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Thermal stratification characteristics of a deep plateau lake and its response to extreme weather: A case study of Fuxian Lake 高原深层湖泊热分层特征及其对极端天气的响应——以抚仙湖为例
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104879
Chao Jin , Wei Ma , Peichen Zhang , Shunxin Feng , Yunfei Wang
Extreme weather events, including heatwaves, cold waves, and strong winds, significantly impact lake thermal stratification and aquatic ecosystem stability. This study applied the Environmental Fluid Dynamics Code (EFDC) hydrodynamic–thermal model to analyze the thermal stratification characteristics of Lake Fuxian and its response to extreme weather. The results indicate that the stratification period spans from March to December, with the mixed layer depth (MLD) varying between 6.86 m and 9.89 m in spring and summer, and deepening to 47.7 m in autumn and winter. Extreme heat compresses the MLD and increases surface temperature by 1.59 °C, while strong winds deepen the MLD, causing cooling at the surface and warming at greater depths. Cold waves slightly reduce the mixed-layer temperature and weaken the thermocline. Air temperature, solar radiation, and wind-driven turbulence jointly control the vertical temperature distribution, with wind-driven circulation playing a key role in surface temperature heterogeneity. These findings highlight the need for adaptive management strategies, such as adjusting water intake depths during heatwaves and enhancing monitoring during extreme weather events, to protect aquatic ecosystems under climate change.
极端天气事件,包括热浪、寒潮和强风,显著影响湖泊热分层和水生生态系统的稳定性。应用环境流体动力学规范(Environmental Fluid Dynamics Code, EFDC)水动力-热模型分析抚仙湖热分层特征及其对极端天气的响应。结果表明:分层期为3 ~ 12月,春夏季混合层深度(MLD)在6.86 ~ 9.89 m之间变化,秋冬季加深至47.7 m;极端的热量压缩了MLD,使表面温度升高了1.59°C,而强风使MLD加深,导致表面冷却而更深的深处变暖。冷波略微降低了混合层温度,减弱了温跃层。大气温度、太阳辐射和风动湍流共同控制着地表温度的垂直分布,其中风动环流对地表温度的非均质性起关键作用。这些发现强调了适应性管理策略的必要性,例如在热浪期间调整取水深度,在极端天气事件期间加强监测,以保护气候变化下的水生生态系统。
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引用次数: 0
The impact of navigation restoration on estuarine aquatic ecosystems: The case of the Xiaoqing River in China 航道修复对河口水生生态系统的影响——以中国小清河为例
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104874
Anfeng Zhang, Yinglan A, Jingzhi Yu, Jin Wu, Yuntao Wang, Baolin Xue, Kaiji Li, Lei Jin
Estuarine ecosystems play vital roles in sustaining regional biodiversity, water purification, and ecological buffering. However, the resumption of navigation can have a marked effect on ecosystem health through changes in water and sediment conditions. In this study, field measurements and remote sensing data were used to assess the ecological health of the Xiaoqing River estuary following the restoration of navigation. It focused on changes in physicochemical habitat factors and their key drivers affecting phytoplankton, zooplankton, and benthic communities. The findings indicate that the water quality in the estuary gradually improved after restoration of navigation, and mild to β-moderate pollution occurred. The water surface area increased and fluctuations decreased. Heavy metal risks still exist in some river mouth areas, with sediment mercury (Hg) and cadmium (Cd) concentrations maintaining mild to moderate levels. Heavy metals are major drivers of aquatic community structures. Zinc (Zn, p=0.044), copper (Cu), and Hg strongly influence planktonic assemblages. Phycocyanin (PC, p=0.006), cobalt (Co, p=0.04), Zn, and organic carbon are key factors for benthic communities. Overall, channel restoration projects have improved water quality and enhanced ecosystem integrity, but risks from residual pollutants persist, necessitating ongoing monitoring and management efforts.
