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Relationships Between Macrostructure and Microstructure in Lamellar Graphite Iron Castings 片状石墨铸件中的宏观结构与微观结构之间的关系
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-22 DOI: 10.1007/s40962-024-01319-3
Björn Domeij, Attila Diószegi

Spherical sheet steel molds filled with gray iron melts of varying chemical compositions and metallurgical conditions were air-cooled until solid, followed directly by austempering to preserve the austenite grain structure. The castings were studied using a combination of cooling curves and quantitative metallography, in order to clarify control of the austenite grain structure and its impact on the local microstructure. A novel method utilizing fast Fourier transform provided visual overview of macroscopic trends in the scale of the flake graphite structure. Castings inoculated with Sr-containing ferrosilicon featured finer eutectic cell structure but coarser equiaxed structure of austenite, emphasizing that melt treatments applied to control the graphite structure may have unintended effects on the austenite grain structure. In most non-inoculated castings, the microstructure was banded, with alternating layers of coarse and fine flake graphite with distance from the casting surface. The extent of the columnar zone of austenite grains showed no correlation with the graphite structure nor the volume fraction of dendrites. The volume-to-surface ratio of dendrites was more uniform in the columnar zone, but increased toward the center in the equiaxed zone. The casting with the highest carbon equivalent (4.34), featured zones containing finer dendrites and graphite. These zones appear to be gaps in the early solidification structure which filled later by secondary dendritic growth from surrounding austenite. This highlights that high carbon equivalent may lead to poor dendrite coherency which can make the microstructure less uniform and less predictable.

用不同化学成分和冶金条件的灰铸铁熔体填充球形薄钢板铸模,空冷至凝固,然后直接进行奥氏体回火以保持奥氏体晶粒结构。为了明确奥氏体晶粒结构的控制及其对局部微观结构的影响,采用冷却曲线和定量金相分析相结合的方法对铸件进行了研究。一种利用快速傅立叶变换的新方法提供了片状石墨结构尺度宏观趋势的直观概览。接种了含锰硅铁的铸件具有更精细的共晶晶胞结构,但奥氏体的等轴晶粒结构更粗大,这强调了为控制石墨结构而进行的熔融处理可能会对奥氏体晶粒结构产生意想不到的影响。在大多数未接种的铸件中,微观结构呈带状,粗片石墨和细片石墨交替分布,距离铸件表面的距离越远。奥氏体晶粒柱状区的范围与石墨结构和枝晶的体积分数没有相关性。在柱状区,枝晶的体积表面比更为均匀,但在等轴区,枝晶的体积表面比向中心增加。碳当量最高(4.34)的铸件具有包含更细树枝状突起和石墨的区域。这些区域似乎是早期凝固结构中的间隙,后来被周围奥氏体的二次枝晶生长所填充。这突出表明,高碳当量可能会导致树枝晶一致性差,从而使微观结构不够均匀和难以预测。
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引用次数: 0
The Effect of Tempering Temperature on Microstructure and Wear Behavior of Tungsten and Boron Alloyed Ni-Hard 4 White Cast Irons 回火温度对钨和硼合金镍硬 4 白口铸铁微观结构和磨损行为的影响
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-22 DOI: 10.1007/s40962-024-01322-8
Burak Barutçuoğlu, Funda Gül Koç, Ersoy Erişir, Gülben Karaarslan

This study investigates the effect of tempering temperature on the microstructure and wear resistance of high-alloy white cast iron (Ni-Hard 4) with 1.15% W and 0.5% B additions. Specimens were austenitized at 850 °C for 5 h, quenched in air, and tempered at temperatures between 250 and 650 °C for 4 h. Equilibrium and non-equilibrium thermodynamic calculations were performed using Thermo-Calc software. After the microstructural investigations, hardness testing was carried out. A pin-on-disk tribometer was used to conduct wear tests under dry sliding conditions. Microstructure and worn surfaces were examined using light and scanning electron microscopes. The results showed that increasing tempering temperature resulted in a higher volume fraction of carbides. It was found that tempering at 550 °C for four hours increases resistance to wear giving the lowest measured values of weight loss and wear rate. Accordingly, tempering allows the precipitation of fine carbides in the martensitic matrix which may increase wear resistance.

