Herein, we present a Co(III)‐catalyzed regioselective C7‐H dienylation of indolines at room temperature employing allenyl carbinol acetate as an efficient dienylating reagent. The reaction proceeds via C‐H activation, regioselective 2,1‐migratory insertion of the allene followed by β‐acetate elimination, resulting in a diverse array of C7‐dienylated indolines. The methodology was further extended to C2‐H dienylation of indoles, affording either branched or linear dienes, contingent on the nature of the substituent present at the allenylic carbon. In addition, hydroarylation of allenes was also successfully achieved with tri‐substituted allenes, which was elusive so far under cobalt catalysis.
{"title":"Co(III)‐Catalyzed Regioselective C‐H Dienylation of Indolines and Indoles with Allenyl Carbinol Acetates","authors":"Chandra Mouleeswara Rao Volla, Rahul Shukla, Anurag Singh, Rakesh Shetty","doi":"10.1002/adsc.202401400","DOIUrl":"https://doi.org/10.1002/adsc.202401400","url":null,"abstract":"Herein, we present a Co(III)‐catalyzed regioselective C7‐H dienylation of indolines at room temperature employing allenyl carbinol acetate as an efficient dienylating reagent. The reaction proceeds via C‐H activation, regioselective 2,1‐migratory insertion of the allene followed by β‐acetate elimination, resulting in a diverse array of C7‐dienylated indolines. The methodology was further extended to C2‐H dienylation of indoles, affording either branched or linear dienes, contingent on the nature of the substituent present at the allenylic carbon. In addition, hydroarylation of allenes was also successfully achieved with tri‐substituted allenes, which was elusive so far under cobalt catalysis.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"38 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ganesh Pawar, Indrajeet Barve, Li-Ching Shen, Chung-Ming SUN
A base‐mediated one‐pot, two‐step, four‐component reaction has been developed to synthesize imidazole‐4(2H)‐ones, utilizing commercially available amino acid esters, aldehydes, alkynes, and amino alcohols. Control experiments and isolation of the intermediate revealed the mechanistic details. This four‐component reaction proceeds via imine formation, followed by the nucleophilic addition of alkyne to form a propargylamine precursor. Subsequently, the propargylamine precursor undergoes base‐mediated conversion into 1‐azadiene, followed by in situ ketene formation to generate (allyl‐dene‐amino)prop‐1‐en‐1‐one. The nucleophilic addition of amino alcohol and subsequent intramolecular cyclization provides imidazole‐4 (2H)‐ones exclusively.
{"title":"Base‐Mediated Four‐Component Intramolecular Cyclization reaction: One‐pot Access to Imidazole‐4‐(2H)‐ones","authors":"Ganesh Pawar, Indrajeet Barve, Li-Ching Shen, Chung-Ming SUN","doi":"10.1002/adsc.202401433","DOIUrl":"https://doi.org/10.1002/adsc.202401433","url":null,"abstract":"A base‐mediated one‐pot, two‐step, four‐component reaction has been developed to synthesize imidazole‐4(2H)‐ones, utilizing commercially available amino acid esters, aldehydes, alkynes, and amino alcohols. Control experiments and isolation of the intermediate revealed the mechanistic details. This four‐component reaction proceeds via imine formation, followed by the nucleophilic addition of alkyne to form a propargylamine precursor. Subsequently, the propargylamine precursor undergoes base‐mediated conversion into 1‐azadiene, followed by in situ ketene formation to generate (allyl‐dene‐amino)prop‐1‐en‐1‐one. The nucleophilic addition of amino alcohol and subsequent intramolecular cyclization provides imidazole‐4 (2H)‐ones exclusively.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"12 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xueqin Chen, Xiaoqing Wen, Yang Fu, Yingtian Liu, Rui Tan, Jiahong Li
A method has been developed for the synthesis of symmetrical and unsymmetrical aryl 1, 2‐diketones at room temperature, without the need for transition metals or photocatalysts. This protocol employs aromatic terminal alkynes or alkenes to react with aryl iodides under conditions involving formate, air, and DMSO. Mechanistic studies indicate that formate, air, and DMSO are all necessary conditions, and that the highly reactive carbon dioxide radical anion (CO2•−) generated under these conditions plays a key role in the reaction.