河口生态系统在维持区域生物多样性、净化水体和生态缓冲等方面发挥着重要作用。然而,恢复通航可以通过改变水和沉积物条件对生态系统健康产生显著影响。本研究采用野外测量和遥感资料对小清河河口航道恢复后的生态健康状况进行了评价。重点研究了影响浮游植物、浮游动物和底栖生物群落的物化生境因子及其主要驱动因素的变化。结果表明:通航恢复后,河口水质逐渐改善,出现轻度至β-中度污染;水面面积增大,波动减小。部分江口地区仍存在重金属风险,沉积物中汞(Hg)和镉(Cd)浓度维持在轻度至中度水平。重金属是水生群落结构的主要驱动因素。锌(Zn, p=0.044)、铜(Cu)和汞对浮游生物组合有强烈影响。藻蓝蛋白(PC, p=0.006)、钴(Co, p=0.04)、锌和有机碳是底栖生物群落的关键因子。总体而言,河道修复工程改善了水质,增强了生态系统的完整性,但残留污染物的风险仍然存在,需要持续的监测和管理工作。
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引用次数: 0
Microplastics distribution on the beach sediment based on satellite remote sensing: A case study in Bali, Indonesia 基于卫星遥感的海滩沉积物微塑料分布:以印度尼西亚巴厘岛为例。
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104864
Mohd Rashidi Abdull Manap , Muhammad Ibadurrahman bin Imizan , Jannik Werner Dams , Felipe D. Sepulveda , Anna Muratore , Lorenza Notargiacomo , Fulvio Ferrara , Nur Hayatna Mukhni
Microplastic (MP) pollution is increasingly recognized as a critical issue in coastal environments, where complex interactions between ocean currents, winds, waves, and human activities govern the transport and deposition of synthetic particles. Although previous studies in Asia have documented MPs accumulation linked to riverine discharge, tourism pressures, and monsoonal circulation, limited work has integrated polymer-level characterization with site-specific hydrodynamic drivers, particularly along the coastlines of Bali. This study addresses this gap by examining how seasonal oceanographic processes influence MPs composition and distribution across three beaches: Keramas Beach (KB), Nyang Nyang Beach (NNB), and Balangan Beach (BB), between January and July 2024. This study provides a baseline, site-specific assessment of microplastic occurrence, polymer composition, and size distribution in three selected beach sediments of Bali, intended to establish reference conditions. Seventeen beach sediments were sampled and processed through dry sieving, microscopy, and attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy to identify particle sizes, morphologies, and polymer types. Hydrodynamic conditions were reconstructed using satellite-derived datasets from the Copernicus Marine Environment Monitoring Service (CMEMS) and the Copernicus Atmosphere Monitoring Service (CAMS), alongside estimates of riverine plastic discharge. A total of 10 MP particles (<5 mm) were identified, with polystyrene (PS) as the dominant polymer, followed by polypropylene (PP), polyvinyl alcohol (PVA), polymethyl methacrylate (PMMA), and three copolymers. MPs occurred primarily as fragments within the 2.5–5 mm range. The average MP concentrations were 2.54 ± 2.30, 2.04 ± 2.49, and 0.61 ± 1.37 MPs/kg dry weight (dw) at KB, NNB, and BB, respectively, following the order KB > NNB > BB. Spatial variability corresponded closely with hydrodynamic patterns: KB exhibited the highest MP concentration due to onshore winds and southwestward currents from the Lombok Strait; BB showed low retention driven by offshore wind stress and weak currents; and NNB displayed intermediate accumulation influenced by longshore drift and moderate river inputs. These findings highlight the value of integrating spectroscopic analysis with remote-sensing hydrodynamics to explain mechanisms of MP deposition, offering a strengthened basis for targeted monitoring, predictive modeling, and coastal pollution management in Bali and neighboring islands.
