasi In-Situ dengan Katalis KOH","authors":"Faizul Baqi, Rizqyta Subtantia Intan Putri, Yustia Wulandari Mirzayanti","doi":"10.20961/equilibrium.v6i2.63257","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i2.63257","url":null,"abstract":"ABSTRAK. Mikroalga Nannochlopsis sp merupakan alternatif bahan baku yang digunakan untuk pembuatan biodiesel karena memiliki kandungan asam lemak dan lipid yang tinggi serta pertumbuhannya yang begitu cepat. Metode yang digunakan yaitu transesterifikasi in situ dimana proses ekstraksi dan transesterifikasi berlangsung secara bersamaan yang terdiri dari 2 tahap, proses transestrifikasi in situ dan pemurnian biodiesel. Proses transeserifikasi in situ berlangsung selama 8 jam setelah itu, dilanjutkan dengan proses distilasi untuk menghilangkan kandungan n-heksana dan di oven selama 2 jam untuk menguapkan air yang tersisa. Penelitian ini memiliki tujuan yaitu untuk mengetahui pengaruh rasio molar minyak mikroalga : metanol dengan variasi katalis yang dimana rasio 1:6 memiliki tingkat kesetimbangan yang tinggi sehingga dapat menghasilkan %yield yang besar. Rasio molar minyak mikroalga : metanol 1:6 dengan variasi katalis KOH 2; 2,5; 3; 3,5; dan 4%w/w, dengan pelarut n-heksana 70%v/v terhadap yield crude dan kandungan FFA. Hasil yield crude biodiesel yang didapatkan pada penelitian ini sebesar 7%, kadar FFA sebesar 0,74 mg NaOH/gr. ABSTRACT. Microalgae Nannochloropsis sp is an alternative raw material which is used for biodiesel production because it has a high content of fatty acids and increased lipid and its growth is so fast. The method was in situ transesterification in which extraction and transesterification processes took place simultaneously and consisted of 2 steps; in situ transesterification process and biodiesel purification. The in-situ transesterification process lasted for 8 hours after that, followed by a distillation process to remove the n-hexane content and in the oven for 2 hours to evaporate the remaining air. The aim of this study was to determine the effect of the molar ratio from microalgae oil: methanol with variations of catalyst where the ratio of 1:6 has a high equilibrium level so that it can produce a large % yield. the molar ratio from microalgae oil: methanol 1:6 with variations of KOH catalysts 2; 2.5; 3; 3.5; and 4%w/w, with solvent n-hexane is 70%v/v to the yield of crude and FFA biodiesel. The variable used was the molar ratio variation of microalgae oil: methanol 1:6. The yield of biodiesel crude obtained was 7%, and FFA content was 0.74 mg NaOH/gr.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74506721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-10-16DOI: 10.20961/equilibrium.v6i2.61216
S. Handayani, Yesaya Emeraldy Priutama, Intan Rahmalia, Farhan Muhammad Hilmi, R. Aryanto, E. Sofiyah, Ariyanti Sarwono, I. W. Suryawan
Abstract: Fecal sludge can be treated by conventional treatment such as pond stabilization which is commonly used to reduce organic concentrations. However, nutrients such as NH3 are still widely measured in the effluent. One of the sewerage treatments in the city of Jakarta, for example, experienced this condition. This study aims to design an appropriate technology to increase the efficiency of nutrient ammonia and total suspended solid (TSS) removal at Duri X IPLT. The unit added in the selected effluent treatment is Granular Activated Carbon (GAC). Design considerations are the characteristics of activated carbon, operating conditions (discharge and contact time), and operating mode (fixed-, expanded-, or fluidized-bed, pumped, or gravity flow). The Carbon Usage Rate for removing ammonia and TSS is 1.384 g/L and 0.378 g/L, respectively. Maintenance is required so that the granular activated carbon (GAC) unit can continue operating and functioning properly. Blockages in carbon transport pipes can occur in many pipes. This can occur due to a too-small pipe, a short bend radius of the pipe, a lack of speed, and a lack of cleaning of the pipe. The eroded pipe is also a common problem that often occurs in unlined mild steel and fiberglass reinforced plastic (FRP), usually in sharp bends.
