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Combining Bromofluoropropene with Water Mist for Suppressing Deep Seated Wood Crib Fires 溴氟丙烯与细水雾复合扑灭深层木槽火灾
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1236
X. Ni, W. Chow, Shaogang Zhang, Mei Zhao, Zhongkui Zheng, Xishi Wang
Application of 2-bromo-3,3,3-trifluoropropene (BTP) with water mist in suppressing deep seated wood crib fires was reported in this paper. Performance of the combination of the two clean fire suppressants was examined by laboratory scale experiments and compared with water mist and BTP used alone. Results showed that coupling of water mist with BTP could extinguish the wood crib fires with high efficiency, in which BTP discharged first could fast extinguish the flame, and the following water mist could cool the wood surface and stop glowing combustion. As a result, a complete fire extinguishment without re-strike was achieved in short time. Furthermore, hydrogen fluoride (HF) acid gas produced in the suppression process was acceptable for the use of water mist in conjunction with BTP.
本文报道了2-溴-3,3,3-三氟丙烯(BTP)与水雾剂在扑灭深层木槽火灾中的应用。通过室内规模试验考察了两种洁净灭火剂的组合性能,并与单独使用的细水雾和BTP进行了比较。结果表明,水雾与BTP耦合能高效扑灭木槽火灾,其中先排放的BTP能快速扑灭火焰,后排放的水雾能冷却木材表面,停止发光燃烧。结果,在短时间内实现了不重燃的完全灭火。此外,抑制过程中产生的氟化氢(HF)酸性气体可用于水雾与BTP结合使用。
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引用次数: 1
Carbon monoxide production during underventilated fires in corridors 走廊通风不良时产生的一氧化碳
Pub Date : 2014-01-01 DOI: 10.3801/IAFSS.FSS.11-316
S. Ukleja, M. Delichatsios, Jianping Zhang, M. Suzanne
This work presents experimental results and non-dimensional correlations of factors and conditions affecting carbon monoxide (CO) production in corridor-like enclosure fires. Thirty eight experiments were performed in a three metre long corridor-like enclosure having a cross section 0.5 m x 0.5 m, door-like openings in the front panel and a propane gas burner located near the closed end being flushed with the floor. Measurements of carbon monoxide concentrations were performed at locations inside the enclosure and also in the exhaust duct of a hood collecting the combustion products for direct comparison. Visual observations through the opening revealed that flames were detaching from the burner for tests with global equivalence ratios (GERs) greater than one for the burning inside the enclosure (underventilated fires). After detachment, flames were travelling towards the opening then finally stayed anchored in the vicinity of the opening and emerged outside. After flames were visible outside, the concentration of CO inside the corridor increases to much higher levels owing to the recirculation of gases inside the enclosure behind the flames. A correlation between CO concentration inside the enclosure and GER was found with CO increasing initially but then decreasing for high global equivalence ratios. An additional correlation was found between the CO yield and the GER in the enclosure before the flames reached and then, anchored at the opening of the enclosure. Finally, it was found that the ratio of CO to smoke yield, yco/ys, is not constant but increases for global equivalence ratios of the enclosure greater than one in contrast to its value being constant for over ventilated conditions.
