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Cobalt decorated egg-shell-type activated carbon pellets: Catalytic application in hydrogen release from boron based solid fuel 钴装饰蛋壳型活性炭颗粒:催化硼基固体燃料释氢的应用
Pub Date : 2023-01-01 DOI: 10.14744/cetj.2023.0002
B. Coşkuner Filiz
Hydrogen became zero-carbon fuel used in fuel-cell or internal combustion engines, regard- ing energy sector green-hydrogen also has become an energy carrier in commercial appli- cations. For supporting decarbonization strategies based on hydrogen, boron-fuels are good options to safely store for mobile technologies. Ammonia borane (NH3BH3) is the one of the boron based fuels that stored 19.6 wt.% H2 in its structure chemically. Cobalt (Co) decorated egg-shell-type activated carbon pellets were synthesized for catalytic application of hydrogen release from NH3BH3. Two different sized pellet type activated carbon was decorated with co- balt by combined procedure as modified vacuum-impregnation method with heat fixation and reduction. The obtained catalysts were characterized by applying optical microscope (OM), scanning electron microscope/energy dispersive X-ray spectroscopy (SEM/EDS), transmis- sion electron microscopy (TEM), nitrogen sorption based surface analyses (BET). Activated carbon provides porous structure for effectively dispersion Co particles while the outer shell shows the catalytic activity for hydrogen generation. Structural characterization results and preliminary activity tests confirmed that fabricated Co@ACPB exhibited better performance compared with Co@ACPS catalysts thanks to thinner shell thickness and higher BET surface area/pore volume properties. The results of the kinetic study showed the core-shell type Co based catalyst catalyzed the reaction and follows the zero-order reaction kinetic model with 41.78 kJmol-1. Activated carbon pellets provide well dispersion and stability of active Co sites, easy separation of used catalysts after the reaction and enable practical regeneration of cata- lytic materials.
氢成为燃料电池或内燃机使用的零碳燃料,在能源领域绿色氢也成为商业应用的能源载体。为了支持基于氢的脱碳战略,硼燃料是安全储存用于移动技术的好选择。氨硼烷(NH3BH3)是硼基燃料中的一种,在其结构中化学储存了19.6 wt.%的H2。合成了钴(Co)修饰的蛋壳型活性炭颗粒,用于催化NH3BH3的氢释放。采用改进的真空浸渍法和热固还原相结合的工艺对两种不同粒径的球团型活性炭进行钴修饰。采用光学显微镜(OM)、扫描电镜(SEM)、x射线能谱(EDS)、透射电镜(TEM)、氮吸附表面分析(BET)等手段对催化剂进行了表征。活性炭具有多孔结构,可有效分散Co颗粒,而其外壳具有催化产氢活性。结构表征结果和初步活性测试证实,与Co@ACPS催化剂相比,制备的Co@ACPB具有更薄的壳厚度和更高的BET表面积/孔体积性能,具有更好的性能。动力学研究结果表明,核壳型Co基催化剂催化了该反应,反应动力学模型为41.78 kJmol-1,符合零级反应模型。活性炭颗粒具有良好的活性Co位点分散性和稳定性,反应后催化剂易于分离,可实现催化材料的实际再生。
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引用次数: 0
A review of water heating systems: A Focus on hybrid technologies prospect in Nigeria 水加热系统综述:着眼于尼日利亚混合技术的前景
Pub Date : 2023-01-01 DOI: 10.14744/cetj.2023.0005
O. Ayodeji
The rising energy demand necessitates a rapid transition to renewable energy and efficient technologies. The Nigerian household sector consumes enormous energy to meet domestic needs such as water heating. Furthermore, rising electricity costs hinders the commercial use of electric water heaters. As a result, energy users rely on conventional methods of heating water. In general, over-reliance on traditional water-heating systems have resulted in envi-ronmental degradation and public health crises. Adopting energy-efficient technologies may improve energy security, mitigate energy crises, reduce costs, and further optimize household energy consumption. This paper provides a comprehensive review of existing and emerging water-heating systems with a summary of recent innovations in water- heating systems. Var-ious types of hybrid and renewable water heating systems, as well as their configurations, are examined. In addition, relevant studies on different water-heating technologies are reviewed and classified according to their contribution, study type, and technology. The review findings are well articulated, and policy recommendations for solar water heating systems are made. This review's findings identify research gaps in the hybrid water-heating technology in Nige-ria. This survey provides insight into solar and hybrid solar systems as an alternative solution to fossil-fuel-based water heating systems.
