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Electromagnetic Properties of Cold-Cure Silicone Mixtures Containing Multi-Walled Carbon Nanotubes 含多壁碳纳米管的冷固化有机硅混合物的电磁性能
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.03.pp.043-046
A. Tkachev, N. Memetov, R. Stolyarov, N. Chapaksov, A. Gerasimova, V. Yagubov, A. Matveentsev, V. Bulgakova, S. Pozdnyakova
Nanocomposite materials based on a cold-cure silicone mixture containing multi-walled carbon nanotubes were obtained. The concentration dependences of the radio-physical properties of materials were investigated. An increase in the efficiency of shielding electromagnetic radiation in the radio frequency range of wavelengths with increasing concentrations of multi-walled carbon nanotubes up to 10 wt. % was verified.
以含多壁碳纳米管的冷固化有机硅混合物为基础,制备了纳米复合材料。研究了材料的放射性物理性质与浓度的关系。在射频波长范围内,随着多壁碳纳米管浓度增加至10 wt. %,屏蔽电磁辐射的效率得到了提高。
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引用次数: 0
Preparation of Composite Materials Containing Polyethylene and Carbon Nanotubes by in situ Ethylene Polymerization over Titanium-Magnesium Catalyst Fixed on the Surface of Carbon Nanotubes 碳纳米管表面钛镁催化剂上乙烯原位聚合制备聚乙烯/碳纳米管复合材料
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.03.pp.033-042
A. A. Zdanovich, M. Matsko, A. Melezhik, A. Tkachev, V. Zakharov
The data on the preparation of composite materials containing polyethylene and multi-walled carbon nanotubes (MWCNTs) of the Taunit brand are presented. To obtain these composites by in situ polymerization, a catalytic system formed by the interaction of an organomagnesium compound and TiCl4 on the surface of nanotubes was used. The catalyst fixed on the MWCNT surface has a high activity in ethylene polymerization and allows to obtain a polymer with different molecular weight. The data on the formation of a polymer on the MWCNT surface and the morphology of composites formed on various Taunit samples are presented.
介绍了聚乙烯与Taunit品牌多壁碳纳米管(MWCNTs)复合材料的制备情况。采用原位聚合法制备了有机镁化合物与二氧化钛在纳米管表面相互作用形成的催化体系。固定在MWCNT表面的催化剂具有较高的乙烯聚合活性,可以获得不同分子量的聚合物。介绍了在纳米碳纳米管表面形成聚合物的数据和在不同单位样品上形成的复合材料的形貌。
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引用次数: 0
Synthesis of Superhard Materials Based on Sphalerite Boron Nitride Using Carbon Nanoparticles as a Phase Conversion Catalyst 以碳纳米颗粒为相变催化剂合成闪锌矿型氮化硼超硬材料
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.03.pp.008-017
P. Vityaz, V. Senyut, M. Kheifets, A. Kolmakov, S. Klimenko
Using modern ideas about the form of the phase diagram of boron nitride, the paper considers thermodynamic parameters and mechanisms of the synthesis of dense phases of boron nitride under equilibrium and nonequilibrium conditions. It has been verified that nanodiamonds, like fullerenes and carbon nanotubes, have catalytic properties and contribute to the solid-state conversion of graphite-like boron nitride to sphalerite modification at high pressures and temperatures. We propose a mechanism for the interaction of nanodiamond under high pressures with the surface of graphite-like boron nitride, which leads to a change in the type of electronic bond in its lattice from sp to sp with the formation of boron nitride with a wurtzite structure and its subsequent transformation into sphalerite boron nitride by the shear mechanism. The use of carbon-coated nanodiamonds resulted in an increase in the catalytically active centers of phase transformation in boron nitride in comparison with unmodified nanodiamonds, which was manifested in an increase in the content of sphalerite boron nitride in materials obtained under comparable technological synthesis conditions. Modified nanodiamonds also contribute to the intensification of the synthesis of superhard polycrystals as compared to uncoated nanodiamond additives, both due to the diffusion of carbon atoms along the grain boundaries of sphalerite boron nitride and due to the rearrangement of graphite microgroups into a diamond structure and sintering of the obtained diamond blocks with grains of sphalerite boron nitride. The process parameters of obtaining superhard polycrystals based on sphalerite boron nitride with the addition of detonation nanodiamond powders after chemical cleaning and surface modification with non-diamond forms of carbon were found.
