Pub Date : 2023-05-02DOI: 10.1177/0021955x231175179
E. Emir, Erkan Bahçe
In recent years, triple periodic minimal surfaces (TPMS) have attracted attention in many applications such as biomaterials, aerospace, defense industry etc. lightweight components with high strength and functionally graded material (FGM). In particular, the mechanical properties and deformation behavior of these structures under load should be examined. In this study, it was aimed to evaluate the manufacturability and mechanical performance of fixed pore size and functional graded porosity (FGP) lattice structures produced by fused deposition modelling (FDM) method. TPMS primitive and gyroid lattice structures designed in the dimensions of 20 × 20 × 20 mm with fixed 20% pore size and functional graded (FG) from 20% to 40% pore size were used in the experiments. In order to reveal the effects of pore size on mechanical performance, uniaxial compression tests were carried out. In addition, for the validation of the experimental results, compression tests with the finite element method (FEM) were simulated for each sample. In the two different pore size changes tested in the study, the gyroid lattice structure showed the highest mechanical performance compared to the primitive lattice structure. In addition, the FEM results were in good agreement with the experimental results.
{"title":"Investigation of the mechanical properties triple periodic minimal surfaces lattice structures with functional graded of porosity","authors":"E. Emir, Erkan Bahçe","doi":"10.1177/0021955x231175179","DOIUrl":"https://doi.org/10.1177/0021955x231175179","url":null,"abstract":"In recent years, triple periodic minimal surfaces (TPMS) have attracted attention in many applications such as biomaterials, aerospace, defense industry etc. lightweight components with high strength and functionally graded material (FGM). In particular, the mechanical properties and deformation behavior of these structures under load should be examined. In this study, it was aimed to evaluate the manufacturability and mechanical performance of fixed pore size and functional graded porosity (FGP) lattice structures produced by fused deposition modelling (FDM) method. TPMS primitive and gyroid lattice structures designed in the dimensions of 20 × 20 × 20 mm with fixed 20% pore size and functional graded (FG) from 20% to 40% pore size were used in the experiments. In order to reveal the effects of pore size on mechanical performance, uniaxial compression tests were carried out. In addition, for the validation of the experimental results, compression tests with the finite element method (FEM) were simulated for each sample. In the two different pore size changes tested in the study, the gyroid lattice structure showed the highest mechanical performance compared to the primitive lattice structure. In addition, the FEM results were in good agreement with the experimental results.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"5 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2023-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79756073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-23DOI: 10.1177/0021955X231166007
Ngoc Uy Lan Du, C. Bethke, Shuaiping Gong, V. Altstaedt, Holger Ruckdaeschel
The use of carbamate to foam epoxy depends significantly on the precured modulus to stabilize the cellular structure. The optimum precured modulus is developed from the reaction of epoxy resin and the neat amine. The selection of the neat amine relies on its reaction temperature with epoxy, which is required to be below the decomposition temperature of carbamate. This study investigates the effect of three different neat amines on the rheological behavior of foaming epoxy-carbamate-amine. They are bisphenol-A diglycidyl ether epoxy (DGEBA), isophorone diamine carbamate (IDPA.CO2), N-aminoethylpiperazine (AEP), 2,4-Diamino-1-methyl-cyclohexan (DMC) and isophorone diamine (IDPA). The mixtures of DGEBA-amine-carbamate are filled in 25% and 75% of the volume of a closed mold. Precuring is carried out at 60°C for 2 h. The foaming and complete curing are conducted at 180°C for 1 h. Having H-active at piperazine, AEP reacts with DGEBA faster and develops a higher precured modulus compared to DMC and IDPA. It is important to note that DGEBA-AEP-IDPA.CO2 exhibits viscoelastic behavior beyond 138°C, seen by its rheological storage modulus lower than loss modulus and its tan delta larger than 1. The reaction between DGEBA and the H-active piperazine of AEP leads only to linear linkage and is unable to further crosslink compared to the primary amine (-NH2). This results in a lower glass transition temperature Tg of DGEBA-AEP-IPDA.CO2. The effect of amine on foaming is more obviously at 25% filling level. DGEBA-AEP-IPDA.CO2 has more spherical and homogeneous cellular structure and the density of 285 kg/m3. Having quite similar chemical structure, both DGEBA-DMC-IPDA.CO2 and DGEBA-IPDA-IPDA.CO2 produce the epoxy foams having cell-interconnection and coalescence; their densities are also similar 301 kg/m3 and 305 kg/m3, respectively. All the foams are closed-cell at 75% of filling level. The cell morphologies are well reflecting the foaming modulus and tan delta behavior.
