首页 > 最新文献

Organic Photonics + Electronics最新文献

英文 中文
High-efficiency and stable blue hyperfluorescence organic light-emitting diode 高效稳定的蓝色高荧光有机发光二极管
Pub Date : 2022-10-03 DOI: 10.1117/12.2632333
Chin-Yiu Chan, Yi‐Ting Lee, Youichi Tsuchiya, H. Nakanotani, C. Adachi
Organic light-emitting diodes (OLEDs) are a promising light-emitting technology useful for various display applications1,2. Despite great progress in this field3-12, there is an ongoing challenge to realize high performance blue OLEDs with efficiency, good color purity, and device lifetime. Here, we report pure-blue (CIEx,y color coordinates of [0.13, 0.16]) OLEDs with high-efficiency (external quantum efficiency of 32 % at 1000 cd m–2 ), narrow-emission (full width half maximum of 19 nm), and good stability (LT95 of 18 hours at an initial luminance of 1000 cd m–2 ). The design is based on a two-unit stacked tandem hyperfluorescence (HF)-OLED with an improved singlet-excited energy transfer process from a sky-blue TADF assistant dopant (AD) (HDT-1) to a pure-blue terminal emitter (TE) (v-DABNA). Furthermore, the effect of dopant concentration of terminal emitter on the device performance of hyperfluorescence OLEDs is studied. Device shows a better color purity when dopant concentration is increased. On the other hand, new hyperfluorescence OLEDs have been fabricated, in which device stability has been extended with a new molecular design of TE.
有机发光二极管(oled)是一种很有前途的发光技术,可用于各种显示应用1,2。尽管该领域取得了很大进展,但实现高效、高颜色纯度和器件寿命的高性能蓝色oled仍然存在挑战。在这里,我们报道了纯蓝色(CIEx,y色坐标为[0.13,0.16])oled,具有高效率(在1000 cd m-2时外量子效率为32%),窄发射(全宽度一半最大值为19 nm)和良好的稳定性(在1000 cd m-2的初始亮度下LT95为18小时)。该设计基于双单元堆叠串联高荧光(HF)-OLED,具有改进的单重激发能量转移过程,从天蓝色TADF辅助掺杂剂(AD) (HDT-1)到纯蓝色终端发射器(TE) (v-DABNA)。进一步研究了终端发射极掺杂剂浓度对高荧光oled器件性能的影响。随着掺杂剂浓度的增加,器件的颜色纯度也随之提高。另一方面,制备了新的高荧光oled,其中新的TE分子设计扩展了器件的稳定性。
{"title":"High-efficiency and stable blue hyperfluorescence organic light-emitting diode","authors":"Chin-Yiu Chan, Yi‐Ting Lee, Youichi Tsuchiya, H. Nakanotani, C. Adachi","doi":"10.1117/12.2632333","DOIUrl":"https://doi.org/10.1117/12.2632333","url":null,"abstract":"Organic light-emitting diodes (OLEDs) are a promising light-emitting technology useful for various display applications1,2. Despite great progress in this field3-12, there is an ongoing challenge to realize high performance blue OLEDs with efficiency, good color purity, and device lifetime. Here, we report pure-blue (CIEx,y color coordinates of [0.13, 0.16]) OLEDs with high-efficiency (external quantum efficiency of 32 % at 1000 cd m–2 ), narrow-emission (full width half maximum of 19 nm), and good stability (LT95 of 18 hours at an initial luminance of 1000 cd m–2 ). The design is based on a two-unit stacked tandem hyperfluorescence (HF)-OLED with an improved singlet-excited energy transfer process from a sky-blue TADF assistant dopant (AD) (HDT-1) to a pure-blue terminal emitter (TE) (v-DABNA). Furthermore, the effect of dopant concentration of terminal emitter on the device performance of hyperfluorescence OLEDs is studied. Device shows a better color purity when dopant concentration is increased. On the other hand, new hyperfluorescence OLEDs have been fabricated, in which device stability has been extended with a new molecular design of TE.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"17 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123183263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mycobacterium tuberculosis detection and genotyping using molecular probe-based biosensor 基于分子探针生物传感器的结核分枝杆菌检测及基因分型
Pub Date : 2022-10-03 DOI: 10.1117/12.2634320
M. Berezovskaya, D. Gorbenko
Nucleic acid analysis is one of the most promising approaches in modern diagnostics, however it usually requires expensive amplification equipment. In this study, we propose and approve a method for bacterial pathogens detection and genotyping using a molecular probe-based biosensor without amplification. The sensor consists of a molecular beacon probe as a signal reporter with a fluorophore and a quencher attached to it, and two DNA strands, which have fragments complementary to the reporter and to the analyzed nucleic acid (analyte). The M. tuberculosis HigA1 gene was detected using this sensor, and a point mutation associated with antibiotic resistance was discriminated. As an additional demonstration of the applicability of the method without amplification, E.Coli 16S rRNA was detected. Amplification-free sample detection has been further tested and achieved.
