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Fabrication of helical micro pins by electrochemical machining 电化学加工螺旋微销的制备
Q3 Engineering Pub Date : 2017-07-17 DOI: 10.1504/IJNM.2017.10005592
L. Hourng, C. Liu, Z. Fen
Helical tools have been proven to enhance the circulation of electrolyte between electrodes in electrochemical micro-drilling. However, the fabrication of micro helical tools is difficult by traditional machining methods. The aim of the present article is to fabricate a helical tungsten micro pin by electrochemical machining. Experimental results show that a helical pin can only be fabricated in the limiting current conditions, and the length of threaded region is proportional to the anode rotating rate. Under the conditions of applied voltage equal to 2.6 V, machining time of two minutes, and the anode rotating rate of 4,000 rpm, an optimal micro helical electrode with thread depth around 17 micro-metre can be obtained. The mechanism for the formation of helical groove is well explained.
螺旋工具已被证明可以增强电化学微钻中电极间电解质的循环。然而,用传统的加工方法制造微螺旋刀具是困难的。本文的目的是利用电化学加工的方法制备螺旋形钨微针。实验结果表明,只有在极限电流条件下才能制成螺旋引脚,且螺纹区长度与阳极转速成正比。在施加电压为2.6 V、加工时间为2分钟、阳极转速为4000转/分的条件下,可得到螺纹深度约为17微米的最佳微螺旋电极。对螺旋槽的形成机理作了较好的解释。
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引用次数: 0
In-plane calibration for AFM AFM平面内校准
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004723
Changsheng Li, Shuming Yang, Chenying Wang, Lin Sun, Zhuangde Jiang
Currently, the x, y scale and the orthogonality of atomic force microscopy (AFM) was independently calibrated by the traditional in-plane calibration methods. There exist theoretical errors because the other two error terms are neglected during the calibration of a certain error term. It has been found that the traditional calibration methods have a rather big theoretical error which is unbearable for nanometrology. In this paper, we propose a calibration method based on multi-measurement of a one-dimensional grating. The x, y scale and the orthogonality can be calibrated simultaneously. This new calibration method was also modified to eliminate the effect of AFM drift by keeping the parallelism between the slow scan direction of AFM and the grating lines of the one-dimensional grating.
目前,原子力显微镜(AFM)的x、y尺度和正交性是通过传统的平面内校准方法独立校准的。由于在校准某一误差项时忽略了其他两个误差项,因此存在理论误差。研究发现,传统的标定方法存在较大的理论误差,纳米计量难以承受。在本文中,我们提出了一种基于一维光栅多次测量的校准方法。x,y标度和正交性可以同时校准。对这种新的校准方法进行了改进,通过保持AFM慢扫描方向与一维光栅光栅线之间的平行度来消除AFM漂移的影响。
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引用次数: 0
Flame synthesis of highly graphitic carbon nano-sphere using cobalt-based catalyst 钴基催化剂火焰合成高石墨碳纳米球
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004721
I. Bu, L. Kao
In this paper a simple and inexpensive method of preparing carbon-based nanomaterials via Co catalyst has been demonstrated. It was shown by using various optical and structural characterisations that well-graphitised carbon nano spheres can be prepared through the proposed process. Through the data extracted from Raman spectra it was found that the as deposited samples showed much lower Id/Ig than previously reported candle-synthesised carbon nanomaterials. Furthermore, under optimised condition, it was found that low resistivity sample can be produced which could be potentially useful in applications as counter electrode in dye sensitise solar cells.