{"title":"Foaming epoxy-amine-carbamate: The effect of different neat amines on rheological and cellular morphology","authors":"Ngoc Uy Lan Du, C. Bethke, Shuaiping Gong, V. Altstaedt, Holger Ruckdaeschel","doi":"10.1177/0021955X231166007","DOIUrl":"https://doi.org/10.1177/0021955X231166007","url":null,"abstract":"The use of carbamate to foam epoxy depends significantly on the precured modulus to stabilize the cellular structure. The optimum precured modulus is developed from the reaction of epoxy resin and the neat amine. The selection of the neat amine relies on its reaction temperature with epoxy, which is required to be below the decomposition temperature of carbamate. This study investigates the effect of three different neat amines on the rheological behavior of foaming epoxy-carbamate-amine. They are bisphenol-A diglycidyl ether epoxy (DGEBA), isophorone diamine carbamate (IDPA.CO2), N-aminoethylpiperazine (AEP), 2,4-Diamino-1-methyl-cyclohexan (DMC) and isophorone diamine (IDPA). The mixtures of DGEBA-amine-carbamate are filled in 25% and 75% of the volume of a closed mold. Precuring is carried out at 60°C for 2 h. The foaming and complete curing are conducted at 180°C for 1 h. Having H-active at piperazine, AEP reacts with DGEBA faster and develops a higher precured modulus compared to DMC and IDPA. It is important to note that DGEBA-AEP-IDPA.CO2 exhibits viscoelastic behavior beyond 138°C, seen by its rheological storage modulus lower than loss modulus and its tan delta larger than 1. The reaction between DGEBA and the H-active piperazine of AEP leads only to linear linkage and is unable to further crosslink compared to the primary amine (-NH2). This results in a lower glass transition temperature Tg of DGEBA-AEP-IPDA.CO2. The effect of amine on foaming is more obviously at 25% filling level. DGEBA-AEP-IPDA.CO2 has more spherical and homogeneous cellular structure and the density of 285 kg/m3. Having quite similar chemical structure, both DGEBA-DMC-IPDA.CO2 and DGEBA-IPDA-IPDA.CO2 produce the epoxy foams having cell-interconnection and coalescence; their densities are also similar 301 kg/m3 and 305 kg/m3, respectively. All the foams are closed-cell at 75% of filling level. The cell morphologies are well reflecting the foaming modulus and tan delta behavior.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"35 1","pages":"231 - 247"},"PeriodicalIF":2.5,"publicationDate":"2023-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72681867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-08DOI: 10.1177/0021955X231162799
Ana P Sartori, H. L. Ornaghi Júnior, N. B. Guerra, P. Wander, M. Giovanela, Regina C Reis Nunes, Janaina da Silva Crespo
Sandwich composites are materials that have superior properties including low weight, high impact energy absorption and high thermal insulation features, compared to conventional materials. In this study, four different sandwich samples were explored for use in cold storage chambers. The composites were created using an injection molding process with polyurethane foam as the core and different materials (glass fiber reinforced polyester, galvanized steel, aluminum sheets and crimped aluminum) as face materials. Morphological, physical and mechanical properties were evaluated. An inexpensive and nondestructive method was used to determine the thermal behavior of the sandwich panels, and the surface temperature evolution was thermally monitored during the tests. In general, results showed that polyurethane had a homogeneous distribution of size and shape with closed cells, which can improve the retention of the insulating gas. Additionally, the compressive strength of polyurethane within the composites exhibited typical values to be used in specific applications. Thus, the sandwich with galvanized steel exhibited lower flexural strength, which provides more freedom in panel design. The overall heat transfer coefficient of the panels in the form of cubes presented values below the maximum limit requested by ABNT NBR-15457. Finally, the composite galvanized steel/polyurethane/galvanized steel achieved the best performance for use as a thermal insulation material in a cold storage chamber.
