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Structure formation and multistep nucleation in CASTING Al-Mg-Si alloys 铸造Al-Mg-Si合金的组织形成和多步形核
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1822632
O. Trudonoshyn, O. Prach, A. Slyudova, V. Lisovskii
ABSTRACT The process of multistep nucleation during solidification in hypoeutectic Al-Mg-Si casting alloys was investigated. The morphology of the nucleating particles, Mg2Si primary crystals and Al-Mg2Si eutectic, was investigated with scanning electron microscopy (SEM) on polished and deep etched microsections. The mechanism of formation of the Mg2Si crystal was attributed to heterogeneous nucleation on the nucleating particles. It was observed that the majority of the alloys particles found in the studied are oxides. It was established that eutectic Al–Mg2Si in hypoeutectic alloys has the morphology of ‘eutectic crystal’, where one face of the crystal has triangular-spiral morphology. The mechanism of formation of Al-Mg2Si eutectic cells is attributed to epitaxial growth on Mg2Si crystals. The microhardness of the structural components (Mg2Si crystals, α-Al dendrites, Al-Mg2Si eutectic, and Al3Ti crystals) was measured using Vickers hardness tester.
研究了亚共晶Al-Mg-Si铸造合金凝固过程中的多步形核过程。用扫描电子显微镜(SEM)在抛光和深蚀刻的微切片上研究了成核颗粒Mg2Si初晶和Al-Mg2Si共晶的形态。Mg2Si晶体的形成机制归因于成核颗粒上的非均匀成核。据观察,在研究中发现的大多数合金颗粒都是氧化物。研究表明,亚共晶合金中的共晶Al–Mg2Si具有“共晶晶体”的形态,其中晶体的一面具有三角形螺旋形态。Al-Mg2Si共晶电池的形成机理是在Mg2Si晶体上外延生长。用维氏硬度计测量了结构成分(Mg2Si晶体、α-Al枝晶、Al-Mg2Si共晶和Al3Ti晶体)的显微硬度。
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引用次数: 5
Thermodynamic behaviour of nitrogen in the carbon saturated Fe-Mn-Si alloy during casting 碳饱和铁锰硅合金中氮在铸造过程中的热力学行为
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1834176
Min-Kyu Paek, Junmo Jeon, D. Lindberg
ABSTRACT The evolution of nitrogen gas formation in cast iron was studied based on the information of the N solubility in the carbon-saturated iron-containing Mn and Si over the wide temperature range. In order to verify the accuracy of the Fe-Mn-Si-C phase diagram, the transition temperatures of the Fe-Mn-2.7 wt%Si-Csat alloys were measured according to the Mn concentration using a differential scanning calorimetry under the purified Ar atmosphere. The recent thermodynamic modelling result of the Fe-Mn-Si-C-N system was used to describe the solubility limit of N in liquid and solid solution in the carbon saturated iron alloys. The cooling and quenching experiments were also carried out to check the effects of temperature and phase transformation on the N solubility limit in the temperature range from 500°C to 900°C.
基于N在碳饱和含铁Mn和Si中的溶解度信息,研究了铸铁中氮气形成的演化过程。为了验证Fe-Mn-Si-C相图的准确性,利用差示扫描量热法在纯化氩气氛下,根据Mn浓度测量了Fe-Mn-2.7 wt%Si-Csat合金的转变温度。利用Fe-Mn-Si-C-N体系的热力学模拟结果,描述了N在饱和碳铁合金中液相和固相的溶解度极限。在500 ~ 900℃温度范围内进行了冷却和淬火实验,考察了温度和相变对N溶解度极限的影响。
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引用次数: 2
Simulations and experiments of mould filling in lost foam casting 消失模铸造充型的模拟与试验
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-09-02 DOI: 10.1080/13640461.2020.1822572
Feng-jun Li, Hua Zhao, F. Ren, Shaobiao Song, X. Shao, A. Volinsky
ABSTRACT A new method for mould filling calculation of lost foam casting (LFC) was developed based on the main hypothesis, which assumes that every point on the melt-pattern interface moves in the radial direction. The value of the normal velocity is calculated by an empirical formula, which is the function of the degree of vacuum, pattern density, pouring temperature, metallic static head, etc. At a given time step, every interface point moves to a new position, and all the points form the shape of the melt-pattern interface. Based on the new position of the interface and the given velocity of the interface cell, the fluid flow and the temperature distribution of the molten metal can be calculated during the mould filling process of LFC. The calculated results were validated by experiments.