微塑料(MP)污染日益被认为是沿海环境中的一个关键问题,洋流、风、波和人类活动之间复杂的相互作用控制着合成颗粒的运输和沉积。虽然先前在亚洲的研究已经记录了MPs的积累与河流排放、旅游压力和季风环流有关,但有限的工作将聚合物水平的表征与特定地点的水动力驱动因素结合起来,特别是在巴厘岛海岸线上。本研究通过研究2024年1月至7月期间季节性海洋学过程如何影响三个海滩(Keramas海滩(KB)、Nyang Nyang海滩(NNB)和Balangan海滩(BB))的MPs组成和分布,解决了这一差距。本研究提供了巴厘岛三个选定海滩沉积物中微塑料发生、聚合物组成和尺寸分布的基线、特定地点评估,旨在建立参考条件。对17个海滩沉积物进行取样,并通过干筛、显微镜和衰减全反射-傅里叶变换红外(ATR-FTIR)光谱进行处理,以确定颗粒大小、形态和聚合物类型。利用哥白尼海洋环境监测服务(CMEMS)和哥白尼大气监测服务(CAMS)的卫星数据集,以及对河流塑料排放的估计,重建了水动力条件。共10个MP粒子(NNB b> BB)。空间变异与水动力模式密切相关:由于陆上风和龙目岛海峡西南流的影响,KB具有最高的MP浓度;BB在海上风应力和弱电流的驱动下,保留率较低;NNB表现为受海岸漂移和适度河流输入影响的中度堆积。这些发现突出了将光谱分析与遥感水动力学相结合来解释MP沉积机制的价值,为巴厘岛及邻近岛屿的针对性监测、预测建模和沿海污染管理提供了强有力的基础。
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引用次数: 0
Variations in microplastic pollution characteristics among different aquaculture modes: A case study from Dongting Lake area, China 不同养殖方式对微塑料污染特征的影响——以洞庭湖地区为例
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104878
Xiuzhen Nie , Diwen Sun , Xiang Long , Jiayi Tian , Xiaofeng Wen , Zixiang Chen , Yiming Qiu , Yawen Wang , Jiachi Shen , Yu Cai , Lingshi Yin
The widespread presence of microplastics in edible aquatic organisms has attracted considerable global attention, Thus, determining the level of microplastic pollution levels is crucial for ensuring dietary safety. In this study, we investigated microplastic contamination across four aquaculture modes (pond, lake, ecological, and facility) and four aquaculture species (fish, prawn, crab, and swamp eel) in the Dongting Lake area, which is a major region aquaculture area in China. The average abundance of microplastics in the aquaculture water in Dongting Lake was 11.58 ± 3.28 items/L. The pollution level was significantly higher in the swamp eel pond than in the fish, prawn and crab ponds. Integrated wetland purification and high-efficiency water treatment systems in ecological and facility fisheries exhibited significantly lower microplastic abundance compared to traditional aquaculture modes; however, a high concentration of microplastics were detected in the tailwater. These results indicate that the microplastic pollution characteristics across aquaculture systems are influenced by cultured species and operational modes. The implementation of ecological or management measures may be effective in reducing microplastic pollution levels. Our results provide a foundation for assessing microplastic contamination in fisheries and for developing management and remediation strategies.
微塑料在食用水生生物中的广泛存在引起了全球的广泛关注,因此,确定微塑料污染水平对于确保饮食安全至关重要。本研究以中国主要的区域水产养殖区洞庭湖区为研究对象,对四种养殖模式(池塘、湖泊、生态和设施)和四种养殖物种(鱼、虾、蟹和沼泽鳗)的微塑料污染进行了调查。洞庭湖水产养殖水体中微塑料平均丰度为11.58±3.28项/L。沼泽鳗鱼池的污染程度显著高于鱼虾蟹池。生态和设施渔业综合湿地净化和高效水处理系统的微塑料丰度显著低于传统水产养殖模式;然而,在尾水中检测到高浓度的微塑料。这些结果表明,不同养殖系统的微塑料污染特征受养殖种类和操作模式的影响。实施生态或管理措施可能有效降低微塑料污染水平。我们的研究结果为评估渔业微塑料污染以及制定管理和补救策略提供了基础。
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引用次数: 0
Evaluation of the protection of aquifers against pollution risks in karstic areas (PAPRIKA) method for predicting Cryptosporidium contamination 岩溶区含水层污染风险保护评价(PAPRIKA)隐孢子虫污染预测方法
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104860
Damien Costa , Maria A. Stoica , Gladys Foissey , Venceslas Villier , Romain Coppée , Antoine Morel , Romy Razakandrainibe , Loïc Favennec , Philippe Audra , Matthieu Fournier
Cryptosporidium spp. are protozoan parasites worldwide distributed, frequently responsible for gastrointestinal outbreaks from waterborne and foodborne origins. Overall European increase cryptosporidiosis incidence have recently been reported. Aim was to evaluate a specific intrinsic vulnerability mapping method for karst aquifers (PaPRIKa method) for application to Cryptosporidium contamination. Risk zones were mapped using the PaPRIKa vulnerability method enabling identification of sampling sites. From January to July 2021, eight sampling sites were investigated monthly. Cryptosporidium and bacterial contamination were evaluated using standard methods and confronted to water conductivity, turbidity, temperature and precipitation data to investigate potential correlation. Until 87% of sampling sites preselected using the PaPRIKa method were contaminated by Cryptosporidium suggesting the relevance of the method for identifying the most vulnerable sites. Oocysts were infectious in 81% of cases.Water temperature and precipitations influenced Cryptosporidium contamination. In the context of global changes where it is expected increase of waterborne disease, efficient tools to predict Cryptosporidium water resources contamination are mandatory. We suggest use of predictive tool for identification of vulnerable sites to monitor integrating nature of soils, levels of precipitations, soil saturation, land cover, urban waste and rearing areas.