{"title":"Development and characterization of sandwich panels for thermal insulation in a cold storage chamber","authors":"Ana P Sartori, H. L. Ornaghi Júnior, N. B. Guerra, P. Wander, M. Giovanela, Regina C Reis Nunes, Janaina da Silva Crespo","doi":"10.1177/0021955X231162799","DOIUrl":"https://doi.org/10.1177/0021955X231162799","url":null,"abstract":"Sandwich composites are materials that have superior properties including low weight, high impact energy absorption and high thermal insulation features, compared to conventional materials. In this study, four different sandwich samples were explored for use in cold storage chambers. The composites were created using an injection molding process with polyurethane foam as the core and different materials (glass fiber reinforced polyester, galvanized steel, aluminum sheets and crimped aluminum) as face materials. Morphological, physical and mechanical properties were evaluated. An inexpensive and nondestructive method was used to determine the thermal behavior of the sandwich panels, and the surface temperature evolution was thermally monitored during the tests. In general, results showed that polyurethane had a homogeneous distribution of size and shape with closed cells, which can improve the retention of the insulating gas. Additionally, the compressive strength of polyurethane within the composites exhibited typical values to be used in specific applications. Thus, the sandwich with galvanized steel exhibited lower flexural strength, which provides more freedom in panel design. The overall heat transfer coefficient of the panels in the form of cubes presented values below the maximum limit requested by ABNT NBR-15457. Finally, the composite galvanized steel/polyurethane/galvanized steel achieved the best performance for use as a thermal insulation material in a cold storage chamber.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"46 1","pages":"215 - 230"},"PeriodicalIF":2.5,"publicationDate":"2023-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86916210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-01DOI: 10.1177/0021955X231165344
Jiankang Wang, Houjian Fa, Hongwei Lu
Thermoplastic polyurethane elastomer (TPU) foams were prepared using the high-pressure autoclave with supercritical fluid carbon dioxide (SC-CO2). The effects of foaming variables (i.e. saturation temperature, saturation pressure, and depressurization rate) on cellular structure and expansion ratio were investigated. The model between expansion ratio and foaming variables was constructed using the Box-Behnken design (BBD) of response surface methodology (RSM), and analysis of variance (ANOVA) was conducted to evaluate the validity and significance of the model. Finally, the interactive effects of foaming variables on the expansion ratio were investigated, and the expansion ratios of maximum and center point from numerical model were verified by experiment. The result showed higher saturation pressure and depressurization rate resulted in the more uniform cellular structure and higher cell density, however the higher saturation temperature resulted in the bigger cell and nonuniform structure. The ranges of average cell diameter and cell density were 15.26–45.4 μm and 0.32 × 108 to 6.24 × 108 cells/cm3, respectively. The model obtained using BBD of RSM was valid to predict the expansion ratio in the design window. The saturation temperature was the most important factor influencing the expansion ratio. With the increase of saturation temperature, the expansion ratio always increases in the design window. The maximum expansion ratio from numerical optimization was 4.91, which was located at saturation temperature 190°C, saturation pressure 12.51 MPa, and depressurization rate 5 MPa/s, and the corresponding experiment value was 4.56. The error between them was 7.13%.
{"title":"Investigation into the effects of foaming variables on the cellular structure and expansion ratio of foamed TPU using response surface methodology","authors":"Jiankang Wang, Houjian Fa, Hongwei Lu","doi":"10.1177/0021955X231165344","DOIUrl":"https://doi.org/10.1177/0021955X231165344","url":null,"abstract":"Thermoplastic polyurethane elastomer (TPU) foams were prepared using the high-pressure autoclave with supercritical fluid carbon dioxide (SC-CO2). The effects of foaming variables (i.e. saturation temperature, saturation pressure, and depressurization rate) on cellular structure and expansion ratio were investigated. The model between expansion ratio and foaming variables was constructed using the Box-Behnken design (BBD) of response surface methodology (RSM), and analysis of variance (ANOVA) was conducted to evaluate the validity and significance of the model. Finally, the interactive effects of foaming variables on the expansion ratio were investigated, and the expansion ratios of maximum and center point from numerical model were verified by experiment. The result showed higher saturation pressure and depressurization rate resulted in the more uniform cellular structure and higher cell density, however the higher saturation temperature resulted in the bigger cell and nonuniform structure. The ranges of average cell diameter and cell density were 15.26–45.4 μm and 0.32 × 108 to 6.24 × 108 cells/cm3, respectively. The model obtained using BBD of RSM was valid to predict the expansion ratio in the design window. The saturation temperature was the most important factor influencing the expansion ratio. With the increase of saturation temperature, the expansion ratio always increases in the design window. The maximum expansion ratio from numerical optimization was 4.91, which was located at saturation temperature 190°C, saturation pressure 12.51 MPa, and depressurization rate 5 MPa/s, and the corresponding experiment value was 4.56. The error between them was 7.13%.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"158 1","pages":"147 - 164"},"PeriodicalIF":2.5,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86353046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-03-01DOI: 10.1177/0021955X231165343
