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Assessment of eggshell and CaCO3 reinforced recycled aluminium green metal matrix 蛋壳和碳酸钙增强再生铝绿色金属基体的评价
Q3 Engineering Pub Date : 2023-06-01 DOI: 10.5604/01.3001.0053.7662
L. M. Hasan, A. Ali
In this study, an environmentally friendly metal matrix was prepared, and the influence of eggshell powder and CaCO3 particles on the tensile strength and hardness of recycled aluminium were assessed.A matrix made of recycled aluminium was employed. Calcium carbonate and eggshells served as the study's reinforcing materials. Separately, weight percentages of 2, 4, and 8% of eggshell and calcium carbonate were used. The samples were made by sand-casting.The results showed that both eggshell and calcium carbonate positively affect the hardness, yield, and ultimate tensile strength of recycled aluminium. The hardness values were improved as the percentage of the eggshell increased. The maximum hardness was achieved at 2% calcium carbonate. Similarly, the highest improvement of yield strength was for 2% CaCO3 addition, while the highest tensile strength was obtained at 8% eggshell addition.To get better results, it would be desirable to use finer eggshells than those utilized in this study.Composites made with an aluminium matrix exhibit exceptional mechanical and physical characteristics. The most challenging obstacle to overcome is the cost of metal matrix composites. Eggshells are a by-product that could be employed as a lightweight, affordable form of reinforcement. One way to get rid of this by-product, improve composite characteristics, and lower the cost of aluminium composite is to use eggshells.A comparative investigation was carried out to determine the effects of adding agricultural by-product eggshell, and commercial CaCO3 reinforcement material on the characteristics of recycled aluminium matrix integrated 425 m sized eggshell and CaCO3 separately as a reinforcement material to create a metal matrix that is beneficial to the environment.
本研究制备了一种环保金属基体,考察了蛋壳粉和CaCO3颗粒对再生铝抗拉强度和硬度的影响。采用了由再生铝制成的基体。碳酸钙和蛋壳作为研究的增强材料。蛋壳和碳酸钙的重量百分比分别为2%、4%和8%。样品由砂型铸造而成。结果表明,蛋壳和碳酸钙对再生铝的硬度、屈服和极限抗拉强度均有积极影响。硬度值随蛋壳含量的增加而提高。在碳酸钙含量为2%时达到最大硬度。同样,CaCO3添加量为2%时,屈服强度提高幅度最大,蛋壳添加量为8%时,拉伸强度提高幅度最大。为了获得更好的结果,最好使用比本研究中使用的更细的蛋壳。由铝基制成的复合材料具有优异的机械和物理特性。需要克服的最具挑战性的障碍是金属基复合材料的成本。蛋壳是一种副产品,可以作为一种轻量级的、负担得起的加固形式。一种消除这种副产品,改善复合材料特性,降低铝复合材料成本的方法是使用蛋壳。通过对比研究,确定了添加农副产蛋壳和商用CaCO3增强材料对425 m尺寸鸡蛋和CaCO3分别作为增强材料的再生铝基特性的影响,从而形成有利于环境的金属基。
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引用次数: 0
Modernisation of the workplace as a result of the outbreak of the pandemic 由于大流行病的爆发,工作场所实现了现代化
Q3 Engineering Pub Date : 2023-06-01 DOI: 10.5604/01.3001.0053.7666
A. Kania, M. Polok-Rubiniec, A. Włodarczyk-Fligier
of this paper is to propose modernisation activities, including the improvement of machines and devices that will increase work safety during the epidemic state for the workplace of an injection moulding machine operator in a selected manufacturing company.In the work brief analyses of a production line and a workplace of an injection moulding machine operator were carried out. Then the threats that occur at the analysed workplace were identified. The risk assessment was done using three methods: matrix according to the PN-N-18002:2011 standard, Risk Score and PHA.The results of the occupational risk assessment obtained by the three assessment methods were similar and gave similar results. The greatest and unacceptable risk has occurred for the threat of SARS-CoV-2 virus infection. Therefore, the following modernisation solutions were proposed: the introduction of mandatory epidemiological questionnaires, online training for company employees, the use of a three-axis robot, replacement of traditional disinfection dispensers with automatic ones.The results of re-assessing the occupational risk after introducing the proposed improvements showed that the occupational risk was significantly reduced mainly to the low or very low levels.The proposed modernisation solutions at the workplace of an injection moulding machine operator can be used for each workplace and each epidemiological state.