摘要基于熔模界面上各点径向运动的主要假设,提出了一种计算消失模铸造充型量的新方法。法向速度是真空程度、模型密度、浇注温度、金属静水头等因素的函数,用经验公式计算出法向速度。在给定的时间步长,每个界面点移动到一个新的位置,所有的点形成熔化模式界面的形状。根据新的界面位置和给定的界面单元速度,可以计算出LFC充型过程中的流体流动和熔融金属的温度分布。通过实验验证了计算结果。
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引用次数: 3
Mechanism of P-wave promoting the solidification feeding in the low-pressure casting of ZL205A alloy p波促进ZL205A合金低压铸造凝固喂入的机理
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-08-06 DOI: 10.1080/13640461.2020.1804168
Guixin Dai, Shi-ping Wu, Wei Chen, Xixi Huang
ABSTRACT The effect of P/S-wave on the solidification feeding and the mechanism of vibration promoting the solidification feeding in the low-pressure casting are discussed in the paper. The casting defects were analysed by X-ray non-destructive testing and the buoyancy method. It can be found that the compactness of casting is greatly improved by vibration. In the solidification feeding, according to vibration theory, P-wave will play a decisive role. When the transmission direction of P-wave is perpendicular to the feeding direction, it will lead to the alternation of dense-sparse state in the solidification system. When feeding is blocked, in the sparse state, the diameter of the feeding channel will increase, so that the pressure loss of feeding decreases. At the feeding end, the feeding pressure will make the solidification feeding again. On the contrary, vibration can’t further promote the feeding in the dense state.
本文讨论了P/ s波对低压铸造凝固喂料的影响以及振动促进凝固喂料的机理。采用x射线无损检测和浮力法对铸件缺陷进行了分析。结果表明,振动大大提高了铸件的致密性。在凝固喂料过程中,根据振动理论,纵波将起决定性作用。当纵波的传播方向与进料方向垂直时,将导致凝固系统中密疏状态的交替。当进料受阻时,在稀疏状态下,进料通道直径增大,使进料压力损失减小。在加料端,加料压力将使凝固再次加料。反之,在致密状态下,振动不能进一步促进进给。
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引用次数: 2
strain induced melt activation (SIMA): original concept, its impact and present understanding 应变诱发熔体激活(SIMA):最初的概念,它的影响和目前的理解
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-08-01 DOI: 10.1080/13640461.2020.1801561
F. Czerwinski
ABSTRACT The concept of converting dendritic structures into globular morphologies through solid-state deformation, termed as strain-induced melt activation (SIMA), is assessed. Although the original invention defined the specific two-stage deformation scenario, almost four decades of extensive research, involving a variety of ferrous and non-ferrous alloys, subjected to conventional and severe plastic deformations, caused its evolution. According to present understanding, any deformation of cast structures with a strain level sufficient to trigger recrystallisation leads to dendrite-to-globule transition during subsequent partial melting. It is proposed that the SIMA term should not only be associated with the particular deformation scenario but should be seen as a broad synonym for a variety of thermomechanical treatments, explored for controlling the solidification microstructure. Such an updated definition expands applicability of the SIMA concept from bulk billets to coarse particulates and fine powders.
