Hydrometallurgy最新文献

{"title":"Precipitation of the ultrafine equiaxial near-spherical gibbsite with low oil absorption value by adding mixed seeds","authors":"Jinquan Wen,&nbsp;Guihua Liu,&nbsp;Tiangui Qi,&nbsp;Qiusheng Zhou,&nbsp;Zhihong Peng,&nbsp;Xiaobin Li,&nbsp;Yilin Wang,&nbsp;Leiting Shen","doi":"10.1016/j.hydromet.2025.106586","DOIUrl":"10.1016/j.hydromet.2025.106586","url":null,"abstract":"<div><div>Ultrafine, near-spherical gibbsite with a low oil-absorption value hold significant potential for use in advanced flame-retardant fillers, polishing materials and dense alumina-bearing ceramics owing to its regular morphology, high dispersibility and good flowability. In this study, ultrafine equiaxial near-spherical gibbsite with a medium particle size (d₅₀) of 359 nm and an oil-absorption values of 25.0 mL/100 g was precipitated by seeded precipitation from sodium aluminate solution. The mixed seeds, comprising bayerite and gibbsite, were prepared by the addition of NaHCO₃, Al₂(SO₄)₃, and H₂O₂, respectively. A high bayerite content in the NaHCO₃-induced seeds, combined with significant supersaturation fluctuations, enabled a precipitation efficiency exceeding 51 % at an initial temperature of 80 °C for 35 h. Preferential growth of the (110), (100), and (001) planes occurred during the early stage, followed by the emergence of the (101) and (112) planes in the mid-to-late stage. High supersaturation from bayerite dissolution and adsorption of Al(OH)₄⁻ ions promoted the development of (001), (110), (100), (101), and (112) planes, resulting in the formation of equiaxial near-spherical gibbsite. Furthermore, the low surface energy and high zeta potential of the well-crystallized gibbsite precipitated from NaHCO₃-induced seeds contributed to its low oil absorption. These findings indicate that the presence of bayerite in seeds, elevated interfacial supersaturation, and high temperature collectively facilitate the formation of ultrafine, equiaxial, near-spherical gibbsite.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"239 ","pages":"Article 106586"},"PeriodicalIF":4.8,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145270436","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The cyanidation of gold. III. Mechanistic details of the role of lead and sulfide ions","authors":"M. Nicol","doi":"10.1016/j.hydromet.2025.106584","DOIUrl":"10.1016/j.hydromet.2025.106584","url":null,"abstract":"<div><div>The role of lead ions in the cyanidation of gold has been extensively studied in this investigation. In addition to a speciation analysis using accepted thermodynamic data, the equilibrium potential for the deposition of lead under cyanidation conditions has been estimated. This has been used in conjunction with other electrochemical measurements to confirm that bulk lead metal is not deposited on a gold surface during cyanidation. The underpotential deposition of lead has been confirmed and it has been shown that an incomplete layer of lead is responsible for the increased rates in the presence of lead. The detrimental effect of high lead concentrations appears to be the result of the formation of a complete lead layer on the gold surface.</div><div>A less extensive study of the effect of sulfide ions on the rate of cyanidation has confirmed that low (micro-molar) concentrations of sulfide ions enhance the dissolution of gold in cyanide solutions but inhibit the rate of dissolution at high concentrations. The detrimental effect is associated with the anodic oxidation of gold and the formation of a passivating layer of Au₂S is possibly responsible. There does not appear to be a significant effect of sulfide on the kinetics of the cathodic reduction of oxygen. A gold alloy containing 10 % silver is less susceptible to the inhibitory effect of sulfide ions.