Pub Date : 2022-04-24DOI: 10.20961/equilibrium.v6i1.58249
Viona Rohmah Armia Gita Kusuma, Gemilang Ramadhan Syahputraningrat, H. Rahman, Fadilah Fadilah
Abstrak. Extra virgin olive oil (EVOO) adalah olahan pertama minyak zaitun tanpa campuran ekstrak lainnya yang mengandung senyawa antioksidan berupa senyawa fenolik, tokoferol, squalene, klorofil, β-karoten, dan polifenol. Kandungan antioksidan ini mudah teroksidasi sehingga perlu dipertahankan dengan cara mikroenkapsulasi. Mikroenkapsulasi merupakan penyalutan tipis dengan polimer pada partikel kecil zat padat dan dispersi zat cair dimana ukuran partikel antara 1-5000 µm. Riset ini bertujuan untuk mengetahui pengaruh penambahan volume bahan inti dan komposisi campuran polimer pada mikroenkapsulasi EVOO dengan penyalut polimer alam kappa-karagenan dan glukomanan menggunakan metode koaservasi. Keberhasilan EVOO tersalut dalam polimer ditunjukkan berdasarkan rendemen mikrokapsul, Fourier Transform Infra Red Spectrophotometer (FTIR), Scanning Electron Microscope (SEM), dan efisiensi enkapsulasi. Hasil riset didapatkan penambahan volume minyak dan campuran komposisi polimer berpengaruh terhadap efisiensi yang dihasilkan. Efisiensi enkapsulasi tertinggi terdapat pada penambahan volume EVOO 0,5 mL sebesar 74,996% dan komposisi polimer pada 0,2 g kappa-karagenan + 0,1 g glukomanan sebesar 77,5637%. Kata kunci: Extra Virgin Olive Oil, Koaservasi, Mikroenkapsulasi, Polimer Abstract. Extra virgin olive oil (EVOO) is the first processed olive oil without other extracts containing antioxidant compounds in the form of phenolic compounds, tocopherols, squalene, chlorophyll, β -carotene, and polyphenols. These antioxidants are easily oxidized so it need to be maintained using microencapsulation. Microencapsulation is a thin polymer coating on small solid particles and liquid dispersions where the particle size ranges from 1-5000 µm. The aim of the research is to determine the effect of the volume of core material and the composition of polymer mixture on EVOO microencapsulation using mixture natural polymer kappa-carrageenan and glucomannan by coacervation method. The success of coating EVOO by the polymer was demonstrated based on the yield, Fourier Transform Infra Red Spectrophotometer (FTIR), Scanning Electron Microscope (SEM), and encapsulation efficiency. The results showed that the addition of oil volume and a mixture of polymer compositions affected the resulting efficiency. The highest encapsulation efficiency was found in the addition of 0.5 mL EVOO which provides efficiency 74.996% and polymer composition at 0.2 g of kappa-carrageenan + 0.1 g of glucomannan which provides efficiency 77.5637%.Keywords:Extra Virgin Olive Oil, Coaservation Microencapsulation, Polymer
抽象。特级橄榄油混合(EVOO)是第精制橄榄油中没有其他提取物中含有一种化合物,抗氧化剂酚化合物,tokoferol、squalene叶绿素,β-karoten,和多酚。它的抗氧化剂含量很容易氧化，因此需要进行微浸来维持。Mikroenkapsulasi是penyalutan薄与聚合物在固体和液体分散体的小颗粒粒度之间1-5000µm。本研究旨在研究将EVOO显微浸聚合物与天然kappa-karagenan和gluco留意方法的观察方法结合起来的影响。EVOO在聚合物中的成功率是基于基于微生物兰尼、傅立叶变换红外线光镜米、扫描电子微镜和吸收效率。研究发现，石油体积增加和聚合物成分混合会影响其效率。最高的渗流效率是在EVOO 0.5 mL增加74.996%和聚合物成分在0.2 g kappa-karagenan + 0.1 g胶质增加77.5637%。关键词:特级初榨橄榄油，观察，微灌注，抽象聚合物。特级橄榄油(EVOO)是《第一processed橄榄油没有其他摘录containing antioxidant compounds in the form of酚compounds, tocopherols squalene有叶绿素,β-carotene,和polyphenols。这些抗氧化剂和抗氧化剂容易氧化，所以需要使用小肠。Microencapsulation is a thin液体固体聚合物涂料on small particles and dispersions那里的粒子大小从1-5000 rangesµm。研究对象的目的是确定核心材料体积和可塑聚合物在EVOO - carragenan和glucocomannan coacerd方法下的效果。聚合物中浮华的成功体现在农作物上，傅立叶变形红外线仪、扫描电子显微镜和耗竭性。结果表明，石油体积的增加和聚合物商业的混合影响了可再生的努力。最重要的效率消耗是在0.5毫升的effiention中发现的，以3.4万996%和聚合物composition at 0.2 g的kappa- carragenan + 0.0.1 g的果糖，以7.5637%的功用。额外的橄榄油，微缩缩，聚合物