本研究探讨了回火温度对添加 1.15% W 和 0.5% B 的高合金白口铸铁(Ni-Hard 4)微观组织和耐磨性的影响。试样在 850 °C 下奥氏体化 5 小时,在空气中淬火,并在 250 至 650 °C 之间的温度下回火 4 小时,使用 Thermo-Calc 软件进行平衡和非平衡热力学计算。微观结构研究结束后,进行了硬度测试。在干滑动条件下,使用针盘摩擦磨损测试仪进行磨损测试。使用光学显微镜和扫描电子显微镜对微观结构和磨损表面进行了检测。结果表明,回火温度升高导致碳化物的体积分数增加。在 550 °C 下回火四小时可提高耐磨性,使重量损失和磨损率的测量值最低。因此,回火可使细小碳化物在马氏体基体中析出,从而提高耐磨性。
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引用次数: 0
Iron and Steel Castings and Core Production Results from Finer Grades of Chromite Sand in Shell Applications 壳体应用中更细级铬铁矿砂的钢铁铸件和铁芯生产结果
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-19 DOI: 10.1007/s40962-024-01311-x
Rob Steele, Kelley Kerns, Patricia LaFay, Victor LaFay

Chromite sands have been utilized to produce cores in foundries for many years. This investigation focuses on finer grades of chromite sand for core produced with shell technology. The specific shell cores produced result from the unique thermal characteristics of finer grades of chromite sand. The resulting castings demonstrate a high level of casting integrity.

多年来,铸造厂一直使用铬铁矿砂生产型芯。本次调查的重点是采用壳体技术生产芯材的较细级铬铁矿砂。较细级的铬铁矿砂具有独特的热特性,因此能生产出特定的型芯。所生产的铸件具有很高的铸造完整性。
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引用次数: 0
Determination of Thermal Properties of Foundry Green Sand to Improve Numerical Simulation 确定铸造用青砂的热性能以改进数值模拟
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-18 DOI: 10.1007/s40962-024-01313-9
P. Jacquet, A. Vaucheret, M. Souêtre, J. F. Carton

Numerical simulation of the foundry process, aimed at reducing costs and production lead times, directly impacts the responsiveness and competitiveness of the foundries that employ it. Three experiments were conducted to establish the values of specific heat capacity (Cp), density (ρ), and thermal conductivity (λ) of green sand over a measurement range spanning from room temperature to over 800 °C. These experiments yielded representative data for the real properties of silico-clay sand, which were subsequently substituted for the generic properties provided in the NovaFlow&Solid® software database. It is worth noting that this study is not limited to a single software; the physical properties obtained can be transferred to other simulation software as well. A cooling simulation was conducted with the corrected physical properties of the sand, and the resulting curve better reflects reality than the one initially obtained with the original values. Having a more precise knowledge of the exact temperature of the metal at a given moment is crucial for predicting certain defects.

铸造工艺的数值模拟旨在降低成本和缩短生产周期,直接影响到采用该工艺的铸造厂的反应能力和竞争力。我们进行了三次实验,以确定绿砂在从室温到超过 800 °C 的测量范围内的比热容 (Cp)、密度 (ρ) 和热导率 (λ) 值。这些实验得出了硅质粘土砂真实属性的代表性数据,随后将其替换为 NovaFlow&Solid® 软件数据库中提供的通用属性。值得注意的是,这项研究并不局限于一种软件;所获得的物理性质也可以转移到其他模拟软件中。使用修正后的砂物理特性进行了冷却模拟,结果曲线比最初使用原始值得到的曲线更好地反映了实际情况。更精确地了解特定时刻金属的确切温度对于预测某些缺陷至关重要。
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引用次数: 0
Study on Semi-solid Slurry Preparation Process, Microstructure, and Mechanical Properties of Truck Bracket 卡车支架半固态浆料制备工艺、微观结构和机械性能研究
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-18 DOI: 10.1007/s40962-024-01330-8
Zihan Lang, Feng Wang, Zibo Gao, Xudong Du, Jinwei Li, Zhi Wang, Le Zhou, Pingli Mao

