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Growth Kinetics and Development of the Solid–Liquid Interface in Low-Carbon and High-Alloy Steel Castings Enabled by Confocal Microscopy 通过共聚焦显微镜观察低碳钢和高合金钢铸件固液界面的生长动力学和发展过程
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-11 DOI: 10.1007/s40962-024-01402-9
Katelyn Kiser, Viraj A. Athavale, Laura Bartlett, Mario Buchely, Ronald O’Malley

High-Temperature Laser Scanning Confocal Microscopy (HT-LSCM) is an in situ technique that can be used for direct observation of the microstructure during melting, solidification, and solid-state cooling. Therefore, this tool is a powerful method that can be used to understand how cooling conditions affect the solidification structure and degree of alloy segregation in steel castings. In the current study, specimen shape and size were optimized for this technique using an ultra-low-carbon steel. HT-LSCM was then utilized to observe the melting and solidification phenomena as a function of cooling rate for the ultra-low-carbon steel as well as a high-alloy austenitic manganese and aluminum steel. The growth kinetics and evolution of the solid–liquid interface during solidification were derived from time-lapse videos. The resulting solidification microstructure was determined utilizing scanning electron microscopy.

高温激光扫描共聚焦显微镜 (HT-LSCM) 是一种现场技术,可用于直接观察熔化、凝固和固态冷却过程中的微观结构。因此,该工具是一种强大的方法,可用于了解冷却条件如何影响钢铸件的凝固结构和合金偏析程度。在当前的研究中,使用超低碳钢优化了该技术的试样形状和尺寸。然后利用 HT-LSCM 观察超低碳钢以及高合金奥氏体锰铝钢的熔化和凝固现象与冷却速度的函数关系。通过延时视频得出了凝固过程中固液界面的生长动力学和演变过程。利用扫描电子显微镜确定了由此产生的凝固微观结构。
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引用次数: 0
Study on the Precipitation Strengthening Mechanism of Mg–10Zn–5Al–0.2Sc Alloy Mg-10Zn-5Al-0.2Sc 合金的沉淀强化机理研究
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-11 DOI: 10.1007/s40962-024-01406-5
A. X. Jiang, Z. Y. You, S. S. Jin, Y. G. Zhang, M. J. Zhang, K. Y. Wang

The Mg–10Zn–5Al–0.2Sc (wt%) alloy was fabricated through gravity casting and subsequent heat treatment. The microstructure and precipitates of the alloy samples were meticulously examined using OM, SEM/EDS, and TEM/HRTEM. The results indicate that the microstructure of the alloy comprises a MgZnAl phase along with a minor presence of Al2Sc. The incorporation of Sc serves to refine the grain size of the alloy while introducing vacancies and dislocations within the microstructure. After heat treatment, an abundance of rod-shaped nanoscale MgZnAl and MgZn phases precipitate within the grains, with these phases exhibiting a perpendicular relationship in terms of precipitation orientation, leading to the formation of numerous dislocations and planar defects. The nanoscale MgZnAl and MgZn phases, characterized by a hexagonally close-packed structure, contribute significantly (68.59%) to the enhancement of the yield strength of the heat-treated alloy. These phases demonstrate a degree of coherence with the α-Mg matrix, impeding dislocation motion, and effectively absorbing and storing dislocations, thereby mitigating strain and distortion concentrations within the phases during tensile deformation. This mechanism reinforces the strengthening effect of coherent interfaces, ultimately improving the strength and ductility of the alloy. After heat treatment, the alloy attains a tensile strength of 221 MPa, a yield strength of 208.45 MPa, and an elongation of 0.99%, representing enhancements of 33.13%, 38.88%, and 0.49%, respectively, compared to the matrix alloy.

