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Fundamental flame spread and toxicity evaluation of fire retarded polymers 阻燃聚合物的基本火焰蔓延和毒性评价
Pub Date : 2014-01-01 DOI: 10.3801/IAFSS.FSS.11-846
M. Suzanne, S. Ukleja, M. Delichatsios, Jianping Zhang, B. Karlsson
A simple method is developed for characterizing the fire performance and toxicity of polymers using basically three but up to five parameters if necessary. The first parameter is related to fire spread and growth (corresponding to UL-94 and the FIGRA of SBI), the second parameter is the smoke yield (corresponding to the SMOGRA of SBI), the third parameter is the inefficiency of combustion (related to unburned hydrocarbon compounds and their toxicity as verified by tube furnace measurements), the fourth parameter is the mass of residue remaining and the fifth parameter is a heat release parameter for thermally thin conditions (the maximum mass loss rate in TGA multiplied by the effective heat of combustion deduced from the Cone Calorimeter tests). The developed methodology was used to compare brominated and halogen free fire retardants in formulations of PBT, PA66, PPE/HIPS and PC/ABS. It is confirmed that the studied environmentally friendly alternatives to brominated fire retardants offer comparable fire performance with lower toxicity.
开发了一种简单的方法来表征聚合物的防火性能和毒性,基本使用三个参数,必要时最多使用五个参数。第一个参数与火势蔓延和生长有关(对应于UL-94和SBI的FIGRA),第二个参数是产烟量(对应于SBI的SMOGRA),第三个参数是燃烧效率低(与未燃烧的碳氢化合物及其毒性有关,经管式炉测量证实)。第四个参数是残余残留物的质量,第五个参数是热薄条件下的热释放参数(热重分析中的最大质量损失率乘以从锥量热计测试中推断出的有效燃烧热)。采用该方法对PBT、PA66、PPE/HIPS和PC/ABS配方中的溴化阻燃剂和无卤阻燃剂进行了比较。研究证实,所研究的环境友好型溴化阻燃剂替代品具有相当的防火性能和较低的毒性。
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引用次数: 5
Role of montmorillonite for enhancing fire retardancy of intumescent PLA 蒙脱土对膨胀型聚乳酸阻燃性的增强作用
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-808
G. Fontaine, A. Gallos, S. Bourbigot
This work deals with the effect of an organomodified montmorillonite (OMMT, cloisite C30B) in intumescent PLA, which makes it nonflammable. The use of OMMT dramatically improves the fire properties of intumescent PLA in terms of limiting oxygen index (LOI) and heat release rate (HRR), which is almost zero. The part played by OMMT in the improvement of the FR performance was studied using a Microscale Combustion Calorimeter (MCC), solid-state NMR ( 13 C, 31 P and 27 Al) and specific set-up for temperature and swelling measurements in the char during fire test. It is shown that the clay increases the efficiency of the protective char by strongly limiting heat and mass transfer.
本文研究了一种有机改性蒙脱土(OMMT, cloite C30B)在膨胀型聚乳酸中的作用,使其不易燃。在极限氧指数(LOI)和热释放率(HRR)方面,OMMT的使用显著提高了膨胀型PLA的防火性能,几乎为零。使用微尺度燃烧量热计(MCC)、固态核磁共振(13c、31p和27al)以及在燃烧测试中焦炭的温度和膨胀测量的特定设置,研究了OMMT在改善FR性能方面所起的作用。结果表明,粘土通过强烈地限制传热传质,提高了保护炭的效率。
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引用次数: 13
Fuel Volatility Effects on Pool Fires in Compartments with Low Ventilation 低通风舱室中燃料挥发对池火的影响
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-331
O. Aljumaiah, G. Andrews, A. Jimenez, N. R. Duhoon, H. Phylaktou
Pool fires in low ventilation compartments give rise to ghosting flames and their toxic and particulate emissions were investigated for 400mm square pool fires in a 1.6 m 3 compartment with ventilation of 0.035 kg/m 2 s, air mass flow rate per pool surface area. These conditions produced global compartment equivalence ratios that were rich and this did occur for kerosene and heptane , but diesel and toluene only achieved near stoichiometric conditions. The low ventilation produced low ceiling temperatures of between 380 and 480 o C with the highest temperature for diesel and the lowest for heptane. Particulate mass emissions were highest for kerosene at 6.5 g/kgf and lowest for heptane at 0.9 g/kgf. Soot emissions were lowest for heptane at 0.2 g/kgf and highest for kerosene at 5 g/kgf. These are relatively low soot emissions, due to the low fire temperatures for near stoichiometric combustion. These low temperatures were mainly due to low combustion efficiencies with high CO and HC yields.
