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Review of Laser-Induced Graphene (LIG) Produced on Eco-Friendly Substrates 激光诱导石墨烯(LIG)在环保基底上的生产回顾
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-02-24 DOI: 10.1007/s40684-024-00595-y
Hye-ran Moon, Byunghoon Ryu

Laser-induced graphene (LIG) has been extensively researched due to its facile fabrication on various carbon-containing substrates using simple laser scribing. In recent years, advancements have enabled the production of LIG on environmentally friendly substrates, opening new possibilities for designing sustainable electronics that minimize adverse environmental effects. This paper provides an overview of the latest advancements in manufacturing technologies for LIG on eco-friendly substrates, such as paper, wood, lignin biomass, cloth, food, and biocompatible parylene-C. Furthermore, a comparative analysis is conducted between LIG generated on eco-friendly substrates and graphene patterns printed using commercially available graphene ink. This analysis emphasizes the potential efficacy of LIG as an efficient manufacturing technique for producing conductive graphene patterns. The review also outlines the remaining challenges requiring attention to advance these manufacturing processes and outlooks future opportunities, which can serve as a valuable guide for both novice researchers unfamiliar with LIG and experienced researchers aiming to utilize eco-friendly substrates in their study.

激光诱导石墨烯(LIG)通过简单的激光划线就能在各种含碳基底上轻松制备,因此得到了广泛的研究。近年来,激光诱导石墨烯技术的进步使得在环保基底上生产石墨烯成为可能,这为设计可持续电子产品、最大限度地减少对环境的不利影响提供了新的可能性。本文概述了在纸张、木材、木质素生物质、布料、食品和生物相容性对二甲苯-C 等环保基材上制造 LIG 的最新技术进展。此外,还对在环保基底上生成的 LIG 与使用市售石墨烯墨水印刷的石墨烯图案进行了比较分析。这项分析强调了 LIG 作为生产导电石墨烯图案的高效制造技术的潜在功效。综述还概述了推进这些制造工艺所需注意的其余挑战,并展望了未来的机遇,这对不熟悉 LIG 的新手研究人员和希望在研究中利用环保基底的资深研究人员都是一个宝贵的指导。
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引用次数: 0
Dry Transfer Printed Hole Transport Layer for Hysteresis-Free Colloidal Quantum Dot Solar Cells 用于无滞后胶体量子点太阳能电池的干转移印制空穴传输层
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-02-10 DOI: 10.1007/s40684-023-00594-5
Hyung Cheoul Shim, Jung Hoon Song, Areum Kim, Hye-Mi So, Seungmin Hyun, Sohee Jeong

Colloidal quantum dot (CQD) solar cells have drawn a lot of attention because of their potential for bandgap engineering, which enables broad and powerful absorption in the wavelength of sunlight, and low-cost process based on the solution phase production. However, the interfacial problems resulting from the heterojunction structure containing electron and hole transport layers cause a hysteresis phenomenon that weakens the device stability. We used the dry-transfer technique to implement a hole transport layer (HTL) with enhanced interfacial properties in devices. This approach is highly reproducible and allows for precise thickness control of the HTL. It also uses substantially less environmentally harmful organic solvents for the ligand exchange process than those required by the previous layer-by-layer (LbL) deposition technique. Additionally, about 400 nm thick CQD film could be deposited without the ligand exchange process, and a power conversion efficiency of 10% with minimized hysteresis was achieved using this method. Moreover, by improving the interfacial properties over the traditional LbL approach, it was feasible to lower the charge transfer resistance related to the device's hysteresis by a factor of up to four or more.