The semi-solid slurry preparation process, microstructure, and mechanical properties of truck coarse filter bracket were studied in this paper. The semi-solid aluminum alloy slurry with high solid fraction was prepared by the Slurry Enthalpy Equilibrium Device (SEED) method, and the optimum slurry preparation parameters were determined through the observation and analysis of the slurry microstructure as follows: pouring temperature 700 °C, rotation speed 180 r/min, and crucible temperature 400 °C. The average grain size and shape factor of the slurry prepared under these conditions are 50.448 μm and 0.799. Die casting trial production which used the best process parameters of slurry preparation and die casting was carried out. The results show that the die casting parts are completely filled with no obvious surface defects. It can be seen from the cutting experiment and X-ray non-destructive test that the internal structure is dense and uniform, and there are no obvious casting defects that were observed such as cracks and holes. The semi-solid die castings were strengthened by T6 heat treatment. The experimental results showed that the optimal heat treatment parameters were a solution temperature of 470 °C and time of 4 h, aging temperature of 175 °C and time of 12 h. Under these conditions, the microstructure morphology was improved significantly. The tensile strength and yield strength reached 342.1 MPa and 309.1 MPa, respectively, which were 38.9% and 95.3% higher than the semi-solid state, and the elongation was 4.5%.

本文研究了卡车粗滤支架的半固态浆料制备工艺、微观结构和力学性能。采用浆料焓平衡装置(SEED)法制备了高固含率的半固态铝合金浆料,通过对浆料微观组织的观察和分析,确定了最佳浆料制备参数为:浇注温度 700 ℃,转速 180 r/min,坩埚温度 400 ℃。在这些条件下制备的浆料的平均晶粒大小和形状系数分别为 50.448 μm 和 0.799。采用浆料制备和压铸的最佳工艺参数进行了压铸试制。结果表明,压铸件完全填充,没有明显的表面缺陷。从切削实验和 X 射线无损检测可以看出,内部结构致密均匀,没有观察到明显的铸造缺陷,如裂纹和孔洞。对半固态压铸件进行了 T6 热处理强化。实验结果表明,最佳热处理参数为固溶温度 470 ℃、时间 4 小时,时效温度 175 ℃、时间 12 小时。拉伸强度和屈服强度分别达到 342.1 兆帕和 309.1 兆帕,比半固态分别提高了 38.9% 和 95.3%,伸长率为 4.5%。
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引用次数: 0
The Effect of Si Content on the Microstructure and Mechanical Properties of Al–1.2Mg–xSi–1.2Cu–0.6Mn Cast Alloy 硅含量对 Al-1.2Mg-xSi-1.2Cu-0.6Mn 铸造合金微观结构和力学性能的影响
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-17 DOI: 10.1007/s40962-024-01339-z
Zulai Li, Zhixiang Yang, Fei Zhang, Yifan Shi, He Wei, Junlei Zhang, Han Xiao

In this paper, the effect of Si content on the microstructure and mechanical properties of the Al–1.2Mg–xSi–1.2Cu–0.6Mn cast alloy was investigated. The study aimed to explore the optimal addition of Si element to improve the comprehensive properties of alloys. The microstructure, phase composition and fracture morphology of the alloy were determined through OM, SEM, EBSD and XRD analysis. The Si content in the alloy ranged from 0.48 to 2.4 wt.%. With the increase of Si content, the number of strengthening phases increases, which improves the comprehensive properties of the alloy. When the Si content is 0.8 wt.%, the eutectic Mg2Si transforms from rod-shaped to larger block shaped, and the formation of coarse Mg2Si phase limits the elongation of the alloy. When the Si content is 2.4 wt.%, fine Al2Cu phases are present in this alloy and coexist with Al(Fe,Mn)Si phases, while an increase in the Si content appears as partially accompanied by an incipient crystalline Si phase around the Al(Fe,Mn)Si phase. The alloy exhibits a maximum tensile strength, yield strength and elongation of 198.2 MPa, 101.2 MPa and 4.96%, respectively, with a hardness of 80.94 Hv. It consists of five alloy phases, mainly α-Al, Mg2Si, Al(Fe, Mn)Si eutectic phase, Q-AlCuMgSi eutectic phase and the beginning crystalline silicon phase formed due to the increased Si content. The Si content can improve alloy strength, but there is some damage to the toughness of the alloy. Higher silicon alloy content results in the formation of fine Al2Cu eutectic. This result makes it possible to achieve a higher level of strength with a reduced loss of ductility in the alloy.