核酸分析是现代诊断中最有前途的方法之一,但它通常需要昂贵的扩增设备。在这项研究中,我们提出并批准了一种基于分子探针的生物传感器的细菌病原体检测和基因分型方法。该传感器包括一个分子信标探针作为信号报告器,其上附有一个荧光团和一个淬灭器,以及两条DNA链,其片段与报告器和被分析的核酸(分析物)互补。利用该传感器检测结核分枝杆菌HigA1基因,并鉴定出与抗生素耐药性相关的点突变。为了进一步证明该方法无需扩增的适用性,我们检测了大肠杆菌16S rRNA。进一步测试并实现了无扩增样品检测。
{"title":"Mycobacterium tuberculosis detection and genotyping using molecular probe-based biosensor","authors":"M. Berezovskaya, D. Gorbenko","doi":"10.1117/12.2634320","DOIUrl":"https://doi.org/10.1117/12.2634320","url":null,"abstract":"Nucleic acid analysis is one of the most promising approaches in modern diagnostics, however it usually requires expensive amplification equipment. In this study, we propose and approve a method for bacterial pathogens detection and genotyping using a molecular probe-based biosensor without amplification. The sensor consists of a molecular beacon probe as a signal reporter with a fluorophore and a quencher attached to it, and two DNA strands, which have fragments complementary to the reporter and to the analyzed nucleic acid (analyte). The M. tuberculosis HigA1 gene was detected using this sensor, and a point mutation associated with antibiotic resistance was discriminated. As an additional demonstration of the applicability of the method without amplification, E.Coli 16S rRNA was detected. Amplification-free sample detection has been further tested and achieved.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"12212 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130830861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Completely printed flexible carbon nanotube based transistor using poly-vinyl alcohol (PVA) as gate dielectric via aerosol jet printing 以聚乙烯醇(PVA)为栅极介质,采用气溶胶喷射打印技术完全打印出柔性碳纳米管晶体管
Pub Date : 2022-10-03 DOI: 10.1117/12.2633716
B. Mishra, C. Howlader, Yihong Chen
The availability of printable dielectric materials and their printability is one of the major roadblocks to printed flexible electronics. Here, we report the performance of fully printed field-effect transistors using polyvinyl alcohol (PVA) as dielectric and carbon nanotube (CNT) as a semiconducting layer. As fewer numbers of research are available on printed PVA films, here we investigate ink formulation and printing parameters for PVA and their effects on device performances. Aerosol jet Printer was used to obtain a highly dense CNT network and pinhole-free thin PVA dielectric layer that resulted in a high on/off ratio and drain current. This completely printed transistor with polymer dielectric will be a great contribution to flexible electronic devices.