{"title":"Pemanfaatan Polimer Alam Kappa-Karagenan dan Glukomanan untuk Mikroenkapsulasi Extra Virgin Olive Oil","authors":"Viona Rohmah Armia Gita Kusuma, Gemilang Ramadhan Syahputraningrat, H. Rahman, Fadilah Fadilah","doi":"10.20961/equilibrium.v6i1.58249","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.58249","url":null,"abstract":"Abstrak. Extra virgin olive oil (EVOO) adalah olahan pertama minyak zaitun tanpa campuran ekstrak lainnya yang mengandung senyawa antioksidan berupa senyawa fenolik, tokoferol, squalene, klorofil, β-karoten, dan polifenol. Kandungan antioksidan ini mudah teroksidasi sehingga perlu dipertahankan dengan cara mikroenkapsulasi. Mikroenkapsulasi merupakan penyalutan tipis dengan polimer pada partikel kecil zat padat dan dispersi zat cair dimana ukuran partikel antara 1-5000 µm. Riset ini bertujuan untuk mengetahui pengaruh penambahan volume bahan inti dan komposisi campuran polimer pada mikroenkapsulasi EVOO dengan penyalut polimer alam kappa-karagenan dan glukomanan menggunakan metode koaservasi. Keberhasilan EVOO tersalut dalam polimer ditunjukkan berdasarkan rendemen mikrokapsul, Fourier Transform Infra Red Spectrophotometer (FTIR), Scanning Electron Microscope (SEM), dan efisiensi enkapsulasi. Hasil riset didapatkan penambahan volume minyak dan campuran komposisi polimer berpengaruh terhadap efisiensi yang dihasilkan. Efisiensi enkapsulasi tertinggi terdapat pada penambahan volume EVOO 0,5 mL sebesar 74,996% dan komposisi polimer pada 0,2 g kappa-karagenan + 0,1 g glukomanan sebesar 77,5637%. Kata kunci: Extra Virgin Olive Oil, Koaservasi, Mikroenkapsulasi, Polimer Abstract. Extra virgin olive oil (EVOO) is the first processed olive oil without other extracts containing antioxidant compounds in the form of phenolic compounds, tocopherols, squalene, chlorophyll, β -carotene, and polyphenols. These antioxidants are easily oxidized so it need to be maintained using microencapsulation. Microencapsulation is a thin polymer coating on small solid particles and liquid dispersions where the particle size ranges from 1-5000 µm. The aim of the research is to determine the effect of the volume of core material and the composition of polymer mixture on EVOO microencapsulation using mixture natural polymer kappa-carrageenan and glucomannan by coacervation method. The success of coating EVOO by the polymer was demonstrated based on the yield, Fourier Transform Infra Red Spectrophotometer (FTIR), Scanning Electron Microscope (SEM), and encapsulation efficiency. The results showed that the addition of oil volume and a mixture of polymer compositions affected the resulting efficiency. The highest encapsulation efficiency was found in the addition of 0.5 mL EVOO which provides efficiency 74.996% and polymer composition at 0.2 g of kappa-carrageenan + 0.1 g of glucomannan which provides efficiency 77.5637%.Keywords:Extra Virgin Olive Oil, Coaservation Microencapsulation, Polymer ","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73514813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-04-22DOI: 10.20961/equilibrium.v6i1.58786
Fadilah Fadilah, Mujtahid Kaavessina, S. Distantina, Dwi Ardiana Setyawhardani, Endang Kwartiningsih, Aida Nur Ramadhani, Isa Fakhruddin, Amaldo Firjarahadi Tane
ABSTRAK.Poli asam laktat adalah polimer hidrofobik yang termasuk dalam kelas biomaterial yang bersifat biodegradable. Poli asam laktat berpotensi untuk dijadikan komposit polimer konduktif (conductive polymer composite - CPC) yang dipergunakan sebagai bahan semikonduktor dengan cara mencampurkan grafit kepadanya. Perilaku adsorpsi uap air perlu dipelajari untuk mengetahui stabilitas komposit dan ditunjukkan melalui kurva isotherm adsorpsi uap air. Tujuan dari penelitian ini adalah mempelajari isotherm adsorpsi uap air komposit poli asam laktat/grafit pada berbagai komposisi grafit. Pengamatan terhadap isotherm adsorpsi uap air dilakukan dengan metode gravimetri pada berbagai kondisi kelembaban relatif. Hasil yang diperoleh menunjukkan bahwa kurva isotherm mengikuti tipe II menurut kasifikasi Brunauer, yaitu kurva berbentuk sigmoidal. Semakin tinggi kondisi kelembaban relatif, semakin besar kandungan air kesetimbangan. Peningkatan kandungan air kesetimbangan secara tajam terjadi pada kondisi kelembaban di atas 75%. Semakin tinggi komposisi grafit, semakin besar kandungan uap air kesetimbangan. Data kesetimbangan dicocokkan dengan model kesetimbangan sorpsi uap air yaitu model Guggenhiem-Anderson-deBoer (GAB), model Peleg, dan model Oswin. Model GAB memberikan gambaran isotherm yang terbaik.
