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Control of the Ionomer Contents in the Electrode Catalyst Layer for Enhanced Performance of Methanol–Water Electrolyzers for Hydrogen Production 控制电极催化剂层中的离子聚合物含量以提高甲醇-水电解槽的制氢性能
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-22 DOI: 10.1007/s40684-024-00618-8
Dong-Hoon Kang, Sungmin Kang, Seog-Young Yoon, Dong-Hyun Peck

Methanol–water electrolysis technology, which electrochemically produces hydrogen using methanol instead of water, has received significant attention given that the substantial amount of power required by conventional water electrolysis can be drastically reduced when using it. This study investigates the electrochemical performance and microstructural characteristics of methanol–water electrolyzers according to the ionomer-to-carbon (I/C) ratio range of 0.5–2.0 in electrode catalyst layers. The lowest voltage at the same current density is observed at an I/C ratio of 1.5 at the anode. When the I/C ratio was 2.0, the voltage was observed to be approximately 25% higher than that at an I/C ratio of 1.5. A microstructural analysis shows a decrease of the specific surface area due to catalyst agglomeration at I/C ratios higher than 1.5. The results of the BET analysis showed a decrease in the surface area with an increase in the I/C ratio. Furthermore, when the I/C ratio exceeds 1.5, separated layers of excessive amounts of ionomer are observed, possibly blocking the electron conduction pathways in the electrode catalyst layer. The energy conversion efficiency of the developed methanol–water electrolyzer was assessed in an current density range of 0.08–0.80 A cm−2, demonstrating values between 81.4% and 92.4%.

甲醇-水电解技术是一种利用甲醇代替水进行电化学制氢的技术,由于使用这种技术可以大幅降低传统水电解所需的大量电能,因此受到了广泛关注。本研究根据电极催化剂层中离子聚合物与碳(I/C)的比率范围 0.5-2.0 研究了甲醇-水电解槽的电化学性能和微观结构特征。阳极的 I/C 比为 1.5 时,相同电流密度下的电压最低。当 I/C 比为 2.0 时,电压比 I/C 比为 1.5 时高约 25%。微观结构分析表明,当 I/C 比大于 1.5 时,催化剂团聚导致比表面积减小。BET 分析结果表明,比表面积随着 I/C 比的增加而减小。此外,当 I/C 比超过 1.5 时,会出现过量离子聚合物的分离层,可能会阻塞电极催化剂层中的电子传导路径。在 0.08-0.80 A cm-2 的电流密度范围内,对所开发的甲醇-水电解槽的能量转换效率进行了评估,结果显示其值在 81.4% 到 92.4% 之间。
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引用次数: 0
Towards Sustainable Manufacturing: A Maturity Assessment for Urban Smart Factory 实现可持续制造:城市智能工厂成熟度评估
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-22 DOI: 10.1007/s40684-023-00554-z
Seyed Mohammad Mehdi Sajadieh, Sang Do Noh

The manufacturing industry is currently confronted with global challenges such as customization demands, climate change, and energy scarcity. To address these challenges and improve efficiency, the industry is exploring the integration of Industry 4.0 and smart manufacturing. One promising approach for incorporating smart factory technology into urban manufacturing is the Urban Smart Factory (USF), which aims to create a sustainable, resilient, and human-centric environment. However, existing Industry 4.0 maturity models are insufficient for evaluating the diverse aspects of the USF. To bridge this gap, this study proposes a novel maturity model specifically designed to assess the integration of smart manufacturing principles and technologies within the USF, with a focus on achieving sustainability, resilience, and human-centricity. The practicality of this model is demonstrated through two case studies from different sectors, showcasing its applicability for evaluating the readiness of manufacturing firms to adopt the USF. Additionally, this research presents potential directions for future academic investigations interested in this topic.

