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Atacamite discolouration under the influence of arsenates in wall paintings in the Kizil Grottoes, Xinjiang, China 中国新疆克孜尔石窟壁画中砷酸盐影响下的阿托孔石变色现象
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-13 DOI: 10.1186/s40494-024-01406-y
Ling Shen, Jie Yang, Jiakun Wang, Shaoping Lin, Hui Zhang, Zhaozhao Liu, Zhibo Zhou

This study was focused on a specific blue‒green pigment applied on the edges of the green blocks of wall paintings in the Kizil Grottoes, the earliest Buddhist cave complex in China containing many wall paintings. Based on in situ portable XRF analyses, μ-Raman spectroscope, elemental analysis (SEM–EDS and EPMA-WDS) and μ-XRPD analyses, the pigment was proven to be lavendulan [NaCaCu5(AsO4)4Cl·5H2O], which has not been reported in ancient wall painting studies before. Lavendulan was found to coexist with atacamite [Cu2(OH)3Cl] in some of the samples in the study and showed a nanoneedle-like morphology. Further investigations of lavendulan revealed that it was probably not originally used as a pigment but was generated by the transformation of atacamite under the influence of arsenates [As(V)] and Na+. This phenomenon and the related mechanism were discovered in this study and are discussed in this paper. As an important cultural heritage site in the Silk Road, the Route Network of the Chang’an-Tianshan Corridor and the Kizil Grottoes are listed as UNESCO World and Natural Heritage sites. The pigment types and preservation conditions of wall paintings are similar to those of many wall paintings found along the Silk Road, and further attention should be given to this discolouration mechanism for heritage site conservation.

这项研究的重点是中国最早的佛教石窟群--克孜尔石窟(包含许多壁画)中涂抹在壁画绿色块边缘的一种特殊蓝绿色颜料。根据原位便携式 XRF 分析、μ-拉曼光谱、元素分析(SEM-EDS 和 EPMA-WDS)和μ-XRPD 分析,该颜料被证实为熏杜兰[NaCaCu5(AsO4)4Cl-5H2O],这在以前的古代壁画研究中从未报道过。研究发现,在一些样本中,拉芬杜兰与阿塔卡明石[Cu2(OH)3Cl]共存,并呈现出纳米针状形态。对拉文杜兰的进一步研究发现,它最初可能并不是用作颜料,而是在砷酸盐[As(V)]和 Na+ 的影响下,由阿塔卡明石转化生成的。本研究发现了这一现象及其相关机理,并在本文中进行了讨论。作为丝绸之路的重要文化遗产地,长安-天山廊道路网和克孜尔石窟被联合国教科文组织列为世界遗产和自然遗产。壁画的颜料类型和保存条件与丝绸之路沿线发现的许多壁画相似,在遗产地保护中应进一步关注这种变色机制。
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引用次数: 0
Digitalizing cultural heritage through metaverse applications: challenges, opportunities, and strategies 通过元应用实现文化遗产数字化:挑战、机遇和战略
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-13 DOI: 10.1186/s40494-024-01403-1
Dipima Buragohain, Yahui Meng, Chaoqun Deng, Qirui Li, Sushank Chaudhary

Preservation and accessibility of cultural heritage have become essential with the rapid advancements of globalization and modernization endeavors constantly threatening historical artifacts and sites across the world. The advent of the metaverse, with its immersive and interactive capabilities, presents a novel approach to safeguarding and promoting cultural heritage. The current study aims to explore the potential of metaverse applications in digitalizing cultural heritage, encompassing virtual reconstructions, educational outreach, global accessibility, and sustainability. It conducts a systematic literature review using PRISMA guidelines to collect, screen, and evaluate existing research enquiries into investigating current practices and technologies in the digitalization of heritage preservation. The study also conducts case study research to investigate the challenges and opportunities associated with the virtual preservation of tangible and intangible cultural assets, including issues of authenticity, representation, and sustainability. Furthermore, it evaluates the impact of metaverse applications on public engagement and cultural education. The findings provide valuable insights into developing innovative strategies for preserving cultural heritage in the digital age while highlighting best practices and guidelines for optimizing metaverse applications in cultural heritage preservation.

