The Kutch Basin of western India exposes one of the most complete, fossiliferous marine Cenozoic sedimentary sequences of India. Precise depositional ages of these sequences are of great importance in the reconstruction of palaeoclimatic and palaeobiogeographic histories of the basin. Due to the poorly constrained foraminiferal biostratigraphic ages, we conducted high-resolution 87Sr/86Sr chronology of the various fossiliferous, stratigraphically continuous units of Oligocene–Miocene strata in Kutch Basin. Besides updating the previously determined 87Sr/86Sr chronology, we report new numerical depositional ages for Oligocene–Miocene formations and members, and correlated these ages to the existing biostratigraphic schemes. The new 87Sr/86Sr data indicates a depositional age range between 28.64 + 0.29/-1.11 and 23.51 + 1.53/-1.85 Ma (Rupelian-Chattian) for the Maniyara Fort Formation, between 23.07 + 0.94/1.39 and 18.09 + 0.24/-0.57 Ma (Chattian-Burdigalian) for the Khari Nadi Formation, and between 15.11 + 0.56/-2.87 and 12.29 + 1.22/-1.9 Ma (Langhian-Serravallian) for the Chhasra Formation. The sedimentation rate, determined through numerical ages derived from 87Sr/86Sr, indicates an increase in sedimentation for the Khari Nadi (0.23 ± 0.04 cm/kyr) and Chhasra (0.12 ± 0.04 cm/kyr) formations, likely related to uplift of the Himalaya-Tibetan plateau and intensification of the Indian Summer Monsoon. The bulk sediment element ratios (V/Ni, Ni/Co and V/Cr) indicate oxic to suboxic palaeo-redox conditions during deposition of the Oligocene–Miocene successions of the basin. Based on new and updated 87Sr/86Sr chronology, the depositional environments and sedimentation rates of the Kutch sequence are correlated with changes in sea-level, sedimentation rates in the Arabian Sea and Bay of Bengal, and the global climate changes across the Oligocene–Miocene boundary.
{"title":"Strontium isotope stratigraphy of marine Oligocene–Miocene sedimentary successions of Kutch Basin, western India","authors":"Rimjhim Singh, Ravikant Vadlamani, Sunil Bajpai, Abhayanand Singh Maurya","doi":"10.1002/gj.4961","DOIUrl":"10.1002/gj.4961","url":null,"abstract":"<p>The Kutch Basin of western India exposes one of the most complete, fossiliferous marine Cenozoic sedimentary sequences of India. Precise depositional ages of these sequences are of great importance in the reconstruction of palaeoclimatic and palaeobiogeographic histories of the basin. Due to the poorly constrained foraminiferal biostratigraphic ages, we conducted high-resolution <sup>87</sup>Sr/<sup>86</sup>Sr chronology of the various fossiliferous, stratigraphically continuous units of Oligocene–Miocene strata in Kutch Basin. Besides updating the previously determined <sup>87</sup>Sr/<sup>86</sup>Sr chronology, we report new numerical depositional ages for Oligocene–Miocene formations and members, and correlated these ages to the existing biostratigraphic schemes. The new <sup>87</sup>Sr/<sup>86</sup>Sr data indicates a depositional age range between 28.64 + 0.29/-1.11 and 23.51 + 1.53/-1.85 Ma (Rupelian-Chattian) for the Maniyara Fort Formation, between 23.07 + 0.94/1.39 and 18.09 + 0.24/-0.57 Ma (Chattian-Burdigalian) for the Khari Nadi Formation, and between 15.11 + 0.56/-2.87 and 12.29 + 1.22/-1.9 Ma (Langhian-Serravallian) for the Chhasra Formation. The sedimentation rate, determined through numerical ages derived from <sup>87</sup>Sr/<sup>86</sup>Sr, indicates an increase in sedimentation for the Khari Nadi (0.23 ± 0.04 cm/kyr) and Chhasra (0.12 ± 0.04 cm/kyr) formations, likely related to uplift of the Himalaya-Tibetan plateau and intensification of the Indian Summer Monsoon. The bulk sediment element ratios (V/Ni, Ni/Co and V/Cr) indicate oxic to suboxic palaeo-redox conditions during deposition of the Oligocene–Miocene successions of the basin. Based on new and updated <sup>87</sup>Sr/<sup>86</sup>Sr chronology, the depositional environments and sedimentation rates of the Kutch sequence are correlated with changes in sea-level, sedimentation rates in the Arabian Sea and Bay of Bengal, and the global climate changes across the Oligocene–Miocene boundary.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140596101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiao Cui, Gen-Hou Wang, Shou-Ting Zhang, Jonathan Atuquaye Quaye, Jie Zhou, Ying-Jie Zhang, Wen-Pan Cen, Xi Gao
The tectonic deformation reaction to multi-plate convergence in the northern Guizhong Depression, as well as its geodynamic process, remain poorly understood. Two phases of intracontinental deformation are identified using field geological investigations, paleo-stress inversion and seismic reflection sections: (1) early NE–SW-directed compression during the Middle Triassic to Early Jurassic; (2) later NW–SE-directed compression during the Middle Jurassic to Early Cretaceous. The reconstruction of paleo-stress provides robust constraints on the spatiotemporal evolution of stress within the Guizhong Depression. The regional SW–NE-directed compression during the Middle Triassic to Early Jurassic was driven by the collision and convergence between the Indochina and South China blocks, resulting in the formation of NW–SE-directed compressional structures during the Indosinian Period. The later SE–NW-directed paleo-stress field was probably driven by the NW-directed subduction of the Paleo–Pacific Plate during the Middle Jurassic to Early Cretaceous.