{"title":"Visible‐Light‐Promoted Photocatalyst‐Free Unsymmetrical Synthesis of Diaryl 1, 2‐Diketones from Terminal Alkynes/ Alkenes and Aryl Halides under the Formate‐Air‐DMSO Condition","authors":"Xueqin Chen, Xiaoqing Wen, Yang Fu, Yingtian Liu, Rui Tan, Jiahong Li","doi":"10.1002/adsc.202401310","DOIUrl":"https://doi.org/10.1002/adsc.202401310","url":null,"abstract":"A method has been developed for the synthesis of symmetrical and unsymmetrical aryl 1, 2‐diketones at room temperature, without the need for transition metals or photocatalysts. This protocol employs aromatic terminal alkynes or alkenes to react with aryl iodides under conditions involving formate, air, and DMSO. Mechanistic studies indicate that formate, air, and DMSO are all necessary conditions, and that the highly reactive carbon dioxide radical anion (CO2•−) generated under these conditions plays a key role in the reaction.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"74 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anjali Dahiya, Kalyan Dhara, Jordan GARO, Julien Gicquiaud, Alexandre Karnat, Murielle Berlande, Philippe Hermange, Jean-Marc Sotiropoulos, Patrick Toullec
A chiral Brønsted acid‐catalyzed synthesis of axially chiral alkenes was developed via an enantioselective and para‐selective Friedel–Crafts reaction between phenols and 1‐alkynylnaphth‐2‐ols. This methodology features an efficient hydroarylation with high functional group tolerance, complete para‐selectivity, excellent yields (up to 99%), and enantioselectivities (up to 94% ee) in the presence of a N‐triflylphosphoramide catalyst. DFT calculations were performed to investigate para‐selectivity and results indicate that both kinetics and thermodynamics parameters are more favorable compared to ortho‐selectivity.
{"title":"Brønsted Acid‐Catalyzed Enantioselective and para‐Selective Addition of Phenols to 1‐Alkynylnaphth‐2‐ols","authors":"Anjali Dahiya, Kalyan Dhara, Jordan GARO, Julien Gicquiaud, Alexandre Karnat, Murielle Berlande, Philippe Hermange, Jean-Marc Sotiropoulos, Patrick Toullec","doi":"10.1002/adsc.202401457","DOIUrl":"https://doi.org/10.1002/adsc.202401457","url":null,"abstract":"A chiral Brønsted acid‐catalyzed synthesis of axially chiral alkenes was developed via an enantioselective and para‐selective Friedel–Crafts reaction between phenols and 1‐alkynylnaphth‐2‐ols. This methodology features an efficient hydroarylation with high functional group tolerance, complete para‐selectivity, excellent yields (up to 99%), and enantioselectivities (up to 94% ee) in the presence of a N‐triflylphosphoramide catalyst. DFT calculations were performed to investigate para‐selectivity and results indicate that both kinetics and thermodynamics parameters are more favorable compared to ortho‐selectivity.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"81 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992654","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Qi Wu, Fang Zhang, Qichao Zhang, Lin He, Jichang Liu, Guang-Fen Du
Imidazolium-dithiocarboxylate zwitterions (NHC•CS2), a novel organocatalyst that derived from N-heterocyclic carbene (NHC), was used to activate cyclopropenones. Under the catalysis of 10 mol% NHC•CS2, a range of phenols, alcohols, primary and secondary amines react with cyclopropenones to produce trisubstituted α, β-unsaturated esters and amides in 46-95% yield. More than 68 products, including 7 natural product derivatives have been synthesized through this method. Mechanism study showed NHC•CS2 act as a Lewis base to activate the C=C double bond of cyclopropenones and trigger the ring-opening reaction. HRMS analysis indicated the formation of the key adduct of NHC•CS2 and cyclopropenone. More importantly, this study demonstrated completely different catalytic activity of NHC•CS2 and NHC catalysts, the latter one cannot catalyse these reactions.
{"title":"Imidazolium-dithiocarboxylate zwitterions catalysed ring-opening additions of cyclopropenones","authors":"Qi Wu, Fang Zhang, Qichao Zhang, Lin He, Jichang Liu, Guang-Fen Du","doi":"10.1002/adsc.202401476","DOIUrl":"https://doi.org/10.1002/adsc.202401476","url":null,"abstract":"Imidazolium-dithiocarboxylate zwitterions (NHC•CS2), a novel organocatalyst that derived from N-heterocyclic carbene (NHC), was used to activate cyclopropenones. Under the catalysis of 10 mol% NHC•CS2, a range of phenols, alcohols, primary and secondary amines react with cyclopropenones to produce trisubstituted α, β-unsaturated esters and amides in 46-95% yield. More than 68 products, including 7 natural product derivatives have been synthesized through this method. Mechanism study showed NHC•CS2 act as a Lewis base to activate the C=C double bond of cyclopropenones and trigger the ring-opening reaction. HRMS analysis indicated the formation of the key adduct of NHC•CS2 and cyclopropenone. More importantly, this study demonstrated completely different catalytic activity of NHC•CS2 and NHC catalysts, the latter one cannot catalyse these reactions.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"7 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kai Matsui, Kohei Toh, Tatsuhiro Sakamoto, Manabu Hatano, Kazuaki Ishihara
The latest insights into multiply selective Diels–Alder (DA) reactions is presented, where a chiral‐cavity‐structured Lewis‐acidic boron catalyst is employed. The catalyst ((R)‐1) is capable of recognizing both dienes and dienophiles, primarily due to the influence of the suitable steric factors of its cavity. By taking advantage of the structural and exo‐product‐inducing properties of (R)‐1, even in the presence of a mixture of inseparable dienes, the target products were successfully obtained in high yield with high enantioselectivity. As (R)‐1 exhibited the capacity to differentiate between three‐dimensional isomeric transition‐state structures in DA reactions, this work contributes to the advancement of artificial enzyme‐like catalysis, which has so far remained elusive.
