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Study on the feasibility of alternatives for phenolic resins used in sand casting 砂型铸造用酚醛树脂替代品的可行性研究
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2022-02-16 DOI: 10.1080/13640461.2022.2036415
Syeda Talat Arshad, A. Shah, Aqueel Shah
ABSTRACT Phenolic resins are in-organic polymers with properties that make them high-strength binders with great potential for modification. The base-catalyzed phenol-formaldehyde resins provide the desired hardness to the core avoiding sand slipping on the surface. A modified resol type phenolic resin is developed for this study with minimum ingredients to compare it with existing recipes in the literature. A batch of cores was prepared with the standard 1-inch cross-section briquettes (dog-bone) with modified resol and cured through hot-curing process. Hardness and ultimate tensile strength values of these cores were compared with previous data present in literature. The average hardness as well the tensile strength from modified resol was higher than the cores from previous hot coating resol recipes and the gas-set cores present in the literature. Furthermore, the surface roughness of the cores was examined through Atomic Force Microscopy (AFM), and the ten-point height (Rz) value was lower than existing recipes.
摘要酚醛树脂是一种有机聚合物,其性能使其成为具有巨大改性潜力的高强度粘合剂。碱催化的酚醛树脂为芯体提供所需的硬度,避免沙子在表面打滑。本研究开发了一种改性甲阶酚醛树脂,其成分最少,并与文献中现有的配方进行了比较。用具有改性甲阶酚醛树脂的标准1英寸横截面压块(狗骨)制备一批芯,并通过热固化工艺进行固化。将这些岩芯的硬度和极限抗拉强度值与文献中已有的数据进行了比较。改性甲阶酚醛树脂的平均硬度和拉伸强度高于文献中存在的先前热涂层甲阶酚醛配方的芯和气固芯。此外,通过原子力显微镜(AFM)检查了芯的表面粗糙度,并且十点高度(Rz)值低于现有配方。
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引用次数: 0
Study on the mechanism of titanium improving the hot ductility of peritectic microalloyed steels in brittle zone III 钛提高包晶微合金钢脆区热延性的机理研究
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-11-02 DOI: 10.1080/13640461.2021.2011655
Xiaogang Yang, L. Xie, Chao-bin Lai, Diqiang Luo
ABSTRACT In the current article, the influence of titanium on the hot ductility of peritectic-microalloyed steels, in the temperature range 600°C to 950°C, was investigated by tensile testing. The morphology of the fracture and the behaviour of precipitates, inclusions and microstructures near the fracture surface were observed and discussed. It was found that within the test temperature range, the reduction in area values of titanium-bearing steels were almost greater than 40%, which were much larger than those of titanium-free steels. This improvement was due to the formation of (TixNb1-x)(CyN1-y) precipitates and titanium-aluminium oxides with high titanium content that could act as the nucleation sites for dimples to promote the occurrence of ductile fracture. In addition, the austenite grain was refined and more uniform in size. The thickness together with the maintain temperature range of the ferrite films which distribute only along austenite grain boundaries were reduced.
摘要本文通过拉伸试验研究了钛对包晶微合金钢在600°C至950°C温度范围内的热塑性的影响。观察和讨论了断口的形貌以及断口附近沉淀物、夹杂物和微观结构的行为。研究发现,在试验温度范围内,含钛钢的面积折减率几乎大于40%,远大于无钛钢。这种改进是由于形成了(TixNb1-x)(CyN1-y)沉淀物和具有高钛含量的钛铝氧化物,它们可以作为凹坑的成核位点,以促进韧性断裂的发生。此外,奥氏体晶粒细化,尺寸更加均匀。降低了仅沿奥氏体晶界分布的铁氧体膜的厚度和维持温度范围。
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引用次数: 1
Selection of technological additives to the composition of the moulding mixtures based on water glass 基于水玻璃的模塑混合物组成的工艺添加剂的选择
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-11-02 DOI: 10.1080/13640461.2021.2015889
N. A. Kidalov, A. S. Adamova, N. V. Grigoreva
ABSTRACT In the foundry for the production of moulds and cores, mixtures based on water glass are widely used. During their hardening, the coagulation of liquid glass occurs, as a result of which the mixture obtains high strength characteristic. A significant drawback of moulding mixtures based on water glass is low knockout due to increased sintering ability of water glass with moulding sand. To improve knockout, weak additives are introduced into the composition of moulding mixtures. This paper analyses the characteristics of organic weak additives for the composition of moulding mixtures based on water glass. It is shown that the main indicators which affecting to the knockout of mixtures are the amount of evolved gases and the forming carbon formation. With an increase in coefficient of thermal destruction, the knockout of the mixtures based on water glass mixture is reduced by increasing the amount of formed carbon.