本文的目的是提出现代化的活动,包括机器和设备的改进,将增加工作安全在流行病状态的注射成型机操作员的工作场所在一个选定的制造公司。对注塑机操作人员的生产线和工作场所进行了简要分析。然后确定了在分析的工作场所发生的威胁。采用三种方法进行风险评估:根据PN-N-18002:2011标准的矩阵、风险评分和PHA。三种评价方法得出的职业风险评价结果相似,评价结果相似。最大和不可接受的风险是SARS-CoV-2病毒感染的威胁。因此,提出了以下现代化解决方案:引入强制性流行病学问卷,对公司员工进行在线培训,使用三轴机器人,用自动消毒机取代传统的消毒机。引入改进措施后,对职业风险进行重新评估的结果表明,职业风险主要降低到低或极低水平。在注塑机操作员的工作场所提出的现代化解决方案可用于每个工作场所和每个流行病学状态。
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引用次数: 0
Studying the influence of waste glass and montmorillonite powders on the thermal conductivity and hardness of poly(methyl methacrylate) polymer matrix 研究了废玻璃和蒙脱土粉末对聚甲基丙烯酸甲酯聚合物基体导热性和硬度的影响
Q3 Engineering Pub Date : 2023-06-01 DOI: 10.5604/01.3001.0053.7661
Alaa Almansoori, R. Ghadban, M.H. Ali, M. Sabri
The present study aims to evaluate the effect of montmorillonite nanoclay (MMT) and waste glass powder (WGP) on the hardness and thermal conductivity of PMMA polymer composites. Thus, this study concentrates on the potential use of MMT and WGP as reinforcements, in different concentrations, in PMMA polymer matrix, with the expectation of improving the performance of PMMA polymer composites in various applications.There is a growing demand for PMMA with increased mechanical properties and thermal stability for applications where inorganic glass would fail. Montmorillonite (MMT) clay and Waste Glass Powder (WGP) have physical and chemical properties compatible with PMMA. Therefore, they could potentially enhance PMMAs hardness and thermal conductivity. Silicon dioxide in glass silica and MMT and octahedral aluminium hydroxide sheet in MMT can strengthen both covalent and hydrogen bonding architecture in PMMA composite for better mechanical strength and thermal conductivity. Thus, PMMA composites were designed by combining MMT powder and WGP powder in different ratios before being incorporated into the PMMA polymer matrix and tested for hardness and thermal conductivity.The present study measured Brinell Hardness (HB) and electrical conductivity values of four PMMA composites containing different proportions of MMT and WGP. MMT/WGP filler mix had optimal hardiness (HB number = 74) when glass content was 1% (3MMT1G) or better still (HB number = 63) when an equal mix ratio was used (1MMT1G). PMMA composite with 3MMT1G also had the highest thermal conductivity (0.01899W/m.K-1). However, the higher the glass content, the lower the thermal conductivity of the PMMA composite. Thus, the present study has demonstrated that 3MMT1G filler was the best for enhancing the thermal and mechanical properties of PMMA composite.The results of this study demonstrate the potential of this new composite material for a variety of applications. Further research is needed to explore the full potential of this material and to develop new and improved versions.Reusing waste glass as filler materials in composites requires minimal processing and therefore has lower environmental impacts than synthetic options.Experimental data from the present study has provided new insights into Glass/MMT mix design in PMMA composites. The PMMA composite containing 3MMT1G exhibited the best hardness and thermal conductivity characteristics. Thus, the present study has successfully optimised Glass/MMT mix design for PMMA composite for applications requiring these features.
