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Electrocaloric properties of Sr and Sn doped BCZT lead-free ceramics Sr和Sn掺杂BCZT无铅陶瓷的电热性能
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-08-01 DOI: 10.1051/epjap/2020200165
S. Patel, Manish Kumar
In the present work, the electrocaloric (EC) effect in lead-free Sr and Sn doped (Ba0.85 Ca0.075 Sr0.075 )(Zr0.1 Ti0.88 Sn0.02 )O3 ceramic prepared by solid-state method has been investigated. The phase purity and pure perovskite phase formation with Sr and Sn doping is confirmed by X-ray diffraction. The adiabatic temperature change ΔT (due to the EC effect), entropy change (ΔS) and refrigeration capacity (RC) are estimated under various electric fields. The maximum peak values of ΔT, ΔS and RC are found as 1.5 K, 1.8 J/kg.K and 2.75 J/kg, respectively under the applied electric field of 33 kV/cm at 305 K. It is also observed that the ΔT, ΔS and RC decreases with an increase in applied temperature. Moreover, the estimated values of EC properties are significantly high which indicates that fabrication of Sr and Sn doped lead-free ceramics can be advantageous for EC applications.
本文研究了固态法制备无铅Sr和Sn掺杂(Ba0.85 Ca0.075 Sr0.075)(Zr0.1 Ti0.88 Sn0.02)O3陶瓷的电热效应。通过x射线衍射证实了Sr和Sn掺杂后的相纯度和纯钙钛矿相的形成。计算了不同电场作用下的绝热温度变化ΔT (EC效应)、熵变ΔS和制冷量RC。ΔT、ΔS和RC的最大峰值分别为1.5 K、1.8 J/kg。在305k、33kv /cm的外加电场作用下,分别为K和2.75 J/kg。随着温度的升高,材料的ΔT、ΔS和RC均呈下降趋势。此外,电化学性能的估计值也非常高,这表明制备Sr和Sn掺杂的无铅陶瓷对电化学应用是有利的。
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引用次数: 3
Tribological properties of hydrogenated boron carbide (BxC:Hy) thin films on stainless steel deposited by RF-PECVD technique RF-PECVD沉积不锈钢表面氢化碳化硼(BxC:Hy)薄膜的摩擦学性能
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-08-01 DOI: 10.1051/epjap/2020190323
A. Bute, Neelima Khare, Sanjiv Kumar, D. Bhattacharya, Kulwant Singh, A. Sahu, N. Chand, S. Sinha
This study narrates the findings regarding investigation of tribological properties of Bx C:Hy thin films deposited by Radio Frequency Plasma Enhanced Chemical Vapour Deposition (RF-PECVD) technique. To study tribological properties, two sets of films were prepared with variation in composition and thickness by tuning deposition parameters. Tribological properties were studied in ambience for three different applied vertical load values (5, 10 and 15 N). Lower self-bias (−75 V) seems advantageous for synthesis of Bx C:Hy films offering superior hardness, lubricity and wear resistance in tribologically stressed conditions. For a given composition, the film with the highest thickness (∼3 μm) exhibited better friction and wear resistance, offering lowest co-efficient of friction (COF) ∼0.23 for 5 N load and specific wear rate of 2.56 × 10−5 mm3 /Nm for 10 N load. Lower self-bias during deposition (−75 V) seems advantageous for synthesis of Bx C:Hy films having high hardness (∼2800 HK) and excellent Co-efficient of friction (COF).