在低通风隔间中,池火会产生重隐火焰,研究了在1.6平方米隔间中400mm平方的池火的毒性和颗粒排放,通风为0.035 kg/m 2 s,每池表面积的空气质量流量。这些条件产生了丰富的整体隔室等效比,煤油和庚烷确实出现了这种情况,但柴油和甲苯只达到了接近化学计量的条件。低通风产生的天花板温度较低,在380至480℃之间,柴油温度最高,庚烷温度最低。煤油的微粒质量排放最高,为6.5 g/kgf,庚烷的微粒质量排放最低,为0.9 g/kgf。庚烷的烟尘排放量最低,为0.2 g/kgf,煤油最高,为5 g/kgf。这些是相对较低的烟尘排放,由于低的火温度为近化学计量燃烧。这些低温主要是由于燃烧效率低,CO和HC产率高。
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引用次数: 10
Smoke induced flow in two rooms mechanically ventilated and linked with a horizontal vent type opening 烟雾在两个机械通风的房间中产生,并与一个水平通风口型开口相连
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-486
P. Hugues, Varrall Kevin, Audouin Laurent, V. Olivier
This work deals with smoke movements between two mechanically ventilated compartments interconnected by a vent. Based on large scale fire tests, it discusses the effect of vent flow on smoke stratification. The tests concern a 97kW propane fire in a 120m 3 enclosure connected to an adjacent 170m 3 enclosure, both mechanically ventilated. The renewal rate is the varying parameter (from 2.3h -1 to 8h -1 ) typical to operating conditions in nuclear installations. The present contribution investigates the effect of the vent flow on the smoke distribution in both rooms. The temperature and species concentration distributions are analyzed. The effect of ventilation flow rate on the smoke filling and the smoke distribution in both rooms is presented. From mass balance equations, an indirect method is proposed to compute the flow rates at vent (net, upward and downward) only from gas temperatures and species concentrations in both rooms without considering direct measurements at the vent. This indirect method is compared to a direct method (computation of flow rates from spatial integration of temperature and velocity field at the vent cross section). The analysis discusses the application of this indirect method for large scale fire test experiments
这项工作涉及两个由通风口连接的机械通风隔间之间的烟雾运动。在大型火灾试验的基础上,探讨了通风口对烟气分层的影响。试验涉及在一个120平方米的封闭环境中发生97kW丙烷火,该封闭环境与相邻的170平方米封闭环境相连,两个封闭环境都是机械通风的。更新率是核设施典型运行条件的变化参数(从2.3h -1到8h -1)。本论文研究了通风口流量对两个房间烟气分布的影响。分析了温度分布和物种浓度分布。研究了通风流量对两室烟气填充和烟气分布的影响。根据质量平衡方程,提出了一种间接的方法,仅从两个房间的气体温度和物质浓度计算通风口(净、向上和向下)的流量,而不考虑通风口的直接测量。将这种间接方法与直接方法(通过通风口截面温度场和速度场的空间积分计算流量)进行了比较。分析了该间接方法在大型火灾试验中的应用
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引用次数: 5
Spectral Aspects of Bench-Scale Flammability Testing: Application to Hardwood Pyrolysis 光谱方面的实验尺度可燃性测试:应用于硬木热解
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-165
M. Chaos
The anaerobic pyrolysis of wood material used to palletize commodities is studied in a Fire Propagation Apparatus (FPA) for a range of heating conditions relevant to fires. The data collected, consisting of mass loss rate, cumulative mass loss, and surface temperature, are used to determine model-specific material properties using inverse modeling and optimization methodologies previously developed in our laboratory. However, in this study, considerable effort is placed on determining the radiation environment that characterizes the FPA tests as well as how the radiation interacts with the samples. This is done on the basis of the recognition that boundary conditions have a pronounced effect on the output of a given pyrolysis model and, thus, the optimization results. The spectral radiance from the FPA heaters as well as the absorptivity/emissivity of the material surface are measured herein. The spectral features of the surface indicate that markedly different effective emissivities and absorptivities can be exhibited by the material depending on the spectral distribution of incident radiation. These effects are included in the pyrolysis model used to extract model-specific material properties so that the optimization process can, in a sense, be decoupled from boundary conditions. Therefore, it is expected that the approach described in this study can ensure that the derived model-specific properties can be applied to practical scenarios that are characterized by radiation environments that differ from those in bench-scale test apparatuses such as the FPA.
