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IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-07-01 DOI: 10.1177/0021955X211019492
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引用次数: 0
Application of computed tomography data–based modelling technique for polymeric low density foams, Part A: Model development 基于计算机断层扫描数据的聚合物低密度泡沫建模技术的应用,第一部分:模型开发
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-06-28 DOI: 10.1177/0021955X211028166
Anna Hössinger-Kalteis, M. Reiter, M. Jerabek, Z. Major
In this research study, a methodology is introduced for generating finite element simulation models for low density closed cell foams based on computed tomography (CT) measurement results. Creating this kind of simulation models can be very expensive with regard to modelling and computational effort. Hence, a combined modelling technique based on CT data and Voronoi diagrams is developed that minimizes this effort, but nevertheless, generates simulation models with a realistic microstructure. In this article, the generation of simulation models using this modelling method and the necessary adaptation of the models concerning microstructural features to consider, for example, anisotropic properties of the foam, are described. Furthermore, simulations are performed to investigate the mechanical performance of the foam models and to compare the results with several analytical models and experimental data. Finally, conclusions regarding the applicability and possible further extensions of the model are provided.
在这项研究中,介绍了一种基于计算机断层扫描(CT)测量结果生成低密度闭孔泡沫的有限元模拟模型的方法。就建模和计算工作而言,创建这种模拟模型可能非常昂贵。因此,开发了一种基于CT数据和Voronoi图的组合建模技术,可以最大限度地减少这种工作量,但仍然可以生成具有真实微观结构的模拟模型。在本文中,描述了使用这种建模方法生成的仿真模型,以及考虑泡沫的各向异性等微观结构特征的模型的必要调整。此外,模拟研究了泡沫模型的力学性能,并将结果与几种分析模型和实验数据进行了比较。最后,对模型的适用性和可能的进一步推广给出了结论。
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引用次数: 6
A machine learning approach to estimate the strain energy absorption in expanded polystyrene foams 一种估计膨胀聚苯乙烯泡沫应变能吸收的机器学习方法
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-05-29 DOI: 10.1177/0021955X211021014
Alejandro E. Rodríguez-Sánchez, H. Plascencia-Mora
Traditional modeling of mechanical energy absorption due to compressive loadings in expanded polystyrene foams involves mathematical descriptions that are derived from stress/strain continuum mechanics models. Nevertheless, most of those models are either constrained using the strain as the only variable to work at large deformation regimes and usually neglect important parameters for energy absorption properties such as the material density or the rate of the applying load. This work presents a neural-network-based approach that produces models that are capable to map the compressive stress response and energy absorption parameters of an expanded polystyrene foam by considering its deformation, compressive loading rates, and different densities. The models are trained with ground-truth data obtained in compressive tests. Two methods to select neural network architectures are also presented, one of which is based on a Design of Experiments strategy. The results show that it is possible to obtain a single artificial neural networks model that can abstract stress and energy absorption solution spaces for the conditions studied in the material. Additionally, such a model is compared with a phenomenological model, and the results show than the neural network model outperforms it in terms of prediction capabilities, since errors around 2% of experimental data were obtained. In this sense, it is demonstrated that by following the presented approach is possible to obtain a model capable to reproduce compressive polystyrene foam stress/strain data, and consequently, to simulate its energy absorption parameters.