摘要:粪便污泥可采用常规处理方法，如池塘稳定化处理，通常用于降低有机浓度。然而，诸如NH3之类的营养物质仍在污水中广泛测量。例如，雅加达市的一个污水处理系统就遇到了这种情况。本研究旨在设计一种合适的工艺来提高Duri X IPLT对营养氨和总悬浮固体(TSS)的去除效率。在选定的污水处理中添加的单元是颗粒活性炭(GAC)。设计考虑的因素是活性炭的特性、操作条件(放电和接触时间)和操作模式(固定、膨胀或流化床、泵送或重力流)。去除率为1.384 g/L，去除率为0.378 g/L。需要进行维护，以便颗粒活性炭(GAC)单元能够继续正常运行和功能。许多管道都可能发生碳输送管道堵塞。这可能是由于管道太小，管道弯曲半径短，速度不足以及管道清洁不足造成的。腐蚀管也是一个常见的问题，经常发生在没有衬里的低碳钢和玻璃钢(FRP)中，通常是在急弯处。
{"title":"Planning of Granular Activated Carbon Unit to Remove Ammonia and TSS at IPLT X, Kota Jakarta","authors":"S. Handayani, Yesaya Emeraldy Priutama, Intan Rahmalia, Farhan Muhammad Hilmi, R. Aryanto, E. Sofiyah, Ariyanti Sarwono, I. W. Suryawan","doi":"10.20961/equilibrium.v6i2.61216","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i2.61216","url":null,"abstract":"Abstract: Fecal sludge can be treated by conventional treatment such as pond stabilization which is commonly used to reduce organic concentrations. However, nutrients such as NH3 are still widely measured in the effluent. One of the sewerage treatments in the city of Jakarta, for example, experienced this condition. This study aims to design an appropriate technology to increase the efficiency of nutrient ammonia and total suspended solid (TSS) removal at Duri X IPLT. The unit added in the selected effluent treatment is Granular Activated Carbon (GAC). Design considerations are the characteristics of activated carbon, operating conditions (discharge and contact time), and operating mode (fixed-, expanded-, or fluidized-bed, pumped, or gravity flow). The Carbon Usage Rate for removing ammonia and TSS is 1.384 g/L and 0.378 g/L, respectively. Maintenance is required so that the granular activated carbon (GAC) unit can continue operating and functioning properly. Blockages in carbon transport pipes can occur in many pipes. This can occur due to a too-small pipe, a short bend radius of the pipe, a lack of speed, and a lack of cleaning of the pipe. The eroded pipe is also a common problem that often occurs in unlined mild steel and fiberglass reinforced plastic (FRP), usually in sharp bends.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77589789","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-10-16DOI: 10.20961/equilibrium.v6i2.64322
Ankit Stephen Thomas
Abstract: Over the past decade, lead halide perovskite light absorbers have been the conventionally used perovskite light absorbers. However, there is an urgent call for alternative perovskite materials with toxicity levels and poor stability to UV radiations. Antimony-based perovskites have proven to be a material with unique optoelectronic properties, conventional fabrication processes, low-toxicity levels and high stability values. In this review, we look into the structure of antimony perovskites, the various research achievements over recent years, and the challenges and opportunities ahead for this budding technology. The review also highlights the various computational, theoretical and experimental studies done by researchers to highlight the peculiar Lead-free perovskite materials and their distinctive features. Although the efficiency levels of these devices are not very high, the improvements they have made with remarkable stability characteristics make them a viable candidate for commercial perovskite photovoltaics
{"title":"A Review on Antimony-based Perovskite Solar Cells","authors":"Ankit Stephen Thomas","doi":"10.20961/equilibrium.v6i2.64322","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i2.64322","url":null,"abstract":"Abstract: Over the past decade, lead halide perovskite light absorbers have been the conventionally used perovskite light absorbers. However, there is an urgent call for alternative perovskite materials with toxicity levels and poor stability to UV radiations. Antimony-based perovskites have proven to be a material with unique optoelectronic properties, conventional fabrication processes, low-toxicity levels and high stability values. In this review, we look into the structure of antimony perovskites, the various research achievements over recent years, and the challenges and opportunities ahead for this budding technology. The review also highlights the various computational, theoretical and experimental studies done by researchers to highlight the peculiar Lead-free perovskite materials and their distinctive features. Although the efficiency levels of these devices are not very high, the improvements they have made with remarkable stability characteristics make them a viable candidate for commercial perovskite photovoltaics","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80957740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRAK. Konsumsi energi pada sektor transportasi di Indonesia sangat besar dikarenakan penggunaan BBM yang sangat besar. Besarnya proporsi penggunaan BBM untuk transportasi juga diikuti dengan besarnya subsidi pemerintah untuk BBM. Data sepanjang tahun 2010-2020 menunjukkan realisasi subsidi BBM selalu lebih besar dibandingkan dengan yang dianggarkan. Sehingga perlunya alternatif untuk mengurangi konsumsi BBM pada sektor transportasi. Dari sisi teknis peluang penggunaan bioetanol generasi 1 (G1) berbahan molasses mudah di aplikasikan karena proses yang sederhana. Dari analisis ekonomi terlihaat bahawa projek ini layak dilakukan ketika NPV dan DCFROR bernilai positif, sehingga saat harga molasses 1.500,00/ Kg dan harga bioetanol 15.000,00/ liter projek ini layak dilakukan, begitu juga ketika harga molasses 2.061,00/ Kg dan harga bioetanol 16.000,00/ liter serta ketika harga molasses 2.061,00/ Kg dan harga bioetanol 15.000,00/ liter, namun ketika harga molasses 2.061,00/ Kg dan harga bioetanol 12.113,00/ liter projek ini tidak layak dilakukan karena NPV dan DCFROR bernilai negatif. Dari hasil simulasi tersebut diketahui bahwa harga molases dan bioetanol sangat berpengaruh terhadap realisasi substitusi BBM dengan bioetanol, selain itu ketersedian bahan baku yaitu molasses juga perlu diperhatikan untuk menjaga kontinuitas proses. ABSTRACT. Energy consumption in the transportation sector in Indonesia is very large due to the very large use of fuel. A large proportion of the use of fuel for transportation is also followed by the number of government subsidies for fuel. Data throughout 2010-2020 show that the realization of fuel subsidies is always higher than the budgeted one. So the need for alternatives to reduce fuel consumption in the transportation sector. From a technical point of view, the opportunity to use bioethanol generation 1 (G1) which is made from molasses is easy to apply because of the simple process. From the economic analysis, it can be seen that this project is feasible when the NPV and DCFROR are positive, so when the molasses price is 1.500,00/Kg and the bioethanol price is 15,000.00/liter this project is feasible, as well as when the molasses price is 2.061,00/Kg and the price of molasses is 2.061,00/Kg. bioethanol 16.000,00/liter and when the price of molasses is 2.061,00/Kg and the price of bioethanol is 15.000,00/liter, but when the price of molasses is 2.061,00/Kg and the price of bioethanol is 12.113,00/liter this project is not feasible because of NPV and DCFROR have a negative value. From the simulation results, it is known that the price of molasses and bioethanol is very influential on the realization of the substitution of fuel with bioethanol, the availability of raw materials or molasses also needs to be considered to maintain the continuity of the process.
