Tuning multiple noncovalent interactions to form multicomponent photoactive electron donor−acceptor (EDA) complexes for driving chemical reactions presents significant challenges yet holds profound implications. Hantzsch ester (HE) is recognized as an exceptional EDA donor, while it typically forms binary EDA complexes requiring stoichiometric amounts. Ternary EDA complexes involving HE in catalytic EDA systems remain scarce. Herein, we developed a H‐bonding‐assisted catalytic ternary EDA complex strategy employing HE for the synthesis of diverse isoquinoline‐1,3(2H,4H)‐diones. This operationally simple, visible‐light‐mediated platform efficiently converted primary, secondary, and tertiary carboxylic acids‐derived NHP esters into structurally diverse alkylated isoquinoline‐1,3(2H,4H)‐diones.
{"title":"Catalytic Photoactive Ternary Electron Donor–Acceptor Complex Enabled Synthesis of Isoquinoline‐1,3(2H,4H)‐Diones","authors":"Qian–Qian Xu, Qing Li, Zong‐Bo Xie, Huo‐Yu Rao, Zhang‐Gao Le, Zhen–Zhen Xu, Zhi‐Qiang Zhu","doi":"10.1002/adsc.70207","DOIUrl":"https://doi.org/10.1002/adsc.70207","url":null,"abstract":"Tuning multiple noncovalent interactions to form multicomponent photoactive electron donor−acceptor (EDA) complexes for driving chemical reactions presents significant challenges yet holds profound implications. Hantzsch ester (HE) is recognized as an exceptional EDA donor, while it typically forms binary EDA complexes requiring stoichiometric amounts. Ternary EDA complexes involving HE in catalytic EDA systems remain scarce. Herein, we developed a H‐bonding‐assisted catalytic ternary EDA complex strategy employing HE for the synthesis of diverse isoquinoline‐1,3(2H,4H)‐diones. This operationally simple, visible‐light‐mediated platform efficiently converted primary, secondary, and tertiary carboxylic acids‐derived NHP esters into structurally diverse alkylated isoquinoline‐1,3(2H,4H)‐diones.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"1 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145455206","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zeinab Hosseinpour, Dirk Bockfeld, René Frank, Matthias Tamm
An anionic N ‐heterocyclic carbene ligand with a weakly coordinating borate entity in the backbone (WCA‐NHC) is employed in the preparation of zwitterionic zinc complexes. Among these, zinc hydride species [(WCA‐IDipp)ZnH] 2 and [(WCA‐IDipp)ZnH(THF) 2 ] (WCA = B(C 6 F 5 ) 3 , IDipp = 1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene) were obtained either as a dinuclear zinc complex with two bridging hydrides or as a monomeric complex with a single terminal hydride, respectively. In these zwitterionic complexes, the positive charge at zinc is compensated by the anionic carbene ligand WCA‐IDipp. The overall neutral complexes display excellent solubility in organic solvents and were demonstrated as efficient catalysts in hydrosilylation reactions of aldehydes and ketones.
{"title":"Zinc Hydride Complexes Stabilized by Anionic N ‐Heterocyclic Carbenes for Hydrosilylation of Aldehydes and Ketones","authors":"Zeinab Hosseinpour, Dirk Bockfeld, René Frank, Matthias Tamm","doi":"10.1002/adsc.70208","DOIUrl":"https://doi.org/10.1002/adsc.70208","url":null,"abstract":"An anionic <jats:italic>N</jats:italic> ‐heterocyclic carbene ligand with a weakly coordinating borate entity in the backbone (WCA‐NHC) is employed in the preparation of zwitterionic zinc complexes. Among these, zinc hydride species [(WCA‐IDipp)ZnH] <jats:sub>2</jats:sub> and [(WCA‐IDipp)ZnH(THF) <jats:sub>2</jats:sub> ] (WCA = B(C <jats:sub>6</jats:sub> F <jats:sub>5</jats:sub> ) <jats:sub>3</jats:sub> , IDipp = 1,3‐bis(2,6‐diisopropylphenyl)imidazolin‐2‐ylidene) were obtained either as a dinuclear zinc complex with two bridging hydrides or as a monomeric complex with a single terminal hydride, respectively. In these zwitterionic complexes, the positive charge at zinc is compensated by the anionic carbene ligand WCA‐IDipp. The overall neutral complexes display excellent solubility in organic solvents and were demonstrated as efficient catalysts in hydrosilylation reactions of aldehydes and ketones.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"10 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145455225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A triflic acid-mediated iodocarbocyclization of allylic and homoallylic sulfonamides with iodoarenes has been developed for the synthesis of benzo-fused saturated N-heterocycles. The combination of iodoarenes and triflic acid provides an efficient electrophilic iodine species for the iodocarbocyclization under ambient reaction conditions. A variety of sulfonamides derived from benzylamines, phenethylamines, and anilines were successfully transformed into the corresponding iodine-functionalized benzo-fused N-heterocycles in good to high yields.