不断增长的能源需求要求迅速过渡到可再生能源和高效技术。尼日利亚的家庭部门消耗了大量的能源来满足诸如热水等家庭需求。此外,不断上涨的电费阻碍了电热水器的商业使用。因此,能源使用者依靠传统的方法来加热水。一般来说,对传统热水系统的过度依赖导致了环境恶化和公共卫生危机。采用节能技术可以提高能源安全,缓解能源危机,降低成本,进一步优化家庭能源消费。本文对现有的和新兴的水加热系统进行了全面的回顾,并总结了最近在水加热系统中的创新。各种类型的混合和可再生水加热系统,以及他们的配置,进行了检查。此外,对不同热水技术的相关研究进行了综述,并根据其贡献、研究类型和技术进行了分类。审查结果得到了很好的阐述,并对太阳能热水系统提出了政策建议。本综述的发现确定了尼日利亚混合水加热技术的研究空白。这项调查提供了洞察太阳能和混合太阳能系统作为替代解决方案,以化石燃料为基础的热水系统。
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引用次数: 0
Optimization of air inlet features of an active indirect mode solar dryer: A response surface approach 主动间接模式太阳能干燥机进气特性优化:响应面法
Pub Date : 2023-01-01 DOI: 10.14744/cetj.2023.0003
P. Etim
The effect of air flowing into an in an active indirect mode solar dryer was studied. The study aimed at optimizing the airflow features of a solar dryer of active indirect feature using Response Surface Methodology (RSM). The factors of the experiment included the product slice thickness of the experimental product and the air vent of the dryer. The two factors were considered at five levels and a total of 13 experimental runs derived. The air vent was based on the following shape orientations: square, rectangular, circular, and triangular. The thickness of the product was considered at five levels of 4, 8, 12, 16 and 20 mm. The responses from the experimental set up were the air flow rate and drag force, which were determined using established equations. The optimum values for the air flow rate and drag force were 0.0275 m3/s and 0.0476N, respectively. The corresponding optimal conditions which gave the optimum responses were 100 cm2 - square inlet and product slice thickness of 20 mm for air flow rate and 80 cm2 -rectangular inlet and product slice thickness of 20 mm for drag force, respectively. The models for predicting the responses were adequate, with r-square values 0.9463 and 0.9376 and desirabilities of 99.2 and 95.0% for air flow rate and drag force respectively. The experiment was repeated using the optimal conditions to validate the optimum responses. The variation between the predicted and experimental data was less than 8%.
研究了在主动间接式太阳能干燥机中空气流入对干燥效果的影响。采用响应面法(Response Surface Methodology, RSM)对主动式间接特征太阳能干燥机的气流特性进行了优化研究。实验的影响因素包括实验产品的产品切片厚度和烘干机的通风量。这两个因素在5个水平上被考虑,总共推导了13个实验运行。通风口基于以下形状方向:方形、矩形、圆形和三角形。产品的厚度分为4、8、12、16和20毫米五个级别。实验装置的响应是空气流速和阻力,这是由建立的方程确定的。风速和阻力的最优值分别为0.0275 m3/s和0.0476N。相应的最优条件为:空气流量为100 cm2的方形进口,产品片厚为20 mm;阻力为80 cm2的矩形进口,产品片厚为20 mm。该模型对空气流量和阻力的r平方值分别为0.9463和0.9376,理想度分别为99.2%和95.0%。在最佳条件下重复实验,验证最佳反应。预测值与实验值的差异小于8%。
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引用次数: 0
Introduction to a New Journal: Clean Energy Technologies Journal (CETJ) 《清洁能源技术杂志》(CETJ)简介
Pub Date : 2023-01-01 DOI: 10.14744/cetj.2022.0001
B. Ozkaya
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引用次数: 0
A new line stability index for voltage stability analysis based on line loading 一种新的基于线路负荷的电压稳定分析指标
Pub Date : 2023-01-01 DOI: 10.14744/cetj.2023.0004
Kadir Doğanşahin
Voltage stability has always been a very important issue in the planning and operation of pow- er systems, but today it is much more serious. Power systems are in a transition period. The conventional centralized configuration of the power system has been transforming into a de- centralized and deregulated form. The electrification of different sectors is accelerating the increase in demand for electrical energy. Increasing energy demand, differentiating consump- tion profiles, and diversifying consumers have made power system operations more complex. All these transformations take place in the shadow of rising economic and environmental con- cerns. Therefore, a general approach has been adopted to derive the greatest possible benefit from existing systems, rather than constructing new facilities. As a result, it is aimed to operate the systems close to limit values as much as possible. The voltage stability of systems operating close to the limit values needs to be examined more precisely. There are many voltage stability indices in the literature. However, most of them are based on various ignorance or assumptions. In this study, a new index is proposed, which is based on line loading and considering multiple line parameters. It has been observed that the suggested index gives consistent results in all varying conditions and different loading types.