胶体量子点(CQD)太阳能电池具有带隙工程的潜力,可实现对太阳光波长的广泛而强大的吸收,而且基于溶液相生产的工艺成本低,因此备受关注。然而,包含电子和空穴传输层的异质结结构所产生的界面问题会导致滞后现象,从而削弱器件的稳定性。我们采用干法转移技术在器件中实现了具有增强界面特性的空穴传输层(HTL)。这种方法具有很高的可重复性,可以精确控制 HTL 的厚度。与之前的逐层(LbL)沉积技术相比,它还大大减少了配体交换过程中对环境有害的有机溶剂的使用。此外,无需配体交换过程就能沉积约 400 nm 厚的 CQD 薄膜,并利用这种方法实现了 10% 的功率转换效率,同时将滞后现象降至最低。此外,与传统的 LbL 方法相比,通过改善界面特性,可以将与器件滞后有关的电荷转移电阻降低四倍或更多。
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引用次数: 0
Solvothermal Synthesis of PtNi Nanoparticle Thin Film Cathode with Superior Thermal Stability for Low Temperature Solid Oxide Fuel Cells 溶热合成具有优异热稳定性的铂镍纳米薄膜阴极,用于低温固体氧化物燃料电池
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-02-10 DOI: 10.1007/s40684-023-00576-7
Jiyoon Shin, Kittiwat Kamlungsua, Hao-Yang Li, Pei-Chen Su

This work adopts solvothermal synthesis to fabricate PtNi nanoparticles as thin film cathodes with superior resistance against thermally driven agglomeration for low temperature solid oxide fuel cells (LT-SOFCs) operating at 450 ºC. Metal-based porous electrodes are common choices for thin film LT-SOFCs, but pure metals with high density nanoscale porosities are vulnerable to thermal agglomeration, which imposes challenges to maintaining high performance with long-term stability. Typical Pt-based thin film cathodes are previously reported to sustain a record high 600 ºC of thermal annealing with acceptable morphological stability, but the temperature is still too low for practical LT-SOFC application. In this work, the solvothermal synthesized PtNi nanoparticle thin films show superior thermal stability, sustaining 10 h of annealing at 800 ºC without significant agglomeration observed. By controlling the length of synthesis time, the particle sizes and Pt loading ratio can be varied. The cost-effective solvothermal synthesis process for the fabrication of PtNi thin film cathode is a promising way for LT-SOFC manufacturing in scale as it involves no vacuum process like typical sputtering.

Graphical Abstract

本研究采用溶液热合成法制造铂镍纳米粒子,作为薄膜阴极,具有优异的抗热聚结能力,适用于在 450 ºC 温度下工作的低温固体氧化物燃料电池(LT-SOFC)。金属基多孔电极是薄膜 LT-SOFC 的常见选择,但具有高密度纳米级多孔性的纯金属易受热聚结影响,这给保持高性能和长期稳定性带来了挑战。之前有报道称,典型的铂基薄膜阴极可在 600 ºC 的高温热退火条件下保持可接受的形态稳定性,但这一温度对于 LT-SOFC 的实际应用来说仍然过低。在这项工作中,溶热合成的铂镍纳米粒子薄膜显示出卓越的热稳定性,可在 800 ºC 下持续退火 10 小时,且未观察到明显的团聚现象。通过控制合成时间的长短,可以改变颗粒大小和铂负载率。这种用于制造铂镍薄膜阴极的溶解热合成工艺不需要像典型的溅射法那样的真空工艺,因此是一种具有成本效益的大规模制造 LT-SOFC 的可行方法。
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引用次数: 0
Sound-Based Depth Estimation of Glass Microchannel in Laser-Induced Backside Wet Etching Using Wavelet Transform 利用小波变换对激光诱导背面湿蚀刻中的玻璃微通道进行基于声音的深度估计
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-02-08 DOI: 10.1007/s40684-023-00590-9
Geun Young Kim, Dae-Seob Song, Kui-Kam Kwon, Sung-Hoon Ahn

Laser-induced backside wet etching (LIBWE) has been proposed to fabricate high-quality micromachined components on transparent materials. However, the process is limited by poor repeatability when fabricating high-aspect-ratio structures, even under the same conditions due to uncertainties arising from the thermal process and the complex mechanisms associated with the indirect irradiation of the etching process. Such errors could lead to redundant trials and wastages when trying to achieve the desired dimension. To identify the factors causing these variations, we targeted the process sounds generated during the etching. This study uses a microphone to measure factors that result in variations in material removal quantity during the etching process under the same conditions. The sound was filtered at frequencies between 3 and 6 kHz, which were selected as characteristic frequencies for the process under various laser conditions. By integrating the root mean squared value of the detail coefficient of the wavelet transform, the depth estimation closely matched the measured depth of the fabricated part. This finding suggests that determining the etching rate from sound at a certain characteristic frequency during the LIBWE process is feasible; this approach can improve the accuracy and repeatability of the process. Based on this estimation mechanism, we designed a closed-loop feedback control system capable of fabricating highly accurate microchannels in the range of 80–120 μm with a maximum error of 5.6%.