Kata kunci:
adsorpsi uap air, kesetimbangan, komposit, poli asam laktat/grafit, pemodelan
ABSTRACT. Poly(lactic acid)/PLA is a hydrophobic polymer that belongs to the class of biodegradable biomaterial. PLA can be used as material in the manufacture of conductive polymer composite (CPC), which is used as a semiconductor material by mixing graphite into it. The water vapor adsorption behavior needs to be studied to determine the stability of the composite. This research aims to investigate the water vapor adsorption isotherm in poly(lactic acid)/graphite composites on various graphite compositions. The gravimetric method carried observations on the water vapor adsorption isotherm at various relative humidity conditions. The results obtained indicate that the isotherm curve follows type II according to the Brunauer classification. The higher the relative humidity, the greater the equilibrium water content. A sharp increase in the equilibrium water content occurs at humidity conditions above 75%. The higher the graphite composition, the greater the equilibrium moisture content. The Guggenhiem-Anderson-deBoer (GAB), Peleg, and Oswin sorption models were used to fit the experimental data. The GAB model best described the isotherms of the composites.
{"title":"Isotherm Adsorbsi Uap Air Komposit Poli(asam laktat) - Grafit","authors":"Fadilah Fadilah, Mujtahid Kaavessina, S. Distantina, Dwi Ardiana Setyawhardani, Endang Kwartiningsih, Aida Nur Ramadhani, Isa Fakhruddin, Amaldo Firjarahadi Tane","doi":"10.20961/equilibrium.v6i1.58786","DOIUrl":"https://doi.org/10.20961/equilibrium.v6i1.58786","url":null,"abstract":"<p><strong><span lang=\"EN-US\">ABSTRAK.</span></strong><span lang=\"EN-US\">Poli asam laktat adalah polimer hidrofobik yang termasuk dalam kelas biomaterial yang bersifat biodegradable. Poli asam laktat berpotensi untuk dijadikan komposit polimer konduktif (<em>conductive polymer composite</em> - CPC) yang dipergunakan sebagai bahan semikonduktor dengan cara mencampurkan grafit kepadanya. Perilaku adsorpsi uap air perlu dipelajari untuk mengetahui stabilitas komposit dan ditunjukkan melalui kurva isotherm adsorpsi uap air. Tujuan dari penelitian ini adalah mempelajari isotherm adsorpsi uap air komposit poli asam laktat/grafit pada berbagai komposisi grafit. Pengamatan terhadap isotherm adsorpsi uap air dilakukan dengan metode gravimetri pada berbagai kondisi kelembaban relatif. Hasil yang diperoleh menunjukkan bahwa kurva isotherm mengikuti tipe II menurut kasifikasi Brunauer, yaitu kurva berbentuk <em>sigmoidal</em>. Semakin tinggi kondisi kelembaban relatif, semakin besar kandungan air kesetimbangan. Peningkatan kandungan air kesetimbangan secara tajam terjadi pada kondisi kelembaban di atas 75%. Semakin tinggi komposisi grafit, semakin besar kandungan uap air kesetimbangan. Data kesetimbangan dicocokkan dengan model kesetimbangan sorpsi uap air yaitu model <em>Guggenhiem-Anderson-deBoer</em> (GAB), model <em>Peleg</em>, dan model <em>Oswin</em>. Model GAB memberikan gambaran <em>isotherm</em> yang terbaik.</span></p><p><strong><span lang=\"EN-US\">Kata kunci:</span></strong></p><p align=\"left\">adsorpsi uap air, kesetimbangan, komposit, poli asam laktat/grafit, pemodelan </p><p align=\"left\"> </p><p align=\"left\"><strong><span lang=\"EN-US\">ABSTRACT. </span></strong><span lang=\"EN-US\">Poly(lactic acid)/PLA is a hydrophobic polymer that belongs to the class of biodegradable biomaterial. PLA can be used as material in the manufacture of conductive polymer composite (CPC), which is used as a semiconductor material by mixing graphite into it. The water vapor adsorption behavior needs to be studied to determine the stability of the composite. This research aims to investigate the water vapor adsorption isotherm in poly(lactic acid)/graphite composites on various graphite compositions. The gravimetric method carried observations on the water vapor adsorption isotherm at various relative humidity conditions. The results obtained indicate that the isotherm curve follows type II according to the Brunauer classification. The higher the relative humidity, the greater the equilibrium water content. A sharp increase in the equilibrium water content occurs at humidity conditions above 75%. The higher the graphite composition, the greater the equilibrium moisture content. The Guggenhiem-Anderson-deBoer (GAB), Peleg, and Oswin sorption models were used to fit the experimental data. The GAB model best described the isotherms of the composites.</span></p><p align=\"left\"><strong>Keywords:</strong></p><p align=\"left\">composite, equilibrium, modeling, poly(lactic acid)/ ","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-04-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78659863","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-18DOI: 10.20961/equilibrium.v5i2.58479