{"title":"TfOH-Mediated Iodocarbocyclization of Alkenyl Sulfonamides with Iodoarenes","authors":"Kosuke Yamamoto, Izumi Nakayama, Kentaro Higa, Masami Kuriyama, Osamu Onomura","doi":"10.1002/adsc.70205","DOIUrl":"https://doi.org/10.1002/adsc.70205","url":null,"abstract":"A triflic acid-mediated iodocarbocyclization of allylic and homoallylic sulfonamides with iodoarenes has been developed for the synthesis of benzo-fused saturated N-heterocycles. The combination of iodoarenes and triflic acid provides an efficient electrophilic iodine species for the iodocarbocyclization under ambient reaction conditions. A variety of sulfonamides derived from benzylamines, phenethylamines, and anilines were successfully transformed into the corresponding iodine-functionalized benzo-fused N-heterocycles in good to high yields.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"26 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145455205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wangyu Li, Shiwen Zhou, He Tang, Fengjian Chu, Hongru Feng, Yuanjiang Pan
A convenient and efficient metal‐free protocol has been reported for formylation of various amines with carbon dioxide. This reaction can proceed under ambient conditions and show a broad substrate scope, encompassing primary amines, secondary amines, chiral amino acid esters, and bioactive molecules. Furthermore, this method offers several advantages, including the preservation of substrate chirality, ease of separation and purification, and the suitability of formic acid and formate salts as reactants in this reaction.
{"title":"A Mild Reductant N‐Heterocyclic‐Carbene‐Ligated Borane for N ‐Formylation of Amines with CO 2 under Ambient Conditions","authors":"Wangyu Li, Shiwen Zhou, He Tang, Fengjian Chu, Hongru Feng, Yuanjiang Pan","doi":"10.1002/adsc.70079","DOIUrl":"https://doi.org/10.1002/adsc.70079","url":null,"abstract":"A convenient and efficient metal‐free protocol has been reported for formylation of various amines with carbon dioxide. This reaction can proceed under ambient conditions and show a broad substrate scope, encompassing primary amines, secondary amines, chiral amino acid esters, and bioactive molecules. Furthermore, this method offers several advantages, including the preservation of substrate chirality, ease of separation and purification, and the suitability of formic acid and formate salts as reactants in this reaction.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"2 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145447912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alkenyl nitrile derivatives represent important structural motifs found in a variety of natural products, active pharmaceuticals, and functional materials. Over the past decade, significant progress has been made in the development of efficient and selective catalytic methods for synthesizing alkenyl nitriles from alkenes, alkynes, and other precursors under relatively mild conditions with new synthetic technologies. However, a comprehensive summary of the synthesis of alkenyl nitriles has yet to be established in recent literature. This perspective highlights the latest advancements in the synthesis of alkenyl nitriles through the cyanation of alkenes, alkynes, and other starting materials, leading to functionalized alkenyl nitrile derivatives. The remaining challenges and future perspectives at the conclusion of the review is also discussed. It is hoped that this overview will inspire the development of novel approaches to access diverse alkenyl nitriles and facilitate their applications in organic chemistry and drug research.
{"title":"Recent Strategies for the Synthesis of Alkenyl Nitriles Derivatives","authors":"Xingnuo Zhou, Qingcheng Feng, Hui Xu, Chao Shu","doi":"10.1002/adsc.70161","DOIUrl":"https://doi.org/10.1002/adsc.70161","url":null,"abstract":"Alkenyl nitrile derivatives represent important structural motifs found in a variety of natural products, active pharmaceuticals, and functional materials. Over the past decade, significant progress has been made in the development of efficient and selective catalytic methods for synthesizing alkenyl nitriles from alkenes, alkynes, and other precursors under relatively mild conditions with new synthetic technologies. However, a comprehensive summary of the synthesis of alkenyl nitriles has yet to be established in recent literature. This perspective highlights the latest advancements in the synthesis of alkenyl nitriles through the cyanation of alkenes, alkynes, and other starting materials, leading to functionalized alkenyl nitrile derivatives. The remaining challenges and future perspectives at the conclusion of the review is also discussed. It is hoped that this overview will inspire the development of novel approaches to access diverse alkenyl nitriles and facilitate their applications in organic chemistry and drug research.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"37 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145434523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chen‐Qi Zhu, Hua‐Tao Wu, Min Liu, Yi‐Li You, Yan‐Shu Luo, Ren‐Hao Li
An efficient method for the ionic hydrosulfonylation of alkenes lacking electron‐withdrawing groups has been developed. This transformation proceeds smoothly to afford benzyl sulfone products, featuring easy operation, a broad substrate scope, good atomic economy, the use of sodium sulfinates as a safe sulfone source, and water/alcohol as green solvents. Furthermore, our strategy enables the synthesis of tertiary carbon sulfone compounds.