隐孢子虫是一种分布在世界各地的原生动物寄生虫,经常引起水传播和食源性胃肠道疾病暴发。最近有报道称,欧洲隐孢子虫病发病率总体上升。目的评价喀斯特含水层固有脆弱性定位方法(PaPRIKa法)在隐孢子虫污染研究中的应用。使用PaPRIKa漏洞方法绘制风险区域,以便识别采样点。2021年1 - 7月,每月调查8个采样点。采用标准方法评价隐孢子虫和细菌污染,并与水的电导率、浊度、温度和降水数据进行比较,探讨潜在的相关性。直到使用PaPRIKa方法预先选择的采样点中有87%被隐孢子虫污染,这表明该方法与识别最脆弱的位点的相关性。卵囊在81%的病例中具有传染性。水温和降水影响隐孢子虫污染。在全球变化的背景下,水传播疾病预计会增加,预测隐孢子虫水资源污染的有效工具是必要的。我们建议使用预测工具来识别脆弱地点,以监测土壤的综合性质、降水水平、土壤饱和度、土地覆盖、城市废物和饲养区域。
{"title":"Evaluation of the protection of aquifers against pollution risks in karstic areas (PAPRIKA) method for predicting Cryptosporidium contamination","authors":"Damien Costa ,&nbsp;Maria A. Stoica ,&nbsp;Gladys Foissey ,&nbsp;Venceslas Villier ,&nbsp;Romain Coppée ,&nbsp;Antoine Morel ,&nbsp;Romy Razakandrainibe ,&nbsp;Loïc Favennec ,&nbsp;Philippe Audra ,&nbsp;Matthieu Fournier","doi":"10.1016/j.jconhyd.2026.104860","DOIUrl":"10.1016/j.jconhyd.2026.104860","url":null,"abstract":"<div><div><em>Cryptosporidium</em> spp. are protozoan parasites worldwide distributed, frequently responsible for gastrointestinal outbreaks from waterborne and foodborne origins. Overall European increase cryptosporidiosis incidence have recently been reported. Aim was to evaluate a specific intrinsic vulnerability mapping method for karst aquifers (PaPRIKa method) for application to <em>Cryptosporidium</em> contamination. Risk zones were mapped using the PaPRIKa vulnerability method enabling identification of sampling sites. From January to July 2021, eight sampling sites were investigated monthly. <em>Cryptosporidium</em> and bacterial contamination were evaluated using standard methods and confronted to water conductivity, turbidity, temperature and precipitation data to investigate potential correlation. Until 87% of sampling sites preselected using the PaPRIKa method were contaminated by <em>Cryptosporidium</em> suggesting the relevance of the method for identifying the most vulnerable sites. Oocysts were infectious in 81% of cases.Water temperature and precipitations influenced <em>Cryptosporidium</em> contamination. In the context of global changes where it is expected increase of waterborne disease, efficient tools to predict <em>Cryptosporidium</em> water resources contamination are mandatory. We suggest use of predictive tool for identification of vulnerable sites to monitor integrating nature of soils, levels of precipitations, soil saturation, land cover, urban waste and rearing areas.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"277 ","pages":"Article 104860"},"PeriodicalIF":4.4,"publicationDate":"2026-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146073938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of key control factors on pollutant migration by suspended cutoff walls in contaminated sites 污染场地悬浮截流墙对污染物迁移的关键控制因素评价
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104867
Honghan Dong , Yun-Min Chen , Wenjie Xu
This study develops a two-dimensional numerical model for seepage and pollutant transport in sites with suspended cutoff walls, grounded in the advection–dispersion equation. The impacts of key factors, including the pressure head of the pollution source, the site's horizontal hydraulic gradient, and the horizontal distance between the downstream wall and the pollution source, on the non-linear seepage distribution and the wall's anti-pollution performance were investigated. Centrifuge model tests were conducted to confirm the numerical model's dependability. Furthermore, the concentration at the downstream wall bottom reaching 10% C0 was established as the threshold for identifying the suspended