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Review on Optical and Electrical Properties of Conducting Polymers 导电聚合物的光电性能研究进展
Pub Date : 2016-06-21 DOI: 10.1155/2016/5842763
M. Bajpai, R. Srivastava, R. Dhar, R. S. Tiwari
We reviewed optical and electrical properties of conjugated polymers. The charge transport models to describe the hole and electron transport mechanism are also included in the electrical properties of conjugated polymers. The effect of optical and electrical properties after doping is also indexed in this paper.
综述了共轭聚合物的光学和电学性质。描述空穴和电子输运机制的电荷输运模型也包括在共轭聚合物的电学性质中。本文还对掺杂后的光学和电学性质的影响进行了索引。
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引用次数: 17
DFT Study on the Carrier Concentration and Temperature-Dependent Thermoelectric Properties of Antimony Selenide 硒化锑载流子浓度及温度相关热电性质的DFT研究
Pub Date : 2016-05-25 DOI: 10.1155/2016/7296847
A. Jayaraman, A. B. Kademane, Muralikrishna Molli
We present the thermoelectric properties of Antimony Selenide (Sb2Se3) obtained using first principles calculations. We investigated the electronic band structure using the FP-LAPW method within the sphere of the density functional theory. Thermoelectric properties were calculated using BoltzTrap code using the constant relaxation time () approximation at three different temperatures 300 K, 600 K, and 800 K. Seebeck coefficient () was found to decrease with increasing temperature, electrical conductivity () was almost constant in the entire temperature range, and electronic thermal conductivity () increased with increasing temperature. With increase in temperature decreased from 1870 μV/K (at 300 K) to 719 μV/K (at 800 K), electronic thermal conductivity increased from 1.56 × 1015 W/m K s (at 300 K) to 3.92 × 1015 W/m K s (at 800 K), and electrical conductivity decreased from 22 × 1019/Ω m s (at 300 K) to 20 × 1019/Ω m s (at 800 K). The thermoelectric properties were also calculated for different hole concentrations and the optimum concentration for a good thermoelectric performance over a large range of temperatures (from 300 K to 1000 K) was found for hole concentration around 1019 cm−3.
本文介绍了用第一性原理计算得到的硒化锑(Sb2Se3)的热电性质。在密度泛函理论的范围内,利用FP-LAPW方法研究了电子能带结构。在300 K、600 K和800 K三种不同温度下,使用BoltzTrap代码使用恒定弛豫时间()近似计算热电性能。塞贝克系数()随温度升高而减小,电导率()在整个温度范围内几乎不变,电子导热系数()随温度升高而增大。随着温度的升高,电子导热系数从1870 μV/K (300 K)下降到719 μV/K (800 K),电子导热系数从1.56 × 1015 W/m K s (300 K)增加到3.92 × 1015 W/m K s (800 K);电导率从22 × 1019/Ω m s(在300 K时)下降到20 × 1019/Ω m s(在800 K时)。我们还计算了不同空穴浓度下的热电性能,发现在大温度范围内(从300 K到1000 K)具有良好热电性能的最佳空穴浓度为1019 cm−3左右。
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引用次数: 8
Effect of Solvents on the Ultrasonic Velocity and Acoustic Parameters of Polyvinylidene Fluoride Solutions 溶剂对聚偏氟乙烯溶液超声声速及声学参数的影响
Pub Date : 2016-04-26 DOI: 10.1155/2016/9582582
S. S. Kulkarni, U. V. Khadke
Ultrasonic studies provide a wealth of information in understanding the molecular behavior and intermolecular interaction of polymer solvent mixtures. Attempts were made to measure ultrasonic velocity, density, and viscosity for the mixture of polyvinylidene fluoride (PVDF) in acetone and dimethylformamide (DMF) of various stoichiometric ratios at 300 K using crystal controlled ultrasonic interferometer (Mittal make), pyknometer (specific gravity bottle), and Ostwald viscometer, respectively. The acoustic parameters adiabatic compressibility (), intermolecular free path length (), acoustic impedance (), relative association (RA), ultrasonic attenuation (), and relaxation time () have been estimated using experimental data with well-known techniques. The variation of these acoustic parameters is explained in terms of solute-solvent molecular interaction in a polymer solution.