研究了纳米蒙脱土(MMT)和废玻璃粉(WGP)对PMMA聚合物复合材料硬度和导热性能的影响。因此,本研究主要关注MMT和WGP作为增强剂在PMMA聚合物基体中不同浓度的潜在应用,以期提高PMMA聚合物复合材料在各种应用中的性能。在无机玻璃失效的应用中,对具有更高机械性能和热稳定性的PMMA的需求不断增长。蒙脱土(MMT)粘土和废玻璃粉(WGP)具有与PMMA相容的物理和化学性能。因此,它们可以潜在地提高pmma的硬度和导热性。玻璃二氧化硅和MMT中的二氧化硅和MMT中的八面体氢氧化铝片可以增强PMMA复合材料的共价和氢键结构,从而提高机械强度和导热性。因此,将MMT粉末和WGP粉末按不同比例混合,设计PMMA复合材料,然后将其掺入PMMA聚合物基体中,并测试其硬度和导热性。本研究测量了四种含有不同比例的MMT和WGP的PMMA复合材料的布氏硬度(HB)和电导率值。当玻璃含量为1% (3MMT1G)时,MMT/WGP填料混合物的耐寒性最佳(HB值= 74),当使用相同的混合比例(1MMT1G)时,HB值更好(HB值= 63)。含3MMT1G的PMMA复合材料导热系数最高(0.01899W/m.K-1)。然而,玻璃含量越高,PMMA复合材料的导热系数越低。因此,本研究表明,3MMT1G填料对于提高PMMA复合材料的热性能和力学性能是最好的。这项研究的结果证明了这种新型复合材料在各种应用中的潜力。需要进一步的研究来探索这种材料的全部潜力,并开发新的和改进的版本。再利用废玻璃作为复合材料的填充材料需要最少的加工,因此比合成材料对环境的影响更小。本研究的实验数据为PMMA复合材料中玻璃/MMT的混合设计提供了新的见解。含3MMT1G的PMMA复合材料具有最佳的硬度和导热性能。因此,目前的研究已经成功地优化了玻璃/MMT混合设计的PMMA复合材料的应用需要这些功能。
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引用次数: 0
A comprehensive review of polymer materials and selective laser sintering technology for 3D printing 高分子材料和选择性激光烧结技术在3D打印中的应用综述
Q3 Engineering Pub Date : 2023-05-01 DOI: 10.5604/01.3001.0053.7286
F.E. Jabri, A. Ouballouch, L. Lasri, R. El alaiji
This review analyses different approaches used to study selective laser sintering (SLS) technology of polymer materials. These main approaches concern: thermal behaviour, fatigue and surface roughness.Regarding the first behaviour, researchers extensively studied the impact of process parameters, including scan speed, laser, power and laser energy density, on the thermal behaviour of 3D printed parts. Numerical and experimental analyses are used to conduct process parameter evaluations.Laser power and scan speed are the most significant parameters of the laser energy density. For the second, according to test protocols and quantitative analysis performed, the authors concluded that the combination of small and large laser energy density particles generates higher sintering and better fatigue resistance. Moreover, tensile analysis in different environments showed that testing in the water decreased the fatigue life of polymer samples. The influence of process parameters on the mechanical properties and surface roughness of 3D parts is also analysed. In addition, the investigators found that the additives increase the surface roughness of 3D printed parts.This review shows that researchers can focus on creating a combination of these approaches to expand the use of this process for industrial part production.All these investigations have made it possible to determine the optimal process conditions to ensure higher quality, optimal surface quality and better fatigue strength.
本文综述了高分子材料选择性激光烧结技术的研究方法。这些主要方法涉及:热行为、疲劳和表面粗糙度。对于第一种行为,研究人员广泛研究了包括扫描速度、激光、功率和激光能量密度在内的工艺参数对3D打印部件热行为的影响。采用数值分析和实验分析进行工艺参数评价。激光功率和扫描速度是影响激光能量密度最重要的参数。其次,根据测试方案和定量分析,作者得出结论,大小激光能量密度颗粒的组合可以产生更高的烧结性能和更好的抗疲劳性能。此外,不同环境下的拉伸分析表明,水中测试降低了聚合物样品的疲劳寿命。分析了工艺参数对三维零件力学性能和表面粗糙度的影响。此外,研究人员发现,添加剂增加了3D打印部件的表面粗糙度。这篇综述表明,研究人员可以专注于创建这些方法的组合,以扩大该工艺在工业零件生产中的应用。所有这些研究使确定最佳工艺条件成为可能,以确保更高的质量,最佳的表面质量和更好的疲劳强度。
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引用次数: 0
Increasing the accuracy of measuring the physicochemical parameters of wastewater samples when implementing a new informative method 在实施一种新的信息方法时,提高了测量废水样品理化参数的准确性
Q3 Engineering Pub Date : 2023-05-01 DOI: 10.5604/01.3001.0053.7288
V. Sebko, V. Zdorenko, N. Zashchepkina, S. Barylko
The necessity of developing new multi-parameter electromagnetic methods to obtain the information on controlled wastewater samples from fruit juice production has been proved. Based on the universal transformation functions G = f(x) and = f(x) obtained in the work, which relates the amplitude and phase components of the multi-parameter MFP signal with the parameters of wastewater samples, a three-parameter method for joint measurement control of the electrical conductivity , relative dielectric constant r and temperature t of wastewater samples from the production of apple juice. An algorithm for joint multi-parameter measurements of the parameters , r and t based on a transformer electromagnetic transducer (MFP) has been developed, the switching scheme provides for heating a wastewater sample during measurement control to simulate production conditions. Since the amplitude and phase components of the MFP multi-parameter signal depend on the temperature t, sample heating also makes it possible to create information redundancy and improve the accuracy of wastewater sample identification. The implementation of the proposed method makes it possible to indirectly determine the composition of wastewater samples, using only one transducer with known physical properties, all this leads to an increase in the accuracy of measuring the parameters of wastewater samples in comparison with reference methods and measuring instruments and ultimately allows choosing a promising