抽象。印尼运输部门的能源消耗是巨大的，因为燃料的使用非常广泛。汽油运输使用比例以及政府对汽油的补贴水平。2010年至2020年的数据显示，燃料补贴的实现总是比预算更高。因此，在运输部门需要替代燃料的需要。由1代(G1)衍生的生物乙醇的技术机会，由于使用过程的简单，很容易被应用。terlihaat经济分析的这个项目值得当NPV和DCFROR总有积极价值,所以当价格糖浆1.500,00 /公斤,价格15.000,00生物乙醇生产国,升这个项目值得做,当糖浆2.061,00 /公斤,价格也是16.000,00 -升生物乙醇生产国,以及当糖浆2.061,00 /公斤,价格15.000,00生物乙醇生产国,价格升,但当糖蜜价格为2061.1 / Kg，生物乙醇价格为12113.00 /升时，该项目不值得进行，因为NPV和DCFROR具有负面价值。根据这些模拟结果，molases和bio乙醇的价格与生物乙醇的替代品的实现有着深远的影响，除了必须考虑到糖浆的原料可用性，以便保持进程的持续持续性。抽象。印尼运输区的能量消耗与燃料的使用非常相似。政府补贴的汽油数量也在效仿。2010-2020年的数据显示，燃料的实现衰退总是比预算更高。因此，在运输区需要减少燃料的替代方案。从一个技术观点来看，用生物乙醇生成的机会很容易因为简单的处理而被接受。从《经济分析,它可以看到这就是这个项目是可行的时候NPV和DCFROR是阳性,所以当《bioethanol糖浆价格是1.500,00 /公斤,价格是15000点/升。这个项目是可行的,as well as的时候糖浆价格是2.061,00公斤和糖浆之普莱斯是2.061,00 /公斤。bioethanol 16.000,00 -普莱斯》升当糖浆是2.061,00公斤and the price of bioethanol是15.000,00 /升,但当《糖浆价格是2.061,00 / Kg和《bioethanol普莱斯是12.113,00升这项目不可行,因为NPV DCFROR著作百科全书》祝你们负价值。从结果的模拟来看，我们知道糖浆和生物乙醇的价格与生物乙醇的实现关系密切，而原始材料或糖浆的应用也需要被考虑来延续这些进程。
{"title":"Kajian Teknoekonomi Bioetanol Berbahan Molasses Sebagai Alternatif Substitusi BBM","authors":"Awaludin Fitroh Rifa'i, Widyanggoro Pamungkas, Rosana Budi Setyawati, Candra Pangesti Setiawan, J. Waluyo","doi":"10.20961/equilibrium.v6i1.63158","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.63158","url":null,"abstract":"ABSTRAK. Konsumsi energi pada sektor transportasi di Indonesia sangat besar dikarenakan penggunaan BBM yang sangat besar. Besarnya proporsi penggunaan BBM untuk transportasi juga diikuti dengan besarnya subsidi pemerintah untuk BBM. Data sepanjang tahun 2010-2020 menunjukkan realisasi subsidi BBM selalu lebih besar dibandingkan dengan yang dianggarkan. Sehingga perlunya alternatif untuk mengurangi konsumsi BBM pada sektor transportasi. Dari sisi teknis peluang penggunaan bioetanol generasi 1 (G1) berbahan molasses mudah di aplikasikan karena proses yang sederhana. Dari analisis ekonomi terlihaat bahawa projek ini layak dilakukan ketika NPV dan DCFROR bernilai positif, sehingga saat harga molasses 1.500,00/ Kg dan harga bioetanol 15.000,00/ liter projek ini layak dilakukan, begitu juga ketika harga molasses 2.061,00/ Kg dan harga bioetanol 16.000,00/ liter serta ketika harga molasses 2.061,00/ Kg dan harga bioetanol 15.000,00/ liter, namun ketika harga molasses 2.061,00/ Kg dan harga bioetanol 12.113,00/ liter projek ini tidak layak dilakukan karena NPV dan DCFROR bernilai negatif. Dari hasil simulasi tersebut diketahui bahwa harga molases dan bioetanol sangat berpengaruh terhadap realisasi substitusi BBM dengan bioetanol, selain itu ketersedian bahan baku yaitu molasses juga perlu diperhatikan untuk menjaga kontinuitas proses. ABSTRACT. Energy consumption in the transportation sector in Indonesia is very large due to the very large use of fuel. A large proportion of the use of fuel for transportation is also followed by the number of government subsidies for fuel. Data throughout 2010-2020 show that the realization of fuel subsidies is always higher than the budgeted one. So the need for alternatives to reduce fuel consumption in the transportation sector. From a technical point of view, the opportunity to use bioethanol generation 1 (G1) which is made from molasses is easy to apply because of the simple process. From the economic analysis, it can be seen that this project is feasible when the NPV and DCFROR are positive, so when the molasses price is 1.500,00/Kg and the bioethanol price is 15,000.00/liter this project is feasible, as well as when the molasses price is 2.061,00/Kg and the price of molasses is 2.061,00/Kg. bioethanol 16.000,00/liter and when the price of molasses is 2.061,00/Kg and the price of bioethanol is 15.000,00/liter, but when the price of molasses is 2.061,00/Kg and the price of bioethanol is 12.113,00/liter this project is not feasible because of NPV and DCFROR have a negative value. From the simulation results, it is known that the price of molasses and bioethanol is very influential on the realization of the substitution of fuel with bioethanol, the availability of raw materials or molasses also needs to be considered to maintain the continuity of the process.