传统的基于压缩载荷的膨胀聚苯乙烯泡沫材料的机械能量吸收模型,涉及从应力/应变连续介质力学模型中导出的数学描述。然而,这些模型中的大多数要么使用应变作为在大变形状态下工作的唯一变量,要么通常忽略了能量吸收特性的重要参数,如材料密度或施加载荷的速率。这项工作提出了一种基于神经网络的方法,该方法通过考虑其变形、压缩加载率和不同密度,产生能够映射膨胀聚苯乙烯泡沫的压应力响应和能量吸收参数的模型。这些模型是用压缩试验中获得的真实数据进行训练的。提出了两种选择神经网络结构的方法,其中一种是基于实验设计策略。结果表明,可以获得一个单一的人工神经网络模型,该模型可以抽象出材料中所研究条件下的应力和能量吸收解空间。此外,将该模型与现象学模型进行了比较,结果表明,神经网络模型在预测能力方面优于现象学模型,因为获得的实验数据误差约为2%。在这个意义上,它证明了,通过遵循提出的方法是可能获得一个模型能够再现压缩聚苯乙烯泡沫的应力/应变数据,因此,模拟其能量吸收参数。
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引用次数: 6
Characteristics of pre-strained polyisocyanurate foam: Deformation recovery and compressive mechanical behavior at cryogenic temperature 预应变聚异氰脲酸酯泡沫的特性:低温下的变形恢复和压缩力学行为
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-05-25 DOI: 10.1177/0021955X211020293
Seul-Kee Kim, Jeong-Dae Kim, Dong-Ha Lee, Jeong‐Hyeon Kim, Jaemyung Lee
In this study, mechanical characteristics of pre-strained polyisocyanurate foam were investigated based on the uniaxial compression test. The compression test procedure was divided into two steps: pre-straining and the typical compression test for the recovered specimen. To evaluate the effect of pre-straining, four different compressive strains were considered, and the temperature and the strain rate dependencies on its mechanical characteristics were analyzed. Test results showed that the recovery ratio decreased substantially for 0.85 (ambient temperature) and 0.25 (cryogenic temperature), and polyisocyanurate foam pre-strained at cryogenic temperature revealed an earlier start of densification. Based on the deformation mechanism of the polymeric foam, the collapse of cells in the pre-strained polyisocyanurate foam was addressed to explain the distinguished features in compressive mechanical characteristics regarding test conditions.
在单轴压缩试验的基础上,研究了预应变聚异氰脲酸酯泡沫的力学特性。压缩试验分为预应变试验和典型压缩试验两步。为了评价预应变的效果,考虑了4种不同的压缩应变,分析了温度和应变速率对其力学特性的依赖关系。试验结果表明,在0.85(常温)和0.25(低温)条件下,回复率明显降低,低温预应变的聚异氰脲酸酯泡沫开始致密化的时间提前。基于聚合物泡沫的变形机理,研究了预应变聚异氰脲酸酯泡沫中细胞的崩塌现象,以解释不同试验条件下压缩力学特性的显著特征。
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引用次数: 1
Solid-state foaming of acrylonitrile butadiene styrene through microcellular 3D printing process 利用微孔3D打印技术制备丙烯腈-丁二烯-苯乙烯固态发泡
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-05-04 DOI: 10.1177/0021955X211009443
Rupesh Dugad, G. Radhakrishna, A. Gandhi
The lightweight products with superior specific strength are in great demand in numerous applications such as automotive, aerospace, biomedical, sports, etc. This work focussed on the manufacturing of lightweight products using the cellular three dimensional (3D) printing process. In this work, the continuous microcellular morphology has been developed in a single foamed filament using 3 D printing of carbon-di-oxide (CO2) saturated acrylonitrile butadiene styrene (ABS) filaments. The microcellular structures with average cell size in the range of 6–1040 µm were developed. The influence of printing parameters; nozzle temperature, feed rate, and flow rate on the foam characteristics and cell morphology at different levels were investigated. The different kinds of observed foamed extrudate irregularities were discussed.