method of wastewater treatment in accordance with the analysis of experimental data. The data obtained indicate the acidic composition of wastewater; therefore, it is proposed to neutralise industrial waste at the outlet of the finished product. The methodology of the above studies lies in the fact that, within the framework of a specific scientific approach, it is necessary to expand the functional and technical capabilities of the electromagnetic device by implementing a new multi-parameter electromagnetic method for joint measurements of the physicochemical parameters of wastewater samples.The essence of the proposed three-parameter method of joint measurement control of parameters t, r and t is based on the analysis of the interaction of an external homogeneous magnetic field with the magnetic field of eddy currents induced in a conductive electrolytic liquid (in a wastewater sample). Based on the input of special normalised parameters, as well as the obtained universal transformation functions G = f(x) and = f(x), which relate the physicochemical parameters , r and t of the electrolytic liquid medium (wastewater samples from apple juice production) with the amplitude and phase components of the multi-parameter signal MFP, at a constant frequency of the magnetic field f, the implementation of a three-parameter electromagnetic method of joint measurement control of the electrical conductivity , relative permittivity r and temperature t have been proposed. At the same time, using the th
所研究的方法有以下局限性:直径的变化范围为20mm至55mm。下限由电磁场的频率设定,上限由换能器框架的直径设定,57mm。测量是在均匀的纵向磁场中进行的,MFP绕组的长度必须是直径的十倍才能达到这种磁场均匀性。样品长度必须大于或等于换能器的绕组长度,即lo ln。由于换能器的磁场是均匀的,因此产品的径向不对准不会影响测量结果。MFP框架限制了产品的错位。研究发现,在4% ~ 6%范围内的样品偏差对废水样品理化参数的测量结果没有实际影响。温度的变化导致磁化绕组的电阻r发生变化,因此变流器的绕组必须与环境隔热(用mitre胶带包裹,涂上BF-19粘合剂,然后在EKPS-500马弗炉中以t = 300℃的温度烘烤)。该工作的实际意义在于,通过对所得的废水样品理化参数值进行分析,可以及时预防废水偏离国际城市污水排放标准规定指标的原因,并采取措施防止居住区人工和天然水库的污染。以及开发食品和加工工业废水处理的有效方法。所得到的关系式描述了通用变换函数G = f(x)和= f(x),以及基于MFP测定废水样品的比电导率、相对介电常数r和温度t的测量和计算操作算法,使设计:构建和创建基于智能设备的自动化测量装置,这些设备以现象学方法测量电解液体介质的物理和化学参数作为其操作理论的基础。电磁换能器(EMT)理论已进一步发展了一个样品的弱电解液与酸性成分(样品从苹果汁生产废水)。
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引用次数: 0
Analysis of the process of qualifying the welding technology of S355JR structural steel using the submerged arc welding method 分析了采用埋弧焊法确定S355JR结构钢焊接工艺的过程
Q3 Engineering Pub Date : 2023-05-01 DOI: 10.5604/01.3001.0053.7287
A. Wieczorska, W. Labuda
This paper presents the issue of welding technology qualification using the example of structural steel S355JR with a plate thickness of 25 mm and 100 mm, bevelling V. The main objective of this work was to attempt to perform a full qualification of the submerged arc welding process in accordance with the requirements of PN EN ISO 15614. Particular attention was paid to the issue of the qualification of welding technology. The samples were subjected to non-destructive testing, i.e. visual and penetrant testing, as well as ultrasonic testing and heat treatment. This was followed by destructive testing, including macroscopic testing and hardness testing. According to the proposed procedure for the recognition of submerged arc welding technology, once the necessary tests had been carried out and the protocols with positive results had been obtained. The documentation had been completed, the analysis needed to obtain certificates of conformity for factory production control and welding quality was carried out.Submerged arc welding is often used for highly responsible butt joints, particularly when joining thick components. This has been achieved through the proper design of the preparation of the parts to be welded and the development of a welding technology that practically eliminates the pre-phase that occurs in traditional technology, thereby eliminating the risk of it affecting the quality of the welded joint.During the implementation of submerged arc welding, a number of technological problems were encountered. The first test joints contained many defects, i.e. sticking and slag inclusions inside the welds. In addition, obtaining welds with the correct profile and removing the slag from the weld groove was difficult. These obstacles were eliminated experimentally by carrying out successive tests using different parameters and welding groove geometries.The correct implementation of any welding process depends on its input parameters. These parameters include welding current, welding speed, welding current, wire diameter, welding voltage and many others. Submerged arc welding (SAW) is widely used in the industry for manufacturing as it is more reliable, provides deep penetration in the work, ensures a smooth finish on objects, and results in high productivity.The technology was developed for a company that manufactures control discs for steam turbines.
