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Archaeological textiles preserved by copper mineralization 铜矿化保存的考古纺织品
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-28 DOI: 10.1186/s40494-024-01418-8
Rui Jia, Hailing Zheng, Haodong Chen, Min Feng, Jinpeng Jiao, Xiaojing Kang, Jianjun Yu, Bing Wang, Zhaoxia Zhang, Yang Zhou, Zhiqin Peng

The mineralization mechanism responsible for the fossilization of archaeological textiles in close proximity to metal artifacts presents a sophisticated preservation process at both macro and micro levels. This study examines archaeological textiles dating from 2200 BC to AD 1900, sourced from three distinct archaeological sites. The focus is on understanding the microstructural degradation of fibers within a specific burial environment and the preservation achieved through mineralization. These archaeological fibers of archaeological textiles exhibit morphological preservation in the immediate vicinity of copper-based objects. Utilizing tools such as a digital camera, scanning electron microscopy with energy dispersive spectroscopy (SEM–EDS), high-resolution synchrotron-based microtomography (μCT), and enzyme-linked immunosorbent assay (ELISA), we examined fiber morphology, conducted elemental analysis, identified fiber types, and analyzed fiber characteristics. Our findings reveal the presence of smooth-surfaced wools and silks, fibers covered with calculi, and fiber impressions—all subjected to mineralization. These mineralized fibers can be categorized into three distinct stages of mineralization, each exhibiting varying carbon content. We inferred a correlation between mineralization rate and carbon content while also identifying mineralization density distribution on these textiles. Lastly, this study provides insights into the preservation states of textiles across three different mineralization stages, enriching our understanding of the deterioration of organic archaeological material.

考古纺织品在靠近金属文物的地方形成化石,其矿化机制从宏观和微观两个层面展示了一个复杂的保存过程。本研究考察了公元前 2200 年至公元 1900 年的考古纺织品,这些纺织品来自三个不同的考古遗址。重点是了解纤维在特定埋藏环境中的微观结构退化以及通过矿化实现的保存。这些考古纺织品的考古纤维在铜制物品附近呈现出形态保存。我们利用数码相机、扫描电子显微镜与能量色散光谱仪(SEM-EDS)、高分辨率同步加速器显微层析成像(μCT)和酶联免疫吸附试验(ELISA)等工具,检查了纤维形态,进行了元素分析,确定了纤维类型,并分析了纤维特征。我们的研究结果表明,存在表面光滑的羊毛和蚕丝、被结石覆盖的纤维以及纤维印痕--所有这些都发生了矿化。这些矿化纤维可分为三个不同的矿化阶段,每个阶段的含碳量各不相同。我们推断出矿化率与碳含量之间的相关性,同时还确定了这些纺织品上的矿化密度分布。最后,这项研究为纺织品在三个不同矿化阶段的保存状态提供了见解,丰富了我们对有机考古材料老化的理解。
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引用次数: 0
Evaluation of indoor daylighting performance changes in a historical khan building in Istanbul 伊斯坦布尔一座历史悠久的坎儿井建筑室内采光性能变化评估
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-27 DOI: 10.1186/s40494-024-01409-9
Asli Agirbas, Ayse Ozlem Dal

The daylighting feature of historical buildings can be accepted as an intangible heritage since it contributes to the unique atmosphere of the buildings. However, with the change of the built environment and the change of the historical building itself, the level of daylight intake of historical buildings changes. This study contributes to the field by revealing the daylighting performance changes of a historical khan building which has a unique architectural characteristics. The changes in the daylighting levels of Buyuk Yeni Khan, one of the largest historical khans in Istanbul, are examined through its modifications. Using 3D Lidar scanning technology, the current state of the khan is scanned. The daylight intake and glare analyzes of the khan for its current and original states are made through simulations, and the values found are compared. DA, cDA, UDI, sDA and DGP metrics are used in the simulations. As a result, due to the changes such as enlargements along the arcades, additional overhangs and the change of window ratios of the facades of the rooms on the ground floor, the rooms of the khan have different daylighting values compared to its original state.

