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Electronic and optical properties of double perovskites A2BX6 (A = Cs; B = Sn, and (X = Cl, Br, I.) using modified Becke Johonson potential study 双钙钛矿A2BX6 (A = Cs)的电子光学性质B = Sn, (X = Cl, Br, i)采用改进的Becke johnson电位研究
Pub Date : 2022-10-03 DOI: 10.1117/12.2632942
K. Vamsi Krishna, S. Sritanvi, N. Reddy, S. Reddy, Deepika Nandyala, Anand Pandarinath, G. Nagakumari, R. Mahesh, P. Venugopal Reddy, Vinay Kandrapu
Using the density functional theory, a first-principle approach, the structural, electronic, and optical properties of the double perovskites A2BX6 (A= Cs; B=Sn; X=Cl, Br, and I) were calculated. Calculated parameters lattice constants and band gaps agree with experimental and theoretical observations. The band gap of the A2BX6 compounds is within the optimal range for single-junction photovoltaic applications. The ideal band gap, high dielectric constants, and optimum light absorption of these perovskites make them suitable for high performance single and multi-junction perovskite solar cells
利用密度泛函理论,第一性原理方法,研究了双钙钛矿A2BX6 (a = Cs;B = Sn;X=Cl, Br, I)。计算的参数、晶格常数和带隙与实验和理论观测结果一致。A2BX6化合物的带隙在单结光伏应用的最佳范围内。这些钙钛矿理想的带隙、高介电常数和最佳的光吸收使它们适合高性能的单结和多结钙钛矿太阳能电池
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引用次数: 0
Modulation in charge distribution via polyethylenimine-incorporation into ZnO electron transport layer and its impact on quantum-dots light emitting device stability 聚乙烯亚胺掺入ZnO电子传输层调制电荷分布及其对量子点发光器件稳定性的影响
Pub Date : 2022-10-03 DOI: 10.1117/12.2631581
Dongsub Chung, H. Aziz
Polyethylenimine (PEI) is sometimes used as a passivation layer at the interface between ZnO electron transport layer and quantum-dots emission layer in quantum-dots light emitting devices (QDLEDs). We recently find that blending ZnO with PEI (ZnO:PEI) is advantageous over using it in a separate layer in terms of device stability. In this work, a comparative study between the ZnO:PEI with a neat ZnO ETL is conducted. The ZnO:PEI ETL results in improvement in both EQE and lifetime of QDLEDs compared to the ZnO ETL. By replacing the ZnO ETL with the ZnO:PEI ETL, delayed EL measurements reveal changes in charge distribution across the QDLED. Applying a reverse bias pulse shows that the reversible delayed EL components in the QDLED with the ZnO:PEI ETL stemmed from the electrons placed in a hole transport layer (HTL). The electrons in the HTL induce an annihilation of accumulated holes at the QD EML/HTL that can be a cause of device degradation. The result provides a new insight into the importance of managing charge distribution across the QDLED via ZnO ETL modification for realizing highly stable QDLEDs.
在量子点发光器件(qdled)中,聚乙烯亚胺(PEI)有时被用作ZnO电子传输层和量子点发射层之间的钝化层。我们最近发现,在器件稳定性方面,ZnO与PEI (ZnO:PEI)混合比在单独的层中使用更有利。本文对ZnO:PEI与ZnO ETL进行了对比研究。与ZnO ETL相比,ZnO:PEI ETL提高了qdled的EQE和寿命。通过将ZnO ETL替换为ZnO:PEI ETL,延迟EL测量揭示了qdle上电荷分布的变化。施加反向偏置脉冲表明,ZnO:PEI ETL的QDLED中的可逆延迟EL分量源于放置在空穴传输层(HTL)中的电子。HTL中的电子诱导QD EML/HTL中积累的空穴湮灭,这可能是导致器件退化的原因。该结果为通过ZnO ETL修饰来管理电荷分布对于实现高稳定QDLED的重要性提供了新的见解。
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引用次数: 0
Liquid crystal beam steering devices for LiDAR applications 用于激光雷达的液晶光束转向装置
Pub Date : 2022-10-03 DOI: 10.1117/12.2633683
Yannanqi Li, Zhenyi Luo, Shin‐Tson Wu
A novel beam steering angle expander is demonstrated by cascading two polymeric liquid crystal polarization lenses with different diopters. The lens module functions as a planar telescope, which offers some attractive features such as high precision, lightweight, and low cost. The magnifier offers wide-angle, continuous steering when integrated with an active fine-angle beam steering device. The potential application for LiDAR is emphasized.