{"title":"Ionic Hydrosulfonylation of Alkenes with Sodium Sulfinates for Highly Efficient Synthesis of Benzyl Sulfones","authors":"Chen‐Qi Zhu, Hua‐Tao Wu, Min Liu, Yi‐Li You, Yan‐Shu Luo, Ren‐Hao Li","doi":"10.1002/adsc.70199","DOIUrl":"https://doi.org/10.1002/adsc.70199","url":null,"abstract":"An efficient method for the ionic hydrosulfonylation of alkenes lacking electron‐withdrawing groups has been developed. This transformation proceeds smoothly to afford benzyl sulfone products, featuring easy operation, a broad substrate scope, good atomic economy, the use of sodium sulfinates as a safe sulfone source, and water/alcohol as green solvents. Furthermore, our strategy enables the synthesis of tertiary carbon sulfone compounds.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"1 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145434524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhicong Zhu, Xiaoyu Zhou, Wei Xiao, Gang Liu, Jie Wu
In the past 10 years, P ‐hydrido‐1,3,2‐diazaphospholenes (DAP‐Hs) have been demonstrated to be able to reduce carbonyls, imines, and enones. However, the 1,6‐conjugate reduction transformations catalyzed by DAP‐Hs have been rarely studied. Herein, we developed a DAP‐catalyzed 1,6‐conjugate reduction of p ‐QMs with DAP‐Br as the precatalyst. Furthermore, the dienone could also be well tolerated in this transformation.
{"title":"Diazaphospholene‐Catalyzed 1,6‐Conjugate Reduction of Para‐Quinone Methides","authors":"Zhicong Zhu, Xiaoyu Zhou, Wei Xiao, Gang Liu, Jie Wu","doi":"10.1002/adsc.70202","DOIUrl":"https://doi.org/10.1002/adsc.70202","url":null,"abstract":"In the past 10 years, <jats:italic>P</jats:italic> ‐hydrido‐1,3,2‐diazaphospholenes (DAP‐Hs) have been demonstrated to be able to reduce carbonyls, imines, and enones. However, the 1,6‐conjugate reduction transformations catalyzed by DAP‐Hs have been rarely studied. Herein, we developed a DAP‐catalyzed 1,6‐conjugate reduction of <jats:italic>p</jats:italic> ‐QMs with DAP‐Br as the precatalyst. Furthermore, the dienone could also be well tolerated in this transformation.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"22 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145434525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this work, we report a novel approach for synthesizing P‐chiral phosphines through Mn(I)‐catalyzed enantioselective hydrophosphination of vinyl sulfones. A distinctive feature of this system is its solvent‐dependent stereoinversion, which enables the formation of products with opposite configurations using the same catalyst enantiomer. This phenomenon has been demonstrated across a range of vinyl sulfones and diarylphosphines, providing access to both configurations of P‐stereogenic phosphines with a single catalytic system.
{"title":"P‐Stereogenic Phosphines via Mn(I)‐Catalyzed Asymmetric Hydrophosphination of Vinyl Sulfones: A Case of Solvent‐Induced Stereoinversion","authors":"Bin Wan, Syuzanna R. Harutyunyan","doi":"10.1002/adsc.70198","DOIUrl":"https://doi.org/10.1002/adsc.70198","url":null,"abstract":"In this work, we report a novel approach for synthesizing P‐chiral phosphines through Mn(I)‐catalyzed enantioselective hydrophosphination of vinyl sulfones. A distinctive feature of this system is its solvent‐dependent stereoinversion, which enables the formation of products with opposite configurations using the same catalyst enantiomer. This phenomenon has been demonstrated across a range of vinyl sulfones and diarylphosphines, providing access to both configurations of P‐stereogenic phosphines with a single catalytic system.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"1 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145434527","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhen Fan, Hao Zhang, Mei Li, Enai Dai, Tianxin Zhang, Houping Xia, Jiandong Pang
A core challenge in photocatalytic water splitting for hydrogen production, as a clean method of hydrogen fuel generation, lies in simultaneously achieving efficient hydrogen production and long‐term stability of catalysts. Herein, we report the successful synthesis of a novel bimetallic cluster‐based metal‐organic framework (MOF) exhibiting exceptional performance for visible‐light‐driven photocatalytic hydrogen production. This unique MOF catalyst demonstrates a remarkably high hydrogen evolution rate of 20,778.7 μmol g −1 h −1 under visible‐light irradiation, significantly surpassing many MOF photocatalysts. Crucially, the MOF exhibits outstanding stability, maintaining its high catalytic activity over multiple reaction cycles without significant degradation. The synergistic effects within the bimetallic clusters and sensitively light‐responsive linkers are regarded as the key contributors to both the enhanced efficiency and remarkable durability. This work presents a highly promising and stable MOF photocatalyst for efficient solar energy harnessing towards clean hydrogen fuel generation.