制造业目前面临着定制化需求、气候变化和能源短缺等全球性挑战。为了应对这些挑战并提高效率,该行业正在探索工业 4.0 与智能制造的融合。城市智能工厂(USF)是将智能工厂技术融入城市制造业的一个很有前景的方法,其目的是创造一个可持续发展、有弹性和以人为本的环境。然而,现有的工业 4.0 成熟度模型不足以评估 USF 的各个方面。为了弥补这一不足,本研究提出了一个新颖的成熟度模型,专门用于评估 USF 中智能制造原则和技术的集成,重点是实现可持续性、弹性和以人为本。该模型的实用性通过两个来自不同行业的案例研究得以体现,展示了其在评估制造企业采用 USF 的准备情况方面的适用性。此外,本研究还为今后对这一主题感兴趣的学术研究提出了潜在的方向。
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引用次数: 0
Digital Twin and Deep Reinforcement Learning-Driven Robotic Automation System for Confined Workspaces: A Nozzle Dam Replacement Case Study in Nuclear Power Plants 用于密闭工作空间的数字孪生和深度强化学习驱动的机器人自动化系统:核电站喷嘴坝更换案例研究
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-18 DOI: 10.1007/s40684-023-00593-6
Su-Young Park, Cheonghwa Lee, Suhwan Jeong, Junghyuk Lee, Dohyeon Kim, Youhyun Jang, Woojin Seol, Hyungjung Kim, Sung-Hoon Ahn

Robotic automation has emerged as a leading solution for replacing human workers in dirty, dangerous, and demanding industries to ensure the safety of human workers. However, practical implementation of this technology remains limited, requiring substantial effort and costs. This study addresses the challenges specific to nuclear power plants, characterized by hazardous environments and physically demanding tasks such as nozzle dam replacement in confined workspaces. We propose a digital twin and deep-reinforcement-learning-driven robotic automation system with an autonomous mobile manipulator. The study follows a four-step process. First, we establish a simplified testbed for a nozzle dam replacement task and implement a high-fidelity digital twin model of the real-world testbed. Second, we employ a hybrid visual perception system that combines deep object pose estimation and an iterative closest point algorithm to enhance the accuracy of the six-dimensional pose estimation. Third, we use a deep-reinforcement-learning method, particularly the proximal policy optimization algorithm with inverse reachability map, and a centroidal waypoint strategy, to improve the controllability of an autonomous mobile manipulator. Finally, we conduct pre-performed simulations of the nozzle dam replacement in the digital twin and evaluate the system on a robot in the real-world testbed. The nozzle dam replacement with precise object pose estimation, navigation, target object grasping, and collision-free motion generation was successful. The robotic automation system achieved a (92.0%) success rate in the digital twin. Our proposed method can improve the efficiency and reliability of robotic automation systems for extreme workspaces and other perilous environments.

在肮脏、危险和要求苛刻的行业中,机器人自动化已成为替代人类工人的主要解决方案,以确保人类工人的安全。然而,这项技术的实际应用仍然有限,需要大量的努力和成本。本研究针对核电站所面临的特殊挑战,其特点是危险的环境和体力要求高的任务,如在狭窄的工作空间内更换喷嘴坝。我们提出了一种数字孪生和深度强化学习驱动的机器人自动化系统,该系统带有一个自主移动机械手。这项研究分为四个步骤。首先,我们建立了一个简化的喷嘴水坝更换任务测试平台,并实现了真实世界测试平台的高保真数字孪生模型。其次,我们采用了一种混合视觉感知系统,该系统结合了深度物体姿态估计和迭代最近点算法,以提高六维姿态估计的准确性。第三,我们采用深度强化学习方法,特别是带有反可达性图的近程策略优化算法和向心航点策略,来提高自主移动机械手的可控性。最后,我们在数字孪生中对喷嘴水坝更换进行了预演模拟,并在实际测试平台的机器人上对系统进行了评估。通过精确的物体姿态估计、导航、目标物体抓取和无碰撞运动生成,喷嘴水坝更换获得了成功。机器人自动化系统在数字孪生中的成功率达到了92.0%。我们提出的方法可以提高机器人自动化系统在极端工作空间和其他危险环境中的效率和可靠性。
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引用次数: 0
Effect of Electrolyte Thickness of Thin Film Solid Oxide Fuel Cell on Nanostructure and Performance 薄膜固体氧化物燃料电池电解质厚度对纳米结构和性能的影响
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-15 DOI: 10.1007/s40684-024-00600-4

