Pub Date : 2020-06-01DOI: 10.22059/JCHPE.2020.254905.1225
S. Hashemi, Mahmood Dinmohammad, M. Bagheri
In the present study, in order to predict the activity coefficient of inorganic ions, 12 cases of aqueous chloride solution were considered (AClx=1,2; A=Li, Na, K, Rb, Mg, Ca, Ba, Mn, Fe, Co, Ni). For this study, the UNIQUAC thermodynamic model is desired and its adjustable parameters are optimized with the Genetic + PSO algorithm. The optimization of the UNIQUAC model with PSO+ genetic algorithms has good results. So that the minimum and maximum electrolyte error of the whole system are 0.00044 and 0.0091, respectively. For this study, a temperature of 298.15 and a pressure of 1 is considered. Also, in this study for the electrolyte system, the Artificial bee colony (ABC) algorithm, and Imperialist competitive algorithm (ICA) has been studied. The results showed that the Artificial bee colony algorithm has a lower accuracy than the Genetic+ Particle swarm optimization (PSO) algorithm. The minimum concentration was 0.1 Molality and the maximum concentration was 3 Molality. Based on the results, the activity coefficient of LiCl, NaCl, KCl, RbCl + H2O, MgCl2, CaCl2, BaCl2, MnCl2, FeCl2, CoCl2 NiCl2 depends on the ionic strength of the electrolyte system.
{"title":"Optimization of Extended UNIQUAC Model Parameter for Mean Activity Coefficient of Aqueous Chloride Solutions using Genetic+PSO","authors":"S. Hashemi, Mahmood Dinmohammad, M. Bagheri","doi":"10.22059/JCHPE.2020.254905.1225","DOIUrl":"https://doi.org/10.22059/JCHPE.2020.254905.1225","url":null,"abstract":"In the present study, in order to predict the activity coefficient of inorganic ions, 12 cases of aqueous chloride solution were considered (AClx=1,2; A=Li, Na, K, Rb, Mg, Ca, Ba, Mn, Fe, Co, Ni). For this study, the UNIQUAC thermodynamic model is desired and its adjustable parameters are optimized with the Genetic + PSO algorithm. The optimization of the UNIQUAC model with PSO+ genetic algorithms has good results. So that the minimum and maximum electrolyte error of the whole system are 0.00044 and 0.0091, respectively. For this study, a temperature of 298.15 and a pressure of 1 is considered. Also, in this study for the electrolyte system, the Artificial bee colony (ABC) algorithm, and Imperialist competitive algorithm (ICA) has been studied. The results showed that the Artificial bee colony algorithm has a lower accuracy than the Genetic+ Particle swarm optimization (PSO) algorithm. The minimum concentration was 0.1 Molality and the maximum concentration was 3 Molality. Based on the results, the activity coefficient of LiCl, NaCl, KCl, RbCl + H2O, MgCl2, CaCl2, BaCl2, MnCl2, FeCl2, CoCl2 NiCl2 depends on the ionic strength of the electrolyte system.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"26 1","pages":"1-12"},"PeriodicalIF":0.0,"publicationDate":"2020-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77210429","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The goal of this experimental study is to determine the effects of different parameters (Flow rate, cuttings density, cuttings size, and hole inclination degree) on hole cleaning efficiency. Freshwater was used as a drilling fluid in this experiment. The experiments were conducted by using flow loop consist of approximately 14 m (46 ft) long with transparent glass test section of 3m (9.84 ft.) long with 4 inches (101.6 mm) ID, the inner metal drill pipe with 2 inches (50.8 mm) OD settled with eccentric position positive 0.5. The results obtained from this study show that the hole cleanings efficiency become better with high flow rate (21 m3/hr) and it increase as the hole inclination angles increased from 60 to 90 degree due to dominated of the rolling force. The cuttings size has negative influence on cuttings recovered as size increased and that is true for all cuttings specific gravity due to direct effect of the cuttings size and density on the gravity force which work against lifting force. The increasing of hole inclination angle above 60 degree will affect positively on cuttings removal efficiency.
