首页 > 最新文献

Geomechanics and Geophysics for Geo-Energy and Geo-Resources最新文献

英文 中文
Research on the theory and method of reduced-hole blasting for large cross-section tunnel based on explosive energy dissipation 基于爆炸能量耗散的大断面隧道减孔爆破理论与方法研究
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-28 DOI: 10.1007/s40948-024-00816-3
Xingchao Tian, Tiejun Tao, Caijin Xie

The traditional tunnel drilling and blasting method places cut holes at the lower center of the excavation face, resulting in an excessive number of blasting holes. With the continuous increase in cross-section area, this design concept can no longer meet the requirements of safe and efficient tunnel boring for large cross-section tunnels. This paper puts forward the theory and method of reduced-hole blasting for large cross-section tunnels, as an alternative to the traditional drilling and blasting method of the “more holes, less charge” design concept. Based on the explosion energy dissipation law and rock’s critical crushing energy dissipation characteristics, the calculation method of the extrapolation distance of the wedge-cut holes is given. The optimum extrapolation distance of the wedge-cut holes was verified using numerical simulation and field tests. The results show that the number of drilling holes can be reduced by about 15.8% using the theory and method proposed in this paper, and at the same time, the damage of retained rock can be effectively controlled. The results of this study can provide a reference for the design of blast network parameters for similar large cross-section tunnels.

传统的隧道钻爆法是在开挖面的下部中心位置开孔,导致爆破孔数量过多。随着断面面积的不断增大,这种设计理念已不能满足大断面隧道安全高效掘进的要求。本文提出了大断面隧道减孔爆破的理论和方法,以替代传统钻爆法的 "多孔少药 "设计理念。根据爆炸能量耗散规律和岩石临界破碎能量耗散特性,给出了楔切孔外推距离的计算方法。通过数值模拟和现场试验验证了楔切孔的最佳外推距离。结果表明,采用本文提出的理论和方法,钻孔数量可减少约 15.8%,同时,可有效控制对保留岩体的破坏。该研究结果可为类似大断面隧道的爆破网路参数设计提供参考。
{"title":"Research on the theory and method of reduced-hole blasting for large cross-section tunnel based on explosive energy dissipation","authors":"Xingchao Tian, Tiejun Tao, Caijin Xie","doi":"10.1007/s40948-024-00816-3","DOIUrl":"https://doi.org/10.1007/s40948-024-00816-3","url":null,"abstract":"<p>The traditional tunnel drilling and blasting method places cut holes at the lower center of the excavation face, resulting in an excessive number of blasting holes. With the continuous increase in cross-section area, this design concept can no longer meet the requirements of safe and efficient tunnel boring for large cross-section tunnels. This paper puts forward the theory and method of reduced-hole blasting for large cross-section tunnels, as an alternative to the traditional drilling and blasting method of the “more holes, less charge” design concept. Based on the explosion energy dissipation law and rock’s critical crushing energy dissipation characteristics, the calculation method of the extrapolation distance of the wedge-cut holes is given. The optimum extrapolation distance of the wedge-cut holes was verified using numerical simulation and field tests. The results show that the number of drilling holes can be reduced by about 15.8% using the theory and method proposed in this paper, and at the same time, the damage of retained rock can be effectively controlled. The results of this study can provide a reference for the design of blast network parameters for similar large cross-section tunnels.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"27 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141165934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study of mechanical properties of artificial dam for coal mine underground reservoir under cyclic loading and unloading 循环加载和卸载条件下煤矿地下水库人工大坝力学性能的试验研究
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-14 DOI: 10.1007/s40948-024-00815-4
Xin Lyu, Ke Yang, Chaoshui Xu, Juejing Fang, Minke Duan, Zhainan Zhang

This study investigates the stability of an artificial dam used in an underground reservoir in a coal mine under periodic weighting imposed by overlying rock strata. For this purpose, cyclic loading and unloading tests with different stress amplitudes were designed. Differences in the mechanical performance of the artificial dam with and without overlying strata were analyzed using a uniaxial compression test. The mechanical properties of the structure under constant-amplitude cyclic loading and unloading were characterized. Further, the law of influence of stress amplitude on stability was discussed. A formula for predicting the mechanical performance of the artificial dam with its overlying rocks (hereafter referred to as the complex) was finally derived and was suitable for clarifying the law of damage in the complex under cyclic loading and unloading. The results showed that the complex had changed the internal structure of rocks. The strength and deformation of the complex were intermediate to that of either single structure. All three underwent brittle failure. During the constant-amplitude loading and unloading tests, the hysteresis loop could be divided into three phases, namely, sparse, dense, and sparse again, with a shift in the turning point in rock deformation memory effect. As the stress amplitude increased during the test, the damping ratio of the specimens decreased, and the area of the hysteresis loop increased non-linearly. The dynamic elastic modulus decreased first and then increased. The confidence interval for the formula fitted based on the test results was above 97%. Damage to the complex caused by constant-amplitude loading and unloading could be divided into three stages. An increase in peak stress served as a catalyst for the evolution of small cracks within the specimens into median and large cracks, thereby accelerating the damage process.

