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DFT study of Oxidation Initiation for Different Compound in Gasoline 汽油中不同化合物氧化起始的DFT研究
Pub Date : 2018-05-01 DOI: 10.18178/JOCET.2018.6.3.468
Na Li, J. Long, Yi Zhao, Zhiping Tao, Zhenyu Dai
A DFT study of oxidation initiation reaction for same carbon number but different type hydrocarbon compound in gasoline was performed. Firstly, the homolytic dissociation energies of the C-H bond in various hydrocarbon molecules were calculated and the C-H active site which was most likely to be attacked by oxygen molecules was obtained. Then, the reaction barrier of oxidation initiation reaction for different gasoline hydrocarbon molecules was compared. Furthermore, frontier orbital theory was used to analyze the chain initiation mechanism. It was found that the symmetry and energy gap of the HOMO orbitals of gasoline hydrocarbon molecules and the LUMO orbitals of oxygen molecule are the decisive factors in the oxidation initiation reaction. The results indicate that the reaction barrier of the olefin is much lower than other hydrocarbons. On the other hand, the energy gap between the HOMO orbital of 2, 4-hexadiene and the LUMO orbital of the oxygen is much lower than other molecules just followed by 1-hexene.
对汽油中相同碳数不同类型烃类化合物的氧化引发反应进行了离散傅里叶变换研究。首先,计算各种碳氢化合物分子中C-H键的均解能,得到最容易被氧分子攻击的C-H活性位点;然后比较了不同汽油烃分子氧化引发反应的反应势垒。利用前沿轨道理论分析了链的起链机理。发现汽油烃分子HOMO轨道和氧分子LUMO轨道的对称性和能隙是氧化引发反应的决定性因素。结果表明,烯烃的反应势垒远低于其他烃类。另一方面,2,4 -己二烯的HOMO轨道和氧的LUMO轨道之间的能隙比紧随1-己二烯的其他分子要小得多。
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引用次数: 3
Study on the Change of South Korea Outdoor Design Temperature according to the Assigned Period 韩国室外设计温度按指定时段变化研究
Pub Date : 2018-05-01 DOI: 10.18178/jocet.2018.6.3.465
A. Nam, Snust Seoul South Korea Environment, Jong Jun Park, Young-il Kim, K. Chung
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引用次数: 2
Modeling and Prediction of Tracer Tests in Dongli Lake Area in Tianjin, China 天津东丽湖地区示踪剂试验建模与预测
Pub Date : 2018-05-01 DOI: 10.18178/jocet.2018.6.3.461
Wanli Wang, Guiling Wang, Chunlei Liu, Vaiva Čypaitė
The Jxw geothermal reservoir in the Dongli Lake area is an extensive, low temperature geothermal system hosted mainly by Mesoproterozoic dolomitic limestones. In order to study the flow paths and predict the recovery time and tracer concentration in the production well, a numerical method using Visual MODFLOW software were applied. For the most pessimistic case (longitudinal dispersivity equals to 383.5 m), the tracer will take more than a year to arrive at the production well, with concentration values outside of the detection limit. Results show that there is no direct connection between production and injection wells.
东丽湖地区Jxw地热储层是一个以中元古代白云质灰岩为主的广泛低温地热系统。为了研究生产井的流动路径,预测采油时间和示踪剂浓度,采用Visual MODFLOW软件进行了数值模拟。在最悲观的情况下(纵向色散为383.5 m),示踪剂需要一年多的时间才能到达生产井,浓度超出检测极限。结果表明,生产井与注水井之间没有直接联系。
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引用次数: 1
Investigation of Alternative Power Distribution and Optimal Configuration through the Implementation of Clustering Algorithms-Based Microgrids for a Case Study 基于聚类算法的微电网替代配电及优化配置研究
Pub Date : 2018-05-01 DOI: 10.18178/JOCET.2018.6.3.471
D. Cheong, T. Fernando, H. Iu, Mark Reynolds, James R. E. Fletcher
 Abstract— This paper presents a novel approach to optimizing rural electrical power transmission network. The primary objective of this project is to determine an optimal (more economical) network configuration for a case study where large portions of network assets are approaching the end of their life cycle. Therefore, this is the most opportune time to redesign, and implement economically beneficial distribution alternatives such as microgrids and standalone power systems and, to evaluate the economic benefits of a combination of distribution alternatives. The latter alongside multiple microgrids have often been overlooked by past studies. Using Minimum Spanning Trees (MSTs) and clustering algorithms, the ideal location of microgridsand combination of distribution alternatives can be investigated. The results obtained from this study suggest that implementing microgrids and standalone power systems, drastically reduce the total cost of the network when compared to anoverhead transmission MST network. Furthermore, a combination of an overhead network with microgrids and standalone power systems resulted in the most economical network