电压稳定一直是电力系统规划和运行中一个非常重要的问题,但在今天,电压稳定问题更加严重。电力系统正处于转型期。电力系统由传统的集中式配置向分散式、放松管制的形式转变。不同行业的电气化正在加速对电能需求的增长。不断增长的能源需求、不同的消费特征和多样化的消费者使电力系统的运行更加复杂。所有这些转变都是在经济和环境问题日益严重的阴影下发生的。因此,采用的一般方法是从现有系统中获得最大可能的利益,而不是建造新的设施。因此,它的目的是操作系统接近限值尽可能多。需要更精确地检查接近极限值运行的系统的电压稳定性。文献中有许多电压稳定指标。然而,其中大多数都是基于各种无知或假设。本文提出了一种基于线路负荷并考虑多种线路参数的新指标。已观察到,所建议的指数给出一致的结果,在所有不同的条件和不同的加载类型。
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引用次数: 0
A Hybrid Approach for Optimal Sizing of Inverter-Based Distributed Generation Unit in Presence of Harmonic Distortion Limit 谐波失真限制下逆变器分布式发电机组优化尺寸的混合方法
Pub Date : 2022-06-01 DOI: 10.18178/jocet.2022.10.2.532
B. Motling, S. Paul, S. Dey
This paper presents a hybrid approach to calculate the optimal size of inverter-based distributed generation unit located at any given bus of a radial distribution network to minimize the active power loss in the network in presence of limit imposed on the maximum allowable value of total harmonic distortion in bus voltages. The suggested approach combines efficient iterative computations with a rule base developed in the present work, and requires much less computation compared to the evolutionary population based methods reported so far, to reach the desired solution. In support of this claim, the proposed methodology was tested on two bench-mark distribution test systems, and the test results were compared and validated with those obtained using Particle Swarm Optimization technique. PSO has been chosen for comparison as it is one of the most widely used among the evolutionary population based methods due to its simple approach, ease of implementation, and also because of its superiority in terms of precision, robustness and speed of convergence. From the comparative results it has been established that the proposed method can provide solution for the problem undertaken in this work with significantly less computation than is required by the evolutionary computation based methods.
本文提出了一种基于逆变器的分布式发电机组在给定径向配电网母线电压总谐波失真最大值限制下的最优尺寸计算方法,以使电网有功损耗最小。所建议的方法结合了有效的迭代计算和目前工作中开发的规则库,与迄今为止报道的基于进化种群的方法相比,需要更少的计算,以达到期望的解决方案。为了支持这一说法,在两个基准配电测试系统上对所提出的方法进行了测试,并将测试结果与使用粒子群优化技术获得的结果进行了比较和验证。选择粒子群算法进行比较,因为它是基于进化种群的方法中使用最广泛的方法之一,因为它方法简单,易于实现,并且在精度,鲁棒性和收敛速度方面具有优势。对比结果表明,与基于进化计算的方法相比,所提出的方法可以显著减少计算量,从而解决本研究中所面临的问题。
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引用次数: 1
The Feasibility of the First Utility-Scale Wind Farm in Saudi Arabia (The 400 MW Dumat Al-Jandal Project) 沙特阿拉伯第一个公用事业规模风电场的可行性(400兆瓦Dumat Al-Jandal项目)
Pub Date : 2022-03-01 DOI: 10.18178/jocet.2022.10.1.531
Kamel Almutairi, R. Alahmadi
Saudi Arabia has an ambitious plan to diversify its power generation resources. Part of this plan includes launching the King Salman Renewable Energy Initiative (KSREI). The goal of this work is to study the feasibility of the first utility-scale wind farm in Saudi Arabia, known as the 400 MW Dumat Al-Jandal project, and was conducted using the System Advisor Model (SAM) software. As the hub height of the wind turbine is usually different from the height at which the wind measurements are taken, the wind speeds were extrapolated to different heights using different methods. These methods are the power law using two different shear coefficients and the logarithmic law. The simulations were performed for 113 commercial wind turbines with different sizes and power curves to help enhance our understanding of the effects of these factors on wind farm performance. The technical analysis shows that the capacity factors of the most efficient wind machine types varied from 35.5%–26.8%, 32.9%–25.5%, and 29.7%–23.7% for the heights 140 m, 110 m, and 80 m, respectively. From an economic perspective, the levelized cost of energy (LCOE) of the most efficient wind machine types varied from 3.23–4.57 ¢/kWh, 3.55–4.84 ¢/kWh, and 4.02-5.82 ¢/kWh for the heights 140 m, 110 m, and 80 m, respectively. The lowest possible LCOE (3.23 ¢/kWh), according to this analysis, is in the same range of the submitted LCOE by the project’s winning bidder. Finally, the net present value (NPV) shows that the project is economically feasible.