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"239 ","pages":"Article 106584"},"PeriodicalIF":4.8,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145271037","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Field-effect separation of rare earth elements in gelatin-supported media","authors":"Benjamin Schroeder ,&nbsp;Michael Free ,&nbsp;Prashant K. Sarswat","doi":"10.1016/j.hydromet.2025.106585","DOIUrl":"10.1016/j.hydromet.2025.106585","url":null,"abstract":"<div><div>The unique optical, electronic, and magnetic properties of the Rare Earth Elements (La-Lu + Sc, Y) have led to a significant increase in their demand by a wide variety of industries. This, coupled with the significant difficulty associated with their extraction, separation, and purification, has resulted in a strong interest in replacing the traditional solvent extraction with a new approach. In response, a new technology called “Field-Effect Separation” (FES) has been developed, which utilizes differences in the magnetic susceptibilities of ions in a strong field to separate them from one another. While it has been demonstrated that this approach can work, it is necessary to more fully understand and optimize the separation of elements. The approach taken to study this was to suspend a solution of REE ions in a firm gelatin, separating them using a strong magnet, freezing the sample to preserve separation, and taking fine slices to analyze the concentration of ions at different spatial positions relative to the magnet as well as different times relative to the beginning of the magnetic field exposure. The results show a significant concentration effect for the magnetically susceptible REEs near the magnet's surface, while the non-susceptible ions seem relatively unconcentrated by the magnetic field. Additionally, among the susceptible REEs, at certain, short separation timescales, a significant stratification of REEs was observed. This suggests that the REEs can be separated from one another using FES assuming a correct time and length scale can be selected for the system.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"239 ","pages":"Article 106585"},"PeriodicalIF":4.8,"publicationDate":"2025-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145270451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Understanding limitations to monazite concentrate dissolution in oxalic acid","authors":"Mark Stephen Henderson,&nbsp;Laurence Gerald Dyer,&nbsp;Bogale Tadesse","doi":"10.1016/j.hydromet.2025.106582","DOIUrl":"10.1016/j.hydromet.2025.106582","url":null,"abstract":"<div><div>Prior works with organic acids have shown dissolution of rare earth element (REE) bearing phosphate minerals with oxalic acid, solubilising phosphate and depositing rare earth oxalates that can be solubilised in a second stage. Previously published information shows local maxima in recovery and hypothesised reaction control mechanisms. The current article investigates reaction limitations (mineralogical and thermodynamic) in greater depth to inform process development.</div><div>Monazite concentrate was treated with oxalic acid at temperatures in a range from 30 °C to 95 °C. Various factors were found to influence the extent of phosphorus dissolution. Previous studies achieved &lt;32 % phosphate dissolution at 65 °C, this work has demonstrated the ability to achieve in excess of 65 % conversion using a multi-stage, cross flow leach at 45 °C with a large reduction in simultaneous iron dissolution.</div><div>Approximately 65 % of the phosphorus was solubilised using a multi-stage, cross-flow leach system. Two different monazite compositional signatures, indicative of variations in REE and phosphorus contents, were identified displaying significantly different reactivity. One form readily dissolved in oxalic acid, the other experienced little or no reaction.</div><div>Calculated oxalate losses to the reprecipitated salts and complexation with solution components was used to estimate availability of free oxalate, this was supported by the concentration of elements with low oxalate solubility (Ca and Ce). It was demonstrated that free oxalate is a limiting factor in dissolution. It is therefore evident that under different conditions, there are both mineralogical and solution thermodynamic drivers for reaction rate and extent achievable.