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Optical Microscopy: Seeing is Believing: In Situ/Operando Optical Microscopy for Probing Electrochemical Energy Systems (Adv. Mater. Technol. 10/2020) 光学显微镜:眼见为实:原位/操作光学显微镜探测电化学能量系统(Adv. Mater)。抛光工艺。10/2020)
Pub Date : 2020-10-01 DOI: 10.1002/admt.202070060
Binbin Chen, Hao Zhang, J. Xuan, G. Offer, Huizhi Wang
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引用次数: 1
The I–V Characteristics of M–BaxSr1–xTiO3–M Thin Film Structures with Oxygen Vacancies. Part 1 含氧空位M-BaxSr1-xTiO3-M薄膜结构的I-V特性第1部分
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.01.pp.008-017
V. Buniatyan, H. R. Dastoyan
The paper presents a detailed study of the I–V characteristics of m-ferroelectric-m {Pt/BaxSt1–xTiO3/Pt (Pt/BST/Pt)} thin film structure. The Schottky barrier thermal/field assisted and Pool–Frenkel (PF) emission along with the punch-through in the central region of the film are proposed for the interpretation of experimental I–V dependence. It is shown that both the Schottky barrier thermal/-field assisted emission and Pool–Frenkel emission from the oxygen vacancies conditioned traps may take place simultaneously. The effect of electric field on the electron (hole) emission from the trapping centers, in the symmetric Pt/BST/Pt thin film structure has been considered. The analysis of the PF effect indicates that the trapping centers are activated at very high electric fields, exceeding 10 V/cm. In Part 2 of the paper, based on the results and assumptions pointed in Part 1, analytical expressions were derived for Schottky barrier thermal/-field assisted and Pool–Frenkel emission currents. The computer modeling theoretical dependencies of the I–V characteristics has been compared with the experimental measured results and obtained good agreements.
本文详细研究了m-铁电-m {Pt/ BaxSt1-xTiO3 /Pt (Pt/BST/Pt)}薄膜结构的I-V特性。提出了肖特基势垒热场辅助和池- frenkel (PF)发射以及薄膜中心区域的穿孔来解释实验I-V依赖性。结果表明,氧空位条件阱的肖特基势垒热场辅助发射和池- frenkel发射可以同时发生。研究了对称Pt/BST/Pt薄膜结构中电场对捕获中心电子(空穴)发射的影响。对PF效应的分析表明,捕获中心在超过10 V/cm的高电场下被激活。在论文的第二部分中,基于第一部分的结果和假设,导出了Schottky势垒热场辅助和Pool-Frenkel发射电流的解析表达式。将计算机模拟的I-V特性的理论依赖关系与实验测量结果进行了比较,得到了较好的一致性。
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引用次数: 0
Innovative Research of Ultra-Jet Dispersion and Suspension Technologies for Processing and Modifying Liquids 液体处理与改性的超射流分散与悬浮技术创新研究
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.03.pp.068-075
Kyaw Myo Htet, M. Glotova, A. Galinovsky
Currently used dispersion methods are not able to provide sufficient dispersion of nanomodifiers in liquids. This circumstance significantly reduces the effectiveness of the subsequent use of liquid-phase nanomodifiers which are widely used in the production of a variety of composite polymer and ceramic structures. The article discusses a new method of dispersing and suspending liquids using ultra-jet technology. The results of experimental testing confirming the effectiveness of ultra-jet technologies for producing liquid suspensions with nanomodifiers are presented. Two different types of powder were chosen as liquid modifiers: boehmite and carbon nanotubes. Moreover, special technological equipment was developed to conduct the experiment. The results of the analysis of the obtained liquid suspensions containing nanomodifiers allow us to recommend this dispersion technology for use on an industrial scale.