可印刷介质材料的可用性及其可印刷性是印刷柔性电子的主要障碍之一。本文报道了聚乙烯醇(PVA)作为介质,碳纳米管(CNT)作为半导体层的全印刷场效应晶体管的性能。由于对印刷PVA薄膜的研究较少,本文研究了PVA的油墨配方和印刷参数及其对器件性能的影响。使用气溶胶喷射打印机获得高密度碳纳米管网络和无针孔的薄PVA介电层,从而获得高开/关比和漏极电流。这种完全印刷的聚合物电介质晶体管将对柔性电子器件做出巨大贡献。
{"title":"Completely printed flexible carbon nanotube based transistor using poly-vinyl alcohol (PVA) as gate dielectric via aerosol jet printing","authors":"B. Mishra, C. Howlader, Yihong Chen","doi":"10.1117/12.2633716","DOIUrl":"https://doi.org/10.1117/12.2633716","url":null,"abstract":"The availability of printable dielectric materials and their printability is one of the major roadblocks to printed flexible electronics. Here, we report the performance of fully printed field-effect transistors using polyvinyl alcohol (PVA) as dielectric and carbon nanotube (CNT) as a semiconducting layer. As fewer numbers of research are available on printed PVA films, here we investigate ink formulation and printing parameters for PVA and their effects on device performances. Aerosol jet Printer was used to obtain a highly dense CNT network and pinhole-free thin PVA dielectric layer that resulted in a high on/off ratio and drain current. This completely printed transistor with polymer dielectric will be a great contribution to flexible electronic devices.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"62 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121030667","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Photorefractive effect of smectic liquid crystals and their application to laser ultrasonic remote sensing 近晶液晶的光折变效应及其在激光超声遥感中的应用
Pub Date : 2022-10-03 DOI: 10.1117/12.2633374
T. Sasaki, Takaaki Yagami, Toshinobu Takashi, Kai Suzuki, Gouta Ikeda, Y. Ishii, K. Le, Y. Naka
The photorefractive effect of flexoelectric smectic liquid crystal mixtures was investigated and applied to a laser ultrasonic measurement. Smectic liquid crystal mixtures, composed of smectic-C liquid crystals, photoconductive chiral compounds, and a sensitizer, are known to exhibit a fast photorefractive effect. The principle of the ultrasonic measurement is that a nanosecond laser pulse is shot on an object to cause an ultrasonic vibration, a continuous laser beam is irradiated on the object, and the ultrasonic variation is detected using photorefractive two-beam coupling. This method can be used to investigate the thickness and the internal structure of an object without contact.
研究了挠性电致晶液晶混合物的光折变效应,并将其应用于激光超声测量。由smic - c液晶、光导手性化合物和敏化剂组成的smic液晶混合物具有快速的光折变效应。超声波测量的原理是在物体上发射纳秒级激光脉冲引起超声振动,连续激光束照射在物体上,利用光折变双光束耦合检测超声变化。该方法可用于研究无接触物体的厚度和内部结构。
{"title":"Photorefractive effect of smectic liquid crystals and their application to laser ultrasonic remote sensing","authors":"T. Sasaki, Takaaki Yagami, Toshinobu Takashi, Kai Suzuki, Gouta Ikeda, Y. Ishii, K. Le, Y. Naka","doi":"10.1117/12.2633374","DOIUrl":"https://doi.org/10.1117/12.2633374","url":null,"abstract":"The photorefractive effect of flexoelectric smectic liquid crystal mixtures was investigated and applied to a laser ultrasonic measurement. Smectic liquid crystal mixtures, composed of smectic-C liquid crystals, photoconductive chiral compounds, and a sensitizer, are known to exhibit a fast photorefractive effect. The principle of the ultrasonic measurement is that a nanosecond laser pulse is shot on an object to cause an ultrasonic vibration, a continuous laser beam is irradiated on the object, and the ultrasonic variation is detected using photorefractive two-beam coupling. This method can be used to investigate the thickness and the internal structure of an object without contact.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"163 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122551605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the modeling of organic electrochemical transistors 有机电化学晶体管的建模研究
Pub Date : 2022-10-03 DOI: 10.1117/12.2633291
Lukas M. Bongartz, Matteo Cucchi, K. Leo, H. Kleemann