本文叙述了射频等离子体增强化学气相沉积(RF-PECVD)技术沉积Bx C:Hy薄膜摩擦学性能的研究结果。为了研究其摩擦学性能,通过调整沉积参数制备了两组不同成分和厚度的薄膜。在环境中研究了三种不同的垂直载荷值(5、10和15 N)下的摩擦学性能。较低的自偏置(- 75 V)似乎有利于合成Bx C:Hy薄膜,在摩擦应力条件下具有优异的硬度、润滑性和耐磨性。对于给定的成分,厚度最高(~ 3 μm)的薄膜具有更好的摩擦和耐磨性,在5 N负载下具有最低的摩擦系数(COF) ~ 0.23,在10 N负载下具有2.56 × 10−5 mm3 /Nm的比磨损率。沉积过程中较低的自偏置(−75 V)似乎有利于合成具有高硬度(~ 2800 HK)和优异摩擦系数(COF)的Bx C:Hy薄膜。
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引用次数: 1
Using fine-structured gratings to implement mid-infrared dual-band absorbers 采用精细结构光栅实现中红外双波段吸收器
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-08-01 DOI: 10.1051/epjap/2020200087
Xin He, Jinliang Jie, Junbo Yang, Yunxin Han, Sen Zhang
A dual narrowband absorber operating at mid-infrared (mid-IR) frequencies was numerically investigated. The structure consists of a fine-structured silicon grating on a gold film. Each unit cell of the fine-structured silicon grating is composed of two different silicon bars. When illuminated by a transverse-magnetic (TM) polarized plane wave, the absorber will create two absorption bands. At normal incidence, the two absorption bands have respective peak wavelengths of ∼3.864 µm and ∼3.994 µm, and respective bandwidths of ∼28 nm and ∼36 nm. The level of absorption can be higher than 0.998. It is shown that the two absorption bands are related to different silicon bars in each unit cell. Moreover, the physical origin of the two absorption bands is attributed to the different surface-plasmon-polariton (SPP) modes excited in the absorber.
对工作于中红外(中红外)频率的双窄带吸收器进行了数值研究。该结构由金薄膜上的结构精细的硅光栅组成。细结构硅光栅的每个单元格由两个不同的硅棒组成。当被横磁(TM)极化平面波照射时,吸收器将产生两个吸收带。在正常入射下,两个吸收带的峰值波长分别为~ 3.864µm和~ 3.994µm,带宽分别为~ 28 nm和~ 36 nm。吸收水平可高于0.998。结果表明,两个吸收带与每个晶胞内不同的硅棒有关。此外,两个吸收带的物理起源归因于吸收器中激发的表面等离子体极化子(SPP)模式的不同。
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引用次数: 2
Sensitivity of germanium content on growth conditions of silicon-germanium nanoparticles prepared in nonthermal capacitively-coupled plasmas 锗含量对非热容耦合等离子体中制备的硅锗纳米颗粒生长条件的敏感性
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-08-01 DOI: 10.1051/epjap/2020190302
Md. Seraj Uddin, C. Vijayan, J. Rath
We report on the synthesis of Si1−x Ge x alloy nanocrystals by very-high-frequency plasma-enhanced chemical vapor deposition (VHF PECVD) technique at different silane to germane gas flow ratio (R) in a mixture of (H2 +Ar) dilution gas and H2 dilution gas alone. TEM, SAED, EDS studies and HAADF-STEM mapping of the samples were done to investigate the NCs' size, crystallinity and distribution of Si and Ge in the Si1−x Ge x alloy NCs. The average estimated size of the NCs in all the samples are in the order of exciton Bohr radius of Ge (24.3 nm), thereby indicating the probability of good quantum confinement. The alloy nature of NCs was confirmed in Raman study. The content of Ge in SiGe NCs was evaluated from Raman spectra which show a direct correlation with the fraction of hydrogen flow in the dilution gas mixture.
本文报道了在不同硅烷/锗气体流量比(R)下,在(H2 +Ar)稀释气体和单独的H2稀释气体中,采用甚高频等离子体增强化学气相沉积(VHF PECVD)技术合成Si1−x Ge x合金纳米晶体。通过对样品的TEM、SAED、EDS和HAADF-STEM图谱分析,研究了Si1−x Ge x合金NCs中Si和Ge的尺寸、结晶度和分布。所有样品中NCs的平均估计尺寸都在激子玻尔半径为Ge (24.3 nm)的数量级,从而表明了良好量子约束的可能性。拉曼实验证实了纳米碳化物的合金性质。用拉曼光谱测定了锗纳米碳化物中Ge的含量,结果表明,锗纳米碳化物中Ge的含量与稀释气体中氢气流动的比例直接相关。
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引用次数: 1
Application of artificial neuronal networks in extracting parameters of solar cells 人工神经网络在太阳能电池参数提取中的应用
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-08-01 DOI: 10.1051/epjap/2020200109
M. Khalis, R. Masrour
This paper presents a new neural network-based approach that aims to use the back propagation multilayer perceptual (MLP) propagation algorithm to improve the extraction of parameters from a solar cell based on the single-diode model from the experimentally measured characteristic I (V ). The I (V ) current function as a model function for the neural network, is used the Lambert function W and I can be expressed as an explicit function. The main five parameters of interest of the function I (V ) are the photocurrent, I ph , the saturation current in inverse diode, I 0 , the ideality factor of the diode, n , the resistance in series, RS and shunt resistance, R Sh . We have used the Matlab to find the five parameters of the cell. To verify the proposed approach, we chose two different solar cells made of mono- and polycrystalline silicon. The comparison between the measured values and the results of the proposed model shows great precision. Finally, the values found of the five parameters by our approach are compared with those found by the method of least squares (MLS).
