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SMST 2022: Extended Abstracts from the International Conference on Shape Memory and Superelastic Technologies最新文献

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Effect of Flash Annealing on the Microstructure and Fatigue Life of a Ni-rich NiTi-20 at.% Hf High Temperature Shape Memory Alloy 闪蒸退火对富镍NiTi-20合金组织和疲劳寿命的影响。高温形状记忆合金
Faith Gantz, Michael T Wall, M. L. Young, D. Forbes
Typical processing techniques involve thermo-mechanically treating the material such as cold working and subsequent annealing to control grain and precipitate size, shape, orientation, and morphology. Shape memory alloy (SMA) mechanical properties rely heavily on microstructural features such as precipitates and grain size to extend fatigue life. Novel approaches to control microstructural features have used laser anneal on amorphous NiTi thin films to recrystallize grains and short-time annealing on NiTi after angular extrusion and cold-drawn fine wires. A recent study examined rapid thermal annealing (RTA) on Ni-lean NiTi- 10 at.% Hf wires as an effective method for controlling grain size and extending actuation fatigue; however, flash annealing or RTA on Ni-rich NiTiHf high-temperature SMA (HTMSA) wires has not been investigated. Based on a larger study, Ni-rich NiTi-20 at.% Hf HTSMA was down-selected for further processing. This study investigates the effect of flash annealing on the thermo-mechanical properties of a Ni-rich Ni50.3Ti29.7Hf20 HTSMA. Microstructural changes were examined using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). Actuation fatigue properties were also evaluated at 300 MPa. The results indicate that flash annealing HTSMA wires is an effective method for controlling grain size and extending fatigue life. The heating rate and time held are crucial parameters to control microstructural features such as grain size and coherency.
典型的加工技术包括对材料进行热机械处理,如冷加工和随后的退火,以控制晶粒和析出物的大小、形状、取向和形态。形状记忆合金(SMA)的力学性能在很大程度上依赖于微观组织特征,如析出物和晶粒尺寸,以延长疲劳寿命。非晶态NiTi薄膜的激光退火使晶粒再结晶,以及角挤压和冷拔细丝后的NiTi短时间退火是控制微观组织特征的新方法。最近的一项研究对Ni-lean NiTi- 10 at的快速热退火(RTA)进行了研究。% Hf焊丝作为控制晶粒尺寸和延长驱动疲劳的有效方法;然而,对富ni - NiTiHf高温SMA (HTMSA)丝的闪蒸退火或RTA尚未进行研究。根据一项更大的研究,富含镍的NiTi-20在。选择% Hf HTSMA进行进一步处理。研究了闪蒸退火对富镍Ni50.3Ti29.7Hf20 HTSMA热力学性能的影响。采用扫描电子显微镜(SEM)、能谱仪(EDS)和透射电子显微镜(TEM)观察其微观结构变化。在300 MPa下,还评估了驱动疲劳性能。结果表明,闪蒸退火是一种控制晶粒尺寸、延长疲劳寿命的有效方法。加热速率和时间是控制晶粒尺寸和相干性等微观结构特征的关键参数。
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引用次数: 0
Improving Elastocaloric Cooling Performance by Applying Novel Thermodynamic Cycle 应用新型热力循环改善弹热冷却性能
Parham Kabirifar, Jonas Trojer, M. Brojan, J. Tušek
Shape memory alloys such as NiTi can be used as recyclable, nontoxic, nonflammable, and environmentally friendly solid refrigerants in elastocaloric cooling/heat-pumping. Thin wires under tension and thin- walled tubes under compression that allow for fast and efficient heat transfer are excellent candidates to be applied in elastocaloric devices and were therefore selected for this study. Multiple thermodynamic cycles were studied with an emphasis on the parameters of the holding period of the cycle (essential for heat transfer between the elastocaloric material and the heat sink/source). The results reveal that the applied thermodynamic cycle significantly affects the thermomechanical response and thus the cooling/heating efficiency of the shape memory material.
形状记忆合金(如NiTi)可作为可回收、无毒、不易燃、环保的固体制冷剂用于弹性热冷却/热泵。在拉伸下的细导线和在压缩下的薄壁管允许快速有效的热传递,是应用于弹性热器件的优秀候选人,因此被选择用于本研究。研究了多个热力学循环,重点是循环保持周期的参数(对于弹性材料和散热器/热源之间的热传递至关重要)。结果表明,施加的热力学循环显著影响形状记忆材料的热力学响应,从而影响其冷却/加热效率。
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引用次数: 0
Internal Liquid Metal Channels to Enable High Power Additively Manufactured SMA Actuators 内部液态金属通道实现高功率增材制造SMA致动器
Jacob Mingear, Brady K. Allen, Jessica J. Zamarripa, D. Hartl
Shape memory alloys are capable of producing some of the highest actuation stresses (~300 MPa) of any active material. However, large monolithic SMA actuators, which can induce the tremendous forces required in some applications, are currently limited to low cyclic actuation frequencies due to their associated high thermal masses coupled with innate low thermal diffusivities of the material. An increase in the effective thermal diffusivity of an SMA actuator system will result in an increase in actuation frequency; accordingly, this would lead to the ability to perform more cycles over a given time interval and subsequently yield an overall higher actuator power density (energy density with time). This current work presents ongoing research in the design, manufacturing, enabling surface engineering (such as chemical etching and anodization), and testing of internal channel additively manufactured SMA actuator designs, including a tensile bar variation and planned testing of an optimized cantilever beam.