本研究探讨了煤矿地下水库中使用的人工大坝在上覆岩层周期性加权作用下的稳定性。为此,设计了不同应力振幅的循环加载和卸载试验。通过单轴压缩试验分析了有上覆岩层和无上覆岩层人工大坝的机械性能差异。分析了结构在恒定振幅循环加载和卸载下的力学性能。此外,还讨论了应力振幅对稳定性的影响规律。最终得出了人工大坝及其上覆岩石(以下简称 "复合体")的力学性能预测公式,该公式适用于阐明复合体在循环加载和卸载下的破坏规律。结果表明,复合体改变了岩石的内部结构。复合结构的强度和变形介于单一结构和复合结构之间。三种结构都发生了脆性破坏。在恒定振幅加载和卸载试验过程中,滞环可分为三个阶段,即稀疏、致密和再稀疏阶段,岩石变形记忆效应的转折点发生了变化。试验过程中,随着应力振幅的增大,试样的阻尼比减小,滞环面积非线性增大。动态弹性模量先减小后增大。根据试验结果拟合的公式的置信区间在 97% 以上。恒定振幅加载和卸载对复合材料造成的破坏可分为三个阶段。峰值应力的增加是试样内部小裂纹演变为中裂纹和大裂纹的催化剂,从而加速了破坏过程。
{"title":"Experimental study of mechanical properties of artificial dam for coal mine underground reservoir under cyclic loading and unloading","authors":"Xin Lyu, Ke Yang, Chaoshui Xu, Juejing Fang, Minke Duan, Zhainan Zhang","doi":"10.1007/s40948-024-00815-4","DOIUrl":"https://doi.org/10.1007/s40948-024-00815-4","url":null,"abstract":"<p>This study investigates the stability of an artificial dam used in an underground reservoir in a coal mine under periodic weighting imposed by overlying rock strata. For this purpose, cyclic loading and unloading tests with different stress amplitudes were designed. Differences in the mechanical performance of the artificial dam with and without overlying strata were analyzed using a uniaxial compression test. The mechanical properties of the structure under constant-amplitude cyclic loading and unloading were characterized. Further, the law of influence of stress amplitude on stability was discussed. A formula for predicting the mechanical performance of the artificial dam with its overlying rocks (hereafter referred to as the complex) was finally derived and was suitable for clarifying the law of damage in the complex under cyclic loading and unloading. The results showed that the complex had changed the internal structure of rocks. The strength and deformation of the complex were intermediate to that of either single structure. All three underwent brittle failure. During the constant-amplitude loading and unloading tests, the hysteresis loop could be divided into three phases, namely, sparse, dense, and sparse again, with a shift in the turning point in rock deformation memory effect. As the stress amplitude increased during the test, the damping ratio of the specimens decreased, and the area of the hysteresis loop increased non-linearly. The dynamic elastic modulus decreased first and then increased. The confidence interval for the formula fitted based on the test results was above 97%. Damage to the complex caused by constant-amplitude loading and unloading could be divided into three stages. An increase in peak stress served as a catalyst for the evolution of small cracks within the specimens into median and large cracks, thereby accelerating the damage process.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"42 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pore structure response at different scales in coal to cyclical liquid nitrogen treatment and its impact on permeability and micromechanical properties 煤中不同尺度的孔隙结构对循环液氮处理的响应及其对渗透性和微观力学性能的影响
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-14 DOI: 10.1007/s40948-024-00789-3
Changbao Jiang, Qi Sun, Bozhi Deng, Bowen Yang, Jianquan Guo

The methane in the coal seams of abandoned mines is a valuable natural gas resource. However, the ultra-low permeability of coal seams restricts the extraction of coalbed methane. The liquid nitrogen fracturing technology is a novel approach suitable for enhancing the permeability of coal seams in abandoned mines. The ultra-low temperature could potentially facilitate the growth and propagation of pores and fractures in coal seams. In this study, we observed inconsistent alterations in coal properties measured by multiple instruments at different scales, whether in dry or wet coal specimens. This suggests that the mechanisms influencing the pore structure due to LN2 treatment differ across various scales in dry and wet coal specimens. For dry specimens, heterogeneous thermal deformation and freezing shrinkage exhibited opposing effects during LN2 treatment. Thermal stress-induced micro-fractures might counteract the freezing contraction of micropores in coal matrices, preventing a significant decrease in coal macropores and fractures. In wet specimens, the effects of LN2 treatment on wet coal specimens were predominantly controlled by frost heaving. However, due to low water saturation, LN2 treatment had negligible effects on coal micropores, even in the presence of local frost heaving. In field applications, water migration from smaller to larger pores could further diminish the impact of LN2 treatment on micropores.

