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Mechanism for formation of porcine blood hydrogels used as additives in the mortar of traditional Chinese architectural painting 用作中国传统建筑绘画砂浆添加剂的猪血水凝胶的形成机理
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-03-01 DOI: 10.1186/s40494-024-01191-8
Cong Cheng, Yeting Zhu, Jingyi Zhang, Wei Li, Gele Teri, Lizhen Zheng, Daodao Hu

Ancient Chinese architecture drawing is a unique form of ancient Chinese art. Porcine blood hydrogels are distinctive ingredients used to prepare the composite material of the substrate layer for architecture drawing. This investigation was focused on the mechanism for porcine blood hydrogel formation. Based on the traditional Chinese recipe for the preparation of porcine blood-lime mortar, samples with different ratios of porcine blood and lime water were prepared, and the molecular-scale interactions between the lime water and proteins in the porcine blood were examined with FTIR spectroscopy, Raman spectroscopy, XRD, XPS, fluorescence spectroscopy, contact angle and rheology studies. The mechanical properties and morphological features of the samples were detected with a rheometer, universal material testing machine and SEM. The results indicated that an appropriate amount of lime water was required for gelation of the porcine blood. With the appropriate alkalinity, sufficient carboxyl groups on the fibrin chains were deprotonated, and coordination with Ca2+ ions formed enough cross-links for support networks within the structure of the porcine blood hydrogel. Complexation of deprotonated carboxyl groups on the fibrin chains with Ca2+ ions led to the formation of a hydrophobic surface due alterations of the fibrin conformation and increased the adhesive properties of the hydrogel. With the hydrogel used as an ingredient in the preparation of a substrate layer composite, it is suggested that the hydrophobic surface of the hydrogel facilitated mixing with hydrophobic tung oil during preparation of the composite material, and strong adhesion of the hydrogel increased the mechanical strength and crack resistance of the substrate layer.

中国古代建筑图画是中国古代艺术的一种独特形式。猪血水凝胶是制备建筑绘画基底层复合材料的独特成分。本次研究的重点是猪血水凝胶的形成机理。根据中国传统的猪血石灰浆制备配方,制备了不同比例的猪血和石灰水样品,并通过傅立叶变换红外光谱、拉曼光谱、XRD、XPS、荧光光谱、接触角和流变学研究,考察了石灰水和猪血中蛋白质之间的分子尺度相互作用。流变仪、万能材料试验机和扫描电镜检测了样品的机械性能和形态特征。结果表明,猪血凝胶化需要适量的石灰水。在适当的碱度下,纤维蛋白链上足够的羧基被去质子化,并与 Ca2+ 离子配位形成足够的交联,从而在猪血水凝胶的结构中形成支撑网络。纤维蛋白链上的去质子化羧基与 Ca2+ 离子络合后,由于纤维蛋白构象的改变而形成了疏水表面,并增强了水凝胶的粘合性能。将水凝胶用作制备基底层复合材料的成分,表明水凝胶的疏水表面有利于在制备复合材料时与疏水桐油混合,水凝胶的强粘附性提高了基底层的机械强度和抗裂性。
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引用次数: 0
Hyperspectral imaging and convolutional neural networks for augmented documentation of ancient Egyptian artefacts 高光谱成像和卷积神经网络用于古埃及文物的扩增记录
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-03-01 DOI: 10.1186/s40494-024-01182-9
Costanza Cucci, Tommaso Guidi, Marcello Picollo, Lorenzo Stefani, Lorenzo Python, Fabrizio Argenti, Andrea Barucci

The study aims at investigating the use of reflectance Hyperspectral Imaging (HSI) in the Visible (Vis) and Near Infrared (NIR) range in combination with Deep Convolutional Neural Networks (CNN) to address the tasks related to ancient Egyptian hieroglyphs recognition. Recently, well-established CNN architectures trained to address segmentation of objects within images have been successfully tested also for trial sets of hieroglyphs. In real conditions, however, the surfaces of the artefacts can be highly degraded, featuring corrupted and scarcely readable inscriptions which highly reduce the CNNs capabilities in automated recognition of symbols. In this study, the use of HSI technique in the extended Vis-NIR range is proposed to retrieve readability of degraded symbols by exploiting spectral images. Using different algorithmic chains, HSI data are processed to obtain enhanced images to be fed to the CNN architectures. In this pilot study, an ancient Egyptian coffin (XXV Dynasty), featuring a degraded hieroglyphic inscription, was used as a benchmark to test, in real conditions, the proposed methodological approaches. A set of Vis-NIR HSI data acquired on-site, in the framework of a non-invasive diagnostic campaign, was used in combination with CNN architectures to perform hieroglyphs segmentation. The outcomes of the different methodological approaches are presented and compared to each other and to the results obtained using standard RGB images.