激光诱导背面湿法蚀刻(LIBWE)已被提出用于在透明材料上制造高质量的微加工元件。然而,在制造高宽比结构时,即使在相同的条件下,该工艺也会受到可重复性差的限制,这是因为热处理过程和蚀刻过程间接照射相关的复杂机制所产生的不确定性。当试图达到所需的尺寸时,这些误差可能会导致重复试验和浪费。为了找出导致这些变化的因素,我们将目标锁定在蚀刻过程中产生的声音上。这项研究使用麦克风测量在相同条件下蚀刻过程中导致材料去除量变化的因素。声音在 3 至 6 kHz 的频率范围内进行了滤波,这些频率被选为各种激光条件下加工过程的特征频率。通过对小波变换的细节系数的均方根值进行积分,深度估算结果与制造部件的测量深度非常吻合。这一发现表明,在 LIBWE 过程中,通过某一特征频率的声音来确定蚀刻率是可行的;这种方法可以提高过程的准确性和可重复性。基于这种估计机制,我们设计了一种闭环反馈控制系统,该系统能够制造出 80-120 μm 范围内的高精度微通道,最大误差为 5.6%。
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引用次数: 0
Wavelet Packet Transform and Deep Learning-based Fusion of Audio-Visual Signals: A Novel Approach for Enhancing Laser Cleaning Effect Evaluation 基于小波包变换和深度学习的视听信号融合:增强激光清洁效果评估的新方法
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-02-01 DOI: 10.1007/s40684-023-00589-2
Haipeng Huang, Liang Li, Shiwei Liu, Bentian Hao, Dejun Ye

In response to the insufficient detection capability of laser paint stripping effects for a single modality and the high operational and cost requirements of existing multi-monitoring technologies, a method is proposed to integrate visual and auditory signals for evaluating laser paint stripping effects. Utilizing wavelet packet transformation for a more detailed understanding of the variations in paint-stripping sound signals, more representative energy features are extracted. The EfficientNetv2 network, optimized with an attention mechanism, further enhances the focus on crucial features. The image feature vectors are concatenated with the energy features extracted from the sound signals, forming a new and more informative feature vector for paint stripping effect discrimination. Experimental results demonstrate that the multi-feature fusion detection algorithm significantly improves the accuracy of paint stripping effect discrimination, reaching 98.7%. The 98.9% F1-Score and the smoothly converging loss curve also indicate the algorithm's effective control over category imbalance and training stability. This research is of paramount importance for improving the evaluation of laser cleaning technology effects and provides insights into multi-modal feature fusion for other relevant fields of study.

针对单一模式对激光脱漆效果的检测能力不足,以及现有多重监测技术对操作和成本的高要求,提出了一种整合视觉和听觉信号以评估激光脱漆效果的方法。利用小波包变换来更详细地了解脱漆声音信号的变化,从而提取出更具代表性的能量特征。通过注意力机制优化的 EfficientNetv2 网络进一步加强了对关键特征的关注。图像特征向量与从声音信号中提取的能量特征相串联,形成一个新的、信息量更大的特征向量,用于脱漆效果判别。实验结果表明,多特征融合检测算法显著提高了脱漆效果判别的准确率,达到 98.7%。98.9% 的 F1 分数和平稳收敛的损失曲线也表明该算法能有效控制类别不平衡和训练稳定性。这项研究对改进激光清洁技术效果评估具有重要意义,并为其他相关研究领域的多模态特征融合提供了启示。
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引用次数: 0
Physicochemical Aspects of Platinum Nanoparticles (PtNPs) from Biological Synthesis: Influence of Plant Leaf Based Extracts as the Reducing Agent 生物合成铂纳米粒子(PtNPs)的物理化学方面:植物叶基提取物作为还原剂的影响
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-01-31 DOI: 10.1007/s40684-023-00592-7
Khanittha Ponsanti, Benchamaporn Tangnorawich, Sitakan Natphopsuk, Surachet Toommee, Chiravoot Pechyen