{"title":"Paleo-stress reconstruction and implications for the Mesozoic tectonic evolution of the Guizhong Depression, South China Block","authors":"Xiao Cui, Gen-Hou Wang, Shou-Ting Zhang, Jonathan Atuquaye Quaye, Jie Zhou, Ying-Jie Zhang, Wen-Pan Cen, Xi Gao","doi":"10.1002/gj.4955","DOIUrl":"10.1002/gj.4955","url":null,"abstract":"<p>The tectonic deformation reaction to multi-plate convergence in the northern Guizhong Depression, as well as its geodynamic process, remain poorly understood. Two phases of intracontinental deformation are identified using field geological investigations, paleo-stress inversion and seismic reflection sections: (1) early NE–SW-directed compression during the Middle Triassic to Early Jurassic; (2) later NW–SE-directed compression during the Middle Jurassic to Early Cretaceous. The reconstruction of paleo-stress provides robust constraints on the spatiotemporal evolution of stress within the Guizhong Depression. The regional SW–NE-directed compression during the Middle Triassic to Early Jurassic was driven by the collision and convergence between the Indochina and South China blocks, resulting in the formation of NW–SE-directed compressional structures during the Indosinian Period. The later SE–NW-directed paleo-stress field was probably driven by the NW-directed subduction of the Paleo–Pacific Plate during the Middle Jurassic to Early Cretaceous.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140596113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The northeastern periphery of the Qaidam Basin is a crucial region for comprehending the northeastward growth of the Tibetan Plateau, as it documents Late Cenozoic crustal deformation that elucidates the plateau's growth process. In this study, we reconstruct three stages of crustal deformation in the northeastern periphery of the Qaidam Basin during the Late Cenozoic based on interpretation of growth strata from five seismic profiles, structural mapping of the typical superimposed folds and detailed detrital zircon analysis within the study area. (1) During the Early Miocene to Late Miocene period (23–8.6 Ma), there was NW–SE extensional deformation in the northeast margin of the Qaidam Basin, which exerted control over the deposition of the Youshashan Formation. (2) The NW–SE shortening occurred during the Late Miocene period (8.6–8.1 Ma), subsequent to the deposition of the Youshashan Formation and preceding the deposition of the Shizigou Formation, resulting in a parallel unconformity between these two geological units. (3) The intense shortening of the NE–SW direction occurred during the Late Miocene and Pliocene epochs (8.1–2.5 Ma). The timing of this deformation aligns with the sedimentary age of the Shizigou Formation, suggesting that the initial deformation age may represent the onset of NE extrusion from the Tibetan Plateau towards the northeast margin of the Qaidam Basin. The present study not only delineates a Late Cenozoic structural dome resulting from two-stage crustal shortening in the northeastern periphery of the Tibetan Plateau, but also provides a crucial evidence for reconstructing the Late Cenozoic intracontinental deformation process in this region.
{"title":"The Late Cenozoic crustal deformation in the northeastern periphery of the Qaidam Basin, northwest China","authors":"Jiaqi Wang, Wei Shi, Chang Zhong, Junjie Hu","doi":"10.1002/gj.4958","DOIUrl":"10.1002/gj.4958","url":null,"abstract":"<p>The northeastern periphery of the Qaidam Basin is a crucial region for comprehending the northeastward growth of the Tibetan Plateau, as it documents Late Cenozoic crustal deformation that elucidates the plateau's growth process. In this study, we reconstruct three stages of crustal deformation in the northeastern periphery of the Qaidam Basin during the Late Cenozoic based on interpretation of growth strata from five seismic profiles, structural mapping of the typical superimposed folds and detailed detrital zircon analysis within the study area. (1) During the Early Miocene to Late Miocene period (23–8.6 Ma), there was NW–SE extensional deformation in the northeast margin of the Qaidam Basin, which exerted control over the deposition of the Youshashan Formation. (2) The NW–SE shortening occurred during the Late Miocene period (8.6–8.1 Ma), subsequent to the deposition of the Youshashan Formation and preceding the deposition of the Shizigou Formation, resulting in a parallel unconformity between these two geological units. (3) The intense shortening of the NE–SW direction occurred during the Late Miocene and Pliocene epochs (8.1–2.5 Ma). The timing of this deformation aligns with the sedimentary age of the Shizigou Formation, suggesting that the initial deformation age may represent the onset of NE extrusion from the Tibetan Plateau towards the northeast margin of the Qaidam Basin. The present study not only delineates a Late Cenozoic structural dome resulting from two-stage crustal shortening in the northeastern periphery of the Tibetan Plateau, but also provides a crucial evidence for reconstructing the Late Cenozoic intracontinental deformation process in this region.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140596105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Liquefaction-induced lateral spread is a kind of ground deformation caused by soil liquefaction, which is a danger to houses, roads and other infrastructures. In order to systematically investigate the influence law of different parameters on lateral displacement, this paper establishes a numerical model of the seismic responses of gently sloping grounds through the open-source finite element software OpenSees and carries out a large number of calculations considering various working conditions. Based on the calculation results, eXtreme Gradient Boosting (XGBoost) and random forest (RF) regression are used to build the proxy models for lateral spread displacement prediction. The finite element model was verified by using the multiple VELACS No. 2 centrifuge experiments. Finally, the model was interpreted using SHapley Additive exPlanation (SHAP) method. The results of the model training showed that both models were able to achieve a good fit to the numerical calculation results, with the RF model having a smaller prediction error for the centrifuge experiments. The model interpretation results showed that the modified cumulative absolute velocity (CAV5) was the most important input variable in the model, and the importance of ground slope (S), relative density (Dr) and thickness of liquefiable soil layer (HL) was relatively high. In addition, the influence of each parameter on the lateral displacement is consistent with the actual situation, reflecting the rationality of the model prediction process. In addition, the results showed that there is a threshold for the modified cumulative absolute velocity (CAV5) and Arias intensity (Ia) that leads to a significant increase in lateral displacement. The thresholds of CAV5 and Ia are 1.3 g s and 1.0 m/s, respectively. These thresholds are in good agreement with the thresholds for triggering the overall initial liquefaction of the soil layer determined by related studies, which provides a reference for the evaluation of liquefaction-induced lateral displacement.