这项工作提出了实验结果和影响一氧化碳(CO)生产的因素和条件的无量纲相关性在走廊状围场火灾。38个实验是在一个3米长的走廊式封闭室内进行的,该封闭室内的横截面为0.5米× 0.5米,前面板上有类似门的开口,丙烷气体燃烧器位于封闭端附近,与地板一起冲洗。一氧化碳浓度的测量在箱体内的位置进行,也在一个引擎盖的排气管道中进行,收集燃烧产物进行直接比较。通过开口进行的目视观察显示,火焰正在从燃烧器上分离出来,用于测试整体等效比(ger)大于1的外壳内燃烧(通风不良的火灾)。分离后,火焰向洞口移动,最终停留在洞口附近,并向外蔓延。在看到外面的火焰后,由于火焰后面的外壳内气体的再循环,走廊内的CO浓度增加到更高的水平。封地内CO浓度与GER之间存在相关性,当整体等效比较高时,CO浓度先升高后降低。在火焰到达之前,在外壳内的CO产量和GER之间发现了额外的相关性,然后锚定在外壳的开口处。最后,我们发现CO与产烟量之比yco/ys不是恒定的,但当围护结构的整体等效比大于1时,它的值会增加,而在过度通风条件下,它的值是恒定的。
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引用次数: 3
An Experimental Study Evaluating the Burning Dynamics of Pitch Pine Needle Beds Using the FPA 用FPA评价沥青松针床燃烧动力学的实验研究
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1406
Jan C. Thomas, A. Simeoni, Michael R. Gallagher, N. Skowronski
Pine needle litters, a key fuel in coniferous forest systems, are highly porous fuel beds. They provide a source of continuous fuel medium that can be easily ignited and will sustain flame spread on the ground during forest fires. This work represents an experimental study that is focused on the influence of the fuel moisture content on the burning dynamics and the flammability characteristics of forest fuel beds. The FM Global Fire Propagation Apparatus was utilized to obtain time to ignition, heat release rate, total heat released and CO/CO2 concentration data. The methodologies applied in previous studies were improved with new modifications. The results were analyzed with respect to the sample’s fuel moisture content as well as other test conditions, such as airflow condition (wind), sample holder openness and external heat flux. The importance of the fuel moisture content is critical to understand as the majority of fuels present in the natural environment have elevated moisture content compared to dead dry fuel. Samples studied are representative of wet ground fuels as well as live fuels which do burn when crowning conditions develop. The results presented here are a building block for developing an experimental database that can be used to understand the influence of environmental conditions on the flammability of porous forest fuels and assess the risks that comes with a wildfire. Furthermore, the data can also be used for fire behavior model validation.
松针凋落物是针叶林系统的重要燃料,是高度多孔的燃料床。它们提供了一种连续的燃料介质,可以很容易地点燃,并在森林火灾期间维持火焰在地面上的蔓延。本文主要研究了燃料含水率对森林燃料床燃烧动力学和可燃性特性的影响。利用FM全球火焰传播仪获得点火时间、放热率、总放热量和CO/CO2浓度数据。在以往的研究中应用的方法得到了改进,并进行了新的修改。分析了样品的燃料含水率以及其他测试条件,如气流条件(风)、样品支架开度和外部热通量。理解燃料水分含量的重要性是至关重要的,因为与完全干燥的燃料相比,存在于自然环境中的大多数燃料的水分含量较高。所研究的样品既有湿地燃料的代表,也有在形成顶盖条件时燃烧的活燃料的代表。这里提出的结果是开发一个实验数据库的基础,该数据库可用于了解环境条件对多孔森林燃料可燃性的影响,并评估野火带来的风险。此外,这些数据还可以用于火灾行为模型的验证。
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引用次数: 12
Basic Experiment on the Heat Release Property of a Tsunami Fire Fueled by Debris and Fuel Oil Spilled on the Sea Surface Following Tsunami 海啸后海面散落的残骸和燃料油引发海啸火灾的放热特性基础实验
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-758
Tomoaki Nishino, Hidekazu Suzuki, T. Tsuchihashi
This paper describes an effort to model the heat release rate curve of a tsunami fire. A tsunami fire is defined as a fire that breaks out in coastal areas inundated by a tsunami following an earthquake. Tsunami fires may result in the ignition of tsunami refuge buildings. One type of tsunami fire is a fire where fuel oil spilled from tanks and an enormous amount of debris such as timber, broken houses and expanded polystyrene are burning together on the sea surface. We conducted basic combustion experiments for this type of fire using a pool with a size of 600 mm square where heat release rates were measured by varying the types of debris and the exposed surface areas of fuel oil. Furthermore, a model for heat release rate at the fully developed phase and time to the beginning of fire decay was proposed. The predictions of the proposed model are shown to be more conservative in comparison with the experimental data.