本研究旨在调查可见光(Visible)和近红外(NIR)范围内反射率高光谱成像(HSI)与深度卷积神经网络(CNN)的结合使用情况,以解决与古埃及象形文字识别相关的任务。最近,针对图像内物体分割而训练的成熟 CNN 架构也成功地在象形文字试验集上进行了测试。然而,在现实条件下,文物的表面可能会严重退化,碑文被损坏且几乎不可读,这大大降低了 CNN 自动识别符号的能力。本研究提出在扩展的可见光-近红外范围内使用 HSI 技术,通过利用光谱图像来检索退化符号的可读性。通过使用不同的算法链,对 HSI 数据进行处理以获得增强图像,并将其输入 CNN 架构。在这项试验性研究中,使用了一具古埃及棺材(二十五王朝)作为基准,在真实条件下测试所提出的方法。在非侵入性诊断活动框架内现场获取的一组可见光-近红外 HSI 数据与 CNN 架构相结合,用于执行象形文字分割。本文介绍了不同方法的结果,并将其与使用标准 RGB 图像获得的结果进行了比较。
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引用次数: 0
Application of computer vision technology in surface damage detection and analysis of shedthin tiles in China: a case study of the classical gardens of Suzhou 计算机视觉技术在中国薄瓦表面损伤检测和分析中的应用:苏州古典园林案例研究
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-29 DOI: 10.1186/s40494-024-01185-6
Lina Yan, Yile Chen, Liang Zheng, Yi Zhang

In computer artificial intelligence, there is great potential in research on the protection of Suzhou's traditional gardens, a world cultural heritage site. As a special material in Suzhou's traditional garden architecture, shedthin tile is widely used in roof base laying and is one of the important materials for building roofs. However, professionals need to reach the roof and spend much time and effort assessing the damage before repairing it. Therefore, the main goals of this study are to investigate a machine learning-based method for finding targets and determining the type of surface damage on a shedthin tile using the YOLOv4 model trained in this study. Using 500 shedthin tile on-site photos as training samples, the model was trained for 750 epochs. The main results of this study are as follows: (1) An object detection method based on machine learning can efficiently and accurately identify damage content, overcoming the manpower and time–cost limitations of traditional assessment methods. (2) The detection model in this study has an accuracy of 85.89% for water stain recognition of shedthin tiles, 93.29% for surface scaling, 87.37% for color aberration, and 96.15% for too wide a gap. The comprehensive accuracy is 90.20%, which meets the basic testing requirements. (3) The model demonstrated its robustness and reliability in complex environments in application tests in actual scenarios, providing a methodological reference for computer vision and target detection technology in cultural heritage protection.

在计算机人工智能领域,对世界文化遗产苏州传统园林的保护研究大有可为。作为苏州传统园林建筑中的一种特殊材料,筒瓦被广泛应用于屋顶基础铺设,是建筑屋顶的重要材料之一。然而,专业人员需要到达屋顶,花费大量时间和精力对损坏情况进行评估后才能进行修复。因此,本研究的主要目标是研究一种基于机器学习的方法,利用本研究中训练的 YOLOv4 模型寻找目标并确定薄瓦表面损坏的类型。使用 500 张薄板现场照片作为训练样本,对模型进行了 750 次历时训练。本研究的主要结果如下:(1) 基于机器学习的物体检测方法能够高效、准确地识别损坏内容,克服了传统评估方法在人力和时间成本上的限制。(2)本研究中的检测模型对脱落薄砖的水渍识别准确率为 85.89%,对表面结垢的识别准确率为 93.29%,对色差的识别准确率为 87.37%,对缝隙过大的识别准确率为 96.15%。综合准确率为 90.20%,满足基本测试要求。(3) 在实际场景的应用测试中,该模型证明了其在复杂环境下的鲁棒性和可靠性,为文化遗产保护中的计算机视觉和目标检测技术提供了方法参考。
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引用次数: 0
Mt. Ebal curse tablet? A refutation of the claims regarding the so called Mt. Ebal curse tablet 以巴山诅咒石碑?驳斥所谓以巴山诅咒石碑的说法
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-26 DOI: 10.1186/s40494-023-01130-z

Abstract

A refutation of the claims by Scott Stripling et al. regarding the epigraphic analysis and paleographic contents of the folded lead object discovered on Mt. Ebal in 2019 during the wet-sifting of dump piles from a previous archaeological excavation by Adam Zertal. This piece of lead is often referred to as the “Mt. Ebal Curse Tablet”. An article regarding this find, by Stripling et al., titled “You are Cursed by the God YHW:” an early Hebrew inscription from Mt. Ebal”, was published on May 23, 2023, in the Heritage Science journal.