{"title":"Optimization of Hole Cleaning and Cuttings Removal in High Inclined Till Horizontal Well","authors":"Karrar Ahmed Mohammed, Ayad A. Alhaleem","doi":"10.31699/ijcpe.2020.1.9","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.9","url":null,"abstract":"The goal of this experimental study is to determine the effects of different parameters (Flow rate, cuttings density, cuttings size, and hole inclination degree) on hole cleaning efficiency. Freshwater was used as a drilling fluid in this experiment. The experiments were conducted by using flow loop consist of approximately 14 m (46 ft) long with transparent glass test section of 3m (9.84 ft.) long with 4 inches (101.6 mm) ID, the inner metal drill pipe with 2 inches (50.8 mm) OD settled with eccentric position positive 0.5. The results obtained from this study show that the hole cleanings efficiency become better with high flow rate (21 m3/hr) and it increase as the hole inclination angles increased from 60 to 90 degree due to dominated of the rolling force. The cuttings size has negative influence on cuttings recovered as size increased and that is true for all cuttings specific gravity due to direct effect of the cuttings size and density on the gravity force which work against lifting force. The increasing of hole inclination angle above 60 degree will affect positively on cuttings removal efficiency.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"146 1","pages":"61-66"},"PeriodicalIF":0.0,"publicationDate":"2020-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74780894","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This research was aimed to determine the petrophysical properties (porosity, permeability and fluid saturation) of a reservoir. Petrophysical properties of the Shuiaba Formation at Y field are determined from the interpretation of open hole log data of six wells. Depending on these properties, it is possible to divide the Shuiaba Formation which has thickness of a proximately 180-195m, into three lithological units: A is upper unit (thickness about 8 to 15 m) involving of moderately dolomitized limestones; B is a middle unit (thickness about 52 to 56 m) which is composed of dolomitic limestone, and C is lower unit ( >110 m thick) which consists of shale-rich and dolomitic limestones. The results showed that the average formation water resistivity for the formation (Rw = 0.021), the average resistivity of the mud filtration (Rmf = 0.57), and the Archie parameters determined by the picket plot method, where m value equal to 1.94, n value equal to 2 and a value equal to 1. Porosity values and water saturation Sw were calculated along with the depth of the composition using IP V3.5 software. The interpretation of the computer process (CPI) showed that the better porous zone holds the highest amount of hydrocarbons in the second zone. From the flow zone indicator method, there are four rock types in the studied reservoir.
{"title":"Petrophysical Properties of an Iraqi Carbonate Reservoir Using Well Log Evaluation","authors":"Sarah S. Zughar, A. Ramadhan, A. K. Jaber","doi":"10.31699/ijcpe.2020.1.8","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.8","url":null,"abstract":"This research was aimed to determine the petrophysical properties (porosity, permeability and fluid saturation) of a reservoir. Petrophysical properties of the Shuiaba Formation at Y field are determined from the interpretation of open hole log data of six wells. Depending on these properties, it is possible to divide the Shuiaba Formation which has thickness of a proximately 180-195m, into three lithological units: A is upper unit (thickness about 8 to 15 m) involving of moderately dolomitized limestones; B is a middle unit (thickness about 52 to 56 m) which is composed of dolomitic limestone, and C is lower unit ( >110 m thick) which consists of shale-rich and dolomitic limestones. The results showed that the average formation water resistivity for the formation (Rw = 0.021), the average resistivity of the mud filtration (Rmf = 0.57), and the Archie parameters determined by the picket plot method, where m value equal to 1.94, n value equal to 2 and a value equal to 1. Porosity values and water saturation Sw were calculated along with the depth of the composition using IP V3.5 software. The interpretation of the computer process (CPI) showed that the better porous zone holds the highest amount of hydrocarbons in the second zone. From the flow zone indicator method, there are four rock types in the studied reservoir.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"51 1","pages":"53-59"},"PeriodicalIF":0.0,"publicationDate":"2020-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86683639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2020-03-30DOI: 10.31699/ijcpe.2020.1.10
W. A. Noori, D. A. H. Al-Timimi, B. J. Kadhim
The analysis, behavior of two-phase flow incompressible fluid in T-juction is done by using "A Computational Fluid Dynamic (CFD) model" that application division of different in industries. The level set method was based in “Finite Element method”. In our search the behavior of two phase flow (oil and water) was studed. The two-phase flow is taken to simulate by using comsol software 4.3. The multivariable was studying such as velocity distribution, share rate, pressure and the fraction of volume at various times. The velocity was employed at the inlet (0.2633, 0.1316, 0.0547 and 0.0283 m/s) for water and (0.1316 m/s) for oil, over and above the pressure set at outlet as a boundary condition. It was observed through the program that the shear rate increased in the mixing area and begins to decrease after the mixing area, for the pressure suddenly decreases in the mixing area and after this area begins to decrease linearly with the length of the tube.