{"title":"The Latest Insights into Multiply Selective Diels–Alder Reactions Using a Chiral‐Cavity‐Structured Lewis‐Acidic Boron Catalyst","authors":"Kai Matsui, Kohei Toh, Tatsuhiro Sakamoto, Manabu Hatano, Kazuaki Ishihara","doi":"10.1002/adsc.202401560","DOIUrl":"https://doi.org/10.1002/adsc.202401560","url":null,"abstract":"The latest insights into multiply selective Diels–Alder (DA) reactions is presented, where a chiral‐cavity‐structured Lewis‐acidic boron catalyst is employed. The catalyst ((R)‐1) is capable of recognizing both dienes and dienophiles, primarily due to the influence of the suitable steric factors of its cavity. By taking advantage of the structural and exo‐product‐inducing properties of (R)‐1, even in the presence of a mixture of inseparable dienes, the target products were successfully obtained in high yield with high enantioselectivity. As (R)‐1 exhibited the capacity to differentiate between three‐dimensional isomeric transition‐state structures in DA reactions, this work contributes to the advancement of artificial enzyme‐like catalysis, which has so far remained elusive.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"14 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992366","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nikola Petrovic, Gabriele Laudadio, Chase A. Salazar, Caleb J. Kong, Jenson Verghese, Alexander Hesketh, Giselle P. Reyes, Jean-Nicolas Desrosiers, C. Oliver Kappe, David Cantillo
A scalable electrochemical procedure for the synthesis of carboxylic acids from organic halides has been developed using a spinning cylinder electrode electrochemical reactor. The electrochemical process is based on the reductive dehalogenation of the starting material followed by trapping of the resulting carbanion with CO2. The protocol is compatible both with organic chlorides and bromides and uses inexpensive graphite and stainless steel as electrode materials. As sacrificial metal anodes are avoided, the method can be readily scaled up in flow mode. The procedure is compatible with a wide range of substrates (24 examples), including aryl and alkyl halides as well as heterocyclic compounds. Multigram scale preparations in flow mode have been demonstrated by processing 600 mL of reaction mixture in an electrolyte recirculation setup.
{"title":"Scalable Electrochemical Dehalogenative Carboxylation without a Sacrificial Metal Anode","authors":"Nikola Petrovic, Gabriele Laudadio, Chase A. Salazar, Caleb J. Kong, Jenson Verghese, Alexander Hesketh, Giselle P. Reyes, Jean-Nicolas Desrosiers, C. Oliver Kappe, David Cantillo","doi":"10.1002/adsc.202401538","DOIUrl":"https://doi.org/10.1002/adsc.202401538","url":null,"abstract":"A scalable electrochemical procedure for the synthesis of carboxylic acids from organic halides has been developed using a spinning cylinder electrode electrochemical reactor. The electrochemical process is based on the reductive dehalogenation of the starting material followed by trapping of the resulting carbanion with CO2. The protocol is compatible both with organic chlorides and bromides and uses inexpensive graphite and stainless steel as electrode materials. As sacrificial metal anodes are avoided, the method can be readily scaled up in flow mode. The procedure is compatible with a wide range of substrates (24 examples), including aryl and alkyl halides as well as heterocyclic compounds. Multigram scale preparations in flow mode have been demonstrated by processing 600 mL of reaction mixture in an electrolyte recirculation setup.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"24 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Raquel Hernández-Ruiz, Marta Solas, Samuel Suárez-Pantiga, María R. Pedrosa, Roberto Sanz
A molybdenum‐catalyzed deoxygenation of sulfoxides, pyridine and quinoline N‐oxides, N‐hydroxybenzotriazoles, as well as the reduction of nitroarenes to anilines, has been developed using monocyclic terpenes such as γ‐terpinene as an environmentally benign hydrogen surrogate. The only byproducts generated are water and p‐cymene, under neat reaction conditions in which the terpene acts as both solvent and reducing agent. These features make this approach a highly attractive and sustainable alternative for the reduction of S−O and N−O containing compounds. Additionally, the reaction exhibited excellent chemoselectivity, tolerating a wide variety of functional groups.