废弃矿井煤层中的甲烷是一种宝贵的天然气资源。然而,煤层的超低渗透性限制了煤层气的开采。液氮压裂技术是一种适用于提高废弃矿井煤层渗透性的新方法。超低温有可能促进煤层中孔隙和裂缝的生长和扩展。在这项研究中,我们观察到,无论是在干煤试样还是湿煤试样中,通过多种仪器在不同尺度上测量到的煤炭特性都发生了不一致的变化。这表明,在干煤和湿煤试样的不同尺度上,LN2 处理对孔隙结构的影响机制是不同的。对于干试样,在 LN2 处理过程中,异质热变形和冷冻收缩表现出相反的效应。热应力引起的微裂缝可能会抵消煤基质中微孔的冷冻收缩,从而防止煤的宏观孔隙和裂缝显著减少。在湿试样中,LN2 处理对湿煤试样的影响主要由冻胀控制。然而,由于水饱和度低,即使存在局部冻胀,LN2 处理对煤微孔的影响也微乎其微。在现场应用中,水从较小的孔隙向较大的孔隙迁移可能会进一步减弱 LN2 处理对微孔的影响。
{"title":"Pore structure response at different scales in coal to cyclical liquid nitrogen treatment and its impact on permeability and micromechanical properties","authors":"Changbao Jiang, Qi Sun, Bozhi Deng, Bowen Yang, Jianquan Guo","doi":"10.1007/s40948-024-00789-3","DOIUrl":"https://doi.org/10.1007/s40948-024-00789-3","url":null,"abstract":"<p>The methane in the coal seams of abandoned mines is a valuable natural gas resource. However, the ultra-low permeability of coal seams restricts the extraction of coalbed methane. The liquid nitrogen fracturing technology is a novel approach suitable for enhancing the permeability of coal seams in abandoned mines. The ultra-low temperature could potentially facilitate the growth and propagation of pores and fractures in coal seams. In this study, we observed inconsistent alterations in coal properties measured by multiple instruments at different scales, whether in dry or wet coal specimens. This suggests that the mechanisms influencing the pore structure due to LN<sub>2</sub> treatment differ across various scales in dry and wet coal specimens. For dry specimens, heterogeneous thermal deformation and freezing shrinkage exhibited opposing effects during LN<sub>2</sub> treatment. Thermal stress-induced micro-fractures might counteract the freezing contraction of micropores in coal matrices, preventing a significant decrease in coal macropores and fractures. In wet specimens, the effects of LN<sub>2</sub> treatment on wet coal specimens were predominantly controlled by frost heaving. However, due to low water saturation, LN<sub>2</sub> treatment had negligible effects on coal micropores, even in the presence of local frost heaving. In field applications, water migration from smaller to larger pores could further diminish the impact of LN<sub>2</sub> treatment on micropores.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"26 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926721","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rock fines breakage by flow-induced stresses against drag: geo-energy applications 流动诱导应力对阻力的岩石细粒破碎:地质能源应用
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-11 DOI: 10.1007/s40948-024-00804-7
Sara Borazjani, Abolfazl Hashemi, Cuong Nguyen, Grace Loi, Thomas Russell, Nastaran Khazali, Yutong Yang, Bryant Dang-Le, Pavel Bedrikovetsky

The paper presents a strength-failure mechanism for colloidal detachment by breakage and permeability decline in reservoir rocks. The current theory for permeability decline due to colloidal detachment, including microscale mobilisation mechanisms, mathematical and laboratory modelling, and upscaling to natural reservoirs, is developed only for detrital particles with detachment that occurs against electrostatic attraction. We establish a theory for detachment of widely spread authigenic particles due to breakage of the particle-rock bonds, by integrating beam theory of particle deformation, failure criteria, and creeping flow. Explicit expressions for stress maxima in the beam yield a graphical technique to determine the failure regime. The core-scale model for fines detachment by breakage has a form of maximum retention concentration of the fines, expressing rock capacity to produce breakable fines. This closes the governing system for authigenic fines transport in rocks. Matching of the lab coreflood data by the analytical model for 1D flow exhibits two-population particle behaviour, attributed to simultaneous detachment and migration of authigenic and detrital fines. High agreement between the laboratory and modelling data for 16 corefloods validates the theory. The work is concluded by geo-energy applications to (i) clay breakage in geological faults, (ii) typical reservoir conditions for kaolinite breakage, (iii) well productivity damage due to authigenic fines migration, and (iv) feasibility of fines breakage in various geo-energy extraction technologies.

