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Photochemical Oxidative Cleavage and Dihydroxylation of Unsaturated Fatty Acids Using Triplet Nitroarenes 利用三态硝基芳烃的光化学氧化裂解和不饱和脂肪酸的二羟基化
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-22 DOI: 10.1002/ejlt.70004
Piotr T. Błyszczyk, Daniele Leonori

The widespread use of bio-derived lipids as renewable feedstock chemicals requires their synthetic modification for downstream applications. Herein, we demonstrate the use of nitroarenes as photo-responsive oxidants for the synthesis of aldehydes and 1,2-diols from unsaturated fatty acids. This approach addresses the conventional use of hazardous and toxic reagents such as ozone (O3) and osmium tetroxide (OsO4). The successful employment of stable and nontoxic nitroarenes in oxidation chemistry is demonstrated on a series of industrially relevant fatty acids including carboxylic acids and their methyl ester equivalents producing oxygen-enriched substrates.

生物源性脂类作为可再生原料化学品的广泛使用,需要对其进行合成改性以供下游应用。在这里,我们展示了硝基芳烃作为光反应氧化剂的使用,用于从不饱和脂肪酸合成醛和1,2-二醇。这种方法解决了臭氧(O3)和四氧化锇(OsO4)等危险和有毒试剂的传统使用问题。稳定无毒的硝基芳烃在氧化化学中的成功应用证明了一系列工业上相关的脂肪酸,包括羧酸及其甲酯当量,产生富氧底物。
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引用次数: 0
Enzymatic Valorization of Fatty Acids in Oleochemical Synthesis 油脂化学合成中脂肪酸的酶促增值
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-18 DOI: 10.1002/ejlt.70000
Florian Tieves, Frank Hollmann

Fatty acids derived from renewable resources, such as vegetable oils, serve as essential feedstocks in various industries, including surfactants, cosmetics, lubricants, and polymers. Although current industrial applications of fatty acids are mainly centered around carboxylate group transformations, recent advancements in biocatalysis have opened new possibilities for converting fatty acids into valuable chemical building blocks. This contribution critically assesses novel biocatalytic transformations of fatty acids, including hydroxylation of the alkyl chain, epoxidation of C═C double bonds, reduction of the carboxylate group, and decarboxylation. These reactions hold great potential for producing important intermediates for chemical synthesis.

Practical Application: The enzymatic valorization of fatty acids offers transformative potential for sustainable oleochemical synthesis, presenting practical applications across various industries. Hydroxylated and epoxidized fatty acids are promising precursors for the production of polyesters, bio-based lubricants, and surfactants. Sophorolipids, derived from hydroxylated fatty acids, are gaining attraction as renewable biosurfactants with applications in detergents and cosmetics. Epoxidized fatty acids serve as intermediates for eco-friendly adhesives, coatings, and polymers. Furthermore, decarboxylation reactions yield alkanes, viable as biofuels, whereas reductions of carboxyl groups enable selective synthesis of aldehydes and alcohols for fragrances and pharmaceutical intermediates. The scalability of these biocatalytic transformations, combined with their mild operational conditions and high specificity, can substantially reduce environmental impact and production costs. These applications highlight biocatalysis as a pivotal technology for advancing the chemical industry toward sustainable practices.

脂肪酸来源于可再生资源,如植物油,是许多行业的基本原料,包括表面活性剂、化妆品、润滑剂和聚合物。虽然目前脂肪酸的工业应用主要集中在羧酸基转化上,但最近生物催化的进展为将脂肪酸转化为有价值的化学构件开辟了新的可能性。这篇论文批判性地评估了脂肪酸的新型生物催化转化,包括烷基链的羟基化、C = C双键的环氧化、羧酸基的还原和脱羧。这些反应在生产重要的化学合成中间体方面具有很大的潜力。实际应用:脂肪酸的酶促增值为可持续的油脂化学合成提供了变革性的潜力,在各个行业都有实际应用。羟基化和环氧化脂肪酸是生产聚酯、生物基润滑剂和表面活性剂的有前途的前体。从羟基化脂肪酸中提取的槐油脂作为可再生生物表面活性剂在洗涤剂和化妆品中的应用越来越受到关注。环氧化脂肪酸可作为环保粘合剂、涂料和聚合物的中间体。此外,脱羧反应产生烷烃,可以作为生物燃料,而羧基的减少可以选择性地合成醛和醇,用于香料和医药中间体。这些生物催化转化的可扩展性,加上其温和的操作条件和高特异性,可以大大减少对环境的影响和生产成本。这些应用突出了生物催化作为推动化学工业走向可持续实践的关键技术。
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引用次数: 0
Catalytic Dehydrogenation of Lauric Acid and a Potential Use in Polyester Synthesis 月桂酸催化脱氢及其在聚酯合成中的潜在应用
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-17 DOI: 10.1002/ejlt.70003
Luis Santos Correa, Emma Stapf, Timo Nonner, Michael A. R. Meier