历史建筑的采光特征可以被视为一种非物质遗产,因为它有助于营造建筑的独特氛围。然而,随着建筑环境的变化和历史建筑本身的变化,历史建筑的采光水平也会发生变化。本研究通过揭示一座具有独特建筑特色的历史性坎儿井建筑的日照性能变化,为该领域做出了贡献。本研究通过对伊斯坦布尔最大的历史建筑之一 Buyuk Yeni Khan 的改造,对其日照水平的变化进行了研究。利用三维激光雷达扫描技术,对汗宫的现状进行了扫描。通过模拟,对当前和原始状态下的日光摄入量和眩光进行了分析,并对发现的数值进行了比较。模拟中使用了 DA、cDA、UDI、sDA 和 DGP 指标。结果显示,由于拱廊的扩大、悬挑的增加以及底层房间外墙窗户比例的改变等变化,大汗的房间与原始状态相比具有不同的采光值。
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引用次数: 0
The polder systems legacies in the early twentieth century affect the contemporary landscape in the Jianghan Plain of Hubei, China 二十世纪初遗留下来的围垦系统影响了中国湖北江汉平原的当代景观
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-27 DOI: 10.1186/s40494-024-01426-8
Yikai Li, Hemiao Dai, Zhiyun Dai, Li Zhang

The long-term interaction between the environment and humans has significantly shaped contemporary landscapes worldwide. As a heritage landscape, the polder is essential for understanding the impact of the past human activities on contemporary landscape on low-lying area of land. In this case study, we reconstructed the regional spatial distribution of the polders in the early twentieth century and examined their coherence over the past century using historical maps and other materials in the Jianghan Plain. The results revealed several key findings: (1) In the early twentieth century, there were 1571 polders covering an area of 11,826.1 km2 with a perimeter of 17,035.9 km. (2) These polders exhibited a J-shaped distribution, with few large-scale polders despite their substantial areas. (3) The shape of these polders reflected an ability to balance human needs and the natural environment. (4) Considerable regional differences in these polders were attributed to centuries-old interactions between humans and the environment. (5) The remnants of these early twentieth century polders have had a lasting influence on the contemporary landscape, particularly in rural areas. This case study underscores how taking into account a broader historical perspective can enhance our understanding of present-day landscapes and, more importantly, the role that past human actions have played in shaping them.

环境与人类之间的长期互动极大地塑造了世界各地的当代景观。围垦地作为一种遗产景观,对于了解过去人类活动对当代低洼地景观的影响至关重要。在本案例研究中,我们利用江汉平原的历史地图和其他资料,重建了二十世纪初圩田的区域空间分布,并考察了它们在过去一个世纪中的连贯性。研究结果显示了几个重要发现:(1)20 世纪初,江汉平原共有圩田 1571 个,面积 11826.1 平方公里,周长 17035.9 公里。(2) 这些圩田呈 "J "形分布,尽管面积很大,但大型圩田很少。(3) 这些圩田的形状反映了人类需求与自然环境之间的平衡能力。(4) 这些圩田的巨大区域差异归因于几个世纪以来人类与环境之间的相互作用。(5) 这些二十世纪早期围垦地的遗迹对当代景观,尤其是农村地区的景观产生了持久的影响。本案例研究强调了从更广阔的历史视角考虑问题,可以加深我们对当今景观的理解,更重要的是,可以加深我们对人类过去的行为在塑造这些景观方面所发挥的作用的理解。
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引用次数: 0
A multi-disciplinary analysis of the Portrait of Philip the Good in Dijon 对第戎《好人菲利普肖像》的多学科分析
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-26 DOI: 10.1186/s40494-024-01414-y
Jan Verheyen, David Buti, Laura Cartechini, Raffaella Fontana, Magdalena Iwanicka, Marco Raffaelli, Piotr Targowski

One of the finest fifteenth-century portraits of the Burgundian Duke Philip the Good resides in the Musée des Beaux-Arts in Dijon. This small yet exceptionally crafted panel holds significance for both historians and art historians alike. Surprisingly, prior to this study, the context, the dating and the authorship of the piece remained obscure, and the widely circulated hypothesis of it being “a copy of a lost portrait by Rogier van der Weyden” has never been corroborated by convincing arguments. Clarifying the context, dating and authorship of the painting were the primary objectives of the investigations discussed in the article. Therefore, this painting underwent a multidisciplinary investigation spanning both the positive and human sciences. Macro-XRF scans were conducted alongside hyperspectral reflectance scans, multispectral imaging in the visible and infrared range, and optical coherence tomography. These analyses were complemented by an art historical study. As a result, a precise delineation between authentic and retouched sections was achieved. This article does not merely present the various perspectives separately but constructs a coherent narrative based on all these foundations. This holistic multidisciplinary research methodology produced a clear account, albeit with some scope for future inquiry. The involvement of the painter Pieter Cristus was conclusively demonstrated. This painter, whether himself personally, an assistant in the workshop or a contemporary follower, is attributed to the genesis of this work, which is presumed to be not the original portrait but a contemporaneous copy, possibly commissioned by the Burgundian Duke himself. While we no longer remain in the dark and have lifted some veils, this study also paves the way for further investigation into this panel and the numerous other portraits of Philip the Good.