摘要 对斯科特-斯特里普林(Scott Stripling)等人关于亚当-泽尔塔尔(Adam Zertal)2019 年在以巴山上对之前考古发掘的垃圾堆进行湿筛时发现的折叠铅块的书法分析和古文字学内容的说法进行驳斥。这块铅片通常被称为 "埃巴尔山诅咒石碑"。2023 年 5 月 23 日,《遗产科学》杂志发表了 Stripling 等人撰写的一篇关于这一发现的文章,题为 "You are Cursed by the God YHW:" an early Hebrew inscription from Mt.
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引用次数: 0
Sustainable development strategy for historic neighborhood shrinkage: taking Puhuiquan neighborhood in Yulin, China, as an example 历史街区萎缩的可持续发展战略:以中国榆林蒲汇泉街区为例
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-22 DOI: 10.1186/s40494-024-01180-x
Yuzhao Zhang, Shanshan Chen, Mark A. Hoistad

Western cities have been confronted with the challenges of 'urban shrinkage' as changes in economic and production models have caused population migrations. China, in its recent history, has experienced rapid and dynamic growth in its cities. However, as its economy is evolving, it too is being confronted with 'urban shrinkage' challenges. Populations have been shifting inside small and medium sized cities in response to problems created during this rapid growth period. Most heritage areas have suffered from depopulation, neglect and disinvestment. The historic Puhuiquan neighborhood in Yulin City is a classic example of the current Chinese version of 'urban shrinkage'. Yulin City, founded as a military city five centuries ago, has shifted its focus away from its historic purpose into a resource-based city. Yulin’s planning developed new areas, drawing population out of the historic Puhuiquan neighborhood. This area is the home to a unique urban cultural landscape where land and architecture have merged to create the development of various types of 'cave' houses. Suffering from the effects of 'urban shrinkage', this research explores the causes and potential solutions for the area employing both 'smart shrinkage' and 'urban renewal' strategies, informed by local resident participation, to develop a sustainable renewal strategy for this heritage area.

由于经济和生产模式的变化导致人口迁移,西方城市一直面临着 "城市萎缩 "的挑战。中国的城市在近代史上经历了快速而充满活力的发展。然而,随着经济的发展,中国也面临着 "城市萎缩 "的挑战。为了应对快速发展时期产生的问题,人口不断向中小城市转移。大多数遗产区都受到人口减少、忽视和投资减少的影响。榆林市历史悠久的蒲汇泉街区就是当前中国版 "城市萎缩 "的典型例子。五百年前,榆林市作为一座军事城市而建立,如今它的重心已从历史目的转移到资源型城市。榆林的规划开发了新的区域,将人口从历史悠久的蒲汇泉街区吸引出来。该地区形成了独特的城市文化景观,土地与建筑相融合,发展出各种类型的 "窑洞 "房屋。由于受到 "城市萎缩 "的影响,本研究通过当地居民的参与,采用 "智能萎缩 "和 "城市更新 "两种策略,探索该地区的原因和潜在解决方案,为这一遗产地区制定可持续的更新策略。
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引用次数: 0
Deep learning based approaches from semantic point clouds to semantic BIM models for heritage digital twin 基于深度学习的从语义点云到语义 BIM 模型的遗产数字孪生方法
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-21 DOI: 10.1186/s40494-024-01179-4

Abstract

This study focuses on the application of deep learning for transforming semantic point clouds into semantic Building Information Models (BIM) to create a Heritage Digital Twin, centering on Taoping Village, a site of historical and cultural significance in Sichuan, China. Utilizing advanced technologies such as unmanned aerial vehicles and terrestrial laser scanning, we capture detailed point cloud data of the village. A pivotal element of our methodology is the KP-SG neural network, which exhibits outstanding overall performance, particularly excelling in accurately identifying 11 categories. Among those categories, buildings and vegetation, achieves recognition rates of 81% and 83% respectively, and a 2.53% improvement in mIoU compared to KP-FCNN. This accuracy is critical for constructing detailed and accurate semantic BIM models of Taoping Village, facilitating comprehensive architecture and landscape analysis. Additionally, the KP-SG’s superior segmentation capability contributes to the creation of high-fidelity 3D models, enriching virtual reality experiences. We also introduce a digital twin platform that integrates diverse datasets, their semantic information, and visualization tools. This platform is designed to support process automation and decision-making and provide immersive experiences for tourists. Our approach, integrating semantic BIM models and a digital twin platform, marks a significant advancement in preserving and understanding traditional villages like Taoping and demonstrates the transformative potential of deep learning in cultural heritage conservation.