本文以钢板厚度为25mm和100mm,坡口v的S355JR结构钢为例,提出了焊接技术鉴定的问题。本工作的主要目的是根据PN EN ISO 15614的要求,尝试对埋弧焊工艺进行全面鉴定。对焊接技术的鉴定问题给予了特别的关注。样品进行了无损检测,即目测和渗透检测,以及超声波检测和热处理。其次是破坏性测试,包括宏观测试和硬度测试。根据拟议的埋弧焊技术识别程序,一旦进行了必要的试验,并取得了积极的结果。文件已完成,为工厂生产控制和焊接质量获得合格证书所需的分析已进行。埋弧焊通常用于高度可靠的对接接头,特别是在连接厚构件时。这是通过正确设计待焊部件的准备和开发焊接技术实现的,该技术实际上消除了传统技术中出现的预阶段,从而消除了其影响焊接接头质量的风险。埋弧焊在实施过程中,遇到了许多技术问题。第一次试验的接头存在很多缺陷,如粘接和夹渣。此外,获得具有正确轮廓的焊缝和从焊缝坡口清除渣是困难的。通过使用不同的参数和焊接坡口几何形状进行连续试验,消除了这些障碍。任何焊接工艺的正确实施都取决于其输入参数。这些参数包括焊接电流、焊接速度、焊接电流、丝径、焊接电压等。埋弧焊(SAW)在制造业中被广泛应用,因为它更可靠,在工作中提供深度渗透,确保物体表面光滑,并导致高生产率。这项技术是为一家生产汽轮机控制盘的公司开发的。
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引用次数: 0
Characterization of galvanized steel-low alloy steel arc stud welded joint 镀锌钢-低合金钢电弧螺柱焊接接头的表征
Q3 Engineering Pub Date : 2023-04-01 DOI: 10.5604/01.3001.0053.6707
S. Abbas, M. Alali, M. Abass, W. Abbas
This paper investigates the possibility of successfully welding a Low Alloy Steel (LAS) stud to Galvanized Steel (GS) plate.Arc Stud Welding (ASW) was performed on joining LAS studs to GS plates. Welding parameters were selected based on weld trails. The first tests of the welded joints were based on visual inspection for welding defects such as lack of fusion and undercut welding defects. The good quality should be free of these defects and have full weld reinforcement. Other weld qualifications included torque strength test, microhardness test, and microstructure examination.The LAS studs have been successfully welded to a galvanized steel plate using the arc stud welding process. Higher welding current with adjusted welding time (800 A, 0.3 s) gave full weld reinforcement, the best joint appearance, and strength. Martensite phase was detected in the weld area and heat affected zone (HAZ), affecting the joint mechanical properties. Hardness property varied across the welded joint, and maximum hardness was recorded at the HAZ at the stud side. Hardness increased with the increasing welding current. At 800 A, welding current hardness was 10% higher than at 400 and 600 A. Torque strength was affected by weld reinforcement, and 800 A gave the best weld reinforcement that produced the highest torque strength.The main research limitation is the difficulty of welding LAS studs and GS plates. In conventional welding methods, such as gas metal arc welding, it is hard to get full weld penetration due to the geometry restrictions of the joint, which results in partial weld penetration between the studs and the plates. Furthermore, the issue of zinc evaporation during welding can be reduced by the advantage of the very high welding speed (in milliseconds) of ASW that overcomes the problem of continuous welding that usually results in the formation of harmful porosities and poor weldability.In this research, galvanized steel plates were successfully welded to LAS studs using the ASW process. The welding parameters for this dissimilar welding joint were carefully selected. Microstructure changing due to the welding process was investigated. The joint mechanical properties were evaluated.
