Wireless Power Transfer (WPT) is a promising technology that can potentially mitigate the energy provisioning problem for sensor networks. In order to efficiently replenish energy for these battery-powered devices, designing appropriate scheduling and charging path planning algorithms is essential and challenging. Whilst previous studies have tackled this challenge, the conjoint influences of network topology, charging path planning, and energy threshold distribution in Wireless Rechargeable Sensor Networks (WRSNs) are still in their infancy. We mitigate the aforementioned problem by proposing novel algorithmic solutions to efficient sector-based on-demand charging scheduling and path planning. Specifically, we first propose a hexagonal cluster-based deployment of nodes such that finding an NP-Complete Hamiltonian path is feasible. Second, each cluster is divided into multiple sectors and a charging path planning algorithm is implemented to yield a Hamiltonian path, aimed at improving the Mobile Charging Vehicle (MCV) efficiency and charging throughput. Third, we propose an efficient algorithm to calculate the importance