通过级联两个不同屈光度的聚合物液晶偏振透镜,展示了一种新型的光束转向角扩展器。该透镜模块具有平面望远镜的功能,具有精度高、重量轻、成本低等特点。该放大镜提供广角,连续转向时集成了一个主动细角光束转向装置。强调了激光雷达的潜在应用。
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引用次数: 1
Diffraction of obliquely incident light at oblique helicoidal cholesteric 斜入射光在斜螺旋形胆甾体上的衍射
Pub Date : 2022-10-03 DOI: 10.1117/12.2637321
M. Mrukiewicz, O. Iadlovska, S. Shiyanovskii, O. Lavrentovich
We demonstrate experimentally that diffraction of light incident obliquely at the oblique helicoidal cholesteric (ChOH) structure results in scattering at both the half- (P/2) and the full pitch (P) periodicities. Transmission spectra at P and P/2 are observed in the Vis spectral range, tunable by the electric field and the angle of light incidence. Diffraction at P/2 shows two distinct spectral bands for p- and s-polarized incident light. Diffraction at P is a single wide band. Unique optical properties of ChOH are attractive for applications such as electrically tunable band-pass filters, optical rotators, and beam-steering devices.
我们通过实验证明,斜入射于斜螺旋胆甾体(ChOH)结构的光的衍射会导致半(P/2)和全(P)周期的散射。P和P/2处的透射光谱在可见光谱范围内,可通过电场和光入射角度进行调节。P/2衍射显示P偏振和s偏振入射光有两个不同的光谱带。P点的衍射是一个单一的宽带。ChOH独特的光学特性对电可调谐带通滤波器、光学旋转器和光束导向装置等应用具有吸引力。
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引用次数: 0
Toward chemical sensing: an electrochemical study of the selectivity trend of metal phthalocyanines 走向化学感应:金属酞菁选择性趋势的电化学研究
Pub Date : 2022-10-03 DOI: 10.1117/12.2633101
M. S. Hossain, A. Takshi
Metalated phthalocyanines (MPcs) are a special class of organic semiconductors having unique chemical structures and properties. The material’s conjugated 18-π electron structure enables a strong fusion with carbon nano tubes (CNTs) which have a highly delocalized π electron structure. This strong binding between MPc and CNT facilitates the study of the material in an electrochemical cell. Here in this account, we report a novel method of identifying the selectivity and sensitivity trend of several MPcs with different metal cores through an electrochemical approach. Sensor electrode was prepared by drop casting the MPc solution on paper strips coated with CNT ink, and then tested in electrochemical cell in a 2-electrode fashion. The nature of the redox reactions between MPc and the VOC analytes (i.e., acetone, ethanol, isopropanol, and methanol) were studied through cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry. Four different metalated phthalocyanines (CoPc, CuPc, MgPc, and ZnPc) are studied here. Experimental results suggest large shift in conductivity in the CoPc sensor upon exposure to ethanol, MgPc sensor upon exposure to isopropanol, and ZnPc sensor upon exposure to acetone.
金属化酞菁(MPcs)是一类特殊的有机半导体,具有独特的化学结构和性能。该材料的共轭18-π电子结构使其能够与具有高度离域π电子结构的碳纳米管(CNTs)进行强聚变。MPc和碳纳米管之间的这种强结合促进了电化学电池中材料的研究。在本文中,我们报告了一种通过电化学方法识别几种不同金属芯的MPcs的选择性和灵敏度趋势的新方法。将MPc溶液滴注在涂有碳纳米管油墨的纸条上制备传感器电极,并在电化学电池中以双电极方式进行测试。通过循环伏安法(CV)、电化学阻抗谱法(EIS)和计时电流法研究了MPc与VOC分析物(即丙酮、乙醇、异丙醇和甲醇)之间氧化还原反应的性质。本文研究了四种不同的金属化酞菁(CoPc、CuPc、MgPc和ZnPc)。实验结果表明,CoPc传感器在暴露于乙醇时,MgPc传感器暴露于异丙醇时,ZnPc传感器暴露于丙酮时,电导率发生了很大的变化。
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引用次数: 0
Solubility and molecular alignment behavior of liquid-crystalline polymers by scanning wave photopolymerization 扫描波光聚合液晶聚合物的溶解度和分子排列行为
Pub Date : 2022-10-03 DOI: 10.1117/12.2635808
T. Ishiyama, Y. Kobayashi, H. Nakamura, M. Aizawa, K. Hisano, S. Kubo, A. Shishido
Functional soft materials with controlled molecular alignment are attracting much attention in various fields due to their excellent flexibility and functional properties. Among conventional alignment methods, mechanical methods such as rubbing the polymer surface are well-known as a facile route to align various molecules. Besides, photoalignment methods, using photoresponsive molecules and polarized light, enable precise alignment control towards advanced functions. As a novel alignment method combining the advantages of both mechanical and photoalignment methods, we have developed scanning wave photopolymerization (SWaP) where phototriggered molecular diffusion is applied to align molecules. Since it uses the molecular diffusion as a driving force for alignment control, SWaP has the potential to align a variety of molecules. For further exploration of the mechanism, it is necessary to understand the polymer properties; thus, the synthesis of polymers applicable to solution-based analyses is highly desired. In this study, we conducted SWaP to synthesize soluble liquid-crystalline polymer films with one-dimensional alignment. Furthermore, we compared the molecular alignment behavior between SWaP and the conventional rubbing alignment technique using a soluble polymer, and revealed that only SWaP can induce a unidirectional molecular alignment in film.
