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The luminescent properties of GdAlO3:Tb3+ phosphors based on molten salts addition 熔盐加成GdAlO3:Tb3+荧光粉的发光性能
Q3 Engineering Pub Date : 2019-01-08 DOI: 10.1504/IJNM.2019.10018324
Jinkai Li, Wenzhi Wang, Z. Liu
The (Gd1−xTbx)AlO3 (x = 0-0.12) were obtained through ammonium bicarbonate co-precipitation technology. The pure-phase (Gd1−xTbx)AlO3 with good dispersion could be obtained at relatively lower temperature of 1,000°C. Under optimum UV excitation into 275 nm, the photoluminescence (PL) spectra display a series of 5D4−7FJ transitions of Tb3+ in (Gd1−xTbx)AlO3 system with the strongest green emission at ~546 nm. The overlapping between 8S7/2−6IJ intra f-f transition of Gd3+ and 4f8-4f75d1 transition of Tb3+ at 275 nm suggesting the Gd3+ → Tb3+ energy transfer, and the quenching contents of Tb3+ was found to be ~10 at%. The luminescent property of GdAlO3:Tb3+ phosphor could be further improved with molten salt incorporation. The optimal composition of molten salts was determined to be the mixture of NaCl/Na2SO4 (5 wt% NaCl), and the mass ratio of mixture molten salts to precursor was 2:1. The relationship between the luminescent property and molten salts composition were studied in detail.
采用碳酸氢铵共沉淀技术制备了(Gd1−xTbx)AlO3(x=0-0.12)。在1000°C的相对较低温度下,可以获得具有良好分散性的纯相(Gd1−xTbx)AlO3。在275nm的最佳紫外激发下,(Gd1−xTbx)AlO3体系中Tb3+的光致发光(PL)光谱显示出一系列5D4−7FJ跃迁,在~546nm处具有最强的绿光发射。在275nm处Gd3+的8S7/2−6IJ f-f内跃迁和Tb3+的4f8-4f75d1跃迁之间的重叠表明Gd3+→ Tb3+能量转移,Tb3+的猝灭含量为~10at%。掺入熔盐可以进一步提高GdAlO3:Tb3+荧光粉的发光性能。熔盐的最佳组成确定为NaCl/Na2SO4(5wt%NaCl)的混合物,并且混合物熔盐与前体的质量比为2:1。详细研究了熔盐组成与发光性能的关系。
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引用次数: 2
Sulphur-doped banana peel-derived activated carbon as electrode materials for supercapacitors 硫掺杂香蕉皮活性炭作为超级电容器电极材料
Q3 Engineering Pub Date : 2019-01-08 DOI: 10.1504/IJNM.2019.10018335
H. Chen, Zhuangzhi Zhao, Peirong Qi, Gang Wang, Lei Shi, Feng Yu
Agricultural waste banana peel (BP) as a sustainable biomass resource is used to produce porous carbon (PC) and activated carbon (AC) materials. Sulphur-doped banana peel-derived AC (S-BP-AC) was successfully prepared for supercapacitors. The results show that the S-BP-AC presents a high Brunauer-Emmett-Teller surface area of 2,224.9 m2/g, a large pore volume of 0.77 cm3/g, and a suitable pore-size distribution of approximately 0.8 nm. It is easy to bring S-BP-AC into contact with an electrolyte. The S-BP-AC electrode had great specific capacitance of 162.5 F/g at a current density of 0.5 A/g in a 6 M KOH aqueous electrolyte. The results indicate that the S-BP-AC can be applied to use in high performance supercapacitors.
农业废弃香蕉皮(BP)作为一种可持续的生物质资源,用于生产多孔炭(PC)和活性炭(AC)材料。成功制备了含硫香蕉皮衍生AC (S-BP-AC)超级电容器。结果表明,S-BP-AC具有22224.9 m2/g的高brunauer - emmet - teller表面积,0.77 cm3/g的大孔体积,孔径分布约为0.8 nm。很容易使S-BP-AC与电解质接触。在6 M KOH水溶液中,当电流密度为0.5 a /g时,S-BP-AC电极的比电容达到162.5 F/g。结果表明,S-BP-AC可用于高性能超级电容器。
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引用次数: 7
Scalable synthesis of Sn nanoparticles encapsulated in hierarchical porous carbon networks for high-rate reversible lithium storage 用于高速率可逆锂存储的多层多孔碳网络中Sn纳米粒子的可扩展合成
Q3 Engineering Pub Date : 2019-01-08 DOI: 10.1504/IJNM.2019.10018329
Qingbin Zhu, Jinghao Liu, Y. Zhong, Guicun Li
Sn nanoparticles encapsulated in hierarchical porous carbon networks ([email protected]) have been synthesised by the carbothermal reduction reaction of sodium stannate-crosslinked sodium polyacrylate xerogel. The synthetic strategy is simple and effective for the scalable production of [email protected] The [email protected] show homogeneous distribution of Sn nanoparticles within hierarchical porous conductive carbon matrix. The obtained [email protected] exhibit high reversible discharge capacity (1,652.1 mAh g−1 at 0.1 A g−1), superior rate performance (499.7 mAh g−1 at 2 A g−1), and excellent cycling stability (553.0 mA h g−1 at 1.5 A g−1 after 150 cycles). The superior lithium storage performances of the [email protected] are due to uniform distribution of Sn nanoparticles within hierarchical porous conductive carbon network, which could not only provide a conductive matrix, but also buffer huge volume change caused by lithiation and thus guarantee integrity of the [email protected] structure.