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81125812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Batik dye waste pollutes the Bengawan Solo River in high levels. One of the effective efforts to overcome pollution in the aquatic environment is through a degradation process using photocatalysts with UV-rays. In this research, carbon nitride nanosheets as photocatalyst with zirconium and cobalt doping was used. The addition of doping on g-C3N4 nanosheets was able to improve the photocatalytic performance. The purpose of this study was to determine the effect of various types of doping on the photoremediation performance of carbon nitride nanosheets. Synthesize Co-doped g-C3N4 nanosheets and Zr-doped g-C3N4 nanosheets was carried out by synthesizing pure g-C3N4 nanosheets using melamine and ammonium sulfate that calcined at 600°C. Afterwards, the mixture was impregnated by Zr and Co-doped using a vacuum evaporator. The effectiveness of the photocatalyst to degrading rhodamine-B was analyzed using X-Ray Diffraction (XRD) and UV-Visible Spectrophotometer. The result shows that photodegradation performance of Co and Zr-doped g-C3N4 nanosheets has increased. Based on the absorbance data of photocatalysts, the Zr-doped g-C3N4 nanosheets photocatalyst give the most optimal results in degrading rhodamine-B with the final rhodamine-B concentration close to zero.
{"title":"Sintesis Metal-Doped Carbon Nitride Nanosheets sebagai Pengurai Limbah Pewarna secara Fotokatalisis","authors":"Tsabitul Faiz, Taradiva Nabila, Anatta Wahyu Budiman","doi":"10.20961/equilibrium.v6i1.62258","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.62258","url":null,"abstract":"Batik dye waste pollutes the Bengawan Solo River in high levels. One of the effective efforts to overcome pollution in the aquatic environment is through a degradation process using photocatalysts with UV-rays. In this research, carbon nitride nanosheets as photocatalyst with zirconium and cobalt doping was used. The addition of doping on g-C3N4 nanosheets was able to improve the photocatalytic performance. The purpose of this study was to determine the effect of various types of doping on the photoremediation performance of carbon nitride nanosheets. Synthesize Co-doped g-C3N4 nanosheets and Zr-doped g-C3N4 nanosheets was carried out by synthesizing pure g-C3N4 nanosheets using melamine and ammonium sulfate that calcined at 600°C. Afterwards, the mixture was impregnated by Zr and Co-doped using a vacuum evaporator. The effectiveness of the photocatalyst to degrading rhodamine-B was analyzed using X-Ray Diffraction (XRD) and UV-Visible Spectrophotometer. The result shows that photodegradation performance of Co and Zr-doped g-C3N4 nanosheets has increased. Based on the absorbance data of photocatalysts, the Zr-doped g-C3N4 nanosheets photocatalyst give the most optimal results in degrading rhodamine-B with the final rhodamine-B concentration close to zero.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72930671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-08-08DOI: 10.20961/equilibrium.v6i1.62552
Ardimas Fauzan Huwaidi, Edy Supriyo
ABSTRAK. Plastik menimbulkan kerusakan lingkungan karena sifatnya yang sulit terurai secara alami. Banyaknya ampas tebu di Indonesia dan tingginya kandungan selulosa dapat digunakan sebagai pengisi pada pembuatan bioplastik. Selulosa memberikan sifat kedap air, menghambat biodegradasai, dan meningkatkan kuat tarik bioplastik. Oleh karena itu dilakukan penelitian pembuatan bioplastik menggunakan ampas tebu sebagai pengisi. Pembuatan bioplastik menggunakan metode solution casting. Hasil terbaik pengujian daya serap air pada rasio pati:ampas tebu 7,5:2,5; massa sorbitol 2,3 gr; dan suhu 75oC dengan nilai 46,638%. Hasil terbaik pengujian biodegradasi pada rasio pati:ampas tebu 8,5:1,5; masssa sorbitol 2,7 gr; dan suhu 65oC dengan nilai 88,253%. Hasil terbaik pengujian kuat tarik dan perpanjangan putus dengan nilai 2.9574 N/mm2 dan 0.8896%. Hasil kedua pengujian masih belum memenuhi standar SNI 7828:2014.