Due to their synaptic functionality based on interacting electronic and ionic charge carriers, organic electrochemical transistors (OECTs) appeal as highly attractive candidates for a new generation of organic neuromorphic devices. Despite their acknowledged application potential, little is still known about the underlying physics and traditional transistor models fail to accurately describe the phenomena observed. This deficiency comes in part from the fact that such models are largely based on an electrostatic approach for metal-oxide-semiconductor field-effect transistors (MOSFETs), which is a very strong abstraction to the volumetric and complex processes in OECTs. On the other hand, material studies reveal the potential of an alternative approach, taking into account the electrochemical processes by means of thermodynamics and thus considering the OECTs intricacy. These two approaches oppose each other in explaining OECTs, neither of which can claim a comprehensive explanation of the transistor on its own so far. A unification of the two sides, on the other hand, could come much closer to a substantial explanation and provide a more accurate picture of reality. After giving a short overview of the most significant concepts of the two explanatory directions, a framework is presented that might come very close to this merger, as it accurately reproduces essential transfer properties of OECTs in terms of thermodynamics for the first time.
由于其基于相互作用的电子和离子载流子的突触功能,有机电化学晶体管(OECTs)成为新一代有机神经形态器件的极具吸引力的候选者。尽管它们具有公认的应用潜力,但人们对其潜在的物理特性知之甚少,传统的晶体管模型也无法准确描述所观察到的现象。这种缺陷部分来自于这样一个事实,即这些模型主要基于金属氧化物半导体场效应晶体管(mosfet)的静电方法,这是对OECTs中体积和复杂过程的非常强的抽象。另一方面,材料研究揭示了另一种方法的潜力,通过热力学考虑到电化学过程,从而考虑到OECTs的复杂性。这两种方法在解释oect时相互对立,到目前为止,这两种方法都不能单独对晶体管进行全面的解释。另一方面,双方的统一可能更接近于一个实质性的解释,并提供一个更准确的现实图景。在对两个解释方向中最重要的概念进行简要概述之后,提出了一个可能非常接近这种合并的框架,因为它第一次从热力学的角度准确地再现了OECTs的基本转移特性。
{"title":"On the modeling of organic electrochemical transistors","authors":"Lukas M. Bongartz, Matteo Cucchi, K. Leo, H. Kleemann","doi":"10.1117/12.2633291","DOIUrl":"https://doi.org/10.1117/12.2633291","url":null,"abstract":"Due to their synaptic functionality based on interacting electronic and ionic charge carriers, organic electrochemical transistors (OECTs) appeal as highly attractive candidates for a new generation of organic neuromorphic devices. Despite their acknowledged application potential, little is still known about the underlying physics and traditional transistor models fail to accurately describe the phenomena observed. This deficiency comes in part from the fact that such models are largely based on an electrostatic approach for metal-oxide-semiconductor field-effect transistors (MOSFETs), which is a very strong abstraction to the volumetric and complex processes in OECTs. On the other hand, material studies reveal the potential of an alternative approach, taking into account the electrochemical processes by means of thermodynamics and thus considering the OECTs intricacy. These two approaches oppose each other in explaining OECTs, neither of which can claim a comprehensive explanation of the transistor on its own so far. A unification of the two sides, on the other hand, could come much closer to a substantial explanation and provide a more accurate picture of reality. After giving a short overview of the most significant concepts of the two explanatory directions, a framework is presented that might come very close to this merger, as it accurately reproduces essential transfer properties of OECTs in terms of thermodynamics for the first time.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"176 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121044487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of some smectic liquid crystals’ retardation switching behavior on beam steering performance 某些近晶液晶的延迟开关特性对光束转向性能的影响
Pub Date : 2022-10-03 DOI: 10.1117/12.2632870
A. Mochizuki
Influence of in-plane only retardation switching of an SSD (Smectic Single Domain) liquid crystal both on light diffraction efficiency and beam steering performance has been investigated. An SSD liquid crystal’s in-plane only retardation switching keeping its molecular director always perpendicular to the externally applied electric field is reasonably assumed to provide unique performance both on light diffraction and beam steering. The in-plane only retardation switching was confirmed with polarimetry and light throughput dynamic profiles both for linearly and circularly polarized incident beams. Using the SSD liquid crystal, < 1 ms response with up to 6 degrees steering has been confirmed.