通过锡酸钠交联聚丙烯酸钠干凝胶的碳热还原反应,合成了包封在分级多孔碳网络中的Sn纳米颗粒(〔email protected〕)。该合成策略简单有效,可用于[电子邮件保护]的可扩展生产。[电子邮件保护]Sn纳米颗粒在分级多孔导电碳基体中均匀分布。所获得的[电子邮件保护]表现出高的可逆放电容量(在0.1 A g−1下为1652.1 mAh g−1)、优异的倍率性能(在2 A g−2下为499.7 mAh g–1)和优异的循环稳定性(150次循环后在1.5 A g−1.5下为553.0 mA h g−2)。〔email protected〕优异的储锂性能是由于Sn纳米颗粒在分级多孔导电碳网络中的均匀分布,这不仅可以提供导电基体,还可以缓冲锂化引起的巨大体积变化,从而保证〔email protective〕结构的完整性。
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引用次数: 0
Preparation and characterization of cMWCNTs-mSA/mCS bipolar membrane for electrochemical synthesis 电化学合成用cMWCNTs mSA/mCS双极膜的制备与表征
Q3 Engineering Pub Date : 2019-01-08 DOI: 10.1504/IJNM.2019.10014399
Suyu Shi, Linan Wang, K. Zhao, Chuntai Liu, G. Zheng
In this study, a bipolar membrane (BPM) of sodium alginate (SA) and chitosan (CS) was prepared based on carboxyl multi-walled carbon nanotubes (cMWCNTs). To improve the compatibility of anion-exchange layer and cation-exchange layer, polyvinyl alcohol (PVA) was blended with both the SA and CS, respectively. A casting method was employed to prepare the modified BPM named as cMWCNTs-mSA/mCS BPM for simplicity. The morphology, thermal and structure stability, electrochemical properties and ion penetrability of the BPM were characterised. Scanning electron microscopy (SEM) images illustrate a structure consisting of two distinct layers that are closely combined with each other. Thermal gravimetric (TG) results indicate that the thermal stability of cMWCNTs-mSA/mCS BPM is significantly improved. Swelling behaviour implies a proper hydrophilic performance and excellent structure stability in alkali solution. Compared with SA/CS BPM, the working voltage of cMWCNTs-mSA/mCS BPM is decreased sharply. Furthermore, the cMWCNTs-mSA/mCS BPM exhibited higher ion penetrability which is beneficial for electrochemical synthesis.
在本研究中,以羧基多壁碳纳米管(cMWCNTs)为基础,制备了海藻酸钠(SA)和壳聚糖(CS)的双极膜(BPM)。为了提高阴离子交换层和阳离子交换层的相容性,将聚乙烯醇(PVA)分别与SA和CS共混。为了简便起见,采用浇铸法制备了改性BPM,命名为cMWCNTs mSA/mCS BPM。对BPM的形态、热稳定性和结构稳定性、电化学性能和离子渗透性进行了表征。扫描电子显微镜(SEM)图像显示了由两个彼此紧密结合的不同层组成的结构。热重分析(TG)结果表明,cMWCNTs mSA/mCS BPM的热稳定性显著提高。溶胀行为意味着在碱溶液中具有适当的亲水性能和优异的结构稳定性。与SA/CS BPM相比,cMWCNTs mSA/mCS BPM的工作电压明显降低。此外,cMWCNTs mSA/mCS BPM表现出更高的离子穿透性,这有利于电化学合成。
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引用次数: 0
Simulation of microstructure evolution coupled with fabrication parameters for two-phase ceramic tool materials 两相陶瓷刀具材料微观结构演变与加工参数耦合的模拟
Q3 Engineering Pub Date : 2018-10-04 DOI: 10.1504/IJNM.2018.10016340
B. Fang, Chonghai Xu, G. Xiao
A computer simulation coupled with fabrication parameters for the sintering process of two-phase ceramic tool materials has been developed using a two-dimensional hexagon lattice model mapped from ...