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"239 ","pages":"Article 106582"},"PeriodicalIF":4.8,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145322433","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Cationic polyacrylamide (CPAM) assisted leaching of rare earth ore containing clay minerals by inhibiting swelling and promoting permeation of ammonium sulfate solution","authors":"Meiling Jiang ,&nbsp;Huifang Yang ,&nbsp;Wenqian Cui ,&nbsp;Yunbo Yang ,&nbsp;Zhenyue Zhang ,&nbsp;Zhengyan He ,&nbsp;Zhigao Xu ,&nbsp;Ming Wu ,&nbsp;Jun Zhao ,&nbsp;Ruan Chi","doi":"10.1016/j.hydromet.2025.106583","DOIUrl":"10.1016/j.hydromet.2025.106583","url":null,"abstract":"<div><div>In-situ leaching of clay-based weathered crust elution-deposited rare earth ore (WCE-DREO) is prone to landslides resulting from the swelling of clay minerals, which compromises both ecological safety, economics and efficiency of mining. This study used the cationic polyacrylamide (CPAM), mixed with 2.0 wt% (NH₄)₂SO₄ to form a composite leaching agent to address this issue, which serves two purposes: (i) it acts as an inhibitor of clay swelling, (ii) it promotes the permeation of the leaching agent. Linear swelling tests and column leaching experiments were conducted to evaluate the effect of CPAM on swelling inhibition and permeation promotion in rare earth ore leaching. The underlying mechanisms were tested and analyzed through a series of advanced characterization methods. The findings demonstrate that the addition of CPAM significantly enhances the permeation of the leaching agent. Furthermore, the composite leaching agent of (NH₄)₂SO₄ and CPAM inhibits the swelling at higher CPAM concentrations. At a CPAM concentration of 3 × 10⁻⁴ wt%, the seepage time of the leaching agent is minimized—effectively reduced by 46 %, compared to using 2.0 wt% (NH₄)₂SO₄ alone. The CPAM structure contains amine groups and positively charged quaternary ammonium groups which enable the adsorption of CPAM onto the clay mineral interlayer and surface through hydrogen bonding and electrostatic interactions. This adsorption affects in four ways: (i) hinders the entry of water molecules into the mineral interlayers, (ii) reduces electrostatic repulsion, (iii) compresses the diffuse double layer, and (iv) promotes the aggregation of fine particles into larger clusters. These effects further inhibit the swelling of clay minerals and promote the permeation of the leaching agent. At the same time, the long-chain structure of CPAM helps to entangle fine clay mineral particles into larger clusters. This prevents clogging of the permeation channel due to the movement of fine particles along with the (NH₄)₂SO₄ solution, thereby increasing the seepage rate. Additionally, CPAM can enter the clay mineral layers to discharge internal water and further inhibit swelling. This study provides theoretical insights and technical support for the safe and highly efficient mining of WCE-DREO.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"239 ","pages":"Article 106583"},"PeriodicalIF":4.8,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145270437","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The cyanidation of gold. II. The cathodic reduction of oxygen","authors":"M. Nicol","doi":"10.1016/j.hydromet.2025.106580","DOIUrl":"10.1016/j.hydromet.2025.106580","url":null,"abstract":"<div><div>An extensive study has been undertaken of the reduction of oxygen on various gold electrodes under conditions appropriate to the cyanide leaching of gold. Voltammetric studies with various gold electrodes and ring-disk electrode measurements with pure gold have demonstrated that the 2-step reduction involving peroxide as an intermediate is complex with variable extents of production of peroxide and reduction to water depending on the electrode material and solution purity. There is thus no simple stoichiometry for the reduction of oxygen although the use of a 2-electron reduction is probably the best approximation under plant conditions. This is contrary to the often accepted 4-electron process.</div><div>The nature of the gold surface is important with lower reactivity of gold‑silver alloy and plant electrodes relative to pure gold. The sensitivity of oxygen to the presence of underpotentially deposited lead has been demonstrated in solutions contaminated with lead ions. Lead ions have a significant catalytic effect on the kinetics of oxygen reduction that can be attributed to the known effect of underpotentially deposited lead on the reduction of oxygen on gold electrodes in acidic and highly alkaline solutions. Thus, both the anodic dissolution of gold and the cathodic reduction of oxygen are catalysed in the presence of low concentrations of lead ions.