沙特阿拉伯有一个雄心勃勃的计划,使其发电资源多样化。该计划的一部分包括启动萨勒曼国王可再生能源倡议(KSREI)。这项工作的目标是研究沙特阿拉伯第一个公用事业规模的风电场的可行性,被称为400兆瓦的Dumat Al-Jandal项目,并使用系统顾问模型(SAM)软件进行。由于风力机的轮毂高度通常与风速测量的高度不同,因此采用不同的方法外推风速到不同的高度。这些方法是使用两个不同剪切系数的幂律和对数律。为了更好地理解这些因素对风电场性能的影响,我们对113台不同尺寸和功率曲线的商用风力涡轮机进行了模拟。技术分析表明,在140 m、110 m和80 m高度,最有效风力机类型的容量因子分别为35.5% ~ 26.8%、32.9% ~ 25.5%和29.7% ~ 23.7%。从经济角度来看,在140 m、110 m和80 m高度,最高效的风力机类型的平准化能源成本(LCOE)分别为3.23 ~ 4.57分/kWh、3.55 ~ 4.84分/kWh和4.02 ~ 5.82分/kWh。根据这一分析,最低的LCOE(3.23美分/千瓦时)与项目中标人提交的LCOE在同一范围内。最后,净现值(NPV)表明该项目在经济上是可行的。
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引用次数: 0
The Role of Electric Snowmobiles and Rooftop Energy Production in the Arctic: The Case of Longyearbyen 电动雪地车和屋顶能源生产在北极的作用:以朗伊尔城为例
Pub Date : 2021-12-01 DOI: 10.18178/jocet.2021.9.4.530
S. Dadman, B. Bremdal, Kristoffer Tangrand
The research presented here has been conducted in the Smart Charge project. It has addressed the use of renewables, e-mobility and battery charging in the Arctic as part of an effort to solicit fossil-fuelled alternatives. Of particular interest has been to determine what impact and support electric snowmobiles can provide together with local, renewable energy production. The relevance of vehicle-togrid/ building (V2G/B) solutions have been investigated in the project too. The idea has been to use electric snowmobiles for load shaving during extensive periods of the year. The research has looked at cost aspects, value stacking, climate impact as well as aggregated effects of controlled fleet management of idle snowmobiles. A case study undertaken at Longyearbyen at Svalbard, Norway has provided the most important empirical basis for the research presented. The research concludes that electric snowmobiles can have a positive effect on the local energy system and despite limited range can be quite attractive for the individual to operate if energy for charging is based on local driving solar power.
这里介绍的研究是在智能充电项目中进行的。作为寻求化石燃料替代品努力的一部分,它已经解决了在北极使用可再生能源、电动汽车和电池充电的问题。特别感兴趣的是确定电动雪地车与当地可再生能源生产一起可以提供什么样的影响和支持。该项目还研究了车辆与电网/建筑(V2G/B)解决方案的相关性。这个想法是在一年中大量的时间里使用电动雪地车来减载。该研究着眼于成本方面、价值叠加、气候影响以及对闲置雪地车车队进行控制管理的总体效应。在挪威斯瓦尔巴群岛的朗伊尔城进行的案例研究为所提出的研究提供了最重要的经验基础。研究得出结论,电动雪地车可以对当地能源系统产生积极影响,尽管范围有限,但如果充电能源是基于当地驱动的太阳能,那么对个人来说还是相当有吸引力的。
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引用次数: 1
Implementing of a Usable Tool for Selecting Operations to Upgrade Biogas to Biomethane 沼气升级为生物甲烷的实用操作选择工具的实现