本文介绍了储层岩石中胶体破碎脱落和渗透率下降的强度-失效机制。目前关于胶体脱落导致渗透率下降的理论,包括微尺度动员机制、数学和实验室建模,以及上升到天然储层的理论,仅针对在静电吸引下发生脱落的脱落颗粒。我们通过整合颗粒变形的梁理论、失效标准和蠕动流,建立了广泛分布的自生颗粒因颗粒-岩石键断裂而脱离的理论。梁中应力最大值的明确表达式产生了一种确定破坏机制的图形技术。岩心尺度的细粒破碎脱落模型具有细粒最大保留浓度的形式,表达了岩石产生可破碎细粒的能力。这就关闭了岩石中自生细粒输运的调控系统。一维流动分析模型与实验室岩心充注数据的匹配显示了双群颗粒行为,这归因于自生细粒和碎屑的同时脱落和迁移。16 次岩心充水的实验室数据与模型数据之间的高度一致验证了这一理论。最后,将地质能源应用于(i)地质断层中的粘土破碎,(ii)高岭石破碎的典型储层条件,(iii)自生细粒迁移对油井生产力的破坏,以及(iv)各种地质能源开采技术中细粒破碎的可行性。
{"title":"Rock fines breakage by flow-induced stresses against drag: geo-energy applications","authors":"Sara Borazjani, Abolfazl Hashemi, Cuong Nguyen, Grace Loi, Thomas Russell, Nastaran Khazali, Yutong Yang, Bryant Dang-Le, Pavel Bedrikovetsky","doi":"10.1007/s40948-024-00804-7","DOIUrl":"https://doi.org/10.1007/s40948-024-00804-7","url":null,"abstract":"<p>The paper presents a strength-failure mechanism for colloidal detachment by breakage and permeability decline in reservoir rocks. The current theory for permeability decline due to colloidal detachment, including microscale mobilisation mechanisms, mathematical and laboratory modelling, and upscaling to natural reservoirs, is developed only for <i>detrital particles</i> with detachment that occurs against electrostatic attraction. We establish a theory for detachment of widely spread <i>authigenic particles</i> due to breakage of the particle-rock bonds, by integrating beam theory of particle deformation, failure criteria, and creeping flow. Explicit expressions for stress maxima in the beam yield a graphical technique to determine the failure regime. The core-scale model for fines detachment by breakage has a form of maximum retention concentration of the fines, expressing rock capacity to produce breakable fines. This closes the governing system for authigenic fines transport in rocks. Matching of the lab coreflood data by the analytical model for 1D flow exhibits two-population particle behaviour, attributed to simultaneous detachment and migration of authigenic and detrital fines. High agreement between the laboratory and modelling data for 16 corefloods validates the theory. The work is concluded by geo-energy applications to (i) clay breakage in geological faults, (ii) typical reservoir conditions for kaolinite breakage, (iii) well productivity damage due to authigenic fines migration, and (iv) feasibility of fines breakage in various geo-energy extraction technologies.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"55 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanism of overburden fracture induced earthquakes in coal seam mining 煤层开采中覆盖层断裂诱发地震的机理
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-09 DOI: 10.1007/s40948-024-00809-2
Quan Zhang, Junpeng Zou, Yu-Yong Jiao, Yujing Jiang, Qihua Kou

Mining-induced earthquakes are unnatural seismic events that frequently occur in high-position hard and thick rock strata during coal mining. Considering the frequent occurrence of strong mining-induced earthquakes in the Dongtan mining area, this study analysed the fracture migration characteristics of hard and thick rock strata and the focal mechanism of mining-induced earthquakes based on Volasov’s thick-plate and moment tensor inversion theories. The results showed that the main key strata were difficult to break under single-panel mining conditions because of the thick and high-strength rock strata and breakage of the main key strata is caused by multiple-panel mining. Volasov’s thick-plate theoretical calculation indicated an initial fracture span of the main key strata was 314 m, which is consistent with the actual mining distance of the working face. This verified that strong mining-induced earthquakes were induced by the initial fracture of the main key strata. In coal mining, the pure shear failure type of mining-induced earthquakes indicated the highest percentage, and the shear fracture of rock strata was the primary cause of strong mining-induced earthquakes. The dip angle of the focal fracture surface in mining-induced earthquakes was generally within 15°. Through an analysis of the focal mechanism of mining-induced earthquakes, it has a certain guiding role in explaining the mechanism of mining-induced earthquakes.

采动诱发地震是指在煤矿开采过程中,高位硬厚岩层经常发生的非自然地震事件。针对东滩矿区频繁发生矿井诱发强震的特点,本研究基于沃拉索夫厚板理论和力矩张量反演理论,分析了硬厚岩层的断裂迁移特征和矿井诱发地震的动力机制。结果表明,在单板开采条件下,由于岩层厚且强度高,主要关键地层难以破碎,而多板开采则会造成主要关键地层的破碎。Volasov 的厚板理论计算表明,主要关键地层的初始断裂跨度为 314 米,这与工作面的实际开采距离一致。这验证了采矿诱发的强震是由主要关键地层的初始断裂诱发的。在煤矿开采中,纯剪切破坏类型的矿井诱发地震所占比例最高,岩层的剪切断裂是矿井诱发强震的主要原因。矿山诱发地震的焦点断裂面倾角一般在 15°以内。通过对矿山诱发地震的病灶机理分析,对解释矿山诱发地震的机理具有一定的指导作用。
{"title":"Mechanism of overburden fracture induced earthquakes in coal seam mining","authors":"Quan Zhang, Junpeng Zou, Yu-Yong Jiao, Yujing Jiang, Qihua Kou","doi":"10.1007/s40948-024-00809-2","DOIUrl":"https://doi.org/10.1007/s40948-024-00809-2","url":null,"abstract":"<p>Mining-induced earthquakes are unnatural seismic events that frequently occur in high-position hard and thick rock strata during coal mining. Considering the frequent occurrence of strong mining-induced earthquakes in the Dongtan mining area, this study analysed the fracture migration characteristics of hard and thick rock strata and the focal mechanism of mining-induced earthquakes based on Volasov’s thick-plate and moment tensor inversion theories. The results showed that the main key strata were difficult to break under single-panel mining conditions because of the thick and high-strength rock strata and breakage of the main key strata is caused by multiple-panel mining. Volasov’s thick-plate theoretical calculation indicated an initial fracture span of the main key strata was 314 m, which is consistent with the actual mining distance of the working face. This verified that strong mining-induced earthquakes were induced by the initial fracture of the main key strata. In coal mining, the pure shear failure type of mining-induced earthquakes indicated the highest percentage, and the shear fracture of rock strata was the primary cause of strong mining-induced earthquakes. The dip angle of the focal fracture surface in mining-induced earthquakes was generally within 15°. Through an analysis of the focal mechanism of mining-induced earthquakes, it has a certain guiding role in explaining the mechanism of mining-induced earthquakes.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"12 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Physical and mechanical characteristics deterioration and crack evolution of sandy mudstone in an open-pit mine under multiple freeze–thaw cycles 露天矿砂质泥岩在多次冻融循环下的物理和机械特性劣化及裂缝演变
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-09 DOI: 10.1007/s40948-024-00808-3
Guoyu Yang, Yanlong Chen, Qihang Xie, Peng Wu, Yu Zhang