超声研究为了解聚合物溶剂混合物的分子行为和分子间相互作用提供了丰富的信息。分别用晶体控制超声干涉仪(Mittal make)、比重仪(比重瓶)和奥斯特瓦尔德粘度计(Ostwald粘度计)测量了不同化学计量比的聚偏氟乙烯(PVDF)与丙酮和二甲基甲酰胺(DMF)的混合物在300 K下的超声速度、密度和粘度。声学参数绝热压缩率()、分子间自由路径长度()、声阻抗()、相对关联(RA)、超声衰减()和弛豫时间()已经用已知的实验数据进行了估计。这些声学参数的变化是根据溶质-溶剂分子在聚合物溶液中的相互作用来解释的。
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引用次数: 13
Coalescing Aid Influences on Acrylic Latexes Property and Film Formation Process 聚结剂对丙烯酸乳液性能及成膜过程的影响
Pub Date : 2016-01-01 DOI: 10.1155/2016/1380791
Wang Yi, Zhonghua Chen, Yu Fei
The coalescing aid of propylene glycol phenyl ether (PPh) influences on the latexes system and its film formation process have been demonstrated in this paper. The latexes with different are synthesized by seeded semicontinuous emulsion polymerization. The PPh have a significant impact on the water evaporation stage, in which PPh decreased the water evaporation rate for a low latex system but accelerated the rate for a high latex. This result was quantified using Routh-Russel model which was a useful model for the prediction of the latex particle deformation mechanisms. The different amounts of PPh can change the latex particle deformation mechanisms. The TGA results show that the PPh still exist in the latexes films during drying. The microstructures of the latex film which dry under 70°C with the PPh for different time display that the PPh can accelerate the polymer molecules motion and the diffusion rate for the latex coalescence stage.
本文论述了聚结剂丙二醇苯基醚(PPh)对乳液体系及其成膜过程的影响。采用种子半连续乳液聚合法制备了不同类型的乳液。PPh对水分蒸发阶段有显著影响,在低乳胶体系中,PPh降低了水分蒸发速率,而在高乳胶体系中,PPh加快了水分蒸发速率。采用Routh-Russel模型对这一结果进行了量化,该模型是预测胶乳颗粒变形机理的有效模型。不同量的PPh可以改变乳胶颗粒的变形机制。TGA结果表明,在干燥过程中,PPh仍存在于胶膜中。用PPh在70℃下干燥不同时间的乳胶膜的微观结构表明,PPh可以加速聚合物分子的运动和乳胶聚并阶段的扩散速度。
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引用次数: 2
Investigating the Relationship between Knitted Fabric Porosity and Light Permeability 针织物孔隙率与透光性关系的研究
Pub Date : 2016-01-01 DOI: 10.1155/2016/7536108
Manoj Kumar Imrith, R. Unmar, S. Rosunee
The present paper attempts to investigate the relationship between fabric porosity and light permeability of the knitted structures, namely, rib 1 × 1, rib 2 × 1, single jersey, and plain structure. The rationale is that pores (in a fabric) would allow light to pass through but at the same time provide a quantitative assessment of the UV light permeability of the knitted fabrics, an indication of the protective capacity of the fabrics against UV radiation. The porosity and corresponding light permeability of the knitted structures were measured after varying the following knitting parameters: stitch length, stitch density, and tension on the machine. Furthermore, this work has enabled the development of an apparatus that can measure the amount of light transmitted through the knitted fabrics. The results generated by the equipment were validated through the use of regression equations.
本文研究了1 × 1罗纹、2 × 1罗纹、单布和平纹结构的织物孔隙率与透光性的关系。其基本原理是(织物中的)毛孔允许光线通过,但同时提供了对针织织物的紫外线透气性的定量评估,表明织物对紫外线辐射的防护能力。在机器上改变以下针织参数:针长、针密度和张力后,测量针织结构的孔隙率和相应的透光性。此外,这项工作还开发了一种仪器,可以测量通过针织织物的光透射量。通过回归方程验证了设备产生的结果。
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引用次数: 5
Microstructure Evolution and Grain Growth Model of AZ31 Magnesium Alloy under Condition of Isothermal 等温条件下AZ31镁合金组织演变及晶粒长大模型
Pub Date : 2015-12-30 DOI: 10.1155/2015/897686
Zhongtang Wang, Ling-Yi Wang, Lizhi Liu
Microstructure evolution of AZ31 magnesium alloy in annealing process had been investigated by experiment study at heating temperature range of 150°C–450°C and holding time range of 15 min–60 min. The effects of heating temperature and holding time on grain growth had been analyzed. The results presented that the grain size tends to grow up with the increase of holding time at a certain temperature. At a certain holding time, the grain size increased firstly and then decreased at the heating temperature range of 150–250°C. And when heating temperature is higher than 250°C, the grain grows up gradually with the increase of heating temperature. The grain growth model of AZ31 Mg alloy has been established by regression based on the experimental data at temperature of 250–450°C, and the relative error between model calculation results and experimental results is less than 19.07%. Activation energy of grain growth of AZ31 magnesium alloy had been determined.
