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Impact of grape marc, as a partial replacer of sugar and wheat flour, on the bioaccessibility of polyphenols, technological, sensory, and quality properties of cake by mixture design approach 采用混合设计法研究葡萄马克作为糖和小麦粉的部分替代品对蛋糕中多酚类物质的生物可及性、工艺、感官和品质的影响
IF 1.6 4区 农林科学 Pub Date : 2022-09-01 DOI: 10.1515/ijfe-2022-0203
Kubra Bursa, Goksen Isik, R. Yıldırım, Gorkem Ozulku, Nasim Kian-pour, O. S. Toker, I. Palabiyik, M. Gulcu
Abstract This investigation aimed to valorize grape marc (GM) in the formulation of cakes for ideal technological, nutritional and organoleptic properties. The GM (0–20%) was used for the partial substitution of wheat flour (40–50%) and sugar (40–50%). Total polyphenols in the cake samples, their post digestion, and bioaccessibility varied from 65.49–462.07; 13.34–608.62 mg GAE/g, and 23.42–315.47%, respectively. The values of the elastic modulus of the batter were higher than those of the viscous modulus, indicating the elastic behavior of the cakes. The hardness and springiness ranged from 2.20–4.22 N, and 0.85–0.98 mm, respectively. The results predicted by mixture design revealed that the samples including 50% wheat flour, 48.73% sugar, and 1.94% GM were the best formulation for the optimization of organoleptic properties. According to the results, GM can be used to develop cakes with a good nutritional composition as well as functional, sensory, and quality attributes at the industrial scale.
摘要本研究旨在对葡萄马克(GM)在蛋糕配方中的应用进行优化,以获得理想的工艺、营养和感官特性。采用转基因(0 ~ 20%)部分替代小麦粉(40 ~ 50%)和糖(40 ~ 50%)。饼样中总多酚、后消化和生物可及性变化范围为65.49 ~ 462.07;13.34 ~ 608.62 mg GAE/g, 23.42 ~ 315.47%。面糊的弹性模量高于粘性模量,说明面糊具有弹性。硬度为2.20 ~ 4.22 N,弹性为0.85 ~ 0.98 mm。混合设计预测结果表明,以50%小麦粉、48.73%糖、1.94%转基因玉米为最佳配方,可优化其感官性能。由此可见,利用转基因技术可以开发出具有良好营养成分、功能、感官和品质属性的蛋糕。
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引用次数: 0
Changes of wort characteristic components through low thermal stress boiling 低热应力煮沸对麦汁特征成分的影响
IF 1.6 4区 农林科学 Pub Date : 2022-09-01 DOI: 10.1515/ijfe-2021-0363
Xiaoyong Dai, Fan Zhang, Wei Wu, Qing Xu, Long-yuan Wu, Zhanyong Li
Abstract This paper systematically studied the changes of wort characteristic components under various low thermal stress boiling, and separation methods of Dimethyl-Sulfide (DMS) accumulated in wort due to low thermal stress boiling. Compared with conventional boiling, the combined boiling (boiling at 3% evaporation rate and 98 °C holding temperature for 30 min) demonstrated that the change rates of solidifiable nitrogen, iso-α-acid and color were no more than 5%, the absorbance of thiobarbituric acid (TBA) reaction mixture decreased by 13.7%, and DMS can be separated by vacuum film stripping after whirlpool. For 98 °C holding temperature boiling, the differences in absorbance of TBA reaction mixture, iso-α-acid and color were 16, 11.6 and 5%, respectively. The solidifiable nitrogen content was equivalent to the 28 mg/L limit and DMS must be removed by vacuum film stripping two times. From the perspective of application, it is necessary to improve the separation efficiency of DMS subsequently.