In open-pit mines located in cold regions north of the 38°N latitude, there are significant freeze–thaw phenomena in slope rocks. This study conducted freeze–thaw cycle tests, considering the number of freeze–thaw cycles and the freezing temperature, on sandy mudstone commonly found in the slopes of open-pit mines. The investigation focused on the effects of freeze–thaw cycles on the physical and mechanical properties and acoustic emission (AE) characteristics of sandy mudstone. The results show that, with an increase in the number of freeze–thaw cycles and a decrease in freezing temperature, the sandy mudstone specimens exhibit nonlinear exponential changes in mass loss rate, P-wave velocity loss rate, peak strain, uniaxial compressive strength (UCS) and elastic modulus, and the amplitude of these changes gradually decreases. The stress–strain curves of specimens shift gradually from apparently brittle to plastic. Simultaneously, the microstructure changes from dense to loose, the micro surface transitions from flat to rough, and cracks and pore defects gradually develop. The peak AE ringing counts, cumulative AE ringing counts, crack initiation stress, and crack damage stress of the specimens all decrease with an increase in the number of freeze–thaw cycles and a decrease in freezing temperature. This suggests a shift from brittle failure to ductile failure. However, the ratio of crack initiation stress and crack damage stress to peak stress does not vary significantly with the number of freeze–thaw cycles and freezing temperature.

在北纬 38° 以北寒冷地区的露天矿中,边坡岩石存在严重的冻融现象。本研究对露天矿边坡常见的砂质泥岩进行了冻融循环试验,考虑了冻融循环次数和冻结温度。调查的重点是冻融循环对砂质泥岩物理和机械性能以及声发射(AE)特性的影响。结果表明,随着冻融循环次数的增加和冻结温度的降低,砂质泥岩试样的质量损失率、P 波速度损失率、峰值应变、单轴抗压强度(UCS)和弹性模量均呈现非线性指数变化,且变化幅度逐渐减小。试样的应力-应变曲线从明显的脆性逐渐转变为塑性。同时,微观结构由致密变为疏松,微观表面由平整变为粗糙,裂纹和孔隙缺陷逐渐产生。试样的峰值 AE 振铃数、累积 AE 振铃数、裂纹起始应力和裂纹破坏应力都随着冻融循环次数的增加和冻结温度的降低而降低。这表明试样从脆性破坏转变为韧性破坏。不过,裂纹起始应力和裂纹破坏应力与峰值应力的比率并不随冻融循环次数和冻结温度的变化而显著变化。
{"title":"Physical and mechanical characteristics deterioration and crack evolution of sandy mudstone in an open-pit mine under multiple freeze–thaw cycles","authors":"Guoyu Yang, Yanlong Chen, Qihang Xie, Peng Wu, Yu Zhang","doi":"10.1007/s40948-024-00808-3","DOIUrl":"https://doi.org/10.1007/s40948-024-00808-3","url":null,"abstract":"<p>In open-pit mines located in cold regions north of the 38°N latitude, there are significant freeze–thaw phenomena in slope rocks. This study conducted freeze–thaw cycle tests, considering the number of freeze–thaw cycles and the freezing temperature, on sandy mudstone commonly found in the slopes of open-pit mines. The investigation focused on the effects of freeze–thaw cycles on the physical and mechanical properties and acoustic emission (AE) characteristics of sandy mudstone. The results show that, with an increase in the number of freeze–thaw cycles and a decrease in freezing temperature, the sandy mudstone specimens exhibit nonlinear exponential changes in mass loss rate, P-wave velocity loss rate, peak strain, uniaxial compressive strength (UCS) and elastic modulus, and the amplitude of these changes gradually decreases. The stress–strain curves of specimens shift gradually from apparently brittle to plastic. Simultaneously, the microstructure changes from dense to loose, the micro surface transitions from flat to rough, and cracks and pore defects gradually develop. The peak AE ringing counts, cumulative AE ringing counts, crack initiation stress, and crack damage stress of the specimens all decrease with an increase in the number of freeze–thaw cycles and a decrease in freezing temperature. This suggests a shift from brittle failure to ductile failure. However, the ratio of crack initiation stress and crack damage stress to peak stress does not vary significantly with the number of freeze–thaw cycles and freezing temperature.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"24 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140942152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research on abutment stress distribution of roof-cutting coalface: numerical simulation and field measurement 顶板切割煤层的基台应力分布研究:数值模拟和实地测量
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-06 DOI: 10.1007/s40948-024-00796-4
Yangyang Guo, Xiaoli Liu, Weitao Li, Feng Du, Ji Ma, Ruipeng Qian, Ningning Huo

During the processing of deep mining, revealing the distribution of abutment pressure is significant for controlling stability of the entry. In this study, the abutment pressure distribution of roof-cutting coalface was investigated by FLAC3D and self-developed flexible detection unit (FDU). In the numerical simulation, the double-yield model was built to analyze the goaf abutment pressure under the fracturing roofs to maintain entry (FRME). Compared with the non-fracturing side, the peak value of the advanced abutment pressure on the fracturing side is reduced by 19.29% on average, the influence range (span) increases by 30.78% and the distance between the peak value and the working face increases by 66.7%. The goaf abutment pressure within 23m near the cutting side is significantly higher than other areas along the dip. The FDU was employed in the coalface to record the change of advanced abutment stress. And the field measured results are in well agreement with the numerical results.