本文研究了硅含量对 Al-1.2Mg-xSi-1.2Cu-0.6Mn 铸造合金微观结构和机械性能的影响。研究旨在探索最佳的硅元素添加量,以改善合金的综合特性。通过光学显微镜(OM)、扫描电镜(SEM)、EBSD 和 XRD 分析确定了合金的微观结构、相组成和断口形貌。合金中的硅含量范围为 0.48 至 2.4 wt.%。随着硅含量的增加,强化相的数量也随之增加,从而改善了合金的综合性能。当 Si 含量为 0.8 wt.% 时,共晶 Mg2Si 由棒状转变为较大的块状,粗 Mg2Si 相的形成限制了合金的伸长。当 Si 含量为 2.4 wt.% 时,合金中出现细小的 Al2Cu 相,并与 Al(Fe,Mn)Si 相共存,而当 Si 含量增加时,Al(Fe,Mn)Si 相周围会出现部分初晶 Si 相。该合金的最大抗拉强度、屈服强度和伸长率分别为 198.2 MPa、101.2 MPa 和 4.96%,硬度为 80.94 Hv。它由五种合金相组成,主要是 α-Al、Mg2Si、Al(Fe,Mn)Si 共晶相、Q-AlCuMgSi 共晶相以及因 Si 含量增加而形成的初晶硅相。硅含量可提高合金强度,但对合金的韧性有一定损害。较高的硅合金含量可形成细小的 Al2Cu 共晶。这一结果使合金在获得更高强度的同时减少了韧性的损失。
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引用次数: 0
Metalcasting Industry Research 金属铸造行业研究
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-10 DOI: 10.1007/s40962-024-01318-4
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引用次数: 0
From the Editor 编辑的话
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-08 DOI: 10.1007/s40962-024-01317-5
Thomas Prucha
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引用次数: 0
Effects of Silicon in High-Cr White Cast Irons 高铬白口铸铁中硅的影响
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-05 DOI: 10.1007/s40962-024-01315-7
Richard B. Gundlach, John M. Tartaglia

To improve their performance, this research characterized the effects of Si on various attributes of high-Cr white cast irons. Hypoeutectic alloys of 15 and 25% Cr white irons were produced with Si levels varying of 0.4, 1 and 1.6%Si and poured into 3-inch (75-mm) Y-block sand molds. Various tests were used to determine the optimum hardening temperature and the kinetics of pearlite transformation. In addition, image analysis was performed to determine eutectic carbide fraction. Furthermore, energy-dispersive spectroscopy analysis was conducted to determine the distributions of the alloying elements among the various solidification constituents. Raising Cr from 15 to 25% caused the optimum hardening temperature to rise from 1680 to 1920 °F (915 to 1050 °C). In the 15% Cr series, an increase of 1.2% Si raised the optimum hardening temperature by 80 °F (50 °C), whereas, for the 25% Cr series, the optimum hardening temperature was unchanged. Peak hardness was significantly higher (by 50 HB) in the leaner Cr alloys and the peak hardness in both the 15% and 25% Cr alloys decreased slightly (by 20 HB) when the Si content was increased from 0.4 to 1.6%. However, the hardenability (the time to the onset of pearlite transformation) increased with increasing Si content. The influence of Si on % eutectic saturation was not clear. When analyzing carbide fraction, Si had a negligible effect in the 15%Cr series, but seemed to cause the 25%Cr series to develop less eutectic carbide, that is, become more hypoeutectic. Cr was richest in the eutectic carbides and leanest in the eutectic austenite matrix. Si was largely rejected from the eutectic carbides and richest in the eutectic austenite.