摘要系统地研究了不同低热应力沸腾条件下麦芽汁特征组分的变化,以及低热应力煮沸条件下积累在麦芽汁中的二甲基硫醚(DMS)的分离方法。与常规沸腾相比,组合沸腾(在3%蒸发率和98°C保温30min下沸腾)表明,可固化氮、异α酸和颜色的变化率不超过5%,硫代巴比妥酸(TBA)反应混合物的吸光度下降13.7%,涡流后真空膜汽提可分离DMS。在98°C保温沸腾条件下,TBA反应混合物、异α酸和颜色的吸光度差异分别为16%、11.6%和5%。可固化氮含量相当于28mg/L的限值,DMS必须通过真空膜汽提两次来去除。从应用的角度来看,后续有必要提高DMS的分离效率。
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引用次数: 1
Effects of sucrose and sodium chloride pretreatments on cassava and plantain chips fried in CLA-enriched soybean oil: an analysis of acrylamide content, microstructure, and other physical properties 蔗糖和氯化钠预处理对在富含cla的大豆油中油炸的木薯和大蕉片的影响:丙烯酰胺含量、微观结构和其他物理性质的分析
IF 1.6 4区 农林科学 Pub Date : 2022-08-29 DOI: 10.1515/ijfe-2021-0263
J. Rodríguez‐Miranda, E. Herman‐Lara, J. C. Serrano-Niño, Bruno Alberto Sánchez-Ruiz, C. E. Martínez-Sánchez
Abstract The purpose of this research was to evaluate the effect of soaking plantain and cassava chips in sucrose or sodium chloride (NaCl) on their physical properties and acrylamide content after frying in Conjugated Linoleic Acid (CLA)-enriched soybean oil. Plantain and cassava were cut into 1 mm thick slices and soaked for 20 min in a solution of 30% sucrose or 3% NaCl at 40 °C, separately. Soaking in sucrose and NaCl had no significant effect (p < 0.05) on water loss, porosity, hardness, or microstructure. The acrylamide content ranged from 634 to 3177 µg/kg. The use of CLA-enriched oil had no significant effect (p < 0.05) on the physical characteristics evaluated in this study. Frying reduced the CLA content in the chips from an initial 31.8% in the oil to 22.25 and 21.69% in plantain and cassava chips, respectively.
摘要本试验研究了在富含共轭亚油酸(CLA)的大豆油中,用蔗糖或氯化钠(NaCl)浸泡大蕉和木薯片,对其油炸后的物理性质和丙烯酰胺含量的影响。将大蕉和木薯切成1mm厚的薄片,分别在30%蔗糖或3% NaCl溶液中浸泡20 min,温度为40℃。蔗糖和NaCl浸泡对其失水、孔隙度、硬度和微观结构均无显著影响(p < 0.05)。丙烯酰胺含量为634 ~ 3177µg/kg。使用富含cla的油对本研究评估的物理特性没有显著影响(p < 0.05)。油炸后,大蕉片和木薯片的CLA含量分别从油中的31.8%降至22.25%和21.69%。
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引用次数: 1
Modelling thermal diffusivity of meat during freezing 模拟肉类在冷冻过程中的热扩散
IF 1.6 4区 农林科学 Pub Date : 2022-08-17 DOI: 10.1515/ijfe-2021-0351
J. Carson, D. Hoang
Abstract When modelling a thermal process such as freezing, it is convenient to make use of thermal property models based on the food’s composition; however, there does not appear to be any suitable models specifically for thermal diffusivity. In the absence of such models, thermal diffusivity may be determined from models for effective thermal conductivity, specific heat capacity and density as functions of composition, as well as an appropriate ice fraction model. However, the accuracy of the predictions is strongly dependent on the choice of effective thermal property models. In particular, the effective specific heat capacity model must incorporate the effect of latent heat release as a function of temperature. For meat during freezing, it is recommended that the Dul’Nev Novikov effective thermal conductivity model, Pham’s ice fraction model and Chen’s effective heat capacity model are used.
摘要在对冷冻等热过程进行建模时,可以方便地使用基于食品成分的热特性模型;然而,似乎没有任何适合的模型专门用于热扩散率。在没有这种模型的情况下,热扩散率可以根据有效热导率、比热容和密度作为组成函数的模型以及适当的冰分数模型来确定。然而,预测的准确性在很大程度上取决于有效热性能模型的选择。特别是,有效比热容模型必须将潜热释放的影响作为温度的函数。对于冷冻过程中的肉类,建议使用Dul'Nev-Novikov有效导热系数模型、Pham的冰分数模型和Chen的有效热容模型。
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引用次数: 0
Degradation kinetics of carpaine and antioxidant properties of dried Carica papaya leaves as affected by drying methods 干燥方法对番木瓜干叶中Carican的降解动力学及抗氧化性能的影响
IF 1.6 4区 农林科学 Pub Date : 2022-08-17 DOI: 10.1515/ijfe-2021-0369
J. Y. Yap, C. Hii, S. P. Ong, K. Lim, F. Abas, K. Pin
Abstract Carpaine in papaya leaves has the potential to treat dengue fever and it also contains antioxidants which could prevent or inhibit oxidation processes in the human body. Studies were conducted on the effects of storage on carpaine retention and antioxidant properties of dried papaya leaves. Results showed that the Weibull model could predict well the degradation kinetics of carpaine in all samples (freeze drying and hot air drying at 60 °C and 70 °C) except for hot air dried samples at 80 °C and shade dried samples (first order model). Generally, freeze dried samples showed the highest half-life whereas total polyphenols content and antioxidant properties (ABTS and DPPH free radical scavenging activities) of all dried samples decreased with storage period. An increasing trend in total colour difference (ΔE * ) was observed in all samples possibly due to chlorophyll degradation. It is thus recommended to select freeze dried samples for storage purpose due to better stability as indicated by the lowest rate constant (k = 0.0135 1/month) and the highest half-life (t1/2 = 51.2 months).