具有优异比强度的轻量化产品在汽车、航空航天、生物医学、体育等众多应用中都有很大的需求。这项工作的重点是使用蜂窝三维(3D)打印工艺制造轻质产品。在这项工作中,使用二氧化碳饱和丙烯腈-丁二烯-苯乙烯(ABS)长丝的3d打印技术,在单个泡沫长丝中开发了连续的微细胞形态。得到了平均细胞尺寸为6 ~ 1040µm的微细胞结构。印刷参数的影响;研究了喷嘴温度、进料速度和流量对不同水平泡沫特性和细胞形态的影响。讨论了所观察到的各种泡沫挤出物的不规则性。
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引用次数: 2
Patents May issue 专利可以发布
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-05-01 DOI: 10.1177/0021955X211010586
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引用次数: 0
Morphological, thermal and mechanical properties of recycled HDPE foams via rotational molding 循环成型再生HDPE泡沫塑料的形态、热、机械性能
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-04-29 DOI: 10.1177/0021955X211013793
Y. Dou, D. Rodrigue
In this study, foamed recycled high density polyethylene (rHDPE) parts were produced by rotational molding using different concentration (0 to 1% wt.) of a chemical blowing agent (CBA) based on azodicarbonamide. From the samples produced, a complete morphological, thermal and mechanical characterization was performed. The morphological analysis showed a gradual increase in the average cell size, while the cell density firstly increased and then decreased with increasing CBA content. As expected, increasing the CBA content decreased the foam density as well as the thermal conductivity. Although increasing the CBA content decreased both tensile and flexural properties, the impact strength showed a similar trend as the cell density with an optimum CBA content around 0.1% wt. Finally, neat rHDPE samples were also produced by compression molding. The results showed negligible differences between the rotomolded and compression molded properties indicating that optimal rotomolding conditions were selected. These results confirm the possibility of using 100% recycled polymers to produce rotomolded foam parts.
在这项研究中,泡沫回收高密度聚乙烯(rHDPE)部件是通过旋转成型使用不同浓度(0至1%重量)的化学发泡剂(CBA)基于偶氮二酰胺。从产生的样品中,进行了完整的形态学,热学和力学表征。形态学分析表明,随着CBA含量的增加,细胞平均大小逐渐增大,细胞密度先增大后减小。正如预期的那样,CBA含量的增加降低了泡沫密度和导热系数。虽然增加CBA含量会降低拉伸和弯曲性能,但当CBA含量在0.1% wt左右时,冲击强度与细胞密度呈相似趋势。最后,通过压缩成型也可以生产出整齐的rHDPE样品。结果表明,滚塑和压缩成型性能之间的差异可以忽略不计,这表明选择了最佳的滚塑条件。这些结果证实了使用100%回收聚合物生产滚塑泡沫部件的可能性。
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引用次数: 7
Cellular Bi2O3/natural rubber composites for light-weight and lead-free gamma-shielding materials and their properties under gamma irradiation 蜂窝状Bi2O3/天然橡胶复合材料的轻质无铅屏蔽材料及其在γ辐射下的性能
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-04-26 DOI: 10.1177/0021955X21997353
Phakamat Limarun, T. Markpin, N. Sombatsompop, E. Wimolmala, K. Saenboonruang
This work investigated the effects of a radiation-protective filler, namely bismuth oxide (Bi2O3), and blowing agents, namely azodicarbonamide (ADC) and oxy-bis (benzene sulfonyl) hydrazide (OBSH), on gamma attenuation and the mechanical, physical, and morphological properties of cellular natural rubber (NR) composites for potential use as light-weight and lead-free gamma-shielding materials. The contents of Bi2O3 were varied from 100 to 300 and 500 parts per hundred of rubber by weight (phr) and the contents of ADC or OBSH were varied from 0 to 8 and 16 phr. The results indicated that the addition of Bi2O3 enhanced the overall gamma-shielding ability, density, tensile modulus, and hardness (Shore OO), but lowered the tensile strength and elongation at break. On the other hand, the addition of ADC or OBSH resulted in decreases in the density, linear attenuation coefficient (μ), and overall tensile properties but an increase in the mass attenuation coefficient (μm), with ADC producing better mechanical properties than samples with OBSH. In addition, investigations on the properties of the cellular Bi2O3/NR composites under additional 35 kGy and 70 kGy gamma irradiation revealed that the irradiated samples had increased density, tensile modulus, and hardness (Shore OO), but decreased tensile strength, elongation at break, and μm after such ageing. In conclusion, the overall results suggested that the developed cellular Bi2O3/NR composites not only had efficient and promising gamma-shielding and mechanical properties but also offered comfort and light-weight to users, which could potentially reduce discomforts caused by wearing heavier conventional radiation-protective equipment.