I. Koch, Gina Preiss, M. Müller-Pabel, B. Grüber, Johannes Meuchelböck, H. Ruckdäschel, M. Gude
Closed-cell bead foams with their hierarchical geometrical structure are a challenge for statistical reconstruction and finite element modelling. For the purpose of providing the fundamental micro- and meso-structural descriptors - wall thickness, cell as well as bead volume and sphericity - of expanded polypropylene bead foams of different density, 3D-images from X-ray computed tomography are analyzed. A detailed description of development and application of an image analysis methodology for the determination of feature distributions from CT-scans of different level of detail is provided. The methods are based on off-the-shelf algorithms provided by the open-source package distribution FIJI. It should be highlighted, that beside essential methods such as thresholding, euclidean distance and watershed transformation here the Trainable WEKA segmentation is applied for separating material phases in the images. Although the methods elaborated are generally very case sensitive, the reader benefits from the validation strategies applied, so that development of individual methods into the direction of reliability, repeatability and automation is supported.
{"title":"Analysis of density-dependent bead and cell structure of expanded polypropylene bead foams from X-ray computed tomography of different resolution","authors":"I. Koch, Gina Preiss, M. Müller-Pabel, B. Grüber, Johannes Meuchelböck, H. Ruckdäschel, M. Gude","doi":"10.1177/0021955X231165343","DOIUrl":"https://doi.org/10.1177/0021955X231165343","url":null,"abstract":"Closed-cell bead foams with their hierarchical geometrical structure are a challenge for statistical reconstruction and finite element modelling. For the purpose of providing the fundamental micro- and meso-structural descriptors - wall thickness, cell as well as bead volume and sphericity - of expanded polypropylene bead foams of different density, 3D-images from X-ray computed tomography are analyzed. A detailed description of development and application of an image analysis methodology for the determination of feature distributions from CT-scans of different level of detail is provided. The methods are based on off-the-shelf algorithms provided by the open-source package distribution FIJI. It should be highlighted, that beside essential methods such as thresholding, euclidean distance and watershed transformation here the Trainable WEKA segmentation is applied for separating material phases in the images. Although the methods elaborated are generally very case sensitive, the reader benefits from the validation strategies applied, so that development of individual methods into the direction of reliability, repeatability and automation is supported.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"37 1","pages":"165 - 184"},"PeriodicalIF":2.5,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79890736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-02-24DOI: 10.1177/0021955X231152680
Martin Hamann, S. Andrieux, M. Schütte, Daniel Telkemeyer, M. Ranft, W. Drenckhan
The interest in polyurethane rigid (PUR) foams as potent thermally insulating materials for a wide range of applications continues to grow as the minimization of CO2 emissions has become a global issue. Controlling the thermal insulation efficiency of PUR foams starts with the control of their morphology. Although the presence of micrometric air bubbles originating from air entrainment during the blending of the PU reactive mixture has been shown to influence the final PUR foam morphology, detailed experimental investigations on how exactly they affect the final PUR foam pore size are still lacking. To fill this gap, we use a double-syringe mixing device, which allows to control the number of air bubbles generated during a first air entrainment step, before using the same device to blend the reactive components in a sealed environment, avoiding further air entrainment. Keeping all experimental parameters constant except for the air bubble density in the reactive mixture, we can correlate changes of the final PUR foam morphology with the variation of the air bubble density in the initially liquid reactive mixture. Our results confirm recent findings which suggest the presence of two different regimes of bubble nucleation and growth depending on the presence or absence of dispersed air bubbles in the liquid reactive mixture. Our study pushes those insights further by demonstrating an inverse relation between the air bubble density in the liquid reactive mixture and the final pore volume of the PUR foam. For example, at constant chemical formulation and blending conditions, we could vary the final pore size between 400–1600 μm simply by controlling the amount of pre-dispersed air bubbles within the system. We are confident that the presented approach may not only provide a valuable model experiment to scan formulations in R&D laboratories, but it may also provide suggestions for the optimization of industrial processes.