Pub Date : 2021-09-01 DOI: 10.18178/jocet.2021.9.3.529
L. Gómez, S. Luque, Alejandra Gutiérrez, R. ArraibiJ.
In Spain, biomethane and biogas are still starting to be considered as an alternative to natural gas. A good way of promoting these renewable energies is supporting small and cheap treatment plants near to the place where the biogas is produced and where the biomethane can be used on site, fostering the circular economy. An easily usable simulation tool for selecting the best sequence of unit operations for treating biogas (based on adsorption, absorption, and membranes) has been designed. Pollutants modelled are CO2, CH4, NH3, SH2, CO2, O2, N2, H2O and siloxanes. This tool was used as first step to design a flexible and portable prototype for treating small flows of biogas as those produced in livestock which has been later built and is on operation.
在西班牙,生物甲烷和沼气仍被视为天然气的替代品。推广这些可再生能源的一个好方法是在沼气产生地附近支持小型和廉价的处理厂,并在那里可以就地使用生物甲烷,从而促进循环经济。设计了一个易于使用的模拟工具,用于选择处理沼气的最佳单元操作顺序(基于吸附,吸收和膜)。模拟的污染物包括CO2、CH4、NH3、SH2、CO2、O2、N2、H2O和硅氧烷。这一工具被用作设计一种灵活和便携式原型的第一步,用于处理牲畜产生的小流量沼气,该原型后来建成并投入使用。
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引用次数: 0
Empirical Evaluation of Fixed and Single-Axis Tracking Photovoltaic System: Case of ASHRAE Solar Radiation Modelling for Medina, Saudi Arabia 固定和单轴跟踪光伏系统的实证评价:以沙特阿拉伯麦地那ASHRAE太阳辐射模型为例
Pub Date : 2021-09-01 DOI: 10.18178/jocet.2021.9.3.528
Raed Alahmdi, Abdulrahman Alansari, Mohanad Abualkhair, Abdulrahman Almoghamisi, D. Minerals
The main problem in studying the feasibility of solar systems is the enormous gap between theory and experimental radiation intensity, so to get accurate results there is a need for studying energy production in the site of the system empirically. In this study, the energy production of both fixed PV panel system and the system with single-axis tracking were empirically evaluated in Medina, Saudi Arabia. The two systems had the same 270 Wp PV panel. The fixed system was tilted by 23.5 degrees, and the single-axis tracker was tilted by 26 degrees. Both systems had an azimuth angle of zero degrees. A closedloop three-points controller was used to control the tracker with 120 degrees rotation range. The two systems operated simultaneously in July, and the data were collected for 14 days. The empirical results showed that the tracker increased the generated energy by 48.5% during the testing period. As a comparing method, a modified ASHRAE model was used to estimate the increase in the panel's energy output with and without the single-axis tracker, and RMSE and MBE were calculated. It's been found that the experimental energy generation is 10%, 5% less than the estimation of the modified model for the fixed system and the tracking system, respectively. Finally, based on the analysis, it's been estimated that the singleaxis tracker will increase the generated energy by 22.5% yearly in Medina.
研究太阳系可行性的主要问题是理论辐射强度与实验辐射强度之间的巨大差距,因此为了获得准确的结果,需要对系统现场的产能进行经验研究。本研究对沙特阿拉伯麦地那固定光伏板系统和单轴跟踪系统的发电量进行了实证评估。这两个系统具有相同的270 Wp光伏面板。固定系统倾斜23.5度,单轴跟踪器倾斜26度。两个系统的方位角都是0度。采用闭环三点控制器对跟踪器进行120度旋转控制。7月,两套系统同时运行,数据采集时间为14天。实证结果表明,该跟踪器在测试期间的发电量提高了48.5%。作为比较方法,采用改进的ASHRAE模型估计安装和不安装单轴跟踪器后面板能量输出的增量,并计算RMSE和MBE。实验结果表明,固定系统和跟踪系统的实验发电量分别比修正模型的估计值小10%、5%。最后,在分析的基础上,估计单轴跟踪器每年将使麦地那的发电量增加22.5%。
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引用次数: 1
期刊
Journal of Clean Energy Technologies
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