本文提出了一种新的基于神经网络的方法,旨在使用反向传播多层感知(MLP)传播算法来改进基于单二极管模型的太阳能电池参数从实验测量的特性I (V)中提取的方法。I (V)电流函数作为神经网络的模型函数,使用朗伯特函数W, I可以表示为显式函数。函数I (V)主要关心的五个参数是光电流I ph、反向二极管饱和电流I 0、二极管理想因数n、串联电阻RS和并联电阻R Sh。我们使用Matlab找到了电池的五个参数。为了验证所提出的方法,我们选择了由单晶硅和多晶硅制成的两种不同的太阳能电池。实测值与模型计算结果的比较表明,该模型具有较高的精度。最后,将该方法得到的5个参数值与最小二乘法得到的值进行了比较。
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引用次数: 4
Spin transition properties of metal (Zn, Mn) diluted Fe(phen)2(NCS)2 spin-crossover thin films 金属(Zn, Mn)稀释Fe(phen)2(NCS)2自旋交叉薄膜的自旋跃迁特性
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-08-01 DOI: 10.1051/epjap/2020200056
S. Saha, S. Mandal
We report here the effect of metal (Zn and Mn) dilution on the spin transition of Fe(phen)2 (NCS)2 thin film spin-crossover (SCO) complex. The SCO complexes are deposited on glass and indium-tin-oxide (ITO) coated glass by dip-coating technique. The growth of the films is clearly confirmed by the appearance of the sharp optical absorption band at 521–540 nm corresponding to 1 A1g to 1 T1g ligand field absorption of the SCO complex. Although the microstructure of the films remains unaffected by metal dilution, substitution of Fe(II) by either Zn(II) (diamagnetic) or Mn(II) (paramagnetic) results in subtle changes in the bonding environment of the host metal as inferred form X-ray diffraction and Raman studies. The high spin to low spin (or vice versa) transition can be triggered either by electric field or magnetic field as revealed in the measured current (I )–voltage (V ) profile or magnetization data of the films. The data further shows the effect of metal dilution on the spin transition temperatures(T1/2 ), produced hysteresis loop width and loop area, which are the crucial parameter for fabricating spin-based room temperature switching devices.
本文报道了金属(Zn和Mn)稀释对Fe(phen)2 (NCS)2薄膜自旋交叉(SCO)配合物自旋跃迁的影响。采用浸涂技术将SCO配合物沉积在玻璃和氧化铟锡(ITO)镀膜玻璃上。在521-540 nm处出现的尖锐光学吸收带,对应于SCO配合物的1a1g到1t1g配体场吸收,清楚地证实了薄膜的生长。虽然薄膜的微观结构不受金属稀释的影响,但从x射线衍射和拉曼研究中可以推断,用Zn(II)(抗磁性)或Mn(II)(顺磁性)取代Fe(II)会导致宿主金属的键合环境发生微妙变化。高自旋到低自旋(或相反)的转变可以由电场或磁场触发,如测量的电流(I) -电压(V)分布或薄膜的磁化数据所示。数据进一步表明,金属稀释对自旋转变温度(T1/2)、产生的滞后环宽度和环路面积的影响,是制作基于自旋的室温开关器件的关键参数。
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引用次数: 3
Study of femtosecond laser pulse induced shockwave in aluminum-coated dielectric target 飞秒激光脉冲在镀铝介质靶中的诱导冲击波研究
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-07-01 DOI: 10.1051/epjap/2020190014
Chuliang Zhou, Y. Bai, Zhongpeng Li, Yingying Ding, Haiyi Sun, Ye Tian
The influence of the preplasma on laser induced shockwave in the laser and aluminum-coated planar dielectric target interaction at vacuum has been investigated with the shadowgraphy method. While the laser irradiate on the aluminum-coated dielectric target at intensity of about 1017  W/cm2 , the metallic layers absorb laser energy, evaporate and ionize into plasma, it is verified that the scale length of laser-produced plasma is dramatically dependent on the contrast ratio of femtosecond-laser while the main laser pulse energy is almost kept. The characteristics of laser induced shock wave in nanosecond time scale were studied. In the nanosecond time scale, shock wave is only observed in the case of relatively short plasma scale length. This result can be explained by the dissipation of the shock wave during its propagation in the preplasma. In addition, we performed numerical simulation with MULTI2D to get an insight into the propagation of shock wave in the overdense plasma [R. Ramis, J. Meyer-ter-Vehn, and J. Ramirez, Comput. Phys. Commun. 180 , 977 (2009)].