本文运用氮化硼相图形式的现代思想,研究了平衡和非平衡条件下氮化硼致密相合成的热力学参数和机理。研究证实,纳米金刚石与富勒烯和碳纳米管一样,具有催化性能,有助于在高压和高温下将类石墨氮化硼固态转化为闪锌矿改性。我们提出了一种高压下纳米金刚石与类石墨氮化硼表面相互作用的机制,该机制导致其晶格中的电子键类型从sp变为sp,形成具有纤锌矿结构的氮化硼,随后通过剪切机制转变为闪锌矿型氮化硼。与未经修饰的纳米金刚石相比,碳包覆纳米金刚石的使用增加了氮化硼的催化活性相变中心,这表现在在可比工艺合成条件下获得的材料中闪锌矿型氮化硼的含量增加。与未涂覆的纳米金刚石添加剂相比,改性纳米金刚石还有助于增强超硬多晶的合成,这是由于碳原子沿着闪锌矿氮化硼的晶界扩散,以及石墨微基团重排成金刚石结构,并将获得的金刚石块与闪锌矿氮化硼晶粒烧结。研究了在闪锌矿型氮化硼中加入爆轰纳米金刚石粉末,经化学清洗和表面非金刚石碳改性后获得超硬多晶的工艺参数。
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引用次数: 3
Method for Recording and Reproducing an Experimental Research into the Field Emitter Properties Based on Carbon Nanotubes 基于碳纳米管的场发射极特性实验研究
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.03.pp.018-027
A. G. Kolosko, V. S. Chernova, S. Filippov, E. O. Popov
A method for recording and emulating a complex experiment in field emission was developed. The method includes processing of three types of data streams: data on the electrical characteristics of the field cathode (voltage and current pulses), data on the field emission projector (glow patterns) and time-of-flight mass spectrometer data (mass spectra of volatile products in the measuring chamber). The LabView software environment implements an algorithm for synchronous reproduction of multichannel experiment data with the possibility of processing it in real time. The program has a built-in set of software tools that implement the functionality and repeat the experiment many times, pause at specified points in time, as well as change the time flow rate in the emulation. The capabilities of the method are demonstrated by the example of studying field emission from a nanocomposite field cathode based on carbon nanotubes.
提出了一种记录和模拟复杂场发射实验的方法。该方法包括处理三种类型的数据流:场阴极的电特性数据(电压和电流脉冲),场发射投影仪的数据(发光模式)和飞行时间质谱仪数据(测量室中挥发性产物的质谱)。LabView软件环境实现了多通道实验数据的同步再现算法,并实现了对实验数据的实时处理。该程序具有一套内置的软件工具,可以实现多次重复实验的功能,在指定的时间点暂停,以及在仿真中改变时间流率。以碳纳米管为基材的纳米复合场阴极的场发射为例,验证了该方法的有效性。
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引用次数: 2
Increasing of a Lithium-Ion Supercapacitor Specific Energy by Introducing LiNi1/3Mn1/3Co1/3O2 Additive into the Active Carbon-Based Cathode Material 在活性炭基正极材料中引入LiNi1/3Mn1/3Co1/3O2添加剂提高锂离子超级电容器比能
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.02.pp.033-039
A. V. Desyatov, Khimki Russia Global Co Llc, M. Chaika, V. V. Besedin, E. V. Bulavina, A. V. Denisenko, N. A. Shibanov
In this paper, we investigated the effect of the cathode material additive LiNi1/3Mn1/3Co1/3O2 (NMC111) on the capacity and specific energy of a hybrid lithium-ion supercapacitor (HLISC) with a positive electrode based on active carbon, a negative electrode based on graphite, and an auxiliary lithium electrode. The introduction of 35 % of the mass. NMC111 made it possible to increase the specific capacity of the storage device energy by ~ 77 % compared to a lithium-ion supercapacitor (LISC) with a cathode based on pure, non-doped active carbon. It was found that cycling at high current densities does not cause significant changes in the HLISC characteristics. This type of hybrid element proved to have two advantages. At low current densities, it exhibits charge-discharge properties of a lithium-ion battery with a high specific energy, and at high current densities, it exhibits the properties of a lithium-ion supercapacitor with a high specific power.
本文研究了正极材料添加剂LiNi1/3Mn1/3Co1/3O2 (NMC111)对复合锂离子超级电容器(HLISC)容量和比能的影响,HLISC的正极为活性炭,负极为石墨,辅助电极为锂。引入35%的质量。与基于纯非掺杂活性炭的阴极锂离子超级电容器(LISC)相比,NMC111使存储装置能量的比容量增加了77%。研究发现,在高电流密度下循环不会引起HLISC特性的显著变化。这种杂交元件被证明有两个优点。在低电流密度下,它具有高比能锂离子电池的充放电特性,在高电流密度下,它具有高比能锂离子超级电容器的特性。
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引用次数: 1
The p–T–x-State Diagram of the Mg–Ni System Mg-Ni体系的p - t - x态图
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.03.pp.003-007
Y. Levinsky, M. M. Alymov, L. Rokhlin
The analysis of equilibrium in the Mg–Ni system was carried out. Alloys on its basis are promising for use as sorbents and hydrogen storage (START). The conditions for the production and operation of such alloys imply strict control of the pressure of hydrogen. In this regard, phase equilibria in the Mg–Ni system must be considered not only depending on the composition and temperature, but also on the pressure of hydrogen. The most complete graphical representation of the equilibrium in the Mg–Ni system is given by a three-dimensional state diagram: pressure-temperature-composition (p–T–x), the projection of the three-phase equilibrium lines of this diagram on the pressure-temperature plane (p–T-state diagram), isobaric and isothermal sections of the diagram, diagram in pMg–T coordinates. Based on the analysis of experimental data on equilibrium in this system, the article presents the most important options of the listed types of diagrams. The presented diagram variants can be useful in optimizing the technology and operation of sorbents and START alloys of the Mg–Ni system.
