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Retracted: Liquid-Phase Synthesis of Nano-Zinc Oxide and Its Photocatalytic Property. 撤回:纳米氧化锌的液相合成及其光催化性能
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-29 eCollection Date: 2023-01-01 DOI: 10.1155/2023/9879471
International Journal Of Analytical Chemistry

[This retracts the article DOI: 10.1155/2022/6977424.].

[本文撤消了文章 DOI:10.1155/2022/6977424]。
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引用次数: 0
Retracted: Application of Cross-Linked and Non-Cross-Linked Hyaluronic Acid Nano-Needles in Cosmetic Surgery. 撤回:交联和非交联透明质酸纳米针在美容手术中的应用。
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-29 eCollection Date: 2023-01-01 DOI: 10.1155/2023/9859273
International Journal Of Analytical Chemistry

[This retracts the article DOI: 10.1155/2022/4565260.].

[此文撤稿,DOI: 10.1155/2022/4565260.]。
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引用次数: 0
Retracted: Application of Nanocomposite Energy Storage Materials in Green Building Design. 撤回:纳米复合储能材料在绿色建筑设计中的应用。
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-29 eCollection Date: 2023-01-01 DOI: 10.1155/2023/9854164
International Journal Of Analytical Chemistry

[This retracts the article DOI: 10.1155/2022/7739734.].

[本文撤回了文章 DOI:10.1155/2022/7739734]。
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引用次数: 0
Retracted: Application of Cement-Based Carbon Fiber Material in Construction of Building Durability. 撤回:水泥基碳纤维材料在建筑耐久性施工中的应用。
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-29 eCollection Date: 2023-01-01 DOI: 10.1155/2023/9807316
International Journal Of Analytical Chemistry

[This retracts the article DOI: 10.1155/2022/3562209.].

[本文撤回了文章 DOI:10.1155/2022/3562209.]。
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引用次数: 0
Retracted: Preparation and Sound Insulation Performance of Polystyrene Building Flame Retardant and Thermal Insulation Building Materials. 撤回:聚苯乙烯建筑阻燃隔热材料的制备和隔音性能。
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-29 eCollection Date: 2023-01-01 DOI: 10.1155/2023/9832879
International Journal Of Analytical Chemistry

[This retracts the article DOI: 10.1155/2022/6444367.].

[本文撤消了文章 DOI:10.1155/2022/6444367]。
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引用次数: 0
Retracted: Preparation of Porous Ceramic Building Decoration Materials by Foaming Method and Research on Nanomechanical Properties. 撤回:发泡法制备多孔陶瓷建筑装饰材料及其纳米力学性能研究
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-29 eCollection Date: 2023-01-01 DOI: 10.1155/2023/9897809
International Journal Of Analytical Chemistry

[This retracts the article DOI: 10.1155/2022/8339503.].

[本文撤回文章 DOI:10.1155/2022/8339503]。
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引用次数: 0
Retracted: Reservoir Physical Properties and Micropore Nanocharacteristics of Cores in the Shihezi Formation, Sudong District, Sulige Gas Field, Ordos Basin. 撤回:鄂尔多斯盆地苏里格气田苏东区石河子地层岩心储层物性及微孔纳米特征
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-29 eCollection Date: 2023-01-01 DOI: 10.1155/2023/9783476
International Journal Of Analytical Chemistry

[This retracts the article DOI: 10.1155/2022/6008603.].

[本文撤回了文章 DOI:10.1155/2022/6008603.]。
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引用次数: 0
Chemical Application of Topological Indices in Infertility Treatment Drugs and QSPR Analysis. 拓扑指数在不孕症治疗药物中的化学应用及QSPR分析。
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-24 eCollection Date: 2023-01-01 DOI: 10.1155/2023/6928167
Sobia Sultana

The main challenges faced by medical researchers while producing novel drugs are time commitment, amplified costs, creating a safety profile for the medications, reduced solubility, and a lack of experimental data. Chemical graph theory makes an important theoretical contribution to drug development and design by investigating the structural properties of molecules. To improve drug research and assess the effectiveness of treatments, topological indices aim to provide a mathematical representation of molecular structures. In this study, the author examined a number of recently used drugs, including tamoxifen, mesterolone, anastrozole, and letrozole which are used to treat infertility. We compute the topological descriptors with the limiting behaviors associated with these pharmaceutical drugs and offer degree-based topological parameters for them. We conducted a QSPR investigation on the prospective degree-based topological descriptors using quadratic, cubic, exponential, and logarithmic regression models.