在150℃~ 450℃的加热温度和15 min ~ 60 min的保温时间下,对AZ31镁合金退火过程中的组织演变进行了实验研究。分析了加热温度和保温时间对晶粒生长的影响。结果表明:在一定温度下,随着保温时间的延长,晶粒尺寸有增大的趋势;保温一定时间后,在150 ~ 250℃的加热温度范围内,晶粒尺寸先增大后减小。当加热温度高于250℃时,随着加热温度的升高,晶粒逐渐长大。基于250 ~ 450℃温度下的实验数据,通过回归建立了AZ31镁合金晶粒长大模型,模型计算结果与实验结果的相对误差小于19.07%。测定了AZ31镁合金晶粒长大的活化能。
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引用次数: 2
Wear and Corrosion of Cast Al Alloy Piston with and without Brake Oil 使用和不使用刹车油的铸铝合金活塞的磨损和腐蚀
Pub Date : 2015-11-01 DOI: 10.1155/2015/763618
O. Ajibola, D. Oloruntoba
The effects of wear and corrosion of cast AA6061 aluminium alloy were studied with and without brake fluid using a wear jig while the corrosion rate was determined in brake fluid for 70 days under two experimental set-ups. The tests, yielded 0.00000123 g/mm2/min highest wear rate at 147000 wear cycles and 0.0334 mg/mm2/yr as the highest corrosion rate within the early 39th day of immersion in oil, the values being considered comparatively lower than those obtained for Al alloy in most common wet abrasion test and corrosion in aqueous solutions as previously reported in literature. The material loss rates to wear and corrosion were determined from the equations relating to wear and corrosion based on the ASTM designations. The results show that the combined actions of wear and corrosion contribute to the total loss of piston material immersed in brake oil. This is greater than either of their effects individually on cast Al alloy in the brake oil.
采用磨损夹具研究了加制动液和不加制动液对铸态AA6061铝合金的磨损和腐蚀影响,并在两种试验装置下测定了制动液在铸态AA6061铝合金中70天的腐蚀速率。试验结果表明,在147000次磨损循环时,最高磨损率为0.00000123 g/mm2/min,在浸油后的第39天内,最高腐蚀率为0.0334 mg/mm2/yr,这一数值被认为比以往文献中报道的铝合金在最常见的湿磨损试验和水溶液腐蚀中获得的结果要低。材料的磨损和腐蚀损失率是根据ASTM规定的磨损和腐蚀相关方程确定的。结果表明,磨损和腐蚀的共同作用导致了活塞材料在制动油中的全部损耗。这比它们对刹车油中铸铝合金的单独影响都要大。
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引用次数: 10
Effect of MgFeSi Inoculant on Properties of Cast 6061 Al Alloy for Brake Master Piston Application MgFeSi孕育剂对铸造6061铝合金制动总活塞性能的影响
Pub Date : 2015-10-18 DOI: 10.1155/2015/756219
O. Ajibola, D. Oloruntoba
The influence of varying amount of MgFeSi inoculant on properties of cast 6061 Al alloy for brake master piston application has been studied and reported in this paper. Cast samples were produced at three pouring temperatures (700, 750, and 800°C) with MgFeSi varied from 1 to 3%. Wear resistance tests were performed on cast alloy in brake oil. Wear resistance tests results were validated by nondestructive examinations using photomicroscopy, SEM, EDX, and XRD data. The addition of MgFeSi influenced both the mechanical (hardness, strength, and wear resistance) and metallurgical properties (microstructures) of the cast alloy. Al grains were more refined and yielded good strength properties. Inoculating the melt with MgFeSi forms insoluble compound particles and is responsible for grain refinement. The increased amount of MgFeSi from 1 to 3% improved the wear resistance of the cast piston under lubricating condition using brake oil.