Abstract

Advances in nanotechnology have enabled solid oxide fuel cells to perform high-efficiency energy conversion at lower operating temperatures than before. In particular, the thin film electrolyte can effectively offset the drop in ion conductivity at a low operating temperature due to a reduced ion path. In this study, the performance difference of solid oxide fuel cells according to the thickness of these thin film electrolytes was compared. Thin film solid oxide fuel cells were fabricated with YSZ electrolytes of 3.3 μm, 4.0 μm, and 4.7 μm thickness using different sputtering deposition times. First, the thickness of the electrolyte affected the gas tightness. The OCV of the cell using the 3.3 μm, 4.0 μm, and 4.7 μm thick electrolyte showed 1.01 V, 1.03 V and 1.05 V respectively. As the sputter deposition time increased, the surface grain size of the YSZ electrolyte also increased, affecting both the electrolyte's ohmic and the electrode's polarization resistance. Therefore, the difference in the thickness of the electrolyte showed a dramatic difference in performance. The cells with 3.3 μm, 4.0 μm, and 4.7 μm thick electrolytes showed performances of 193 mW/cm2, 99 mW/cm2, and 57 mW/cm2, respectively at 500 °C.

摘要 纳米技术的进步使固体氧化物燃料电池能够在比以前更低的工作温度下进行高效的能量转换。特别是,薄膜电解质可以有效抵消低工作温度下由于离子路径减少而导致的离子电导率下降。在这项研究中,比较了固体氧化物燃料电池的性能差异取决于这些薄膜电解质的厚度。利用不同的溅射沉积时间,分别用 3.3 μm、4.0 μm 和 4.7 μm 厚度的 YSZ 电解质制造了薄膜固体氧化物燃料电池。首先,电解质的厚度会影响气密性。使用 3.3 μm、4.0 μm 和 4.7 μm 厚电解质的电池的 OCV 分别为 1.01 V、1.03 V 和 1.05 V。随着溅射沉积时间的增加,YSZ 电解液的表面晶粒尺寸也随之增大,从而影响了电解液的欧姆电阻和电极的极化电阻。因此,电解质厚度的不同会导致性能的巨大差异。电解质厚度分别为 3.3 μm、4.0 μm 和 4.7 μm 的电池在 500 °C 时的性能分别为 193 mW/cm2、99 mW/cm2 和 57 mW/cm2。
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引用次数: 0
Electromagnetic Joining for Multi-material Tubular Components: A Comprehensive Review 多材料管状组件的电磁接合:全面回顾
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-08 DOI: 10.1007/s40684-024-00599-8
Deepak Kumar, Sachin D. Kore, Arup Nandy

Multi-material tubular components have found versatile applications in various products and machine parts because of their ability to offer simultaneous advantages of the constituent materials, such as corrosion-resistance, lightweight, higher strength, and electrical conductivity in one single component. However, creating such components using traditional joining methods possess a lot of challenges due to differences in the properties of joining materials resulting in defects such as hot cracking, embrittlement and intermetallic formation. Therefore, solid-state cold processes like electromagnetic forming can be of great use in joining such multi-material components, referred to as electromagnetic joining (EMJ). This article presents a comprehensive review that considers almost all the major aspects of the subject. This article presents a thorough detailed review of the EMJ processes. It begins by providing a broad overview of the process, tracing its history and development up to the present day, and highlighting its prevalent usage in industry. Following this, an in-depth analysis of the current state of the art in EMJ is given. The working principle is then explained, along with a comprehensive examination of the different stages of the EMJ process. The various factors that influence the quality of the joint and their effects are also discussed in detail. In the end, detailed conclusions are drawn, and future research insights are highlighted.