对Mg-Ni体系进行了平衡分析。以其为基础的合金在吸附剂和储氢(START)方面具有广阔的应用前景。这种合金的生产和操作条件要求严格控制氢的压力。在这方面,Mg-Ni体系中的相平衡不仅取决于组成和温度,还必须考虑氢的压力。Mg-Ni体系平衡最完整的图形表示是三维状态图:压力-温度-组成(p-T-x),该图三相平衡线在压力-温度平面上的投影(p -t -状态图),图的等温和等温部分,图在pMg-T坐标下。本文在对该系统平衡实验数据分析的基础上,提出了所列图表类型中最重要的选项。所提出的图变体可用于优化Mg-Ni体系的吸附剂和START合金的工艺和操作。
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引用次数: 0
A Method for Determining Wear Resistance and Wear Depth of Thin-Layer Functional Coatings 测定薄层功能涂层耐磨性和磨损深度的方法
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.04.pp.017-020
M. Markov, Y. Fadin, I. Kravchenko, A. Galinovsky, A. Belyakov, A. Bykova
The surface of metallic materials in friction pairs is protected from contact interaction by applying functional coatings. The minimum loads set in standard friction machines can be critical and instantly abrade the modified surface. Consequently, new promising approaches are needed in the development of coating diagnostics. This paper presents the approbation of a new promising method for evaluating thin-layer coatings based on the acoustic emission method using a reference sample.
摩擦副中的金属材料表面通过应用功能涂层来防止接触相互作用。在标准摩擦机中设定的最小载荷可能是关键的,并立即磨损改性表面。因此,涂层诊断的发展需要新的有前途的方法。本文提出了一种基于声发射法的评价薄层涂层的新方法。
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引用次数: 0
Three Important Refinements of the Condensed Matter Detonation Theory 凝聚态爆轰理论的三个重要改进
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.04.pp.030-033
V. S. Trofimov, E. Petrov
Some sections of the theory of shock-wave processes in condensed media require substantial refinement. From a detailed analysis of the concept of heat of reaction, it follows that the three known heats of reaction characterize the same transformation of the reacting medium from three different sides. When considering the flows of a reacting medium, it is necessary to take into account turbulence and its changes as an analogue of thermal motion and physicochemical transformations of matter. Based on the analysis of the results of a unique experiment, it was concluded that the deformation of the condensed medium is a factor that determines the reaction rate along with temperature.
压缩介质中激波过程理论的某些部分需要大量的改进。从对反应热概念的详细分析可以得出,已知的三种反应热从三个不同的侧面表征了反应介质的相同转变。在考虑反应介质的流动时,有必要把湍流及其变化作为热运动和物质的物理化学转化的类似物加以考虑。通过对一个独特实验结果的分析,得出了随着温度的变化,凝结介质的变形是决定反应速率的因素。
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引用次数: 0
Analytical and Procedural Decision-Making Models for Process Improvement Projects in Testing Laboratories 测试实验室过程改进项目的分析和程序决策模型
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.04.pp.067-075
S. Al-Busaidi, S. V. Ponomarev
The article discusses an analytical model used in evaluation effectiveness and relative efficiency indicators of the processes performance in testing laboratories and a procedural model used to support manager in decision-making for implementing process improvement projects in the testing laboratories.
本文讨论了用于评价测试实验室过程绩效的有效性和相对效率指标的分析模型,以及用于支持管理者决策实施测试实验室过程改进项目的程序模型。
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引用次数: 0
The I–V Characteristics of M–BaxSr1–xTiO3–M Thin Film Structures with Oxygen Vacancies. Part 2 含氧空位M-BaxSr1-xTiO3-M薄膜结构的I-V特性第2部分
Pub Date : 2020-01-01 DOI: 10.17277/amt.2020.04.pp.058-066
V. Buniatyan, H. Dashtoyan, A. Davtyan
In Part 2 of the paper, based on the results and assumptions pointed in Part 1, analytical expressions were derived for Schottky barrier thermal/field assisted and Poole-Frenkel emission currents. The computer modeling theoretical dependencies of the I–V characteristics has been compared with the experimental measured results and obtained good agreements.
在论文的第二部分中,基于第一部分的结果和假设,导出了Schottky势垒热场辅助和Poole-Frenkel发射电流的解析表达式。将计算机模拟的I-V特性的理论依赖关系与实验测量结果进行了比较,得到了较好的一致性。
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引用次数: 0
期刊
Image Journal of Advanced Materials and Technologies
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