在与火灾相关的一系列加热条件下,在火焰传播装置(FPA)中研究了用于码垛商品的木材材料的厌氧热解。收集到的数据,包括质量损失率、累积质量损失率和表面温度,用于使用我们实验室先前开发的逆建模和优化方法确定模型特定的材料特性。然而,在这项研究中,相当大的努力放在确定辐射环境的特点,FPA测试以及辐射如何与样品相互作用。这样做的基础是认识到边界条件对给定热解模型的输出有显著影响,因此对优化结果也有显著影响。本文测量了FPA加热器的光谱辐射以及材料表面的吸收/发射率。表面的光谱特征表明,入射辐射的光谱分布不同,材料的有效发射率和吸收率也不同。这些影响都包含在用于提取模型特定材料属性的热解模型中,因此在某种意义上,优化过程可以与边界条件解耦。因此,预计本研究中描述的方法可以确保推导出的模型特定特性可以应用于实际场景,这些场景的辐射环境与FPA等实验规模测试设备中的辐射环境不同。
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引用次数: 44
Fire Performance of a Full-Scale Building Subjected to Earthquake Motions: Test Specimen, Seismic Motions and Performance of Fire Protection Systems 全尺寸建筑物在地震运动下的防火性能:试样、地震运动和防火系统的性能
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-732
Jin-Kyung Kim, B. Meacham, Haejun Park, T. Hutchinson, E. Pantoli
A full-scale, five-story building specimen was erected on the Large Outdoor High Performance Shake Table (LHPOST) at the University of California, San Diego, outfitted with various nonstructural components and systems (NCSs), and subjected to a series of earthquake motion tests and compartment scale fire tests. The aim of these tests was to increase knowledge on the performance of NCS and contents during earthquakes and post-earthquake fire events. An overview of the building specimen, earthquake motions and performance of NCS critical to building fire safety are presented. Outcomes illustrate the extent of damage to compartment barriers, facade systems, egress systems and fire protection systems that could occur given different levels of ground motion, and how such damage could impact occupant life safety and emergency response during fires in earthquake-damaged buildings. Details of the postearthquake fire tests and fire performance observations are presented in an associated paper [1].
在加州大学圣地亚哥分校的大型室外高性能振动台(LHPOST)上建立了一个全尺寸的五层建筑样本,配备了各种非结构部件和系统(NCSs),并进行了一系列地震运动测试和隔室尺度火灾测试。这些测试的目的是增加对地震和震后火灾事件中NCS性能和内容的认识。概述了对建筑消防安全至关重要的建筑试样、地震运动和NCS性能。结果说明了在不同程度的地面运动下可能发生的隔间屏障、立面系统、出口系统和消防系统的损坏程度,以及这些损坏如何影响地震受损建筑物火灾时的居住者生命安全和应急响应。地震后火灾试验和火灾性能观测的详细情况见相关论文[1]。
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引用次数: 6
Comparative evaluation method for fire safety design of large storage spaces 大型仓储空间消防安全设计的比较评价方法
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-933
Zhenkun Wu, Haihang Li, Yaping He, Dechuang Zhou, Jian Wang
The design philosophy “the safety level of a performance-based designed building should not be lower than that of a prescriptive” with objectives of property protection and life safety was implemented in this paper. Three countervailing solutions were adopted to reduce fire risk in the 11664 m 2 case storage. Besides, a virtual prescriptive storage with identical length-width ratio and similar ventilation conditions as the performance-based was designed for comparison. After designing the fire development event tree and simulating six fire scenarios using FDS, the two objectives were achieved as fire severity and risk of property loss of the performance-based design storage were found to be no higher than those of the prescriptive design and ASETs were greater than RSETs for all fire scenarios.
本文贯彻了以财产保护和生命安全为目标的“性能型设计建筑的安全水平不应低于规范要求”的设计理念。采用了三种抵消方案来降低11664m2箱子存储的火灾风险。此外,还设计了一个与性能型相同长宽比、相似通风条件的虚拟规定性储层进行比较。在设计了火灾发展事件树并使用FDS模拟了6种火灾场景后,发现基于性能的设计存储的火灾严重程度和财产损失风险不高于规定性设计,并且所有火灾场景的ASETs都大于RSETs,从而实现了两个目标。
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引用次数: 1
Use of the Extreme Value Analysis in Determining Annual Probability of Exceedance for Bushfire Protection Design 极值分析在确定森林防火设计年超越概率中的应用
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1379
Grahame Douglas, Yaping He, Yang Xiang, E. Morris
Historically extreme value analysis has been used to guide human activities against many forms of natural hazards such as floods, storms, heat waves and wind. However, it has not been used for extreme fire weather assessment. This may be because forest fire danger index is a composite of differing parameters which may not be regarded as being associated with adverse fire weather individually, however, collectively may result in Extreme fire weather conditions. This paper offers new insights in the use of the extreme value analysis for the McArthur Forest Fire Danger Index (FFDI) so as to provide a scientific basis for planning, development and building construction in bushfire prone areas. The underlying principle is to use the recurrence of fire weather as measured by FFDI as the planning or design fire weather reference. The recurrence is determined by the applying the Generalised Extreme Value Analysis to local historical weather data of limited time period. The resultant distribution is fitted with an appropriate regression curve which allows the extrapolation beyond the available weather data recording period. The method is applied to a number of weather districts in the state of New South Wales of Australia. The derived FFDIs corresponding to the nominated recurrence is compared with the FFDIs based on traditional empirical methods.