Suratno Lourentius
In order to meet the need for Liquified Petroleum Gas in Indonesia, which is currently around seventy percent of which is still imported, it is necessary to find a replacement. One of the efforts to replace the Liquified Petroleum Gas is by utilizing dimethyl ether which can be produced from coal as raw material. Coal can be catalytically converted to syngas and then syngas can be catalytically converted to dimethyl ether via a direct two-step or one-step route. This paper will discuss the one-step synthesis of dimethyl ether from syngas using Cu-Zn-Al/g-Alumina as a bifunctional catalyst. The syngas used consists of carbon monoxide and hydrogen with a mole ratio of 1:2. The conversion reaction was carried out in a fixed-bed reactor at the pressure of 40 bar, the temperature of 240-300 0C, and the space velocity of 29.3-32.7 mL/g catalyst/minute. The highest conversion of CO that can be achieved is 90.08 % at a temperature of 300 oC and the space velocity of 29.3 mL/g catalyst/minute. The synthesis product was analyzed using GC. The dimethyl ether is an environmentally friendly fuel and non-toxic compound that does not destroy ozone, does not contain sulfur, and has a calorific value of about 30.5 MJ/kg which is lower than 50.56 MJ/kg
{"title":"Synthesis of Syngas into Dimethyl Ether Using Cu-Zn-Al/-Alumina Bifunctional Catalyst as an Environmentally Friendly Fuel for Substituting Liquified Petroleum Gas","authors":"Suratno Lourentius","doi":"10.20961/equilibrium.v5i2.58479","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i2.58479","url":null,"abstract":"In order to meet the need for Liquified Petroleum Gas in Indonesia, which is currently around seventy percent of which is still imported, it is necessary to find a replacement. One of the efforts to replace the Liquified Petroleum Gas is by utilizing dimethyl ether which can be produced from coal as raw material. Coal can be catalytically converted to syngas and then syngas can be catalytically converted to dimethyl ether via a direct two-step or one-step route. This paper will discuss the one-step synthesis of dimethyl ether from syngas using Cu-Zn-Al/g-Alumina as a bifunctional catalyst. The syngas used consists of carbon monoxide and hydrogen with a mole ratio of 1:2. The conversion reaction was carried out in a fixed-bed reactor at the pressure of 40 bar, the temperature of 240-300 0C, and the space velocity of 29.3-32.7 mL/g catalyst/minute. The highest conversion of CO that can be achieved is 90.08 % at a temperature of 300 oC and the space velocity of 29.3 mL/g catalyst/minute. The synthesis product was analyzed using GC. The dimethyl ether is an environmentally friendly fuel and non-toxic compound that does not destroy ozone, does not contain sulfur, and has a calorific value of about 30.5 MJ/kg which is lower than 50.56 MJ/kg","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-01-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76699861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2022-01-13DOI: 10.20961/equilibrium.v5i2.54249
F. Putri, Aditya Surya Pratama, Fasha El Sauzsa, Dwi Ardiana Setyawardhani
Kesambi seed oil (Schleichera oleosa) is one of the resources that can be utilized as an alternative to substitute palm oil in cooking oil production due to its lower moisture content, peroxide value, and saponification number. However, the high level of free fatty acid (FFA) and cyanide acid (HCN) contents in kesambi seed oil requires further purification prior to commercialization. In this study, the purification process of kesambi seed oil was carried out with degumming, adsorption, and neutralization techniques. The degumming process was conducted using phosphoric acid for 20 minutes. Afterwards, the adsorption process was carried out using 25% (w/w) zeolite for 14 h. The neutralization process was subsequently performed with sodium hydroxide. The results showed that as much as 32.87 g of gum was removed during the degumming process. The picric acid tests verified that the adsorption using zeolite reduced the HCN contents, which indicates that the treated oil is safe to consume. The FFA test results showed that the final FFA content for each process was 7.23, 6.46, 6.21%, respectively. This study unfolds the potential of kesambi seed oil as future cooking oil by improving its quality that can satisfy the Indonesia National Standard.
