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A Novel Tris(2-aminoethyl)amine Based Tripodal Ligand: Synthesis and Solution Coordination Studies with Trivalent Iron and Chromium 一种新型三(2-氨基乙基)胺基三足配体:与三价铁和铬的合成及配位研究
Pub Date : 2016-11-23 DOI: 10.1155/2016/3757418
M. Baral, A. Gupta, Rifat Akbar, B. K. Kanungo
A novel tris(2-aminoethyl)amine (TREN) based tripodal ligand TRENOL (L) has been synthesized and characterized by elemental analysis and UV-VIS, IR, 1H, and 13C NMR spectroscopic methods. The coordination behaviour of the ligand with H
合成了一种新的三(2-氨基乙基)胺(TREN)基三足配体TRENOL (L),并通过元素分析、紫外可见光谱、红外光谱、1H和13C NMR等方法对其进行了表征。配体与H的配位行为
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引用次数: 3
Comparison of Surface and Structural Properties of Carbonaceous Materials Prepared by Chemical Activation of Tomato Paste Waste: The Effects of Activator Type and Impregnation Ratio 番茄酱废化学活化制备碳质材料的表面和结构性能比较:活化剂类型和浸渍比的影响
Pub Date : 2016-11-22 DOI: 10.1155/2016/8236238
N. Özbay, A. Yargic
Activated carbons were prepared by carbonization of tomato paste processing industry waste at 500°C followed by chemical activation with KOH, K2CO3, and HCl in N2 atmosphere at low temperature (500°C). The effects of different activating agents and impregnation ratios (25, 50, and 100 wt.%) on the materials’ characteristics were examined. Precursor, carbonized tomato waste (CTW), and activated carbons were characterized by using ultimate and proximate analysis, thermogravimetric analysis (TG/DTG), Fourier transform-infrared (FT-IR) spectroscopy, X-ray fluorescence (XRF) spectroscopy, point of zero charge measurements ( ), particle size analyzer, scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, nitrogen adsorption/desorption isotherms, and X-ray diffraction (XRD) analysis. Activation process improved pore formation and changed activated carbons’ surface characteristics. Activated carbon with the highest surface area (283 m3/g) was prepared by using 50 wt.% KOH as an activator. According to the experimental results, tomato paste waste could be used as an alternative precursor to produce low-cost activated carbon.
以番茄酱加工工业废料为原料,在500℃下碳化,然后在低温(500℃)的N2气氛中用KOH、K2CO3和HCl进行化学活化,制备了活性炭。考察了不同活化剂和浸渍率(25wt .%, 50%, 100wt .%)对材料性能的影响。采用极限和近似分析、热重分析(TG/DTG)、傅里叶变换红外(FT-IR)光谱、x射线荧光(XRF)光谱、零电荷点测量()、粒度分析仪、扫描电子显微镜(SEM)、能量色散x射线(EDX)光谱、氮吸附/解吸等温线和x射线衍射(XRD)分析对前驱体、碳化番茄废(CTW)和活性炭进行了表征。活化过程改善了活性炭的孔隙形成,改变了活性炭的表面特性。以50wt为原料制备了比表面积最高的活性炭(283 m3/g)。% KOH作为活化剂。根据实验结果,番茄酱废料可以作为生产低成本活性炭的替代前驱体。
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引用次数: 13
Synthesis, X-Ray Crystal Structure Study, Hirshfeld Surface Analysis, and Biological Activity of N-(2-amino-phenyl)-2-methyl-benzamide N-(2-氨基苯基)-2-甲基苯酰胺的合成、x射线晶体结构研究、Hirshfeld表面分析及生物活性研究
Pub Date : 2016-11-14 DOI: 10.1155/2016/5951013
Latha Rani Nagaraju, Lakshmi Ranganatha Venkataravanappa, S. Anandalwar, S. Khanum
The title compound crystallizes in monoclinic crystal system, with space group . The compound exhibits intermolecular interactions of the types N–H⋯N, C–H⋯O, and C–H⋯π; intramolecular interactions of the type N–H⋯N. The intercontacts are also studied using Hirshfeld surface analysis. The compound showed no remarkable antibacterial activity when screened against two gram-negative and two gram-positive bacteria.