本文介绍了一种简单、廉价的Co催化剂制备碳基纳米材料的方法。通过使用各种光学和结构表征表明,通过所提出的工艺可以制备出石墨化良好的碳纳米球。通过从拉曼光谱中提取的数据发现,沉积样品的Id/Ig比先前报道的蜡烛合成碳纳米材料低得多。此外,在优化条件下,发现可以生产低电阻率样品,这可能在染料敏化太阳能电池的对电极应用中具有潜在的用途。
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引用次数: 0
Fabrication of Janus graphene hybrids with controlled structure and high stability 具有可控结构和高稳定性的Janus石墨烯杂化材料的制备
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004719
Yaling Li, Jiao Wu, Kun Qian, Jingjing Wan, Ying Wang, Baohong Liu, Xiaojing Zhang
Janus hybrids, the anisotropic materials, have displayed very strong potentials in diverse research fields like life science and photology due to their unique properties. In this study, using graphene as an efficient nanoparticles (NPs) carrier, we present the fabrication of two-dimensional (2D) Janus hybrids (gold NPs/graphene) superstructures through a rapid, solventless sputtering method in 10-30 seconds. The micropores in graphene (~0.5 nm) is much smaller than the sputtered gold NPs, which can allow the sheet material to mesh gold NPs in one side to form a Janus structure. The size and morphology of gold NPs can be fine controlled on graphene by adjusting the sputtering current and time, while the resulting graphene hybrids enjoy tunable NPs area density and desirable thermal stability. The performance of hybrids has also been explored through standard electrochemical experiments.
Janus杂化材料是一种各向异性材料,由于其独特的性质,在生命科学和光子学等不同研究领域显示出强大的潜力。在这项研究中,我们使用石墨烯作为有效的纳米颗粒(NP)载体,通过快速、无溶剂的溅射方法在10-30秒内制备了二维(2D)Janus杂化物(金纳米粒子/石墨烯)超结构。石墨烯中的微孔(~0.5nm)比溅射的金纳米颗粒小得多,这可以使片状材料在一侧将金纳米颗粒网格化,形成Janus结构。通过调节溅射电流和时间,可以在石墨烯上精细控制金纳米粒子的尺寸和形态,而所得的石墨烯杂化物具有可调的纳米粒子面积密度和理想的热稳定性。还通过标准电化学实验对杂化物的性能进行了探索。
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引用次数: 1
PEDOT:PSS coated Gold Nanopillar Microelectrodes with Ultralow Impedance for Neural Interfaces PEDOT:PSS包覆的神经界面超低阻抗金纳米柱微电极
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004717
C. Nick, H. Schlaak, C. Thielemann
Improving the neuron-electrode interface has been a focus of biomedical research for the last decade. Low impedance, high charge storage capacities and small geometrical surface area are desired for excellent recording conditions. A common way to improve this interface is to increase the electrochemically active surface area of the electrode using nanoporous or nanostructured electrode materials. In this paper, the fabrication of microelectrodes with very high aspect ratio gold nanopillars coated with the conducting polymer PEDOT:PSS is presented. The electrodes are simulated, manufactured and studied using scanning electron microscopy, atomic force microscopy, impedance spectroscopy, cyclic voltammetry and neural cell culture experiments. We show that PEDOT:PSS coated nanopillar electrodes have improved capacity, reduced impedance and in-vitro recordings reveal high signal-to-noise ratio. Depending on pillar height the impedance is more than 350 times smaller compared to planar gold electrodes at 1 kHz and reveals an electrode capacity more than 1,000 times higher.
在过去的十年中,改善神经元-电极界面一直是生物医学研究的焦点。低阻抗,高电荷存储容量和小的几何表面积是理想的记录条件。改善这种界面的一种常用方法是使用纳米多孔或纳米结构电极材料来增加电极的电化学活性表面积。本文介绍了用导电聚合物PEDOT:PSS包覆高纵横比金纳米柱制备微电极的方法。利用扫描电镜、原子力显微镜、阻抗谱、循环伏安法和神经细胞培养实验对电极进行了模拟、制造和研究。我们发现PEDOT:PSS涂层纳米柱电极具有提高容量,降低阻抗和体外记录显示高信噪比的优点。根据柱高的不同,阻抗比平面金电极在1khz时小350倍以上,而电极容量则高出1000倍以上。
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引用次数: 0
Study on the effect of grain boundary on the mechanical properties of polysilicon by molecular dynamics simulation 分子动力学模拟研究晶界对多晶硅力学性能的影响
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004718
Xiaoguang Guo, Changheng Zhai, R. Kang, D. Guo
Three-dimensional molecular dynamics simulations are conducted to investigate the effect of grain boundary on the mechanical properties of polycrystalline silicon. The load-displacement curves and nanohardness curves are obtained. The coordination analysis method is introduced to visualise the motion of the silicon atoms. The diagram about stress distribution is applied to analyse the mechanical behaviour of polysilicon under stress. The results show that when the moving direction of the indenter is almost the same as the grain boundary, grain boundaries become sliding source, which causes the suddenly unloading phenomenon. As a result, the nanohardness is continuously decreasing in the process of sliding. When the moving direction of the indenter is perpendicular to the grain boundary, the dislocations of the polysilicon are limited at grain boundaries, pile-up phenomenon occurs, which means the hardening mechanism is directly related to the nanoscale grain boundaries.