形状记忆合金能够产生任何活性材料中最高的一些驱动应力(~ 300mpa)。然而,大型单片SMA致动器在某些应用中可以产生所需的巨大力,由于其相关的高热质量加上材料固有的低热扩散率,目前仅限于低循环致动频率。SMA致动器系统有效热扩散系数的增加会导致致动频率的增加;因此,这将导致能够在给定的时间间隔内执行更多的循环,随后产生更高的执行器功率密度(随时间的能量密度)。目前的工作展示了正在进行的设计、制造、表面工程(如化学蚀刻和阳极氧化)和内部通道增材制造SMA致动器设计测试方面的研究,包括拉伸杆的变化和优化悬臂梁的计划测试。
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引用次数: 1
Features of Deformation of Thin Superelastic TiNi Wire 超弹性TiNi细丝的变形特征
E. Marchenko, G. Baigonakova, S. Gunther, O. Mamazakirov
TiNi-based wire is widely used in the manufacture of surgical implants and designs due to its biocompatibility and ability to undergo viscoelastic deformation with tissues, withstanding millions of deformation cycles without destruction. TiNi is a self-passivating material, as it forms a complex surface oxide layer that protects the material from corrosion and is itself biocompatible. The functional properties of TiNi wire are determined by the structure, composition, and thickness. The purpose of this work is to study the deformation behavior of thin TiNi wires depending on the thickness. TiNi wires of different thicknesses (40, 60, 90 µm) were tested by uniaxial tension to rupture and in the load-unload cycle (5 cycles). The results found that All TiNi wires exhibit the effect of superelasticity at a relative strain of 5-7%. With an increase in the wire thickness from 40 to 90 µm, the values of the martensitic shear stress increase from 450 to 1200 MPa and the tensile strength increases from 1300 to 3150 MPa.
由于其生物相容性和与组织进行粘弹性变形的能力,可以承受数百万次的变形循环而不受破坏,ti基金属丝被广泛用于外科植入物的制造和设计。TiNi是一种自钝化材料,因为它形成一个复杂的表面氧化层,保护材料免受腐蚀,并且本身具有生物相容性。TiNi丝的功能性能是由其结构、成分和厚度决定的。本工作的目的是研究TiNi细丝随厚度变化的变形行为。对40、60、90µm不同厚度的TiNi钢丝进行单轴拉伸断裂和5次加载-卸载循环试验。结果表明,在相对应变为5-7%时,所有TiNi钢丝均表现出超弹性效应。当线材厚度从40µm增加到90µm时,马氏体剪切应力值从450增大到1200 MPa,抗拉强度从1300增大到3150 MPa。
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引用次数: 0
An Overview of ASTM Standard Test Methods for Shape Memory Alloy Actuation Materials 形状记忆合金驱动材料的ASTM标准试验方法概述
D. Nicholson, O. Benafan, G. Bigelow, F. Sczerzenie, D. Forbes, B. Van Doren, J. Mabe, A. Demblon, I. Karaman
Standard test methods for Uniaxial Constant Force Thermal Cycling (UCFTC) and Uniaxial Pre-strain and Free Recovery (UPFR) have been published under ASTM as E3097 and E3098, respectively. These two test methods capture the two most important responses in shape memory alloys (SMAs) for actuation, which is load-biased shape memory effect and classical shape memory effect. These test methods measure the transformation properties such as transformation temperatures, actuation strain, and residual strain to provide data for the characterization and selection of SMA materials, quality control, design allowables, and actuator design. In light of this recent development, additional test methods are still needed to fully support the transition of SMA actuators to production use. First, there is a recognized need for a test method that defines and evaluates the evolution of actuation properties and actuation lifecycle during repeated UCFTC. Second, rotary SMA actuation has been demonstrated as a practical and valuable actuator form as highlighted recently during flight test of the spanwise adaptive wing and reconfigurable vortex generators and in remote controlled actuated wind tunnel models. To this end, two new test methods have been proposed to ASTM that extend the applicability of E3097 to repeated UCFTC and torsional testing, respectively. This paper provides an update on the development of SMA standardized test methods for actuator applications highlighting their need and envisioned approaches.