标题化合物结晶为单斜晶系,具有空间群。该化合物表现出N - h⋯N、C-H⋯O和C-H⋯π类型的分子间相互作用;N - h⋯N型的分子内相互作用。用赫希菲尔德表面分析法研究了接触面。该化合物对两种革兰氏阴性菌和两种革兰氏阳性菌均无明显的抑菌活性。
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引用次数: 2
Saccharomyces cerevisiae Catalyzed Cyclocondensation Reaction: Synthesis of Pyrazoline 酿酒酵母催化的环缩合反应:吡唑啉的合成
Pub Date : 2016-10-25 DOI: 10.1155/2016/7425913
Nitesh D. Punyapreddiwar, A. Wankhade, S. Zodape, Umesh R. Pratap
A simple, efficient, and environment friendly method has been developed for the synthesis of pyrazoline by the cyclocondensation of chalcones and hydrazine hydrate using very cheaper catalyst, baker’s yeast (Saccharomyces cerevisiae). The 3,5-diphenyl pyrazolines are synthesized in moderate to good yield. The method also overcomes drawbacks of the previous pyrazoline synthetic methods and provides a new efficient route to 3,5-diphenyl pyrazoline derivatives.
研究了一种简单、高效、环保的查尔酮和水合肼环缩合合成吡唑啉的方法。以中高收率合成了3,5-二苯基吡唑啉。该方法也克服了以往吡唑啉合成方法的不足,为制备3,5-二苯基吡唑啉衍生物提供了一条新的高效途径。
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引用次数: 1
Theoretical Energy and Exergy Analyses of Proton Exchange Membrane Fuel Cell by Computer Simulation 质子交换膜燃料电池理论能量和火用分析的计算机模拟
Pub Date : 2016-09-18 DOI: 10.1155/2016/2684919
I. Gimba, A. Abdulkareem, A. Jimoh, A. Afolabi
A mathematical model of a proton exchange membrane fuel cell (PEMFC) was developed to investigate the effects of operating parameters such as temperature, anode and cathode pressures, reactants flow rates, membrane thickness, and humidity on the performance of the modelled fuel cell. The developed model consisted of electrochemical, heat energy and exergy components which were later simulated using a computer programme. The simulated model for the voltage output of the cell showed good conformity to the experimental results sourced from the literature and revealed that the operating pressure, temperature, and flow rate of the reactants positively affect the performance and efficiencies (energy and exergy) of the cell. The results also indicated that high membrane thickness above 150 μm is unfavourable to both the fuel cell performance and the cell energy and exergy efficiencies. The simulated results obtained on the influence of membrane humidity on the cell performance indicated that membrane humidity positively favours both the performance and energy and exergy efficiencies of the cell. It can therefore be inferred that the performance of the PEMFC and energy and exergy efficiencies of the cell are greatly influenced by the operating pressure, temperature, membrane thickness, membrane humidity, and the flow rates of fuel and oxidant.
建立了质子交换膜燃料电池(PEMFC)的数学模型,研究了温度、阳极和阴极压力、反应物流速、膜厚度和湿度等操作参数对模型燃料电池性能的影响。所建立的模型由电化学、热能和火用成分组成,随后用计算机程序对其进行了模拟。电池电压输出的模拟模型与文献实验结果吻合良好,表明反应物的操作压力、温度和流速对电池的性能和效率(能量和火用)有积极影响。研究结果还表明,膜厚度超过150 μm,不利于燃料电池的性能和电池的能量和火用效率。膜湿度对电池性能影响的模拟结果表明,膜湿度对电池的性能和能量效率都有积极的促进作用。由此可以推断,PEMFC的性能以及电池的能量和火用效率受到操作压力、温度、膜厚度、膜湿度以及燃料和氧化剂流量的极大影响。
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引用次数: 26
Emerging Photovoltaics: Organic, Copper Zinc Tin Sulphide, and Perovskite-Based Solar Cells 新兴光伏:有机、铜锌锡硫化物和钙钛矿基太阳能电池
Pub Date : 2016-09-06 DOI: 10.1155/2016/3971579
Shraavya Rao, Ankita Morankar, Himani Verma, P. Goswami
As the photovoltaics industry continues to grow rapidly, materials other than silicon are being explored. The aim is to develop technologies that use environmentally friendly, abundant materials, low-cost manufacturing processes without compromising on efficiencies and lifetimes. This paper discusses three of the emerging technologies, organic, copper zinc tin sulphide (CZTS), and perovskite-based solar cells, their advantages, and the possible challenges in making these technologies commercially available.