在深部采矿加工过程中,揭示基底压力的分布对控制入口的稳定性具有重要意义。本研究利用 FLAC3D 和自主研发的柔性检测单元(FDU)对顶板切割煤层的台背压力分布进行了研究。在数值模拟中,建立了双屈服模型来分析压裂顶板维持进入(FRME)下的矢状基底压力。与非压裂侧相比,压裂侧超前支护压力峰值平均降低了 19.29%,影响范围(跨度)增加了 30.78%,峰值与工作面的距离增加了 66.7%。靠近切削侧 23 米范围内的山麓台地压力明显高于沿倾角的其他区域。在煤层中使用了 FDU 来记录超前基坑应力的变化。实地测量结果与数值结果完全一致。
{"title":"Research on abutment stress distribution of roof-cutting coalface: numerical simulation and field measurement","authors":"Yangyang Guo, Xiaoli Liu, Weitao Li, Feng Du, Ji Ma, Ruipeng Qian, Ningning Huo","doi":"10.1007/s40948-024-00796-4","DOIUrl":"https://doi.org/10.1007/s40948-024-00796-4","url":null,"abstract":"<p>During the processing of deep mining, revealing the distribution of abutment pressure is significant for controlling stability of the entry. In this study, the abutment pressure distribution of roof-cutting coalface was investigated by FLAC3D and self-developed flexible detection unit (FDU). In the numerical simulation, the double-yield model was built to analyze the goaf abutment pressure under the fracturing roofs to maintain entry (FRME). Compared with the non-fracturing side, the peak value of the advanced abutment pressure on the fracturing side is reduced by 19.29% on average, the influence range (span) increases by 30.78% and the distance between the peak value and the working face increases by 66.7%. The goaf abutment pressure within 23m near the cutting side is significantly higher than other areas along the dip. The FDU was employed in the coalface to record the change of advanced abutment stress. And the field measured results are in well agreement with the numerical results.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"84 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental study on the influence of external fluids on the pore structure of carbonaceous shale 外部流体对碳质页岩孔隙结构影响的实验研究
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-03 DOI: 10.1007/s40948-024-00806-5
Ying Yang, Jianguang Wei, Yinhua Liu, Quanshu Zeng, Jingde Lin, Jiangtao Li

Shale reservoirs have complex mineral compositions and are rich in micro-scale pores. It is of great scientific and engineering significance to explore the mechanism of external fluids on the pore throat structure of shale. In this paper, pure carbonaceous shale is taken as the research object, and the mechanism of the influence of slip water and reflux fluid on the pore throat structure is analyzed by using nuclear magnetic resonance (NMR) technology. Then, the sensitivity of different types of shale to external fluids is comparatively analyzed and summarized. The results show that (1) the oil slick has a certain effect on the total porosity of different types of shale. The rate of change is shown as carbonaceous shale (− 7.1%) > pure shale (− 1.6%). (b) For slickwater, the average reduction of macro- and micro/nanopores in carbonaceous shale is 90.0% and 5.0%, respectively, while the average reduction of macro- and mesopores in pure shale is 17.7% and 6.8%, respectively. (c) Total porosity of different shale types is insensitive to refluxing fluids. The average increase in macro-, meso-, and small pores of carbonaceous shale is 31.8%, 23.6%, and 20.2%, respectively; the average increase in macro- and small pores of pure shale is 17.1%.