具有可控分子取向的功能软材料以其优异的柔韧性和功能特性在各个领域受到广泛关注。在传统的排列方法中,机械方法,如摩擦聚合物表面,是众所周知的一种简单的方法来排列各种分子。此外,光校准方法利用光响应分子和偏振光,实现了对高级功能的精确校准控制。扫描波光聚合(SWaP)是一种结合机械和光定向两种方法优点的新型定向方法,利用光触发分子扩散技术对分子进行定向。由于SWaP利用分子扩散作为驱动分子对分子进行排列控制,因此SWaP具有对多种分子进行排列的潜力。为了进一步探索其机理,有必要了解聚合物的性质;因此,聚合物的合成适用于基于溶液的分析是非常需要的。在这项研究中,我们通过SWaP来合成具有一维排列的可溶性液晶聚合物薄膜。此外,我们比较了SWaP和传统的摩擦取向技术在可溶聚合物中的分子取向行为,发现只有SWaP才能诱导膜中的单向分子取向。
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引用次数: 0
Stability of fiber-based organic electrochemical transistors with a gel electrolyte for wearable electronics 可穿戴电子产品用凝胶电解质纤维基有机电化学晶体管的稳定性
Pub Date : 2022-10-03 DOI: 10.1117/12.2633175
Nestor O. Marquez Rios, A. Takshi
With the increasing interest in wearable electronics, still, building electronic circuits on fabrics is challenging. Among different approaches, fiber shape electrochemical transistors are potentially suitable for various applications, particularly for bioelectronics. Fiber-based devices are getting popular because of their low fabrication cost, lightweight, and mechanical flexibility without losing their properties as sensors and transistors. In this work, we have studied an organic electrochemical transistor made from two conductive threads with a gel electrolyte. The transistor was tested when it was exposed to an acidic solution which then showed a change in the drain current. The results from testing the conductive thread between the drain and source reviled the effect of the pH on the PEDOT:PSS coating used as the semiconducting material in the transistor design. The results are encouraging for the applications in new low-cost, flexible bioelectronics sensing devices.
随着人们对可穿戴电子产品的兴趣日益浓厚,在织物上构建电子电路仍是一项挑战。在不同的方法中,光纤形状的电化学晶体管有可能适用于各种应用,特别是生物电子学。基于光纤的设备越来越受欢迎,因为它们制造成本低、重量轻、机械灵活性好,同时又不失去传感器和晶体管的特性。在这项工作中,我们研究了一种由两根导电线和凝胶电解质制成的有机电化学晶体管。当晶体管暴露在酸性溶液中时,测试结果显示漏极电流发生了变化。测试漏极和源极之间的导电线的结果揭示了pH值对晶体管设计中用作半导体材料的PEDOT:PSS涂层的影响。这一结果对于在新型低成本、柔性生物电子传感装置中的应用是令人鼓舞的。
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引用次数: 1
Blue LED light enhances the growth of Cinchona officinalis L. cultured in vitro 蓝光LED光对金鸡纳体外培养的生长有促进作用
Pub Date : 2022-10-03 DOI: 10.1117/12.2633167
Oscar Vivanco-Galván, Yuliana Jiménez-Gaona, D. Castillo, Hernán Lucero
Cinchona officinalis L. is one of the most important and historically medicinal plants from which the antimalarial drug known as quinine is extracted. It is currently an endangered species. Thus, in vitro culture techniques are applied to propagate the species and to evaluate the effect of artificial light on the physiological development of C. Officinalis L. under controlled conditions. In that sense, the current study has determined the impact of blue led light on the enhancement of growth and number of shoots of Cinchona officinalis L. In vitro explants of C. Officinalis L were cultured on Murashige and Skoog (MS) medium and cultured under the white (control) and blue light-emitting diodes (LED) light. After eight weeks, growth and bud numbers were determined in C. officinalis L. Interestingly, blue light treatment increased the shoot length and bud numbers in comparison with the control. Incorporating blue light during in vitro propagation of C. Officinalis L can be a beneficial way to increase plant quality. Future perspectives could include the impact of blue light on the production of secondary metabolites, activities of antioxidant enzymes, and protein expression of in vitro-grown C. Officinalis L.