随着光伏产业的持续快速发展,人们正在探索硅以外的材料。其目标是开发使用环保、丰富的材料、低成本制造工艺而不影响效率和寿命的技术。本文讨论了有机、铜锌锡硫化物(CZTS)和钙钛矿基太阳能电池这三种新兴技术,它们的优势,以及使这些技术商业化可能面临的挑战。
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引用次数: 21
Preparation and Characterization of Chitosan-Humic Acid-Zerovalent Iron Nanocomposite for Nitrate Reduction in Water 壳聚糖-腐殖酸-零价铁纳米复合材料在水中还原硝酸盐的制备与表征
Pub Date : 2016-09-05 DOI: 10.1155/2016/1895854
C. Akinremi, Nikechukwu N. Omosun, S. Adewuyi, J. Azeez, Sanyaolu Nurudeen Olanrewaju
A new zerovalent iron chitosan-humic acid nanocomposite was prepared and tested for nitrate ion reduction in water. Humic acid was used for intramolecular cross-linking of the chitosan linear chains to increase the active sites on the chitosan biopolymer and then further used as a stabilizer to synthesize zerovalent iron nanoparticles by the reduction of iron (II) chloride with sodium borohydride. Characterization of the products was carried out using infrared spectroscopy, scanning electron microscope, energy dispersive X-ray, and X-ray diffractometer. Batch experiments were conducted for the reduction of nitrate in water using different concentrations of the products in different concentrations of nitrate ion and at different contact time. The adsorption equilibrium data for the nitrate solution gave a favorable adsorption according to the Langmuir equation. Varying the nanocomposite-to-nitrate ion ratio generally led to faster nitrate reduction, with the pseudofirst-order rate constant for the adsorption increasing with increase in nanocomposite-to-nitrate ion ratio. Nitrate removal efficiency of zerovalent iron chitosan-humic acid nanocomposite was further confirmed using real water samples obtained from drainage waste and river with an initial nitrate concentration of and  ppm, respectively. The reduction of nitrate in water using the nanocomposite was concluded to be highly effective.
制备了一种新型零价铁壳聚糖-腐植酸纳米复合材料,并对其在水中还原硝酸盐离子进行了试验。利用腐植酸对壳聚糖线性链进行分子内交联,增加壳聚糖生物高聚物上的活性位点,再用硼氢化钠还原氯化铁,作为稳定剂合成零价铁纳米颗粒。利用红外光谱、扫描电镜、能量色散x射线和x射线衍射仪对产物进行表征。采用不同浓度的产品,在不同浓度的硝酸盐离子和不同的接触时间下,对水中硝酸盐进行了批量还原实验。根据Langmuir方程,硝酸溶液的吸附平衡数据显示出良好的吸附效果。改变纳米复合材料与硝酸盐离子的比例,通常会导致硝酸盐的还原速度加快,吸附的伪一级速率常数随着纳米复合材料与硝酸盐离子比例的增加而增加。利用排水废水和河流中硝酸盐初始浓度分别为ppm和ppm的真实水样,进一步验证了零价铁壳聚糖-腐殖酸纳米复合材料对硝酸盐的去除效果。纳米复合材料对水中硝酸盐的还原效果良好。
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引用次数: 8
The Influence of the MRSP on the Freezing and Evaporation Processes of the Magnesium Sulfate Subtype Salt Lake Brine MRSP对硫酸镁亚型盐湖卤水冻结和蒸发过程的影响
Pub Date : 2016-08-30 DOI: 10.1155/2016/7427413
Liu Qinghai, Kongjin Zhu, Liu Yuntao, Xing-Ling Liu, Li Feng, Li Guoju, Yong Yang, Liao Yonghua, Liu Shenglin, Wenyi Song
We have developed a new concept, which is the mass fraction ratio of sulfate and potassium ions (MRSP), for the magnesium sulfate subtype salt lake, which is calculated using the metastable phase diagram. We also studied the trend of the MRSP values with the temperature and the influence of the MRSP values on the evaporation process. The experimental results indicated that the MRSP value showed significantly negative trend with decrease of refrigerated temperature. Moreover, when the MRSP value of the objective brine is reduced to less than or equal to the Specific Value by freezing operation, the great changes of crystal morphology and stage of K+ and will take place, which makes the sequence of salts precipitation of the freezing-evaporation different from the direct-evaporation.