第戎美术馆收藏着十五世纪最精美的勃艮第公爵菲利普的肖像画之一。对于历史学家和艺术史学家来说,这幅小巧但工艺精湛的画板都具有重要意义。令人惊讶的是,在这项研究之前,该作品的背景、年代和作者一直模糊不清,而广为流传的关于它是 "罗吉尔-凡-德-魏登遗失肖像的复制品 "的假设也从未得到令人信服的论证。澄清这幅画的背景、年代和作者是本文讨论的调查工作的主要目标。因此,我们对这幅画进行了跨学科调查,涵盖了积极科学和人文科学。在进行宏观 XRF 扫描的同时,还进行了高光谱反射扫描、可见光和红外线范围内的多光谱成像以及光学相干断层扫描。艺术史研究对这些分析进行了补充。因此,对真迹和经过修饰的部分进行了精确的划分。本文并不只是分别介绍各种观点,而是在所有这些基础上构建了一个连贯的叙事。这种多学科的整体研究方法产生了清晰的叙述,尽管还存在一些未来研究的空间。画家彼得-克里斯图斯(Pieter Cristus)的参与得到了确凿的证明。据推测,这幅作品并非肖像原作,而是同时代的摹本,可能是勃艮第公爵本人委托绘制的。虽然我们已不再蒙在鼓里,揭开了一些面纱,但这项研究也为进一步研究这幅画以及菲利普-古德的其他众多肖像铺平了道路。
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引用次数: 0
Optimization of structural reinforcement assessment for architectural heritage digital twins based on LiDAR and multi-source remote sensing 基于激光雷达和多源遥感的建筑遗产数字双胞胎结构加固评估优化
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-23 DOI: 10.1186/s40494-024-01404-0
Yanru Shi, Ming Guo, Jiawei Zhao, Xuanshuo Liang, Xiaoke Shang, Ming Huang, Shuai Guo, Youshan Zhao

This study investigates the geometric modelling of architectural heritage digital twins constructed based on multi-source point cloud data and its effectiveness in structural reinforcement assessment. Particular emphasis has been placed on the use of static stiffness rules to identify areas of structural weakness in the geometric models of digital twins and the need for their reinforcement, in order to prevent potential structural problems and to ensure the long-term preservation of the built heritage. Taking Yingxian wooden pagoda as a study case, based on the collection of multi-source point cloud data, the digital twin geometric model is constructed through fine modelling, decoupling of digital models, and geometric transformation. This enhances the true reflection of the column-architrave structure morphology, providing a more accurate model for structural stress analysis. Based on verifying the accuracy of the digital twin geometric model, the instability conditions are identified through static stiffness rules and the deformation values at multiple points are analyzed, enabling precise identification of weak areas in the column-architrave structure. Two types of reinforcement measures are designed and simulated for the structural weak areas identified through the geometric modelling, and the optimal reinforcement scheme is obtained after detailed analysis, according to which specific adjustments and optimization strategies are proposed to enhance the overall stability and durability of the structure. The results showed that the maximum deformation value of 4.65 mm existed in column M2W23, which required reinforcement. Aluminum reinforcement reduced the deformation to 3.5 mm (24.7% reduction), while CFRP fabric reinforcement was more effective, reducing the deformation to 2.8 mm (39.7% reduction), showing high stability. The research results demonstrate the potential application of digital twin technology in architectural heritage preservation and restoration, providing methodological and empirical guidance for heritage preservation research.