随着全球化和现代化进程的快速发展,文化遗产的保护和可获取性变得至关重要,而全球化和现代化进程不断威胁着世界各地的历史文物和遗址。具有沉浸式和交互式功能的元世界的出现,为保护和促进文化遗产提供了一种新的方法。本研究旨在探索元数据应用在文化遗产数字化方面的潜力,包括虚拟重建、教育推广、全球可访问性和可持续性。研究采用 PRISMA 准则进行了系统的文献综述,以收集、筛选和评估现有的研究调查,调查遗产保护数字化的当前做法和技术。本研究还开展了案例研究,调查与虚拟保存物质和非物质文化资产相关的挑战和机遇,包括真实性、代表性和可持续性等问题。此外,研究还评估了元世界应用对公众参与和文化教育的影响。研究结果为制定数字时代文化遗产保护的创新战略提供了宝贵的见解,同时强调了在文化遗产保护中优化元海外应用的最佳实践和指导方针。
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引用次数: 0
Integrated study on the conservation of ecocultural heritage in the Tiantai Mountain area, China 中国天台山地区生态文化遗产保护综合研究
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-12 DOI: 10.1186/s40494-024-01398-9
Yanxuan Zhao, Hui Wu, Yingjia Fan, Hexian Jin, Yifan Wang, Lei Lu

This study deeply analyzes the ecocultural heritage of the Tiantai Mountain area in Eastern China, assesses its current status and explores effective mechanisms for its conservation and construction. Employing remote sensing technology, kernel density analysis and Minimum Cumulative Resistance Model, the study comprehensively evaluated the environmental characteristics of the region and its role in historical and modern conservation efforts. The results demonstrate the unique distribution patterns of ecocultural heritage in various conservation zones, such as restoration, controlled construction and core conservation zone. Furthermore, the study highlights the importance of religious beliefs and clan systems in the preservation of traditional knowledge and practices, with significant impacts of local community participation on conservation strategies. This research provides new theoretical and practical support for the implemention of ecocultural heritage conservation and development within religiously significant areas, highlights the need for conservation measures and synergistic strategies between ecological and cultural practices.

本研究深入分析了中国东部天台山地区的生态文化遗产,评估了其现状,并探索了其保护和建设的有效机制。研究运用遥感技术、核密度分析和最小累积阻力模型,全面评价了该地区的环境特征及其在历史和现代保护工作中的作用。研究结果表明了生态文化遗产在不同保护区(如恢复区、控制建设区和核心保护区)的独特分布模式。此外,研究还强调了宗教信仰和宗族制度在保护传统知识和习俗方面的重要性,以及当地社区参与对保护战略的重要影响。这项研究为在具有重要宗教意义的地区实施生态文化遗产保护和发展提供了新的理论和实践支持,强调了采取保护措施的必要性以及生态与文化实践之间的协同策略。
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引用次数: 0
Scientific analysis of folk contract documents from Tianshui region: insights of fiber use and preservation state 天水地区民间契约文书的科学分析:对纤维使用和保存状况的启示
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-12 DOI: 10.1186/s40494-024-01390-3
Mengfan Ge, Zhou Gu, Feifei Tian, Jiatong Shi, Yiming Yang, Jilong Shi, Bin Han

Folk contract documents (FCD) are valuable materials for studying social history, and the paper they use reflects the social realities of different eras and social classes. Research and scientific analysis of numerous FCD samples after the fourteenth century are rare. We conducted a study on 96 Tianshui folk contract documents (TFCD, 107 paper samples) from the Tianshui area of Gansu Province, Northwest China, taking into account both the textual content and the materiality of paper carriers, and interpreted the results from multiple lines of evidence and discussion. Physical performance analysis revealed that the paper used by the northern folk exhibits a lower apparent density, which is not conducive to the long-term preservation of paper. The preservation status investigation, curtain pattern analysis, and fiber analysis show that the paper used in the TFCD differs from traditional cultural paper regarding disease types, production precision, and fiber materials, providing a basis for its protection and restoration. The analysis of chemical components indicated that the aging and yellowing of paper can be correlated with the content of sulfur and carbonyl groups. The feasibility of using pyrolysis gas chromatography-mass spectrometry (Py-GC/MS) analysis to quickly identify papermaking fibers in a large number of paper samples was proposed. By utilizing various techniques to inspect the paper of documents, this study helps to enhance the academic understanding of FCD materials. In addition, it expands the knowledge base of Northwest handmade paper.