采用三维分子动力学方法研究了晶界对多晶硅力学性能的影响。得到了载荷-位移曲线和纳米硬度曲线。引入配位分析方法,使硅原子的运动可视化。用应力分布图分析了多晶硅在应力作用下的力学行为。结果表明:当压头移动方向与晶界方向基本一致时,晶界成为滑动源,导致突然卸载现象;因此,在滑动过程中,纳米硬度不断降低。当压头的移动方向垂直于晶界时,多晶硅的位错被限制在晶界处,出现堆积现象,说明硬化机制与纳米级晶界直接相关。
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引用次数: 0
Experiment on self-sharpening fine super-hard abrasive tool 自锐超硬精细磨具试验研究
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004716
Feng Kaiping, Zhou Zhao-zhong, H. Fan, J. Yuan
In order to improve the efficiency of ultra-precision processing, the self-sharpening fine super-hard abrasive tool is presented. Diamond abrasive tool samples adding three different soluble fillers Zn, CaO and SiO2 were prepared separately and soaked in dressing dissolvent to verify dissolving capacity of the soluble fillers in the dressing dissolvent. Grinding experiments of using three novel abrasive tools were carried out compared with conventional super-hard diamond abrasive tool. The experiment result showed that the combination of abrasive adding filler Zn and FeCl3 solution showed good performance, the surface roughness of the K9 glass reduced from Ra = 1.9307 µm to Ra = 0.1011 µm after 4 h grinding. During grinding, soluble fillers exposed on the abrasive surface were dissolved by dressing dissolvent, worn abrasive grains shed, new abrasive grains were exposed to achieve abrasive dressing.
为了提高超精密加工的效率,提出了一种自锐超硬精磨具。分别制备了添加Zn、CaO和SiO2三种不同可溶性填料的金刚石磨具样品,并将其浸泡在修整溶剂中,验证了可溶性填料在修整溶剂中的溶解能力。采用三种新型磨具与常规超硬金刚石磨具进行了磨削实验对比。实验结果表明,磨料添加填料Zn和FeCl3溶液的组合性能良好,研磨4 h后,K9玻璃的表面粗糙度由Ra = 1.9307µm降至Ra = 0.1011µm。在研磨过程中,暴露在磨料表面的可溶性填料被修整溶剂溶解,磨损的磨粒脱落,新的磨粒暴露出来,实现磨料修整。
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引用次数: 0
Ultrasonic assisted electrolytic grinding of titanium alloy Ti-6Al-4V 钛合金Ti-6Al-4V的超声辅助电解磨削
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004720
Yongbo Wu, Sisi Li, M. Nomura, Satoshi Kobayahi, T. Tachibana
Aiming at the development of a novel grinding technology for the high efficient machining of difficult to machine materials such as titanium alloy Ti-6Al-4V, an ultrasonic assisted electrolytic grinding (UAEG) method was proposed. Firstly, an experimental apparatus was constructed by installing an electrolytic mechanism on an existing 3D CNC machine tool attached with an ultrasonic spindle. Then, after the performance test has been carried out for the constructed apparatus, UAEG experiments of Ti-6Al-4V specimen were conducted on the apparatus to investigate the effects of the ultrasonic vibration of grinding wheel and the electrolytic phenomenon on the grinding force and the work surface quality. The experimental results indicate that the ultrasonic assisted electrolytic grinding is greatly beneficial to the decrease in grinding force and the improvement in the work surface quality compared to conventional grinding.