containment system's failure. The research findings demonstrate that modifications to the site flow field due to parameter changes are a significant factor contributing to the macroscopic variations in pollutant migration. As the pressure head of the pollution source diminishes from 1.2 m to 0.3 m, the peak flow velocity at the mid-point of the liner bottom reduces by 25.6%, while the service life of the wall extends by 51.1%. The site flow-field distribution is significantly impacted, with the wall's service life increasing by 209.1% and 22.8%, respectively, as the site's horizontal hydraulic gradient decreases from 0.04 to 0.01 and the horizontal distance between the downstream wall and the pollution source increases from 4 m to 16 m. Therefore, the design of suspended cutoff walls in risk control of contaminated sites with deeply buried aquitards should focus on aspects related to these three factors.
本研究建立了一个基于平流-弥散方程的具有悬空截流墙场地渗流和污染物运移的二维数值模型。研究了污染源压头、场地水平水力梯度、下游墙与污染源水平距离等关键因素对非线性渗流分布和墙抗污染性能的影响。通过离心模型试验验证了数值模型的可靠性。并将下游壁底浓度达到10% C0作为悬置安全壳系统失效的识别阈值。研究结果表明,参数变化对现场流场的影响是造成污染物迁移宏观变化的重要因素。当污染源压头从1.2 m减小到0.3 m时,衬管底部中点峰值流速降低25.6%,壁寿命延长51.1%。随着场地水平水力梯度从0.04减小到0.01,下游墙与污染源的水平距离从4 m增加到16 m,对场地流场分布产生了显著影响,墙的使用寿命分别增加了209.1%和22.8%。因此,深埋输水污染场地风险控制中的悬式防渗墙设计应重点考虑这三个因素的相关方面。
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引用次数: 0
Tracing coastal nonpoint sources of agricultural organic pollution based on soil sequestration and retention processes: A case study of the Yellow River Delta, China 基于土壤固存和滞留过程的沿海农业有机污染源追踪——以黄河三角洲为例
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104871
Youxiao Wang , Zhaomin Zhang , Zhonghe Zhao , He Li , Yingjun Sun , Chong Huang , Banghua Zhang , Gaohuan Liu
China has been confronted with severe agricultural nonpoint source pollution (AGNSP) from livestock and poultry, which increases chemical oxygen demand (COD). To explore the sources of COD in surface waters from the perspective of ecosystem processes, taking the coastal watershed of the Yellow River Delta (YRD) of China as a typical study area, we have adopted a method that integrates the scale and positioning of livestock and poultry breeding, a pollutant generation coefficient, and kernel density estimation (KDE) to assess the COD diffusion risk during watershed soil erosion processes. Moreover, verification and analysis were performed by combining soil sampling data with hydrological and water quality monitoring data for the estuary. Additionally, we selected Spearman's coefficient for correlation analysis between surface soil organic matter (SOM) and related natural-anthropogenic factors. The main conclusions are as follows: the terrestrial COD pollution risks generated by livestock and poultry significantly influence SOM (p < 0.001) and are most strongly correlated in non-arable lands, especially saline-alkali land (rs = 0.86) mainly because of natural soil erosion process. Arable land has the highest SOM concentrations but has lower correlations with the COD generation risks obtained by the KDE method, mainly because of cultivation activities. At the watershed scale, surface runoff is the dominant driver of estuarine COD fluxes but has certain dilution effects on COD concentrations. Furthermore, there usually exists the spillover effects of AGNSP from livestock and poultry usually occur due to the imbalanced distributions between the area of arable land and the supply of manure within watersheds. Our study provides an effective and rapid assessment method for determining the AGNSP risk of COD derived from livestock and poultry.