The substitution of depleting fossil resources by renewable resources is of paramount importance, especially for polymer chemistry with its large production volume, in order to guarantee a more sustainable future. Herein, a new three-step reaction sequence was developed to synthesize renewable fatty acid–based dimethyl esters from saturated fatty acids. The sequence consists of a catalytic dehydrogenation with molecular oxygen as oxidant, an esterification with methanol, and a dimerization reaction with dithiols via thia-Michael addition. Three new dimethyl esters were thus synthesized from lauric acid and fully characterized via infrared, 1H NMR, and 13C NMR spectroscopy as well as mass spectrometry. Polyesters with molecular weights ranging from 26.0 to 31.8 kDa were obtained by polycondensation of each dimethyl ester with 1,12-dodecanediol. Methyl crotonate–based polymers were prepared for comparison with the fatty acid–derived materials. Thermogravimetric analysis revealed that the long side chains led to improved thermal stability, and differential scanning calorimetry showed side chain crystallization for one polymer.

Practical Applications Renewable dimethyl esters are valuable monomers for the sustainable synthesis of polyesters and polyamides. The herein-reported synthesis strategy valorized saturated fatty acids, a typically less useful resource for polymer chemistry.

用可再生资源替代消耗殆尽的化石资源是至关重要的,特别是对于产量巨大的聚合物化学来说,为了保证一个更可持续的未来。本文提出了以饱和脂肪酸为原料合成可再生脂肪酸基二甲酯的三步反应方法。该序列包括以分子氧为氧化剂的催化脱氢反应,与甲醇的酯化反应,以及通过硫-迈克尔加成与二硫醇的二聚反应。以月桂酸为原料合成了三种新的二甲酯,并通过红外、1H NMR、13C NMR以及质谱对其进行了表征。通过与1,12-十二烷二醇缩聚,得到分子量为26.0 ~ 31.8 kDa的聚酯。制备了巴豆酸甲酯基聚合物,并与脂肪酸衍生材料进行了比较。热重分析表明,长侧链提高了聚合物的热稳定性,差示扫描量热法显示了一种聚合物的侧链结晶。可再生二甲酯是可持续合成聚酯和聚酰胺的重要单体。本文报道的合成策略使饱和脂肪酸增值,而饱和脂肪酸通常是聚合物化学中不太有用的资源。
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引用次数: 0
Impact of Dietary Mineral and Vitamin Supplementation on Meat Quality and Nutritional Profile and Gene Expression in Goats 饲粮中添加矿物质和维生素对山羊肉质、营养状况和基因表达的影响
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-17 DOI: 10.1002/ejlt.70005
Arun K. Verma, V. Rajkumar, Ravindra Kumar, K. Gururaj, Tarun Pal Singh, Tanuja Kushwah, Manish Kumar Chatli

This study investigated the impact of dietary supplementation with different forms of minerals and vitamins on growth, carcass cum meat qualities, and gene expression in Barbari goat kids. Four groups of goat kids (six kids in each group) of 6–7 months were fed different diets for 120 days: a basal diet (Group A), a basal diet with vitamins and inorganic minerals (Group B), a basal diet with vitamins and organic minerals (Group C), and a basal diet with vitamins and nano minerals (Group D). Growth parameters, carcass, meat qualities, and expression of genes relevant to growth, metabolism, antioxidant activity, and myogenesis were assessed. Significant differences (p < 0.05) were observed among the groups in growth and carcass quality. Meat from supplemented groups had a lower cooking loss (except Group B) and higher pigments and vitamins. Group D had lower (p < 0.05) meat yellowness, and Group C had higher shear force. Significantly (p < 0.05) higher Fe, Zn, and Se were recorded in Group C and D meats. Fatty acid profile of meat was significantly (p < 0.05) affected by dietary treatments, and Group D meat had higher (p < 0.05) saturated fatty acid (SFA), polyunsaturated fatty acid (PUFA), and n-6 PUFA. The supplementation influenced the expression of the studied genes.