单轴恒力热循环(UCFTC)和单轴预应变和自由恢复(UPFR)的标准测试方法分别在ASTM E3097和E3098下发布。这两种测试方法捕捉了形状记忆合金驱动过程中最重要的两种响应,即负载偏置形状记忆效应和经典形状记忆效应。这些测试方法测量转换性能,如转换温度、驱动应变和残余应变,为SMA材料的表征和选择、质量控制、设计允许值和执行器设计提供数据。鉴于最近的发展,仍然需要额外的测试方法来完全支持SMA执行器向生产使用的过渡。首先,需要一种测试方法来定义和评估在重复UCFTC过程中驱动特性和驱动生命周期的演变。其次,旋转SMA驱动已被证明是一种实用且有价值的驱动形式,最近在展向自适应机翼和可重构涡发生器的飞行试验以及遥控驱动风洞模型中得到了突出表现。为此,ASTM提出了两种新的测试方法,分别将E3097的适用性扩展到重复的UCFTC和扭转测试。本文提供了执行器应用的SMA标准化测试方法的最新发展,突出了他们的需求和设想的方法。
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引用次数: 1
Wear and Tribology Behavior of Superelastic Ni-Ti Tubes under Fatigue Cycling in Compression 压缩疲劳循环下超弹性Ni-Ti管的磨损与摩擦学行为
J. Cerar, P. Jan, J. Klemenc, M. Kalin, J. Tušek
Compressive loading of shape memory alloys (SMA) is gaining considerable attention in recent years due to the improved fatigue life compared to tensile loading. This can be beneficial in applications such as dampers, actuators, and particularly elastocaloric cooling. SMA elements, however, tend to buckle under compressive loading and their stability can be enhanced by utilizing properly designed holders, i.e., structures that support SMA elements and prevent them from buckling. On the other hand, these supporting structures are in contact with SMA elements, which can cause wear and their premature failure, intensified by the lateral expansion of material under compression. In current literature, a majority of experiments are focused on reciprocating sliding wear of tungsten carbide or variations of bearing steel balls/discs/pins/rings on NiTi plates as well as on comparison of wear performance of NiTi with other materials. The aim of this present work is to theoretically and experimentally study tribological conditions between the tube and supporting element (bushing) and to find the most compatible material to NiTi in order to minimize wear, provide adequate structural support, and finally to enhance the overall fatigue behavior.
形状记忆合金(SMA)的压缩载荷与拉伸载荷相比具有更高的疲劳寿命,近年来受到越来越多的关注。这在阻尼器,执行器,特别是弹性热冷却等应用中是有益的。然而,SMA元件在压缩载荷下往往会发生屈曲,通过使用适当设计的支架,即支持SMA元件并防止其屈曲的结构,可以增强其稳定性。另一方面,这些支撑结构与SMA元件接触,这可能导致磨损和其过早失效,并且由于材料在压缩下的侧向膨胀而加剧。在目前的文献中,大多数实验都集中在碳化钨的往复滑动磨损或轴承钢球/盘/销/环在NiTi板上的变化,以及NiTi与其他材料的磨损性能比较。本工作的目的是通过理论和实验研究管与支撑元件(衬套)之间的摩擦学条件,并找到与NiTi最相容的材料,以最大限度地减少磨损,提供足够的结构支撑,最终提高整体疲劳性能。
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引用次数: 0
ASTM F2129 Cyclic-Potentiodynamic Polarization Testing of Nitinol Stents Indicated for Use in the GI Tract 用于胃肠道的镍钛诺支架的循环电位动态极化测试
Steven E. Walak, N. Budiansky
Nitinol self-expanding stents are used to treat disease in all areas of the human gastrointestinal (GI) tract. Chemistry along the GI tract changes both spatially and temporally with pH ranging from 1.2 in the stomach to 8.5 in the common bile duct. A variety of secretions add ions, digestive enzymes, and proteins to the environment along the GI tract. Establishing absolute acceptance criteria for corrosion resistance of metallic implants presents a unique challenge in this constantly changing environment. In this study, cyclic potentiodynamic polarization corrosion tests were conducted over several years at multiple labs in accordance with the requirements of ASTM F2129. Braided Nitinol wire stents with thermal oxide surface representing a range of GI tract stents with good clinical history were tested in solutions selected to simulate the target anatomy in the human gastrointestinal tract. The results suggest that acceptance criteria for devices tested in simulated vascular environments do not reflect requirements for successful devices used in the varied chemical environments of the GI tract. Breakdown voltage acceptance criterion need to consider the clinical application and in-body use environment. Inherent test variability must also be considered when demonstrating statistical equivalence to clinically successful comparator devices or fixed value specifications.