液化引起的侧向扩展是一种由土壤液化引起的地面变形,对房屋、道路等基础设施具有一定的危害。为了系统研究不同参数对侧向位移的影响规律,本文通过开源有限元软件 OpenSees 建立了缓坡地地震响应数值模型,并考虑各种工况条件进行了大量计算。在计算结果的基础上,利用极梯度提升(XGBoost)和随机森林(RF)回归建立了横向扩展位移预测的代理模型。通过多次 VELACS 2 号离心机实验对有限元模型进行了验证。最后,使用 SHapley Additive exPlanation(SHAP)方法对模型进行了解释。模型训练结果表明,两个模型都能很好地拟合数值计算结果,其中射频模型对离心机实验的预测误差较小。模型解释结果表明,修正累积绝对速度(CAV5)是模型中最重要的输入变量,地面坡度(S)、相对密度(Dr)和可液化土层厚度(HL)的重要性相对较高。此外,各参数对侧向位移的影响与实际情况相符,反映了模型预测过程的合理性。此外,结果表明,修正的累积绝对速度(CAV5)和阿里亚斯强度(Ia)存在导致侧向位移显著增加的阈值。CAV5 和 Ia 的阈值分别为 1.3 g s 和 1.0 m/s。这些临界值与相关研究确定的引发土层整体初始液化的临界值十分吻合,为评估液化引起的侧向位移提供了参考。
{"title":"Evaluation of liquefaction-induced lateral spread displacement based on ensemble learning","authors":"Zhixiong Chen, Chao Tan, Chenglong Wang, Yuhui Chen, Jian Chen, Yonghong Wang","doi":"10.1002/gj.4951","DOIUrl":"10.1002/gj.4951","url":null,"abstract":"<p>Liquefaction-induced lateral spread is a kind of ground deformation caused by soil liquefaction, which is a danger to houses, roads and other infrastructures. In order to systematically investigate the influence law of different parameters on lateral displacement, this paper establishes a numerical model of the seismic responses of gently sloping grounds through the open-source finite element software OpenSees and carries out a large number of calculations considering various working conditions. Based on the calculation results, eXtreme Gradient Boosting (XGBoost) and random forest (RF) regression are used to build the proxy models for lateral spread displacement prediction. The finite element model was verified by using the multiple VELACS No. 2 centrifuge experiments. Finally, the model was interpreted using SHapley Additive exPlanation (SHAP) method. The results of the model training showed that both models were able to achieve a good fit to the numerical calculation results, with the RF model having a smaller prediction error for the centrifuge experiments. The model interpretation results showed that the modified cumulative absolute velocity (CAV<sub>5</sub>) was the most important input variable in the model, and the importance of ground slope (<i>S</i>), relative density (<i>D</i><sub>r</sub>) and thickness of liquefiable soil layer (<i>H</i><sub>L</sub>) was relatively high. In addition, the influence of each parameter on the lateral displacement is consistent with the actual situation, reflecting the rationality of the model prediction process. In addition, the results showed that there is a threshold for the modified cumulative absolute velocity (CAV<sub>5</sub>) and Arias intensity (<i>I</i><sub>a</sub>) that leads to a significant increase in lateral displacement. The thresholds of CAV<sub>5</sub> and <i>I</i><sub>a</sub> are 1.3 g s and 1.0 m/s, respectively. These thresholds are in good agreement with the thresholds for triggering the overall initial liquefaction of the soil layer determined by related studies, which provides a reference for the evaluation of liquefaction-induced lateral displacement.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.4,"publicationDate":"2024-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140596283","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The central Inner Mongolia, located at the intersection of the northern margin of the North China Craton (NCC) and the Central Asian Orogenic Belt, is crucial for deciphering the Late Palaeozoic tectonic evolution associated with the subduction and closure of the Palaeo-Asian Ocean (PAO). Our study focused on petrology, detrital zircon LA–ICP–MS U–Pb geochronology and whole-rock geochemistry for the Late Carboniferous to Permian sandstones within the Shuanmazhuang, Dahongshan, Naobaogou, and Laowopu formations in Siziwang Banner, central Inner Mongolia. This comprehensive analysis shed light on the dynamic interplay between the NCC and the South Mongolia Block. Detrital zircon U–Pb ages in investigated samples mainly cluster between 250 and 2650 Ma, with significant peaks at 2.4–2.5 Ga, 1.8–2.0 Ga, 400–430 Ma, and 250–320 Ma, respectively. The geochemistry data are characterized by SiO2 contents (56.29–77.95 wt. %), Na2O / K2O ratios (0.45–1.58) and SiO2/Al2O3 ratios between 4.33 and 7.44. Moreover, they exhibit the slight enrichment in large ion lithophile elements (Rb and Ba) and the depletion in high field strength elements (Nb, Ta, Th, and U). These facts indicate that the sedimentary detritus predominantly originates from felsic sources, probably deriving from the Late Carboniferous–Permian continental island arc-related intermediate-acid igneous rocks, the Late Ordovician-Silurian magmatic rocks in the Bainaimiao arc and the basements of the NCC. Furthermore, our present results also suggest that during the Early–Middle Permian, accelerating oceanic crust subduction triggered significant magmatic events in Siziwang Banner, leading to rapid uplift and the erosion of arc magmatic rocks, as well as the abundant corresponding sediments. Subsequently, the gradual convergence and eventual collision between the NCC and the Southern Mongolian Block took place at the end of the Permian, representing final closure of the PAO.