目前使用的分散方法不能提供纳米改性剂在液体中的充分分散。这种情况大大降低了液相纳米改性剂后续使用的有效性,而液相纳米改性剂广泛应用于各种复合聚合物和陶瓷结构的生产。本文讨论了一种利用超射流技术进行液体分散和悬浮的新方法。通过实验验证了超射流技术制备纳米改性液体悬浮液的有效性。选择两种不同类型的粉末作为液体改性剂:薄水铝石和碳纳米管。此外,还研制了专门的工艺设备进行实验。对所获得的含有纳米改性剂的液体悬浮液的分析结果使我们能够推荐这种分散技术用于工业规模。
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引用次数: 1
Analysis of Oscillatory Processes in Elastic and Viscoelastic Media and Structural Elements to Predict Equipment Shutdown 弹性和粘弹性介质中的振荡过程分析以及预测设备停机的结构元件
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.01.pp.036-042
E. Mailybayev, U. Umbetov, A. Seitmuratov, A. Shynykulova
Free vibration problems of a flat element are investigated by all boundary value problems; generalization of the decomposition method in dynamics is given to solve boundary value problems, while it is shown that the decomposition method gives an exact solution obtained by the direct method, which in turn makes it possible to test the parts of production plants for wear leading to the shutdown of the equipment or the whole process. By checking the strength of the equipment parts, studying the degree of risk of possible breakdowns, emergency shutdowns can be predicted, and it is also possible to create controlled shutdowns.
用所有边值问题研究了平面单元的自由振动问题;将分解方法推广到求解边值问题的动力学领域,并证明分解方法能给出直接法的精确解,从而使生产装置部件的磨损测试成为可能,从而导致设备或整个过程的停机。通过检查设备部件的强度,研究可能发生故障的风险程度,可以预测紧急停机,也可以创建可控停机。
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引用次数: 0
Composite Materials Based on Foam Polyurethane and Graphene Nanoplates Effectively Screening Electromagnetic Radiation 泡沫聚氨酯与石墨烯纳米板复合材料有效屏蔽电磁辐射
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.01.pp.068-073
N. Memetov, A. Gerasimova, R. Stolyarov, A. Tkachev, A. Melezhik, N. Chapaksov, A. Osipkov, P. Mikhalev, A. Provatorov
Composite materials based on polyurethane foam and graphene nanoplates (GNP) for shielding from electromagnetic radiation in the frequency range from 2 to 12 GHz were made by impregnation. The use of phenol-formaldehyde resin (PFS) as a binder component promoted good adhesion of graphene to the polymer matrix and made it possible to obtain samples of composites with a high graphene concentration of ~ 50 wt %. An increase in the shielding efficiency of composites was found both with an increase in the frequency of electromagnetic radiation and with an increase in the concentration of GNP in them. The maximum shielding value was 75 dB at a frequency of 12 GHz and graphene concentration of 50 % by mass. It is concluded that the impregnation method proved to be promising for the manufacture of flexible and lightweight composite foams effective for shielding electromagnetic interference in the range from 2 to 12 GHz.
采用浸渍法制备了基于聚氨酯泡沫和石墨烯纳米片(GNP)的屏蔽2 ~ 12 GHz频率电磁辐射的复合材料。使用酚醛树脂(PFS)作为粘合剂组分,促进了石墨烯与聚合物基体的良好粘附,并使获得石墨烯浓度高达50%的复合材料样品成为可能。复合材料的屏蔽效率随着电磁辐射频率的增加和GNP浓度的增加而增加。在12 GHz频率和石墨烯质量浓度为50%时,最大屏蔽值为75 dB。结果表明,浸渍法制备柔性轻量化复合泡沫具有良好的屏蔽2 ~ 12 GHz电磁干扰性能。
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引用次数: 0
Improving Durability of Electric Motor Bearing Shields Using Combined Technology 采用组合式技术提高电机轴承屏蔽的耐久性
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.04.pp.034-040
Y. Kuznetsov, I. Kravchenko, A. Galinovsky, D. D. Yakovlev, I. D. Makarov
A combined technology for increasing the durability of bearing holes of electric motor bearing shields made of aluminum alloys is presented. The assessment of the wear resistance of the formed coatings is given.