Kata kunci:
Ampas Tebu, Bioplastik, dan Selulosa
ABSTRACT. Plastic causes environmental pollution because it is difficult to decompose in nature. The large amount of bagasse in Indonesia and the high cellulose content can be used as filler for making bioplastics. Cellulose as a bioplastic filler provides water resistance, inhibits biodegradation, and increases tensile strength. Therefore, research was conducted using bagasse as a bioplastic filler. Bioplastics are made by the solution casting method. The best results of water absorption at the ratio of starch: bagasse 7.5:2.5; mass of sorbitol 2,3 g; and temperature of 75oC with a value of 46.638%. The best results of biodegradability at the ratio of starch: bagasse 8.5:1.5; mass of sorbitol 2,7 g; and temperature of 65oC with a value of 88.253%. The best results of tensile strength and elongation at break are 2.9574 N/mm2 and 0.8896%. The results of the both tests still do not meet the requirements of SNI 7818:2014 standard.
{"title":"Pembuatan Plastik Biodegradable Pati Jagung Terplastisasi Sorbitol dengan Pengisi Selulosa dari Ampas Tebu","authors":"Ardimas Fauzan Huwaidi, Edy Supriyo","doi":"10.20961/equilibrium.v6i1.62552","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.62552","url":null,"abstract":"<p><strong>ABSTRAK</strong>. Plastik menimbulkan kerusakan lingkungan karena sifatnya yang sulit terurai secara alami. Banyaknya ampas tebu di Indonesia dan tingginya kandungan selulosa dapat digunakan sebagai pengisi pada pembuatan bioplastik. Selulosa memberikan sifat kedap air, menghambat biodegradasai, dan meningkatkan kuat tarik bioplastik. Oleh karena itu dilakukan penelitian pembuatan bioplastik menggunakan ampas tebu sebagai pengisi. Pembuatan bioplastik menggunakan metode <em>solution casting. </em>Hasil terbaik pengujian daya serap air pada rasio pati:ampas tebu 7,5:2,5; massa sorbitol 2,3 gr; dan suhu 75<sup>o</sup>C dengan nilai 46,638%. Hasil terbaik pengujian biodegradasi pada rasio pati:ampas tebu 8,5:1,5; masssa sorbitol 2,7 gr; dan suhu 65<sup>o</sup>C dengan nilai 88,253%. Hasil terbaik pengujian kuat tarik dan perpanjangan putus dengan nilai 2.9574 N/mm<sup>2</sup> dan 0.8896%. Hasil kedua pengujian masih belum memenuhi standar SNI 7828:2014.</p><p align=\"left\"><strong>Kata kunci:</strong></p><p>Ampas Tebu, Bioplastik, dan Selulosa</p><p> </p><p><strong>ABSTRACT. </strong>Plastic causes environmental pollution because it is difficult to decompose in nature. The large amount of bagasse in Indonesia and the high cellulose content can be used as filler for making bioplastics. Cellulose as a bioplastic filler provides water resistance, inhibits biodegradation, and increases tensile strength. Therefore, research was conducted using bagasse as a bioplastic filler. Bioplastics are made by the solution casting method. The best results of water absorption at the ratio of starch: bagasse 7.5:2.5; mass of sorbitol 2,3 g; and temperature of 75<sup>o</sup>C with a value of 46.638%. The best results of biodegradability at the ratio of starch: bagasse 8.5:1.5; mass of sorbitol 2,7 g; and temperature of 65<sup>o</sup>C with a value of 88.253%. The best results of tensile strength and elongation at break are 2.9574 N/mm<sup>2</sup> and 0.8896%. The results of the both tests still do not meet the requirements of SNI 7818:2014 standard.</p><p align=\"left\"><strong>Keywords:</strong></p><p align=\"left\">Bagasse, Bioplastic, and Cellulose</p>","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76571063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-08-01DOI: 10.20961/equilibrium.v6i1.61498
J. Waluyo, Paryanto Paryanto, M. Margono, Sofiana Mukti Wigati, Shafira Rachmadhani, Ibnu Pranoto, Yulinar Pramesti Cahyani
ABSTRAK. Kabupaten Boyolali memiliki jumlah penduduk tertinggi kedua di eks-Karesidenan Surakarta sehingga limbah cair domestik yang dihasilkan juga tinggi. Hal ini mendorong upaya pengelolaan limbah domestik menggunakan SANFAB ST 600. Penelitian ini bertujuan untuk mengetahui efektivitas kinerja IPAL Individual SANFAB ST 600 setelah diberi perlakuan dengan Anaerobic Granule Bacteria. SANFAB ST 600 memiliki volume 600 L dan berkapasitas 1-4 orang. Air limbah rumah tangga yang dialirkan ke inlet ST akan menuju ke settler, selanjutnya mengalir secara upstream dalam unit Anaerobic Filter dan terjadi penguraian zat pencemar oleh bakteri anaerobik. Pengambilan sampel dilakukan pada dua rumah di Dusun Karangmojo, Kabupaten Boyolali. Sampel diuji di BLKK Yogyakarta untuk parameter TSS, COD, BOD, konsentrasi Amonia, pH, dan ORP. Pada minggu ketiga di Rumah Bapak Wahyudi, karakteristik outlet ST memiliki nilai TSS 25,5 mg/L, Amonia 0,255 mg/L, BOD 