研究了平面内纯延迟开关对单畴液晶衍射效率和光束导向性能的影响。我们合理地假设固态硬盘液晶的面内延迟开关使其分子方向始终垂直于外加电场,从而提供了独特的光衍射和光束导向性能。通过对线偏振和圆偏振入射光束的偏振和光通量动态分析,证实了仅面内延迟开关的存在。使用固态硬盘液晶,响应小于1毫秒,高达6度转向已被证实。
{"title":"Influence of some smectic liquid crystals’ retardation switching behavior on beam steering performance","authors":"A. Mochizuki","doi":"10.1117/12.2632870","DOIUrl":"https://doi.org/10.1117/12.2632870","url":null,"abstract":"Influence of in-plane only retardation switching of an SSD (Smectic Single Domain) liquid crystal both on light diffraction efficiency and beam steering performance has been investigated. An SSD liquid crystal’s in-plane only retardation switching keeping its molecular director always perpendicular to the externally applied electric field is reasonably assumed to provide unique performance both on light diffraction and beam steering. The in-plane only retardation switching was confirmed with polarimetry and light throughput dynamic profiles both for linearly and circularly polarized incident beams. Using the SSD liquid crystal, < 1 ms response with up to 6 degrees steering has been confirmed.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"54 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132968873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The role of OLED emissive layer polarization in sub-turn-on charge accumulation OLED发射层极化在亚导通电荷积累中的作用
Pub Date : 2022-10-03 DOI: 10.1117/12.2633591
E. Pakhomenko, R. Holmes
Preferential alignment of molecular permanent dipole moments, known as spontaneous orientation polarization (SOP), is present in many materials employed in the active layers of organic light-emitting devices (OLEDs). This phenomenon leads to the formation of bound polarization charge, which is compensated by polaron accumulation at voltages below turn-on. While most prior work has focused on polarization in the device electron transport layer (ETL), here we examine the impact of emissive layer SOP by systematically probing polaron accumulation and exciton-polaron quenching in phosphorescent OLEDs. To gain a deeper understanding of polaron accumulation, device capacitance is systematically probed as a function of voltage across samples with polar and nonpolar emissive layers. We find that capacitance measurements can be used to track not only the number of accumulated charges, but also its location within the device active layers. This study provides an analysis framework that allows further insights on the charge accumulation process in OLEDs, thus improving our understanding of SOP in OLEDs
分子永久偶极矩的优先排列被称为自发取向极化(SOP),存在于有机发光器件(oled)有源层中使用的许多材料中。这种现象导致束缚极化电荷的形成,这是由极化子积累在电压低于导通补偿。虽然大多数先前的工作都集中在器件电子传输层(ETL)的极化上,但在这里,我们通过系统地探测磷光oled中的极化子积累和激子-极化子猝灭来研究发射层SOP的影响。为了更深入地了解极化子积累,系统地探测了器件电容作为具有极性和非极性发射层的样品之间电压的函数。我们发现电容测量不仅可以用于跟踪累积电荷的数量,还可以用于跟踪其在器件有源层中的位置。本研究提供了一个分析框架,可以进一步了解oled中的电荷积累过程,从而提高我们对oled中SOP的理解
{"title":"The role of OLED emissive layer polarization in sub-turn-on charge accumulation","authors":"E. Pakhomenko, R. Holmes","doi":"10.1117/12.2633591","DOIUrl":"https://doi.org/10.1117/12.2633591","url":null,"abstract":"Preferential alignment of molecular permanent dipole moments, known as spontaneous orientation polarization (SOP), is present in many materials employed in the active layers of organic light-emitting devices (OLEDs). This phenomenon leads to the formation of bound polarization charge, which is compensated by polaron accumulation at voltages below turn-on. While most prior