多种材料的管状部件在各种产品和机械部件中得到了广泛的应用,因为它们能够在单一部件中同时具备各种组成材料的优点,如耐腐蚀、重量轻、强度高和导电性好。然而,由于连接材料的特性不同,导致热裂纹、脆化和金属间形成等缺陷,使用传统连接方法制造此类部件面临着诸多挑战。因此,固态冷工艺(如电磁成形)在连接此类多材料组件(称为电磁连接 (EMJ))方面大有用武之地。本文全面回顾了这一主题的几乎所有主要方面。本文对 EMJ 工艺进行了全面详细的评述。文章首先概述了该工艺,追溯了其历史和发展现状,并重点介绍了其在工业中的普遍应用。随后,对 EMJ 的技术现状进行了深入分析。然后解释了其工作原理,并对 EMJ 工艺的不同阶段进行了全面审查。此外,还详细讨论了影响接头质量的各种因素及其影响。最后,得出了详细的结论,并强调了未来的研究见解。
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引用次数: 0
Flutter-Driven Piezoelectric Wind Energy Harvesting System Based on PVDF Nanofiber for Low Power Applications 基于 PVDF 纳米纤维的扑腾驱动压电风能收集系统,适用于低功耗应用
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-07 DOI: 10.1007/s40684-024-00596-x
Junseo Gu, Donghyun Lee, Heesung Park, Kwanlae Kim

With the increase of low-powered electronic devices, there is growing social interest in environmentally friendly energy sources capable of replacing batteries. In this study, a flutter-driven piezoelectric nanogenerator (FD-PENG) using electrospun PVDF nanofiber was fabricated to create a wind-energy harvesting device. The FD-PENG was composed of a PVDF nanofiber mat (active layer) and Al foil (electrodes), with these components encapsulated by polyethylene terephthalate (PET) film using an ordinary coating machine. The short-circuit current generated from the FD-PENG during a bending test was significantly enhanced by optimizing the electrospinning process and with the proper alignment of the PVDF nanofibers. The dynamic behavior of the FD-PENG with respect to various wind speeds was systematically analyzed by categorizing its motion into four distinct modes. The flapping mode, in which the FD-PENG displays the largest amplitude of oscillation, was induced when wind speed was in the range of (3-4~mathrm{ m}/{text{s}}). The FD-PENG generated open-circuit voltage of approximately 10 V at a wind speed of (4~mathrm{ m}/{text{s}}) and exhibited excellent durability over 10,000 cycles. Using a single FD-PENG, maximum power approaching 14.66 μW was achieved under an external load of 1.1 MΩ. Furthermore, the wind speed inducing the flapping mode was modulated by the shape of the FD-PENG. The results here show that the wind energy harvester can be applied at a wide range of wind speeds by modifying the shape of the FD-PENG.