{"title":"Simulation of Two Phase Flow Mixing Co – Current in T Junction Using Comsol","authors":"W. A. Noori, D. A. H. Al-Timimi, B. J. Kadhim","doi":"10.31699/ijcpe.2020.1.10","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.10","url":null,"abstract":"The analysis, behavior of two-phase flow incompressible fluid in T-juction is done by using \"A Computational Fluid Dynamic (CFD) model\" that application division of different in industries. The level set method was based in “Finite Element method”. In our search the behavior of two phase flow (oil and water) was studed. The two-phase flow is taken to simulate by using comsol software 4.3. The multivariable was studying such as velocity distribution, share rate, pressure and the fraction of volume at various times. The velocity was employed at the inlet (0.2633, 0.1316, 0.0547 and 0.0283 m/s) for water and (0.1316 m/s) for oil, over and above the pressure set at outlet as a boundary condition. It was observed through the program that the shear rate increased in the mixing area and begins to decrease after the mixing area, for the pressure suddenly decreases in the mixing area and after this area begins to decrease linearly with the length of the tube.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"68 1","pages":"67-74"},"PeriodicalIF":0.0,"publicationDate":"2020-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80270364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The present research was conducted to reduce the sulfur content of Iraqi heavy naphtha by adsorption using different metals oxides over Y-Zeolite. The Y-Zeolite was synthesized by a sol-gel technique. The average size of zeolite was 92.39 nm, surface area 558 m2/g, and pore volume 0.231 cm3/g. The metals of nickel, zinc, and copper were dispersed by an impregnation method to prepare Ni/HY, Zn/HY, Cu/HY, and Ni + Zn /HY catalysts for desulfurization. The adsorptive desulfurization was carried out in a batch mode at different operating conditions such as mixing time (10,15,30,60, and 600 min) and catalyst dosage (0.2,0.4,0.6,0.8,1, and 1.2 g). The most of the sulfur compounds were removed at 10 min for all catalyst types. The maximum sulfur removal was 56% using (Ni+Zn)/HY catalyst at 1.2 g dose for 24 h. The adsorption kinetics and isotherm of sulfur removal were studied, and results indicated that desulfurization adsorption kinetic was 2nd order, and Temkin and Freundlich models were the best representation isotherm.
{"title":"Adsorptive Desulfurization of Iraqi Heavy Naphtha Using Different Metals over Nano Y Zeolite on Carbon Nanotube","authors":"Hussam Mousa, H. Hussein","doi":"10.31699/ijcpe.2020.1.4","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.4","url":null,"abstract":"The present research was conducted to reduce the sulfur content of Iraqi heavy naphtha by adsorption using different metals oxides over Y-Zeolite. The Y-Zeolite was synthesized by a sol-gel technique. The average size of zeolite was 92.39 nm, surface area 558 m2/g, and pore volume 0.231 cm3/g. The metals of nickel, zinc, and copper were dispersed by an impregnation method to prepare Ni/HY, Zn/HY, Cu/HY, and Ni + Zn /HY catalysts for desulfurization. The adsorptive desulfurization was carried out in a batch mode at different operating conditions such as mixing time (10,15,30,60, and 600 min) and catalyst dosage (0.2,0.4,0.6,0.8,1, and 1.2 g). The most of the sulfur compounds were removed at 10 min for all catalyst types. The maximum sulfur removal was 56% using (Ni+Zn)/HY catalyst at 1.2 g dose for 24 h. The adsorption kinetics and isotherm of sulfur removal were studied, and results indicated that desulfurization adsorption kinetic was 2nd order, and Temkin and Freundlich models were the best representation isotherm.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"77 1","pages":"23-31"},"PeriodicalIF":0.0,"publicationDate":"2020-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90081608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The reserve estimation process is continuous during the life of the field due to risk and inaccuracy that are considered an endemic problem thereby must be studied. Furthermore, the truth and properly defined hydrocarbon content can be identified just only at the field depletion. As a result, reserve estimation challenge is a function of time and available data. Reserve estimation can be divided into five types: analogy, volumetric, decline curve analysis, material balance and reservoir simulation, each of them differs from another to the kind of data required. The choice of the suitable and appropriate method relies on reservoir maturity, heterogeneity in the reservoir and data acquisition required. In this research, three types of reserve estimation used for the Mishrif formation / Amara oil field volumetric approach in mathematic formula (deterministic side) and Monte Carlo Simulation technique (probabilistic side), material balance equation identified by MBAL software and reservoir simulation adopted by Petrel software geological model. The results from these three methods were applied by the volumetric method in the deterministic side equal to (2.25 MMMSTB) and probabilistic side equal to (1.24, 2.22, 3.55) MMMSTB P90, P50, P10 respectively. OOIP was determined by MBAL software equal to (2.82 MMMSTB). Finally, the volume calculation of OOIP by using the petrel static model was (1.92 MMMSTB). The percentage error between material balance and the volumetric equation was equal to 20% while the percentage error between the volumetric method and petrel software was 17%.