{"title":"Bimetallic Cluster Metal‐Organic Frameworks for Rapid Photocatalytic Water Splitting to Produce Hydrogen","authors":"Zhen Fan, Hao Zhang, Mei Li, Enai Dai, Tianxin Zhang, Houping Xia, Jiandong Pang","doi":"10.1002/adsc.70203","DOIUrl":"https://doi.org/10.1002/adsc.70203","url":null,"abstract":"A core challenge in photocatalytic water splitting for hydrogen production, as a clean method of hydrogen fuel generation, lies in simultaneously achieving efficient hydrogen production and long‐term stability of catalysts. Herein, we report the successful synthesis of a novel bimetallic cluster‐based metal‐organic framework (MOF) exhibiting exceptional performance for visible‐light‐driven photocatalytic hydrogen production. This unique MOF catalyst demonstrates a remarkably high hydrogen evolution rate of 20,778.7 μmol g <jats:sup>−1 </jats:sup> h <jats:sup>−1</jats:sup> under visible‐light irradiation, significantly surpassing many MOF photocatalysts. Crucially, the MOF exhibits outstanding stability, maintaining its high catalytic activity over multiple reaction cycles without significant degradation. The synergistic effects within the bimetallic clusters and sensitively light‐responsive linkers are regarded as the key contributors to both the enhanced efficiency and remarkable durability. This work presents a highly promising and stable MOF photocatalyst for efficient solar energy harnessing towards clean hydrogen fuel generation.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"1 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145434526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Development of environmentally benign methods for CP bond formation is of great significance due to the extensive applications of organophosphorus compounds in pharmaceuticals and agrochemicals. Herein, we report a polyoxovanadate‐based Cu–organic framework, [Cu 3 (pty) 2 ][V 8 O 23 ]·H 2 O ( Cu‐POV , pty = 4′‐(pyridin‐4‐yl)‐2,2′:6′,2″‐terpyridine), for catalyzing the cross‐dehydrogenative coupling of N‐aryl tetrahydroisoquinolines with diarylphosphine oxides to form CP bonds using molecular oxygen (O 2 ) as an oxidant in green ethanol medium. The outstanding efficiency of Cu‐POV stems from a synergistic mechanism involving its structural Cu II and V V centers: the two activate the N‐aryl tetrahydroisoquinolines through single‐electron transfer and subsequently react with O 2 to generate the key superoxide radical species. The catalyst can be recycled at least six times without compromising performance, and applied in gram‐scale reaction with a turnover number of 2025.
{"title":"Eco‐Friendly and Additive‐Free Synthesis of CP Bonds: Synergistic Catalysis by a Polyoxovanadate‐Based Cu–Organic Framework Using Molecular Oxygen","authors":"Longchen Xie, Hongrui Tian, Yuqing Wang, Yanfeng Bi, Baokuan Chen","doi":"10.1002/adsc.70206","DOIUrl":"https://doi.org/10.1002/adsc.70206","url":null,"abstract":"Development of environmentally benign methods for CP bond formation is of great significance due to the extensive applications of organophosphorus compounds in pharmaceuticals and agrochemicals. Herein, we report a polyoxovanadate‐based Cu–organic framework, [Cu <jats:sub>3</jats:sub> (pty) <jats:sub>2</jats:sub> ][V <jats:sub>8</jats:sub> O <jats:sub>23</jats:sub> ]·H <jats:sub>2</jats:sub> O ( Cu‐POV , pty = 4′‐(pyridin‐4‐yl)‐2,2′:6′,2″‐terpyridine), for catalyzing the cross‐dehydrogenative coupling of N‐aryl tetrahydroisoquinolines with diarylphosphine oxides to form CP bonds using molecular oxygen (O <jats:sub>2</jats:sub> ) as an oxidant in green ethanol medium. The outstanding efficiency of Cu‐POV stems from a synergistic mechanism involving its structural Cu <jats:sup>II</jats:sup> and V <jats:sup>V</jats:sup> centers: the two activate the N‐aryl tetrahydroisoquinolines through single‐electron transfer and subsequently react with O <jats:sub>2</jats:sub> to generate the key superoxide radical species. The catalyst can be recycled at least six times without compromising performance, and applied in gram‐scale reaction with a turnover number of 2025.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"78 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145427395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
京公网安备 11010802042870号
京ICP备2023020795号-1
扫码关注我们
求助内容：
应助结果提醒方式：