本文研究了低合金钢(LAS)螺柱成功焊接到镀锌钢板(GS)的可能性。采用电弧螺柱焊(ASW)将LAS螺柱与GS板连接。根据焊缝轨迹选择焊接参数。焊接接头的第一次试验是基于目视检查焊接缺陷,如缺乏熔合和下切焊接缺陷。良好的质量应该没有这些缺陷,并有充分的焊接加固。其他焊接资格包括扭矩强度测试、显微硬度测试和显微结构检查。采用电弧螺柱焊工艺成功地将LAS螺柱焊接到镀锌钢板上。较大的焊接电流,调整焊接时间(800 A, 0.3 s),焊缝增强充分,接头外观和强度最佳。焊缝区和热影响区存在马氏体相,影响了接头的力学性能。焊接接头的硬度性能各不相同,最大硬度记录在螺柱侧的热影响区。硬度随焊接电流的增大而增大。在800 A时,焊接电流硬度比400和600 A时高10%。转矩强度受焊缝补强的影响,800a的焊缝补强效果最好,产生的转矩强度最高。研究的主要局限是LAS螺柱与GS板的焊接困难。在传统的焊接方法中,如气体保护金属电弧焊,由于接头的几何形状的限制,很难得到完全的焊透,导致螺柱与板之间的部分焊透。此外,由于ASW的焊接速度非常快(毫秒级),克服了连续焊接通常会导致有害孔隙形成和可焊性差的问题,因此可以减少焊接过程中锌的蒸发问题。在本研究中,采用ASW工艺成功地将镀锌钢板焊接到LAS螺柱上。对这种异种焊接接头的焊接参数进行了精心选择。研究了焊接过程中组织的变化。对接头力学性能进行了评价。
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引用次数: 0
Statistical methods in the analysis of strength parameters of epoxy-glass composites modified with rubber recyclate 再生橡胶改性环氧玻璃复合材料强度参数分析的统计方法
Q3 Engineering Pub Date : 2023-04-01 DOI: 10.5604/01.3001.0053.6702
S. Drewing, N. Abramczyk, D. Żuk, T. Dyl
The article presents a statistical analysis of strength parameters of newly developed epoxy-glass composite materials modified with the addition of rubber recyclate.Three variants of materials with a percentage of recyclate content in the composite matrix of 3%, 5%, 7% and a reference variant without the addition of recyclate were used for the study. The samples were subjected to an impact test on a ZWICK RKP 450IR-GE impact hammer. Resilience measurement values were subjected to statistical analyses at the significance level = 95%, such as: testing the normality of distributions with the Shapiro-Wilk test, testing differences between pairs with the Student's t-test for dependent groups, and testing ANOVA differences for independent groups.The Shapiro-Wilk test confirmed that the resilience variables for all tested samples were in normal distributions; therefore the highest power parametric tests were used to test the differences. Using the Student's t-test, it was confirmed that between pairs of variables in configurations: standard sample with the modified sample, there were significant statistical differences in the distribution of resilience values for all samples. ANOVA confirmed significant changes in impact strength in 10 comparison variants.The obtained test results showed that in 9 compared cases, there were significant statistical differences, and in one case, there were no significant differences.The performed statistical analyses confirmed their significant usefulness in the process of qualification of strength parameters for materials with high anisotropy, such as composites.The manufactured products are innovative in terms of the method of using the addition of rubber recyclate as a filler for epoxy-glass composites. The use of static methods for their study also has practical value. It optimizes the analysis methods of the results of measurements of strength parameters of new composite materials.
本文对新研制的添加再生橡胶改性的环氧玻璃复合材料的强度参数进行了统计分析。研究中使用了复合基质中再生物含量百分比分别为3%、5%、7%的三种材料变体和不添加再生物的参考变体。样品在ZWICK RKP 450IR-GE冲击锤上进行了冲击试验。弹性测量值在显著性水平= 95%下进行统计学分析,如:使用Shapiro-Wilk检验检验分布的正态性,使用Student's t检验检验成对之间的差异,使用独立组的方差分析检验差异。夏皮罗-威尔克检验证实,所有被测样本的弹性变量均服从正态分布;因此,采用最高功率参数检验来检验差异。通过学生t检验证实,在标准样本和修正样本配置的变量对之间,所有样本的弹性值分布都有显著的统计学差异。方差分析证实了10个比较变量中冲击强度的显著变化。得到的检测结果显示,9例比较病例有显著的统计学差异,1例比较病例无显著差异。统计分析证实了这些方法在高各向异性材料(如复合材料)强度参数确定过程中的重要作用。制造的产品在使用添加橡胶回收物作为环氧玻璃复合材料填料的方法方面具有创新性。采用静态方法对其进行研究也具有实用价值。对新型复合材料强度参数测量结果的分析方法进行了优化。
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引用次数: 1
The characterization study of inhibited silica/silicate scale using vinyl sulfonated copolymer (VS-Co) 乙烯基磺化共聚物(VS-Co)抑制二氧化硅/硅酸盐垢的表征研究
