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Establishing a silica gel zone in well annulus and evaluating its performance in blocking vertical water flow
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2025.104510
Lirong Zhong, Jonathan N. Thomle, Rob D. Mackley, Zoe G. Vincent, Frederick D. Day-Lewis
Wells are often constructed for monitoring purposes with relatively long screen lengths (e.g., >10 m). Vertical water flows can occur within the artificial or natural filter pack annulus that surround the screened interval, bypassing packer assemblies installed inside the wellbore. Attempts to isolate discrete vertical zones during groundwater sampling are unsuccessful when annular vertical flow occurs which lead to remedy decisions based on biased or incorrect interpretations. Blocking vertical annular water flow and contaminant transport will help obtain more accurate concentrations of contaminants from sampling in targeted depth intervals. The application of silica gels formed from the injected colloidal silica (CS) suspensions is a novel approach to minimize or prevent vertical movement of groundwater in the surrounding filter pack annulus. In this study, we tested the feasibility of injecting CS suspensions to target locations and developed a modified CS formulation that is injectable and prevents gravity sinking. We studied the spatial distribution and penetration of silica gel at laboratory scale in model well annulus with surrounding formations. We evaluated the performance of the silica gel in blocking vertical water flow in the annulus and in minimizing chemical transport through the gel zone. CS suspension formulations have been defined that are ready for injection, persist in target locations, and form gel within desired time frames. Injection of CS suspensions achieved uniform distribution in a well annulus filter pack, fully occupied the annulus pore space, and penetrated the formation surrounding the filter packer with a sufficient distance to create a hydraulic annular seal when the injection was applied at a sufficient rate. Silica gel that formed in the annulus blocked vertical water flow and stopped the chemical transport through the gel zone. This research reveals that using CS suspension injection and sequential gelation (CS-GEL) is a promising technology for blocking vertical water flow and chemical transport through the filter pack in targeted zones within the annulus of long-screened well systems.
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引用次数: 0
Characterization and risk assessment of microplastics pollution in Mohamaya Lake, Bangladesh 孟加拉国莫哈玛雅湖微塑料污染的特征和风险评估。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2024.104487
Mohammed Manik , Md. Tauhid Hossain , Paolo Pastorino
Microplastics (MPs) have recently gained attention as emerging environmental contaminants, yet knowledge of their distribution, sources, and risks in freshwater lakes remains limited. This study examined the occurrence and risk of MPs in water and sediment samples from eight locations in Mohamaya Lake (Bangladesh) collected in April and May 2023. MPs were identified using stereomicroscopy and FTIR, revealing concentrations of 20–95 particles/L in water and 550–1900 particles/kg (d.w.) in sediment, with mean values of 50.62 ± 9.95 particles/L and 1068.75 ± 521.49 particles/kg (d.w.). Dominant MPs were blue fibers, 0–0.5 mm in size, with HDPE, PET and LDPE as the most common polymers. This study used four indices (nemerow pollution index-NPI, contamination factor-CF, pollution load index-PLI, and polymer hazard index-PHI) to assess MP pollution, revealing light to high contamination levels. While NPI indicated light pollution, CF, PLI, and PHI highlighted areas of moderate to high risk, with certain polymers showing high to extreme toxicity. This study deepens understanding of MP contamination in Bangladesh's freshwater lakes, underscoring the need for research on ecotoxicology, regulation, and associated challenges.
微塑料(MPs)作为新兴的环境污染物最近引起了人们的关注,但对它们在淡水湖中的分布、来源和风险的了解仍然有限。本研究检查了2023年4月和5月在孟加拉国Mohamaya湖8个地点收集的水和沉积物样本中MPs的发生率和风险。利用立体显微镜和红外光谱对MPs进行了鉴定,发现水中的MPs浓度为20 ~ 95粒/L,沉积物中的MPs浓度为550 ~ 1900粒/kg (d.w.),平均值分别为50.62±9.95粒/L和1068.75±521.49粒/kg (d.w.)。主要的MPs是蓝色纤维,尺寸为0-0.5 mm,以HDPE, PET和LDPE为最常见的聚合物。本研究采用四个指标(nemerow污染指数- npi、污染因子- cf、污染负荷指数- pli和聚合物危害指数- phi)来评估MP污染,揭示了高污染水平的光。NPI表示光污染,而CF、PLI和PHI则强调了中度至高风险区域,某些聚合物显示出高至极高的毒性。这项研究加深了对孟加拉国淡水湖泊中多聚磷污染的理解,强调了对生态毒理学、监管和相关挑战进行研究的必要性。
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引用次数: 0
Aging-mediated selective adsorption of antibiotics by tire wear particles: Hydrophobic and electrostatic interactions effects 老化介导的轮胎磨损颗粒对抗生素的选择性吸附:疏水和静电相互作用效应。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2024.104482
Jiale Xu , Yuting Zhang , Shaoxin Zi , Xuanqi Zhang , Zhengtong Qian , Jin Liu
Tire wear particles (TWPs), as a prevalent form of microplastic pollution in aquatic environments, have been shown to adsorb antibiotics, potentially exacerbating their toxic effects. This study provides a comprehensive analysis of the adsorption of ofloxacin (OFL), ciprofloxacin (CIP), sulfadiazine (SDZ), and tetracycline (TC) on TWPs that have undergone various aging processes, including cyclic freeze-thaw and ozone aging. We observed a significant increase in the specific surface area (SBET) of TWPs after aging, from an initial 2.81 ± 0.29 to 6.63 ± 0.16 m2/g for ozone-aged TWPs. This enhancement in surface area and pore volume led to a respective 1.36-fold and 28-fold increase in adsorption capacity for OFL and CIP, highlighting the substantial impact of aging on TWPs' adsorptive properties. Conversely, the adsorption of SDZ and TC was reduced post-aging, suggesting a complex interaction between antibiotic physicochemical properties and TWPs' surface characteristics. The pseudo-second-order model, indicating chemisorption interactions, effectively described the adsorption kinetics, with the Freundlich isotherm model capturing the adsorption behavior more accurately than the Langmuir model. Our findings underscore the critical role of hydrophobic and electrostatic interactions in the adsorption process, particularly for SDZ and TC. This study's results offer crucial insights into the environmental implications of TWPs, emphasizing the need for further research on their role in the transport and fate of antibiotics in aquatic ecosystems.