畜禽非点源污染严重,导致化学需氧量(COD)增加。为从生态系统过程的角度探讨地表水COD的来源,以黄河三角洲沿海流域为典型研究区,采用畜禽养殖规模与定位、污染物生成系数、核密度估算(KDE)相结合的方法,对流域土壤侵蚀过程中COD扩散风险进行了评估。并将土壤采样数据与河口水文水质监测数据相结合进行验证分析。此外,我们选取Spearman系数进行表层土壤有机质(SOM)与相关自然-人为因子的相关分析。主要结论如下:畜禽产生的陆源COD污染风险显著影响土壤有机质(p < 0.001),且与非耕地相关性最强,尤其是盐碱地(rs = 0.86),主要是由于自然土壤侵蚀过程。耕地的SOM浓度最高,但与KDE法所得的COD生成风险相关性较低,主要受耕作活动的影响。在流域尺度上,地表径流是河口COD通量的主要驱动因素,但对COD浓度有一定的稀释作用。此外,由于流域内耕地面积与粪肥供应的分布不平衡,畜禽AGNSP往往存在溢出效应。本研究为确定畜禽源性COD的AGNSP风险提供了一种有效、快速的评估方法。
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引用次数: 0
Methodology for evaluating matrix diffusion and sorption parameters in crystalline rocks: Application to laboratory and in-situ diffusion experiments at the Grimsel Test Site 评价结晶岩石中基质扩散和吸附参数的方法:在格里姆塞尔试验场的实验室和现场扩散实验中的应用
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104865
Yuta Fukatsu , Tomomi Oguri , Takafumi Hamamoto , Keisuke Ishida , Andrew Martin , Yukio Tachi
For long-term safety assessments of deep geological disposal, evaluating effective diffusion coefficients (De) and distribution coefficients (Kd) under in-situ conditions remains a critical yet challenging task due to practical limitations. This study aims to establish a methodology for evaluating these parameters under realistic geological conditions through an integrated analysis of a long-term in-situ diffusion (LTD-II) experiment and complementary laboratory through-diffusion experiments in Grimsel granodiorite. The proposed approach combines (i) post analysis of cored samples to characterize spatial variations in pore connectivity and anisotropic transport, (ii) numerical modeling that accounts for the borehole disturbed zone (BDZ), and (iii) laboratory diffusion experiments to verify the consistency and reliability of in-situ parameter estimation.
The modeling reproduced both the depletion curves and the tracer concentration profiles observed in the LTD-II experiment, particularly the sharp gradients within a few millimeters from the injection hole, which were attributed to BDZ. The derived De and Kd values for sorbing tracers (Na+, Cs+, and Ba2+) were consistent between laboratory and in-situ conditions for transport distances up to several centimeters, confirming the reliability of the parameter derivation approach for sorbing species over short distances. In contrast, non-sorbing tracers (HTO and 36Cl) exhibited depth-dependent concentration variations extending ∼50 cm from the injection hole. The De values of non-sorbing tracers were two to three times higher than those obtained in laboratory tests, yet remained within the same order of magnitude. These variations of non-sorbing tracers could be qualitatively explained by anisotropic transport along foliation and minor advection over several tens of centimeters, highlighting the importance of accounting for local structural and hydraulic variations when interpreting in-situ diffusion data.
These results demonstrate that integrating in-situ diffusion data with laboratory verification and spatial profiling provides a methodology for deriving diffusion and sorption parameters representative of in-situ conditions, and clarifies the practical limitations and applicable range of transport modeling in crystalline rocks.