随着低功耗电子设备的增多,社会对能够替代电池的环保能源的兴趣与日俱增。本研究利用电纺 PVDF 纳米纤维制造了一种扑动驱动压电纳米发电机(FD-PENG),以创建风能收集装置。FD-PENG 由 PVDF 纳米纤维毡(活性层)和铝箔(电极)组成,使用普通涂布机将这些组件封装在聚对苯二甲酸乙二醇酯(PET)薄膜中。通过优化电纺丝工艺和正确排列 PVDF 纳米纤维,FD-PENG 在弯曲测试中产生的短路电流显著提高。系统分析了 FD-PENG 在不同风速下的动态行为,将其运动分为四种不同的模式。当风速在(3-4~mathrm{ m}/{text{s}}) 范围内时,FD-PENG显示出最大振幅的拍打模式。在风速为(4~mathrm{ m}/{text{s}})时,FD-PENG 产生的开路电压约为 10 V,并在 10,000 次循环中表现出良好的耐久性。使用单个 FD-PENG 时,在 1.1 MΩ 的外部负载下可获得接近 14.66 μW 的最大功率。此外,诱发拍打模式的风速可通过 FD-PENG 的形状进行调节。研究结果表明,通过改变 FD-PENG 的形状,风能收集器可应用于各种风速。
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引用次数: 0
Processing Challenges and Delamination Prevention Methods in Titanium-Steel DED 3D Printing 钛钢 DED 三维打印中的加工挑战和分层预防方法
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-07 DOI: 10.1007/s40684-024-00598-9
Alberto Andreu, Sanglae Kim, Insup Kim, Jeong-Hwan Kim, Jinhong Noh, Suhan Lee, Wonhee Lee, Pei-Chen Su, Yong-Jin Yoon

Direct Energy Deposition (DED) 3D printing has gained significant importance in various industries due to its ability to fabricate complex and functional parts with reduced material waste, and to repair existing components. Titanium alloys, known for their exceptional mechanical properties and biocompatibility, are widely used in DED 3D printing applications, where they offer benefits such as lightweight design possibilities and high strength-to-weight ratio. However, given the high material cost of titanium alloys, certain applications can benefit from the coating capabilities of DED to achieve the advantages of titanium on a distinct material substrate. Nevertheless, challenges related to material incompatibility and the development of unwanted brittle phases still affect the successful deposition of titanium alloys on steel substrates with DED 3D printing. This paper investigates the processing challenges and reviews delamination prevention methods, specifically targeting titanium-steel interfaces. In particular, the formation of unwanted brittle Ti–Fe intermetallics and methods to circumvent their formation are explored. The findings of this research contribute to a deeper understanding of the processing challenges and delamination prevention methods in DED 3D printing.

直接能量沉积(DED)三维打印技术能够制造复杂的功能部件,减少材料浪费,还能修复现有部件,因此在各行各业都具有重要意义。钛合金以其优异的机械性能和生物相容性而闻名,被广泛应用于 DED 3D 打印应用中,具有轻质设计和高强度重量比等优点。然而,由于钛合金的材料成本较高,某些应用可以受益于 DED 的涂层功能,在不同的材料基底上实现钛合金的优势。尽管如此,与材料不相容性和不需要的脆性相的发展有关的挑战仍然影响着使用 DED 三维打印技术在钢基底上成功沉积钛合金。本文特别针对钛钢界面,研究了加工过程中的挑战,并回顾了防止分层的方法。特别是探讨了不希望形成的脆性钛-铁金属间化合物以及避免其形成的方法。该研究成果有助于加深对 DED 3D 打印中的加工挑战和分层预防方法的理解。
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引用次数: 0
Feasibility Assessment of Simultaneous Biaxial Test Methodology by Segmentation Approach for a Supersized Wind Turbine Blade Evaluation 通过分段法评估同步双轴测试方法在超大型风力涡轮机叶片评估中的可行性
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-07 DOI: 10.1007/s40684-024-00597-w
Kwangtae Ha, Daeyong Kwon, Cheol Yoo, Kyuhong Kim