{"title":"Using Different Methods to Predict Oil in Place in Mishrif Formation / Amara Oil Field","authors":"M. Najeeb, F. Kadhim, Ghazwan Noori Saed","doi":"10.31699/ijcpe.2020.1.5","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.5","url":null,"abstract":"The reserve estimation process is continuous during the life of the field due to risk and inaccuracy that are considered an endemic problem thereby must be studied. Furthermore, the truth and properly defined hydrocarbon content can be identified just only at the field depletion. As a result, reserve estimation challenge is a function of time and available data. Reserve estimation can be divided into five types: analogy, volumetric, decline curve analysis, material balance and reservoir simulation, each of them differs from another to the kind of data required. The choice of the suitable and appropriate method relies on reservoir maturity, heterogeneity in the reservoir and data acquisition required. In this research, three types of reserve estimation used for the Mishrif formation / Amara oil field volumetric approach in mathematic formula (deterministic side) and Monte Carlo Simulation technique (probabilistic side), material balance equation identified by MBAL software and reservoir simulation adopted by Petrel software geological model. The results from these three methods were applied by the volumetric method in the deterministic side equal to (2.25 MMMSTB) and probabilistic side equal to (1.24, 2.22, 3.55) MMMSTB P90, P50, P10 respectively. OOIP was determined by MBAL software equal to (2.82 MMMSTB). Finally, the volume calculation of OOIP by using the petrel static model was (1.92 MMMSTB). The percentage error between material balance and the volumetric equation was equal to 20% while the percentage error between the volumetric method and petrel software was 17%.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"21 1","pages":"33-38"},"PeriodicalIF":0.0,"publicationDate":"2020-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85790374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In the present study, advanced oxidation treatment, the TiO2 /UV/H2O2 process was applied to decolorisation of the reactive yellow dyes in aqueous solution. The UV radiation was carried out with a 6 W low-pressure mercury lamp. The rate of color removal was studied by measuring the absorbency at a characteristic wavelength. The effects of H2O2 dosage, dye initial concentration and pH on decolorisation kinetics in the batch photoreactor were investigated. The highest decolorisation rates were observed (98.8) at pH range between 3 and 7. The optimal levels of H2O2 needed for the process were examined. It appears that high levels of H2O2 could reduce decolorisation by scavenging the *OH. The color degradation rate decreases as the dye concentration increases. The rate coefficient (k=0.0319 min-1) of degradation, follows the pseudo-first-order kinetics.
{"title":"Photocatalytic Degradation of Reactive Yellow Dye in Wastewater using H2O2/TiO2/UV Technique","authors":"N. Mohammed, Abeer I. Alwared, M. Salman","doi":"10.31699/ijcpe.2020.1.3","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.3","url":null,"abstract":"In the present study, advanced oxidation treatment, the TiO2 /UV/H2O2 process was applied to decolorisation of the reactive yellow dyes in aqueous solution. The UV radiation was carried out with a 6 W low-pressure mercury lamp. The rate of color removal was studied by measuring the absorbency at a characteristic wavelength. The effects of H2O2 dosage, dye initial concentration and pH on decolorisation kinetics in the batch photoreactor were investigated. The highest decolorisation rates were observed (98.8) at pH range between 3 and 7. The optimal levels of H2O2 needed for the process were examined. It appears that high levels of H2O2 could reduce decolorisation by scavenging the *OH. The color degradation rate decreases as the dye concentration increases. The rate coefficient (k=0.0319 min-1) of degradation, follows the pseudo-first-order kinetics.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"30 1","pages":"15-21"},"PeriodicalIF":0.0,"publicationDate":"2020-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84165324","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Laith Farhan, Faleh H. M. Al-Mahdawi, Adel Sherif Hammadi
There are several oil reservoirs that had severe from a sudden or gradual decline in their production due to asphaltene precipitation inside these reservoirs. Asphaltene deposition inside oil reservoirs causes damage for permeability and skin factor, wettability alteration of a reservoir, greater drawdown pressure. These adverse changing lead to flow rate reduction, so the economic profit will drop. The aim of this study is using local solvents: reformate, heavy-naphtha and binary of them for dissolving precipitated asphaltene inside the oil reservoir. Three samples of the sand pack had been prepared and mixed with a certain amount of asphaltene. Permeability of these samples calculated before and after mixed with asphaltenes. Then, the permeability of samples calculated after solvents injection into that porous media. After that, all the values of samples permeability converted to average permeability damage compared with the pure samples. The results show the average permeability damage of samples that mixed with 20 gm was 24 %, but after reformate injected reduced to 14 %. After injected heavy naphtha to porous media, the average permeability reduced only to 17%. The binary solvent had been prepared from reformatted mixed with heavy naphtha gained the best results because it dropped the average permeability damage to 10%.