Practical Application: Intake of desirable macro- and micronutrients through dietary means is always preferred over supplements. Meat, including from goat, rich in unsaturated and polyunsaturated fatty acids, omega fatty acids, Fe, Zn, Se, and vitamins A and E, can help address nutritional deficits and wellbeing, thus having a greater consumer preference and market potential. The present research showed that the supplementation of vitamins and organic and nano trace elements increased their contents in meat, besides improvements in animal growth, muscle mass, and fatty acid profile. Higher costs of organic and nano-minerals may be a limiting factor for their application in goat production. However, this could be countered by upscaling their production, better absorption, bioactivities, animal growth performance, desirable meat quality and healthier nutrient profile, lower dose rate, and eco-friendly nature. The upregulation of the studied genes indicates interaction between supplemented micronutrients and genes, besides highlighting the possible mode of action. Thus, this approach could be very promising in the production of meat with an improved fatty acid profile and rich in trace elements and vitamins.

本研究探讨了日粮中添加不同形式的矿物质和维生素对巴巴利山羊幼山羊生长、胴体和肉品质以及基因表达的影响。选取6 ~ 7月龄的4组山羊(每组6只),分别饲喂基础饲粮(a组)、基础饲粮中添加维生素和无机矿物质(B组)、基础饲粮中添加维生素和有机矿物质(C组)和基础饲粮中添加维生素和纳米矿物质(D组),为期120 D。观察生长参数、胴体、肉质以及与生长、代谢、抗氧化活性和肌肉形成相关的基因表达。显著差异(p <;各组间生长和胴体品质差异均达0.05)。添加组肉的蒸煮损失较低(B组除外),色素和维生素含量较高。D组(p <;0.05)肉黄度,且C组剪切力较高。显著(p <;C组和D组肉的铁、锌、硒含量均高于对照组(0.05)。肉的脂肪酸分布显著(p <;0.05),且D组肉品含量高于(p <;0.05)饱和脂肪酸(SFA)、多不饱和脂肪酸(PUFA)和n-6 PUFA。添加物影响了所研究基因的表达。实际应用:通过饮食摄入所需的宏量和微量营养素总是比补充剂更可取。包括羊肉在内的肉类富含不饱和和多不饱和脂肪酸、欧米茄脂肪酸、铁、锌、硒以及维生素A和E,可以帮助解决营养不足和健康问题,因此具有更大的消费者偏好和市场潜力。本研究表明,补充维生素、有机元素和纳米微量元素可提高肉类中有机元素和微量元素的含量,并可改善动物生长、肌肉质量和脂肪酸结构。有机和纳米矿物的高成本可能是限制其在山羊生产中的应用的一个因素。然而,这可以通过提高产量、更好的吸收、生物活性、动物生长性能、理想的肉质和更健康的营养成分、更低的剂量率和生态友好的性质来解决。所研究的基因的上调表明补充微量营养素和基因之间的相互作用,除了突出可能的作用方式。因此,这种方法在生产脂肪酸含量更高、富含微量元素和维生素的肉类方面非常有前景。
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引用次数: 0
Issue Information: Eur. J. Lipid Sci. Technol. 发行信息:欧元。J.油脂科学。抛光工艺。
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-14 DOI: 10.1002/ejlt.70006
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引用次数: 0
Engineering Diesters From Saturated Fatty Acids and C2–C4 Diols: How Branching Influence Rheological, Flow, and Crystallization Properties 饱和脂肪酸和C2-C4二醇的工程酯:分支如何影响流变、流动和结晶性质
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-14 DOI: 10.1002/ejlt.202400211
Michele Emanuele Fortunato, Rosa Vitiello, Francesco Taddeo, Luigi Faro, Salvatore Mallardo, Rosa Turco, Riccardo Tesser, Vincenzo Russo, Martino Di Serio