医学研究人员在生产新药时面临的主要挑战是时间承诺、成本增加、为药物创建安全性概况、溶解度降低以及缺乏实验数据。化学图论通过研究分子的结构性质,对药物的开发和设计做出了重要的理论贡献。为了改进药物研究和评估治疗效果,拓扑指数旨在提供分子结构的数学表示。在这项研究中,作者检查了一些最近使用的药物,包括他莫昔芬、美司酮、阿那曲唑和来曲唑,这些药物用于治疗不孕症。我们计算了与这些药物相关的限制行为的拓扑描述符,并为它们提供了基于度的拓扑参数。我们使用二次、三次、指数和对数回归模型对未来基于学位的拓扑描述符进行了QSPR调查。
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引用次数: 0
Determination of Multicomponents in Rubi Fructus by Near-Infrared Spectroscopy Technique 近红外光谱法测定枸杞中多种成分含量
4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-06 DOI: 10.1155/2023/5575944
Wenjun Du, Chunyan Wu, Hesong Yu, Qingran Kong, Yunjian Xu, Weidong Zhang
Objective. Rubi Fructus (RF) is a dry aggregate fruit of Rubus (Rosaceae). It has shown significant pharmacological effects such as anti-oxidation, hypoglycemic, and anti-inflammatory. A combination of near-infrared (NIR) spectroscopy and partial least squares regression (PLSR) under seven different spectral data preprocessing techniques was used to determine the performance of quantitative analysis correction models which employed moisure, ellagic acid, and total flavonoids as indicators of RF. Methods. Ninety-seven different RF batches were collected for NIR spectra. By using primary analysis techniques such as drying method, high-performance liquid chromatography (HPLC), and ultraviolet visible spectrophotometry (UV-Vis), the contents of moisure, ellagic acid, and total flavonoids were determined. The NIR spectral data and the primary analysis method data were correlated through PLSR. Seven methods were used for pretreating the spectral data, including no spectral pretreatment, first derivative, standard normalized variate, multiple scattering corrections, elimination of constant offset, and minimum maximum normalization. The quantitative analysis correction models adopted PLSR chemometrics for moisture, ellagic acid and total flavonoids were developed, and their effectiveness was evaluated using the correlation coefficient (R), ratio of prediction to deviation (RPD), and root mean square error (RMSE). Results. The first derivative was combined with variable standardization, elimination of constant offset, and multiple scattering corrections, respectively, to pretreat the PLSR models for moisture, ellagic acid, and total flavonoids. The R-values of the PLSR models for moisture, ellagic acid, and total flavonoids were, respectively, 0.9788, 0.9468, and 0.9748, all of which were higher than 0.90, and the RPD values were 4.9, 3.1, and 4.5, respectively, which were all larger than 3.0. The RMSE ratios of the calibration set and the test set were 0.98, 0.94, and 1.0, respectively. Conclusion. The R-values of the NIR-PLSR models for moisture, ellagic acid, and total flavonoids are all greater than 0.90 after suitable pretreatments, indicating that the models are reliable. The RPD values are more than 3.0, which indicate that the models are good and useable for quality control. The RMSE ratios are closed to 1, indicating that the calibration set and test set had same distribution and the models were not overfitting indicating good predictability.
目标。Rubi Fructus (RF)是蔷薇科Rubus(蔷薇科)的一种干燥的聚集体果实。具有显著的抗氧化、降血糖、抗炎等药理作用。采用近红外光谱(NIR)和偏最小二乘回归(PLSR)相结合的方法,在7种不同的光谱数据预处理技术下,对以水分、鞣花酸和总黄酮为RF指标的定量分析校正模型的性能进行了研究。方法。收集了97个不同批次的RF进行近红外光谱分析。采用干燥法、高效液相色谱法(HPLC)、紫外可见分光光度法(UV-Vis)等主要分析技术,测定其水分、鞣花酸和总黄酮的含量。近红外光谱数据与原始分析方法数据通过PLSR进行相关性分析。采用7种方法对光谱数据进行预处理,包括不进行光谱预处理、一阶导数、标准归一化变量、多次散射校正、消除常数偏移和最小最大值归一化。采用PLSR化学计量学建立了水分、鞣花酸和总黄酮的定量分析修正模型,并通过相关系数(R)、预测偏差比(RPD)和均方根误差(RMSE)对模型的有效性进行了评价。结果。第一阶导数分别与可变标准化、消除常数偏移和多重散射校正相结合,对PLSR模型中的水分、鞣花酸和总黄酮进行预处理。水分、花藻酸和总黄酮的PLSR模型r值分别为0.9788、0.9468和0.9748,均大于0.90,RPD值分别为4.9、3.1和4.5,均大于3.0。校准集和测试集的RMSE分别为0.98、0.94和1.0。结论。水分、鞣花酸和总黄酮的NIR-PLSR模型经适当预处理后的r值均大于0.90,表明模型是可靠的。RPD值均大于3.0,表明模型效果良好,可用于质量控制。RMSE接近于1,说明校正集和检验集分布相同,模型没有过拟合,可预测性好。
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引用次数: 0
Method Validation and Measurement Uncertainty (MU) Evaluation on Enrofloxacin and Ciprofloxacin in the Aquatic Products. 水产品中恩诺沙星和环丙沙星的方法验证及测量不确定度评定。
IF 1.8 4区 化学 Q3 CHEMISTRY, ANALYTICAL Pub Date : 2023-11-04 eCollection Date: 2023-01-01 DOI: 10.1155/2023/5554877
Li Liu, Nanbiao Long, Juan Zhou, Manxue Liu, Shaobo He, Wuying Chu