通过固态变形将枝晶结构转化为球状形态的概念,称为应变诱导熔体激活(SIMA),进行了评估。虽然最初的发明定义了具体的两阶段变形场景,但近四十年的广泛研究,涉及各种黑色和非黑色金属合金,遭受常规和严重的塑性变形,导致了它的发展。根据目前的理解,任何足以触发再结晶的应变水平的铸造组织的变形都会导致在随后的部分熔化过程中枝晶到球的转变。本文提出,SIMA一词不仅应与特定的变形情景相关联,而且应被视为用于控制凝固组织的各种热处理的广义同义词。这样一个更新的定义扩展了SIMA概念的适用性,从散装坯料到粗颗粒和细粉末。
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引用次数: 9
Investigations on the suitability of banana peel powder as an alternative additive in synthetic green sand moulding system 香蕉皮粉作为合成绿砂成型系统替代添加剂的适用性研究
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-07-29 DOI: 10.1080/13640461.2020.1796294
V. Siddharth, D. Rao, B. R. Ramana Murthy
ABSTRACT An experimental study focused on the determination of mechanical properties of synthetic green sand system using Nagavali river sand by adding banana peel powder as an additive. Compression strength, shear strength, mould hardness bulk density and permeability are the various properties found in the laboratory following standard testing procedures. Sand aggregate is prepared by mixing the bentonite as binder and banana peel powder as an additive to the silica sand in various amounts. Encouraging results in terms of strength and hardness are obtained by testing the standard sand samples. In fact, the properties exhibited are almost similar to the values obtained by addition of 2% dextrin as an additive to the sand aggregate. Since the banana peel powder can be easily prepared which is most economical in terms of cost compared with dextrin, that can be an alternative additive in preparing the sand moulds to obtain adequate strength and hardness.
以纳加瓦里河砂为原料,添加香蕉皮粉作为添加剂,研究了合成绿砂体系的力学性能。抗压强度、抗剪强度、模具硬度、体积密度和渗透性是在实验室按照标准测试程序发现的各种性能。以膨润土为粘结剂,以香蕉皮粉为添加剂,以不同的量加入到硅砂中,制备砂骨料。通过对标准砂样的强度和硬度测试,取得了令人鼓舞的结果。事实上,所表现出的性能几乎与添加2%糊精作为砂骨料添加剂所获得的值相似。由于香蕉皮粉可以很容易地制备,与糊精相比在成本上是最经济的,因此可以作为制备砂模的替代添加剂,以获得足够的强度和硬度。
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引用次数: 5
On the heterogeneous nucleation pressure for hydrogen pores in liquid aluminium 铝液中氢孔的非均匀形核压力
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-07-21 DOI: 10.1080/13640461.2020.1797335
M. Tiryakioğlu
ABSTRACT Heterogeneous nucleation based on the spherical cap model has been used in this study to evaluate nucleation pressure and the number of hydrogen atoms necessary for nucleation. Calculations have shown that the minimum heterogeneous nucleation pressure that can be achieved is in the order of 1 GPa, which is four orders of magnitude larger than the values assumed in the literature. Implications of the results are discussed.
摘要基于球帽模型的非均匀成核已被用于评估成核压力和成核所需的氢原子数。计算表明,可以实现的最小非均匀成核压力约为1GPa,比文献中假设的值大四个数量级。讨论了结果的含义。
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引用次数: 9
Effect of cast iron microstructure on adherence of an epoxy protection 铸铁组织对环氧保护层附着力的影响
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-06-08 DOI: 10.1080/13640461.2020.1778151
A. Freulon, A. T. Trinh, J. Lacaze, B. Malard, K. Vu
ABSTRACT To study the influence of the microstructure of cast iron on the adhesion of an epoxy coating, ferritic, pearlitic and austempered samples were prepared in as-received, polished and oxidised states. A pull-off test (dry adhesion) was performed before immersing in water while the cross-cut test was made after 24 days of exposition in distilled water (wet adhesion). X-rays were combined with optical microscopy (LOM) and scanning electron microscopy (SEM) for surface analysis. The adhesion of the epoxy coating on the cast iron surface firstly depends on the roughness of the surface; polished samples showed high adherence by comparison with as-received samples. On the oxidised samples, the surface oxide significantly improves the adhesion of the coating in both dry and wet states for all three sample microstructure. The presence of carbide in the structure was observed to decrease adherence.