民间契约文书(FCD)是研究社会历史的宝贵资料,其使用的纸张反映了不同时代和社会阶层的社会现实。对 14 世纪以后的大量民间契约文书样本进行研究和科学分析的情况并不多见。我们对西北甘肃天水地区的 96 份天水民间契约文书(TFCD,107 份纸样)进行了研究,兼顾了文字内容和纸张载体的物理性能,并从多方面进行了考证和讨论,对研究结果进行了解读。物理性能分析表明,北方民间使用的纸张表观密度较低,不利于纸张的长期保存。保存状况调查、帘纹分析和纤维分析表明,保护区使用的纸张在病害类型、制作精度、纤维材料等方面与传统文化用纸有所不同,为其保护和修复提供了依据。化学成分分析表明,纸张的老化和泛黄与硫和羰基的含量有关。提出了利用热解气相色谱-质谱分析法(Py-GC/MS)快速鉴定大量纸张样本中造纸纤维的可行性。通过利用各种技术检测文献纸张,本研究有助于加深学术界对 FCD 材料的了解。此外,它还扩展了西北手工纸的知识库。
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引用次数: 0
Experimental and finite element assessment of stabilizing configurations for underground heritage sites 地下文物遗址稳定结构的实验和有限元评估
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-12 DOI: 10.1186/s40494-024-01384-1
Sayed Hemeda

Heritage sites in Alexandria, Egypt, are some of the UNESCO world heritage sites at high risk from geo-environmental hazards, in particular caused by sea level rise and heavy rain due to the climate change. Recently, safeguarding UNESCO world subterranean and built heritage draws more attention. After recent environmental catastrophies in Alexandria, sustainable conservation materials and stabilizing configurations of underground monumental structures has also become urgent and highly demanded. Based on typical damage due to the heavy weathering caused by the ground water table and salt, this paper offers a guide for engineers and conservators, where rock structures consolidation and stabilizing configurations to protect these structures in the static state and against strong seismic events is presented. In this paper, typical geotechnical problems and damage to the Catacombs of of Kom El-Shoqafa are presented first, followed by an experimental evaluation methodology that includes spectroscopic and morphological characterization in addition to the mechanical testing of untreated and treated rock samples with synthetic organosilicone and acrylic compounds. The effectiveness of the new silica-based consolidants was evaluated in terms of the amount of solid adsorbed, mechanical properties (e.g., surface hardness, ultrasonic velocity, modulus of elasticity and modulus of compressive strength), and resistance to salt crystallization. The treated groups showed better mechanical strength than the control group. The ability of the treated samples to resist climate change negative impact was also greatly improved. According to laboratory tests, new silica-based hardeners and hydrophobic materials have great potential for strengthening weathered Calcarenitic rock structures. It was observed that the rock samples containing the modified binder (MTMOS + Wacher BS 15) reach higher mechanical strength parameters. After the experimental study (testing procedures), FEM analysis was performed using PLAXIS 2D code to validate the silica-based consolidants and verify their efficiency in improving the response of rock structures in static and seismic states against strong earthquake events. The results of this work confirm the high potential of low-cost injection techniques and stabilizing configurations (pre- stressed anchors and concrete friction piles) technology, confirming the possibility of achieving significant improvement in the geotechnical properties of Calcarenitic rock structures and enhancing the seismic performance of underground archaeological structures using low-cost injection technology that is easy to manufacture.

埃及亚历山大的遗产地是联合国教科文组织世界遗产地中面临地质环境危害高风险的一些遗产地,特别是由于气候变化造成的海平面上升和暴雨。最近,保护联合国教科文组织世界地下遗产和建筑遗产的工作引起了更多关注。在亚历山大最近发生的环境灾难之后,可持续的保护材料和地下古迹结构的稳定配置也变得十分紧迫和迫切。本文以地下水位和盐分造成的严重风化导致的典型破坏为基础,为工程师和保护人员提供指导,介绍了岩石结构加固和稳定配置,以保护这些结构在静态和强震事件中的安全。本文首先介绍了 Kom El-Shoqafa 大墓的典型岩土工程问题和损坏情况,然后介绍了实验评估方法,包括光谱和形态特征,以及对未经处理和使用合成有机硅和丙烯酸化合物处理过的岩石样本进行机械测试。从固体吸附量、机械性能(如表面硬度、超声波速度、弹性模量和压缩强度模量)以及抗盐结晶性等方面对新型硅基固化剂的效果进行了评估。与对照组相比,处理组显示出更好的机械强度。经过处理的样品抵抗气候变化负面影响的能力也大大提高。根据实验室测试,新型硅基固化剂和疏水材料在加固风化钙钛矿岩石结构方面具有巨大潜力。据观察,含有改性粘结剂(MTMOS + Wacher BS 15)的岩石样本具有更高的机械强度参数。在实验研究(测试程序)之后,使用 PLAXIS 2D 代码进行了有限元分析,以验证硅基固结剂,并验证其在改善岩石结构在静态和地震状态下对强震事件的响应方面的效率。这项工作的结果证实了低成本注入技术和稳定配置(预应力锚杆和混凝土摩擦桩)技术的巨大潜力,证实了利用易于制造的低成本注入技术显著改善钙钛矿岩石结构的岩土特性和提高地下考古结构抗震性能的可能性。
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引用次数: 0
The Changsha historic urban area: a study on the evolution characteristics and influencing factors of the connectivity of construction land 长沙历史城区:建设用地连通性演变特征及影响因素研究
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-07 DOI: 10.1186/s40494-024-01401-3
Boyang Zhang, Jinyu Fan, Piao Zhang, Sha Shen, Yangming Ren