work has focused on polarization in the device electron transport layer (ETL), here we examine the impact of emissive layer SOP by systematically probing polaron accumulation and exciton-polaron quenching in phosphorescent OLEDs. To gain a deeper understanding of polaron accumulation, device capacitance is systematically probed as a function of voltage across samples with polar and nonpolar emissive layers. We find that capacitance measurements can be used to track not only the number of accumulated charges, but also its location within the device active layers. This study provides an analysis framework that allows further insights on the charge accumulation process in OLEDs, thus improving our understanding of SOP in OLEDs","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114437684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Stable colloidal suspension of graphene oxide liquid crystals: optical characteristics and electro-optic switching for sample 氧化石墨烯液晶稳定胶体悬浮液:光学特性及样品电光开关
Pub Date : 2022-10-03 DOI: 10.1117/12.2646205
S. Shahini, Michel Meylender, Tom Menei, S. Campidelli, G. Scalia
Graphene oxide liquid crystal has very interesting optical and electro-optic properties. In fact, reorientation occurs already at few volts per millimeter and the disk-like graphene oxide flakes, typically suspended in water, can form liquid crystal phases at very low concentration due to the large aspect ratio of the flakes. The liquid crystal formation depends on the flake size, their concentration but also on the magnitude of the repulsive and attractive inter-flakes forces. However, the spatial confinement has relevance too on the macroscopic alignment and even in inducing birefringence as visible in filaments and in more confining configurations. Unlike graphene, graphene oxide has a very small light absorption in the visible, in some regions actually negligible. However, even if the colloidal characteristics are preserved and there is still birefringence, the optical characteristic can change due to near-UV exposure, resulting in an increase of optical absorption. This has the consequence that the imaginary part has to be included in the general refractive index expression and in the optical transmission evaluation. Stability is an important aspect for graphene oxide suspensions either for changes in the optical characteristics or the destabilization of the suspension due to partial or total reduction leading to the formation of reduced graphene oxide, but also for the isotropic – nematic phase separation occurring for concentrations in the bi-phase region. All these aspects are very relevant also for electro-optic applications. It will be shown here that some issues can be solved and improved if the chosen phase is the nematic phase.
氧化石墨烯液晶具有非常有趣的光学和电光性质。事实上,在每毫米几伏特的电压下就会发生重定向,通常悬浮在水中的圆盘状氧化石墨烯薄片,由于薄片的宽高比很大,可以在非常低的浓度下形成液晶相。液晶的形成取决于薄片的大小,它们的浓度,但也取决于薄片间的排斥力和吸引力的大小。然而,空间约束也与宏观排列有关,甚至与在细丝和更受限的构型中可见的诱导双折射有关。与石墨烯不同的是,氧化石墨烯在可见光中具有非常小的光吸收,在某些区域实际上可以忽略不计。然而,即使胶体特性被保留,仍然存在双折射,由于近紫外照射,光学特性也会发生变化,导致光学吸收增加。这就产生了虚部必须包含在一般折射率表达式和光透射率评估中。稳定性是氧化石墨烯悬浮液的一个重要方面,无论是由于光学特性的变化,还是由于部分或全部还原导致氧化石墨烯还原形成的悬浮液的不稳定,还是由于双相区域浓度发生的各向同性-向列相分离。所有这些方面都与电光应用密切相关。这里将显示,如果选择的相位是向列相,则可以解决和改进一些问题。