In response to the increasing demand for sustainable materials, this study explores the structure–property relationships of 22 novel diesters synthesized from C2–C4 linear and branched diols and saturated fatty acids (SFAs), targeting the improvement of vegetable oil-based lubricants’ oxidative stability and low-temperature performance. Diesters based on pelargonic (C9), lauric (C12), myristic (C14), and palmitic (C16) acids were characterized for viscosity, crystallization temperature, and flow behavior. Branched diols significantly enhanced low-temperature properties, with 1,2-butanediol and 1,3-butanediol diesters always exhibiting the lowest crystallization temperatures. Viscosity increased with fatty acid chain length, whereas branching caused a slight reduction due to steric hindrance. Most diesters showed shear-thickening behavior, modeled by the Herschel–Bulkley equation. Additionally, all diesters demonstrated excellent oxidative stability, surpassing 300 min in accelerated aging tests. These findings suggest that the synthesized diesters, particularly those with branched diols, offer promise as sustainable, high-performance alternatives for industrial lubricant applications.

Practical Application: The diesters synthesized from saturated fatty acids and C2–C4 diols offer strong potential as bases for bio-based lubricants, particularly in applications requiring high oxidative stability. The esters, particularly those derived from branched diols, exhibit improved cold flow properties, due to their lower crystallization temperatures, making them ideal candidates for use in industries requiring lubricants that perform well in low-temperatures conditions. Their shear-thickening behavior also makes them ideal for shock-absorbing uses. The comprehensive analysis and results presented in this study provide a valuable reference for selecting the optimal combination of fatty acids and alcohols to tailor synthetic esters with specific properties, addressing diverse needs in the lubricant industry. This work serves as a practical guide for developing high-performance, sustainable lubricant formulations.

为了应对日益增长的可持续材料需求,本研究探索了由C2-C4线性和支链二醇与饱和脂肪酸合成的22种新型二酯的结构-性能关系,旨在提高植物油基润滑油的氧化稳定性和低温性能。以天龙酸(C9)、月桂酸(C12)、肉豆丝酸(C14)和棕榈酸(C16)为基础的二酯的粘度、结晶温度和流动特性进行了表征。支链二醇显著提高了低温性能,其中1,2-丁二醇和1,3-丁二醇二酯的结晶温度最低。粘度随脂肪酸链长的增加而增加,而支链由于位阻导致粘度略有降低。根据Herschel-Bulkley方程,大多数化合物表现出剪切增厚的行为。此外,所有二酯均表现出优异的氧化稳定性,在加速老化试验中超过300分钟。这些发现表明,合成的二酯,特别是那些具有支链二醇的二酯,有望成为工业润滑油应用的可持续、高性能替代品。实际应用:由饱和脂肪酸和C2-C4二醇合成的二酯为生物基润滑油提供了强大的潜力,特别是在需要高氧化稳定性的应用中。由于其较低的结晶温度,酯类,特别是从支化二醇衍生的酯类,表现出更好的冷流动性能,使其成为需要在低温条件下表现良好的润滑剂的理想候选者。它们的剪切增厚性能也使它们成为理想的减震用途。本研究的综合分析和结果为选择脂肪酸和醇的最佳组合来定制具有特定性能的合成酯提供了有价值的参考,以满足润滑油行业的不同需求。这项工作为开发高性能、可持续的润滑剂配方提供了实用指南。
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引用次数: 0
In Vitro Digestion of High-Fat Commercial Dairy Products: Detailed Analysis of Lipid Classes 高脂肪商业乳制品的体外消化:脂类的详细分析
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-14 DOI: 10.1002/ejlt.70001
Eirin Stork, Dag Ekeberg, Hanne M. Devle, Einar Jonsson, Lene Ruud, Tove Devold, Siv Skeie

This study aimed to comprehensively analyze lipid classes after in vitro digestion of high-fat commercial dairy products. The research focused on the fatty acid (FA) profiles of triacylglycerols, diacylglycerols, monoacylglycerols (MAG), free FA (FFA), and polar lipids of digested full-fat cream, full-fat sour cream, cream cheese, and a Gouda-type cheese. We employed the INFOGEST 2.0 digestion model. The isolated lipids were fractionated by solid-phase extraction, and the FA profile of each fraction was analyzed using GC–MS. The digested dairy products revealed similar results for the relative amounts of the analyzed lipid classes. However, the cream digest had a significantly lower amount of MAG than the other products. Furthermore, the proportion of individual FAs and FA groups in the lipid classes was found to vary significantly between the digested dairy products. The replicates of cream cheese and sour cream showed a homogenous lipid digestion, whereas the lipid classes after digestion of cream and the Gouda-type cheese were more diverse. This could be due to differences in product pH and protein and calcium content.