本文描述了一种模拟海啸火灾热释放率曲线的方法。海啸火灾是指在地震后被海啸淹没的沿海地区发生的火灾。海啸火灾可能导致海啸避难建筑着火。海啸火灾的一种类型是,燃料油从油箱中溢出,木材、破碎的房屋和膨胀的聚苯乙烯等大量碎片在海面上一起燃烧。我们对这种类型的火灾进行了基本的燃烧实验,使用了一个600平方毫米大小的水池,通过改变碎片的类型和燃料油的暴露表面积来测量热释放率。此外,还建立了充分发育阶段的放热速率模型和火灾衰减开始的时间模型。与实验数据相比,该模型的预测结果更为保守。
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引用次数: 3
Thermal degradation and flame-retardant properties of epoxy acrylate resins modified with a novel flame retardant containing phosphorous and nitrogen 新型含磷氮阻燃剂改性环氧丙烯酸酯树脂的热降解及阻燃性能
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-883
X. Qian, Q. Tai, Yuan Hu, R. Yuen, T. Chee
A novel monomer containing phosphorus and nitrogen (EBAPP) has been synthesized by allowing phenyl dichlorophosphate to react with ethylenediamine and 2-hydroxyethyl acrylate (HEA). The structure of EBAPP was characterized by FTIR, 1 H NMR and 31 P NMR. A series of flame-retardant resins was obtained by blending EBAPP with epoxy acrylate (EA) in different ratios and exposing to the UV-light. The flame-retardant properties of the resins were characterized by the limiting oxygen index (LOI) and microscale combustion calorimeter (MCC). The results showed that the incorporation of EBAPP into EA could improve the flame retardancy of EA. The thermal properties of the resins were investigated by thermogravimetric analysis (TGA) in air atmosphere, indicating that EBAPP could improve the char residues at high temperature. Moreover, the thermal degradation of EA/EBAPP resins were investigated by the real-time fourier transform infrared spectra (RTIR) and thermogravimetric analysis/infrared spectrometry (TGA-IR) analysis. The morphologies of the formed chars were observed by scanning electron microscopy (SEM), demonstrating that 20 wt% of EBAPP in EA exhibited the most effective flame retardancy due to the dense char layers formed during combustion.
通过二氯磷酸苯与乙二胺和丙烯酸2-羟乙酯(HEA)反应,合成了一种新型的含磷氮单体(EBAPP)。通过FTIR、1h NMR和31p NMR对EBAPP的结构进行了表征。将EBAPP与环氧丙烯酸酯(EA)按不同比例共混,并在紫外光下曝晒,制得一系列阻燃树脂。用极限氧指数(LOI)和微尺度燃烧量热仪(MCC)对树脂的阻燃性能进行了表征。结果表明,在EA中掺入EBAPP可以改善EA的阻燃性。通过热重分析(TGA)对树脂在空气气氛中的热性能进行了研究,表明EBAPP可以改善高温下的炭渣。采用实时傅里叶变换红外光谱(RTIR)和热重/红外光谱(TGA-IR)分析研究了EA/EBAPP树脂的热降解。通过扫描电镜(SEM)观察了形成的炭的形态,结果表明,在EA中,20%的EBAPP由于在燃烧过程中形成了致密的炭层,表现出最有效的阻燃性。
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引用次数: 7
Fire Testing a New Fluorine-free AFFF Based on a Novel Class of Environmentally Sound High Performance Siloxane Surfactants 基于新型环保型高性能硅氧烷表面活性剂的新型无氟AFFF的燃烧测试
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1261
Ralf Hetzer, F. Kümmerlen, K. Wirz, D. Blunk
The most effective fire extinguishing agents for pool fires are Aqueous Film Forming Foams (AFFF). Today, all available AFFF contain polyfluorinated compounds (PFC), i.e. polyfluorinated tensides (PFT), to establish the aqueous film on the surface of a burning liquid. These fluorinated compounds are persistent, potentially bio-accumulative and toxic. Therefore it is essential to find environmentally sound substitutes for these problematic surfactants. Commercially available fluorine-free foams (FfreeF) lack the ability of aqueous film formation. Although FfreeF are performing well in many situations [1,2], there are numerous scenarios where an aqueous film forming component is mandatory for fast fire extinguishing, e.g. in case of burning liquids. To achieve a well performing AFFF, a new approach is to replace the film forming PFC/PFT by siloxane surfactants. Today, siloxane surfactants are typically used in plant protective agents, in textile surface treatment and as lubricants. As the properties of commercially available siloxane surfactants are not suitable for AFFF, new siloxane surfactants were designed, synthesized and tested for their suitability as film forming ingredients in AFFF formulations. The surface activity and foaming behaviour of model formulations have been determined. Finally, one experimentally fluorine-free AFFF formulation has been subjected to fire tests. In this context a new fire test for scarcely available chemicals is presented.