本文提出了硫酸镁亚型盐湖硫酸盐与钾离子质量分数比(MRSP)的新概念,并利用亚稳相图进行了计算。研究了MRSP值随温度的变化趋势,以及MRSP值对蒸发过程的影响。实验结果表明,随着冷藏温度的降低,MRSP值呈显著的负变化趋势。另外,当冷冻操作使目标卤水的MRSP值降低到小于等于特定值时,K+和的结晶形态和阶段会发生较大的变化,这使得冻结蒸发的盐沉淀顺序不同于直接蒸发。
{"title":"The Influence of the MRSP on the Freezing and Evaporation Processes of the Magnesium Sulfate Subtype Salt Lake Brine","authors":"Liu Qinghai, Kongjin Zhu, Liu Yuntao, Xing-Ling Liu, Li Feng, Li Guoju, Yong Yang, Liao Yonghua, Liu Shenglin, Wenyi Song","doi":"10.1155/2016/7427413","DOIUrl":"https://doi.org/10.1155/2016/7427413","url":null,"abstract":"We have developed a new concept, which is the mass fraction ratio of sulfate and potassium ions (MRSP), for the magnesium sulfate subtype salt lake, which is calculated using the metastable phase diagram. We also studied the trend of the MRSP values with the temperature and the influence of the MRSP values on the evaporation process. The experimental results indicated that the MRSP value showed significantly negative trend with decrease of refrigerated temperature. Moreover, when the MRSP value of the objective brine is reduced to less than or equal to the Specific Value by freezing operation, the great changes of crystal morphology and stage of K+ and will take place, which makes the sequence of salts precipitation of the freezing-evaporation different from the direct-evaporation.","PeriodicalId":15303,"journal":{"name":"Journal of Chemical Technology & Biotechnology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75735083","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Tribological Performance of Si-Doped Hydrogenated Diamond-Like Carbon Coatings in Different Biodiesel 掺硅氢化类金刚石涂层在不同生物柴油中的摩擦学性能
Pub Date : 2016-08-21 DOI: 10.1155/2016/1307691
A. Dorner-Reisel, Z. B. Kavaklioglu, Stefan Svoboda, J. Engemann
In this paper, two kinds of different biodiesel were tested in terms of their impact on wear resistance of Si-DLC coated 100Cr6 flat worn by an oscillating 100Cr6 ball. The knowledge about the tribological behaviour of different types of biodiesel is rare. Rape and soybean are two of the most common natural sources for biodiesel production. Also, if the quality of biodiesel seems to be similar and, according to the demands, biodiesel from different natural origin could affect changes in the tribological behaviour. Although, soybean methyl ester (SME) gives the best results at room temperature wear tests, 150°C SME reaches wear rates of Si-DLC flat against 100Cr6 ball almost double as high as rapeseed methyl ester (RME). It is evident that, with increasing fraction of oxidation stabilizer C23H32O2, the wear rate increases. For silicon doped hydrogenated diamond-like carbon is especially suitable, for use in biodiesels, where certain fraction of humidity, dissociated water, or polar functional groups may present.