在铸造厂生产模具和芯材时,以水玻璃为基础的混合物被广泛使用。在硬化过程中,玻璃液发生凝固,使混合物具有高强度特性。基于水玻璃的模塑混合物的一个显著缺点是由于水玻璃与型砂的烧结能力增加而导致敲除率低。为了提高敲除效果,在混合模的组成中引入了弱添加剂。本文分析了有机弱添加剂在水玻璃基模混合物组成中的特点。结果表明,影响混合物淘汰的主要指标是析出气体的数量和形成碳的形成。随着热破坏系数的增大,水玻璃混合料的淘汰率随着形成碳量的增加而降低。
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引用次数: 1
Effect of friction stir processing on microstructural and mechanical properties of lightweight composites and cast metal alloys – A review 搅拌摩擦处理对轻质复合材料和铸造金属合金组织和力学性能的影响
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-11-02 DOI: 10.1080/13640461.2021.2014667
A. Srivastava, N. Kumar, Ambuj Saxena, S. Tiwari
ABSTRACT Friction stir processing (FSP) is a solid-state processing method that can be used as a microstructural modifier or a post-processing technique. It can be applied to refine the grain structure. It is an eco-friendly manufacturing approach with negligible harmful gases and can be applied to all types of engineering materials. With the continuous development in FSP, now it is used to develop surface composites. The ability to refine the grain structure and uniform dispersion of reinforcement particles with improved mechanical and microstructural properties make it preferable over most of the manufacturing methods. The present work highlights the mechanism of FSP, the effect of dependent and independent process parameters, tool parameters and temperature variation in different zones of the stirring. It also focused on the microstructural features and effect of FSP on mechanical properties such as tensile strength and microhardness of the lightweight composites and cast alloys.
搅拌摩擦加工(FSP)是一种固态加工方法,可以用作微结构改性剂或后处理技术。它可以用于细化晶粒组织。这是一种环保的制造方法,有害气体可以忽略不计,可以应用于所有类型的工程材料。随着FSP技术的不断发展,目前已被用于表面复合材料的研制。细化晶粒结构和均匀分散增强颗粒的能力与改进的机械和微观组织性能使其优于大多数制造方法。本文重点研究了FSP的机理、依赖和独立工艺参数、工具参数和搅拌不同区域温度变化的影响。研究了FSP的微观组织特征及其对轻质复合材料和铸造合金抗拉强度和显微硬度等力学性能的影响。
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引用次数: 7
The investigation of microstructure and high temperature mechanical properties of novel Mg-Al-Sn-Ce alloy produced by HPDC HPDC法制备新型Mg-Al-Sn-Ce合金的显微组织和高温力学性能研究
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-09-23 DOI: 10.1080/13640461.2021.1981034
Rezzan Ördek, L. C. Kumruoglu, Hüseyin Şevik
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引用次数: 0
In-house design of forced convection direct chill casting simulator for casting immiscible Al-Sn alloys 非混相铝锡合金强制对流直接冷铸造模拟器的内部设计
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-08-25 DOI: 10.1080/13640461.2021.1970937
Deepak Patel, A. Kundu, Arjun Kundu, P. Biswas, H. Kotadia, A. Mallik, S. Das
ABSTRACT Al-Sn immiscible alloys possess enhanced tribological properties with increased fatigue strength, which makes them competent among self-lubricating bearing materials. In the present work, a direct chill (DC) casting simulator has been designed and manufactured to cast Al-Sn alloy by forced convection technology. The study embodies two different mechanisms for mechanical forced convection (MFC) by: (i) high shear (HS) rotor-stator device, (ii) conventional stirrer (CS) without stator. Shearing rate of 800 rpm for 60 seconds were kept constant for both the cases. Severe segregation of Sn has been observed in CS-DC cast billet due to prevailed phase separation and gravity sedimentation of Sn-rich phase from Al matrix. However, in the case of HS-DC cast billet uniform distribution of Sn and fine equiaxed grains throughout the volume of the billet has been achieved.