摘要木瓜叶中的Carpaine具有治疗登革热的潜力,它还含有抗氧化剂,可以防止或抑制人体内的氧化过程。研究了贮藏条件对番木瓜干叶的保留和抗氧化性能的影响。结果表明,威布尔模型可以很好地预测所有样品(60°C和70°C的冷冻干燥和热风干燥)中的carpaine降解动力学,但80°C的热风干燥样品和阴凉干燥样品除外(一阶模型)。通常,冷冻干燥的样品显示出最高的半衰期,而所有干燥样品的总多酚含量和抗氧化性能(ABTS和DPPH自由基清除活性)随着储存期的延长而降低。在所有样品中观察到总色差(ΔE*)呈增加趋势,这可能是由于叶绿素降解所致。因此,建议选择冷冻干燥样品进行储存,因为最低速率常数(k=0.0135 1/月)和最高半衰期(t1/2=51.2个月)表明其稳定性更好。
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引用次数: 2
Extraction of phenolic compounds from apple pomace, process modeling and antioxidant potential evaluation of extracts 苹果渣中酚类化合物的提取、工艺模拟及抗氧化潜力评价
IF 1.6 4区 农林科学 Pub Date : 2022-07-01 DOI: 10.1515/ijfe-2022-0012
Lucía Xavier, Justina Pisani, Gustavo Meghirditchian, R. de Mattos, I. Vieitez, Manuel Barrenengoa, B. Zecchi
Abstract Apple pomace, a byproduct of juice and cider production, is rich in phenolic compounds with antioxidant activity. This work studies the kinetics of solid–liquid extraction of phenolic compounds from apple pomace. Extraction kinetics were determined using a 50% water–ethanol solution and fitted to a phenomenological model. Equilibrium isotherms were also modeled. Effective diffusion coefficient values between 1.85x10−11 and 7.37x10−11 m2/s were found. External mass transfer resistance showed negligible results. The best yields (43.94%) were obtained at 60 °C with a solid–liquid ratio of 1:10 g/mL. Those conditions resulted in a total phenolic content of 9.95 mg gallic acid equivalents (GAE)/g apple pomace d.b., antioxidant FRAP activity of 5.07 mmol ascorbic acid equivalents (AAE)/100 g apple pomace d.b. and 3.74 mmol trolox equivalents (TRE)/100 g apple pomace d.b. based on a DPPH assay. Apple pomace extract efficiently stabilized sunflower oil and may represent a natural alternative to synthetic antioxidants.