历史上,极值分析已被用于指导人类活动,以应对多种形式的自然灾害,如洪水、风暴、热浪和大风。然而,它还没有被用于极端火灾天气评估。这可能是因为森林火险指数是不同参数的组合,这些参数可能不被视为单独与不利的火灾天气有关,但集体可能导致极端的火灾天气条件。本文对McArthur森林火险指数(FFDI)极值分析的应用提出了新的见解,为林火易发地区的规划、开发和建筑施工提供科学依据。基本原则是使用FFDI测量的火灾天气的重现性作为规划或设计火灾天气的参考。将广义极值分析应用于有限时间内的本地历史天气资料,确定了这种重现性。所得到的分布与一条适当的回归曲线拟合,使外推可以超越现有的天气数据记录期。该方法应用于澳大利亚新南威尔士州的一些天气区。并与基于传统经验方法的ffdi进行了比较。
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引用次数: 4
An Application Method of Free Burn HRR Data to Room Fire Scenarios 自由燃烧HRR数据在室内火灾场景中的应用方法
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-276
Yusuke Shintani, T. Nagaoka, Y. Deguchi, Kazuyo Harada
An application method of free burn heat release rate (HRR) data for a single seater sofa to predict the burning behavior in a compartment is proposed. A single seater sofa was burnt in an open environment to measure the HRR using a furniture calorimeter. The time-HRR curve was fitted with a model of burning of a cubic polyurethane block developed earlier. The model included the flame spread over horizontal, downward and lateral directions. The flame spread rates were increased if the block received radiative heat from external heat sources other than from the flame. The thermal radiation feedback from the flame, smoke layer, and heated wall surfaces was coupled with the burning model. Using the coupled model, the burning and spread rate of several sofas and a table in a small compartment was calculated and compared with experimental results. The model could reproduce the trend for the increase in HRR qualitatively. However, the time to spread to an adjacent object was not in good agreement. If the time to spread was given input to the model, other parameters such as compartment temperature and so on could be calculated with reasonable agreement.
提出了一种利用单座沙发自由燃烧放热率(HRR)数据预测车厢内燃烧行为的方法。在开放环境中焚烧单座沙发,使用家具量热计测量HRR。时间- hrr曲线与先前建立的立方聚氨酯块体燃烧模型拟合。该模型包括火焰在水平、向下和横向三个方向上的传播。如果砌块接受来自外部热源而不是火焰的辐射热,则火焰传播速率会增加。火焰、烟层和加热壁面的热辐射反馈与燃烧模型相耦合。利用耦合模型对小隔间内几张沙发和一张桌子的燃烧蔓延速度进行了计算,并与实验结果进行了比较。该模型可以定性地再现HRR增加的趋势。然而,扩散到邻近物体的时间并不一致。如果将扩散时间输入到模型中,则其他参数如车厢温度等的计算结果可以比较符合。
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引用次数: 1
Simulating Vented Maize Starch Explosions in a 236 m3 Silo 在236立方米筒仓中模拟玉米淀粉爆炸
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1469
T. Skjold
The paper describes computational fluid dynamics (CFD) simulations of a series of large-scale dust explosion experiments performed in a 236-m 3 silo. Mechanical suspensions were generated by pneumatically injecting maize starch into a 22 m high silo. The experiments included tests with injection from the bottom and from the top of the silo, but the present study only considers bottom injection. The clouds were ignited at various heights above ground. The same experiments have been simulated previously, but the current work involves an updated version of the CFD code and explores the effect of grid resolution on the simulation results. The results from the simulations are in good agreement with the experimental data, and confirm the observation that the reduced explosion pressure in long slender silos is very sensitive to ignition location. The simulation results highlight the effect of dust distribution within the silo, and reproduce the characteristic pressure oscillations, with frequency in the range 4-7 Hz, observed in some of the tests.
本文描述了在一个236米的筒仓中进行的一系列大规模粉尘爆炸实验的计算流体力学(CFD)模拟。机械悬浮液是通过将玉米淀粉气动注入22米高的筒仓而产生的。试验包括筒仓底部和筒仓顶部喷注试验,但本研究只考虑筒仓底部喷注。云层在地面的不同高度被点燃。同样的实验以前已经模拟过,但目前的工作涉及CFD代码的更新版本,并探索网格分辨率对模拟结果的影响。模拟结果与实验数据吻合较好,证实了细长筒仓的降爆压力对点火位置非常敏感。模拟结果突出了筒仓内粉尘分布的影响,重现了部分试验中观察到的特征压力振荡,频率范围在4-7 Hz。
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引用次数: 5
期刊
Fire Safety Science
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