摘要 本研究的重点是应用深度学习将语义点云转换为语义建筑信息模型(BIM),以创建遗产数字孪生体,其中心是中国四川具有历史和文化意义的桃坪村。利用无人机和地面激光扫描等先进技术,我们捕捉到了该村的详细点云数据。KP-SG 神经网络是我们研究方法中的一个关键要素,它表现出了卓越的整体性能,尤其擅长于准确识别 11 个类别。其中,建筑物和植被的识别率分别达到 81% 和 83%,与 KP-FCNN 相比,mIoU 提高了 2.53%。这一准确率对于构建详细、准确的桃坪村语义 BIM 模型至关重要,有助于进行全面的建筑和景观分析。此外,KP-SG 卓越的分割能力有助于创建高保真三维模型,丰富虚拟现实体验。我们还介绍了一个数字孪生平台,该平台整合了各种数据集、其语义信息和可视化工具。该平台旨在支持流程自动化和决策,并为游客提供身临其境的体验。我们的方法整合了语义 BIM 模型和数字孪生平台,标志着在保护和理解像桃坪这样的传统村落方面取得了重大进展,并展示了深度学习在文化遗产保护方面的变革潜力。
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引用次数: 0
Changes and continuity in pottery production and use at Wujiafentou in the core zone of Youziling and Shijiahe cultures in central China 中国中部游子陵文化和石家河文化核心区吴家场头陶器生产和使用的变迁与延续
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-20 DOI: 10.1186/s40494-024-01181-w
Zichen Xie, Ying Hu, Siwei Shan, Qin-Qin Lü, Feiyong Yuan, Tao Li

The Wujiafentou site is located at the heart of the Youziling (5900–5500 cal BP) and Shijiahe (4500–4200 cal BP) cultures in the Handong region, a core area to understand the relationship among economic networks, sociopolitical integration, and regional identity in the middle Yangtze River valley (MYRV) of central China during the Late Neolithic times. Its pottery assemblages are important clues to understanding the pottery production and use before and after the extensive walled town construction activities in the Neolithic MYRV. Wujiafentou is less than 5 km from the Shijiahe walled town, the largest city of its time in the MYRV. This paper applies microscopic examination and chemical and mineralogical analyses to a sample of 152 sherds of the Youziling-period and Shijiahe-period utilitarian vessels unearthed from the Wujiafentou site, revealing the changes and continuity in pottery production and use over time. We also probe into the socio-economic ties between Wujiafentou and the Shijiahe walled town mainly through hong tao bei (red clay cups), which were widely distributed and presumably highly symbolic items of the Shijiahe culture related to drinking, feasts, and rituals. We propose that the Wujiafentou inhabitants produced their red clay cups by mimicking those made within the Shijiahe walled town. Our study highlights an alternative interpretation of the formation of a regional identity during the Shijiahe period.

吴家棚头遗址位于汉东地区游子陵文化(公元前5900-5500年)和石家河文化(公元前4500-4200年)的中心地带,是了解新石器时代晚期中国中部长江中游流域(MYRV)经济网络、社会政治一体化和区域认同之间关系的核心区域。其陶器组合是了解新石器时代长江中游地区大规模城墙建筑活动前后陶器生产和使用情况的重要线索。吴家场头距离石家河城墙不足 5 公里,而石家河城墙是当时马约河谷地区最大的城市。本文对吴家峁遗址出土的游子陵时期和石家河时期的 152 件实用器皿进行了显微镜观察和化学、矿物分析,揭示了陶器生产和使用在时间上的变化和延续。我们还主要通过红陶杯探究了吴家畈头与石家河城墙之间的社会经济联系,红陶杯是石家河文化中与饮酒、宴席和祭祀有关的物品,分布广泛,应该具有很强的象征意义。我们认为,吴家棚头居民是模仿石家河城墙内的红陶杯制作红陶杯的。我们的研究强调了对石家河时期区域特征形成的另一种解释。
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引用次数: 0
Scenery deconstruction: a new approach to understanding the historical characteristics of Nanjing cultural landscape 景观解构:理解南京文化景观历史特征的新方法
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-20 DOI: 10.1186/s40494-024-01177-6
Wenzheng Zhang, Yiwei Wang, Lin Fu, Yike Hu