提出了一种提高电动机铝合金轴承屏蔽轴承孔耐久性的组合工艺。对成形涂层的耐磨性进行了评价。
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引用次数: 0
Overview of Electrochromic Materials and Devices: Scope and Development Prospects 电致变色材料与器件综述:范围与发展前景
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.02.pp.066-073
A. Shchegolkov, E. Tugolukov, A. Shchegolkov
Today, the global energy consumption associated with heating, air conditioning (cooling) and lighting of buildings (which is about 40 %) can be significantly reduced through the use of chromogenic materials or the so-called “Smart Window” technology. Approximately 20–25 % of thermal energy can be saved by reducing heat loss through the windows, and 25–30 % of the electrical energy spent on lighting will be saved by using Smart Window technology instead of conventional windows, which are less energy-efficient in buildings. The article provides an overview of electrochromic materials and the practice of their use in various optical devices, as well as methods for their preparation. The prospects of using various electrochromic materials as coatings for window glasses, mirrors, and large-area displays are considered. A modern analysis of electrochromic devices based on nanostructured materials used in various applications is presented. The latest achievements and developments in the field of electrochromic materials are discussed. The paper discusses the findings of studies and the possibilities of their use for protection from light radiation, in particular, their use as light filters and light modulators for optoelectronic devices are ed.
今天,通过使用显色材料或所谓的“智能窗”技术,与建筑物的供暖、空调(制冷)和照明相关的全球能源消耗(约占40%)可以显着减少。通过减少通过窗户的热量损失,可以节省大约20 - 25%的热能,并且通过使用智能窗户技术代替建筑物中能效较低的传统窗户,可以节省25 - 30%用于照明的电能。本文综述了电致变色材料及其在各种光学器件中的应用,以及电致变色材料的制备方法。展望了利用各种电致变色材料作为窗玻璃、镜子和大面积显示器涂层的前景。介绍了基于纳米结构材料的电致变色器件在各种应用中的现代分析。讨论了电致变色材料领域的最新进展。本文讨论了研究结果及其在光辐射防护方面的应用,特别是在光电器件中用作滤光器和光调制器的可能性。
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引用次数: 3
The Role of Nanoparticle PEGylation in Drug Delivery 纳米颗粒聚乙二醇化在药物传递中的作用
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.02.pp.010-018
E. A. Mun, B. Zhaisanbayeva
Over the past few decades, nanoparticles have been attracting significant attention of researches in chemical, biomedical, pharmaceutical sciences, due to their unique physicochemical properties. This includes ultra small size, large surface area, good biocompatibility and high reactivity. In particular, nanoparticles are promising for pharmaceutical and biomedical fields, as they have been applied as drug carriers and diagnostic tools. However, nanoparticles can be easily detected and cleared out by the mononuclear phagocyte system before delivering the drug to the target site. One of the most widely applied approaches to prolong circulation of nanoparticles is to modify their surfaces with polyethylene glycol (PEG). This paper describes how PEGylation occurs, as well as application of various PEGylated nanoparticles in drug delivery.
在过去的几十年里,纳米颗粒由于其独特的物理化学性质,在化学、生物医学、制药等领域受到了广泛的关注。这包括超小尺寸,大表面积,良好的生物相容性和高反应性。特别是,纳米粒子作为药物载体和诊断工具,在制药和生物医学领域具有广阔的应用前景。然而,在将药物运送到靶点之前,纳米颗粒很容易被单核吞噬细胞系统检测和清除。应用最广泛的延长纳米颗粒循环的方法之一是用聚乙二醇(PEG)修饰其表面。本文介绍了聚乙二醇化是如何发生的,以及各种聚乙二醇化纳米颗粒在药物传递中的应用。
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引用次数: 2
The Effect of Finishing Milling Parameters on the Physico-Mechanical Properties of the Structural Steel Surface Layer of Aircraft Parts 精铣参数对飞机结构钢表层物理力学性能的影响
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.01.pp.027-035
V. Vermel, S. Bolsunovsky, Yu. O. Leontyeva
In modern conditions, a technological milling process of aviation parts implemented on a new generation of CNC machines using carbide cutting tools with hardening coatings modified with nanomaterials, high-speed milling applied for parts made of metal structural materials is of particular importance. High-speed milling differs from traditional milling by increasing the cutting speed by 10 times or more. Increasing the cutting speed and changing a number of other parameters of the high-speed milling process leads to a significant increase in cutting zone temperature and a change in the physico-mechanical properties of the sample surface layer, different from those that arise during traditional milling processing. In turn, the state of the surface layer affects the performance characteristics of parts – strength (static, cyclic, impact), wear resistance, resistance to corrosion, erosion and cavitation. A significant increase in the performance of high-speed milling is achieved by fulfilling the conditions for the correct selection of the cutting tool for the type, condition and configuration of the processed material surfaces, as well as determining the optimal parameters for high-speed milling, which maintains high performance characteristics of aircraft parts. The paper presents the results of determining the state of the surface layer of structural steel samples of grades 30HGSA and EP 817 used for the manufacture of compressor machine blades, sheathing housings, flanges and loaded parts of aircraft structures operating under alternating loads, respectively, after traditional and high-speed milling at different cutting speeds.