摘要苹果渣是果汁和苹果酒生产的副产品,富含具有抗氧化活性的酚类化合物。本文研究了苹果渣中酚类化合物的固液萃取动力学。使用50%的水-乙醇溶液测定萃取动力学,并拟合现象学模型。还对平衡等温线进行了建模。发现有效扩散系数值在1.85x10−11和7.37x10−11 m2/s之间。外部传质阻力显示出可忽略不计的结果。在60°C、固液比为1:10 g/mL的条件下获得了最佳产率(43.94%)。基于DPPH测定,这些条件导致总酚含量为9.95 mg没食子酸当量(GAE)/g苹果渣d.b.,抗氧化FRAP活性为5.07 mmol抗坏血酸当量(AAE)/100 g苹果渣d.b.3.74 mmol特洛氧当量(TRE)/100 g果渣d.b。苹果渣提取物有效稳定了葵花籽油,可能是合成抗氧化剂的天然替代品。
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引用次数: 0
Purification and characterization of catechol oxidase from Posof Badele apple (Malus domestica L): in vitro and in silico studies 巴德勒苹果(Malus domestica L)儿茶酚氧化酶的纯化与鉴定:体外和硅细胞研究
IF 1.6 4区 农林科学 Pub Date : 2022-07-01 DOI: 10.1515/ijfe-2022-0022
Ayhan Çiğdem, U. Güller
Abstract In the current study, polyphenol oxidase (PPO), responsible for enzymatic browning in fruits, was purified from Posof Badele apple (PB) (Malus domestica L.) in two steps as acetone precipitation and affinity chromatography. After purification, the purity of PBPPO was checked by using SDS-PAGE. It was figured out that PBPPO had maximum activity at pH 6.0 and 10 °C and it was stable at pH 5.5 and temperatures of 0–30 °C. Besides, it was determined that Al3+ and Cu2+ metal ions activated the enzyme and the PBPPO was strongly inhibited by ascorbic acid with a Ki constant of 1.67 ± 0.35 µM. Inhibitor-enzyme interactions were examined by molecular docking studies and it was revealed that ascorbic acid had the lowest docking score of −6.54 kcal/mol. We wanted to draw attention to the PB apple, which is red inside as well as outside and very rich in terms of nutrient content.
摘要本研究采用丙酮沉淀和亲和层析两步法,从巴德尔苹果(Malus domestica L.)中分离纯化了果实酶促褐变的多酚氧化酶(PPO)。纯化后用SDS-PAGE检测PBPPO的纯度。结果表明,PBPPO在pH 6.0和10°C时活性最高,在pH 5.5和温度0-30°C时稳定。另外,Al3+和Cu2+金属离子对PBPPO有激活作用,抗坏血酸对PBPPO有较强的抑制作用,Ki常数为1.67±0.35µM。通过分子对接研究考察了抑制剂与酶的相互作用,发现抗坏血酸的对接分数最低,为−6.54 kcal/mol。我们想让大家注意到PB苹果,它内外都是红色的,营养成分非常丰富。
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引用次数: 1
Thermal stability enhancement of berry anthocyanins by co-pigmentation with extracts from natural sources 与天然提取物共着色剂增强浆果花青素的热稳定性
IF 1.6 4区 农林科学 Pub Date : 2022-07-01 DOI: 10.1515/ijfe-2021-0260
Aichurok T. Mazhitova, Aidaikan M. Kasymakunova, N. Turker
Abstract The suitability of mandarin (MP), orange (OP) and pomegranate peel powders (PP) for co-pigmentation of dewberry, viburnum, red hawthorn, black hawthorn, and barberry anthocyanins was investigated. Spectrophotometric measurements indicated co-pigmentation causing both a hyperchromic effect (ΔABSmax = 5–13) and bathochromic shift (Δλvis-max up to 13 nm). The degradation kinetics of anthocyanins were estimated at temperatures ranging from 70 to 90 °C. First-order reactions with rate constants of 0.45–2.93 min−1 and 0.30–2.00 min−1 were observed for the reference and PP co-pigmented samples, respectively. The t1/2 values were 3.90–25.7 h for the reference and 5.8–38.5 h for the co-pigmented samples. The activation energy (Ea) values were higher in co-pigmented samples (49.16–77.77 kJ/mol) than in reference samples (41.82–68.75 kJ/mol), except for black hawthorn, which had a lower Ea value in the co-pigmented sample. The thermodynamic parameters (enthalpy, free energy, and entropy) evaluated indicated a positive effect of co-pigmentation on the thermal treatment of anthocyanins.