This paper outlines an innovative biaxial segment blade test methodology for large wind turbine rotor blades. Today, as a blade size is getting bigger, not only it is hard to find the test facility incorporating blade over 100 m, but also a blade test time and test cost required for certification according to IEC 6140023 are also increased, which could cause the delay of product entrance to wind energy market. The proposed biaxial segment test method mainly aims at improving the efficiency of the fatigue test because fatigue test takes up more than 70% of total test time and 60% of total test time approximately and is also intended to utilize existing test facilities through the segmentation of a large blade. For the feasibility assessment of the novel methodology, the virtual test model of the fatigue test configuration was constructed including virtual mass element, spring element, damping element, blade beam element, and kinematic lever-arm mechanism. Through the optimization process, it was found out that the proposed test methodology has a significant time saving up to 36% compared to conventional blade test method for 90 m blade test, which is even 17% further saving compared to uniaxial segment test. Also, the proposed methodology could save cost by 17% compared to traditional method. Among categories constituting the total cost calculated from 90 m blade case, electricity cost category related to hydraulic pumps necessary to maintain high forces was increased by 7% while labor and material costs reduced by 3% and 3% respectively compared to traditional test approach. The current study also showed that the biaxial segment test method is even more effective for a supersized wind blade. For the 115 m blade, the cost reduction rate was even higher by 5% than one of 90 m blade in addition to the utilization of the existing test facility.

本文概述了一种用于大型风力涡轮机转子叶片的创新型双轴分段叶片测试方法。在叶片尺寸越来越大的今天,不仅很难找到适合 100 米以上叶片的测试设备,而且根据 IEC 6140023 进行认证所需的叶片测试时间和测试成本也在增加,这可能会导致产品延迟进入风能市场。由于疲劳测试占总测试时间的 70% 以上,约占总测试时间的 60%,因此提出的双轴分段测试方法主要是为了提高疲劳测试的效率,同时也是为了通过对大型叶片进行分段测试来利用现有的测试设施。为了评估新方法的可行性,我们构建了疲劳试验配置的虚拟试验模型,包括虚拟质量元件、弹簧元件、阻尼元件、叶片梁元件和运动杠杆臂机构。通过优化过程发现,在 90 米叶片试验中,与传统的叶片试验方法相比,所提出的试验方法显著节省了 36% 的时间,与单轴分段试验相比,甚至还节省了 17% 的时间。此外,与传统方法相比,建议的方法还能节省 17% 的成本。在 90 米叶片案例计算的总成本类别中,与维持高压力所需的液压泵相关的电费类别增加了 7%,而与传统测试方法相比,人工和材料成本分别减少了 3% 和 3%。目前的研究还表明,双轴分段测试方法对超大型风电叶片更为有效。对于 115 米长的叶片,除了利用现有测试设施外,成本降低率甚至比 90 米长的叶片高出 5%。
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引用次数: 0
Experimental Study of Electro-Catalyst Loading on Flexible Polymer Electrolyte Membrane Fuel Cell Performance 电催化剂负载对柔性聚合物电解质膜燃料电池性能的实验研究
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-04 DOI: 10.1007/s40684-024-00603-1
Gyutae Park, Hongnyoung Yoo, Jiwon Baek, Obeen Kwon, Yoonho So, Junghyun Park, Hojae Jang, Hyoun-Myoung Oh, Seonghyeon Yang, Gyuhyeon Kim, Jaeyeon Kim, Taehyun Park

In recent years, flexible electronics has emerged as a promising field that has attracted significant attention as a potential industry of the future. To realize full potential of flexible electronics, flexible power sources are essential. Polymer electrolyte membrane fuel cells (PEMFCs) are well-suited for this purpose, but the high cost of the catalyst, specifically platinum (Pt), is a major hurdle. This study sought to determine the optimal Pt loading for flexible PEMFCs, to reduce waste of catalyst and find a cost-effective solution. The optimal catalyst loading for flexible fuel cells varies depending on the operating environment and conditions. In environments requiring the generation of high power regardless of operating voltage, the optimal Pt loading is 0.1 mgPt cm−2. In contrast, in environments where higher voltage is required with a minimum stacking, the optimal Pt loading is between 0.3 and 0.4 mgPt cm−2. These results demonstrate optimal catalyst loading for flexible fuel cells in consideration of the operating environment and conditions. These results contribute valuable insight into the optimal catalyst loading for various applications, reducing the cost of flexible fuel cells, and paving the way for wider adoption of flexible electronics.

