This study systematically investigated the influence of different oxygen-containing oxidants (NaNO3, KNO3, Ba(NO3) 2) on the combustion performance and radiation characteristics of MgB2/PTFE infrared radiation agents under low-pressure conditions. Through thermal analysis (TG-DTA), combustion product characterization (XRD, SEM), and low-pressure combustion experiments (5–––101 kPa), it was found that the decomposition temperature of the oxidants significantly affected the combustion stability and reaction pathway of the agent in the low-pressure environment. NaNO3 and KNO3, due to their lower decomposition temperatures (374.5 ℃ and 408 ℃ respectively), could still promote the efficient reaction of MgB2 at 5 kPa low pressure, significantly improving the combustion stability and radiation area; while Ba(NO3) 2 had a higher decomposition temperature (577.8 ℃), its system could not burn stably at 5 kPa, but by generating high-emissivity condensed-phase products (such as BaO, BaB6), it effectively enhanced the infrared radiation intensity in the α (1.3–––3 μm), β (3–––5 μm), and γ (8–––14 μm) wavelength bands under low-pressure conditions. The study further revealed the reaction mechanisms of each system: NaNO3/KNO3 mainly produced alkali metal borates (such as Na2B4O7·H2O, K3.67B4O5 (OH) 5), while the Ba(NO3) 2 system formed BaB6 through complex phase changes. The results showed that by regulating the type of oxidant, the combustion efficiency and radiation performance of MgB2/PTFE agents under low pressure could be optimized, providing key theoretical and experimental basis for the design of high-altitude infrared decoy agents.
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