{"title":"Pemurnian Minyak Biji Kesambi (Schleichera oleosa) sebagai Bahan Baku Pembuatan Minyak Goreng","authors":"F. Putri, Aditya Surya Pratama, Fasha El Sauzsa, Dwi Ardiana Setyawardhani","doi":"10.20961/equilibrium.v5i2.54249","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i2.54249","url":null,"abstract":"Kesambi seed oil (Schleichera oleosa) is one of the resources that can be utilized as an alternative to substitute palm oil in cooking oil production due to its lower moisture content, peroxide value, and saponification number. However, the high level of free fatty acid (FFA) and cyanide acid (HCN) contents in kesambi seed oil requires further purification prior to commercialization. In this study, the purification process of kesambi seed oil was carried out with degumming, adsorption, and neutralization techniques. The degumming process was conducted using phosphoric acid for 20 minutes. Afterwards, the adsorption process was carried out using 25% (w/w) zeolite for 14 h. The neutralization process was subsequently performed with sodium hydroxide. The results showed that as much as 32.87 g of gum was removed during the degumming process. The picric acid tests verified that the adsorption using zeolite reduced the HCN contents, which indicates that the treated oil is safe to consume. The FFA test results showed that the final FFA content for each process was 7.23, 6.46, 6.21%, respectively. This study unfolds the potential of kesambi seed oil as future cooking oil by improving its quality that can satisfy the Indonesia National Standard.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2022-01-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81090810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hydrothermal liquifaction is a biomass conversion process, where the structure of the biomass is convert into liquid components under super critical conditions with a high temperature. In this study, glucose is used as biomass. The purpose of this study was to study the reaction kinetics and determine the hydrothermal decomposition of glucose in NaOH solution. This experiment used 10 grams of glucose and dissolve it in 80 mL of NaOH solution then put it in an autoclave. Experiments were carried out by varying the heating temperature carried out in an autoclave with a magnetic stirrer. After heating at various temperatures, the autoclave is immediately cooled down. The processed material is filtered to separate insoluble solids from the liquid phase. The solid residue that has been separated from the liquid phase is then dried in an oven at 105°C for 24 hours. The composition of the filtrate was analyzed using the GC-MS method and the glucose concentration was analyzed using the Lane Eynon method. Prior to GC-MS analysis, the filtrate was distilled at atmospheric pressure until a solid residue remained. The sample analyzed is the result of distillation with a temperature above 100°C to ensure that there is no water and residual glucose in the sample. The results of GC-MS analysis of product samples from the hydrothermal decomposition process had 3 peaks. The first peak shows the compound 1,3 Dipalmitin which has an area of 14.74%, the second peak shows the Olealdehyde compound which has an area of 32.35%, and the third peak shows the 1,2-Epoxyhexadecane compound which has an area of 52.91%. The kinetics results in hydrothermal decomposition of glucose in this experiment obtained a reaction order of 2 with an activation energy (Ea) of 15.91 KJ / mol and a pre-exponential factor of 66.12.
{"title":"KINETIC STUDY ON HYDROTHERMAL COMPOSITION OF GLUCOSE IN NAOH SOLUTION WITH ZNO AS CATALYST","authors":"Bregas Siswahjono Tatag Sembodo, Addiva Febrioka, Adistya Hilga Pratiwi Aprilia","doi":"10.20961/equilibrium.v5i1.53407","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i1.53407","url":null,"abstract":"Hydrothermal liquifaction is a biomass conversion process, where the structure of the biomass is convert into liquid components under super critical conditions with a high temperature. In this study, glucose is used as biomass. The purpose of this study was to study the reaction kinetics and determine the hydrothermal decomposition of glucose in NaOH solution. This experiment used 10 grams of glucose and dissolve it in 80 mL of NaOH solution then put it in an autoclave. Experiments were carried out by varying the heating temperature carried out in an autoclave with a magnetic stirrer. After heating at various temperatures, the autoclave is immediately cooled down. The processed material is filtered to separate insoluble solids from the liquid phase. The solid residue that has been separated from the liquid phase is then dried in an oven at 105°C for 24 hours. The composition of the filtrate was analyzed using the GC-MS method and the glucose concentration was analyzed using the Lane Eynon method. Prior to GC-MS analysis, the filtrate was distilled at atmospheric pressure until a solid residue remained. The sample analyzed is the result of distillation with a temperature above 100°C to ensure that there is no water and residual glucose in the sample. The results of GC-MS analysis of product samples from the hydrothermal decomposition process had 3 peaks. The first peak shows the compound 1,3 Dipalmitin which has an area of 14.74%, the second peak shows the Olealdehyde compound which has an area of 32.35%, and the third peak shows the 1,2-Epoxyhexadecane compound which has an area of 52.91%. The kinetics results in hydrothermal decomposition of glucose in this experiment obtained a reaction order of 2 with an activation energy (Ea) of 15.91 KJ / mol and a pre-exponential factor of 66.12.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82357703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-09DOI: 10.20961/equilibrium.v5i1.54012
Yanuar Bekti Ramadhan, A. Sabrina, Endang Kwartiningsih