{"title":"Dissolving Precipitated Asphaltenes Inside Oil Reservoirs Using Local Solvents","authors":"Laith Farhan, Faleh H. M. Al-Mahdawi, Adel Sherif Hammadi","doi":"10.31699/ijcpe.2020.1.7","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.7","url":null,"abstract":"There are several oil reservoirs that had severe from a sudden or gradual decline in their production due to asphaltene precipitation inside these reservoirs. Asphaltene deposition inside oil reservoirs causes damage for permeability and skin factor, wettability alteration of a reservoir, greater drawdown pressure. These adverse changing lead to flow rate reduction, so the economic profit will drop. The aim of this study is using local solvents: reformate, heavy-naphtha and binary of them for dissolving precipitated asphaltene inside the oil reservoir. Three samples of the sand pack had been prepared and mixed with a certain amount of asphaltene. Permeability of these samples calculated before and after mixed with asphaltenes. Then, the permeability of samples calculated after solvents injection into that porous media. After that, all the values of samples permeability converted to average permeability damage compared with the pure samples. The results show the average permeability damage of samples that mixed with 20 gm was 24 %, but after reformate injected reduced to 14 %. After injected heavy naphtha to porous media, the average permeability reduced only to 17%. The binary solvent had been prepared from reformatted mixed with heavy naphtha gained the best results because it dropped the average permeability damage to 10%.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"18 1","pages":"45-52"},"PeriodicalIF":0.0,"publicationDate":"2020-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73491386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The oxidation desulphurization assisted by ultrasound waves was applied to the desulphurization of heavy naphtha. Hydrogen peroxide and acetic acid were used as oxidants, ultrasound waves as phase dispersion, and activated carbon as solid adsorbent. When the oxidation desulphurization (ODS) process was followed by a solid adsorption step, the performance of overall Sulphur removal was 89% for heavy naphtha at the normal condition of pressure and temperature. The process of (ODS) converts the compounds of Sulphur to sulfoxides/ sulfones, and these oxidizing compounds can be removed by activated carbon to produce fuel with low Sulphur content. The absence of any components (hydrogen peroxide, acetic acid, ultrasound waves and activated carbon) from the ODS process leading to reduce the performance of removal, hydrogen peroxide was the most crucial factor. The ultrasound waves increase the dispersion of carbon, water and oil phase, promotes the interfacial mass transfer, and this leads to accelerates the reaction. The ultrasound waves did not affect the chemical or physical properties of the fuel. The chemical analysis of treated fuel oil showed that <1% of the hydrocarbon fuel compounds were oxidized in the ODS process. In this work, desulphurization by oxidation is the main mechanism was tested with several parameters that effects desulphurization efficiency such as sonication time (5-40) min, activated carbon (0.01-0.5) gm, hydrogen peroxide (1-30) ml, and acetic acid (1-15) ml. It was found that the hydrogen peroxide amounts lead to increase oxidation rates of Sulphur compounds so, the desulphurization efficiency increases. The optimum amounts of oxidants are 10 ml hydrogen peroxide per 100 ml of heavy naphtha. Increasing the amount of acid catalyst lead to increase Sulphur removal, it was found that7.5 ml acid per 10 ml oxidant was the optimum amount. Activated carbon as a solid adsorbent and reaction enhancer with 0.1gm weight was found as the optimum amount for 100 ml heavy naphtha. Increasing sonication time lead to increase desulphurization rate, it was found that (10 min) is the optimum period. By applying the optimum parameters 89% of sulfur can be removed from heavy naphtha with 598.4 ppm Sulphur content.