本研究研究了辐射防护填料,即氧化铋(Bi2O3)和发泡剂,即偶氮二甲酰胺(ADC)和氧-双(苯磺酰)肼(OBSH)对细胞天然橡胶(NR)复合材料的γ衰减和机械、物理和形态性能的影响,这些复合材料有望作为轻质无铅γ屏蔽材料。Bi2O3的含量变化范围为100 ~ 300和500 /橡胶重量(phr), ADC或OBSH的含量变化范围为0 ~ 8和16 /橡胶重量。结果表明,Bi2O3的加入提高了合金的总体屏蔽能力、密度、拉伸模量和硬度(邵氏硬度),但降低了合金的抗拉强度和断裂伸长率。另一方面,添加ADC或OBSH后,材料的密度、线性衰减系数(μ)和整体拉伸性能均有所降低,但质量衰减系数(μm)有所增加,且ADC的力学性能优于添加OBSH的样品。此外,在35 kGy和70 kGy的γ辐照下,研究了细胞状Bi2O3/NR复合材料的性能,发现辐照样品的密度、拉伸模量和硬度(Shore OO)增加,但拉伸强度、断裂伸长率和μm降低。总之,总体结果表明,所开发的蜂窝Bi2O3/NR复合材料不仅具有高效和有前途的γ屏蔽和机械性能,而且具有舒适性和轻质性,这可能会减少佩戴较重的传统辐射防护设备所带来的不适。
{"title":"Cellular Bi2O3/natural rubber composites for light-weight and lead-free gamma-shielding materials and their properties under gamma irradiation","authors":"Phakamat Limarun, T. Markpin, N. Sombatsompop, E. Wimolmala, K. Saenboonruang","doi":"10.1177/0021955X21997353","DOIUrl":"https://doi.org/10.1177/0021955X21997353","url":null,"abstract":"This work investigated the effects of a radiation-protective filler, namely bismuth oxide (Bi2O3), and blowing agents, namely azodicarbonamide (ADC) and oxy-bis (benzene sulfonyl) hydrazide (OBSH), on gamma attenuation and the mechanical, physical, and morphological properties of cellular natural rubber (NR) composites for potential use as light-weight and lead-free gamma-shielding materials. The contents of Bi2O3 were varied from 100 to 300 and 500 parts per hundred of rubber by weight (phr) and the contents of ADC or OBSH were varied from 0 to 8 and 16 phr. The results indicated that the addition of Bi2O3 enhanced the overall gamma-shielding ability, density, tensile modulus, and hardness (Shore OO), but lowered the tensile strength and elongation at break. On the other hand, the addition of ADC or OBSH resulted in decreases in the density, linear attenuation coefficient (μ), and overall tensile properties but an increase in the mass attenuation coefficient (μm), with ADC producing better mechanical properties than samples with OBSH. In addition, investigations on the properties of the cellular Bi2O3/NR composites under additional 35 kGy and 70 kGy gamma irradiation revealed that the irradiated samples had increased density, tensile modulus, and hardness (Shore OO), but decreased tensile strength, elongation at break, and μm after such ageing. In conclusion, the overall results suggested that the developed cellular Bi2O3/NR composites not only had efficient and promising gamma-shielding and mechanical properties but also offered comfort and light-weight to users, which could potentially reduce discomforts caused by wearing heavier conventional radiation-protective equipment.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"139 1","pages":"285 - 303"},"PeriodicalIF":2.5,"publicationDate":"2021-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90154000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Effect of tris(1-chloro-2-propyl)phosphate in combination with aluminum hypophosphite and melamine polyphosphate on flame retardancy and thermal decomposition of rigid polyurethane foams 磷酸三(1-氯-2-丙基)与次磷酸铝和聚磷酸三聚氰胺复合对硬质聚氨酯泡沫的阻燃性和热分解性能的影响
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-04-06 DOI: 10.1177/0021955X211001957
Daifang Xu, Kejing Yu, K. Qian, Weiguo Zhao
RPUF with tris(1-chloro-2-propyl)phosphate (TCPP), melamine polyphosphate (MPP) and aluminum hypophosphite (AHP) alone, as well as their binary and ternary blends, were prepared via a one-step process. The effect of TCPP in combination with AHP and MPP on flame retardancy and thermal decomposition in the RPUF has been investigated. The results show that adding TCPP, MPP and AHP into RPUF simultaneously can significantly ensure the uniform cell structure, enhance the compressive strength, thermal stability and fire resistance of RPUF, decrease the thermal conductivity, the release of toxic HCN at high temperature. TGA results indicate that partial substitution of TCPP with MPP and AHP could improve the char residue. When the content of TCPP is 10 wt%, the optimal ratio of MPP and DPER was 1/2, the TCPP10/MPP3.3/AHP6.7/RPUF sample reached a V1 rating in vertical UL-94 test with a limiting oxygen index of 27.4%. The compressive strength and specific compressive strength (compressive strength/density) for TCPP10/MPP3.3/AHP6.7/RPUF sample increased about 82.6% and 44.3% compared to that of pure RPUF, respectively. The cone calorimeter test results showed that adding EG, MPP and AHP into RPUF simultaneously can significantly decrease the heat release rate (HRR), total heat release (THR) and smoke emission behavior of RPUF sample. Based on these facts, a potential flame-retardant mechanism was proposed.