This study reports the biological synthesis of platinum nanoparticles (PtNPs) using leaf extracts of kaffir lime (Citrus hystrix DC), common basil (Ocimum basilicum Linn) and fragrant pandan (Pandanus amaryllifolius Roxb). These extracts contain sugars, terpenoids, polyphenols, alkaloids, phenolic acids, and proteins, which play an essential role in reducing Pt (IV) solutions to platinum nanoparticles (PtNPs). The PtNPs were extensively characterized, exhibiting spherical morphologies and particle sizes between 20 and 80 nm as indicated by TEM imaging. As shown by the UV–Visible Spectroscopy, the maximum absorption of platinum nanoparticles is at 256 nm. Furthermore, the electrochemical sensor exhibits good analytical performances in detecting glycated hemoglobin (HbA1c) in the real samples.

Graphical Abstract

本研究报告了利用卡菲尔酸橙(Citrus hystrix DC)、普通罗勒(Ocimum basilicum Linn)和香丹(Pandanus amaryllifolius Roxb)的叶提取物进行铂纳米粒子(PtNPs)的生物合成。这些提取物含有糖类、萜类、多酚类、生物碱、酚酸和蛋白质,在将铂 (IV) 溶液还原成铂纳米粒子 (PtNPs) 的过程中发挥了重要作用。这些 PtNPs 具有广泛的特征,如 TEM 成像所示,呈球形,粒径介于 20 纳米和 80 纳米之间。紫外可见光谱显示,铂纳米颗粒的最大吸收波长为 256 纳米。此外,该电化学传感器在检测实际样品中的糖化血红蛋白(HbA1c)方面表现出良好的分析性能。
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引用次数: 0
Improving the Industrial Efficiency of Recycling Aluminum Alloy Chips Using Friction Stir Extrusion: Thin Wires Production Process 利用搅拌摩擦挤压提高铝合金芯片回收的工业效率:薄金属丝生产工艺
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-01-29 DOI: 10.1007/s40684-023-00573-w

Abstract

Friction stir extrusion is one of the most promising solid-state chip recycling techniques because of its relative simplicity and high efficiency. One of the most straightforward applications for the process is the production of recycled wires to be utilized as filler material in welding or welding-based additive manufacturing processes, in order to create an industrial symbiosis link, fostering a circular economy and enhancing the technology readiness level of the process. The scalability of the process to the thin wires needed for such applications has not been investigated so far. In this paper, an experimental and numerical analysis was developed. A dedicated numerical model was first validated and then used to design the tool geometry. The effect of tool rotation and tool force on both “standard” mechanical properties, as Ultimate Tensile Strength and microhardness, and specific properties for the envisaged application, as the wrapping around reels with different radii, was investigated. The numerical model results were used to explain the influence of the process parameters on the material flow as well as on the distribution of the primary field variables, namely temperature, strain, and strain rate. Finally, the energy demand was measured, and the specific energy consumption (SEC) was evaluated. It was found that a conical shoulder surface favors the conditions for effective solid bonding. Low values of the extrusion force have detrimental effects on the wires properties as they result either in insufficient strain, or hot cracking defects. High values of extrusion force results in lower SEC, unlocking the potential of the process as symbiotic link enabler.