页岩储层具有复杂的矿物成分和丰富的微尺度孔隙。探索外部流体对页岩孔喉结构的影响机理具有重要的科学和工程意义。本文以纯碳质页岩为研究对象,利用核磁共振(NMR)技术分析了滑移水和回流液对孔喉结构的影响机理。然后,对比分析并总结了不同类型页岩对外部流体的敏感性。结果表明:(1) 浮油对不同类型页岩的总孔隙度有一定影响。变化率表现为碳质页岩(-7.1%)> 纯页岩(-1.6%)。(b) 对于浮油,碳质页岩的大孔和微孔/纳米孔的平均减少量分别为 90.0% 和 5.0%,而纯页岩的大孔和中孔的平均减少量分别为 17.7% 和 6.8%。(c) 不同类型页岩的总孔隙率对回流流体不敏感。碳质页岩的大孔隙、中孔隙和小孔隙的平均增幅分别为 31.8%、23.6% 和 20.2%;纯页岩的大孔隙和小孔隙的平均增幅为 17.1%。
{"title":"Experimental study on the influence of external fluids on the pore structure of carbonaceous shale","authors":"Ying Yang, Jianguang Wei, Yinhua Liu, Quanshu Zeng, Jingde Lin, Jiangtao Li","doi":"10.1007/s40948-024-00806-5","DOIUrl":"https://doi.org/10.1007/s40948-024-00806-5","url":null,"abstract":"<p>Shale reservoirs have complex mineral compositions and are rich in micro-scale pores. It is of great scientific and engineering significance to explore the mechanism of external fluids on the pore throat structure of shale. In this paper, pure carbonaceous shale is taken as the research object, and the mechanism of the influence of slip water and reflux fluid on the pore throat structure is analyzed by using nuclear magnetic resonance (NMR) technology. Then, the sensitivity of different types of shale to external fluids is comparatively analyzed and summarized. The results show that (1) the oil slick has a certain effect on the total porosity of different types of shale. The rate of change is shown as carbonaceous shale (− 7.1%) &gt; pure shale (− 1.6%). (b) For slickwater, the average reduction of macro- and micro/nanopores in carbonaceous shale is 90.0% and 5.0%, respectively, while the average reduction of macro- and mesopores in pure shale is 17.7% and 6.8%, respectively. (c) Total porosity of different shale types is insensitive to refluxing fluids. The average increase in macro-, meso-, and small pores of carbonaceous shale is 31.8%, 23.6%, and 20.2%, respectively; the average increase in macro- and small pores of pure shale is 17.1%.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"37 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926834","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and numerical simulation investigation of the deformation characteristics of vertical boreholes under non-uniform horizontal principal stress 非均匀水平主应力作用下垂直钻孔变形特性的实验和数值模拟研究
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-03 DOI: 10.1007/s40948-024-00799-1
Xinxin Fang, Sijie Ma, Yunhong Wang, Fengling Li

To study borehole deformation under non-uniform horizontal principal stress in the deep strata, a prediction method for horizontal principal stress was developed based on the morphological parameters of boreholes, the deformation trajectory equation for the standard circular borehole was derived based on elasticity theory, and the morphological characteristics of boreholes were analyzed. Additionally, a quantitative relationship between the geometric parameters of elliptical boreholes and horizontal principal stress was established. Subsequently, uniaxial tests on borehole deformation were conducted to verify elliptical deformation under non-uniform horizontal principal stress. A combined deductive, experimental, and numerical simulation approach to borehole deformation analysis was adopted, and the impact factors of borehole deformation were obtained. The results indicated as following: (1) the deformation morphology of borehole under non-uniform horizontal principal stress was elliptical; (2) for the given lithology, the greater the difference in horizontal principal stress, the greater were the ellipticity and elliptical deformation of borehole; (3) for given stress background, rock strength was inversely proportional to ellipticity. Additionally, the smaller the Young’s modulus and compressive strength, the larger was the Poisson’s ratio and the larger was the ellipticity. For example, the ellipticity of mudstone and coal was greater than that of limestone and sandstone; (4) with an increase in load, the displacement of borehole wall exhibited three stages: initial micro-deformation, accelerated deformation, and stable deformation; (5) horizontal principal stress can be calculated by using the morphological parameters (long and short axes) of an elliptical hole. Furthermore, a horizontal principal stress method theory can be developed based on the morphological parameters of boreholes. The results of our study can provide new ideas and methods for the measurement of in situ stress in deep boreholes and a theoretical basis for the development of equipment for measuring elliptical boreholes.

为研究深部地层非均匀水平主应力作用下的钻孔变形,建立了基于钻孔形态参数的水平主应力预测方法,基于弹性理论推导了标准圆形钻孔的变形轨迹方程,并分析了钻孔的形态特征。此外,还建立了椭圆钻孔几何参数与水平主应力之间的定量关系。随后,对钻孔变形进行了单轴试验,以验证非均匀水平主应力下的椭圆变形。采用演绎、实验和数值模拟相结合的方法进行钻孔变形分析,并得出了钻孔变形的影响因素。结果表明(1)在非均匀水平主应力作用下,钻孔的变形形态为椭圆形;(2)在给定岩性下,水平主应力差越大,钻孔的椭圆度和椭圆变形越大;(3)在给定应力背景下,岩石强度与椭圆度成反比。此外,杨氏模量和抗压强度越小,泊松比越大,椭圆度越大。例如,泥岩和煤的椭圆度大于石灰岩和砂岩的椭圆度;(4)随着荷载的增加,孔壁位移表现出三个阶段:初始微变形、加速变形和稳定变形;(5)利用椭圆孔的形态参数(长轴和短轴)可以计算出水平主应力。此外,还可根据钻孔的形态参数建立水平主应力法理论。我们的研究结果可以为深孔原位应力测量提供新的思路和方法,并为开发椭圆孔测量设备提供理论依据。
{"title":"Experimental and numerical simulation investigation of the deformation characteristics of vertical boreholes under non-uniform horizontal principal stress","authors":"Xinxin Fang, Sijie Ma, Yunhong Wang, Fengling Li","doi":"10.1007/s40948-024-00799-1","DOIUrl":"https://doi.org/10.1007/s40948-024-00799-1","url":null,"abstract":"<p>To study borehole deformation under non-uniform horizontal principal stress in the deep strata, a prediction method for horizontal principal stress was developed based on the morphological parameters of boreholes, the deformation trajectory equation for the standard circular borehole was derived based on elasticity theory, and the morphological characteristics of boreholes were analyzed. Additionally, a quantitative relationship between the geometric parameters of elliptical boreholes and horizontal principal stress was established. Subsequently, uniaxial tests on borehole deformation were conducted to verify elliptical deformation under non-uniform horizontal principal stress. A combined deductive, experimental, and numerical simulation approach to borehole deformation analysis was adopted, and the impact factors of borehole deformation were obtained. The results indicated as following: (1) the deformation morphology of borehole under non-uniform horizontal principal stress was elliptical; (2) for the given lithology, the greater the difference in horizontal principal stress, the greater were the ellipticity and elliptical deformation of borehole; (3) for given stress background, rock strength was inversely proportional to ellipticity. Additionally, the smaller the Young’s modulus and compressive strength, the larger was the Poisson’s ratio and the larger was the ellipticity. For example, the ellipticity of mudstone and coal was greater than that of limestone and sandstone; (4) with an increase in load, the displacement of borehole wall exhibited three stages: initial micro-deformation, accelerated deformation, and stable deformation; (5) horizontal principal stress can be calculated by using the morphological parameters (long and short axes) of an elliptical hole. Furthermore, a horizontal principal stress method theory can be developed based on the morphological parameters of boreholes. The results of our study can provide new ideas and methods for the measurement of in situ stress in deep boreholes and a theoretical basis for the development of equipment for measuring elliptical boreholes.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"2 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926835","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Predicting the compressive strength of tight sandstone based on the low field NMR and pseudo-triaxial compression measurements 基于低场核磁共振和伪三轴压缩测量预测致密砂岩的抗压强度
IF 5 2区 工程技术 Q3 ENERGY & FUELS Pub Date : 2024-05-03 DOI: 10.1007/s40948-024-00805-6
Xinmin Ge, Renxia Zhang, Jianyu Liu, Yiren Fan, Michael Myers, Lori Hathon