近年来,柔性电子技术作为一个前景广阔的领域异军突起,作为未来的潜在产业备受关注。要充分发挥柔性电子器件的潜力,柔性电源必不可少。聚合物电解质膜燃料电池(PEMFC)非常适合这一目的,但催化剂(特别是铂(Pt))的高成本是一个主要障碍。本研究试图确定柔性 PEMFC 的最佳铂负载量,以减少催化剂的浪费,并找到一种具有成本效益的解决方案。柔性燃料电池的最佳催化剂负载量因运行环境和条件而异。在不考虑工作电压而要求产生高功率的环境中,最佳铂负载量为 0.1 mgPt cm-2。相反,在需要较高电压和最小堆叠的环境中,最佳铂负载量为 0.3 至 0.4 毫克铂 cm-2。这些结果表明,考虑到运行环境和条件,柔性燃料电池的催化剂负载量是最佳的。这些结果有助于深入了解各种应用的最佳催化剂负载,降低柔性燃料电池的成本,并为柔性电子产品的广泛应用铺平道路。
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引用次数: 0
A Printable Flexible and Transparent Heater Applicable to Arbitrary Surfaces, Fabricable by the Soft-Contact Micropatterning of an Ionic Metal Solution 通过离子金属溶液的软接触微图案制造适用于任意表面的可打印柔性透明加热器
IF 4.2 3区 工程技术 Q1 ENGINEERING, MANUFACTURING Pub Date : 2024-03-02 DOI: 10.1007/s40684-024-00601-3
Minwook Kim, Hyunchan Noh, Deokyeong Jeong, Eunchang Jeong, Geonhui Jo, Mingyu Kim, Boohyeon Youn, Kwangjun Kim, Jung Hwan Seo, Jong G. Ok

We demonstrate the facile fabrication of flexible and transparent heating structures via the soft-contact printing and patterning (SCOP) of an ionic metal solution layer, a process generally applicable to flat, flexible, and curved surfaces with scalable sizes. The SCOP process involves the conformal contact of a soft micropattern mold onto an ionic metal solution and mild thermal annealing under controlled temperature and pressure conditions to reduce metal ions into a micropatterned metallic structure. Through parametric optimization of the SCOP pressure and annealing temperature, multilayering with sequential SCOP processes, and airbrush coating of a carbon nanotube solution, a printable metallic micropattern can be tailored to a high-performance transparent heater capable of achieving the temperature up to ~ 125 °C at 8 V and optical transmittance of 80% (achievable > 250 °C at 5 V when multilayered and CNT-reinforced). The scalability and solution processability of the developed process pave the way for the high-throughput eco-friendly fabrication of flexible and transparent heaters on arbitrary surfaces as well as many practical devices, including but not limited to printable electronic and photonic components and wearable sensors as well as warm-up gear.

我们展示了通过离子金属溶液层的软接触印刷和图案化 (SCOP) 工艺轻松制造柔性透明加热结构的方法,该工艺一般适用于具有可扩展尺寸的平面、柔性和曲面。SCOP 工艺包括将软微图案模具与离子金属溶液进行保形接触,并在受控温度和压力条件下进行温和的热退火,以将金属离子还原成微图案金属结构。通过对 SCOP 压力和退火温度进行参数优化、采用连续 SCOP 工艺进行多层叠加以及对碳纳米管溶液进行气刷涂层,可打印金属微图案可被定制为高性能透明加热器,在 8 V 电压下温度可高达约 125 °C,光学透射率可达 80%(在多层叠加和碳纳米管增强的情况下,可在 5 V 电压下达到 > 250 °C)。所开发工艺的可扩展性和解决方案的可加工性为在任意表面上以高通量环保方式制造柔性透明加热器以及许多实用设备铺平了道路,这些设备包括但不限于可打印电子和光子元件、可穿戴传感器以及预热设备。
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引用次数: 0
期刊
International Journal of Precision Engineering and Manufacturing-Green Technology
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