{"title":"Oxidation Desulphurization of Heavy Naphtha Improved by Ultrasound Waves","authors":"Bariq Bahmman Jima, N. Majeed","doi":"10.31699/ijcpe.2020.1.2","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.2","url":null,"abstract":"The oxidation desulphurization assisted by ultrasound waves was applied to the desulphurization of heavy naphtha. Hydrogen peroxide and acetic acid were used as oxidants, ultrasound waves as phase dispersion, and activated carbon as solid adsorbent. When the oxidation desulphurization (ODS) process was followed by a solid adsorption step, the performance of overall Sulphur removal was 89% for heavy naphtha at the normal condition of pressure and temperature. The process of (ODS) converts the compounds of Sulphur to sulfoxides/ sulfones, and these oxidizing compounds can be removed by activated carbon to produce fuel with low Sulphur content. The absence of any components (hydrogen peroxide, acetic acid, ultrasound waves and activated carbon) from the ODS process leading to reduce the performance of removal, hydrogen peroxide was the most crucial factor. The ultrasound waves increase the dispersion of carbon, water and oil phase, promotes the interfacial mass transfer, and this leads to accelerates the reaction. The ultrasound waves did not affect the chemical or physical properties of the fuel. The chemical analysis of treated fuel oil showed that <1% of the hydrocarbon fuel compounds were oxidized in the ODS process. In this work, desulphurization by oxidation is the main mechanism was tested with several parameters that effects desulphurization efficiency such as sonication time (5-40) min, activated carbon (0.01-0.5) gm, hydrogen peroxide (1-30) ml, and acetic acid (1-15) ml. It was found that the hydrogen peroxide amounts lead to increase oxidation rates of Sulphur compounds so, the desulphurization efficiency increases. The optimum amounts of oxidants are 10 ml hydrogen peroxide per 100 ml of heavy naphtha. Increasing the amount of acid catalyst lead to increase Sulphur removal, it was found that7.5 ml acid per 10 ml oxidant was the optimum amount. Activated carbon as a solid adsorbent and reaction enhancer with 0.1gm weight was found as the optimum amount for 100 ml heavy naphtha. Increasing sonication time lead to increase desulphurization rate, it was found that (10 min) is the optimum period. By applying the optimum parameters 89% of sulfur can be removed from heavy naphtha with 598.4 ppm Sulphur content.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"20 1","pages":"9-14"},"PeriodicalIF":0.0,"publicationDate":"2020-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76132844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
In this research, the performance of electrocoagulation (EC) using aluminum (Al) electrodes with Monopolar- parallel (MP-P), and bipolar - series (BP-S) arrangement for simultaneous removal of dissolved silica, and hardness ions (calcium, and magnesium) from synthetic blowdown water of cooling tower were investigated. The effects of current density, initial pH and time of electrolysis on the removal efficiency were studied in a batch stirred unit to find out the best-operating conditions. The obtained results for each target species are evidence that BP-S approach is the best for both electrodes configuration operated at a Current density of 1mA/cm2 through 30 min of treatment and pH=10 with the removal of 60 %, 97% and 98% for calcium, magnesium and silica, respectively. This arrangement required an electrical energy consumption of1.8 kWh/m3 which is higher than observed in a parallel arrangement.
{"title":"Different Electrodes Connections in Electrocoagulation of Synthetic Blow down Water of Cooling Tower","authors":"Enas Ali Anwer, B. A. majeed","doi":"10.31699/ijcpe.2020.1.1","DOIUrl":"https://doi.org/10.31699/ijcpe.2020.1.1","url":null,"abstract":"In this research, the performance of electrocoagulation (EC) using aluminum (Al) electrodes with Monopolar- parallel (MP-P), and bipolar - series (BP-S) arrangement for simultaneous removal of dissolved silica, and hardness ions (calcium, and magnesium) from synthetic blowdown water of cooling tower were investigated. The effects of current density, initial pH and time of electrolysis on the removal efficiency were studied in a batch stirred unit to find out the best-operating conditions. The obtained results for each target species are evidence that BP-S approach is the best for both electrodes configuration operated at a Current density of 1mA/cm2 through 30 min of treatment and pH=10 with the removal of 60 %, 97% and 98% for calcium, magnesium and silica, respectively. This arrangement required an electrical energy consumption of1.8 kWh/m3 which is higher than observed in a parallel arrangement.","PeriodicalId":15333,"journal":{"name":"Journal of Chemical and Petroleum Engineering","volume":"94 1","pages":"1-7"},"PeriodicalIF":0.0,"publicationDate":"2020-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74105063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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