This study aims to understand the connectivity characteristics of construction land during the spatial evolution of historic urban areas. The complex network analysis method is employed to examine the evolution of the spatial structure of construction land in the four periods of the Changsha historic urban area. The results indicate that the spatial network morphology of construction land follows a repeated development pattern resembling a cluster–mother–child relationship. Additionally, the vulnerability in the evolution of land use spatial relationships is very low, while the overall stability of the land use network structure decreases. The spatial equilibrium of land use shows a downwards trend, the accessibility of land where existing cultural relics and historic sites are located is generally moderate to low, and some plots require improvement. In the evolution of connectivity in the construction land of historic urban areas, the main development challenges are the uneven growth caused by imbalanced land value influenced by capital and the need to balance the preservation of land use patterns with improved accessibility to cultural relics and historic sites. Therefore, it is highly important to dynamically detect and optimize the network structure of construction land to protect and develop historic urban areas.

本研究旨在了解历史城区空间演变过程中建设用地的连通性特征。研究采用复杂网络分析方法,考察了长沙历史城区四个时期建设用地空间结构的演变过程。结果表明,建设用地的空间网络形态遵循一种类似于集群-母子关系的重复发展模式。此外,土地利用空间关系演变的脆弱性很低,而土地利用网络结构的整体稳定性下降。土地利用的空间均衡性呈下降趋势,现存文物古迹所在地块的可达性总体处于中等偏下水平,部分地块有待改善。在历史城区建设用地的连通性演变过程中,主要的发展挑战是受资本影响的土地价值不平衡导致的不均衡增长,以及需要在保护土地利用模式和提高文物古迹可达性之间取得平衡。因此,动态检测和优化建设用地网络结构对于历史城区的保护和发展至关重要。
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引用次数: 0
The spectral inversion model for electrical conductivity in mural plaster following phosphate erosion based on fractional order differentiation and novel spectral indices 基于分数阶微分和新型光谱指数的磷酸盐侵蚀后壁画灰泥电导率光谱反演模型
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-06 DOI: 10.1186/s40494-024-01385-0
Yikang Ren, Fang Liu
<p>The Dunhuang murals are a precious treasure of China’s cultural heritage, yet they have long been affected by salt damage. Traditional methods for detecting salt content are costly, inefficient, and may cause physical harm to the murals. Among current techniques for measuring salt content in murals, hyperspectral remote sensing technology offers a non-invasive, circumventing issues of high costs, low efficiency. Building on this, the study constructs an inversion model for the Electrical Conductivity (EC) values of mural plaster subjected to phosphate erosion, through the integration of Fractional Order Differentiation (FOD), a novel three-band spectral index, and the Partial Least Squares Regression algorithm. The specific research contents include: (1) Initially, in preparation for the experiments, the materials used to create the samples underwent a rigorous desalting process, and phosphate solutions were prepared using deionized water to ensure uniform experimental conditions and the accuracy of the results. These meticulous preprocessing steps guaranteed that the measured EC values exhibited a clear correlation with the phosphate content. Subsequently, by employing qualitative experimental analysis techniques, this study was able to more accurately simulate the real-world scenarios of mural plaster affected by salt damage, enabling a deeper investigation into the mechanisms by which salts inflict microscopic damage to murals. (2) Explores the absorption mechanisms and characteristic spectral bands of the Electrical Conductivity (EC) values measured after the phosphate erosion of mural plaster. By integrating the optimal spectral indices, a univariate linear regression model is constructed, providing a basis for the rapid quantitative measurement of electrical conductivity in murals. (3) By comparing the accuracy of the Phosphate Simple Ratio (PSR) and Phosphate