{"title":"Detrital zircon U–Pb geochronology and geochemistry of sandstones in the Siziwang Banner, Central Inner Mongolia: Implication for tectonic evolution","authors":"Jinhui Gao, Weimin Li, Yongjiang Liu, Quanbo Wen, Tongjun Liu, Junfeng Zhao, Yingli Zhao, Shigang Zheng, Tao Chen","doi":"10.1002/gj.4959","DOIUrl":"10.1002/gj.4959","url":null,"abstract":"<p>The central Inner Mongolia, located at the intersection of the northern margin of the North China Craton (NCC) and the Central Asian Orogenic Belt, is crucial for deciphering the Late Palaeozoic tectonic evolution associated with the subduction and closure of the Palaeo-Asian Ocean (PAO). Our study focused on petrology, detrital zircon LA–ICP–MS U–Pb geochronology and whole-rock geochemistry for the Late Carboniferous to Permian sandstones within the Shuanmazhuang, Dahongshan, Naobaogou, and Laowopu formations in Siziwang Banner, central Inner Mongolia. This comprehensive analysis shed light on the dynamic interplay between the NCC and the South Mongolia Block. Detrital zircon U–Pb ages in investigated samples mainly cluster between 250 and 2650 Ma, with significant peaks at 2.4–2.5 Ga, 1.8–2.0 Ga, 400–430 Ma, and 250–320 Ma, respectively. The geochemistry data are characterized by SiO<sub>2</sub> contents (56.29–77.95 wt. %), Na<sub>2</sub>O / K<sub>2</sub>O ratios (0.45–1.58) and SiO<sub>2</sub>/Al<sub>2</sub>O<sub>3</sub> ratios between 4.33 and 7.44. Moreover, they exhibit the slight enrichment in large ion lithophile elements (Rb and Ba) and the depletion in high field strength elements (Nb, Ta, Th, and U). These facts indicate that the sedimentary detritus predominantly originates from felsic sources, probably deriving from the Late Carboniferous–Permian continental island arc-related intermediate-acid igneous rocks, the Late Ordovician-Silurian magmatic rocks in the Bainaimiao arc and the basements of the NCC. Furthermore, our present results also suggest that during the Early–Middle Permian, accelerating oceanic crust subduction triggered significant magmatic events in Siziwang Banner, leading to rapid uplift and the erosion of arc magmatic rocks, as well as the abundant corresponding sediments. Subsequently, the gradual convergence and eventual collision between the NCC and the Southern Mongolian Block took place at the end of the Permian, representing final closure of the PAO.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140596102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The Yu'erya gold deposit is a large-scale gold deposit in eastern Hebei. However, the ore genesis is controversial because the gold orebody is closely related to biotite granite in time and space. The hydrothermal processes of the Yu'erya gold deposit can be divided into early quartz (Q1)-pyrite stage, middle quartz (Q2)-sulphide stage and late quartz (Q3)-calcite stage. The Q1 is subdivided into Q1-1 and Q1-2 generations by SEM-CL images, and Q2 is subdivided into Q2-1 and Q2-2 generations. Three types of fluid inclusions (FIs), including aqueous-carbonic type (C-type), aqueous-rich type (W-type) and vapour-rich type (V-type), were observed in the Yu'erya gold deposit. The Q1-1 is dominated by C-type inclusions, and the other quartz is dominated by W-type inclusions. Laser Raman analysis shows that the initial ore-forming fluids mainly belong to the CO2-H2O-NaCl system and gradually transferred to the H2O-NaCl system. The C-type inclusions of Q1-1 show the salinity of 3.1–10.1 (av. 6.9 ± 1.7) wt.% NaCl eqv., and the total homogenization temperature (Th) of 305–391°C. The homogenization temperature decreases gradually from the early to the late stage, with insignificant change in salinity, indicating that fluid cooling is the main precipitation mechanism. Trapping pressures of C-type FIs are estimated at 206–284 MPa and 203–211 MPa for the early and middle stages, corresponding to the mineralization depths of 7.2–9.9 km and 7.1–7.4 km, respectively. The FIs in the early stage indicate that the initial ore-forming fluids are characterized by low salinity and CO2 richness, which are different from those of the intrusion-related gold deposits, but consistent with the orogenic gold deposits.