Practical Applications: The findings of our study indicate the importance of considering lipid classes other than FFA, as well as the FA composition of these, when studying the lipid digestion of different dairy products. This is especially true for MAG, which is absorbed in the intestine along with FFA. The observed differences in the lipid profile of the digested dairy matrices explored in our study demonstrate that product pH, homogenization, texture, and calcium and protein content could impact lipid bioaccessibility, which could potentially have physiological implications. These factors should, therefore, be assessed in relation to lipid digestion.

本研究旨在全面分析高脂商业乳制品体外消化后的脂类。研究重点是消化全脂奶油、全脂酸奶油、奶油奶酪和豪达奶酪的三酰基甘油、二酰基甘油、单酰基甘油(MAG)、游离脂肪酸(FFA)和极性脂质的脂肪酸(FA)谱。我们采用了INFOGEST 2.0消化模型。分离得到的脂质采用固相萃取法进行分离,各组分的FA谱采用GC-MS进行分析。消化后的乳制品中所分析的脂类的相对数量也显示出类似的结果。然而,奶油消化液的MAG含量明显低于其他产品。此外,各个脂肪酸组和脂肪酸组在脂类类中的比例在消化的乳制品之间有显著差异。奶油奶酪和酸奶油的重复消化均为均匀的脂质消化,而奶油和豪达奶酪消化后的脂质种类更为多样化。这可能是由于产品pH值、蛋白质和钙含量的差异。实际应用:我们的研究结果表明,在研究不同乳制品的脂质消化时,考虑除游离脂肪酸以外的脂质类别以及它们的游离脂肪酸组成的重要性。MAG尤其如此,它与FFA一起在肠道中被吸收。在我们的研究中,观察到的消化乳制品基质的脂质谱的差异表明,产品的pH、均质性、质地、钙和蛋白质含量可能会影响脂质的生物可及性,这可能具有潜在的生理意义。因此,这些因素应该与脂质消化有关。
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引用次数: 0
Valorization of Biodiesel Into Bio-Based Plasticizers: Optimization of Epoxidized Fatty Acid Isobutyl Ester Production Using Response Surface Methodology and Artificial Neural Network 生物柴油转化为生物基增塑剂:利用响应面法和人工神经网络优化环氧化脂肪酸异丁基酯的生产
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-09 DOI: 10.1002/ejlt.202400223
Xiaojiang Liang, Haotian Fei, Fengjiao Wu, Jiawei Ma, Zhenyu Wu, Yong Nie

Biodiesel is a promising green chemical feedstock due to its renewability and sustainability. In this study, bio-based plasticizers, epoxidized fatty acid isobutyl esters (Ep-FABEs), were prepared using biodiesel as a feedstock through a combination of transesterification and the formic acid autocatalytic method. The effects of reaction temperature, reaction time, FA/C═C molar ratio, and H2O2/C═C molar ratio on the conversion to oxirane (RCO) during the epoxidation process were investigated using a central composite design. Both response surface methodology (RSM) and artificial neural network (ANN) models were developed to model and optimize the epoxidation process. Comparative analysis revealed that the ANN model demonstrated superior predictive capabilities, with lower mean squared error (MSE), lower mean absolute error (MAE), and a higher coefficient of determination (R2) compared to the RSM model. The ANN model predicted an RCO of 92%, which was closely aligned with the experimental value of 91% under optimized conditions (reaction temperature of 66°C, reaction time of 6.7 h, FA/C═C molar ratio of 0.35, and H2O2/C═C molar ratio of 2.70). Additionally, the physico-chemical properties of Ep-FABEs were further analyzed. These findings provide valuable insights into the production of bio-based plasticizers using biodiesel as a feedstock.