Mg-10Zn-5Al-0.2Sc (wt%) 合金是通过重力铸造和随后的热处理制成的。使用光学显微镜、扫描电子显微镜/电子显微镜和电子显微镜/高温热电子显微镜对合金样品的微观结构和析出物进行了细致的检测。结果表明,合金的微观结构由 MgZnAl 相和少量 Al2Sc 组成。Sc 的加入细化了合金的晶粒大小,同时在微观结构中引入了空位和位错。热处理后,大量棒状纳米级 MgZnAl 和 MgZn 相在晶粒中析出,这些相在析出方向上呈现垂直关系,从而形成大量位错和平面缺陷。纳米级 MgZnAl 和 MgZn 相具有六边形紧密堆积结构,对提高热处理合金的屈服强度有显著作用(68.59%)。这些相与α-镁基体具有一定程度的相干性,阻碍了位错运动,并有效地吸收和储存了位错,从而减轻了拉伸变形过程中各相内部的应变和畸变集中。这种机制加强了相干界面的强化效果,最终提高了合金的强度和延展性。热处理后,合金的抗拉强度达到 221 兆帕,屈服强度达到 208.45 兆帕,伸长率达到 0.99%,与基体合金相比,分别提高了 33.13%、38.88% 和 0.49%。
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引用次数: 0
Effect and Mechanism of Refinement on Macro-segregation in Squeeze Casting Low-Tin Bearing Alloys 精炼对挤压铸造低锡轴承合金宏观偏析的影响和机制
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-10 DOI: 10.1007/s40962-024-01403-8
Ming Xu, Yanguo Yin, Jilin Miao, Xiaoliang Fang, Shan Huang, Guotao Zhang, Congmin Li

During the investigation of the direct squeeze casting process for the production of Al-5Sn-Cu low-tin bearing alloy parts, particularly floating bushings, this study has explored the effect and mechanism of grain refiner on reducing macro-segregation within low-tin bearing alloys. This has provided an effective solution for Sn segregation in the alloy and broadened its application prospects in the bearing field. The findings revealed significant microstructural differences both in the longitudinal and transverse sections, and abnormal macro-segregation of Sn at hot spots without grain refiner. Conversely, grain refinement improved the microstructure, resulting in a uniform distribution of Sn, effectively mitigating the macro-segregation phenomena, especially at hot spot positions. The grain refiner promoted the growth of equiaxed crystals by generating numerous heterogeneous nucleation sites. These played a crucial role during the later stages of solidification by uniformly isolating the Sn-rich liquid phase and preventing the formation of feeding channels for this phase as solidification completed. These actions ultimately prevented the macro-segregation of Sn. The approach not only enhances the quality and reliability of these castings but also provides critical guidance for optimizing the manufacturing of aluminum-based bearing alloys.

在研究直接挤压铸造工艺生产 Al-5Sn-Cu 低锡轴承合金零件(尤其是浮动衬套)的过程中,本研究探讨了晶粒细化剂对减少低锡轴承合金内部宏观偏析的影响和机制。这为解决合金中的锡偏析问题提供了有效方法,并拓宽了其在轴承领域的应用前景。研究结果表明,在没有晶粒细化剂的情况下,纵向和横向截面上的微观结构差异明显,热点处的锡宏观偏析异常。相反,晶粒细化改善了微观结构,使锡分布均匀,有效缓解了宏观偏析现象,尤其是在热点位置。晶粒细化剂通过产生大量异质成核点促进了等轴晶粒的生长。这些点在凝固的后期阶段发挥了关键作用,它们均匀地隔离了富含锡的液相,并在凝固完成后阻止了该相的进料通道的形成。这些作用最终防止了锡的宏观偏析。这种方法不仅提高了铸件的质量和可靠性,还为优化铝基轴承合金的制造提供了重要指导。
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引用次数: 0
A Novel Reclamation Method of Chemical–Mechanical Grinding for Inorganic Binder Waste Sand in Aluminum Alloy Casting Process 铝合金铸造工艺中无机粘结剂废砂的新型化学机械研磨回收方法
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-10 DOI: 10.1007/s40962-024-01395-5
Shengli Hu, Xiaolong Gong, Wucan Wu, Guanling Cai, Wenqiang Ren, Zitian Fan

The current approach to reclaiming inorganic binder waste sand discharged during the aluminum alloy casting process typically involves mechanical grinding combined with calcination treatment (650–700 °C). However, this method encounters challenges such as the accumulation of residual binder on the surface of the reclaimed sand and a subsequent decline in its refractoriness. This study proposes a novel method to reclaim inorganic binder waste sand, by integrating chemical infiltration with mechanical grinding. The effects of different types and concentrations of chemical reagents on the electrical conductivity and Na2O content of the reclaimed sand were investigated. The microstructure and chemical composition of both waste and reclaimed sand were analyzed, and revealing the chemical-mechanical grinding reclamation mechanism. Compared to H2C2O4 and MgCl2 solution, the CaCl2 solution demonstrates superior efficacy in enhancing the quality of reclaimed sand. The electrical conductivity and Na2O content of the reclaimed sand exhibit a rapid decline followed by stabilization with increasing concentration of CaCl2 solution. When the dosage of CaCl2 solution is 5 wt% of the waste sand weight, and the concentration is 10 wt%, the electrical conductivity and Na2O content of the obtained reclaimed sand are 776.7 μS/cm and 0.039%, respectively, meeting the utilization requirements for reclaimed sand. Microscopic analysis reveals that the CaCl2 solution reacts with the residual binder on the surface of the waste sand, disrupting the structure and morphology of the residual binder. After drying, the reaction product crystallizes in the form of blocky inorganic salts, facilitating their removal during mechanical grinding. Finally, the clean reclaimed sand is attained, exhibiting a 24 h tensile strength exceeding 90% of that of new sand.