采用影影法研究了真空条件下激光与镀铝平面介质靶相互作用中预等离子体对激光诱导冲击波的影响。当激光以约1017 W/cm2的强度照射在镀铝介质靶上时,金属层吸收激光能量,蒸发并电离成等离子体,验证了激光产生的等离子体的尺度长度与飞秒激光的对比度有很大的关系,而主激光脉冲能量基本保持不变。研究了激光诱导激波在纳秒时间尺度上的特性。在纳秒时间尺度下,只有在相对较短的等离子体尺度长度下才能观察到激波。这一结果可以用激波在预等离子体中传播过程中的耗散来解释。此外,我们利用MULTI2D进行了数值模拟,以深入了解激波在过密等离子体中的传播[R]。Ramis, J. Meyer-ter-Vehn和J. Ramirez,《计算机》。理论物理。普通。180,977(2009)]。
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引用次数: 1
Design, fabrication and characterization of an electrical-explosively actuated MEMS flyer-accelerator inserted with parallel bridge foils 插入平行桥箔的电爆炸驱动MEMS飞行加速器的设计、制造和表征
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-07-01 DOI: 10.1051/epjap/2020200042
Zhi Yang, Guoqiang Zheng, Peng Zhu, Cong Xu, Qiu Zhang, Ke Wang, R. Shen
Parallel bridge foils (PBF) with four strip foils, which is derived from traditional single bridge foil (SBF), was designed to study the effect of convergence and collision of plasmas and shock waves on driving flyer. Firstly, Electro-thermal simulation of PBF was performed to analyze temperature distribution before melting, which predicted the synchronous burst characteristic of PBF. Subsequently, a capacitor discharging circuit was designed to initiate bridge foils, results indicated PBF reached higher burst power in shorter time compared with SBF due to better matching between PBF and the test circuit. The flow fields of electrical explosion of bridge foils were photographed by ultra-high-speed camera, which displayed PBF almost burst simultaneously. Moreover, PBF had wider and brighter flow field visualization than SBF owing to convergence and superposition of plasma beams. Most importantly, flyer-accelerators inserted with bridge foils were prepared by MEMS technology, and comparative analysis from PDV revealed MEMS flyer-accelerator inserted with PBF had access to better velocity performances, compared with that inserted with SBF. For instance, PBF flyer-accelerator spent mere 168 ns to 2325 m/s at 900 V/0.22 µF, but SBF flyer-accelerator took 335 ns to 1073 m/s. Finally, we proposed a mathematical model for explaining the enhancement effect of flyer velocity, which to some extent showed good agreement with experimentation.
为研究等离子体与激波的汇聚和碰撞对驱动飞片的影响,设计了由传统单桥箔(SBF)演变而来的四条带平行桥箔(PBF)。首先,对PBF进行电热模拟,分析熔点前的温度分布,预测PBF的同步爆裂特性。随后,设计了电容放电电路启动桥接箔,结果表明,由于PBF与测试电路的匹配更好,PBF比SBF在更短的时间内获得更高的突发功率。利用超高速摄像机对桥膜电爆炸流场进行了拍摄,发现桥膜电爆炸流场几乎同时发生爆炸。此外,由于等离子体束的汇聚和叠加,PBF比SBF具有更宽、更亮的流场显示。最重要的是,利用MEMS技术制备了插入桥膜的飞行加速器,并通过PDV进行了对比分析,结果表明,与插入SBF相比,插入PBF的MEMS飞行加速器具有更好的速度性能。例如,在900 V/0.22µF时,PBF飞振加速器的速度仅为168 ns至2325 m/s,而SBF飞振加速器的速度为335 ns至1073 m/s。最后,我们提出了一个数学模型来解释飞片速度的增强效应,该模型与实验结果在一定程度上吻合。
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引用次数: 7
Performance of a rf neutralizer operating with noble gases and iodine 与惰性气体和碘一起工作的射频中和器的性能
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-07-01 DOI: 10.1051/epjap/2020190213
Patrick Dietz, F. Becker, K. Keil, K. Holste, P. Klar
Neutralization of the extracted ion beam is a mandatory task for any ion thruster based space mission. The required lifetimes are in the order of ten thousand hours. This requirement is fulfilled by hollow cathodes operating with xenon, but has not been demonstrated for operation with iodine yet. Furthermore, the power consumption as well as the demand on mass flow should be kept as low as possible. Since the halogen iodine seems to be a viable alternative to xenon for operating ion thrusters, a suitable neutralizer concept that can operate with the corrosive gas for the time periods stated above is required. We propose to use a neutralizer based on an inductively coupled rf discharge as alternative to hollow cathodes. We studied the performance of a prototypical neutralizer operating with iodine as well as the inert gases xenon and krypton and compared the experimental studies with the results of global modeling.