生物柴油具有可再生性和可持续性,是一种很有前途的绿色化工原料。本研究以生物柴油为原料,采用酯交换法和甲酸自催化相结合的方法制备了环氧脂肪酸异丁基酯(Ep-FABEs)生物基增塑剂。采用中心复合设计研究了反应温度、反应时间、FA/C = C的摩尔比和H2O2/C = C的摩尔比对环氧化过程中生成氧环烷(RCO)的影响。采用响应面法(RSM)和人工神经网络(ANN)模型对环氧化过程进行建模和优化。对比分析表明,与RSM模型相比,ANN模型具有更低的均方误差(MSE)、平均绝对误差(MAE)和更高的决定系数(R2),具有更强的预测能力。ANN模型预测的RCO为92%,与优化条件下(反应温度为66℃,反应时间为6.7 h, FA/C = C摩尔比为0.35,H2O2/C = C摩尔比为2.70)的实验值91%非常接近。进一步分析了Ep-FABEs的理化性质。这些发现为使用生物柴油作为原料生产生物基增塑剂提供了有价值的见解。
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引用次数: 0
Deacidification of Coconut Oil Using Different Resins: A Comparative Study 不同树脂对椰子油脱酸的比较研究
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-03 DOI: 10.1002/ejlt.202400179
Bhumika K. P., Mayookha V. P., Arun Sharma K, Suresh Kumar G.

In the food sector, deacidification of vegetable oil is essential for enhancing edible oil's stability, quality, and shelf life. It is still difficult to come up with an efficient deacidification method that makes use of high-acid-value oil to produce edible goods that are both high-quality and value-added. The present work provides a newly developed, adaptable, and long-lasting ion exchange deacidification method. Three different ion exchange resins, that is, Amberlite IRA 400 (AMT), Amberlyst A26 (A26), and Dowex WGR-2 (DOX) at different concentrations were assessed to remove free fatty acids (FFAs) by adsorption using a column, where AMT (85.92%) and A26 (98.02%) showed a good result compared to DOX (75.4%). To further confirm the reduction in the acid value of the treated oil, multiple methods were used, including FFA measurement by titration, gas chromatography (GC), high-performance liquid chromatography (HPLC), and attenuated total reflectance Fourier-transform infrared spectroscopy (ATR-FTIR). All these methods consistently demonstrated a reduction in FFA levels in the oil collected after treatment with resin. Additionally, to assess the effect of the resin on the oil, various physicochemical parameters were analyzed. It was found that most of the tocopherols and tocotrienols were preserved, and there was little to no impact on other key quality parameters.

Practical Applications: Our study offers valuable insights into the development of a deacidification technology for removing FFAs from oil using resins. This environment-friendly method effectively tackles the challenge of high acidity in oils by efficiently adsorbing FFAs. The use of resins provides an efficient solution while retaining the nutritional properties of the oil, making it an appealing alternative to traditional methods. This technology holds significant potential for industrial applications, such as improving the quality and shelf life of edible oils by removing FFA, as well as reducing waste during alkali treatment. Implementing this technique can help promote better practices in the oil processing industry.

在食品领域,植物油的脱酸对提高食用油的稳定性、质量和保质期至关重要。目前还很难找到一种高效的脱酸方法,利用高酸值油生产出高质量和高附加值的食用产品。本工作提供了一种新开发的适应性强、长效的离子交换脱酸方法。以不同浓度的Amberlite IRA 400 (AMT)、Amberlyst A26 (A26)和Dowex WGR-2 (DOX)三种不同的离子交换树脂为吸附柱,对游离脂肪酸(FFAs)的去除效果进行了评价,其中AMT(85.92%)和A26(98.02%)的效果优于DOX(75.4%)。为了进一步证实处理后油的酸值降低,采用了多种方法,包括滴定法测定FFA、气相色谱法(GC)、高效液相色谱法(HPLC)和衰减全反射傅里叶变换红外光谱法(ATR-FTIR)。所有这些方法一致表明,树脂处理后收集的油中FFA水平降低。此外,为了评估树脂对油的影响,分析了各种理化参数。结果发现,大部分生育酚和生育三烯醇被保存下来,对其他关键质量参数的影响很小或没有影响。实际应用:我们的研究为使用树脂从油中去除游离脂肪酸的脱酸技术的发展提供了有价值的见解。这种环境友好的方法通过有效地吸附游离脂肪酸,有效地解决了油脂中高酸度的挑战。树脂的使用提供了一种有效的解决方案,同时保留了油的营养特性,使其成为传统方法的一种有吸引力的替代方案。这项技术在工业应用方面具有巨大的潜力,例如通过去除FFA来提高食用油的质量和保质期,以及减少碱处理过程中的浪费。实施这项技术有助于在石油加工行业推广更好的做法。
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引用次数: 0
Recent Developments and Applications of Vegetable Oil in Fish Feed 植物油在鱼饲料中的最新发展和应用
IF 1.8 3区 农林科学 Q3 FOOD SCIENCE & TECHNOLOGY Pub Date : 2025-02-02 DOI: 10.1002/ejlt.202300235
Xie Gu, Zhi Li Ding, Zhen Zhen Yuan, Shun Yang, Hui Fei