本研究探讨了基于多源点云数据构建的建筑遗产数字孪生模型的几何建模及其在结构加固评估中的有效性。研究特别强调利用静态刚度规则来识别数字孪生建筑几何模型中的结构薄弱区域及其加固需求,以防止潜在的结构问题,确保建筑遗产的长期保护。以应县木塔为研究案例,在多源点云数据采集的基础上,通过精细建模、数字模型解耦、几何变换等方法构建数字孪生几何模型。这增强了柱拱结构形态的真实反映,为结构应力分析提供了更精确的模型。在验证数字孪生几何模型准确性的基础上,通过静态刚度规则识别失稳条件,分析多点变形值,从而精确识别柱拱结构的薄弱区域。针对几何建模确定的结构薄弱区域,设计并模拟了两种加固措施,经过详细分析得出了最优加固方案,并据此提出了具体的调整和优化策略,以提高结构的整体稳定性和耐久性。结果表明,M2W23 柱的最大变形值为 4.65 毫米,需要进行加固。铝加固将变形减小到 3.5 毫米(减小 24.7%),而 CFRP 织物加固更为有效,将变形减小到 2.8 毫米(减小 39.7%),显示出较高的稳定性。研究成果证明了数字孪生技术在建筑遗产保护和修复中的潜在应用,为遗产保护研究提供了方法论和经验指导。
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引用次数: 0
Archaeometa: leveraging blockchain for secure and scalable virtual museums in the metaverse Archaeometa:利用区块链在元宇宙中建立安全、可扩展的虚拟博物馆
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-23 DOI: 10.1186/s40494-024-01416-w
Omer Aziz, Muhammad Shoaib Farooq, Adel khelifi, Mahdia Shoaib

The rapid evolution of the digital landscape has catalyzed the integration of blockchain technology within the domain of cultural heritage, particularly in virtual museums within the Metaverse. This study introduces ArchaeoMeta, a novel framework designed to leverage blockchain technology to enhance security, authenticity, and visitor interaction in a virtual museum environment. Utilizing smart contracts deployed on the Ethereum Sepolia testnet, the framework manages visitor interactions and secures digital artifacts, addressing challenges associated with scalability and user experience under varying loads. The performance evaluation involved simulating user interactions, scaling up to ten thousand concurrent users, to assess the impact on transaction latency, gas usage, and blockchain size. Findings reveal significant scalability challenges, as transaction latency and blockchain size increased with the number of users, highlighting areas for optimization in managing high user traffic within the blockchain infrastructure. This study contributes to the understanding of blockchain applications in cultural heritage, suggesting that while ArchaeoMeta offers a robust platform for virtual museums, enhancements in scalability through layer-2 solutions or alternative blockchain platforms are essential for its practical implementation. The framework sets a precedent for future research in the convergence of blockchain technology and cultural heritage preservation, promising a transformative impact on how digital cultural experiences are curated and consumed.

数字景观的快速发展促进了区块链技术在文化遗产领域的整合,尤其是在元宇宙(Metaverse)中的虚拟博物馆。本研究介绍了ArchaeoMeta,这是一个新颖的框架,旨在利用区块链技术增强虚拟博物馆环境中的安全性、真实性和游客互动性。该框架利用部署在以太坊 Sepolia 测试网络上的智能合约,管理游客互动并保护数字文物,解决了在不同负载下与可扩展性和用户体验相关的挑战。性能评估包括模拟用户交互,将并发用户数量扩展到一万,以评估对交易延迟、气体使用和区块链大小的影响。研究结果表明,随着用户数量的增加,交易延迟和区块链大小也随之增加,这给可扩展性带来了巨大挑战,突出了在区块链基础设施内管理高用户流量的优化领域。这项研究有助于人们了解区块链在文化遗产中的应用,表明虽然 ArchaeoMeta 为虚拟博物馆提供了一个强大的平台,但通过第二层解决方案或替代区块链平台提高可扩展性对其实际实施至关重要。该框架为未来区块链技术与文化遗产保护的融合研究开创了先河,有望对数字文化体验的策划和消费方式产生变革性影响。
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引用次数: 0
Structural visualization analysis applied to the preservation of architectural heritage: the case of stilted houses in southwest Hubei, China 应用于建筑遗产保护的结构可视化分析:以中国湖北西南部的棚屋为例
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-23 DOI: 10.1186/s40494-024-01420-0
Cheng Qian, Tong Wang, Sihan Yu

Wooden buildings represent a unique aspect of China’s architectural heritage. However, over time, these buildings have suffered varying degrees of structural damage, particularly those located in China’s mountainous regions. Frequent natural disasters and inconvenient transportation further exacerbate the vulnerability of these structures. This study focuses on the typical wooden stilt houses found in the Wuling Mountain area of southwest Hubei. The different forms of columns and beams, as well as the overall structural symmetry of the stilt houses, were classified into five common structural types. Precise digital models were established via real photos and collected dimensional data, and these five models were evaluated for static, buckling, utilization, and ultimate limit states. The results indicate that: (1) overall symmetrical structures perform better than asymmetrical ones; (2) structures where all columns are grounded and act as support columns exhibit the best overall mechanical performance; and (3) transverse-tie beams(chuanfang) primarily serve a connecting role rather than a load-bearing role, thus an excess of transverse-tie beams(chuanfang) can reduce the stability of the building structure. Based on the analysis results, targeted protective measures and recommendations were proposed and verified through structural evaluations. These initiatives provide new methods and insights for the protection of architectural heritage.