Normalized Difference Index (PNDI) spectral indices based on the linear regression model, the first six orders of the highest accuracy spectral index were selected as the optimal three-band spectral index combination, used as explanatory variables, with mural plaster electrical conductivity as the response variable, employing the PLSR method to construct the mural phosphate content high-spectral feature inversion model. The study’s findings include: (1) Surfaces of samples deteriorated by phosphate erosion formed numerous irregularly shaped crystal clusters, exhibiting uneven characteristics. (2) By comparing the outcomes of different orders of fractional differentiation, it was found that the model performance reached its optimum at a 0.3 order of differentiation for both PSR and PNDI data, with a determination coefficient (Q<sup>2</sup>) of 0.728. (3) Utilizing PLSR, this study employed the previously determined optimal six-order three-band spectral index combination as explanatory variables, with salt content as the response variable, successfully constructing the high-spectral
敦煌壁画是中国文化遗产的宝贵财富,但长期以来一直受到盐害的影响。传统的盐分检测方法成本高、效率低,而且可能对壁画造成物理伤害。在目前测量壁画含盐量的技术中,高光谱遥感技术提供了一种非侵入性的方法,避免了高成本、低效率的问题。在此基础上,该研究通过整合分数阶微分(FOD)、新型三波段光谱指数和偏最小二乘回归算法,构建了受磷酸盐侵蚀壁画灰泥电导率(EC)值的反演模型。具体研究内容包括(1) 在实验准备阶段,首先对用于制作样品的材料进行了严格的脱盐处理,并使用去离子水配制磷酸盐溶液,以确保实验条件的一致性和实验结果的准确性。这些细致的预处理步骤保证了测得的导电率值与磷酸盐含量具有明确的相关性。随后,通过采用定性实验分析技术,本研究能够更准确地模拟壁画灰泥受盐害的真实场景,从而更深入地研究盐分对壁画造成微观损害的机理。(2) 探索壁画灰泥受到磷酸盐侵蚀后所测电导率(EC)值的吸收机制和特征光谱带。通过整合最佳光谱指数,构建了单变量线性回归模型,为快速定量测量壁画电导率提供了基础。(3) 通过比较基于线性回归模型的磷酸盐简单比(PSR)和磷酸盐归一化差异指数(PNDI)光谱指数的准确性,选取准确性最高的前六阶光谱指数作为最优三波段光谱指数组合,作为解释变量,以壁画灰泥电导率作为响应变量,采用 PLSR 方法构建壁画磷酸盐含量高光谱特征反演模型。研究结果包括(1) 受磷酸盐侵蚀而变质的样品表面形成了许多形状不规则的晶簇,表现出不均匀的特征。(2) 通过比较不同阶次的分数微分结果,发现对于 PSR 和 PNDI 数据,模型性能在 0.3 阶次微分时达到最佳,确定系数 (Q2) 为 0.728。(3) 利用 PLSR,本研究采用之前确定的最佳六阶三波段光谱指标组合作为解释变量,以盐含量作为响应变量,成功构建了壁面电导率的高光谱特征反演模型,判定系数(Q2)为 0.815。这为监测壁画等珍贵文化遗产的盐害状况提供了有效的技术手段。
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引用次数: 0
Lejja archaeological site, Southeastern Nigeria and its potential for archaeological science research 尼日利亚东南部 Lejja 考古遗址及其考古科学研究潜力
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-05 DOI: 10.1186/s40494-024-01383-2
Pamela Ifeoma Eze-Uzomaka, Chioma Vivian Ngonadi, Christian Chukwuma Opata, John Uche Ngonadi

In 2017/2018, two seasons of archaeological surveys were undertaken in Lejja, southeastern Nigeria. The aim of the archaeological field work was to systematically sample the area to locate archaeological sites, scatters of artefacts, features; and to characterize and record these findings. A particular objective was to identify sites with different typological or chronological characteristics and to then select representative examples for further investigation and excavations. This paper thus focuses for the first time; on the general knowledge of the archaeological signatures in addition to iron working that abound at the Lejja site from an archaeological perspective. We aimed to identify sites with evidence of iron production and sites with other characteristics of human habitation to compare inter-site variation. Using ethnoarchaeological studies, archaeological surveys and excavations, sixteen new sites were identified stretching from iron smelting sites to domestic/habitation sites and ancestral sites. We utilized both a systematic transect and an opportunistic approach to locate and map the archaeological sites encountered. The focus of the study was on thirteen key villages in Lejja southeastern Nigeria. Analysis of data shows that there seem to be distinct areas on the landscape for habitation and metal working respectively. However, it is unclear as yet what this distinction represents in terms of social organization, particularly whether they represent one community with different activity sites or two communities with distinct identities or indeed a more complex temporal and spatial patterning.