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"238 ","pages":"Article 106580"},"PeriodicalIF":4.8,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Selective leaching of arsenic from zinc oxide dust in NaOH-(NH2)2CS solution","authors":"Faxin Xiao ,&nbsp;Xinyu Cao ,&nbsp;Qingwen Ma ,&nbsp;Cuixia Yang ,&nbsp;Yaru Zhao ,&nbsp;Ziqi He ,&nbsp;Xuwei Luo ,&nbsp;Junqiang Chen ,&nbsp;Shuchen Sun ,&nbsp;Ganfeng Tu","doi":"10.1016/j.hydromet.2025.106577","DOIUrl":"10.1016/j.hydromet.2025.106577","url":null,"abstract":"<div><div>The selective removal of arsenic from zinc smelting dust is a notable measure toward resource recovery and environmental protection. In this study, a thiourea-assisted alkaline leaching method was employed to selectively extract arsenic from Zn smelting dust. The thermodynamics of arsenic dissolution were investigated first. The effects of NaOH concentration, thiourea concentration, leaching temperature, leaching time, and liquid–solid ratio on arsenic and zinc extraction during alkaline leaching were investigated. The results demonstrated that the addition of thiourea effectively enhanced arsenic extraction from 58.1 % to 77.1 %, while suppressing Zn leaching from 18.4 % to 2.6 %. Under optimal conditions, As, Zn, Fe, Pb, In, and Ag exhibited leaching efficiencies of 77.1 %, 2.6 %, 4.5 %, 2.1 %, 1.3 %, and 3.2 %, respectively, confirming selective arsenic leaching over other elements. Combined XRD, SEM, and XPS characterizations revealed that thiourea facilitated the dissolution of insoluble arsenate minerals and promoted the formation of ZnS and PbS precipitates by releasing S²⁻ into the solution. This process effectively reduced the loss of valuable metals such as Zn and Pb. This method can be used to selectively remove arsenic from As-containing oxidized dust.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"238 ","pages":"Article 106577"},"PeriodicalIF":4.8,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Separation of gallium from acid leachates of zinc smelting slag by tartaric acid coordinated complexation and anion-exchange","authors":"Mingwei Qi ,&nbsp;Minyu Zhu ,&nbsp;Hao Chen ,&nbsp;Yun Liu ,&nbsp;Zhiqiang Lin ,&nbsp;Zezuo Jiang ,&nbsp;Jing Wu ,&nbsp;Chunlin He","doi":"10.1016/j.hydromet.2025.106581","DOIUrl":"10.1016/j.hydromet.2025.106581","url":null,"abstract":"<div><div>The rapid advancement of strategic technologies, including semiconductor manufacturing, 5G infrastructure, renewable energy systems, and aerospace engineering, has driven a surge in global demand for gallium (Ga). To address this need, secondary resources such as zinc smelting slag have emerged as a critical source for gallium recovery. This study proposes a novel strategy for gallium recovery by leveraging the ligand complexation capability of tartaric acid to convert Ga(OH)₃ into negatively charged complexes([GaO₂(OH)C₄H₂O₄]₂⁴⁻), followed by selective adsorption using a polystyrene-based anion-exchange resin (D201 × 7). The results demonstrated that the maximum adsorption capacity was 138 mg/g at pH 4, <em>T</em> = 328 K, <em>t</em> = 45 min and 1:1 M ratio of tartaric acid with Ga. The adsorption process conformed to the pseudo-second-order kinetic and Langmuir isotherm models. The primary mechanism for the adsorption of Ga(III) involved complexation with tartaric acid to form an anionic species and undergo ion exchange via the Cl⁻ functional groups on the D201 × 7 resin. The column experiment demonstrated highly selective adsorption efficiency of Ga(III) in the presence of various interfering metal ions. This study provides a feasible alternative for the separation of Ga(III) from industrial zinc slag processing in sulfuric acid systems and has broad application prospects.