最有效的灭火剂是水成膜泡沫(AFFF)。今天,所有可用的AFFF都含有多氟化合物(PFC),即多氟张力体(PFT),用于在燃烧液体表面建立水膜。这些含氟化合物具有持久性、潜在的生物蓄积性和毒性。因此,寻找这些有问题的表面活性剂的环保替代品是至关重要的。市售的无氟泡沫(FfreeF)缺乏形成水膜的能力。尽管FfreeF在许多情况下表现良好[1,2],但在许多情况下,水成膜成分是快速灭火的必要条件,例如在燃烧液体的情况下。为了获得性能良好的AFFF,一种新的方法是用硅氧烷表面活性剂取代成膜的PFC/PFT。今天,硅氧烷表面活性剂通常用于植物保护剂,纺织品表面处理和润滑剂。由于市面上现有的硅氧烷表面活性剂的性能不适合用于AFFF,设计、合成了新型硅氧烷表面活性剂,并对其作为AFFF成膜成分的适用性进行了测试。确定了模型配方的表面活性和发泡行为。最后,一种实验性无氟AFFF配方已进行了火灾试验。在这种情况下,提出了一种新的对稀有化学品的防火试验。
{"title":"Fire Testing a New Fluorine-free AFFF Based on a Novel Class of Environmentally Sound High Performance Siloxane Surfactants","authors":"Ralf Hetzer, F. Kümmerlen, K. Wirz, D. Blunk","doi":"10.3801/iafss.fss.11-1261","DOIUrl":"https://doi.org/10.3801/iafss.fss.11-1261","url":null,"abstract":"The most effective fire extinguishing agents for pool fires are Aqueous Film Forming Foams (AFFF). Today, all available AFFF contain polyfluorinated compounds (PFC), i.e. polyfluorinated tensides (PFT), to establish the aqueous film on the surface of a burning liquid. These fluorinated compounds are persistent, potentially bio-accumulative and toxic. Therefore it is essential to find environmentally sound substitutes for these problematic surfactants. Commercially available fluorine-free foams (FfreeF) lack the ability of aqueous film formation. Although FfreeF are performing well in many situations [1,2], there are numerous scenarios where an aqueous film forming component is mandatory for fast fire extinguishing, e.g. in case of burning liquids. To achieve a well performing AFFF, a new approach is to replace the film forming PFC/PFT by siloxane surfactants. Today, siloxane surfactants are typically used in plant protective agents, in textile surface treatment and as lubricants. As the properties of commercially available siloxane surfactants are not suitable for AFFF, new siloxane surfactants were designed, synthesized and tested for their suitability as film forming ingredients in AFFF formulations. The surface activity and foaming behaviour of model formulations have been determined. Finally, one experimentally fluorine-free AFFF formulation has been subjected to fire tests. In this context a new fire test for scarcely available chemicals is presented.","PeriodicalId":12145,"journal":{"name":"Fire Safety Science","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85277238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 37
Experimental Study on Suppression of Methane Explosion Containing Obstacles with Ultra-fine Water Mist 超细水雾抑制含障碍物甲烷爆炸的实验研究
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-1247
H. Xue, Y. Li, P. Zhu, W. Qin, Xishi Wang
The effects of obstacles on methane explosion inside a narrow space and its suppression by ultra-fine water mist are investigated experimentally. Two PCB pressure transducers and two E12-1-C-U fast response thermocouples are used to obtain the explosion pressure and temperature, respectively. A Fastcam Ultima APX high speed video camera is used to visualize the process of methane explosion with the influence of obstacles and ultra-fine water mist. The results show that the explosion would be strengthened by the obstacles, while the further strengthening occurs to the cases where the obstacles are farther from the ignition electrode. In addition, the more the obstacles are, the stronger the explosion strengthening will be. The reinforcement effect on gas explosion of the square ring is a little stronger than the column one. The suppression of methane gas explosion containing obstacles with ultra-fine water mist is very effective.