采用一步法制备了三(1-氯-2-丙基)磷酸(TCPP)、三聚氰胺聚磷酸(MPP)和次磷酸铝(AHP)及其二元和三元共混物的RPUF。研究了TCPP与AHP和MPP复合对RPUF中阻燃性和热分解的影响。结果表明,在RPUF中同时加入TCPP、MPP和AHP,可以显著保证RPUF的胞体结构均匀,提高RPUF的抗压强度、热稳定性和耐火性能,降低其导热系数,减少高温下有毒HCN的释放。TGA结果表明,用MPP和AHP部分替代TCPP可以改善炭残留。当TCPP含量为10 wt%, MPP与DPER的最佳配比为1/2时,在UL-94垂直试验中,TCPP10/MPP3.3/AHP6.7/RPUF样品达到V1级,极限氧指数为27.4%。与纯RPUF相比,TCPP10/MPP3.3/AHP6.7/RPUF样品的抗压强度和比抗压强度(抗压强度/密度)分别提高了82.6%和44.3%。锥形量热计测试结果表明,在RPUF中同时添加EG、MPP和AHP,可显著降低RPUF样品的放热率(HRR)、总放热率(THR)和排烟行为。基于这些事实,提出了一种潜在的阻燃机理。
{"title":"Effect of tris(1-chloro-2-propyl)phosphate in combination with aluminum hypophosphite and melamine polyphosphate on flame retardancy and thermal decomposition of rigid polyurethane foams","authors":"Daifang Xu, Kejing Yu, K. Qian, Weiguo Zhao","doi":"10.1177/0021955X211001957","DOIUrl":"https://doi.org/10.1177/0021955X211001957","url":null,"abstract":"RPUF with tris(1-chloro-2-propyl)phosphate (TCPP), melamine polyphosphate (MPP) and aluminum hypophosphite (AHP) alone, as well as their binary and ternary blends, were prepared via a one-step process. The effect of TCPP in combination with AHP and MPP on flame retardancy and thermal decomposition in the RPUF has been investigated. The results show that adding TCPP, MPP and AHP into RPUF simultaneously can significantly ensure the uniform cell structure, enhance the compressive strength, thermal stability and fire resistance of RPUF, decrease the thermal conductivity, the release of toxic HCN at high temperature. TGA results indicate that partial substitution of TCPP with MPP and AHP could improve the char residue. When the content of TCPP is 10 wt%, the optimal ratio of MPP and DPER was 1/2, the TCPP10/MPP3.3/AHP6.7/RPUF sample reached a V1 rating in vertical UL-94 test with a limiting oxygen index of 27.4%. The compressive strength and specific compressive strength (compressive strength/density) for TCPP10/MPP3.3/AHP6.7/RPUF sample increased about 82.6% and 44.3% compared to that of pure RPUF, respectively. The cone calorimeter test results showed that adding EG, MPP and AHP into RPUF simultaneously can significantly decrease the heat release rate (HRR), total heat release (THR) and smoke emission behavior of RPUF sample. Based on these facts, a potential flame-retardant mechanism was proposed.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"216 1","pages":"263 - 284"},"PeriodicalIF":2.5,"publicationDate":"2021-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77002163","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Evaluating the gas-laden ability of polymer melt under atmospheric conditions using a modified torque rheometer 用改进的扭矩流变仪评估常压条件下聚合物熔体的载气能力
IF 2.5 4区 工程技术 Q2 CHEMISTRY, APPLIED Pub Date : 2021-03-05 DOI: 10.1177/0021955X21997351
Xing-Yu Mei, Ying‐Guo Zhou, Hongda Sun, Binbin Dong, Chun-tai Liu, L. Turng