目前回收铝合金铸造过程中排出的无机粘结剂废砂的方法通常包括机械研磨和煅烧处理(650-700 °C)。然而,这种方法也遇到了一些挑战,如残留粘结剂在再生砂表面的积累以及随后耐火度的下降。本研究提出了一种新型的无机粘结剂废砂再生方法,将化学渗透与机械研磨相结合。研究了不同类型和浓度的化学试剂对再生砂电导率和 Na2O 含量的影响。分析了废砂和再生砂的微观结构和化学成分,揭示了化学-机械研磨再生机理。与 H2C2O4 和 MgCl2 溶液相比,CaCl2 溶液在提高再生砂质量方面表现出更优越的功效。随着 CaCl2 溶液浓度的增加,再生砂的电导率和 Na2O 含量迅速下降,随后趋于稳定。当 CaCl2 溶液的用量为废砂重量的 5 wt%,浓度为 10 wt%时,得到的再生砂的电导率和 Na2O 含量分别为 776.7 μS/cm 和 0.039%,满足再生砂的利用要求。显微分析表明,CaCl2 溶液与废砂表面的残留粘结剂发生反应,破坏了残留粘结剂的结构和形态。干燥后,反应产物以块状无机盐的形式结晶,便于在机械研磨过程中去除。最后,就得到了清洁的再生砂,其 24 小时抗拉强度超过新砂的 90%。
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引用次数: 0
From the Editor 编辑的话
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-10 DOI: 10.1007/s40962-024-01399-1
Thomas Prucha
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引用次数: 0
Nondestructive Material Evaluation of Gray Cast Iron Using DC Bias Alternating Magnetic Field 利用直流偏置交变磁场对灰铸铁进行无损材料评估
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-09 DOI: 10.1007/s40962-024-01401-w
S. Mio, K. Kawada, N. Kanemaru, Y. Gotoh

The gray cast iron is used in many machine parts such as pulleys, since it has excellent vibration damping, wear resistance, and castability. Material evaluation of this cast iron is important for quality assurance of machine products. This research proposes a method to identify defective products mixed with good products. Currently, test methods such as Brinell hardness and tensile strength tests are commonly used to check the quality of cast irons. However, these methods are not suitable for inspecting all products in terms of time required. Therefore, it is important to establish an electromagnetic nondestructive test that enables non-contact and fast measurement. It has been found that the use of AC magnetic fields in nondestructive testing methods can be used to measure defective gray cast iron. In this paper, we propose an electromagnetic nondestructive testing method that uses a DC-biased sinusoidal magnetic field, which enables measurements with higher sensitivity than those obtained with AC magnetic fields. The effectiveness of the proposed method is demonstrated through electromagnetic field finite element method (FEM) analysis using the play model method and corroborated by verification experiments.

灰口铸铁具有优异的减震性、耐磨性和可铸性,因此被广泛应用于滑轮等机械零件中。对这种铸铁进行材料评估对于保证机械产品的质量非常重要。本研究提出了一种识别混入良品的次品的方法。目前,通常使用布氏硬度和拉伸强度测试等测试方法来检查铸铁的质量。然而,从所需时间来看,这些方法并不适合检测所有产品。因此,建立一种能够进行非接触式快速测量的电磁无损检测方法就显得尤为重要。研究发现,在无损检测方法中使用交流磁场可用于测量有缺陷的灰铸铁。在本文中,我们提出了一种使用直流偏压正弦磁场的电磁无损检测方法,这种方法比使用交流磁场的测量灵敏度更高。通过使用 play 模型法进行电磁场有限元法(FEM)分析,证明了所提方法的有效性,并通过验证实验予以证实。
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引用次数: 0
Investigation of the Quality of Flywheel SG Iron Sand Casting Using the Optimized Riser Dimensions: Numerical Simulation and Experimental Validation 使用优化的立管尺寸调查飞轮 SG 铁砂铸造的质量:数值模拟与实验验证
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-09 DOI: 10.1007/s40962-024-01407-4
Rajat Upadhyaya, Kamlesh Kumar Singh, Sujeet Kumar Gautam, Rajeev Kumar, Himanshu Khandelwal, J. D. Sharma