{"title":"Genesis of the Yu'erya gold deposit, East Hebei, China: Insights from geology and fluid inclusions","authors":"Xin Wang, Xiao-Hua Deng, Jing Zhang, Xi-Heng He, Abulimiti Aibai","doi":"10.1002/gj.4957","DOIUrl":"10.1002/gj.4957","url":null,"abstract":"<p>The Yu'erya gold deposit is a large-scale gold deposit in eastern Hebei. However, the ore genesis is controversial because the gold orebody is closely related to biotite granite in time and space. The hydrothermal processes of the Yu'erya gold deposit can be divided into early quartz (Q1)-pyrite stage, middle quartz (Q2)-sulphide stage and late quartz (Q3)-calcite stage. The Q1 is subdivided into Q1-1 and Q1-2 generations by SEM-CL images, and Q2 is subdivided into Q2-1 and Q2-2 generations. Three types of fluid inclusions (FIs), including aqueous-carbonic type (C-type), aqueous-rich type (W-type) and vapour-rich type (V-type), were observed in the Yu'erya gold deposit. The Q1-1 is dominated by C-type inclusions, and the other quartz is dominated by W-type inclusions. Laser Raman analysis shows that the initial ore-forming fluids mainly belong to the CO<sub>2</sub>-H<sub>2</sub>O-NaCl system and gradually transferred to the H<sub>2</sub>O-NaCl system. The C-type inclusions of Q1-1 show the salinity of 3.1–10.1 (av. 6.9 ± 1.7) wt.% NaCl eqv., and the total homogenization temperature (<i>T</i><sub>h</sub>) of 305–391°C. The homogenization temperature decreases gradually from the early to the late stage, with insignificant change in salinity, indicating that fluid cooling is the main precipitation mechanism. Trapping pressures of C-type FIs are estimated at 206–284 MPa and 203–211 MPa for the early and middle stages, corresponding to the mineralization depths of 7.2–9.9 km and 7.1–7.4 km, respectively. The FIs in the early stage indicate that the initial ore-forming fluids are characterized by low salinity and CO<sub>2</sub> richness, which are different from those of the intrusion-related gold deposits, but consistent with the orogenic gold deposits.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140596108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The unclear understanding of the source rock characteristics for the Paleogene Dongying Formation in the Bozhong Sag leads to the lack of cognition in oil and gas exploration. This research systematically evaluated the discrepancy in geochemical characteristics of source rock intervals in the Dongying Formation based on detailed analysis using Rock-Eval pyrolysis, total organic carbon (TOC), vitrinite reflectance (Ro), maceral components, stable carbon isotopes and biomarker parameters. It discusses the organic matter sources, depositional environment, thermal maturity and hydrocarbon generation potential in the source rock intervals of the Dongying Formation. The organic matter abundance in the third member (E3d3) and lower sub-member of the second member (E3d2L) of the Dongying Formation is higher, with an average TOC of 2.08% and 1.03%, respectively, indicating that these source rock intervals could have good and excellent quality. The source rocks of the Dongying Formation predominately contain exinite maceral group and type II1 and II2 kerogen. The thermal evolution is mainly in the low-mature and mature stages. The organic matter sources in the Dongying Formation are mainly dominated by mixed origin (the carbon isotope reversal of aromatics also provides a potential explanation). However, the values of 1,2,5−/1,3,6-trimethylnaphthalene, (1,2,5,6 + 1,2,3,5)-tetramethylnaphthalene/tetramethylnaphthalenes, methyldibenzofuran/methylphenanthrene (MDBF/MP) and dibenzofuran/phenanthrene (DBF/PHEN) parameters in the E3d3 and some samples in E3d2L decipher relatively smaller values than other source rock intervals, proving the enhancement of the contribution of lower organisms. Moreover, the terrestrial input in the bottom-up deposition process of the Dongying Formation gradually increases. The depositional environment reveals the Dongying Formation source rocks mainly developed freshwater sulphur-poor lacustrine facies and shallow lake-fluvial delta facies in an open clay-rich sedimentary environment with poor water column stratification, belonging to the typical weak oxidation–reduction depositional conditions. The comprehensive geochemical evaluation concludes that the favourable supply of lower organisms and stable clay-rich depositional environment in the E3d3 interval of the Dongying Formation are potential explanations for the formation of lacustrine source rocks with high organic matter abundance, intermediate thermal evolution and excellent hydrocarbon generation potential, providing a good foundation for the exploration and development prospects of hydrocarbons.