Dietary lipids play a vital role in providing essential fatty acids that are crucial for the regulation of growth, health, reproduction, and overall physiological functions of fish. Traditionally, fish oil (FO) has served as the primary lipid source in commercial fish feed. However, due to the dwindling availability and escalating costs of FO, the sustainable growth of aquaculture has been hindered. On the other hand, vegetable oil (VO) has emerged as a promising alternative lipid source for fish diets, owing to its abundance, cost-effectiveness, and rich content of essential C18 fatty acids. While numerous studies have explored the impact of VO on fish growth and health, it has been noted that most VO cannot entirely replace FO in the diet due to its adverse effects. Hence, current research suggests that innovative strategies such as genetic modification, nutritional programming, and supplementation with functional compounds may help alleviate the negative effects associated with dietary VO. Given the critical need to seek alternative lipid sources in fish feed to address the limited global supply of FO, coupled with the cost-effectiveness and nutrient content of VO, it is imperative to further investigate their application in fish feed formulations to support sustainable fish production.

Practical Applications: This review highlights the importance of finding alternative lipid sources for fish feed in order to support sustainable aquaculture growth. Incorporating vegetable oil (VO) into fish diets can help alleviate the reliance on fish oil, which is becoming increasingly scarce and expensive. However, it is essential to consider the potential negative effects of VO and explore innovative strategies to mitigate these effects. By continuing to research and develop new techniques, such as genetic modification and nutritional programming, we can optimize the use of VO in fish feed formulations to promote healthy growth and reproduction in fish. Overall, this review emphasizes the significance of exploring alternative lipid sources in fish feed to ensure the long-term viability of aquaculture production.

膳食脂类在提供必需脂肪酸方面起着至关重要的作用,这些脂肪酸对鱼类的生长、健康、繁殖和整体生理功能的调节至关重要。传统上,鱼油一直是商业鱼类饲料的主要脂质来源。然而,由于FO的可得性不断减少和成本不断上升,阻碍了水产养殖的可持续增长。另一方面,植物油(VO)由于其丰富、成本效益和丰富的必需C18脂肪酸含量而成为鱼类饲料中有前途的替代脂质来源。虽然有许多研究探讨了鱼油对鱼类生长和健康的影响,但人们注意到,由于其不利影响,大多数鱼油不能完全取代饲料中的鱼油。因此,目前的研究表明,诸如基因改造、营养规划和补充功能化合物等创新策略可能有助于减轻与膳食VO相关的负面影响。鉴于迫切需要在鱼饲料中寻找替代脂质来源,以解决全球有限的鱼油供应问题,再加上鱼油的成本效益和营养含量,进一步研究它们在鱼饲料配方中的应用,以支持可持续的鱼类生产是势在必行的。实际应用:本综述强调了寻找替代脂质来源作为鱼饲料的重要性,以支持可持续的水产养殖增长。将植物油(VO)加入鱼类饲料可以帮助减轻对鱼油的依赖,而鱼油正变得越来越稀缺和昂贵。然而,必须考虑到VO的潜在负面影响,并探索创新策略来减轻这些影响。通过继续研究和开发新技术,如基因改造和营养规划,我们可以优化VO在鱼饲料配方中的使用,以促进鱼类的健康生长和繁殖。总之,这篇综述强调了在鱼类饲料中探索替代脂质来源以确保水产养殖生产的长期可行性的重要性。
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European Journal of Lipid Science and Technology
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