利用二维六边形晶格模型,结合制备参数,对两相陶瓷工具材料的烧结过程进行了计算机模拟。。。
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引用次数: 0
Effects of cutting parameters on temperature and temperature prediction in micro-milling of Inconel 718 切削参数对Inconel 718微铣削温度及温度预测的影响
Q3 Engineering Pub Date : 2018-10-04 DOI: 10.1504/IJNM.2018.10016347
Xiaohong Lu, Hua Wang, Zhenyuan Jia, Yixuan Feng, S. Liang
Inconel 718 is a kind of typical difficult-to-machine material. Micro-milling technology is an effective method for fabricating micro parts of Inconel 718. The change rules of micro-milling temperature differ from those of the traditional processing, which will affect the surface integrity of the workpiece and the tool life of the micro-milling cutter in different ways. To ascertain the effects of cutting parameters on cutting temperature during micro-milling Inconel 718 and achieve the prediction of cutting temperature, some micro-milling experiments are conducted based on the response surface method. The independent and interaction effects of the spindle speed, feed per tooth and axial cutting depth on cutting temperature are investigated. A micro-milling temperature prediction model is established based on the experiment results. The maximum prediction error is 5.3% and the average prediction error is 2.6%. Finally, the accuracy of the proposed model is validated through experiments of micro-milling Inconel 718.
铬镍铁合金718是一种典型的难加工材料。微铣削技术是制备铬镍铁合金718微零件的有效方法。微铣削温度的变化规律与传统加工不同,会以不同的方式影响工件的表面完整性和微铣刀的刀具寿命。为了确定微铣削Inconel 718过程中切削参数对切削温度的影响,实现切削温度的预测,基于响应面法进行了一些微铣削实验。研究了主轴转速、齿进给量和轴向切削深度对切削温度的独立影响和相互作用。根据实验结果建立了微铣削温度预测模型。最大预测误差为5.3%,平均预测误差为2.6%。最后,通过微铣削Inconel 718的实验验证了该模型的准确性。
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引用次数: 2
Surface microstructure parameter optimisation for enhancing light extraction efficiency of LED 提高LED光提取效率的表面微结构参数优化
Q3 Engineering Pub Date : 2018-10-04 DOI: 10.1504/IJNM.2018.10016344
Dong Yuan, Lin Xianyu, L. Yanguo, Guofu Zhou, Li Nan
Surface structure modification is an effective way to enhance light extraction of LED, which is limited by total internal reflection on the interfacial surface. The periodic surface structure manufactured by micromachining was proved to be a feasible way to enhance the light extraction efficiency (LEE) of LEDs. In order to obtain the highest LEE, need to optimise the structural parameters. In this paper, a simplified ray tracing optical model was built to find out a high performance microstructure parameters by simulation. Then, a mathematical model was built to further optimise the optical simulation results, obtained the optimal microstructure parameters for LEE. The performance of optimal microstructure was also studied by optical simulation.
表面结构改性是提高LED光提取的有效途径,而界面全内反射限制了LED光提取。通过微机械加工制造的周期性表面结构被证明是提高LED光提取效率的可行方法。为了获得最高的LEE,需要优化结构参数。本文建立了一个简化的光线跟踪光学模型,通过仿真找出了一个高性能的微观结构参数。然后,建立了数学模型,进一步优化了光学模拟结果,得到了LEE的最佳微观结构参数。通过光学模拟研究了最佳微观结构的性能。
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引用次数: 0
Effect of single grit impacts on initiation and propagation of cracks in ultrasonic assisted grinding of ceramics by using SPH method SPH法陶瓷超声辅助磨削中单颗粒冲击对裂纹萌生和扩展的影响
Q3 Engineering Pub Date : 2018-10-04 DOI: 10.1504/IJNM.2018.10016346
Zhiqiang Liang, Meng Tian, Q. Wang, Xibin Wang, Tianfeng Zhou, L. Jiao, Yongbo Wu
In order to investigate the material removal mechanism in vertical ultrasonic assisted grinding (VUAG) of ceramics, single-grit impact simulation is performed by using smoothed particle hydrodynamics (SPH) method. The initiation and propagation of cracks in grinding of Al2O3 ceramics are analysed. In this simulation, the grit is modelled as a rectangular pyramid diamond indenter and the process of grit impacting on workpiece under different impact speeds is simulated. The critical depth of initiation and propagation of lateral crack is observed. The results show that within a certain range of impact speed, the critical depth of lateral crack decreases with the increasing of impact speed. This means that the brittle fractures are more prone to occur in VUAG. Considering that the material micro-fracture is the main mode in ceramics material grinding under ordinary processing conditions, the material removal rate in VUAG can be improved. Moreover, by observing the surface topography, it can be found that the surface roughness becomes smaller when the impact speed increases.