The primary objective of this investigation is to employ computational simulation analysis of casting to determine effective riser dimensions and eliminate shrinkage porosity in actual spheroidal graphite (SG) iron flywheel casting. A simulation software, Pro-CAST, is used to simulate the solidification process under varying process conditions (i.e., without a riser and with an effective dimension riser). The simulation results are then confirmed by a subsequent experiment using green sand casting. Additionally, a thorough investigation is conducted to determine the correlation between the shrinkage behavior and its morphological characteristics of the cast components. The simulation results infer that the un-optimized dimension of the riser causes the shrinkage porosity and void formation largely in the thicker section, due to the lower eutectic solidification time. However, when the dimension of the riser is optimized, this effect is mitigated simply by ensuring the eutectic solidification time is higher than the eutectic solidification of the thicker section; thus, the mold is completely filled with no shrinkage porosity or void formation. It is evident that there is a good agreement between simulation and experiment when comparing the resulting appearance of components in simulations and experiments.

这项研究的主要目的是利用铸造计算模拟分析来确定有效的冒口尺寸,并消除实际球状石墨(SG)铁飞轮铸件中的缩孔。模拟软件 Pro-CAST 用于模拟不同工艺条件下的凝固过程(即不使用冒口和使用有效尺寸冒口)。模拟结果通过随后的绿砂铸造实验得到证实。此外,还进行了深入调查,以确定收缩行为与铸造部件形态特征之间的相关性。模拟结果推断,由于共晶凝固时间较短,未优化的冒口尺寸会在较厚的部分造成收缩气孔和空隙的形成。然而,当优化了隔水管的尺寸后,只需确保共晶凝固时间高于较厚部分的共晶凝固时间,就可以减轻这种影响;因此,模具可以完全填充,不会产生收缩气孔或空洞。通过比较模拟和实验得出的组件外观,可以明显看出模拟和实验之间存在良好的一致性。
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引用次数: 0
A Study of the Influence and Mechanism of Alumina Ceramic Powder on the High-Temperature Strength of NaCl–Na2CO3 Cores in Die-Casting Production 氧化铝陶瓷粉对压铸生产中 NaCl-Na2CO3 铁芯高温强度的影响及机理研究
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-08 DOI: 10.1007/s40962-024-01400-x
Yang Li, Lai Song, Guangyu Chen, Weihua Liu, Jingkai Zhang, Changyu Sun, Xue Zou, Minghui Bai

Water-soluble salt core materials have high bending strength at room temperature. During high-pressure casting, water-soluble salt cores must withstand high temperatures and impact loads. To obtain a composite water-soluble salt core suitable for high-pressure casting components, sodium chloride and sodium carbonate are used as base salt materials. Ceramic particles of alumina are used as reinforcement materials in the preparation of a water-soluble composite salt core with excellent high-temperature strength via gravity casting. The microstructures of the salt core and fracture surface are observed and characterized. The use of alumina to enhance the sensitivity of the binary salt cores results in a low thermal crack sensitivity coefficient. The alumina particles dispersed in the matrix prevent crack propagation. Simulation results show that sodium aluminate has strong interfacial bonding abilities with other components in the salt core, affecting its high-temperature strength. Further results confirm that sodium aluminate formation enhances the high-temperature strength of salt cores.