{"title":"Investigation on the thermal maturity, organic matter sources and depositional environment of lacustrine source rocks in the Dongying Formation of the Bozhong Sag, Bohai Bay Basin, China","authors":"Guoxiong Li, Chenglin Liu, Zhangxing Chen, Rizwan Sarwar Awan, Feilong Wang, Guangyuan Wang, Hong Yang, Xiaoxiang Zeng, Yuping Wu, Dehao Feng, Taozheng Yang, Zhen-gang Ding","doi":"10.1002/gj.4956","DOIUrl":"10.1002/gj.4956","url":null,"abstract":"<p>The unclear understanding of the source rock characteristics for the Paleogene Dongying Formation in the Bozhong Sag leads to the lack of cognition in oil and gas exploration. This research systematically evaluated the discrepancy in geochemical characteristics of source rock intervals in the Dongying Formation based on detailed analysis using Rock-Eval pyrolysis, total organic carbon (TOC), vitrinite reflectance (<i>R</i><sub><i>o</i></sub>), maceral components, stable carbon isotopes and biomarker parameters. It discusses the organic matter sources, depositional environment, thermal maturity and hydrocarbon generation potential in the source rock intervals of the Dongying Formation. The organic matter abundance in the third member (E<sub>3</sub>d<sub>3</sub>) and lower sub-member of the second member (E<sub>3</sub>d<sub>2</sub><sup>L</sup>) of the Dongying Formation is higher, with an average TOC of 2.08% and 1.03%, respectively, indicating that these source rock intervals could have good and excellent quality. The source rocks of the Dongying Formation predominately contain exinite maceral group and type II<sub>1</sub> and II<sub>2</sub> kerogen. The thermal evolution is mainly in the low-mature and mature stages. The organic matter sources in the Dongying Formation are mainly dominated by mixed origin (the carbon isotope reversal of aromatics also provides a potential explanation). However, the values of 1,2,5−/1,3,6-trimethylnaphthalene, (1,2,5,6 + 1,2,3,5)-tetramethylnaphthalene/tetramethylnaphthalenes, methyldibenzofuran/methylphenanthrene (MDBF/MP) and dibenzofuran/phenanthrene (DBF/PHEN) parameters in the E<sub>3</sub>d<sub>3</sub> and some samples in E<sub>3</sub>d<sub>2</sub><sup>L</sup> decipher relatively smaller values than other source rock intervals, proving the enhancement of the contribution of lower organisms. Moreover, the terrestrial input in the bottom-up deposition process of the Dongying Formation gradually increases. The depositional environment reveals the Dongying Formation source rocks mainly developed freshwater sulphur-poor lacustrine facies and shallow lake-fluvial delta facies in an open clay-rich sedimentary environment with poor water column stratification, belonging to the typical weak oxidation–reduction depositional conditions. The comprehensive geochemical evaluation concludes that the favourable supply of lower organisms and stable clay-rich depositional environment in the E<sub>3</sub>d<sub>3</sub> interval of the Dongying Formation are potential explanations for the formation of lacustrine source rocks with high organic matter abundance, intermediate thermal evolution and excellent hydrocarbon generation potential, providing a good foundation for the exploration and development prospects of hydrocarbons.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140324359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
More than 50 earthquakes occurred in the Luding region, including a 6.8-magnitude earthquake on September 5, 2022, which induced huge amounts of geological disasters. As the main triggered factors for the geological disasters, the vegetation, precipitation and temperature show regular changes on the time axis. Thus, this paper based on the spatial–temporal evolution of the precipitation, temperature and normalized difference vegetation index (NDVI), focuses on the susceptibility of the Luding area using the weighted information content method (ICM) and analytic hierarchy process (AHP) for the post-earthquake regional planning and reconstruction. In the Luding area, it was found that there were 18 debris flow gullies, and 470 geological disasters scattered in the debris flow gullies. The NDVI of the study area has been declining in recent years, with only about 12% of the NDVI increasing from 2015 to 2020. From 2011 to 2015, the annual cumulative precipitation has been dropping overall, while the July average temperature has increasing quadratic functions after decreasing trend. Furthermore, the studied area's geological hazards susceptibility was classified into five categories, with extremely low susceptibility accounting for 5.82%, low susceptibility accounting for 13.61%, moderate susceptibility accounting for 38.54%, high susceptibility accounting for 39.96% and extremely high susceptibility accounting for 2.08%. The geological disasters in moderate, high and extremely high susceptibility accounted for approximately 95.08%, and the covered area of geological disasters in moderate, high and extremely high susceptibility accounted for 88.06%. Through the receiver operating characteristic (ROC) curve of the model verification found the AUC = 0.743. The geological hazards susceptibility study results show that the approach is useful for the analysis and prevention of geological disasters.