Q3 Engineering Pub Date : 2023-04-01 DOI: 10.5604/01.3001.0053.6699
R. Sazali, K. Sorbie, L. Boak, A. Z. Azman, Ismail Mohd Saaid, Aqilah Dollah, N. K. Kassim Shaari, K. Ismail
Silica/silicate scale is a significant problem, especially in oilfield production during Alkaline Surfactant Polymer (ASP) flooding, where chemical inhibitors are the preferred method to prevent them. In this study, the effect of inhibitor vinyl sulfonated copolymer (VS-Co) on silica/silicate scale formation was analysed using X-Ray Diffraction (XRD) and Fourier-transform infrared spectroscopy (FTIR).The functional group type of VS-Co are sulfonate ions, SO3-, and these interact in the scaling process. Bulk-inhibited scaling brine tests were conducted at 60C and pH 8.5. During these tests, the silicon brine (with VS-Co) representing the inhibited ASP leachate was mixed with a magnesium brine representing the connate water to replicate reservoir conditions during ASP flooding. The samples tested in this study were non-inhibited Si/Mg mixed brine of 60 ppm Mg2+ and 940 ppm Si4+ (60Mg:940Si) as a blank, and inhibited 60Mg:940Si mixture with various VS-Co concentrations of 20 ppm, 50 ppm, and 100 ppm. The inhibition efficiency of the VS-Co was determined, followed by the characterisation study of the silica/silicate scale deposited from both test conditions.The IR spectra of all 60Mg:940Si samples show a similar peak at 1050 cm-1 to 1080 cm-1, attributed to a Si-O covalent bond and a band at 790 cm-1 to 800 cm-1 showing the presence of Si-O-Si stretching. XRD patterns produced a broad scattering peak for all samples at 2 of 24 showing that the samples are amorphous silica. For tests of high Mg2+ in the brine mix, 900Mg:940Si, a mix of crystalline silica and crystalline magnesium silicate was produced. Based on these results, it can be concluded that the scale formed even with 100 ppm of VS-Co present. Further studies are required to address how to mitigate scale formation effectively in the future.Based on the research conducted, we can conclude that the VS-Co alone could not significantly inhibit the formation of silica/silicate scale even at the highest concentration (100 ppm) of VS-Co. However, having VS-Co present caused an alteration in IR spectra frequency which requires further investigation to assess how best to develop the inhibiting properties of the VS-Co product. The application of nanoparticles and their successful stories spark the interest of authors in searching for an efficient method of managing the silica/silicate scale where the modification of potential scale inhibitor (SI) with nanoparticles may be able to improve the inhibition efficiency towards the silicate/silicate scale.The presence of VS-Co in the scaling brine only slightly inhibits the Mg2+ ion (initially comes from connate water) from reacting. It is worth further investigation on how this VS-Co can make it happen. Hence, the functional groups responsible for this may be altered by adding other functional groups to provide a synergistic effect in preventing this silica/silicate scale; or by modifying the VS-Co with nanoparticles to improve their adsorption/desorption ca