The heavy metal content is very dangerous because it can pollute the environment. One of the heavy metals waste commonly found in the textile industry is chromium (Cr). Mimosa pudica is a weed plant and its availability is very abundant. However, it also contains tannin which can be developed into tannin gel biosorbent to adsorption heavy metal content in the wastewater. The purpose of this research is to study Mimosa pudica tannin as a Cr biosorbent from textile wastewater. There are two steps to synthesis tannin gel biosorbent. They are the tannin extraction and the condensation polymerization process. Tannin is easily soluble in water so the condensation polymerization process is needed to make it insoluble in water. The extraction of Mimosa pudica tannin was done using water solvent. The condensation polymerization process was done by the reaction of tannin extract and formaldehyde. The Cr content of textile industry wastewater in the Pasar Kliwon, Surakarta was 4 ppm. The results of the biosorption of Cr heavy metal using Mimosa pudica tannin gel showed that the remaining Cr heavy metal was 0.7098 ppm. It was already below the threshold which was 1 ppm. Keywords: biosorption, condensation polymerization, extraction, Mimosa pudica, tannin gel
{"title":"Biosorption of Chromium from Textile Wastewater Using Mimosa pudica Tannin Gel","authors":"Yanuar Bekti Ramadhan, A. Sabrina, Endang Kwartiningsih","doi":"10.20961/equilibrium.v5i1.54012","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i1.54012","url":null,"abstract":"The heavy metal content is very dangerous because it can pollute the environment. One of the heavy metals waste commonly found in the textile industry is chromium (Cr). Mimosa pudica is a weed plant and its availability is very abundant. However, it also contains tannin which can be developed into tannin gel biosorbent to adsorption heavy metal content in the wastewater. The purpose of this research is to study Mimosa pudica tannin as a Cr biosorbent from textile wastewater. There are two steps to synthesis tannin gel biosorbent. They are the tannin extraction and the condensation polymerization process. Tannin is easily soluble in water so the condensation polymerization process is needed to make it insoluble in water. The extraction of Mimosa pudica tannin was done using water solvent. The condensation polymerization process was done by the reaction of tannin extract and formaldehyde. The Cr content of textile industry wastewater in the Pasar Kliwon, Surakarta was 4 ppm. The results of the biosorption of Cr heavy metal using Mimosa pudica tannin gel showed that the remaining Cr heavy metal was 0.7098 ppm. It was already below the threshold which was 1 ppm. Keywords: biosorption, condensation polymerization, extraction, Mimosa pudica, tannin gel","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73470820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-09DOI: 10.20961/equilibrium.v5i1.53229
M. Margono, Louise Louise, Laila Zulhijah Choirudina, Ameilia Ayu Safitri, Fawnia Hanifah
Diabetes mellitus is a top five deadly disease in Indonesia. A healthy diet with consuming low sugar index food is suggested to prevent diabetes mellitus. Rice as the main source of carbohydrate in Indonesia is categorized as food with a high glycemic index. This study is experimenting rice with a low glycemic index that suitable to be consumed by diabetes mellitus sufferer. Various extracts are used in the making of low glycemic index rice such as strobilanthes crispus, cinnamon, and muntingia calabura. The rice is marinated with 1% extract for 2 hours and continued to cook in an autoclave for 15 minutes with temperature 116°C. The rice then dried in an oven at 50°C for 24 hours before it cooked in a rice cooker and can be consumed. The result shows that strobilanthes crispus and cinnamon extract rice has lower glycemic index than common rice.
{"title":"Pengaruh Ekstrak Daun Kecibeling (Strobilanthes crispa), Kayu Manis (Cinnamon), dan Kersen (Muntingia calabura) Terhadap Indeks Glikemik pada Pengolahan Beras Metode Pratanak","authors":"M. Margono, Louise Louise, Laila Zulhijah Choirudina, Ameilia Ayu Safitri, Fawnia Hanifah","doi":"10.20961/equilibrium.v5i1.53229","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i1.53229","url":null,"abstract":"Diabetes mellitus is a top five deadly disease in Indonesia. A healthy diet with consuming low sugar index food is suggested to prevent diabetes mellitus. Rice as the main source of carbohydrate in Indonesia is categorized as food with a high glycemic index. This study is experimenting rice with a low glycemic index that suitable to be consumed by diabetes mellitus sufferer. Various extracts are used in the making of low glycemic index rice such as strobilanthes crispus, cinnamon, and muntingia calabura. The rice is marinated with 1% extract for 2 hours and continued to cook in an autoclave for 15 minutes with temperature 116°C. The rice then dried in an oven at 50°C for 24 hours before it cooked in a rice cooker and can be consumed. The result shows that strobilanthes crispus and cinnamon extract rice has lower glycemic index than common rice.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90748426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The textile industry in Indonesia is growing rapidly, this is confirmed by data from the Badan Pusat Statistik (BPS) which shows that the production of the clothing industry has experienced a significant growth of 15.29 percent in 2019. The use of textile dyes will cause waste problems in the environment. So we need natural dyes as a safer and environmentally friendly alternative. The purpose of this study was to obtain data analysis and to determine the adsorption equilibrium value of the natural dye solution of mangrove Rhizophora stylosa and tingi bark with variations in the amount of dyeing in primisima cloth by comparing it with the Langmuir and Freundlich equations and knowing the role of tunjung and alum in the process of fixing dyes into cloth. This study used a solid-liquid extraction method and then tested by spectrophotometry to obtain initial concentration data. Next, pour the dye that has been tested for its tannin content into a measuring cup and insert the cloth as a medium for mass transfer of tannins from liquid to solid. Samples were taken for each dyeing and tested for tannin content by spectrophotometry and the Ca value was obtained. Isotherm pattern testing. The adsorption test for the absorption process of tannins in natural dyes by cloth was carried out by calculating