摘要 搅拌摩擦挤压是最有前途的固态芯片回收技术之一,因为它相对简单、效率高。该工艺最直接的应用之一是生产回收线材,用作焊接或基于焊接的增材制造工艺的填充材料,以建立工业共生联系,促进循环经济,并提高该工艺的技术就绪水平。迄今为止,还没有人研究过该工艺对此类应用所需的薄金属丝的可扩展性。本文进行了实验和数值分析。首先验证了专用的数值模型,然后利用该模型设计了工具的几何形状。研究了工具旋转和工具力对 "标准 "机械性能(如极限拉伸强度和显微硬度)和设想应用的特定性能(如不同半径的卷轴缠绕)的影响。数值模型的结果用于解释工艺参数对材料流动的影响,以及对温度、应变和应变率等主要现场变量分布的影响。最后,对能量需求进行了测量,并评估了特定能量消耗(SEC)。研究发现,锥形肩面有利于有效的固体粘合。挤出力值过低会导致应变不足或热裂纹缺陷,从而对金属丝的性能产生不利影响。高挤出力值会导致较低的 SEC,从而释放出该工艺作为共生连接促进剂的潜力。
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引用次数: 0
Reinforcement Learning-Based Cutting Parameter Dynamic Decision Method Considering Tool Wear for a Turning Machining Process 考虑刀具磨损的基于强化学习的车削加工过程切削参数动态决策方法
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-01-25 DOI: 10.1007/s40684-023-00582-9

Abstract

Cutting parameter optimization is considered as an effective way for energy consumption saving. In the machining process, the tool wear of cutting tools varies with the rise of the number of workpieces, which has a significant effect on cutting parameters decisions. However, most of existing approaches are conducted for a single workpiece, and cannot select the optimal cutting parameters based on the dynamic changes in tool wear. To this end, a reinforcement learning-based cutting parameter dynamic decision (RLCPDD) method is developed for each workpiece adaptive to the change of tool wear. Specifically, the correlation between the energy consumption, cutting parameters, and tool wear is analyzed, and a multi-objective optimization model considering tool wear is formulated. A Markov Decision Process (MDP) can be used for designing the decision-making of cutting parameters for the machining process. The developed RLCPDD is validated by comparative case study. The case study indicates that: (1) the different cutting parameters can be determined for the different tool wear of cutting tool, and (2) the dynamic decision of cutting parameters based on tool wear can further reduce energy consumption, production time, and production cost by 3.87%, 6.36%, and 6.83% compared with the PSO algorithm.

摘要 切削参数优化被认为是节约能耗的有效途径。在加工过程中,刀具的磨损会随着工件数量的增加而变化,这对切削参数的决策有很大影响。然而,现有的大多数方法都是针对单一工件进行的,无法根据刀具磨损的动态变化选择最佳切削参数。为此,我们针对每个工件开发了一种基于强化学习的切削参数动态决策(RLCPDD)方法,以适应刀具磨损的变化。具体来说,分析了能耗、切削参数和刀具磨损之间的相关性,并制定了一个考虑刀具磨损的多目标优化模型。马尔可夫决策过程(MDP)可用于设计加工过程中的切削参数决策。所开发的 RLCPDD 通过比较案例研究进行了验证。案例研究表明(1) 可针对刀具的不同磨损情况确定不同的切削参数,以及 (2) 基于刀具磨损情况的切削参数动态决策与 PSO 算法相比,可进一步降低能耗、生产时间和生产成本,降幅分别为 3.87%、6.36% 和 6.83%。
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引用次数: 0
Multi-objective Optimization Strategy for Continuous Drilling Parameters of Superalloys 超耐热合金连续钻孔参数的多目标优化策略
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-01-24 DOI: 10.1007/s40684-023-00591-8
Qi Wang, Xi Chen, Qinglong An, Ming Chen, Hun Guo, Yafeng He

There are a large number of holes to be machined on aeroengine components such as blisks, casings, etc. In order to ensure position accuracy, these holes usually need to be drilled continuously in one process. To ensure the machining quality of holes, either replacing the cutting tools in advance leads to an increase in manufacturing costs, or adjusting process parameters leads to a decrease in production efficiency, which is difficult to meet the requirements of efficient and low-cost manufacturing. In response to this issue, this paper proposes a multi-objective optimization strategy for the process parameters of porous continuous drilling of superalloys alloys. A unified mathematical model for multi-objective optimization of drilling parameters has been established, and a tool life prediction model based on machining parameters and a machining process energy consumption model have been established as objective functions. The proposed optimization strategy can select different optimization strategies for different optimization objectives, including: maximum tool life, minimum machining energy consumption, and multi-objective drilling parameter optimization. Finally, experimental verification was conducted on the proposed strategy, and the results showed that the proposed optimization strategy can significantly reduce drilling processing energy consumption and increase the service life of drilling tools.