实验研究了障碍物对狭窄空间内甲烷爆炸的影响以及超细水雾对甲烷爆炸的抑制作用。使用两个PCB压力传感器和两个E12-1-C-U快速响应热电偶分别获得爆炸压力和温度。利用Fastcam Ultima APX高速摄像机,对障碍物和超细水雾影响下的甲烷爆炸过程进行了可视化研究。结果表明:障碍物的存在会增强爆炸强度,障碍物离点火电极越远,爆炸强度越强;障碍物越多,爆炸强化效果越强。方圈对瓦斯爆炸的加固作用略强于柱圈。超细水雾对含障碍物的甲烷瓦斯爆炸的抑制效果非常好。
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引用次数: 1
Ignition temperature and surface emissivity of heterogeneous loosely packed materials from pyrometric measurements 热法测量非均质松散堆积材料的点火温度和表面发射率
Pub Date : 2014-01-01 DOI: 10.3801/IAFSS.FSS.11-262
B. Dlugogorski, S. Hirunpraditkoon, E. Kennedy
This paper reports the ignition temperature and emissivity of heterogeneous materials characterised by high void fraction of between 0.92 and 0.94 and composed of loose particles of shredded grass and paper, planed wood, shredded plastic bags, as well as sugar and bread, with about 95 % of the particles (by mass) of less than 50 mm in size. These materials reflect a typical composition and void fraction of so-called refusederived fuels (RDF), which are obtained from municipal solid waste, then densified and combusted for energy recovery. An infrared pyrometer, with a spectral response range of 8 to 14 µm, recorded the surface temperature of the surrogate RDF, prior to the onset of the flaming combustion, in a stand alone mass loss calorimeter operated at 20 and 45 kW m -2 . The overlapping spectral ranges of the pyrometer and the radiator heater necessitated the development of a practical methodology to obtain the actual surface temperature from the apparent measurements, which included the effect of the reflected radiation. In addition to surface temperatures (292 ‐ 325 °C for 20 kW m -2 and 250 ‐ 294 °C for 45 kW m -2 ), in this contribution, we estimate the actual emissivities (0.95 ‐ 0.98) of the materials from the intensity of the reflected radiation.