对提取的离子束进行中和是任何基于离子推进器的太空任务的强制性任务。所需的寿命约为1万小时。与氙一起工作的空心阴极可以满足这一要求,但尚未证明与碘一起工作。此外,功耗和对质量流量的需求应尽可能低。由于卤素碘似乎是氙操作离子推进器的可行替代品,因此需要一种合适的中和剂概念,可以在上述时间段内与腐蚀性气体一起操作。我们建议使用基于电感耦合射频放电的中和器来替代空心阴极。我们研究了与碘以及惰性气体氙和氪一起工作的原型中和剂的性能,并将实验研究结果与全局模拟结果进行了比较。
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引用次数: 4
Mechanism of broadened phase transition temperature range in LaFeCoSiC compounds prepared upon high-pressure annealing 高压退火制备的LaFeCoSiC化合物相变温度范围变宽的机理
IF 1 4区 物理与天体物理 Q3 Physics and Astronomy Pub Date : 2020-07-01 DOI: 10.1051/epjap/2020200037
Zhengming Zhang
The cobalt-carbon co-doped NaZn13 -type compound LaFe10.95 Co0.65 Si1.4 C0.15 (LFCSC) is one of the most promising candidates for room-temperature working substance in magnetic refrigerator due to its many excellent properties such as large reversible entropy, low cost, and short annealing time. However, owing to the narrow temperature regions of magnetic phase transition in LFCSC, the operation-temperature window for magnetic refrigeration is limited, which restricts its actual application to some extends. In this paper, it is shown that the application of high-pressure to LFCSC during annealing can tailor atomic environment and magnetic transition, which leads to a strongly expanded phase transition temperature range in LFCSC. This broadening behavior can be well understood by importing the magnetoelastic interaction of localized magnetic moments into a microscopic model. The refrigeration performance of the high-pressure annealed sample with wide phase transition temperature range is enhanced according to the relative cooling power (RCP). On the contrary, temperature averaged entropy change (TEC) exhibits a weakened value in the high-pressure annealed sample, which suggests that the magnetic cooling performance could not be effectively improved by simply expanding the phase transition temperature range in the second-order phase transition materials. However, high-pressure annealing would be helpful to the magnetic refrigeration performance for the first-order phase transition materials.
钴碳共掺杂的NaZn13型化合物LaFe10.95 Co0.65 Si1.4 C0.15 (LFCSC)具有可逆熵大、成本低、退火时间短等优点,是磁性冰箱室温工作材料中最有前途的候选材料之一。然而,由于LFCSC的磁相变温度区域较窄,限制了磁制冷的工作温度窗口,在一定程度上制约了其实际应用。研究表明,在LFCSC退火过程中施加高压可以调整原子环境和磁转变,从而使LFCSC的相变温度范围大大扩大。通过将局域磁矩的磁弹性相互作用引入微观模型,可以很好地理解这种展宽行为。宽相变温度范围的高压退火试样的制冷性能随相对冷却功率(RCP)的增大而增大。温度平均熵变(TEC)在高压退火样品中呈减弱趋势,说明单纯扩大二级相变材料的相变温度范围不能有效提高磁冷却性能。高压退火有利于提高一阶相变材料的磁致冷性能。
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引用次数: 3
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European Physical Journal-applied Physics
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