对于深部地质处置的长期安全性评估,由于实际条件的限制,评估原位条件下的有效扩散系数(De)和分布系数(Kd)仍然是一项关键但具有挑战性的任务。本研究旨在通过对Grimsel花岗闪长岩长期原位扩散(LTD-II)实验和补充实验室透扩散实验的综合分析,建立在现实地质条件下评价这些参数的方法。该方法结合了(i)岩心样品的后期分析,以表征孔隙连通性和各向异性输运的空间变化;(ii)考虑井眼扰动区(BDZ)的数值模拟;(iii)实验室扩散实验,以验证原位参数估计的一致性和可靠性。该模型重现了在LTD-II实验中观察到的耗尽曲线和示踪剂浓度曲线,特别是在距注入孔几毫米范围内的急剧梯度,这归因于BDZ。吸附示踪剂(Na+, Cs+和Ba2+)的推导De和Kd值在实验室和现场条件下在长达几厘米的传输距离上是一致的,证实了参数推导方法在短距离上吸附物种的可靠性。相比之下,非吸附示踪剂(HTO和36Cl−)表现出深度依赖的浓度变化,从注射孔延伸至50 cm。非吸附示踪剂的De值比实验室检测的De值高2 ~ 3倍,但仍保持在同一数量级内。这些非吸附示踪剂的变化可以通过沿叶理的各向异性输运和几十厘米的小平流来定性解释,这突出了在解释原位扩散数据时考虑局部结构和水力变化的重要性。这些结果表明,将原位扩散数据与实验室验证和空间剖面相结合,为推导代表原位条件的扩散和吸附参数提供了一种方法,并阐明了结晶岩石输运建模的实际局限性和适用范围。
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引用次数: 0
Groundwater discharge and dissolved inorganic carbon flux into an open-type coal mining subsidence lake in eastern China 中国东部露天采煤沉陷湖地下水排放与溶解无机碳通量
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104870
Chunlu Jiang , Yuqun Zhang , Qianqian Wang
Groundwater discharge and associated dissolved carbon fluxes are essential parameters in wetland ecosystems of coal mining subsidence lakes. Previous studies have shown that groundwater discharge considerably contributes to isolated coal mining subsidence lakes. However, groundwater discharge and associated dissolved inorganic carbon (DIC) flux into open-type subsidence lakes remain poorly understood. In this study, radioactive (222Rn) and stable water isotopes (18O) were used as tracers to establish isotope mass balance models, and to quantify groundwater discharge into an open-type coal mining subsidence lake. The results showed that the estimated lacustrine groundwater discharge (LGD) rates using the 222Rn and 18O mass balance models were 38.54 ± 21.05 mm/d and 27.89 ± 3.53 mm/d, respectively, which accounted for 15.56% and 12.30% of the total source of lake water. On this basis, combined with a DIC end-member mixing model and CO2 diffusion model, DIC flux from LGD was 70.33 ± 1.41 mmol/(m2·d), accounting for 19.10% of the total lake DIC inventory and 65.60% of the total CO2 evasion from the lake. The results suggest that CO2 escape from freshwater lakes may be an important source of atmospheric carbon, which should be included in the carbon budget of lake budgets. The results provide a theoretical basis for accurate assessment of groundwater discharge and the carbon budget in open-type subsidence lakes. This is important for local water environment protection and the utilization of water resources.
地下水流量及其伴生碳通量是煤矿沉陷湖湿地生态系统的重要参数。以往的研究表明,地下水排放对孤立的煤矿沉陷湖有很大的贡献。然而,地下水排放及其伴生的溶解无机碳(DIC)通量对开放式沉陷湖的影响尚不清楚。本研究以放射性同位素(222Rn)和稳定水同位素(18O)为示踪剂,建立同位素质量平衡模型,量化露天采煤沉陷湖地下水排放。结果表明:222Rn和18O质量平衡模型估算的湖泊地下水流量分别为38.54±21.05 mm/d和27.89±3.53 mm/d,分别占湖泊总水源的15.56%和12.30%;在此基础上,结合DIC端元混合模型和CO2扩散模型,得出LGD的DIC通量为70.33±1.41 mmol/(m2·d),占湖泊DIC总存量的19.10%,占湖泊CO2逃避总量的65.60%。结果表明,淡水湖的CO2逸出可能是大气碳的重要来源,应纳入湖泊碳收支。研究结果为准确评价开放式沉降湖的地下水流量和碳收支提供了理论依据。这对当地水环境保护和水资源利用具有重要意义。
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引用次数: 0
Assessment of groundwater vulnerability to heavy metals in four aquifers using machine learning algorithms 利用机器学习算法评估四个含水层地下水对重金属的脆弱性。
IF 4.4 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2026-02-01 DOI: 10.1016/j.jconhyd.2026.104853
Gholamheidari Hamideh , Entezari Mojgan