为了提高这些铸铁的性能,本研究确定了硅对高铬白口铸铁各种属性的影响。在生产含硅量为 0.4%、1% 和 1.6% 的 15% 和 25% 铬白口铁的低共晶合金时,将其浇注到 3 英寸(75 毫米)的 Y 型砂模中。通过各种测试确定了最佳硬化温度和珠光体转变动力学。此外,还进行了图像分析,以确定共晶碳化物组分。此外,还进行了能量色散光谱分析,以确定合金元素在各种凝固成分中的分布情况。将铬含量从 15% 提高到 25%,可使最佳硬化温度从 1680 °F 上升到 1920 °F(915 °C到 1050 °C)。在铬含量为 15% 的系列中,增加 1.2% 的硅会使最佳淬火温度提高 80 °F(50 °C),而在铬含量为 25% 的系列中,最佳淬火温度保持不变。当硅含量从 0.4% 增加到 1.6% 时,较薄的铬合金的峰值硬度明显提高(50 HB),而 15% 和 25% 铬合金的峰值硬度则略有下降(20 HB)。然而,淬透性(波来石转变开始的时间)随着硅含量的增加而增加。硅对共晶饱和度百分比的影响并不明显。在分析碳化物组分时,硅对 15%Cr 系列的影响可以忽略不计,但似乎会导致 25%Cr 系列出现较少的共晶碳化物,即变得更低共晶。共晶碳化物中的铬含量最高,共晶奥氏体基体中的铬含量最低。硅在共晶碳化物中基本被剔除,而在共晶奥氏体中含量最高。
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引用次数: 0
Graphite Spheroids: The Place Where they are Born 石墨球:诞生之地
IF 2.6 3区 材料科学 Q2 METALLURGY & METALLURGICAL ENGINEERING Pub Date : 2024-04-04 DOI: 10.1007/s40962-024-01294-9
Gorka Alonso, D. M. Stefanescu, Beñat Bravo, Ramón Suárez

In the same way that a building needs a solid foundation to remain firm and stable, graphite requires proper nucleation sites to precipitate and grow in the right way. Phenomena that occur during solidification process will determine the nature of the nuclei (non-metallic inclusions), as the topology of the land will establish the quality of a construction. Their presence will define the nucleation potential of the melt, being highly influenced by a multitude of variables such as the base metal composition, the graphite spheroidization treatment, or the inoculation process. A good knowledge of the formation of these particles will help an excellent control of the formation of graphite. Silicates, oxides, sulfides, carbides, and nitrides were found acting as nuclei for graphite depending on the solidification conditions. The objective of this paper is to improve the understanding of the mechanisms that govern nucleation, verifying some theories already described by other researchers, but also developing some new ones. The direct relation between the type of nuclei and the processes that occur during the liquid–solid transformation was also demonstrated.

建筑需要坚实的地基才能保持牢固和稳定,同样,石墨也需要适当的成核场所才能以正确的方式析出和生长。凝固过程中发生的现象将决定晶核(非金属夹杂物)的性质,就像土地的拓扑结构将决定建筑的质量一样。非金属夹杂物的存在将决定熔体的成核潜力,并受到多种变量的高度影响,如基本金属成分、石墨球化处理或接种过程。充分了解这些颗粒的形成,有助于对石墨的形成进行出色的控制。根据凝固条件的不同,硅酸盐、氧化物、硫化物、碳化物和氮化物都可以作为石墨的晶核。本文的目的是加深对成核机制的理解,验证其他研究人员已经描述过的一些理论,同时也提出一些新的理论。本文还证明了核的类型与液固转化过程之间的直接关系。
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引用次数: 0
期刊
International Journal of Metalcasting
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