{"title":"Directing the pore size of rigid polyurethane foam via controlled air entrainment","authors":"Martin Hamann, S. Andrieux, M. Schütte, Daniel Telkemeyer, M. Ranft, W. Drenckhan","doi":"10.1177/0021955X231152680","DOIUrl":"https://doi.org/10.1177/0021955X231152680","url":null,"abstract":"The interest in polyurethane rigid (PUR) foams as potent thermally insulating materials for a wide range of applications continues to grow as the minimization of CO2 emissions has become a global issue. Controlling the thermal insulation efficiency of PUR foams starts with the control of their morphology. Although the presence of micrometric air bubbles originating from air entrainment during the blending of the PU reactive mixture has been shown to influence the final PUR foam morphology, detailed experimental investigations on how exactly they affect the final PUR foam pore size are still lacking. To fill this gap, we use a double-syringe mixing device, which allows to control the number of air bubbles generated during a first air entrainment step, before using the same device to blend the reactive components in a sealed environment, avoiding further air entrainment. Keeping all experimental parameters constant except for the air bubble density in the reactive mixture, we can correlate changes of the final PUR foam morphology with the variation of the air bubble density in the initially liquid reactive mixture. Our results confirm recent findings which suggest the presence of two different regimes of bubble nucleation and growth depending on the presence or absence of dispersed air bubbles in the liquid reactive mixture. Our study pushes those insights further by demonstrating an inverse relation between the air bubble density in the liquid reactive mixture and the final pore volume of the PUR foam. For example, at constant chemical formulation and blending conditions, we could vary the final pore size between 400–1600 μm simply by controlling the amount of pre-dispersed air bubbles within the system. We are confident that the presented approach may not only provide a valuable model experiment to scan formulations in R&D laboratories, but it may also provide suggestions for the optimization of industrial processes.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"53 1","pages":"201 - 214"},"PeriodicalIF":2.5,"publicationDate":"2023-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88510207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-02-23DOI: 10.1177/0021955X231161175
E. Moritzer, Felix Flachmann
Microcellular wood fiber reinforced polymers offer the possibility to reduce the use of fossil raw materials. In particular, thick-walled structures with thicknesses greater than 6 mm offer a high potential for weight savings. This study investigates the cell structures and mechanical properties of injection-molded test specimens. The influence of different thicknesses (6–10 mm) along with different chemical blowing agents (endothermic, exothermic) with varying dosages (0–2 wt%) is analyzed. The investigations reveal that exothermic chemical blowing agents form finer cells consistently to thin-walled structures than endothermic ones. Higher foaming agent content leads to higher pore fractions, with many small cells coalescing into a large open-pore cell network. The mechanical properties depend mainly on the pore content of the sample. The specific tensile properties deteriorate with the use of chemical blowing agents (CFA), whereas the sandwich structure produced with compact edge layers has a positive influence on the specific flexural properties.
{"title":"Morphological and mechanical properties of foamed thick-walled Wood-Plastic-Composite structures","authors":"E. Moritzer, Felix Flachmann","doi":"10.1177/0021955X231161175","DOIUrl":"https://doi.org/10.1177/0021955X231161175","url":null,"abstract":"Microcellular wood fiber reinforced polymers offer the possibility to reduce the use of fossil raw materials. In particular, thick-walled structures with thicknesses greater than 6 mm offer a high potential for weight savings. This study investigates the cell structures and mechanical properties of injection-molded test specimens. The influence of different thicknesses (6–10 mm) along with different chemical blowing agents (endothermic, exothermic) with varying dosages (0–2 wt%) is analyzed. The investigations reveal that exothermic chemical blowing agents form finer cells consistently to thin-walled structures than endothermic ones. Higher foaming agent content leads to higher pore fractions, with many small cells coalescing into a large open-pore cell network. The mechanical properties depend mainly on the pore content of the sample. The specific tensile properties deteriorate with the use of chemical blowing agents (CFA), whereas the sandwich structure produced with compact edge layers has a positive influence on the specific flexural properties.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"75 1","pages":"187 - 199"},"PeriodicalIF":2.5,"publicationDate":"2023-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83220707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A method using in-situ fibrillated polytetrafluoroethylene (PTFE) and octamethylenedicarboxylicdibenzoylhydrazide (TMC-300) supramolecular nucleator was presented to prepare low density polystyrene foams. This study used a torque rheometer in the molten compound preparation of PS/fibrillated-PTFE/TMC-300 composites. Scanning electron microscopy showed in-situ fibrillated polytetrafluoroethylene in Polystyrene melt and a nanofiber network with high aspect ratio. The formation of nanometer-sized fiber networks improved the melt viscoelasticity of matrices which promoted cell nucleation. As the results demonstrated, low-density foams with 11 μm average cell size were obtained using Polystyrene. The self-assembly nucleating agent TMC-300 was then introduced to the composite materials. TMC-300 and polytetrafluoroethylene as a composite cell nucleating agent were used in Polystyrene foams. Meanwhile, their nucleating efficiency was investigated. TMC-300 completed self-assembly in Polystyrene and served as composite nucleating agent in combination with polytetrafluoroethylene. Compared with the sample PS/PTFE-0.5, the average cell size of the sample PS/PTFE-0.5/TMC-2 had a reduction rate of 28.16% from 12.18 μm to 8.75 μm. The cell density increased by an order of magnitude. The composite nucleating agent was successful in controlling Polystyrene foam cell morphology, thus leading to the preparation of low-density Polystyrene microporous foams.