摘要Al-Sn不混溶合金具有增强的摩擦学性能和提高的疲劳强度,这使其在自润滑轴承材料中具有竞争力。本工作设计并制造了一种采用强制对流技术铸造铝锡合金的直接激冷(DC)铸造模拟装置。该研究体现了机械强制对流(MFC)的两种不同机制:(i)高剪切(HS)转子-定子装置,(ii)无定子的传统搅拌器(CS)。对于这两种情况,800rpm持续60秒的剪切速率保持恒定。在CS-DC铸坯中,由于富锡相与Al基体的普遍相分离和重力沉降,观察到锡的严重偏析。然而,在HS-DC铸坯的情况下,已经实现了Sn和细小等轴晶粒在整个铸坯体积中的均匀分布。
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引用次数: 1
A new Ductile Iron for mechanically and thermally strained rolls Part 1: Simulation-based process characterization of hot rolling 一种用于机械和热应变轧辊的新型球墨铸铁。第1部分:基于模拟的热轧工艺表征
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-08-16 DOI: 10.1080/13640461.2021.1965738
M. Liepe, S. Duwe, Martin Schrumpf, R. Bähr, B. Tonn
ABSTRACT When designing a new material for hot rolling rolls, it is necessary to be aware of the conditions in the later utilisation phase. The first step is to quantify stresses, and temperatures the material must tolerate operating in the rolling mills. These characteristics are evaluated by direct measurements and hot rolling simulations. Simulations targeted the identification of the temporal and spatial temperature distribution permeating the roll during the entire rolling process. As a major influence varying cooling conditions had to be accounted for roll temperatures. As an output value the minimum yield stress was identified – the determining factor for the development of a high strength roll material for cast rolls.
在设计一种用于热轧轧辊的新材料时,有必要了解后期利用阶段的条件。第一步是量化应力,以及材料在轧机中必须承受的温度。通过直接测量和热轧模拟对这些特性进行了评价。模拟的目标是识别整个轧制过程中贯穿轧辊的温度时空分布。作为一个主要的影响,不同的冷却条件必须考虑到轧辊温度。作为一个输出值,确定了最小屈服应力,这是开发高强度铸轧轧辊材料的决定因素。
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引用次数: 1
A new ductile iron for mechanically and thermally strained rolls Part 2: material development varying Ni, Mo, Cr content using DoE 一种用于机械和热应变轧辊的新型球墨铸铁。第二部分:利用DoE改变Ni, Mo, Cr含量的材料研制
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-08-07 DOI: 10.1080/13640461.2021.1962639
S. Duwe, M. Liepe, Martin Schrumpf, B. Tonn, R. Bähr
ABSTRACT For manufacturing of steel wires, tubes and profiles in hot rolling mills, the toughest conditions occur in the front rolling stands where the mechanical load comes along with a constant change of hot rolling stock and cooling liquid. Conventional roll materials as pearlitic or acicular cast irons are not able to overcome these intense conditions because of their lack of ductility. A fine selection of alloying elements leads to a new material with a microstructure uniting bainite, austenite and martensite inducing high hardness and strength, without lacking elongation. For this purpose, a full-factorial design of experiments was created consisting of three alloying elements in two concentrations each. The alloys were cast, heat-treated and underwent extensive investigations on mechanical properties and microstructure. The results were analysed and implemented in mathematical models whose combination and optimisation led to the identification of the ideal alloy meeting the required strength, hardness and elongation.