25,01 mg/L, dan COD 47,92 mg/L sehingga sudah sesuai baku mutu. Dari hasil uji dilakukan perhitungan efektivitas pengolahan TSS, BOD, dan COD dengan cara menghitung selisih konstanta inlet dan outlet dibagi dengan konstanta inlet serta perhitungan rasio BOD/COD dengan membagi kadar COD dan BOD setiap sampel. Dari sumber limbah WC dan kamar mandi (Rumah Bapak Wahyudi) bakteri bekerja lebih efektif dibanding sumber limbah WC (Rumah Bapak Somowirejo) dengan efisiensi lebih dari 80% pada minggu ketiga penambahan bakteri. Kata kunci:anaerobic granule bacteria, efisiensi, limbah domestik, IPAL ST 600 ABSTRACT. Boyolali Regency has the second highest population in the residence of Surakarta so the domestic wastewater generation is also high. This led to the management of domestic wastewater using Individual WWTP SANFAB ST 600. This study aims to determine the effectiveness of Individual WWTP SANFAB ST 600 after being treated with Anaerobic Granule Bacteria. The SANFAB ST 600 has a volume of 600 L and a capacity of 1-4 people. Domestic wastewater that flows into the ST inlet will go to the settler, then flows upstream into the Anaerobic Filter unit and decomposed by anaerobic bacteria. Sampling was carried out at two houses in Karangmojo, Boyolali Regency. Samples were tested at BLKK Yogyakarta for parameters of TSS, COD, BOD, Ammonia concentration, pH, and ORP. In the third week at Wahyudi's house, the characteristics of the ST outlet had a value of TSS 25.5 mg/L, Ammonia 0.255 mg/L, BOD 25.01 mg/L, and COD 47.92 mg/L so it already suitable with the standard. From the test results, the effectiveness of TSS, BOD, and COD reduction is calculated by the difference between the inlet and outlet constants divided by the inlet constant and also calculating the BOD/COD ratio by dividing the COD and BOD levels of each sample. From the source of WC and bathroom waste (Mr. Wahyudi's House) the bacteria worked more effectively than the WC source (Mr. Somowirejo's House) with an efficiency of more than 80% in the third week after
抽象。Boyolali地区人口第二多，苏拉卡塔州的家庭污水产量也很高。这推动了国内废物管理的努力，使用圣法第600号。本研究的目的是确定圣法第600个体在接受对颗粒杆菌的无氧杆菌治疗后的表现。圣法第600卷可达600升，可容纳1-4人。家庭废水被输送到入口的清洗液将被输送到settler单位，然后在厌氧过滤器的上游流动，并进行再分解由厌氧细菌污染的物质。在博约拉利区Karangmojo村的两所房屋进行了抽样。样本在BLKK Yogyakarta进行测试，以检测TSS参数、鳕鱼、BOD、氨浓度、pH和ORP。在Wahyudi先生家的第三周，ST出口的特性被认为是TSS 25.5 mg/L，氨0.255 mg/L, BOD 2501 mg/L，以及47.92 mg/L的优质产品。通过计算TSS、BOD和鳕鱼处理的有效性计算，将进口常数和出口除以进口常数和出口之间的差异，并通过除以每个样本的鳕鱼水平和BOD -鳕鱼比来计算。在第三周增加细菌，效率超过80%。关键词:厌氧杆菌，效率，家庭浪费，平均智商。Boyolali Regency在Surakarta的住宅中排名第二的人口也很高。这将通过WWTP SANFAB个人使用第600号的管理。这项研究旨在确定世界自然基金会及其圣圣600后对其个体的影响。圣诞老人有600卷，一卷1-4人。漂浮在圣内的水的驯化会流到管道中，然后流入合成过滤器，通过对细菌的再分解。抽样被带到了卡里莫的两间房子里。样本是测试TSS、鳕鱼、BOD、肺心病、pH和ORP的。在第三周的瓦希迪的房子里，圣分店的特点是TSS 25.5毫克/L, amservits 0255 mg/L, BOD 25.01 mg/L，还有47.92 mg/ i的含量，所以它已经符合标准。从测试结果来看，TSS、BOD和减减的结果是由滞后和出口之间的差异来计算的。从浴室和浴室废物的来源来看，细菌的作用比厕所资源更有效，毒性远远超过细菌处理后第三周的80%。镇痛细菌，effiency，驯化wastewater, IPAL ST 600
{"title":"Evaluasi Kinerja IPAL Individual SANFAB ST 600 dengan Penambahan Anaerobic Granule Bacteria terhadap Outlet IPAL Domestik di Dusun Karangmojo, Boyolali","authors":"J. Waluyo, Paryanto Paryanto, M. Margono, Sofiana Mukti Wigati, Shafira Rachmadhani, Ibnu Pranoto, Yulinar Pramesti Cahyani","doi":"10.20961/equilibrium.v6i1.61498","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.61498","url":null,"abstract":"ABSTRAK. Kabupaten Boyolali memiliki jumlah penduduk tertinggi kedua di eks-Karesidenan Surakarta sehingga limbah cair domestik yang dihasilkan juga tinggi. Hal ini mendorong upaya pengelolaan limbah domestik menggunakan SANFAB ST 600. Penelitian ini bertujuan untuk mengetahui efektivitas kinerja IPAL Individual SANFAB ST 600 setelah diberi perlakuan dengan Anaerobic Granule Bacteria. SANFAB ST 600 memiliki volume 600 L dan berkapasitas 1-4 orang. Air limbah rumah tangga yang dialirkan ke inlet ST akan menuju ke settler, selanjutnya mengalir secara upstream dalam unit Anaerobic Filter dan terjadi penguraian zat pencemar oleh bakteri anaerobik. Pengambilan sampel dilakukan pada dua rumah di Dusun Karangmojo, Kabupaten Boyolali. Sampel diuji di BLKK Yogyakarta untuk parameter TSS, COD, BOD, konsentrasi Amonia, pH, dan ORP. Pada minggu ketiga di Rumah Bapak Wahyudi, karakteristik outlet ST memiliki nilai TSS 25,5 mg/L, Amonia 0,255 mg/L, BOD 25,01 mg/L, dan COD 47,92 mg/L sehingga sudah sesuai baku mutu. Dari hasil uji dilakukan perhitungan efektivitas pengolahan TSS, BOD, dan COD dengan cara menghitung selisih konstanta inlet dan outlet dibagi dengan konstanta inlet serta perhitungan rasio BOD/COD dengan membagi kadar COD dan BOD setiap sampel. Dari sumber limbah WC dan kamar mandi (Rumah Bapak Wahyudi) bakteri bekerja lebih efektif