本文报道了一种非均相材料的点火温度和发射率,其特点是孔隙率高,介于0.92和0.94之间,由碎草和纸、刨花、碎塑料袋、糖和面包等松散颗粒组成,其中约95%的颗粒(按质量计)尺寸小于50mm。这些材料反映了所谓的垃圾衍生燃料(RDF)的典型组成和空隙部分,这些燃料是从城市固体废物中获得的,然后致密化和燃烧以回收能量。红外高温计,光谱响应范围为8到14µm,记录了在火焰燃烧开始之前,替代RDF的表面温度,在一个独立的质量损失量热计中工作在20和45 kW m -2。高温计和辐射加热器的光谱范围重叠,需要开发一种实用的方法,从表观测量中获得实际表面温度,其中包括反射辐射的影响。除了表面温度(20 kW m -2时292 ~ 325°C, 45 kW m -2时250 ~ 294°C)外,我们还通过反射辐射强度估算了材料的实际发射率(0.95 ~ 0.98)。
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引用次数: 4
Experimental Study on the Characteristics of Temperature Field of Fire Room under Stack Effect in a Scaled High-rise Building Model 高层建筑模型烟囱效应下火灾室内温度场特性的实验研究
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-419
W. Shi, J. Ji, Jinhua Sun, S. Lo, Linjie Li, X. Yuan
A set of experiments were conducted in a scaled building model with 12 floors to study on the temperatures of fire room under stack effect in a high-rise building. The fuel mass loss rate, radiant flux, heat flux and temperatures in the atria and fire room at the first floor were experimentally investigated. The flames of pool fires in room are tilted towards the staircase under the air flow induced by the stack effect. The mass loss rate of fuel is influenced slightly by the position of window opened in the staircase, while the temperature distribution in the atria and fire room is different in the opened and closed staircases. The hot smoke temperatures in the atria and fire room at the first floor increase with an increasing pool size. The upper hot smoke temperatures in the atria are higher than those in the fire room in cases with an opened staircase. Compared different positions of the window opened in the staircase, it can be found that the upper hot smoke temperatures in the atria in cases with the 3 rd floor window opened are the highest due to the weaker stack effect. In the closed staircases, the upper hot smoke temperatures in the fire room are great higher than these in the atria at the first floor. Besides, the radiant flux and heat flux of the left sidewalls of staircase in an opened staircase are higher than those in a closed staircase, due to the tilted flame. The results obtained in this paper may be used for the safety design of the room in high-rise buildings.
在12层的比例建筑模型中,对高层建筑烟囱效应下的火灾室内温度进行了研究。实验研究了一楼中厅和火灾室内的燃料质量损失率、辐射通量、热流密度和温度。室内池火的火焰在层叠效应的气流作用下向楼梯倾斜。楼梯开窗位置对燃料质量损失率影响较小,而楼梯开窗和楼梯闭窗对中庭和火室温度分布影响较大。一楼的中庭和火室的热烟温度随着泳池大小的增加而增加。在开放式楼梯的情况下,中庭的上层热烟温度高于防火室内的温度。通过对比不同位置的楼梯开窗,可以发现3楼开窗时,由于烟囱效应较弱,中庭上层热烟温度最高。在封闭的楼梯间中,上层火室的热烟温度比一楼中庭的温度要高得多。此外,由于火焰倾斜,开放式楼梯左侧壁的辐射通量和热流密度比封闭式楼梯高。本文的研究结果可用于高层建筑房间的安全设计。
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引用次数: 2
Finding the Probability of Doors Being Open Using a Continuous Position Logger 使用连续位置记录器寻找门打开的概率
Pub Date : 2014-01-01 DOI: 10.3801/iafss.fss.11-969
K. Frank, M. Spearpoint, S. Weddell
Data for the probability that a doors are open or closed in the event of a fire is sparse. The literature only presents a snap-shot rather than how the position of the door has changed over time. This paper describes the development of a low-cost, unobtrusive logging device that can continuously monitor the position of a door for extended periods. The devices were used to record 180 days of data from 52 doors located in different types of sleeping occupancies: hotels, apartments, dormitories and rest homes. Results were obtained for the probability that doors were open during day-time and night-time; and also during weekdays and weekends. Overall a probability distribution for the fraction of time that a door was found to be open is an inverse Gaussian function with mean µ = 0.104 and shape factor l = 0.0117.
火灾发生时门打开或关闭的概率数据很少。文献只提供了一个快照,而不是门的位置如何随着时间的推移而变化。本文介绍了一种低成本、不显眼的测井设备的开发,该设备可以长时间连续监测门的位置。这些设备被用来记录180天内52扇门的数据,这些门位于不同类型的睡眠场所:酒店、公寓、宿舍和养老院。得到了门在白天和夜间打开的概率;工作日和周末也是如此。总的来说,门被发现打开的时间的概率分布是一个逆高斯函数,平均值µ= 0.104,形状因子l = 0.0117。
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引用次数: 4
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Fire Safety Science
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