对于在热轧机中制造钢丝、钢管和型材,最苛刻的条件发生在前轧制台中,在这里,机械负荷伴随着热轧车辆和冷却液的不断变化。传统的轧辊材料,如珠光体或针状铸铁,由于其缺乏延展性,无法克服这些激烈的条件。通过对合金元素的精细选择,形成了一种结合贝氏体、奥氏体和马氏体的新材料,具有高硬度和高强度,同时又不缺乏伸长率。为此,创建了一个全因子实验设计,由三种合金元素以两种浓度组成。合金经过铸造、热处理,并进行了广泛的力学性能和显微组织研究。结果在数学模型中进行了分析和实现,这些模型的组合和优化导致了满足强度、硬度和伸长率要求的理想合金的识别。
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引用次数: 1
Solid-state phase transformation of ductile cast iron during electroslag remelting cladding 电渣重熔熔覆球墨铸铁的固相转变
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-06-26 DOI: 10.1080/13640461.2021.1945221
Yulong Cao, Yan-wu Dong, Guangqiang Li, Zhou-hua Jiang, Z. Zhao
ABSTRACT A bimetallic composite roll with the cladding layer of high-speed steel (HSS) and the roll core of ductile cast iron (DCI) was manufactured by the electroslag remelting cladding (ESRC) technology, and the changes in the graphite morphology, matrix structure, and mechanical properties of the DCI core before and after the ESRC process were compared. The DCI core was first heated to a very high temperature and then cooled down to room temperature during ESRC which led to a deteriorative graphite morphology with a low spheroidisation rate, a large size, and a nonuniform distribution and also caused a solid-state phase transformation of the matrix structure from lamellar pearlite + few carbides to bainite + large amounts of carbides. Based on the changes of graphite sphericity, matrix structure, carbides content, the tensile strength and impact toughness of DCI before and after the ESRC process changed from 458 MPa, 3.02 J/cm2 to 417 MPa, 5.74 J/cm2, respectively.
采用电渣重熔熔覆(ESRC)技术制备了以高速钢(HSS)包覆层和球墨铸铁(DCI)辊芯为包覆层的双金属复合轧辊,比较了ESRC工艺前后DCI辊芯石墨形貌、基体组织和力学性能的变化。在ESRC过程中,DCI芯先加热到高温,然后冷却到室温,导致石墨形貌恶化,球化率低,尺寸大,分布不均匀,并且导致基体结构从片层珠光体+少量碳化物向贝氏体+大量碳化物转变。基于石墨球度、基体结构、碳化物含量的变化,ESRC工艺前后DCI的抗拉强度和冲击韧性分别从458 MPa、3.02 J/cm2变化到417 MPa、5.74 J/cm2。
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引用次数: 0
On estimating the hydrogen solubility in solid aluminium alloys and the hydrogen solubility difference between the liquidus and solidus temperatures 关于氢在固态铝合金中溶解度的估算以及液相线和固相线温度之间的氢溶解度差异
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2021-03-04 DOI: 10.1080/13640461.2021.1912950
M. Tiryakioğlu
ABSTRACT The solubility of hydrogen in solid binary aluminium alloys has been investigated with data from the literature. As in liquid binary alloys, analysis has shown the effect of Cu, Mg, Si and Zn additions on normalised hydrogen solubility can be estimated by using exponential fits. The method developed previously to estimate hydrogen solubility in liquid commercial alloys has been extended to alloys in their solid state. Estimates for hydrogen solubility at the liquidus and solidus temperatures for five commercial alloys have been calculated. Estimates of the hydrogen solubility difference between liquid and solid alloys have shown that (i) the 206 alloy behaves exactly like pure aluminium (ii) 319 and A356 have much lower differences than pure aluminium, and (iii) hydrogen solubility at the solidus temperature is higher than at the liquidus temperature in alloy 380 and 383.
摘要利用文献资料研究了氢在固态二元铝合金中的溶解度。与液态二元合金一样,分析表明,添加Cu、Mg、Si和Zn对归一化氢溶解度的影响可以通过指数拟合来估计。先前开发的用于估计氢在液态商业合金中溶解度的方法已扩展到固态合金。对五种商用合金在液相线和固相线温度下的氢溶解度进行了估算。对液体和固体合金之间的氢溶解度差异的估计表明,(i)206合金的行为与纯铝完全相似(ii)319和A356具有比纯铝低得多的差异,以及(iii)合金380和383中在固相线温度下的氢溶解度高于在液相线温度下。
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引用次数: 3
期刊
International Journal of Cast Metals Research
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