水溶性盐芯材料在室温下具有很高的抗弯强度。在高压铸造过程中,水溶性盐芯必须承受高温和冲击载荷。为获得适用于高压铸造部件的复合水溶性盐芯,可使用氯化钠和碳酸钠作为基盐材料。在通过重力浇铸制备具有优异高温强度的水溶性复合盐芯时,使用了氧化铝陶瓷颗粒作为增强材料。对盐芯和断裂面的微观结构进行了观察和表征。使用氧化铝提高二元盐芯的灵敏度,可获得较低的热裂纹灵敏系数。分散在基体中的氧化铝颗粒可防止裂纹扩展。模拟结果表明,铝酸钠与盐芯中的其他成分具有很强的界面结合能力,从而影响了盐芯的高温强度。进一步的结果证实,铝酸钠的形成可提高盐芯的高温强度。
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引用次数: 0
Effects of Sc–Er Rare Earth on Solidification Microstructure and Mechanical Properties of A360 Alloy 稀土钪对 A360 合金凝固微观结构和机械性能的影响
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-08 DOI: 10.1007/s40962-024-01397-3
Shuaijie Yuan, Jianfei Peng, Wanlin Wang, Yan Zhan, Jie Zeng, Peiyuan Gan, Junyu Ji

Hypoeutectic Al-Si alloy (A360) is widely used to high-pressure die casting components used in the aerospace, automobile and building industries. An experimental investigation has been conducted concerning the effect of different rare earth Sc and Er additions on the solidification process of A360 alloy. The results indicate that a precipitation phase Al(Sc, Er)2Si2 is formed with the addition of Sc and Er elements. Moreover, the eutectic Si phase evolves from a coarse block-like and irregular polygonal into a granular morphology, and its average size value is decreased from 25.48 μm to 9.46 μm when the content of Sc–Er increases from 0 wt% to 0.6 wt%. In addition, the alloy exhibits an outstanding combination of mechanical and wear resistance properties at a Sc–Er addition of 0.6 wt%. Compared with the unmodified alloy, its ultimate tensile strength has increased from 82.7 MPa to 148.4 MPa and average friction coefficient has decreased from 0.689 to 0.504.

Graphical Abstract

低共晶铝硅合金(A360)被广泛用于航空航天、汽车和建筑行业的高压压铸部件。实验研究了不同稀土 Sc 和 Er 添加量对 A360 合金凝固过程的影响。结果表明,添加 Sc 和 Er 元素后会形成沉淀相 Al(Sc,Er)2Si2。此外,当 Sc-Er 的含量从 0 wt% 增加到 0.6 wt% 时,共晶 Si 相从粗糙的块状和不规则的多边形演变成粒状形态,其平均粒度值从 25.48 μm 减小到 9.46 μm。此外,Sc-Er 的添加量为 0.6 wt%时,合金的机械性能和耐磨性能表现出了出色的结合。与未改性合金相比,其极限抗拉强度从 82.7 兆帕增加到 148.4 兆帕,平均摩擦系数从 0.689 降至 0.504。
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引用次数: 0
Numerical Analysis of the Influence of Demolding Temperature on Final Distortion in Gravity Die Casting Process 重力压铸工艺中脱模温度对最终变形影响的数值分析
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-07-06 DOI: 10.1007/s40962-024-01398-2
S. Gor, N. Wolff, B. Pustal, A. Bührig-Polaczek

Distortion can be a prominent issue in the production of metal casting components, especially when using metal dies. Existing research underscores the pivotal role of the temperature at which the solidified component is extracted from the mold in contribution to the ultimate distortion of the component. This numerical investigation seeks a comprehensive understanding of the factors governing deformation by employing simulations that emulate experimental conditions. The study utilizes coupled thermomechanical simulations, executed through the commercial software “Abaqus,” across varying demolding temperatures. The temporal evolution of distortion is examined, with a focus on influential factors such as elastic and thermal strain. A quantitative and qualitative comparison is drawn between simulation outcomes and experimental results. The difference between experimental and simulation results was observed to increase linearly with higher demolding temperatures. The potential for leveraging the qualitative similarity between experimental and simulation results as a foundation for the development of distortion control strategies is deliberated.

变形是金属铸造部件生产中的一个突出问题,尤其是在使用金属模具时。现有研究强调,凝固部件从模具中取出时的温度对部件的最终变形起着关键作用。这项数值研究通过模拟实验条件,力求全面了解影响变形的因素。研究利用商业软件 "Abaqus "对不同的脱模温度进行热力学耦合模拟。对变形的时间演变进行了研究,重点是弹性应变和热应变等影响因素。对模拟结果和实验结果进行了定量和定性比较。实验结果和模拟结果之间的差异随着脱模温度的升高而呈线性增长。讨论了利用实验和模拟结果之间的定性相似性作为开发变形控制策略基础的可能性。
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引用次数: 0
期刊
International Journal of Metalcasting
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