镍钛诺自膨胀支架用于治疗人类胃肠道所有区域的疾病。随着pH值从胃的1.2到胆总管的8.5,胃肠道的化学变化既有空间上的也有时间上的。各种分泌物沿着胃肠道向环境中添加离子、消化酶和蛋白质。在这种不断变化的环境中,建立金属植入物耐腐蚀的绝对验收标准是一项独特的挑战。在本研究中,根据ASTM F2129的要求,在多个实验室进行了数年的循环动电位极化腐蚀试验。热氧化表面编织镍钛诺丝支架代表了一系列具有良好临床病史的胃肠道支架,在模拟人体胃肠道目标解剖结构的溶液中进行了测试。结果表明,在模拟血管环境中测试的设备的验收标准并不能反映在胃肠道各种化学环境中成功使用的设备的要求。击穿电压验收标准需要考虑临床应用和体内使用环境。在证明与临床成功的比较器装置或固定值规格的统计等效性时,还必须考虑固有的测试变异性。
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引用次数: 0
Hot Forming of Nitinol: Fundamental Investigations and Applications 镍钛诺热成形:基础研究与应用
Stefan Zende, Moritz Pohler, Lucas Bittigkoffer, Nils-Agne Feth
Nitinol's thermomechanical properties are well studied and understood below the so-called martensite death (MD) temperature, above which martensite cannot be induced by mechanical stress: Even at high stresses Nitinol stays in the austenite phase. This paper presents tensile tests performed well above MD (>150 °C) with Nitinol specimens laser cut from tube. The investigations show that Nitinol drastically changes its mechanical properties in this temperature range: The superelastic plateau shortens and finally vanishes. Furthermore, Nitinol starts becoming more ductile.
在所谓的马氏体死亡(MD)温度以下,镍钛诺的热机械性能得到了很好的研究和理解,在此温度以上,马氏体不能由机械应力诱导:即使在高应力下,镍钛诺仍保持在奥氏体相。本文介绍了用激光从管上切割镍钛诺试样,在MD(>150°C)以上进行的拉伸试验。研究表明,在此温度范围内,镍钛诺的力学性能发生了巨大的变化:超弹性平台缩短并最终消失。此外,镍钛诺开始变得更有韧性。
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引用次数: 0
Shape Memory Materials Database (SMMD): Finding Data Anomalies & Trends 形状记忆材料数据库(SMMD):发现数据异常和趋势
P. Caltagirone, O. Benafan, S. Bostic
A comprehensive shape memory materials database (SMMD) repository is being developed that provides access to a large collection of information on shape memory materials (SMMs) in a single source. The collection of point data and metadata provides insight into actuation properties, structural performance, chemical data, processing records, and similar factors pertinent to shape memory alloys, polymers, and ceramics. The data is organized in a 2D and 3D visualization platform allowing users to gain immediate access to data insights and trends with only a few button clicks. All data points have full traceability to the original source to verify findings and create a link to researchers and scientists within the community. In addition to millions of datapoints already displayed, the web-application also offers access to analysis tools, references to international standards, and resources pertinent to the SMM community.
一个全面的形状记忆材料数据库(SMMD)存储库正在开发中,它提供了对单一来源的形状记忆材料(SMMs)的大量信息的访问。点数据和元数据的收集提供了对驱动特性、结构性能、化学数据、处理记录以及与形状记忆合金、聚合物和陶瓷相关的类似因素的深入了解。数据在2D和3D可视化平台中组织,允许用户只需点击几下按钮即可立即访问数据见解和趋势。所有数据点都可以完全追溯到原始来源,以验证发现,并与社区内的研究人员和科学家建立联系。除了已经显示的数以百万计的数据点之外,web应用程序还提供了访问分析工具、参考国际标准和与SMM社区相关的资源的途径。
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引用次数: 0
Comparison of Various Metallography Preparation Methods of Binary NiTi-shape Memory Alloy Specimens 二元镍钛形状记忆合金试样不同金相制备方法的比较
C. Holm, Nefeli Klonis, R. Krieg, R. Theiss, P. Dültgen
In this paper, the results of different selected mechanical and electrolytic preparation methods are compared with regard to the successful visualization of Nitinol microstructure. The results indicate that a commonly specified preparation route may result in false microstructure and therefore in false interpretation of the material, its behavior, and its lifetime condition. An electrolytic preparation is defined that may provide superior metallographic sample preparation results for drawn NiTi materials.
在本文中,比较了不同选择的机械和电解制备方法对镍钛诺微观结构的成功可视化效果。结果表明,通常指定的制备路线可能导致错误的微观结构,从而导致对材料,其行为和寿命状态的错误解释。定义了一种电解制备方法,它可以为拉伸镍钛材料提供优越的金相样品制备结果。
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引用次数: 0
期刊
SMST 2022: Extended Abstracts from the International Conference on Shape Memory and Superelastic Technologies
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