The “Eight Scenic Views Paintings” represent crucial visual materials for investigating the history of cultural landscapes. However, traditional methods of interpreting materials struggle to discern the inherent connections between different landscape elements. This study proposes an approach for deconstructing historical images, taking the example of the Forty Scenic Views in the Late Ming Dynasty in Nanjing, China. To explore the co-occurrence structure, hierarchical clustering, and correlation features among various elements, various digital humanities quantification methods were applied, including spatial analysis of ArcGIS, co-occurrence and clustering of KH Coder, and correlation analysis of SPSS. This study reveals the characteristics of the landscape construction of Nanjing in the Late Ming: natural landscape as the foundation, artificial landscape as the core, and advocating tradition as the fashion. It also uncovers the landscape order: mountains, waters, and scenic views interweaved and coexisted, as well as nature and culture intertwined and clustered. In addition, multiple information graphs of the subordinate and co-occurrence relationships of 20 landscape elements were constructed, 5 landscape paradigms were extracted, and 36 pairs of related relationships were discovered, deepening the historical understanding of the urban landscape construction of Nanjing in the Late Ming. This paper puts forward the idea of analyzing historical images by digital method, which provides some essential and detailed historical basis for explaining the value of cultural landscape heritage and shaping contemporary urban landscape.

八景图 "是研究文化景观历史的重要视觉材料。然而,传统的材料解读方法难以发现不同景观元素之间的内在联系。本研究以中国南京明末《四十景图》为例,提出了一种解构历史图像的方法。为了探索各要素之间的共现结构、层次聚类和相关性特征,应用了多种数字人文量化方法,包括 ArcGIS 的空间分析、KH Coder 的共现和聚类以及 SPSS 的相关性分析。本研究揭示了晚明南京景观建设的特点:以自然景观为基础,以人工景观为核心,以崇尚传统为时尚。同时也揭示了景观秩序:山、水、景交织并存,自然与文化交织集聚。此外,还构建了20个景观要素的从属关系和共生关系的多重信息图,提取了5种景观范式,发现了36对关联关系,深化了对晚明南京城市景观建设的历史认识。本文提出了用数字化方法分析历史影像的思路,为解释文化景观遗产价值、塑造当代城市景观提供了一些必要而详实的历史依据。
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引用次数: 0
Comparative study: enhancing legibility of ancient Indian script images from diverse stone background structures using 34 different pre-processing methods 比较研究:使用 34 种不同的预处理方法提高不同石材背景结构的古印度文字图像的可读性
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-20 DOI: 10.1186/s40494-024-01169-6
J. Jayanthi, P. Uma Maheswari

In recent times, there has been a proactive effort by various institutions and organizations to preserve historic manuscripts as repositories of traditional knowledge and cultural heritage. Leveraging digital media and emerging technologies has proven to be an efficient way to safeguard these invaluable documents. Such technologies not only facilitate the extraction of knowledge from historic manuscripts but also hold promise for global applications. However, transforming inscribed stone artifacts into binary formats presents significant challenges due to angle distortion, subtle differences between foreground and background, background noise, variations in text size, and related issues. A pivotal aspect of effective image processing in preserving the rich information and wisdom encoded in stone inscriptions lies in employing appropriate pre-processing methods and techniques. This research paper places a special focus on elucidating various preprocessing techniques, encompassing resizing, grayscale conversion, enhancement of brightness and contrast, smoothening, noise removal, morphological operations, and thresholding. To comprehensively assess these techniques, we undertake a study involving stone inscription images extracted from the Tanjore Brihadeeswar Temple, dating back to the eleventh century during the reign of Raja Raja Chola. This choice is informed by the manifold challenges associated with image correction, such as distortion and blurring. We undertake an evaluation encompassing a diverse array of stone background structures, including types like flawless-bright-moderately legible, dark-illegible, flawless-bright-illegible, flawless-dull, flawless-irregular-moderate, highly impaired-dark-legible, highly impaired-irregular-illegible, impaired-dark-moderate, impaired-dull-moderately legible, impaired-dusky dark-moderate, and very impaired-dusky dark-legible. Subsequently, the processed outputs are subjected to character recognition and information extraction, with a focus on comparing the outcomes of various pre-processing methods, including binarization and grayscale conversion. This study seeks to contribute insights into the most effective pre-processing strategies for enhancing the legibility and preservation of ancient Indian script images etched onto diverse stone background structures.