轮胎磨损颗粒(TWPs)是水生环境中普遍存在的微塑料污染形式,已被证明可以吸附抗生素,从而可能加剧抗生素的毒性作用。本研究综合分析了氧氟沙星(OFL)、环丙沙星(CIP)、磺胺嘧啶(SDZ)和四环素(TC)在经历了循环冻融和臭氧老化等不同老化过程的twp上的吸附情况。我们观察到老化后TWPs的比表面积(SBET)显著增加,臭氧老化后TWPs的比表面积从最初的2.81±0.29 m2/g增加到6.63±0.16 m2/g。表面面积和孔隙体积的增加导致对OFL和CIP的吸附量分别增加了1.36倍和28倍,突出了老化对TWPs吸附性能的重大影响。相反,老化后SDZ和TC的吸附减少,表明抗生素的物理化学性质与twp的表面特性之间存在复杂的相互作用。表明化学吸附相互作用的伪二阶模型有效地描述了吸附动力学,Freundlich等温线模型比Langmuir模型更准确地捕捉了吸附行为。我们的研究结果强调了疏水和静电相互作用在吸附过程中的关键作用,特别是对于SDZ和TC。这项研究的结果为twp的环境影响提供了重要的见解,强调需要进一步研究它们在水生生态系统中抗生素的运输和命运中的作用。
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引用次数: 0
A modelling framework to analyze climate change effects on radionuclide aquifer contamination 分析气候变化对放射性核素含水层污染影响的模拟框架。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2024.104470
Thomas Matteo Coscia , Francesco Di Maio , Enrico Zio
Non-stationarity of climatic variables (e.g., temperature and precipitation) due to Climate Change (CC) can affect the migration processes of radionuclides released from nuclear activities. In this paper, a framework of analysis is developed to predict the evolution in time of contaminant concentration and fluence under different Climatic Boundary Conditions (CBCs) of precipitation scenarios provided by a climate model integrated with an accurate physical coupled hydraulic-transport model. A case study is worked out with respect to the migration of a radioactive contaminant (232Th) at Kirtland Air Force Base (Albuquerque, New Mexico, USA), for which the different CBCs considered are: i) stationary and ii) non-stationary precipitation. The effects of such alternative hypotheses on the physical modelling results are analysed, using a cross-wavelet analysis. It is shown that fluence is strongly affected by precipitation extremes, more than concentration, and it is claimed that a daily scale on the information and data of CBCs is necessary to model, with sufficient accuracy, the migration process and properly assess the impact of future CC on groundwater contamination.