Using a machine learning framework, this study investigates the spatial distribution and key environmental factors of heavy metal contamination (iron, nickel, lead, copper) in four groundwater aquifers of Isfahan province during the water year 2023–2024. A total of 150 wells were sampled and metal concentrations were determined using ICP-MS, AAS, VGA, and Mercury Analyzer methods in accordance with WHO and Iranian standards. The maximum observed concentrations of iron, nickel, lead and copper were approximately 48, 44.1, 2.9 and 11.2 mg/L respectively, with the peak concentrations of iron and copper in the Damaneh - Daran aquifers, nickel in Bouin and lead in Chadegan. Random Forest (RF) and Support Vector Machine (SVM) models were used, and in RF, 100 trees were used for accurate predictions. Multiple collinearity between environmental predictors, including soil properties, unsaturated and saturated zones, hydraulic parameters, slope, groundwater level, and aquifer depth was assessed through variance inflation factor (VIF), all of which were below 10. Model interpretation showed that soil properties and groundwater level had the greatest influence in RF, while the unsaturated layer was dominant in SVM. Iron decreased with increasing aquifer depth, pore thickness, and water table, while soil permeability and slope increased iron accumulation. Nickel was higher in shallow, shallow, and low-conductivity areas, while lead increased with depth and slope, indicating a nonlinear dependence on hydraulic and soil properties. Copper was positively correlated with soil permeability and negatively correlated with water table. Spatial predictions showed that the Bouin aquifer showed the highest iron and nickel (more than 40 and more than 30 mg/L), lead reached about 44 mg/L in Chadegan, and copper peaked in Bouin from southeast to northwest. RF outperformed SVM by achieving an accuracy of 0.7874, sensitivity of 0.7448, and specificity of 0.8243, while SVM performed poorly. This study innovatively combines machine learning models with the parameters of the DRASTIC analytical model to assess and predict heavy metal contamination in the aquifers of Isfahan province. Overall, the results confirm the nonlinear hydrogeological controls on heavy metal distribution and demonstrate the high capability of RF for reliable prediction of groundwater contamination. This approach provides a transferable method for groundwater quality assessment and supports sustainable aquifer management in arid and semi-arid regions.
利用机器学习框架,研究了2023-2024水年期间伊斯法罕省4个地下水含水层重金属污染(铁、镍、铅、铜)的空间分布及其关键环境因素。共取样150口井,采用ICP-MS、原子吸收光谱法、VGA和汞分析仪方法,按照WHO和伊朗标准测定金属浓度。铁、镍、铅和铜的最大浓度分别约为48、44.1、2.9和11.2 mg/L,铁和铜的峰值在达玛内-达兰含水层,镍在布因含水层,铅在查德干含水层。使用随机森林(RF)和支持向量机(SVM)模型,在随机森林中,使用100棵树进行准确预测。土壤性质、非饱和带和饱和带、水力参数、坡度、地下水位和含水层深度等环境预测因子之间的多重共线性通过方差膨胀因子(VIF)进行评价,结果均小于10。模型解释表明,土壤性质和地下水位对支持向量机的影响最大,而非饱和层对支持向量机的影响最大。铁随含水层深度、孔隙厚度和地下水位的增加而减少,土壤渗透性和坡度增加了铁的积累。在浅层、浅层和低导电性区域,镍含量较高,而铅含量随深度和坡度的增加而增加,表明与水力和土壤性质的非线性依赖。铜与土壤渗透性呈正相关,与地下水位呈负相关。空间预测结果表明,布因含水层铁和镍含量最高(分别大于40和30 mg/L),铅含量在查德干达到44 mg/L左右,铜含量从东南向西北在布因含水层最高。RF的准确率为0.7874,灵敏度为0.7448,特异度为0.8243,优于SVM,而SVM表现较差。本研究创新性地将机器学习模型与DRASTIC分析模型的参数相结合,以评估和预测伊斯法罕省含水层中的重金属污染。总体而言,研究结果证实了水文地质对重金属分布的非线性控制,并证明了RF在可靠预测地下水污染方面的高能力。这种方法为地下水质量评价提供了一种可转移的方法,并支持干旱和半干旱地区的可持续含水层管理。
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引用次数: 0
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Journal of contaminant hydrology
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