摘要研究了桔皮粉(MP)、橙皮粉(OP)和石榴皮粉(PP)对露莓、豆荚、红山楂、黑山楂和杨梅花青素共着色剂的适宜性。分光光度测量表明,共色素沉着引起了深色效应(ΔABSmax = 5-13)和深色偏移(Δλvis-max达13 nm)。在70 ~ 90℃的温度范围内对花青素的降解动力学进行了估计。参考样品和PP共着色样品的一级反应速率常数分别为0.45-2.93 min−1和0.30-2.00 min−1。参考样品t1/2值为3.90 ~ 25.7 h,共色素样品t1/2值为5.8 ~ 38.5 h。除黑山楂的Ea值较低外,共色素样品的Ea值(49.16 ~ 77.77 kJ/mol)高于参比样品(41.82 ~ 68.75 kJ/mol)。热力学参数(焓、自由能和熵)的评估表明,共着色对花青素的热处理有积极的影响。
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引用次数: 2
Detection of chicken and fat adulteration in minced lamb meat by VIS/NIR spectroscopy and chemometrics methods 用VIS/NIR光谱和化学计量学方法检测羊肉肉末中鸡肉和脂肪的掺假
IF 1.6 4区 农林科学 Pub Date : 2022-06-30 DOI: 10.1515/ijfe-2021-0333
Amir Kazemi, A. Mahmoudi, H. Veladi, A. Javanmard
Abstract Meat fraud has been changed to an important challenge to both industry and governments because of the public health issue. The main purpose of this research was to inspect the possibility of using VIS/NIR spectroscopy, combined with chemometric techniques to detect the adulteration of chicken meat and fat in minced lamb meat. 180 samples of pure lamb, chicken and fat and adulterated samples at different levels: 5, 10, 15 and 20% (w/w) were prepared and analyzed after pre-processing techniques. In order to remove additive and multiplicative effects in spectral data, derivatives and scatter-correction preprocessing methods were applied. Principle Component Analysis (PCA) as unsupervised method was applied to compress data. Moreover, Support Vector Machine (SVM) and Soft Independent Modeling Class Analogies (SIMCA) as supervised methods was applied to estimate the discrimination power of these models for nine and three class datasets. The best classification results were 56.15 and 80.70% for classification of nine class and three class datasets respectively with SVM model. This study shows the applicability of VIS/NIR combined with chemometrics to detect the type of fraud in minced lamb meat.
摘要由于公共卫生问题,肉类欺诈已成为行业和政府面临的重要挑战。本研究的主要目的是检验使用可见光/近红外光谱法结合化学计量技术检测羊肉糜中鸡肉和脂肪掺假的可能性。制备了180份纯羊肉、鸡肉和脂肪样品以及不同含量的掺假样品:5%、10%、15%和20%(w/w),并通过预处理技术进行了分析。为了消除光谱数据中的加法和乘法效应,采用了导数和散射校正预处理方法。将主成分分析(PCA)作为一种无监督方法应用于数据压缩。此外,应用支持向量机(SVM)和软独立建模类类比(SIMCA)作为监督方法来估计这些模型对九类和三类数据集的判别能力。用SVM模型对9类数据集和3类数据集进行分类,最佳分类结果分别为56.15%和80.70%。本研究表明VIS/NIR与化学计学相结合可用于检测羊肉糜中的欺诈类型。
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引用次数: 2
Study of heat transfer coefficients and temperature distribution in a continuous flow pasteurizer with helical tubes using model fluids in laminar flow 用层流模型流体研究螺旋管连续流巴氏灭菌器的传热系数和温度分布
IF 1.6 4区 农林科学 Pub Date : 2022-06-24 DOI: 10.1515/ijfe-2021-0340
Guilherme Russo, J. A. Gut
Abstract Modeling of continuous pasteurization is useful for predicting time-temperature history of the product and lethality. The use of helical tubes in the heat exchangers and holding tube can simplify modeling in laminar flow due to the narrowing of the residence time distribution. To present this approach, three model fluids (water, 80% glycerol/water and 1% carboxymethylcellulose) were processed in 25 conditions in a pilot scale unit and the overall heat transfer coefficients of the heater, cooler and holding tube were correlated with Reynolds and Prandtl numbers. For heater and cooler, 3–7 parameters were needed for a fair adjustment, while in the holding tube an average value was obtained. Using these correlations, a simple unidimensional model was simulated to predict the time-temperature history and lethality distribution. Simulation examples for processing at 90 °C provided the F-value contribution of each step showing that this model can be useful for process analysis and design.
摘要连续巴氏灭菌的建模有助于预测产品的时间-温度历史和致死率。由于停留时间分布变窄,在热交换器和保温管中使用螺旋管可以简化层流建模。为了提出这种方法,在中试装置中,在25种条件下处理了三种模型流体(水、80%甘油/水和1%羧甲基纤维素),并将加热器、冷却器和保温管的总传热系数与雷诺数和普朗特数相关联。对于加热器和冷却器,需要3-7个参数才能进行公平调整,而在保温管中则获得了平均值。利用这些相关性,模拟了一个简单的一维模型来预测时间-温度历史和致死率分布。90°C下加工的模拟示例提供了每个步骤的F值贡献,表明该模型可用于工艺分析和设计。
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引用次数: 1
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International Journal of Food Engineering
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