航空发动机部件(如叶盘、壳体等)上需要加工大量的孔。为了确保位置精度,这些孔通常需要在一道工序中连续钻孔。为了保证孔的加工质量,要么提前更换刀具导致制造成本增加,要么调整工艺参数导致生产效率降低,难以满足高效、低成本制造的要求。针对这一问题,本文提出了超合金多孔连续钻孔工艺参数的多目标优化策略。建立了钻孔参数多目标优化的统一数学模型,并建立了基于加工参数的刀具寿命预测模型和加工过程能耗模型作为目标函数。所提出的优化策略可针对不同的优化目标选择不同的优化策略,包括:最大刀具寿命、最小加工能耗和多目标钻孔参数优化。最后,对所提出的优化策略进行了实验验证,结果表明所提出的优化策略能显著降低钻孔加工能耗,提高钻具使用寿命。
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引用次数: 0
Improving mechanical properties of FSWed AA6061-T6 joint by controlling microstructural changes through utilization of stationary shoulder tool in presence of Al2O3 nanoparticles and external cooling 在存在 Al2O3 纳米颗粒和外部冷却的情况下利用固定肩工具控制微结构变化,从而改善 FSWed AA6061-T6 接头的机械性能
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-01-13 DOI: 10.1007/s40684-023-00583-8
Akbar Hosseini, Alireza Fallahi Arezoudar

A novel cooling-assisted stationary shoulder friction stir welding (SSFSW) was employed, using Al2O3 nanoparticles, to achieve high-strength joints in AA6061-T6. The approach resulted in improved mechanical properties, with the optimal joint achieving an efficiency of 91%, representing a substantial increase compared to the 77% efficiency achieved in submerged FSW with rotational shoulder (RFSW). This was accomplished through narrower weld zones, finer grain structure, maintained strengthening precipitates, and more symmetrical temperature and material flow fields. In contrast to RFSW, SSFSW samples exhibited a nugget zone with a grain structure in the nanometer range (900 nm) and a higher density of strengthening precipitates. The underwater SSFSW prevented weakening in the heat-affected zone by reducing the heat input and increasing the cooling rate. As a result, the minimum hardness shifted from the heat affected zone to its boundary with the thermo-mechanically affected zone. The addition of nanoparticles significantly contributed to joint strengthening, and the specimen prepared from the stir zone of the SSFSW-optimum sample achieved a tensile strength of 494 MPa. The primary mechanism of joint strengthening in SSFSW was grain boundary hardening, while quench hardening was the primary mechanism in RFSW. Additionally, the Orowan hardening mechanism had a more significant contribution in SSFSW due to the higher concentration of strengthening precipitates that were retained during the process.

为了在 AA6061-T6 中实现高强度接头,我们采用了一种新颖的冷却辅助固定肩搅拌摩擦焊 (SSFSW),其中使用了 Al2O3 纳米粒子。这种方法提高了机械性能,最佳接头的效率达到 91%,与带旋转肩的埋入式搅拌摩擦焊 (RFSW) 的 77% 的效率相比有了大幅提高。这是通过更窄的焊接区、更细的晶粒结构、保持强化析出物以及更对称的温度场和材料流场实现的。与 RFSW 不同的是,SSFSW 样品显示出晶粒结构在纳米范围(900 纳米)内的金块区,以及更高密度的强化析出物。水下 SSFSW 通过减少热输入和提高冷却速度防止了热影响区的削弱。因此,最低硬度从热影响区转移到了与热机械影响区的边界。纳米颗粒的加入极大地促进了连接强化,从 SSFSW 最佳样品的搅拌区制备的试样达到了 494 兆帕的抗拉强度。在 SSFSW 中,接合强化的主要机制是晶界硬化,而在 RFSW 中,主要机制是淬火硬化。此外,在 SSFSW 中,由于在加工过程中保留了较高浓度的强化析出物,奥罗旺硬化机制的作用更为显著。
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引用次数: 0
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