{"title":"Preparing low-Density microcellular polystyrene foam by in-Situ fibrillated PTFE and supramolecular nucleator TMC-300 in the presence of sc-CO2","authors":"Zhuolun Li, Xiangdong Wang, Yaqiao Wang, Shihong Chen","doi":"10.1177/0021955X231154619","DOIUrl":"https://doi.org/10.1177/0021955X231154619","url":null,"abstract":"A method using in-situ fibrillated polytetrafluoroethylene (PTFE) and octamethylenedicarboxylicdibenzoylhydrazide (TMC-300) supramolecular nucleator was presented to prepare low density polystyrene foams. This study used a torque rheometer in the molten compound preparation of PS/fibrillated-PTFE/TMC-300 composites. Scanning electron microscopy showed in-situ fibrillated polytetrafluoroethylene in Polystyrene melt and a nanofiber network with high aspect ratio. The formation of nanometer-sized fiber networks improved the melt viscoelasticity of matrices which promoted cell nucleation. As the results demonstrated, low-density foams with 11 μm average cell size were obtained using Polystyrene. The self-assembly nucleating agent TMC-300 was then introduced to the composite materials. TMC-300 and polytetrafluoroethylene as a composite cell nucleating agent were used in Polystyrene foams. Meanwhile, their nucleating efficiency was investigated. TMC-300 completed self-assembly in Polystyrene and served as composite nucleating agent in combination with polytetrafluoroethylene. Compared with the sample PS/PTFE-0.5, the average cell size of the sample PS/PTFE-0.5/TMC-2 had a reduction rate of 28.16% from 12.18 μm to 8.75 μm. The cell density increased by an order of magnitude. The composite nucleating agent was successful in controlling Polystyrene foam cell morphology, thus leading to the preparation of low-density Polystyrene microporous foams.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"78 1","pages":"125 - 146"},"PeriodicalIF":2.5,"publicationDate":"2023-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75526802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1177/0021955X221150863
X. Lan, Pengke Huang, Yunkai Chong, Fei Wu, Yaozhuo Su, Haibin Luo, Partrick C. Lee, Wenge Zheng
Expanded polypropylene (EPP) foams have showed wide applications in our daily life, such as automotive and packaging. Usually, autoclave foaming combined with steam-chest molding is the main artwork to prepare the high-precision EPP foam products. However, the foaming behavior of EPP and the excessive pressure required for molding still need to be further improved, which is great significance for energy saving and cost saving, etc. Herein, this study finds that adding a certain amount of polybutene-1 (PB-1) into the PP can help to reduce the temperature and pressure required for foaming/molding, and to broaden the foaming temperature. For example, in order to make the foam beads bonding well and with the expansion ratio of 20, the molding pressure should be higher than 2.7 bar for Neat PP foams, but just 1.5 bar for PP/PB-1 mixtures. Moreover, the effects of PB-1 content on the crystallization properties and foaming/molding behaviors of the PP/PB-1 bead foams are illustrated, and then the mechanical properties are also studied. Furthermore, the low-pressure foaming strategy presented here is beneficial for reducing the barriers of energy consumption and promoting the development of new bead foam materials.