木结构建筑是中国建筑遗产的一个独特方面。然而,随着时间的推移,这些建筑的结构遭到了不同程度的破坏,尤其是那些位于中国山区的建筑。频繁的自然灾害和不便的交通进一步加剧了这些建筑的脆弱性。本研究的重点是湖北西南部武陵山区的典型木结构棚屋。根据棚屋不同的柱梁形式和整体结构对称性,将其划分为五种常见的结构类型。通过真实照片和收集的尺寸数据建立了精确的数字模型,并对这五种模型进行了静态、屈曲、使用和极限状态评估。结果表明(1) 整体对称结构的性能优于非对称结构;(2) 所有柱子都接地并充当支撑柱的结构表现出最佳的整体力学性能;(3) 横向连系梁(川字梁)主要起连接作用而非承重作用,因此过多的横向连系梁(川字梁)会降低建筑结构的稳定性。根据分析结果,提出了有针对性的保护措施和建议,并通过结构评估进行了验证。这些举措为保护建筑遗产提供了新的方法和见解。
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引用次数: 0
Revealing ancient technology: a high-energy X-ray computed tomography examination of a Mesopotamian copper alloy head 揭示古代技术:美索不达米亚铜合金头的高能 X 射线计算机断层扫描检查
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-23 DOI: 10.1186/s40494-024-01417-9
J.-F. de Lapérouse, M. Eppihimer, A. Flisch, R. Zboray

Although the origins of lost wax casting extend back into the 5th millennium BCE, it was not until the development of hollow core casting that life-sized metal sculptures could be produced. Based on existing evidence, the earliest adoption of this technique, which involves the inclusion of a clay core within a wax model, occurred in Iraq (Mesopotamia) during the Early Dynastic III period (ca. 2600–2350 BCE). To date, only one hollow core casting from the succeeding Akkadian period (ca. 2350–2150 BCE)—the Sargon Head in the collection of the Iraq Museum—has been studied from a technical point of view. The recent attribution of The Metropolitan Museum of Art's Head of a ruler to this formative period of hollow core lost wax casting provided the impetus for its examination by high-energy X-ray computed tomography—the most practical technique for an object that is continuously on display that could image in 3D the interior morphology of this sculpture given the considerable thickness of its metal walls. This scan revealed a markedly different style of production than the Sargon Head. Although further research on early castings is required to determine the chronological implications of the differences observed and to elucidate more generally the early development of hollow casting technology, the scan of the Head of a ruler provides evidence of some of the challenges encountered and problem-solving strategies used in the casting process.

尽管失蜡铸造的起源可以追溯到公元前五千年,但直到空心铸造技术的发展,才能制作出真人大小的金属雕塑。根据现有证据,这种在蜡模中加入粘土芯的技术最早出现在伊拉克(美索不达米亚)的早王朝 III 时期(约公元前 2600-2350 年)。迄今为止,人们只从技术角度研究过阿卡德时期(约公元前 2350-2150 年)的一个空心铸件--伊拉克博物馆收藏的萨尔贡头像。最近,大都会艺术博物馆收藏的统治者头像被归属于空心失蜡铸造的这一形成时期,这推动了对该头像进行高能 X 射线计算机断层扫描的研究--对于一件持续展出的物品来说,鉴于其金属壁相当厚,这种最实用的技术可以对该雕塑的内部形态进行三维成像。扫描结果显示,该雕塑的制作风格与萨尔贡头像明显不同。虽然还需要对早期铸件进行进一步研究,以确定所观察到的差异在年代上的影响,并更广泛地阐明空心铸造技术的早期发展,但尺头的扫描提供了在铸造过程中遇到的一些挑战和解决问题策略的证据。
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引用次数: 0
Research on the yingzao chi restoration of palace buildings sans dougong in Ming and Qing Dynasties: a case study of Chongqing 明清无斗拱宫殿建筑的营造修复研究:以重庆为例
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-22 DOI: 10.1186/s40494-024-01419-7
Yihe Bao