本文测试了两种不同的生物柴油对Si-DLC涂层100Cr6平板在振荡100Cr6球上磨损的耐磨性的影响。关于不同类型生物柴油的摩擦学性能的知识是很少的。油菜和大豆是生产生物柴油最常见的两种天然来源。此外,如果生物柴油的质量似乎相似,并且根据需求,来自不同天然来源的生物柴油可能会影响摩擦学行为的变化。虽然大豆甲酯(SME)在室温磨损试验中获得了最好的结果,但150°C时,SME的Si-DLC平板对100Cr6球的磨损率几乎是油菜籽甲酯(RME)的两倍。随着氧化稳定剂C23H32O2加入量的增加,磨损率明显提高。对于硅掺杂的氢化类金刚石碳特别适合用于生物柴油,其中可能存在一定比例的湿度,解离水或极性官能团。
{"title":"Tribological Performance of Si-Doped Hydrogenated Diamond-Like Carbon Coatings in Different Biodiesel","authors":"A. Dorner-Reisel, Z. B. Kavaklioglu, Stefan Svoboda, J. Engemann","doi":"10.1155/2016/1307691","DOIUrl":"https://doi.org/10.1155/2016/1307691","url":null,"abstract":"In this paper, two kinds of different biodiesel were tested in terms of their impact on wear resistance of Si-DLC coated 100Cr6 flat worn by an oscillating 100Cr6 ball. The knowledge about the tribological behaviour of different types of biodiesel is rare. Rape and soybean are two of the most common natural sources for biodiesel production. Also, if the quality of biodiesel seems to be similar and, according to the demands, biodiesel from different natural origin could affect changes in the tribological behaviour. Although, soybean methyl ester (SME) gives the best results at room temperature wear tests, 150°C SME reaches wear rates of Si-DLC flat against 100Cr6 ball almost double as high as rapeseed methyl ester (RME). It is evident that, with increasing fraction of oxidation stabilizer C23H32O2, the wear rate increases. For silicon doped hydrogenated diamond-like carbon is especially suitable, for use in biodiesels, where certain fraction of humidity, dissociated water, or polar functional groups may present.","PeriodicalId":15303,"journal":{"name":"Journal of Chemical Technology & Biotechnology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79847323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Preparation and Characterization of Polymer-Grafted Montmorillonite-Lignocellulose Nanocomposites by In Situ Intercalative Polymerization 原位插层聚合法制备接枝蒙脱石-木质纤维素纳米复合材料及其表征
Pub Date : 2016-08-17 DOI: 10.1155/2016/4137398
Tavengwa Bunhu, N. Chaukura, L. Tichagwa
Lignocellulose-clay nanocomposites were synthesized using an in situ intercalative polymerization method at 60°C and a pressure of 1 atm. The ratio of the montmorillonite clay to the lignocellulose ranged from 1 : 9 to 1 : 1 (MMT clay to lignocelluloses, wt%). The adsorbent materials were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and X-ray powder diffraction (XRD). FTIR results showed that the polymers were covalently attached to the nanoclay and the lignocellulose in the nanocomposites. Both TEM and XRD analysis showed that the morphology of the materials ranged from phase-separated to intercalated nanocomposite adsorbents. Improved thermal stability, attributable to the presence of nanoclay, was observed for all the nanocomposites. The nanocomposite materials prepared can potentially be used as adsorbents for the removal of pollutants in water treatment and purification.
在60℃、1atm的压力下,采用原位插层聚合法制备了木质纤维素-粘土纳米复合材料。蒙脱石粘土与木质纤维素的比例为1:9 ~ 1:1 (MMT粘土与木质纤维素的比例,wt%)。采用傅里叶红外光谱(FTIR)、热重分析(TGA)、透射电子显微镜(TEM)和x射线粉末衍射(XRD)对吸附材料进行了表征。FTIR结果表明,聚合物在纳米复合材料中与纳米粘土和木质纤维素共价结合。TEM和XRD分析表明,材料的形貌从相分离到插层纳米复合吸附剂。由于纳米粘土的存在,所有纳米复合材料的热稳定性都得到了改善。所制备的纳米复合材料可作为吸附剂用于水处理和净化中污染物的去除。
{"title":"Preparation and Characterization of Polymer-Grafted Montmorillonite-Lignocellulose Nanocomposites by In Situ Intercalative Polymerization","authors":"Tavengwa Bunhu, N. Chaukura, L. Tichagwa","doi":"10.1155/2016/4137398","DOIUrl":"https://doi.org/10.1155/2016/4137398","url":null,"abstract":"Lignocellulose-clay nanocomposites were synthesized using an in situ intercalative polymerization method at 60°C and a pressure of 1 atm. The ratio of the montmorillonite clay to the lignocellulose ranged from 1 : 9 to 1 : 1 (MMT clay to lignocelluloses, wt%). The adsorbent materials were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), transmission electron microscopy (TEM), and X-ray powder diffraction (XRD). FTIR results showed that the polymers were covalently attached to the nanoclay and the lignocellulose in the nanocomposites. Both TEM and XRD analysis showed that the morphology of the materials ranged from phase-separated to intercalated nanocomposite adsorbents. Improved thermal stability, attributable to the presence of nanoclay, was observed for all the nanocomposites. The nanocomposite materials prepared can potentially be used as adsorbents for the removal of pollutants in water treatment and purification.","PeriodicalId":15303,"journal":{"name":"Journal of Chemical Technology & Biotechnology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2016-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79113084","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
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Journal of Chemical Technology & Biotechnology
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