dibanding sumber limbah WC (Rumah Bapak Somowirejo) dengan efisiensi lebih dari 80% pada minggu ketiga penambahan bakteri. Kata kunci:anaerobic granule bacteria, efisiensi, limbah domestik, IPAL ST 600 ABSTRACT. Boyolali Regency has the second highest population in the residence of Surakarta so the domestic wastewater generation is also high. This led to the management of domestic wastewater using Individual WWTP SANFAB ST 600. This study aims to determine the effectiveness of Individual WWTP SANFAB ST 600 after being treated with Anaerobic Granule Bacteria. The SANFAB ST 600 has a volume of 600 L and a capacity of 1-4 people. Domestic wastewater that flows into the ST inlet will go to the settler, then flows upstream into the Anaerobic Filter unit and decomposed by anaerobic bacteria. Sampling was carried out at two houses in Karangmojo, Boyolali Regency. Samples were tested at BLKK Yogyakarta for parameters of TSS, COD, BOD, Ammonia concentration, pH, and ORP. In the third week at Wahyudi's house, the characteristics of the ST outlet had a value of TSS 25.5 mg/L, Ammonia 0.255 mg/L, BOD 25.01 mg/L, and COD 47.92 mg/L so it already suitable with the standard. From the test results, the effectiveness of TSS, BOD, and COD reduction is calculated by the difference between the inlet and outlet constants divided by the inlet constant and also calculating the BOD/COD ratio by dividing the COD and BOD levels of each sample. From the source of WC and bathroom waste (Mr. Wahyudi's House) the bacteria worked more effectively than the WC source (Mr. Somowirejo's House) with an efficiency of more than 80% in the third week after ","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79356293","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
ABSTRAK. Carbon nanodots (CNDs) merupakan nanomaterial yang berukuran dibawah 10 nm. CNDs memiliki keunggulan diantaranya yaitu fotostabilitas tinggi, biokompatibilitas baik, toksisitas yang rendah, mudah dibuat, dan ramah lingkungan. Sumber karbon yang digunakan berasal dari molase karena murah dan mudah didapat serta merupakan hasil samping dari pengolahan tebu. Pada penelitian ini digunakan metode pemanasan terbantukan gelombang mikro atau Microwave Assisted Extraction (MAE) yang memberikan hasil suspensi yang homogen, pemanasan efisien, dan waktu yang singkat. Waktu iradiasi mempengaruhi energi gap CNDs dari molase yang dihasilkan. Waktu yang optimum untuk sintesis CNDs dari molase menggunakan metode MAE yaitu selama 3 menit. Efek fluoresensi telah diamati untuk suspensi CNDs yang mengubah warna kuning menjadi warna biru dibawah sinar UV 366 nm. Karakterisasi menggunakan spektrofotometri UV-Vis menunjukan serapan maksimum CNDs dari molase pada panjang gelombang 255 nm dengan energi gap sebesar 4,55 eV.Kata kunci:carbon nanodots, microwave, molaseABSTRACT. Carbon nanodots (CNDs) are nanomaterials with a size below 10 nm. CNDs have advantages such as high photostability, good biocompatibility, low toxicity, easy to manufacture, and environmentally friendly. The carbon source used comes from molasses because it is cheap and easy to obtain and is a by-product of sugarcane processing. In this study, the Microwave Assisted Extraction (MAE) method was used which gave homogeneous suspension results, efficient heating, and short time. The irradiation time affects the energy gap of the CNDs of the molasses produced. The optimum time for the synthesis of CNDs from molasses using the MAE method is 3 minutes. Fluorescence effects have been observed for suspensions of CNDs which turn yellow to blue under 366 nm UV light. Characterization using UV-Vis spectrophotometry showed the maximum absorption of CNDs from molasses at a wavelength of 255 nm with an energy gap of 4.55 eV.Keywords:carbon nanodots, microwave, molasses
{"title":"Sintesis Carbon Nanodots dari Molase Menggunakan Metode Pemanasan Terbantukan Gelombang Mikro","authors":"Mentik Hulupi, Nida Nabilah, Tiana Hasna Nabilah, Keryanti Keryanti, Fauzi Abdilah","doi":"10.20961/equilibrium.v6i1.61212","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.61212","url":null,"abstract":"ABSTRAK. Carbon nanodots (CNDs) merupakan nanomaterial yang berukuran dibawah 10 nm. CNDs memiliki keunggulan diantaranya yaitu fotostabilitas tinggi, biokompatibilitas baik, toksisitas yang rendah, mudah dibuat, dan ramah lingkungan. Sumber karbon yang digunakan berasal dari molase karena murah dan mudah didapat serta merupakan hasil samping dari pengolahan tebu. Pada penelitian ini digunakan metode pemanasan terbantukan gelombang mikro atau Microwave Assisted Extraction (MAE) yang memberikan hasil suspensi yang homogen, pemanasan efisien, dan waktu yang