2017/2018 年,在尼日利亚东南部的 Lejja 进行了两季考古调查。实地考古工作的目的是对该地区进行系统取样,以确定考古遗址、文物散落点和地貌特征,并描述和记录这些发现。一个特别的目标是确定具有不同类型或年代特征的遗址,然后选择具有代表性的实例进行进一步调查和发掘。因此,本文首次从考古学的角度重点介绍了 Lejja 遗址除炼铁之外的其他考古特征。我们的目标是确定有证据表明生产铁器的遗址和有其他人类居住特征的遗址,以比较遗址间的差异。通过民族考古学研究、考古调查和发掘,我们确定了 16 个新遗址,从炼铁遗址到家庭/居住遗址和祖先遗址。我们采用了系统横断面和机会主义方法来定位和绘制所遇到的考古遗址。研究的重点是尼日利亚东南部 Lejja 的 13 个主要村庄。对数据的分析表明,在地形上似乎存在明显的居住区和金属加工区。然而,目前还不清楚这种区别在社会组织方面代表了什么,特别是它们是代表了一个具有不同活动场所的社区,还是代表了两个具有不同特征的社区,或者实际上是一种更为复杂的时空模式。
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引用次数: 0
Mapping the past with historical geographic information systems: layered characteristics of the historic urban landscape of Nanjing, China, since the Ming Dynasty (1368–2024) 利用历史地理信息系统绘制历史地图:明朝(1368-2024 年)以来中国南京城市历史景观的分层特征
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-05 DOI: 10.1186/s40494-024-01400-4
Xuefeng Bai, Xinyu Jiao, Takeru Sakai, Hao Xu

The layering process of the historic urban landscape (HUL) has spatial and temporal characteristics. With the help of digital technology, building a database to collect and manage spatial information on HUL is an effective research method. Taking Nanjing since the Ming Dynasty (1368–2024) as an example, our paper proposes a framework for constructing a historical geographic information system (HGIS) for HUL. The results show that (1) ancient Chinese historical archives have good potential for use in the construction of historical landscape databases. The HGIS can visualize the evolution of HUL and realize the storage, expression, querying, and analysis of information in different formats. (2) The Republic of China is a turning point in the evolution of Nanjing’s HUL. In terms of spatial evolution, the main distribution areas of urban form and characteristic places, as well as the NACH (normalized angular choice) and NAIN (normalized angular integration) cores of the road network, all moved from the south to the north of the city. In terms of typological evolution, the urban form changes from a predominantly residential area to one that emphasizes residential, administrative, educational and industrial areas. The main types of characteristic places shifted from house gardens, temples and ancestral halls to scenic buildings and public gardens. (3) Political factors, urban planning, commercial ports, and land prices influence the layering process of the HUL. The constructed database guides the preservation of HUL from the digital heritage perspective and the construction of other historical databases with spatial characteristics.

城市历史景观(HUL)的分层过程具有时空特征。借助数字技术,建立数据库收集和管理城市历史景观的空间信息是一种有效的研究方法。本文以明代(1368-2024 年)以来的南京为例,提出了构建南京城市历史地理信息系统(HGIS)的框架。研究结果表明:(1) 中国古代历史档案在历史景观数据库建设中具有良好的应用潜力。HGIS 可以直观地展示 HUL 的演变过程,并实现不同格式信息的存储、表达、查询和分析。(2)民国是南京HUL演变的转折点。在空间演进方面,城市形态和特色场所的主要分布区域,以及路网的NACH(归一化角度选择)和NAIN(归一化角度整合)核心,均由城南移至城北。在类型演变方面,城市形态从以居住区为主转变为居住区、行政区、教育区和工业区并重。主要特色场所类型由宅园、寺庙、祠堂向风景建筑、公共园林转变。(3) 政治因素、城市规划、商业港口和土地价格影响着 HUL 的分层过程。所构建的数据库为从数字遗产的角度保护胡同以及构建其他具有空间特征的历史数据库提供了指导。
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引用次数: 0
The effect of traditional processing craft on the hygroscopicity of palm leaf manuscripts 传统加工工艺对棕榈叶手稿吸湿性的影响
IF 2.5 1区 艺术学 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2024-08-05 DOI: 10.1186/s40494-024-01402-2
Dehao Yu, Xuanhua Li, Si’ao Sun, Hong Guo, Hao Luo, Jinmeng Zhu, Liusan Li, Shan Wang, Liuyang Han