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"239 ","pages":"Article 106581"},"PeriodicalIF":4.8,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145236566","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient separation of Al and Fe impurities from La-Ce chloride solution by pH adjustments with ammonium bicarbonate in the presence of triammonium citrate","authors":"Yanzhu Liu ,&nbsp;Fen Nie ,&nbsp;Lihui Liu ,&nbsp;Yanrong Ding ,&nbsp;Ying Ma ,&nbsp;Zhengxiong Ding ,&nbsp;Qing Zhao ,&nbsp;Yongxiu Li","doi":"10.1016/j.hydromet.2025.106578","DOIUrl":"10.1016/j.hydromet.2025.106578","url":null,"abstract":"<div><div>The separation of aluminum from rare earths (REs) by precipitation using pH adjustments with ammonium bicarbonate (ABC) is not satisfactory because of their co-precipitation, which affects the crystallization and the purity of rare earth carbonate. Therefore, it is extremely challenging to obtain high recovery of REs with high purity due to loss of REs during precipitation. This paper proposes a precipitation method using ABC in the presence of triammonium citrate (TAC) to separate aluminum from lanthanum and cerium. The results show that the removal efficiency of iron and aluminum and the loss of REs due to coprecipitation (%) depend on the dosage of TAC and ABC and the solution pH. A complementary relationship exists between the removal efficiency of aluminum and the loss of REs during precipitation. The optimal dosage of TAC is linear with the concentration of aluminum or the molar ratio of aluminum to iron. It was found that the removal efficiency of iron, aluminum and the loss of REs during precipitation are 100 %, 93 % and 5.6 %, respectively, for an iron‑aluminum ratio of 0.05, and the optimal dosage of TAC is 4–5 % of the aluminum content. After removing the aluminum and iron, the calcined RE₂O₃ product with purity of 99.6 % and aluminum content of 0.31 % was obtained. Compared with the products without purification or purification without the addition of TAC, the purity of RE₂O₃ product increased by 9.31 % and 1.39 %, and the aluminum content decreased by 1.99 % and 0.78 % respectively. The addition of TAC can promote the precipitation of aluminum at lower pH through its coordination with iron and aluminum, while reducing the loss of REs during precipitation and decreasing the effect of iron on the removal efficiency aluminum.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"238 ","pages":"Article 106578"},"PeriodicalIF":4.8,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216584","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The cyanidation of gold. 1. Mixed potential and dissolution studies","authors":"M. Nicol","doi":"10.1016/j.hydromet.2025.106579","DOIUrl":"10.1016/j.hydromet.2025.106579","url":null,"abstract":"<div><div>Despite the fact that the cyanidation process for the recovery of gold was patented almost 140 years ago, understanding of the dissolution of gold has proved to be particularly elusive. While it is widely accepted to be a typical electrochemically-based corrosion process, details of the published kinetics of the anodic and cathodic reactions have been found to be very variable with little agreement between many studies, predominantly of the anodic reaction.</div><div>In this series of three papers, an attempt has been made to shed some light on the electrochemistry of gold in cyanide solutions. Unlike many previous studies, the use of gold‑silver alloys and an electrode fabricated using gold from an actual plant have been used in addition to pure gold. Solutions from two gold plants have also been compared to pure solutions.</div><div>The first of these papers summarizes and compares the literature on the anodic characteristics of gold dissolution in cyanide solutions. The use of the mixed-potential model to describe the kinetics of gold dissolution and the important measurement of mixed potentials under typical cyanidation conditions are described in detail with an emphasis on the possible passivation of gold and the effect of the metal and solution composition on the passivation process.</div><div>A number of small scale dissolution experiments using various gold materials and solutions has been undertaken in conjunction with mixed potential and anodic voltammetric measurements. This study has shown that electrochemical studies using pure gold electrodes in pure solutions cannot be used to predict the reactivity of gold under actual plant conditions.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"238 ","pages":"Article 106579"},"PeriodicalIF":4.8,"publicationDate":"2025-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145216647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}