As a unit of measurement for Chinese ancient construction, the yingzao chi (yingzaochi 营造尺) is of great significance to study long-term transformation of culture, construction skills, and the scale design rule of Chinese regional architectural heritage. But few scholars study the restoration method of the yingzao chi of palace buildings sans dougong (斗拱) in Chinese Ming and Qing Dynasties. Based on the yingzao chi theory, this paper studies and improves a theoretical method to help restore the yingzao chi of palace buildings sans dougong in Ming and Qing Dynasties. This method is not limited by the lack of reference of vernacular chi (xiangchi 乡尺) and can restore the yingzao chi of a single building through surveying data, and there is a smaller error in the calculation process. Three typical palace buildings without dougong in Ming and Qing Dynasties in Chongqing are selected as examples. The results show that the restored yingzao chi of these three buildings is highly similar, most likely 320.7–323.6 mm, which can verify the reliability of this method. This study can help to improve the research of yingzao chi and provide theoretical support for the protection of this kind of architectural heritage. Besides, the restoration of the yingzao chi provides a potential opportunity to explore how the technological and cultural of palace architecture spread, develop and blend.

作为中国古代建筑的计量单位,营造尺对于研究中国地域建筑遗产的文化、建造技艺和尺度设计规则的长期变迁具有重要意义。但很少有学者研究中国明清宫殿建筑无斗拱营造图的复原方法。本文以营造之气理论为基础,研究并完善了一种有助于恢复明清宫殿建筑无斗拱营造之气的理论方法。该方法不受缺乏乡尺参考的限制,可以通过测绘数据还原单体建筑的营造气韵,且计算过程中误差较小。本文选取了重庆三座典型的明清无斗拱宫殿建筑为例。结果表明,这三座建筑复原后的营灶气高度相似,最可能为 320.7-323.6 毫米,验证了该方法的可靠性。该研究有助于完善营灶气的研究,为此类建筑遗产的保护提供理论支持。此外,营造螭首的修复也为探索宫廷建筑的技术与文化如何传播、发展与融合提供了一个潜在的机会。
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引用次数: 0
Aging time improves adhesive performance of handmade starch paste for restoration of ancient Chinese books and its mechanism of action 老化时间对用于修复中国古籍的手工淀粉浆粘接性能的改善及其作用机理
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-22 DOI: 10.1186/s40494-024-01423-x
Changwei Wang, Yuqi Yao, Yue Zhang, Xiao Yao

In the restoration of ancient Chinese books, handmade starch paste serves as a paper adhesive, distinguished from traditional starch paste preparation methods. It involves special processes such as starch washing and aging, relying entirely on the artisanal expertise throughout the entire process. The study recreates the process of making handmade starch paste for the restoration of traditional ancient books and investigates the effects of aging time on the apparent viscosity, rheological properties, and adhesive performance of the paste. The results indicate that during aging, the pH of the starch paste decreases significantly, but it has a minimal impact on its apparent viscosity, rheological properties, and paper softness. However, it notably enhances the adhesive performance, with the optimal results observed after 3 days of aging. This is attributed to the decrease in residual protein content in the starch, as well as the significant improvement in swelling power and solubility of the starch. The results of infrared spectroscopy and XRD testing reveal that there are no significant changes in the molecular and crystalline structures of starch during the aging process. The acidic environment produced by starch fermentation promotes protein hydrolysis, emerging as the primary reason for the improved adhesive performance of the paste.

在中国古籍修复中,手工淀粉浆作为一种纸张粘合剂,有别于传统的淀粉浆制备方法。它涉及淀粉洗涤和老化等特殊工序,整个过程完全依靠工匠的专业知识。本研究再现了用于修复传统古籍的手工淀粉浆的制作过程,并研究了老化时间对浆糊表观粘度、流变特性和粘合性能的影响。结果表明,在老化过程中,淀粉糊的 pH 值会明显下降,但对其表观粘度、流变性能和纸张柔软度的影响很小。不过,pH 值明显提高了粘合剂的性能,老化 3 天后可观察到最佳效果。这归因于淀粉中残留蛋白质含量的减少,以及淀粉膨胀力和溶解性的显著提高。红外光谱和 XRD 测试结果表明,在老化过程中,淀粉的分子结构和结晶结构没有发生明显变化。淀粉发酵产生的酸性环境促进了蛋白质水解,这是糊状物粘合性能提高的主要原因。
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