本文研究并报道了MgFeSi孕育剂用量对铸造6061铝合金制动总活塞性能的影响。在三种浇注温度下(700,750和800°C)生产铸造样品,MgFeSi从1%到3%不等。对铸造合金在刹车油中的耐磨性进行了试验。通过显微显微镜、扫描电镜、EDX和x射线衍射等无损检测,验证了耐磨性测试结果。MgFeSi的加入影响了铸造合金的机械性能(硬度、强度和耐磨性)和冶金性能(显微组织)。Al晶粒更加细化,具有良好的强度性能。在熔体中接种mgesi可形成不溶性的复合颗粒,使晶粒细化。MgFeSi添加量从1%增加到3%,提高了铸造活塞在制动油润滑条件下的耐磨性。
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引用次数: 10
Synthesis, Characterization, and Investigation of Visible Light Photocatalytic Activity of C Doped TiO2/CdS Core-Shell Nanocomposite C掺杂TiO2/CdS核壳纳米复合材料的合成、表征及可见光催化活性研究
Pub Date : 2015-10-05 DOI: 10.1155/2015/690568
A. Lavand, Y. S. Malghe, Suraj H. Singh
Carbon (C) doped TiO2/CdS core-shell nanocomposite (C/TiO2/CdS) was synthesized using microemulsion method. Synthesized powder was characterized using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), and UV-visible spectrophotometery. TEM images reveal that C/TiO2/CdS core-shell heterostructure is successfully prepared with CdS as a core and C doped TiO2 as a shell. UV-visible absorption spectra show that CdS nanoparticles act as a sensitizer and effectively enhance the photoabsorption capacity of C/TiO2/CdS nanocomposite in visible region. Visible light photocatalytic activity of synthesized nanocomposite was evaluated for the degradation of methylene blue. C/TiO2/CdS core-shell nanocomposite exhibits better photocatalytic activity as compared to bare TiO2, CdS, CdS/TiO2, and C doped TiO2.
采用微乳液法制备了碳(C)掺杂TiO2/CdS核壳纳米复合材料(C/TiO2/CdS)。采用x射线衍射(XRD)、傅里叶变换红外光谱(FTIR)、能量色散x射线光谱(EDX)、透射电子显微镜(TEM)和紫外可见分光光度法对合成粉体进行了表征。TEM图像显示,以CdS为核心,C掺杂TiO2为壳层,成功制备了C/TiO2/CdS核壳异质结构。紫外可见吸收光谱表明,CdS纳米粒子作为增感剂,在可见光区有效增强了C/TiO2/CdS纳米复合材料的光吸收能力。对合成的纳米复合材料可见光催化降解亚甲基蓝的活性进行了评价。C/TiO2/CdS核壳纳米复合材料比裸TiO2、CdS、CdS/TiO2和C掺杂TiO2表现出更好的光催化活性。
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引用次数: 15
Thermoluminescence and Photoluminescence Study of Erbium Doped CaY2O4 Phosphor 掺铒CaY2O4荧光粉的热致发光和光致发光研究
Pub Date : 2015-09-30 DOI: 10.1155/2015/745052
V. Dubey, R. Tiwari, R. Tamrakar, Chandrabhushan Markande, G. Rathore, M. Pradhan
Phosphor doped with erbium ion with variable concentration (0.5–2 mol%) was synthesized by solid state reaction method. CaY2O4:Er3
采用固相反应法制备了掺有不同浓度(0.5 ~ 2 mol%)铒离子的荧光粉。CaY2O4: Er3
{"title":"Thermoluminescence and Photoluminescence Study of Erbium Doped CaY2O4 Phosphor","authors":"V. Dubey, R. Tiwari, R. Tamrakar, Chandrabhushan Markande, G. Rathore, M. Pradhan","doi":"10.1155/2015/745052","DOIUrl":"https://doi.org/10.1155/2015/745052","url":null,"abstract":"Phosphor doped with erbium ion with variable concentration (0.5–2 mol%) was synthesized by solid state reaction method. CaY2O4:Er3","PeriodicalId":13278,"journal":{"name":"Indian Journal of Materials Science","volume":"19 1","pages":"1-5"},"PeriodicalIF":0.0,"publicationDate":"2015-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82497619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
期刊
Indian Journal of Materials Science
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