二氧化硅/硅酸盐结垢是一个严重的问题,特别是在碱性表面活性剂聚合物(ASP)驱油过程中,化学抑制剂是防止结垢的首选方法。本文采用x射线衍射(XRD)和傅里叶变换红外光谱(FTIR)分析了抑制剂乙烯基磺化共聚物(VS-Co)对二氧化硅/硅酸盐结垢的影响。VS-Co的官能团类型为磺酸盐离子和SO3-,它们在结垢过程中相互作用。在60C和pH 8.5条件下进行了体积抑制结垢盐水试验。在这些测试中,将代表受抑制的三元复合驱渗滤液的硅盐水(含VS-Co)与代表原生水的镁盐水混合,以模拟三元复合驱过程中的储层条件。本研究测试的样品以60 ppm Mg2+和940 ppm Si4+ (60Mg:940Si)的非抑制Si/Mg混合卤水为空白,以20 ppm、50 ppm和100 ppm的不同VS-Co浓度抑制60Mg:940Si混合物。测定了VS-Co的缓蚀效率,然后对两种测试条件下沉积的二氧化硅/硅酸盐垢进行了表征研究。所有60Mg:940Si样品的红外光谱在1050 cm-1至1080 cm-1处显示出相似的峰,归因于Si-O共价键和790 cm-1至800 cm-1处显示Si-O- si拉伸的存在。所有样品的XRD谱图在2 / 24处均出现宽散射峰,表明样品为无定形二氧化硅。为了测试高Mg2+的盐水混合物,生产了900Mg:940Si,结晶二氧化硅和结晶硅酸镁的混合物。根据这些结果,可以得出结论,即使存在100 ppm的VS-Co,也会形成水垢。未来需要进一步研究如何有效地减缓水垢的形成。通过研究可知,即使在最高浓度(100 ppm)下,单独添加VS-Co也不能显著抑制二氧化硅/硅酸盐水垢的形成。然而,有VS-Co的存在会导致红外光谱频率的改变,这需要进一步的研究来评估如何最好地开发VS-Co产品的抑制特性。纳米颗粒的应用及其成功案例激发了作者的兴趣,寻找一种有效的控制二氧化硅/硅酸盐结垢的方法,其中用纳米颗粒改性潜在阻垢剂(SI)可能能够提高对硅酸盐/硅酸盐结垢的抑制效率。VS-Co在结垢盐水中的存在仅轻微抑制Mg2+离子(最初来自原生水)的反应。值得进一步研究的是,这家VS-Co是如何实现这一目标的。因此,可以通过添加其他官能团来改变负责这一点的官能团,以提供防止这种二氧化硅/硅酸盐结垢的协同效应;或者用纳米颗粒修饰VS-Co以提高其吸附/解吸能力。利用各种光谱分析来分析化学抑制剂的抑制机理的新技术是有前途的,其中光谱的变化可能提供化学抑制剂抑制效率的证据。
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引用次数: 0
Development of lightweight geopolymer composites containing perlite and vermiculite 珍珠岩和蛭石轻质地聚合物复合材料的研制
Q3 Engineering Pub Date : 2023-04-01 DOI: 10.5604/01.3001.0053.6696
K. Korniejenko, K. Pławecka, A. Bulut, B. Şahin, G. Azizağaoğlu, B. Figiela
The aim of this work was to prepare and characterise geopolymer composites containing lightweight aggregates - perlite and vermiculite.The geopolymer matrix was prepared on the basis of fly ash, sand and a 6M sodium hydroxide solution with sodium silicate. The properties of the materials were tested 28 days after the preparation of the samples. The following research methods were used to characterise the composites: compressive and flexural strength tests, microstructural tests using a scanning electron microscope, and thermal conductivity were measured.The results obtained showed a slight effect of the additives on the strength properties. Lightweight aggregates are characterised by good coherence with the matrix material. Their addition allowed to reduce the density and lowered the thermal conductivity of the materials. The results obtained indicate that the proposed additives can improve the properties of the geopolymer composite for use in the construction industry.Further research should focus on geopolymer composites with perlite and involve fire-resistant and water-absorption tests.The production of lightweight building materials brings a number of benefits, such as reducing the density of building elements and, at the same time, the entire structure, which results in a reduction in their weight, as well as lower transport costs. Such elements have better thermal and acoustic insulation, reflected in the parameters of buildings. An additional advantage is the reduced environmental impact through better insulation properties, lower fuel consumption during transport, etc.The density of the material can be reduced by using lightweight aggregates or obtaining porous material in the foamed process. In the case of geopolymer composites, a number of studies related to foamed materials have been provided, but there is only a few previous research connected with lightweight aggregates such as perlite and vermiculite.
这项工作的目的是制备和表征含有轻质聚集体的地聚合物复合材料-珍珠岩和蛭石。以粉煤灰、砂子和6M氢氧化钠水玻璃溶液为原料制备地聚合物基质。样品制备后28天对材料的性能进行测试。采用以下研究方法对复合材料进行表征:压缩和弯曲强度测试,使用扫描电子显微镜进行微观结构测试,并测量导热系数。结果表明,添加剂对强度性能影响不大。轻质聚集体的特点是与基体材料具有良好的相干性。它们的加入降低了密度,降低了材料的导热性。结果表明,所提出的添加剂可以改善地聚合物复合材料的性能,可用于建筑行业。进一步的研究应集中在珍珠岩地聚合物复合材料上,并进行耐火和吸水试验。轻质建筑材料的生产带来了许多好处,例如减少了建筑元素的密度,同时,整个结构,从而减少了它们的重量,以及降低了运输成本。这些元素具有更好的隔热和隔音性能,体现在建筑的参数上。另一个优点是通过更好的绝缘性能,降低运输过程中的燃料消耗等减少对环境的影响。材料的密度可以通过使用轻质骨料或在发泡过程中获得多孔材料来降低。就地聚合物复合材料而言,已经提供了许多与泡沫材料有关的研究,但只有少数先前的研究与珍珠岩和蛭石等轻质聚集体有关。
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Journal of Achievements in Materials and Manufacturing Engineering
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