为了开发一种用于钛合金Ti-6Al-4V等难加工材料高效加工的新型磨削技术,提出了一种超声辅助电解磨削(UAEG)方法。首先,通过在现有的带有超声波主轴的三维数控机床上安装电解机构来构建实验装置。然后,在对所构建的装置进行性能测试后,在该装置上对Ti-6Al-4V试样进行了UAEG实验,以研究砂轮的超声振动和电解现象对磨削力和工作表面质量的影响。实验结果表明,与传统磨削相比,超声辅助电解磨削有利于降低磨削力,提高工件表面质量。
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引用次数: 3
Precision cutting of single crystal silicon using CBN tool with large top corner radius 大顶角半径CBN刀具对单晶硅的精密切削
Q3 Engineering Pub Date : 2017-04-27 DOI: 10.1504/IJNM.2017.10004722
Yuya Kobaru, E. Kondo, R. Iwamoto
A lot of studies on the ultra-precision cutting of single crystal silicon have been reported and they used the diamond cutting tools. However, the diamond cutting tools are very expensive. Therefore, if the single crystal diamond tools were replaced with sintered CBN tools, the cost of machining could be fairly reduced. However, it is easily expected that the CBN tools wear out faster than the diamond tools. Therefore, it is very important to find out the optimum cutting conditions in order to reduce tool wear. In this study, precision cutting of single crystal silicon was machined with using CBN cutting tools having chamfer at cutting edge and large nose radius, and the effect of feed rate, cutting speed, depth of cut and nose radius on the tool wear were studied. As a result, the local minimum of width of flank wear land appeared at the feed rate of 30~50 µm/rev.
对单晶硅的超精密切削进行了大量的研究,并使用了金刚石刀具。然而,金刚石切割工具非常昂贵。因此,如果用烧结CBN刀具代替单晶金刚石刀具,则可以大大降低加工成本。然而,很容易预计CBN工具比金刚石工具磨损得更快。因此,找出最佳切削条件以减少刀具磨损是非常重要的。本研究采用CBN切削刀具对单晶硅进行了精密切削,研究了进给量、切削速度、切削深度和刀尖半径对刀具磨损的影响。结果表明,在30~50µm/rev的进给速度下,出现了侧面磨损区宽度的局部最小值。
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引用次数: 2
Dislocation dynamic simulation of dislocation pattern evolution in the early fatigue stages of aluminium single crystal 铝单晶疲劳早期位错模式演化的位错动态模拟
Q3 Engineering Pub Date : 2017-03-02 DOI: 10.1504/IJNM.2017.10003132
Jinxuan Bai, Q. Bai, Xin He, Qingchun Zhang
The two-dimensional discrete dislocation dynamics simulations under fully periodic boundary conditions has been employed to study the dislocation pattern evolution in the early stages of fatigue in aluminium single crystal. Long-range force among of dislocations is solved by line elasticity model, and short-range force is obtained by constitutive equations of dislocation nucleation, slip, pileup and annihilate. Dislocation movement mechanisms of single-slip-oriented and multi-slip systems are simulated and the evolution process of fatigue pattern is revealed. The result shows that dislocation quantity and microstructure strongly depend on external load and internal configuration. The dislocation pattern of single-slip-oriented generate matrix wall, and positive dislocations are vertical alignment and negative dislocations are at the angle of 45° with slip oriented in the initial stage. For multi-slip system, maze structure of dislocations is produced during dislocation multiplication, which eventually transforms into persistent slip band. The result is consistent with the existing experiment.
采用全周期边界条件下二维离散位错动力学模拟方法,研究了铝单晶疲劳初期位错模式的演变。用线弹性模型求解位错间的远程力,用位错成核、滑移、堆积和湮灭本构方程求解位错间的短程力。模拟了单滑移取向和多滑移取向体系的位错运动机制,揭示了疲劳模式的演化过程。结果表明,位错的数量和微观结构与外部载荷和内部结构密切相关。单滑移取向的位错模式形成基体壁面,初始阶段正位错为垂直取向,负位错为与滑移取向成45°夹角。对于多滑移系统,位错在增殖过程中产生迷宫结构,最终转化为持续滑移带。所得结果与已有实验结果一致。
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引用次数: 1
期刊
International Journal of Nanomanufacturing
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