Palm leaf manuscripts, which are crucial carriers of historical, religious, scientific, and artistic information in East and Southeast Asia, specifically encapsulate significant aspects of Buddhist culture and thus require comprehensive research and preservation efforts. The base material of palm leaf manuscripts is processed palm leaves, which are hygroscopic and profoundly affected by environmental humidity. Currently, there is a research gap regarding the impact of traditional processing crafts and natural aging on the hygroscopicity of palm leaf manuscripts. Utilizing dynamic water vapor sorption (DVS), the hygroscopic properties of palm leaves from various years were assessed before and after traditional processing in Yunnan Province, China. The results show that traditional processing slightly increases the equilibrium moisture content (EMC) in environments with 0 to 60% relative humidity (RH), but significantly lowers EMC in high humidity environments, with reductions up to 19.01%. Additionally, hysteresis doubled post-processing, indicating enhanced stability under fluctuating humidity conditions. Sorption models suggest that traditional processing increases the number of adsorption sites while reducing physical adsorption or capillary condensation. FT-IR (Fourier-transform infrared spectroscopy) analysis indicates that the relative contents of cellulose and hemicellulose were reduced by 39.90% and 3.97%, respectively. Degradation occurring in both the crystalline and amorphous regions of cellulose. After natural aging, the hygroscopicity of processed palm leaves improved across the entire humidity range of 0 to 95%, and there was a slight increase in hysteresis. This is due to the increase in both adsorption sites and physical adsorption capabilities. FT-IR results also indicate that the relative contents of cellulose and hemicellulose were decreased by 57.52% and 19.83% after nature aging, respectively. These findings confirm that traditional processing improves the writability and humidity resilience of the leaves, while natural aging enhances their overall hygroscopic properties. This research contributes to our understanding of how humidity damages palm leaf manuscripts. aids in determining optimal RH ranges for storage, and assesses the effectiveness of consolidation treatments in their long–term preservation.

棕榈叶手稿是东亚和东南亚历史、宗教、科学和艺术信息的重要载体,具体体现了佛教文化的重要方面,因此需要进行全面的研究和保护工作。棕榈叶手稿的基本材料是加工过的棕榈叶,棕榈叶具有吸湿性,受环境湿度的影响很大。目前,有关传统加工工艺和自然老化对棕榈叶手稿吸湿性影响的研究尚属空白。利用动态水蒸气吸附(DVS)技术,对中国云南省不同年份的棕榈叶在传统加工前后的吸湿性能进行了评估。结果表明,在相对湿度(RH)为 0% 至 60% 的环境中,传统加工会略微增加平衡含水量(EMC),但在高湿度环境中会显著降低平衡含水量(EMC),降幅高达 19.01%。此外,加工后的滞后现象增加了一倍,表明在湿度波动条件下的稳定性得到了增强。吸附模型表明,传统加工增加了吸附位点的数量,同时减少了物理吸附或毛细管冷凝。傅立叶变换红外光谱分析表明,纤维素和半纤维素的相对含量分别减少了 39.90% 和 3.97%。纤维素的结晶区和无定形区都发生了降解。自然老化后,加工棕榈叶的吸湿性在 0 到 95% 的整个湿度范围内都有所改善,滞后性略有增加。这是由于吸附位点和物理吸附能力都有所增加。傅立叶变换红外光谱结果还表明,纤维素和半纤维素的相对含量在自然老化后分别减少了 57.52% 和 19.83%。这些发现证实,传统加工工艺提高了树叶的可写性和抗湿性,而自然陈化则增强了树叶的整体吸湿特性。这项研究有助于我们了解湿度是如何损害棕榈叶手稿的,有助于确定储存的最佳相对湿度范围,并评估加固处理在长期保存棕榈叶手稿方面的效果。
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