{"title":"Geological hazards susceptibility evaluation based on multi-year spatial–temporal evolution of assessment factors in Luding area, Sichuan Province, China","authors":"Yongping Qu, Xiao Jin","doi":"10.1002/gj.4954","DOIUrl":"10.1002/gj.4954","url":null,"abstract":"<p>More than 50 earthquakes occurred in the Luding region, including a 6.8-magnitude earthquake on September 5, 2022, which induced huge amounts of geological disasters. As the main triggered factors for the geological disasters, the vegetation, precipitation and temperature show regular changes on the time axis. Thus, this paper based on the spatial–temporal evolution of the precipitation, temperature and normalized difference vegetation index (NDVI), focuses on the susceptibility of the Luding area using the weighted information content method (ICM) and analytic hierarchy process (AHP) for the post-earthquake regional planning and reconstruction. In the Luding area, it was found that there were 18 debris flow gullies, and 470 geological disasters scattered in the debris flow gullies. The NDVI of the study area has been declining in recent years, with only about 12% of the NDVI increasing from 2015 to 2020. From 2011 to 2015, the annual cumulative precipitation has been dropping overall, while the July average temperature has increasing quadratic functions after decreasing trend. Furthermore, the studied area's geological hazards susceptibility was classified into five categories, with extremely low susceptibility accounting for 5.82%, low susceptibility accounting for 13.61%, moderate susceptibility accounting for 38.54%, high susceptibility accounting for 39.96% and extremely high susceptibility accounting for 2.08%. The geological disasters in moderate, high and extremely high susceptibility accounted for approximately 95.08%, and the covered area of geological disasters in moderate, high and extremely high susceptibility accounted for 88.06%. Through the receiver operating characteristic (ROC) curve of the model verification found the AUC = 0.743. The geological hazards susceptibility study results show that the approach is useful for the analysis and prevention of geological disasters.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140313909","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shale reservoir has strong heterogeneity in mineral composition and oil content even at a short distance in the same interval. To better understand the accumulation mechanism of shale oil and hydrocarbon migration tendency in the interval, and explore the main influencing factors of distribution. This paper employed various methods, including thin-section observation, TOC (total organic matter (OM)) analysis, rock pyrolysis, Soxhlet extraction, group component separation, and GC–MS (gas chromatography mass spectrometry) analysis of saturated hydrocarbons. The shale oil samples were collected from an exploratory well in the Songliao Basin, and the distribution and enrichment characteristics of shale oil interlayers were analysed. The results show that the first member of Qingshankou Formation (K2qn1) could be divided into six small layers. From Q1 to Q6, the lithofacies could be divided into three types: high-frequency laminar shale, massive shale, and bioclastic shale. The lacustrine matrix shale of K2qn1 in Songliao Basin has medium TOC, and high oil contents, OM conversion rate. The TOC ranges from 1.5 to 4.2 wt%, S1 varies between 1.4 and 4 mg/g, S2 falls within the range of 4 to 10.6 mg/g, Tmax ranges from 351 to 497°C, and the OSI varies between 57 and 115.34 mg HC/g rock. The lower part of the K2qn1, Q1–Q4, characterized by high-frequency laminar shale, contained residual shale oil, while the upper part of the K2qn1, Q5 and Q6, characterized by bioclastic shale and massive mudstone, and are dominated by in-situ type shale oil. The crude oil in K2qn1 is homologous, and primarily undergoes micro-migration. The Q5–Q6 section has the highest light oil content, while other regions with notable light components are located in the middle of Q1, the upper sections of Q2, Q3, and Q4.Q1–Q4 are primarily composed of residual shale oil, whereas Q5–Q6 is primarily composed of in-situ shale oil, and the primary micro-migration direction of shale oil occurs laterally within Q1–Q4. The lateral migration of each section mainly occurs at the upper part of Q3 and Q4, the lower part of Q1 and Q2, the bottom of Q5, and the interface between Q6 and the second member of Qingshankou formation (K2qn2). The block mudstone retains in-situ shale oil, especially light hydrocarbons. Within the high-frequency laminar shale, there is strong horizontal connectivity, and lateral hydrocarbon expulsion serves as the primary mechanism for micro-migration in Q1–Q4. This paper can provide reference values for K2qn1 Formation shale oil and the migration and differential reservoir formation of medium and high-maturity matrix shale oil.
{"title":"Hydrocarbon micro-migration and differential enrichment mechanism of shale oil in upper Cretaceous Qingshankou Formation in Songliao Basin","authors":"Ziheng Guan, Qingqiang Meng, Qian Huang, Xuan Tang, Yansheng Shan, Guangxiang Liu, Shaobin Guo, Jinchuan Zhang, Xiong Cheng, Jinyu Xiong","doi":"10.1002/gj.4952","DOIUrl":"10.1002/gj.4952","url":null,"abstract":"<p>Shale reservoir has strong heterogeneity in mineral composition and oil content even at a short distance in the same interval. To better understand the accumulation mechanism of shale oil and hydrocarbon migration tendency in the interval, and explore the main influencing factors of distribution. This paper employed various methods, including thin-section observation, TOC (total organic matter (OM)) analysis, rock pyrolysis, Soxhlet extraction, group component separation, and GC–MS (gas chromatography mass spectrometry) analysis of saturated hydrocarbons. The shale oil samples were collected from an exploratory well in the Songliao Basin, and the distribution and enrichment characteristics of shale oil interlayers were analysed. The results show that the first member of Qingshankou Formation (K<sub>2</sub>qn<sup>1</sup>) could be divided into six small layers. From Q1 to Q6, the lithofacies could be divided into three types: high-frequency laminar shale, massive shale, and bioclastic shale. The lacustrine matrix shale of K<sub>2</sub>qn<sup>1</sup> in Songliao Basin has medium TOC, and high oil contents, OM conversion rate. The TOC ranges from 1.5 to 4.2 wt%, S<sub>1</sub> varies between 1.4 