{"title":"Autoclave foaming and steam-chest molding of polypropylene/polybutene-1 blend bead foams and their crystallization and mechanical properties","authors":"X. Lan, Pengke Huang, Yunkai Chong, Fei Wu, Yaozhuo Su, Haibin Luo, Partrick C. Lee, Wenge Zheng","doi":"10.1177/0021955X221150863","DOIUrl":"https://doi.org/10.1177/0021955X221150863","url":null,"abstract":"Expanded polypropylene (EPP) foams have showed wide applications in our daily life, such as automotive and packaging. Usually, autoclave foaming combined with steam-chest molding is the main artwork to prepare the high-precision EPP foam products. However, the foaming behavior of EPP and the excessive pressure required for molding still need to be further improved, which is great significance for energy saving and cost saving, etc. Herein, this study finds that adding a certain amount of polybutene-1 (PB-1) into the PP can help to reduce the temperature and pressure required for foaming/molding, and to broaden the foaming temperature. For example, in order to make the foam beads bonding well and with the expansion ratio of 20, the molding pressure should be higher than 2.7 bar for Neat PP foams, but just 1.5 bar for PP/PB-1 mixtures. Moreover, the effects of PB-1 content on the crystallization properties and foaming/molding behaviors of the PP/PB-1 bead foams are illustrated, and then the mechanical properties are also studied. Furthermore, the low-pressure foaming strategy presented here is beneficial for reducing the barriers of energy consumption and promoting the development of new bead foam materials.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"118 1","pages":"29 - 45"},"PeriodicalIF":2.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77416798","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2023-01-01DOI: 10.1177/0021955X231154620
A. S. Pareta, P.K. Singh, A. Sarkar, SK Panda
The fly ash (FA) particulates are used in this study to reinforce the polyurethane foam (PUF) core. The FA particles inclusion improves the mechanical performance of the PUF core under compression by increasing its modulus of elasticity. Low-velocity impacts have damage dynamics that are pretty similar to quasi-static indentation. Consequently, the indentation resistance capability of the PUF core is investigated for three types of indenter nose tips with varied FA wt. Percentages (flat-circular, hemispherical, and conical). The results reveal that the reinforced foam core’s resistance varies with reinforcement percentage under indentation. However, FA reinforcement to PUF does not necessarily improve indentation resistance. The damage mechanism of the PUF core under indentation has been evaluated for each type of indenter. The interaction of crushing, shear, and tear of the damaged surface with the change in indenter nose tip has been explained with 0–20% variation of FA particles. Scanning electron microscope (SEM) images are taken for the analysis of the damaged PUF core cross-section at the indented location. Earlier mechanical findings of the scatter in deformation behavior with the indenter nose tip geometry are substantiated by the SEM studies.
{"title":"Quasi-static indentation damage mechanics of PU foam core reinforced with fly ash particulate","authors":"A. S. Pareta, P.K. Singh, A. Sarkar, SK Panda","doi":"10.1177/0021955X231154620","DOIUrl":"https://doi.org/10.1177/0021955X231154620","url":null,"abstract":"The fly ash (FA) particulates are used in this study to reinforce the polyurethane foam (PUF) core. The FA particles inclusion improves the mechanical performance of the PUF core under compression by increasing its modulus of elasticity. Low-velocity impacts have damage dynamics that are pretty similar to quasi-static indentation. Consequently, the indentation resistance capability of the PUF core is investigated for three types of indenter nose tips with varied FA wt. Percentages (flat-circular, hemispherical, and conical). The results reveal that the reinforced foam core’s resistance varies with reinforcement percentage under indentation. However, FA reinforcement to PUF does not necessarily improve indentation resistance. The damage mechanism of the PUF core under indentation has been evaluated for each type of indenter. The interaction of crushing, shear, and tear of the damaged surface with the change in indenter nose tip has been explained with 0–20% variation of FA particles. Scanning electron microscope (SEM) images are taken for the analysis of the damaged PUF core cross-section at the indented location. Earlier mechanical findings of the scatter in deformation behavior with the indenter nose tip geometry are substantiated by the SEM studies.","PeriodicalId":15236,"journal":{"name":"Journal of Cellular Plastics","volume":"283 1","pages":"47 - 63"},"PeriodicalIF":2.5,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74762438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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