singkat. Waktu iradiasi mempengaruhi energi gap CNDs dari molase yang dihasilkan. Waktu yang optimum untuk sintesis CNDs dari molase menggunakan metode MAE yaitu selama 3 menit. Efek fluoresensi telah diamati untuk suspensi CNDs yang mengubah warna kuning menjadi warna biru dibawah sinar UV 366 nm. Karakterisasi menggunakan spektrofotometri UV-Vis menunjukan serapan maksimum CNDs dari molase pada panjang gelombang 255 nm dengan energi gap sebesar 4,55 eV.Kata kunci:carbon nanodots, microwave, molaseABSTRACT. Carbon nanodots (CNDs) are nanomaterials with a size below 10 nm. CNDs have advantages such as high photostability, good biocompatibility, low toxicity, easy to manufacture, and environmentally friendly. The carbon source used comes from molasses because it is cheap and easy to obtain and is a by-product of sugarcane processing. In this study, the Microwave Assisted Extraction (MAE) method was used which gave homogeneous suspension results, efficient heating, and short time. The irradiation time affects the energy gap of the CNDs of the molasses produced. The optimum time for the synthesis of CNDs from molasses using the MAE method is 3 minutes. Fluorescence effects have been observed for suspensions of CNDs which turn yellow to blue under 366 nm UV light. Characterization using UV-Vis spectrophotometry showed the maximum absorption of CNDs from molasses at a wavelength of 255 nm with an energy gap of 4.55 eV.Keywords:carbon nanodots, microwave, molasses ","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72900925","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-06-22DOI: 10.20961/equilibrium.v6i1.61211
J. D. Dangwang Dikdim, Germain Vaimata Djinsi, Tsamo Cornelius
ABSTRACT. Tanning activity consumes high volumes of water resulting in large volumes of highly colored polluted wastewater being discharged to the environment. In this study, the discoloration of the wastewater of the local artisanal tannery using SiO2 synthesized from rice husks and silica/sand mixture at different process conditions was investigated. The results revealed that the discoloration process is favorable for both adsorbents at 35oC with maximum of 61% for sand/SiO2 mixture system and 64% for SiO2 system. The presence of NaCl electrolyte enhanced the discoloration for both adsorbents increasing from 44% for sand/SiO2 mixture at 0 NaCl to 72% at 0.5M NaCl and from 49% for SiO2 system at 0 NaCl to 63 % at 0.5M NaCl. Increasing the amount of sand from 0.2 to 1 g at fixed SiO2 of 0.1 g in sand/SiO2 mixture showed discoloration from 40-41 % while increasing SiO2 in SiO2 alone system from 0.05 to 0.5 g had a discoloration of 45-71%. Results of this study shows that sand a very abundant local and worldwide material can be complemented with silica in a very low cost tannery wastewater discoloration process.
{"title":"Batch mode treatment of wastewater from the Maroua artisanal tannery using silica extracted from rice husks and silica/sand mixture","authors":"J. D. Dangwang Dikdim, Germain Vaimata Djinsi, Tsamo Cornelius","doi":"10.20961/equilibrium.v6i1.61211","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.61211","url":null,"abstract":"<p><strong>ABSTRACT.</strong> Tanning activity consumes high volumes of water resulting in large volumes of highly colored polluted wastewater being discharged to the environment. In this study, the discoloration of the wastewater of the local artisanal tannery using SiO<sub>2</sub> synthesized from rice husks and silica/sand mixture at different process conditions was investigated. The results revealed that the discoloration process is favorable for both adsorbents at 35<sup>o</sup>C with maximum of 61% for sand/SiO<sub>2</sub> mixture system and 64% for SiO<sub>2</sub> system. The presence of NaCl electrolyte enhanced the discoloration for both adsorbents increasing from 44% for sand/SiO<sub>2</sub> mixture at 0 NaCl to 72% at 0.5M NaCl and from 49% for SiO<sub>2</sub> system at 0 NaCl to 63 % at 0.5M NaCl. Increasing the amount of sand from 0.2 to 1 g at fixed SiO<sub>2</sub> of 0.1 g in sand/SiO<sub>2</sub> mixture showed discoloration from 40-41 % while increasing SiO<sub>2</sub> in SiO<sub>2</sub> alone system from 0.05 to 0.5 g had a discoloration of 45-71%. Results of this study shows that sand a very abundant local and worldwide material can be complemented with silica in a very low cost tannery wastewater discoloration process.</p><p><strong>Keywords:</strong></p><p>Tannery, Wastewater, Silica, Sand, Discoloration</p>","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77446750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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