摘要本文提出了一种优化农村输电网的新方法。这个项目的主要目标是为一个案例研究确定一个最佳的(更经济的)网络配置,其中大部分网络资产正在接近其生命周期的终点。因此,现在是重新设计和实施具有经济效益的配电替代方案(如微电网和独立电力系统)以及评估配电替代方案组合的经济效益的最佳时机。后者以及多个微电网常常被过去的研究所忽视。利用最小生成树(MSTs)和聚类算法,可以研究微网的理想位置和分布方案的组合。从这项研究中获得的结果表明,与架空传输MST网络相比,实施微电网和独立电力系统大大降低了网络的总成本。此外,将架空网络与微电网和独立电力系统相结合,形成了最经济的网络
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引用次数: 4
Influence of Solid State Fault Current Limiter on Grid Connected Photovoltaic System Protection 固态故障限流器对并网光伏系统保护的影响
Pub Date : 2018-05-01 DOI: 10.18178/JOCET.2018.6.3.470
J. P. Sharma, H. Kamath
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引用次数: 2
A DSP-Based Implementation of a Hybrid Solar and Wind Turbine Power Conversion System 基于dsp的太阳能与风力混合动力转换系统的实现
Pub Date : 2018-05-01 DOI: 10.18178/JOCET.2018.6.3.469
Bao-sheng Wang, Chen-Yao Liu, K. Liu, Y. Chien
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引用次数: 0
The Reason Analysis of Holland Blackout on March 27, 2015 and Lessons for Hunan Power Grid 2015年3月27日荷兰大停电原因分析及对湖南电网的启示
Pub Date : 2018-05-01 DOI: 10.18178/JOCET.2018.6.3.472
Meng Xiang, Dongzhen Yu, Wenlin Wang, Jian Zuo, Yangwu Shen, Xiaoqian Xie
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引用次数: 2
Numerical Analysis on Thermal Efficiency of Hybrid Solar Collector with Fin-and-Tube Heat Exchanger 翅片管式混合太阳能集热器热效率数值分析
Pub Date : 2018-05-01 DOI: 10.18178/JOCET.2018.6.3.464
H. U. Choi, R. Fatkhur, C. Son, J. I. Yoon, Y. B. Kim, K. Choi
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引用次数: 0
Economic Analysis on Electrolytic Hydrogen Production by Abandoned Wind Power 废弃风力发电电解制氢的经济分析
Pub Date : 2018-05-01 DOI: 10.18178/JOCET.2018.6.3.460
Guoxin He, Hongshui Lv, Yang Dongmei
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引用次数: 1
Development of a 200-kW Organic Rankine Cycle Power System for Low-Grade Waste Heat Recovery 用于低品位废热回收的200kw有机朗肯循环动力系统的研制
Pub Date : 2018-03-01 DOI: 10.18178/JOCET.2018.6.2.446
Taehong Sung, K. Kim
In this study, we designed a new plate-type heat exchanger system for the previous shell-and-tube evaporator with the same heat rate and additional turbine safety measure. The new evaporator system consists of two plate heat exchangers; one for preheating and the other for subsequent evaporation and superheating. The separate design reduces the liquid level of the evaporator and lowers the risk of liquid inflow into the turbine. For an additional driving stability, a co-current flow configuration was used for the preheater so that a subcooled liquid is introduced to the evaporator instead of a liquid-vapor mixture. A detailed design of the plate heat exchangers was carried out using a commercial software. The new heat exchangers are 75% smaller in volume and 83% smaller in weight. The designed heat exchangers were manufactured and installed in the previous ORC system. The performance was evaluated using an electric heater and a cooling tower as a heat source and heat sink. For the test, the working fluid pump was operated at the design point turbine inlet pressure of 2.13 MPa. Meanwhile, the condensation conditions were not matched to the design point due to the weather effect. Under the analysis condition, the new evaporator system showed an evaporator heat rate of 1662 kW, which is 91% of the design value with a pressure loss of 46 kPa. We calculated a pressure loss of 62.8 kPa for the design point using an equation for simple friction loss. The results showed that our new evaporator system successfully replaced the previous one without big performance losses.
本研究在原有管壳式蒸发器的基础上,设计了一种新的板式换热系统。新型蒸发器系统由两个板式换热器组成;一个用于预热,另一个用于随后的蒸发和过热。分离设计降低了蒸发器的液位,降低了液体流入涡轮的风险。为了增加驱动稳定性,预热器采用了共流配置,这样过冷液体就会被引入蒸发器,而不是液体-蒸汽混合物。利用商业软件对板式换热器进行了详细设计。新的热交换器体积缩小75%,重量减轻83%。所设计的热交换器是在以前的ORC系统中制造和安装的。使用电加热器和冷却塔作为热源和散热器对性能进行了评估。试验中,工作液泵在设计点涡轮进口压力2.13 MPa下运行。同时,由于天气的影响,凝结条件与设计点不匹配。在分析条件下,新蒸发器系统的蒸发器热率为1662 kW,为设计值的91%,压力损失为46 kPa。我们使用简单摩擦损失方程计算出设计点的压力损失为62.8 kPa。结果表明,新蒸发器系统成功地取代了原有的蒸发器系统,且没有造成较大的性能损失。
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引用次数: 3
期刊
Journal of Clean Energy Technologies
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