using the Langmuir and Freundlich equation. Furthermore, the cloth that has been dyed is fixed by tunjung and alum.The most suitable determination of the adsorption capacity of the cloth against natural dyes Rhizopora stylosa and tingi bark is by using the Freundlich adsorption equation compared to the Langmuir equation. This is evidenced by the error value of the Freundlich equation is smaller than the Langmuir equation by showing the value of R2 which is close to number 1. The constant value of the Langmuir equation tingi bark for three times of dyeing obtained the b value is 0.2338 mg/gr and the k value is 0.00517 L/gr. For five of dyeing, the b value is 0.10817 mg/gr and the k value is 0.00421 L/gr. For the seven times of dyeing, the b value is 0.0670 mg/gr and the k value is 0.003899 L/gr. Whereas in the Freundlich equation for tingi bark for three times of dyeing, the n value is 0.4312 mg/g and the k value is 0.36374 x 103 L/gr. For five of dyeing, the n value is 0.30114 mg/g and the k value is 0.99586 x 105 L/g. For seven of dyeing, the n value is 0.2424 mg/g and the k value is 0.9354 x 107 L/g. The constant value of the Langmuir Rhizopora stylosa equation for three times of dyeing, the b value is 0.15635 mg / gr and the k value is 0.005224 L/gr. For five of dyeing, the b value is 0.08141 mg/gr and the k value is 0.004415 L/gr. For the seven of dyeing, the b value is 0.04909 mg/gr and the k value is 0.00408 L/gr. Whereas in the Freundlich equation for Rhizopora stylosa for three times of dyeing, the n value is 0.3862 mg/g and the k value is 0.1090 x 104 L/g. For five of dyeing, the n value is 0.2733 mg/g and the k value is 0.4355 x 106 L/g. For seven o
{"title":"ADSORBSI ZAT WARNA ALAMI BUAH MANGROVE JENIS RHIZOPHORA STYLOSA DAN KULIT KAYU TINGI KE DALAM KAIN DENGAN PENGUNCI TUNJUNG DAN TAWAS","authors":"Paryanto Paryanto, Ayu Mustika Wijaya, D. Widodo, Sonia Waluya, Wahyu Daut Utomo","doi":"10.20961/equilibrium.v5i1.50359","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i1.50359","url":null,"abstract":"The textile industry in Indonesia is growing rapidly, this is confirmed by data from the Badan Pusat Statistik (BPS) which shows that the production of the clothing industry has experienced a significant growth of 15.29 percent in 2019. The use of textile dyes will cause waste problems in the environment. So we need natural dyes as a safer and environmentally friendly alternative. The purpose of this study was to obtain data analysis and to determine the adsorption equilibrium value of the natural dye solution of mangrove Rhizophora stylosa and tingi bark with variations in the amount of dyeing in primisima cloth by comparing it with the Langmuir and Freundlich equations and knowing the role of tunjung and alum in the process of fixing dyes into cloth. This study used a solid-liquid extraction method and then tested by spectrophotometry to obtain initial concentration data. Next, pour the dye that has been tested for its tannin content into a measuring cup and insert the cloth as a medium for mass transfer of tannins from liquid to solid. Samples were taken for each dyeing and tested for tannin content by spectrophotometry and the Ca value was obtained. Isotherm pattern testing. The adsorption test for the absorption process of tannins in natural dyes by cloth was carried out by calculating using the Langmuir and Freundlich equation. Furthermore, the cloth that has been dyed is fixed by tunjung and alum.The most suitable determination of the adsorption capacity of the cloth against natural dyes Rhizopora stylosa and tingi bark is by using the Freundlich adsorption equation compared to the Langmuir equation. This is evidenced by the error value of the Freundlich equation is smaller than the Langmuir equation by showing the value of R2 which is close to number 1. The constant value of the Langmuir equation tingi bark for three times of dyeing obtained the b value is 0.2338 mg/gr and the k value is 0.00517 L/gr. For five of dyeing, the b value is 0.10817 mg/gr and the k value is 0.00421 L/gr. For the seven times of dyeing, the b value is 0.0670 mg/gr and the k value is 0.003899 L/gr. Whereas in the Freundlich equation for tingi bark for three times of dyeing, the n value is 0.4312 mg/g and the k value is 0.36374 x 103 L/gr. For five of dyeing, the n value is 0.30114 mg/g and the k value is 0.99586 x 105 L/g. For seven of dyeing, the n value is 0.2424 mg/g and the k value is 0.9354 x 107 L/g. The constant value of the Langmuir Rhizopora stylosa equation for three times of dyeing, the b value is 0.15635 mg / gr and the k value is 0.005224 L/gr. For five of dyeing, the b value is 0.08141 mg/gr and the k value is 0.004415 L/gr. For the seven of dyeing, the b value is 0.04909 mg/gr and the k value is 0.00408 L/gr. Whereas in the Freundlich equation for Rhizopora stylosa for three times of dyeing, the n value is 0.3862 mg/g and the k value is 0.1090 x 104 L/g. For five of dyeing, the n value is 0.2733 mg/g and the k value is 0.4355 x 106 L/g. For seven o","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91531704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chromium is one of the hazardous heavy metal contained in the industrial wastewater. It can be reduced by various methods, such as adsorption. The purpose of this study was initialized an activated carbon from coconut fiber by various phosphoric acid (H3PO4) activator concentration (0,1M; 0,5M; 1M; 1,5M; 2M) and variation of contact time (30; 60; 90; 120; 150; 180 minutes) to obtain optimum adsorption capacity of chromium. Analysis of the activated coconut fiber carbon by SAA obtained a surface area of 53,39 m2/g. The potassium chromate (K2CrO4) solution was adsorbed by the adsorbent and then analyzed by a UV-VIS Spectrophotometer to measure the chromium content. This study proved that chromium adsorption by activated coconut fiber carbon was increased by the time until reaching optimum condition. Enhancement of adsorption capacity was directly proportional as the more concentrated phosphoric acid activator. Maximum adsorption capacity obtained was 3,464 mg/g and the optimum condition was at contact time of 150 minutes with the phosphoric acid activator concentration of 2M.