{"title":"γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N‐Oxides and Nitroarenes","authors":"Raquel Hernández-Ruiz, Marta Solas, Samuel Suárez-Pantiga, María R. Pedrosa, Roberto Sanz","doi":"10.1002/adsc.202401387","DOIUrl":"https://doi.org/10.1002/adsc.202401387","url":null,"abstract":"A molybdenum‐catalyzed deoxygenation of sulfoxides, pyridine and quinoline N‐oxides, N‐hydroxybenzotriazoles, as well as the reduction of nitroarenes to anilines, has been developed using monocyclic terpenes such as γ‐terpinene as an environmentally benign hydrogen surrogate. The only byproducts generated are water and p‐cymene, under neat reaction conditions in which the terpene acts as both solvent and reducing agent. These features make this approach a highly attractive and sustainable alternative for the reduction of S−O and N−O containing compounds. Additionally, the reaction exhibited excellent chemoselectivity, tolerating a wide variety of functional groups.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"137 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142992655","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
2-deoxyglycosides are prominent constituents of diverse naturally occurring glycans and are known to participate in crucial biological pathways. We herein demonstrate NFSI-TEMPO as an efficient organocatalyst for the formation of 2-deoxy-α-glycosides from glycals. For the first time a catalytic behaviour of NFSI-TEMPO combination has been observed. The reaction conditions have been found suitable for the generation of glycosides from commercial alcohols, amino acid, sterol, phenols and monosaccharide derived alcohols. Broad range of protecting groups on both glycal and glycosyl acceptors as well as alcohols of varied reactivity were found to be compatible for the generation of 2-deoxy-α-glycosides in moderate to good yields. The synthetic potential of the newly established transformation was illustrated by application in trisaccharide synthesis and gram-scale reaction.
{"title":"NFSI-TEMPO Catalysed Stereoselective Synthesis of 2-Deoxyglycosides from Glycals","authors":"Vivek Kumar Sharma, Rima Thakur","doi":"10.1002/adsc.202401450","DOIUrl":"https://doi.org/10.1002/adsc.202401450","url":null,"abstract":"2-deoxyglycosides are prominent constituents of diverse naturally occurring glycans and are known to participate in crucial biological pathways. We herein demonstrate NFSI-TEMPO as an efficient organocatalyst for the formation of 2-deoxy-α-glycosides from glycals. For the first time a catalytic behaviour of NFSI-TEMPO combination has been observed. The reaction conditions have been found suitable for the generation of glycosides from commercial alcohols, amino acid, sterol, phenols and monosaccharide derived alcohols. Broad range of protecting groups on both glycal and glycosyl acceptors as well as alcohols of varied reactivity were found to be compatible for the generation of 2-deoxy-α-glycosides in moderate to good yields. The synthetic potential of the newly established transformation was illustrated by application in trisaccharide synthesis and gram-scale reaction.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"9 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142991172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Regio- and stereoselective β-C(sp3)‒H bond functionalizations of saturated nitrogen heterocycles, amines/amides are challenging and have emerged as an important topic of research in the area of C(sp3)‒H activation. Herein, we have summarized various β-C(sp3)‒H activation/functionalization methods; this review provides an overview of various trending approaches for β-C(sp3)‒H bond activation/functionalization of saturated nitrogen heterocycles, amines/amides. The regio- and stereoselective β-C(sp3)‒H bond activation methods are classified based on the reaction pathways. The literature methods including directing group or ligand-assisted reactions, reactions proceeding through enamine intermediate, redox-neutral methods and other trending methods including photoredox and transitional metal-free methods are discussed with recent updates.
{"title":"Regio- and Stereoselective β-C(sp3)‒H Activation/ Functionalization of Saturated Nitrogen Heterocycles, Amines and Amides","authors":"Sanjay Yadav, Murugesh V, Surisetti Suresh","doi":"10.1002/adsc.202401398","DOIUrl":"https://doi.org/10.1002/adsc.202401398","url":null,"abstract":"Regio- and stereoselective β-C(sp3)‒H bond functionalizations of saturated nitrogen heterocycles, amines/amides are challenging and have emerged as an important topic of research in the area of C(sp3)‒H activation. Herein, we have summarized various β-C(sp3)‒H activation/functionalization methods; this review provides an overview of various trending approaches for β-C(sp3)‒H bond activation/functionalization of saturated nitrogen heterocycles, amines/amides. The regio- and stereoselective β-C(sp3)‒H bond activation methods are classified based on the reaction pathways. The literature methods including directing group or ligand-assisted reactions, reactions proceeding through enamine intermediate, redox-neutral methods and other trending methods including photoredox and transitional metal-free methods are discussed with recent updates.","PeriodicalId":118,"journal":{"name":"Advanced Synthesis & Catalysis","volume":"6 1","pages":""},"PeriodicalIF":5.4,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142991421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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