{"title":"Stable colloidal suspension of graphene oxide liquid crystals: optical characteristics and electro-optic switching for sample","authors":"S. Shahini, Michel Meylender, Tom Menei, S. Campidelli, G. Scalia","doi":"10.1117/12.2646205","DOIUrl":"https://doi.org/10.1117/12.2646205","url":null,"abstract":"Graphene oxide liquid crystal has very interesting optical and electro-optic properties. In fact, reorientation occurs already at few volts per millimeter and the disk-like graphene oxide flakes, typically suspended in water, can form liquid crystal phases at very low concentration due to the large aspect ratio of the flakes. The liquid crystal formation depends on the flake size, their concentration but also on the magnitude of the repulsive and attractive inter-flakes forces. However, the spatial confinement has relevance too on the macroscopic alignment and even in inducing birefringence as visible in filaments and in more confining configurations. Unlike graphene, graphene oxide has a very small light absorption in the visible, in some regions actually negligible. However, even if the colloidal characteristics are preserved and there is still birefringence, the optical characteristic can change due to near-UV exposure, resulting in an increase of optical absorption. This has the consequence that the imaginary part has to be included in the general refractive index expression and in the optical transmission evaluation. Stability is an important aspect for graphene oxide suspensions either for changes in the optical characteristics or the destabilization of the suspension due to partial or total reduction leading to the formation of reduced graphene oxide, but also for the isotropic – nematic phase separation occurring for concentrations in the bi-phase region. All these aspects are very relevant also for electro-optic applications. It will be shown here that some issues can be solved and improved if the chosen phase is the nematic phase.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"819 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126817821","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hybrid color conversion control using OLED and perovskite emitters 使用OLED和钙钛矿发射器的混合颜色转换控制
Pub Date : 2022-10-03 DOI: 10.1117/12.2632662
Hyukmin Kwon, Seokwoo Kang, Sunwoo Park, Seyoung Oh, Jongwook Park
Perovskites is a very promising material that is being extensively studied at the bulk and nanosize scales because it has outstanding optical properties, including high quantum efficiency and narrow emission spectra. To realize a full-color display in the research field of perovskites or perovskite-structured quantum dots (PeQDs), the development of white-light-emitting devices that operate by emitting light of three primary colors (red, green, and blue) has emerged as an active research topic. In this presentation, we report for the first time three-color white-light emission with high brightness from white-emitting PeQD organic light-emitting diodes (WPeQD-OLEDs) fabricated using a PeQD material and organic emitters. The electroluminescence (EL) spectra of the WPeQD-OLEDs showed EL maximum peaks at 460, 527, and 640 nm; the CIE color coordinates of the emitted light were (0.33, 0.40). The EL results confirmed that the maximum luminance was 49,000 cd m−2 and the maximum luminance efficiency and power efficiency were 4.48 cd A−1 and 2.16 lm W−1 . Also, we achieved a new hybrid pink device of perovskite red QD (PRQD) and organic blue emitter (OBE) which have different emission mechanisms in bilayered LED devices. It has pink emission, CIE coordinate of (0.331, 0.204) which cannot be provided by a single emitter.