摘要:为了研究铸铁微观组织对环氧涂层附着力的影响,分别制备了铁素体、珠光体和等温体样品,分别处于接收态、抛光态和氧化态。在浸水前进行拉脱试验(干粘附),在蒸馏水中暴露24天后进行横切试验(湿粘附)。x射线结合光学显微镜(LOM)和扫描电镜(SEM)进行表面分析。环氧涂层在铸铁表面的附着力首先取决于表面的粗糙度;与收到的样品相比,抛光样品显示出较高的粘附性。在氧化后的样品上,表面氧化物显著提高了涂层在干湿两种状态下的附着力。观察到组织中碳化物的存在降低了粘附性。
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引用次数: 1
Surface modification of ductile iron produced by an innovative in-situ casting technique 采用创新原位铸造技术生产球墨铸铁的表面改性
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-05-03 DOI: 10.1080/13640461.2020.1766278
E. Mardaras, R. González-Martínez, R. Bayón, L. Nastac, S. Méndez
ABSTRACT In this study, a chromium carbide layer was fabricated by an in-situ casting technique on ductile iron cast components. The procedure consists of (i) applying a ferrochrome slurry at the surfaces of silica sand moulds to create a surface layer (e.g. coating) and (ii) use a ductile iron alloy to cast the coated moulds. The microstructure of the realised surface layer was characterised and analysed via Scanning Electron Microscopy (SEM), optical microscopy (OM) and X-ray Diffraction (XRD).The corrosion behaviour of the samples was analysed by an electrochemical method using 0.03 M NaCl. The wear tests and Vickers hardness measurements were performed to determine the properties of the surface layer. It was determined that the layer is composed of chromium carbide (Cr7C3), ledeburite and pearlite. The ‘chromium carbide’constituent improved significantly both the wear resistance and the hardness of the surface layer. Electrochemical measurements have indicated that the carbide-based layer exhibits a lower corrosion resistance than the substrate (e.g. casting).
采用原位铸造技术在球墨铸铁件表面制备碳化铬层。该过程包括(i)在硅砂模具表面涂上铬铁浆料以形成表面层(例如涂层)和(ii)使用球墨铁合金铸造涂层模具。通过扫描电子显微镜(SEM)、光学显微镜(OM)和x射线衍射仪(XRD)对实现的面层微观结构进行了表征和分析。用电化学方法分析了样品在0.03 M NaCl溶液中的腐蚀行为。进行了磨损试验和维氏硬度测量,以确定表面层的性能。测定该层由碳化铬(Cr7C3)、莱氏体和珠光体组成。碳化铬成分显著提高了合金的耐磨性和表层硬度。电化学测量表明,碳化物基层的耐腐蚀性低于基材(如铸件)。
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引用次数: 3
Microstructural, mechanical and tribological analysis of functionally graded copper composite 功能梯度铜复合材料的显微组织、力学和摩擦学分析
IF 1.4 4区 材料科学 Q2 Materials Science Pub Date : 2020-05-03 DOI: 10.1080/13640461.2020.1769318
R. N, M. Sam
ABSTRACT Functionally graded Cu-10Sn-5Ni/10B4C composite was fabricated using horizontal centrifugal casting. Microstructural and mechanical properties were superior at reinforcement-rich inner zone where wear tests were conducted based on response surface methodology five-level run order, using pin on disc tribometer. Results showed that wear rate increases linearly with increase in load and sliding velocity whereas with increased sliding distance, it increases non-linearly with reduced slope. Minimum wear is observed at optimum combination of load (10 N), velocity (1 m/s) and sliding distance (500 m). Worn surfaces were analysed using scanning electron microscope to determine the wear mechanisms. Results concluded applied load as the major influential parameter over wear rate leading to occurrence of deep grooves along with delamination at higher loads and shallow grooves along the sliding direction at lower loads. Fabricated composite proves the ability to replace conventional materials for automotive sliding applications, providing improved wear characteristics at dry sliding conditions.
采用水平离心铸造法制备了Cu-10Sn-5Ni/10B4C功能梯度复合材料。在富含钢筋的内部区域,使用销盘式摩擦计,基于响应面法五级运行顺序进行磨损试验,微观结构和机械性能优越。结果表明,磨损率随着载荷和滑动速度的增加呈线性增加,而随着滑动距离的增加,磨损率则随着坡度的减小呈非线性增加。在载荷(10N)、速度(1m/s)和滑动距离(500m)的最佳组合下,磨损最小。使用扫描电子显微镜对磨损表面进行分析,以确定磨损机制。结果表明,外加载荷是影响磨损率的主要参数,导致在较高载荷下出现深槽和分层,在较低载荷下出现沿滑动方向的浅槽。制造的复合材料证明了在汽车滑动应用中取代传统材料的能力,在干燥滑动条件下提供了改进的磨损特性。
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引用次数: 4
期刊
International Journal of Cast Metals Research
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