为了研究陶瓷垂直超声辅助磨削(VUAG)中的材料去除机理,采用光滑粒子流体力学(SPH)方法对单颗粒冲击进行了模拟。分析了Al2O3陶瓷磨削过程中裂纹的萌生和扩展。在该模拟中,将磨料建模为矩形棱锥金刚石压头,并模拟了不同冲击速度下磨料冲击工件的过程。观察到横向裂纹萌生和扩展的临界深度。结果表明,在一定的冲击速度范围内,横向裂纹的临界深度随着冲击速度的增加而减小。这意味着VUAG更容易发生脆性断裂。考虑到在普通工艺条件下,材料微断裂是陶瓷材料磨削的主要模式,VUAG中的材料去除率可以提高。此外,通过观察表面形貌,可以发现当冲击速度增加时,表面粗糙度变小。
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引用次数: 2
Machining position-attitude optimisation in ion beam figuring of high-precision off-axis aspheric surfaces 高精度离轴非球面离子束加工位置-姿态优化
Q3 Engineering Pub Date : 2018-10-04 DOI: 10.1504/IJNM.2018.10016343
Mingjin Xu, Yi-fan Dai, Xuhui Xie, Lin Zhou
High-precision off-axis aspheric components are widely applied in various high-performance optical systems. However, the complicated manufacturing features of off-axis aspheric make it difficult to achieve high-precision surface for traditional optical manufacturing methods. Ion beam figuring (IBF) is a non-contact and highly deterministic method for the final precision optical figuring. In this paper, two different machining position-attitude models are discussed, which have great influence on the machining difficulty and figuring accuracy of IBF. The child mirror coordinate position-attitude model (CCPAM), which is based on the robustness of IBF removal function to small disturbance of target distance and incidence angle, can effectively decrease the sag height and incidence angle, thereby reduce the beam errors and machining difficulty. A linear three-axis IBF system is successfully applied for the figuring of a large-aperture parabolic off-axis aspheric mirror based on the CCPAM and its best-fit sphere. With two iterations of 113 min, surface error is down to 7.658 nm RMS (effective aperture 310 mm × 310 mm). The figuring results indicate IBF can realise the rapid fabrication of high-precision off-axis aspheric based on the machining position-attitude optimisation.
高精度离轴非球面元件广泛应用于各种高性能光学系统中。然而,离轴非球面的复杂制造特性使得传统的光学制造方法难以实现高精度的表面。离子束成像(IBF)是一种非接触、高确定性的最终精密光学成像方法。本文讨论了两种不同的加工位置姿态模型,这两种模型对IBF的加工难度和加工精度有很大影响。基于IBF去除函数对目标距离和入射角小扰动的鲁棒性,建立了儿童反射镜坐标位置姿态模型(CCPAM),可以有效地降低凹陷高度和入射角,从而降低光束误差和加工难度。基于CCPAM及其最佳拟合球面,成功地将线性三轴IBF系统应用于大口径抛物面离轴非球面镜的成像。在113分钟的两次迭代中,表面误差降至7.658 nm RMS(有效孔径310 mm×310 mm)。计算结果表明,IBF可以实现基于加工位置姿态优化的高精度离轴非球面的快速制造。
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引用次数: 1
Design and simulation of ultrasonic horns in ultrasonic vibration machining 超声振动加工中超声喇叭的设计与仿真
Q3 Engineering Pub Date : 2018-10-04 DOI: 10.1504/IJNM.2018.10012496
Zhong Meipeng, J. Yuan, W. Yao, Chen Zhixiang, Zhongdian Chen
Ultrasonic horns are also called ultrasonic shift levers. They magnify ultrasonic vibration amplitude to meet the requirements of ultrasonic machining. To improve the efficiency of ultrasonic grinding, reduce the connecting parts of the lever, and reduce internal stress, the amplitude of the ultrasonic vibration process is defined in this study. The amplitude of the stress and modal simulation was determined using ANSYS was used as the simulation system for ultrasonic horn deformation. The stress and displacement at the end of the ultrasonic horns are the highest; however, the displacement at the node position of the flange is almost zero. The maximum displacement is 14.893 µm, and the minimum displacement is close to zero. Ultrasonic horns in ultrasonic vibration machining meet the requirements of use. It is proved in theory that the performance of the ultrasonic system is reliable and the design is reasonable.
超声波喇叭也被称为超声波换挡杆。它们放大了超声波的振动幅度,以满足超声波加工的要求。为了提高超声磨削效率,减少杠杆连接部件,减小内应力,本研究定义了超声振动过程的幅值。利用ANSYS确定应力幅值并进行模态仿真,作为超声变幅杆变形的仿真系统。超声喇叭末端的应力和位移最大;然而,在法兰节点位置的位移几乎为零。最大位移为14.893µm,最小位移接近于零。超声波喇叭在超声振动加工中满足使用要求。从理论上证明了超声系统的性能可靠,设计合理。
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引用次数: 0
期刊
International Journal of Nanomanufacturing
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