{"title":"Pengaruh Konsentrasi Aktivator Asam Fosfat (H3PO4) pada Pembuatan Karbon Aktif dari Sabut Kelapa terhadap Adsorpsi Logam Kromium","authors":"Hamida Ishmatu Sholikhah, Hartika Rahma Putri, Inayati Inayati","doi":"10.20961/equilibrium.v5i1.53572","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i1.53572","url":null,"abstract":"Chromium is one of the hazardous heavy metal contained in the industrial wastewater. It can be reduced by various methods, such as adsorption. The purpose of this study was initialized an activated carbon from coconut fiber by various phosphoric acid (H3PO4) activator concentration (0,1M; 0,5M; 1M; 1,5M; 2M) and variation of contact time (30; 60; 90; 120; 150; 180 minutes) to obtain optimum adsorption capacity of chromium. Analysis of the activated coconut fiber carbon by SAA obtained a surface area of 53,39 m2/g. The potassium chromate (K2CrO4) solution was adsorbed by the adsorbent and then analyzed by a UV-VIS Spectrophotometer to measure the chromium content. This study proved that chromium adsorption by activated coconut fiber carbon was increased by the time until reaching optimum condition. Enhancement of adsorption capacity was directly proportional as the more concentrated phosphoric acid activator. Maximum adsorption capacity obtained was 3,464 mg/g and the optimum condition was at contact time of 150 minutes with the phosphoric acid activator concentration of 2M.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78352080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2021-08-09DOI: 10.20961/equilibrium.v5i1.53965
T. Paramitha, E. Dyartanti, H. Widiyandari, A. Jumari, A. Nur, I. Inayati, A. W. Budiman, A. Purwanto
With the increasing development of the battery and electric vehicle industry, student's and teacher's understanding of lithium batteries and skills in assembling electric bikes are very important in competing for jobs in these fields. Educational activities regarding batteries and training on assembling electric bike are carried out at SMK Muhammadiyah 6 Karanganyar, because there were no facilities that support the learning and teaching process about electric vehicles and batteries. The method used in this training is lecture, discussion and practice method. The material presented was about the technology of making lithium batteries and electric bike components. While practical activities include the stages of converting conventional bikes into electric bikes with energy from lithium batteries. This activity shows that participants can understand batteries and can apply batteries to electric vehicles, especially electric bikes.
{"title":"Training of Electric Bike Assembly with Lithium Batteries at SMK Muhammadiyah 6 Karanganyar","authors":"T. Paramitha, E. Dyartanti, H. Widiyandari, A. Jumari, A. Nur, I. Inayati, A. W. Budiman, A. Purwanto","doi":"10.20961/equilibrium.v5i1.53965","DOIUrl":"https://doi.org/10.20961/equilibrium.v5i1.53965","url":null,"abstract":"With the increasing development of the battery and electric vehicle industry, student's and teacher's understanding of lithium batteries and skills in assembling electric bikes are very important in competing for jobs in these fields. Educational activities regarding batteries and training on assembling electric bike are carried out at SMK Muhammadiyah 6 Karanganyar, because there were no facilities that support the learning and teaching process about electric vehicles and batteries. The method used in this training is lecture, discussion and practice method. The material presented was about the technology of making lithium batteries and electric bike components. While practical activities include the stages of converting conventional bikes into electric bikes with energy from lithium batteries. This activity shows that participants can understand batteries and can apply batteries to electric vehicles, especially electric bikes.","PeriodicalId":11866,"journal":{"name":"Equilibrium Journal of Chemical Engineering","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2021-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78786829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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