金鸡纳(chinona officinalis L.)是历史上最重要的药用植物之一,抗疟疾药物奎宁(quinine)就是从这种植物中提取的。它目前是濒临灭绝的物种。因此,本文采用体外培养技术对该物种进行了繁殖,并在控制条件下评价了人工光对Officinalis L.生理发育的影响。因此,本研究确定了蓝色led光对金鸡纳生长和芽数的促进作用。将金鸡纳离体培养在Murashige和Skoog (MS)培养基上,在白色(对照)和蓝色发光二极管(led)光下培养。8周后,测定了山药的生长和芽数。有趣的是,与对照相比,蓝光处理增加了山药的茎长和芽数。在Officinalis L离体繁殖过程中加入蓝光是提高植株品质的有效途径。未来的研究方向可能包括蓝光对体外培养的Officinalis L.次生代谢产物的产生、抗氧化酶的活性和蛋白质表达的影响。
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引用次数: 2
Crystallized 2D perovskite for x-ray and visible light detection applications 结晶二维钙钛矿用于x射线和可见光探测应用
Pub Date : 2022-10-03 DOI: 10.1117/12.2632581
Lebin Nie, Jiayun Sun, Gang Li, Kai Wang, W. Choy
Two-dimensional (2D) perovskites with organic spacer ligands are promising materials with superior stability and diversity for various photovoltaic devices. While traditional perovskite precursor solutions using high boiling point solvents easily cause poor uniformity, we demonstrate a new method for rapid crystallization of 2D perovskite by adopting low boiling point solvents. Our results show that 2D perovskite films have a high quality and their processing is simplified and shortened. Photoconductors are made based on the 2D perovskite films and applied in visible light and X-ray detection effectively. These findings suggest the easily processed 2D perovskites promising for practical optoelectronic applications.
具有有机间隔配体的二维(2D)钙钛矿具有优异的稳定性和多样性,是用于各种光伏器件的有前途的材料。传统的钙钛矿前驱体溶液采用高沸点溶剂容易造成均匀性差的问题,本文提出了一种采用低沸点溶剂快速结晶二维钙钛矿的新方法。结果表明,制备的二维钙钛矿薄膜质量高,加工工艺简化、缩短。在二维钙钛矿薄膜的基础上制备了光导体,并有效地应用于可见光和x射线探测。这些发现表明,易于加工的二维钙钛矿具有实际光电应用的前景。
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引用次数: 0
Cholesteric ring resonators 胆甾环谐振器
Pub Date : 2022-10-03 DOI: 10.1117/12.2632230
J. Schmidtke
Cholesteric liquid crystals (CLCs) show a polarization-sensitive photonic band gap (selective reflection band), the band edges exhibiting resonant optical modes for circularly polarized light. In a theoretical treatment, we discuss the optics of cholesteric ring resonators, where the light is confined to a closed path along the cholesteric helix, which is bent into a circle. Apart from the well-known cavity and band-edge resonances, introduction of an artificial defect (defect layer and/or discontinuity of the director orientation) gives rise to additional resonant modes inside the photonic band gap (defect modes). Such systems show a unique combination of ring cavity, band edge, and defect mode resonances.
胆甾型液晶(CLCs)表现出偏振敏感的光子带隙(选择性反射带),带边缘表现出圆偏振光的共振光学模式。在理论处理中,我们讨论了胆甾环谐振器的光学,其中光被限制在沿着胆甾螺旋的封闭路径上,胆甾螺旋弯曲成一个圆。除了众所周知的腔和带边共振外,引入人工缺陷(缺陷层和/或定向器方向的不连续)会在光子带隙内产生额外的共振模式(缺陷模式)。这样的系统显示出独特的环形腔、带边缘和缺陷模共振的组合。
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引用次数: 0
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Organic Photonics + Electronics
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