and 4 mg/g, S<sub>2</sub> falls within the range of 4 to 10.6 mg/g, Tmax ranges from 351 to 497°C, and the OSI varies between 57 and 115.34 mg HC/g rock. The lower part of the K<sub>2</sub>qn<sup>1</sup>, Q1–Q4, characterized by high-frequency laminar shale, contained residual shale oil, while the upper part of the K<sub>2</sub>qn<sup>1</sup>, Q5 and Q6, characterized by bioclastic shale and massive mudstone, and are dominated by in-situ type shale oil. The crude oil in K<sub>2</sub>qn<sup>1</sup> is homologous, and primarily undergoes micro-migration. The Q5–Q6 section has the highest light oil content, while other regions with notable light components are located in the middle of Q1, the upper sections of Q2, Q3, and Q4.Q1–Q4 are primarily composed of residual shale oil, whereas Q5–Q6 is primarily composed of in-situ shale oil, and the primary micro-migration direction of shale oil occurs laterally within Q1–Q4. The lateral migration of each section mainly occurs at the upper part of Q3 and Q4, the lower part of Q1 and Q2, the bottom of Q5, and the interface between Q6 and the second member of Qingshankou formation (K<sub>2</sub>qn<sup>2</sup>). The block mudstone retains in-situ shale oil, especially light hydrocarbons. Within the high-frequency laminar shale, there is strong horizontal connectivity, and lateral hydrocarbon expulsion serves as the primary mechanism for micro-migration in Q1–Q4. This paper can provide reference values for K<sub>2</sub>qn<sup>1</sup> Formation shale oil and the migration and differential reservoir formation of medium and high-maturity matrix shale oil.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140313912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shafi Muhammad, Junlai Liu, Inayat Ullah, Xiaoyu Chen, Lie Ji, Muhammad Aleem Zahid, Naseer Kakar
The Chagai belt to the north of the Afghan block and the east of the Iranian block in the western part of Pakistan is known for occurrence of Oligocene to Miocene calc-alkaline magmatic belt. The present study discusses the characteristics of episodic magmatic activities that contributed to mineralization for the Reko Diq porphyry complex in the western part of the Chagai belt. U–Pb dating of zircons from volcanic rocks of the Reko Diq porphyry complex yielded ages of 25.8 ± 1.8 and 12.29 ± 0.44 Ma for two phases of magmatic crystallization. Geochemical analyses of whole-rock rhyolite and dacite indicate that the rock units are peraluminous calc-alkaline, derived from Andean-type subduction. The magma was formed due to partial melting of the thickened mafic lower crust in a continental arc setting in relation to the subduction of the Neotethys along the Makran subduction zone. The abundance of zircons, Hf, REE, U/Pb and Th indicates high degrees of magmatic evolution. Moreover, the Sr and Nd isotopic data indicate the fractional contribution of depleted N-MORB mantle to the Reko Diq magmas through bulk mixing with magmas derived from the lower continental crust. Short-lived magmatic systems repeated magma injection, and various episodes of hydrothermal fluid flow have led to the formation of porphyry mineralization. Emplacement of the Reko Diq porphyry complex and related Cu–Au mineralization is associated with a series of tectonic–magmatic events at different episodes of the Oligocene–Miocene times.
巴基斯坦西部阿富汗地块以北、伊朗地块以东的 Chagai 带以出现渐新世至中新世钙碱性岩浆带而闻名。本研究讨论了导致查盖带西部 Reko Diq 斑岩复合体成矿的偶发岩浆活动特征。对来自 Reko Diq 斑岩群火山岩的锆石进行了 U-Pb 测定,得出岩浆结晶两个阶段的年龄分别为 25.8 ± 1.8 Ma 和 12.29 ± 0.44 Ma。全岩流纹岩和英安岩的地球化学分析表明,这些岩石单元为过铝钙碱性,源自安第斯型俯冲。岩浆的形成是由于增厚的黑云母下地壳在大陆弧环境中部分熔化所致,与新特提斯沿马克兰俯冲带的俯冲有关。锆石、Hf、REE、U/Pb 和 Th 的丰度表明岩浆演化程度很高。此外,Sr 和 Nd 同位素数据表明,贫化的 N-MORB 地幔通过与来自下部大陆地壳的岩浆大量混合,部分进入了 Reko Diq 岩浆。短暂的岩浆系统反复注入岩浆,以及各种热液流动导致了斑岩矿化的形成。Reko Diq 斑岩群和相关的铜金矿化的形成与渐新世-中新世不同时期的一系列构造-岩浆事件有关。
{"title":"Oligocene–Miocene arc magmatic activities associated with the giant Reko Diq porphyry Cu–Au deposit, western Chagai arc, Balochistan, Pakistan","authors":"Shafi Muhammad, Junlai Liu, Inayat Ullah, Xiaoyu Chen, Lie Ji, Muhammad Aleem Zahid, Naseer Kakar","doi":"10.1002/gj.4931","DOIUrl":"10.1002/gj.4931","url":null,"abstract":"<p>The Chagai belt to the north of the Afghan block and the east of the Iranian block in the western part of Pakistan is known for occurrence of Oligocene to Miocene calc-alkaline magmatic belt. The present study discusses the characteristics of episodic magmatic activities that contributed to mineralization for the Reko Diq porphyry complex in the western part of the Chagai belt. U–Pb dating of zircons from volcanic rocks of the Reko Diq porphyry complex yielded ages of 25.8 ± 1.8 and 12.29 ± 0.44 Ma for two phases of magmatic crystallization. Geochemical analyses of whole-rock rhyolite and dacite indicate that the rock units are peraluminous calc-alkaline, derived from Andean-type subduction. The magma was formed due to partial melting of the thickened mafic lower crust in a continental arc setting in relation to the subduction of the Neotethys along the Makran subduction zone. The abundance of zircons, Hf, REE, U/Pb and Th indicates high degrees of magmatic evolution. Moreover, the Sr and Nd isotopic data indicate the fractional contribution of depleted N-MORB mantle to the Reko Diq magmas through bulk mixing with magmas derived from the lower continental crust. Short-lived magmatic systems repeated magma injection, and various episodes of hydrothermal fluid flow have led to the formation of porphyry mineralization. Emplacement of the Reko Diq porphyry complex and related Cu–Au mineralization is associated with a series of tectonic–magmatic events at different episodes of the Oligocene–Miocene times.</p>","PeriodicalId":12784,"journal":{"name":"Geological Journal","volume":null,"pages":null},"PeriodicalIF":1.8,"publicationDate":"2024-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140197613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}