To investigate the effects of incorporating gas and the associated influencing factors on polymer melt, a method of evaluating the gas-laden ability using modified rheometric measurements was proposed. In this study, common and widely used thermoplastic materials—polypropylene (PP) and high-density polyethylene (HDPE), and their blends with different weight ratios—were selected, and the rheological properties of neat melt and gas-laden melts were tested using a modified torque rheometer. The foamed samples were also produced using a regular injection-molding machine, and the foamed morphology was examined by scanning electron microscope (SEM). The comparison of rheological curves of neat melt and gas-laden melt indicated that the incorporation of gas influenced the rheological properties of the gas-laden polymer melts as evidenced by a decrease of zero-rotational torque and an increase in the melt flow index. The results also suggested that the gas-laden ability of polymer melt could be evaluated quantitatively by the decay (due to desorption) of gas using the modified rheological measurement method. This study also demonstrated that the gas-laden ability can be used to predict the foaming behavior of polymer melts.
为了研究掺入气体及其相关影响因素对聚合物熔体的影响,提出了一种用改进流变法评价聚合物熔体载气能力的方法。本研究选择了常用和广泛使用的热塑性材料聚丙烯(PP)和高密度聚乙烯(HDPE)及其不同重量比的共混物,并使用改进的扭矩流变仪测试了纯熔体和含气熔体的流变特性。采用常规注塑机制备泡沫样品,并通过扫描电镜(SEM)观察泡沫形貌。对纯熔体和含气熔体流变曲线的比较表明,气体的加入影响了含气聚合物熔体的流变特性,表现为零转矩的减小和熔体流动指数的增加。结果还表明,采用改进的流变学测量方法,可以通过气体的衰变(由于解吸)来定量评价聚合物熔体的载气能力。该研究还表明,载气能力可以用来预测聚合物熔体的发泡行为。
{"title":"Evaluating the gas-laden ability of polymer melt under atmospheric conditions using a modified torque rheometer","authors":"Xing-Yu Mei, Ying‐Guo Zhou, Hongda Sun, Binbin Dong, Chun-tai Liu, L. Turng","doi":"10.1177/0021955X21997351","DOIUrl":"https://doi.org/10.1177/0021955X21997351","url":null,"abstract":"To investigate the effects of incorporating gas and the associated influencing factors on polymer melt, a method of evaluating the gas-laden ability using modified rheometric measurements was proposed. In this study, common and widely used thermoplastic materials—polypropylene (PP) and high-density polyethylene (HDPE), and their blends with different weight ratios—were selected, and the rheological properties of neat melt and gas-laden melts were tested using a modified torque rheometer. The foamed samples were also produced using a regular injection-molding machine, and the foamed morphology was examined by scanning electron microscope (SEM). The comparison of rheological curves of neat melt and gas-laden melt indicated that the incorporation of gas influenced the rheological properties of the gas-laden polymer melts as evidenced by a decrease of zero-rotational torque and an increase in the melt flow index. The results also suggested that the gas-laden ability of polymer melt could be evaluated quantitatively by the decay (due to desorption) of gas using the modified rheological measurement method. This study also demonstrated that the gas-laden ability can be used to predict the foaming behavior of polymer melts.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"30 1","pages":"237 - 261"},"PeriodicalIF":2.5,"publicationDate":"2021-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75607456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
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Journal of Cellular Plastics
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