The compressive strength is very important for petroleum and other engineering studies. However, the effect of pore size and fluid distribution on the rock’s strength is not fully understood. We developed comprehensive research to study the controlling factors of the compressive strength based on low field nuclear magnetic resonance (NMR) measurements and pseudo-triaxial compression test for tight sandstones. The relationship between the compressive strength and the NMR obtained parameters are investigated completely, aiming for a better estimation of the compressive strength using the NMR data. The result shows that the rock’s strength is strongly controlled by the pore size distribution and the fluid existing state. Generally, the compressive strength is negatively correlated with the average transversal relaxation time, the movable water saturation, and the porosity, but positively correlated with the irreducible water saturation. The result reveals that the rock with larger pore radius and higher percentage of movable fluid is easier to reach the failure state. Further, the precision of the empirical model by multiple regression of the geometric mean of the relaxation time and the porosity is greatly improved compared with the model established by the brittle minerals, which is potentially to be use for geophysical prospecting when the NMR logging data is available.

抗压强度对石油和其他工程研究非常重要。然而,孔隙大小和流体分布对岩石强度的影响尚未得到充分了解。我们基于低场核磁共振(NMR)测量和致密砂岩伪三轴压缩试验,开展了抗压强度控制因素的综合研究。全面研究了抗压强度与核磁共振所获参数之间的关系,旨在利用核磁共振数据更好地估算抗压强度。结果表明,岩石的强度受孔隙大小分布和流体存在状态的强烈控制。一般来说,抗压强度与平均横向弛豫时间、可动水饱和度和孔隙度呈负相关,而与不可还原水饱和度呈正相关。结果表明,孔隙半径越大、可动流体比例越高的岩石越容易达到破坏状态。此外,与脆性矿物建立的模型相比,通过对弛豫时间和孔隙度的几何平均值进行多元回归而建立的经验模型的精度大大提高,在获得核磁共振测井数据时,该模型可用于地球物理勘探。
{"title":"Predicting the compressive strength of tight sandstone based on the low field NMR and pseudo-triaxial compression measurements","authors":"Xinmin Ge, Renxia Zhang, Jianyu Liu, Yiren Fan, Michael Myers, Lori Hathon","doi":"10.1007/s40948-024-00805-6","DOIUrl":"https://doi.org/10.1007/s40948-024-00805-6","url":null,"abstract":"<p>The compressive strength is very important for petroleum and other engineering studies. However, the effect of pore size and fluid distribution on the rock’s strength is not fully understood. We developed comprehensive research to study the controlling factors of the compressive strength based on low field nuclear magnetic resonance (NMR) measurements and pseudo-triaxial compression test for tight sandstones. The relationship between the compressive strength and the NMR obtained parameters are investigated completely, aiming for a better estimation of the compressive strength using the NMR data. The result shows that the rock’s strength is strongly controlled by the pore size distribution and the fluid existing state. Generally, the compressive strength is negatively correlated with the average transversal relaxation time, the movable water saturation, and the porosity, but positively correlated with the irreducible water saturation. The result reveals that the rock with larger pore radius and higher percentage of movable fluid is easier to reach the failure state. Further, the precision of the empirical model by multiple regression of the geometric mean of the relaxation time and the porosity is greatly improved compared with the model established by the brittle minerals, which is potentially to be use for geophysical prospecting when the NMR logging data is available.</p>","PeriodicalId":12813,"journal":{"name":"Geomechanics and Geophysics for Geo-Energy and Geo-Resources","volume":"122 1","pages":""},"PeriodicalIF":5.0,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140926723","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Geomechanics and Geophysics for Geo-Energy and Geo-Resources
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1