近来,各种机构和组织都在积极努力保护作为传统知识和文化遗产宝库的历史手稿。事实证明,利用数字媒体和新兴技术是保护这些宝贵文献的有效途径。这些技术不仅有助于从历史手稿中提取知识,而且有望在全球范围内得到应用。然而,由于角度失真、前景和背景之间的细微差别、背景噪音、文字大小的变化以及相关问题,将石刻文物转换为二进制格式面临着巨大的挑战。要有效地进行图像处理以保存石刻中的丰富信息和智慧,关键在于采用适当的预处理方法和技术。本研究论文特别注重阐明各种预处理技术,包括调整大小、灰度转换、增强亮度和对比度、平滑处理、去噪、形态学操作和阈值处理。为了全面评估这些技术,我们进行了一项研究,涉及从坦乔尔布里哈德斯瓦神庙(Tanjore Brihadeeswar Temple)提取的石刻图像,其历史可追溯到十一世纪拉贾-乔拉(Raja Raja Chola)统治时期。这一选择是基于图像校正所面临的多重挑战,如失真和模糊。我们对各种不同的石材背景结构进行了评估,包括无瑕疵-明亮-中等可读、暗色-不可读、无瑕疵-明亮-不可读、无瑕疵-暗色、无瑕疵-不规则-中等、高度受损-暗色-可读、高度受损-不规则-不可读、受损-暗色-中等、受损-暗色-中等可读、受损-暗色-中等和极度受损-暗色-可读等类型。随后,对处理后的输出结果进行字符识别和信息提取,重点是比较各种预处理方法(包括二值化和灰度转换)的结果。本研究旨在深入探讨最有效的预处理策略,以提高蚀刻在不同石头背景结构上的古印度文字图像的可读性和保存性。
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引用次数: 0
Correlation study on firing temperature and color of plain pottery excavated from the Tang Dynasty tomb of Liu Jing in Shaanxi, China 中国陕西唐代刘敬墓出土素面陶器烧成温度与颜色的相关性研究
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-02-19 DOI: 10.1186/s40494-024-01178-5

Abstract

Plain pottery excavated from the Tang Dynasty tomb of Liu Jing was taken as the research object. The color, chemical composition, microstructure, and phase were tested to investigate the influencing factors of color for plain pottery fragments. The results indicated that the contents of Fe2O3 and TiO2 in all fragments varied little, and the influence of humic acids in clay as well as the firing atmosphere on the appearance color of plain pottery was excluded. Therefore, the main factor affecting color saturation (C*) was identified as the firing temperature (T). More importantly, the correlation between C* and firing temperature was established by replicas fired at different temperatures. Before the appearance of the glass phase, iron-containing minerals played a major role in coloring, and after that, iron ions in the glass phase and iron crystallization rose the important function of coloring. Consequently, with the increase of firing temperature, C* value increased firstly and then decreased. The inflection point of the fitted C* − T curve corresponded to the glass phase formation temperature. By comparing the estimated firing temperatures obtained by the fitted C* − T correlation curve with the known firing temperature of replicas, it was demonstrated that the color measurement is an ideal method for deducing the firing temperatures of ancient plain pottery.

摘要 以唐代刘敬墓出土的素陶为研究对象。从颜色、化学成分、微观结构和物相等方面对素陶残片的颜色影响因素进行了测试。结果表明,所有碎片中 Fe2O3 和 TiO2 的含量变化不大,排除了陶土中腐殖酸和烧成气氛对素陶外观颜色的影响。因此,影响颜色饱和度(C*)的主要因素被确定为烧成温度(T)。更重要的是,通过在不同温度下烧制的复制品,确定了 C* 与烧制温度之间的相关性。在玻璃相出现之前,含铁矿物在着色中起着主要作用,而在玻璃相出现之后,玻璃相中的铁离子和铁结晶则上升为着色的重要功能。因此,随着焙烧温度的升高,C*值先升高后降低。拟合的 C* - T 曲线的拐点与玻璃相形成温度相对应。通过将拟合 C* - T 相关曲线得到的估计烧成温度与已知复制品的烧成温度进行比较,证明颜色测量是推断古代素陶烧成温度的理想方法。
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