在现代条件下,在新一代数控机床上实现航空零件的技术铣削工艺,使用硬质合金刀具和纳米材料改性的硬化涂层,高速铣削应用于金属结构材料制成的零件尤为重要。高速铣削与传统铣削的不同之处在于切削速度提高了10倍或更多。提高切削速度和改变高速铣削过程的一些其他参数会导致切削区温度的显著升高和样品表面层物理力学性能的变化,这与传统铣削加工过程中产生的变化不同。反过来,表面层的状态影响着零件的性能特征——强度(静态、循环、冲击)、耐磨性、抗腐蚀、侵蚀和空化性。高速铣削性能的显著提高是根据被加工材料表面的类型、条件和结构正确选择刀具的条件,以及确定高速铣削的最佳参数,以保持飞机零件的高性能特性。本文介绍了30HGSA和ep817牌号结构钢试样在不同切削速度下,分别用于压气机叶片、护套外壳、法兰和飞机结构加载件的加工,测定了其表面层在不同切削速度下的状态。
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引用次数: 0
Concrete Modification Using Graphene and Graphene Oxide 石墨烯和氧化石墨烯改性混凝土
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.02.pp.046-056
A. Mashhadani, V. Pershin
The paper considers methods for concrete modification using low-layer graphene and graphene oxide. It was found that graphene oxide and low-layer graphene obtained by liquid-phase shear exfoliation significantly increase the strength of concrete. In our opinion, low-layer graphene has better prospects since it is cheaper and its production technology is environmentally friendly. The viability and future of graphene largely depends on the availability of such a method that allows mass production of high-quality graphene at an affordable price. In this regard, liquid-phase separation of graphite with the formation of low-layer graphene, which can be used to modify concrete, turned out to be a competitive solution. The following main tasks were formulated in order to solve the organizational problems of low-layer graphene industrial production: reducing the concentration of low-layer graphene in concrete; increasing the concentration of low-layer graphene in suspension; developing an industrial technology for the production of concentrate with a high content of low-layer graphene; conducting full-scale experimental studies to determine the optimal concentration of low-layer graphene in concrete.
本文研究了用低层石墨烯和氧化石墨烯改性混凝土的方法。发现氧化石墨烯和液相剪切剥落得到的低层石墨烯显著提高了混凝土的强度。我们认为低层石墨烯价格便宜,生产工艺环保,前景较好。石墨烯的可行性和未来在很大程度上取决于这种方法的可用性,这种方法可以以可承受的价格批量生产高质量的石墨烯。在这方面,石墨的液相分离与形成低层石墨烯,可用于改性混凝土,被证明是一个有竞争力的解决方案。为解决低层石墨烯工业化生产的组织问题,制定了以下主要任务:降低混凝土中低层石墨烯的浓度;提高悬浮液中低层石墨烯的浓度;开发低层石墨烯高含量精矿的工业生产技术;进行全面的实验研究,以确定混凝土中低层石墨烯的最佳浓度。
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引用次数: 1
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Image Journal of Advanced Materials and Technologies
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