钙钛矿是一种非常有前途的材料,由于其具有优异的光学特性,包括高量子效率和窄发射光谱,因此在体和纳米尺度上得到了广泛的研究。为了实现钙钛矿或钙钛矿结构量子点(PeQDs)研究领域的全彩色显示,开发利用三原色(红、绿、蓝)发光的白光发光器件已成为一个活跃的研究课题。在本报告中,我们首次报道了使用PeQD材料和有机发光体制造的白光PeQD有机发光二极管(wpeqd - oled)具有高亮度的三色白光发射。wpeqd - oled的电致发光(EL)光谱在460、527和640 nm处显示出最大的EL峰;发射光的CIE色坐标为(0.33,0.40)。EL结果证实,最大亮度为49,000 cd m−2,最大发光效率和功率效率分别为4.48 cd A−1和2.16 lm W−1。此外,我们还在双层LED器件中实现了具有不同发射机制的钙钛矿红色量子点(PRQD)和有机蓝色发射体(OBE)的新型混合粉红色器件。它具有粉红色的发射,CIE坐标为(0.331,0.204),这是单个发射器无法提供的。
{"title":"Hybrid color conversion control using OLED and perovskite emitters","authors":"Hyukmin Kwon, Seokwoo Kang, Sunwoo Park, Seyoung Oh, Jongwook Park","doi":"10.1117/12.2632662","DOIUrl":"https://doi.org/10.1117/12.2632662","url":null,"abstract":"Perovskites is a very promising material that is being extensively studied at the bulk and nanosize scales because it has outstanding optical properties, including high quantum efficiency and narrow emission spectra. To realize a full-color display in the research field of perovskites or perovskite-structured quantum dots (PeQDs), the development of white-light-emitting devices that operate by emitting light of three primary colors (red, green, and blue) has emerged as an active research topic. In this presentation, we report for the first time three-color white-light emission with high brightness from white-emitting PeQD organic light-emitting diodes (WPeQD-OLEDs) fabricated using a PeQD material and organic emitters. The electroluminescence (EL) spectra of the WPeQD-OLEDs showed EL maximum peaks at 460, 527, and 640 nm; the CIE color coordinates of the emitted light were (0.33, 0.40). The EL results confirmed that the maximum luminance was 49,000 cd m−2 and the maximum luminance efficiency and power efficiency were 4.48 cd A−1 and 2.16 lm W−1 . Also, we achieved a new hybrid pink device of perovskite red QD (PRQD) and organic blue emitter (OBE) which have different emission mechanisms in bilayered LED devices. It has pink emission, CIE coordinate of (0.331, 0.204) which cannot be provided by a single emitter.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"34 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114205571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Performance comparison of continuous optical beam steering approaches 连续光束转向方法的性能比较
Pub Date : 2022-10-03 DOI: 10.1117/12.2633673
Brandon Vreeland, A. V. Van Rynbach, D. Bryant, P. Bos
Two methods for designing a continuous optical beam steering device are to use a linear phase profile based on physical optical pathlength (OPL) , and based on Pancharatnam phase (PP) . There are challenges with both of these basic approaches when considering design goals of high steering angle range, resolution, speed, and efficiency. In this overview talk, a comparison will be made between these two approaches with regard to these design goals. The limiting effects on each of these design goals will be considered with detailed FDTD optical modeling, and compared with experimental measurements.
设计连续光束导向装置的两种方法是基于物理光路长度(OPL)的线性相位轮廓和基于Pancharatnam相位(PP)。当考虑到高转向角度范围、分辨率、速度和效率的设计目标时,这两种基本方法都存在挑战。在这篇概述演讲中,将对这两种方法进行比较,以实现这些设计目标。对每个设计目标的限制影响将通过详细的FDTD光学建模来考虑,并与实验测量进行比较。
{"title":"Performance comparison of continuous optical beam steering approaches","authors":"Brandon Vreeland, A. V. Van Rynbach, D. Bryant, P. Bos","doi":"10.1117/12.2633673","DOIUrl":"https://doi.org/10.1117/12.2633673","url":null,"abstract":"Two methods for designing a continuous optical beam steering device are to use a linear phase profile based on physical optical pathlength (OPL) , and based on Pancharatnam phase (PP) . There are challenges with both of these basic approaches when considering design goals of high steering angle range, resolution, speed, and efficiency. In this overview talk, a comparison will be made between these two approaches with regard to these design goals. The limiting effects on each of these design goals will be considered with detailed FDTD optical modeling, and compared with experimental measurements.","PeriodicalId":145218,"journal":{"name":"Organic Photonics + Electronics","volume":"20 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2022-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127275843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
Organic Photonics + Electronics
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1