This study aimed to investigate a detection method of enrofloxacin and ciprofloxacin to be avail for strictly supervising the quality and safety of aquatic products. The results displayed that the optimal extraction conditions for enrofloxacin and ciprofloxacin were the following five aspects: 15 g dosages of Na2SO4 to dehydrate, 8‰ of acetonitrile and 50% hydrochloric acid to deproteinization, 2 mL dosages of n-hexane to degrease, 10 min of ultrasonic time, and 20 min of extraction (stand) time. Meanwhile, it was also obtained for the optimal detection performance indexes of the recovery, precision, and accuracy from the tests of shrimp, grass carp, and tilapia. In particular, the expanded uncertainties were 2.8601 and 0.8613, and the factors of both the calibration curves (Urel(C)) and the analysis of the experiment (Urel(E)) were the two MU main contributors for enrofloxacin and ciprofloxacin together with the results above 40%. Consequently, the developed novel method was suited for the determination of the enrofloxacin and ciprofloxacin residues in aquatic products and would contribute to reinforce in supervision and inspection of the quality and safety of aquatic products.

本研究旨在建立恩诺沙星和环丙沙星的检测方法,以便严格监督水产品的质量安全。结果表明,恩诺沙星和环丙沙星的最佳提取工艺为:Na2SO4用量为15 g脱水,乙腈用量为8‰,盐酸用量为50%脱蛋白,正己烷用量为2 mL脱脂,超声时间为10 min,提取(静置)时间为20 min。同时,通过对虾、草鱼、罗非鱼的检测,获得了回收率、精密度、准确度的最佳检测性能指标。其中,扩展不确定度分别为2.8601和0.8613,校正曲线(Urel(C))和实验分析(Urel(E))的因素均大于40%,是恩诺沙星和环丙沙星的两个MU主要贡献因子。该方法适用于水产品中恩诺沙星和环丙沙星残留的检测,有助于加强水产品质量安全的监督检查。
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International Journal of Analytical Chemistry
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