气候变化(CC)引起的气候变量(如温度和降水)的非平稳性可影响核活动释放的放射性核素的迁移过程。本文建立了一个分析框架,以预测不同降水情景气候边界条件(CBCs)下污染物浓度和影响的时间演变,该分析框架由气候模式与精确的物理耦合水力-输运模式相结合。在科特兰空军基地(美国新墨西哥州阿尔伯克基)对放射性污染物(232Th)的迁移进行了案例研究,其中考虑的不同CBCs是:i)固定沉淀和ii)非固定沉淀。使用交叉小波分析,分析了这些替代假设对物理模拟结果的影响。研究表明,降水极端事件对影响的影响比对浓度的影响更大,并认为有必要对CBCs的信息和数据进行日尺度的模拟,以达到足够的精度,并正确评估未来CC对地下水污染的影响。
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引用次数: 0
Quantification of denitrification rate in shallow groundwater using the single-well, push-pull test technique
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2025.104500
Aldrin Rivas , Ranvir Singh , David Horne , Jonathan Roygard , Abby Matthews , Michael Hedley
Denitrification has been identified as a significant nitrate attenuation process in groundwater systems. Hence, accurate quantification of denitrification rates is consequently important for the better understanding and assessment of nitrate contamination of groundwater systems. There are, however, few studies that have investigated quantification of shallow groundwater denitrification rates using different analytical approaches or assuming different kinetic reaction models. In this study, we assessed different analytical approaches (reactant versus product) and kinetic reaction (zero-order and first-order) models analysing observations from a single-well, push-pull tests to quantify denitrification rates in shallow groundwater at two sites in the Manawatū River catchment, Lower North Island of New Zealand. Shallow groundwater denitrification rates analysed using the measurements of denitrification reactant (nitrate reduction) and zero-order kinetic models were quantified at 0.42–1.07 mg N L−1 h−1 and 0.05–0.12 mg N L−1 h−1 at the Palmerston North (PNR) and Woodville (WDV) sites, respectively. However, using first-order kinetic models, the denitrification rates were quantified at 0.03–0.09 h−1 and 0.002–0.012 h−1 at the PNR and WDV sites, respectively. These denitrification rates based on the measurements of denitrification reactant (nitrate reduction) were quantified significantly higher (6 to 60 times) than the rates estimated using the measurements of denitrification product (nitrous oxide production). However, the denitrification rate quantified based on the nitrate reduction may provide representative value of denitrification characteristics of shallow groundwater systems. This is more so when lacking practical methods to quantify all nitrogen species (i.e., total N, organic N, nitrite, nitrate, ammoniacal N, nitrous oxide, nitric oxide, and nitrogen gas) in a push-pull test. While estimates of denitrification rates also differed depending on the kinetic model used, both a zero-order and a first-order model appear to be valid to analyse and estimate denitrification rate from push-pull tests. However, a discrepancy in estimates of denitrification rates using either reactant or product and using zero- or first-order kinetics models may have implications in assessment of nitrate transport and transformation in groundwater systems. This necessitates further research and analysis for appropriate measurements and representation of spatial and temporal variability in denitrification characteristics of the shallow groundwater system.
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引用次数: 0
Pathways and risk analysis of arsenic and heavy metal pollution in riverine water: Application of multivariate statistics and USEPA-recommended risk assessment models 河流中砷和重金属污染的途径和风险分析:多变量统计和usepa推荐的风险评估模型的应用。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2024.104483
Kifayatullah Khan , Muhammad Sajawal Khan , Muhammad Younas , Muhammad Yaseen , Abdullah G. Al-Sehemi , Yasar N. Kavil , Chao Su , Niaz Ali , Afsheen Maryam , Ruoyu Liang
This study analyzed surface water from the River Swat, Pakistan, using inductively coupled plasma mass spectrometry, multivariate statistical techniques, and US-EPA risk assessment models to evaluate the concentrations, distribution, pathways, and potential risks of arsenic (As) and heavy metals, including chromium (Cr), manganese (Mn), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), cadmium (Cd), mercury (Hg), and lead (Pb). The results revealed significant correlations (p ≤ 0.01) among metals that indicated common pollution sources, likely influenced by anthropogenic point and non-point activities. Along the monitored sites (S1–S10), the mass flow of ∑metals showed a dynamic pattern: progressively increasing downstream, decreasing at S6–S7, rising again at S7–S8, and then steadily declining toward S10, with Ni being the most abundant metal, followed by Cr > As> Cu > Mn > Co > Zn > Hg > Cd > Pb. The As and Heavy Metal Pollution Index (HPI), As and Heavy Metal Evaluation Index (HEI), and Pollution Index (PI) revealed variations in pollution levels, ranking the metals in the orders of Co > As> Cr > Cd > Mn > Hg > Ni > Pb > Cu > Zn, As> Cr > Ni > Hg > Cd > Co > Mn > Cu > Zn > Pb, and Hg > Ni > As> Co > Cu > Cd > Mn > Zn > Pb, respectively. However, according to the risk assessment, overall individual metal contamination in the River Swat water was below the ecological risk threshold (ERI 〈110). Where, the Chronic Daily Intakes (CDIs), Hazard Quotients (HQs), Hazard Indices (HIs), Cancer Risks (CRs), and Total Cancer Risks (TCRs) of Cr, Mn, Co, Ni, Cu, Zn, As, Cd, Hg, and Pb associated with daily river water intake and dermal contact indicate that long-term exposure to untreated river water may pose both carcinogenic and non-carcinogenic health risks to residents.
本研究分析了巴基斯坦斯瓦特河的地表水,使用电感耦合等离子体质谱法、多元统计技术和US-EPA风险评估模型来评估砷(As)和重金属的浓度、分布、途径和潜在风险,包括铬(Cr)、锰(Mn)、钴(Co)、镍(Ni)、铜(Cu)、锌(Zn)、镉(Cd)、汞(Hg)和铅(Pb)。结果表明,各金属元素之间存在显著的相关性(p≤0.01),表明常见污染源可能受到人为点源和非点源活动的影响。沿监测点位(s1 ~ S10),∑金属的质量流表现为下游逐渐增加,在s6 ~ s7处下降,在s7 ~ s8处再次上升,然后向S10方向稳步下降,其中Ni含量最高,Cr > As> Cu > Mn > Co > Zn > Hg > Cd > Pb含量次之。和重金属污染指数(HPI),重金属评价指标(黑),和污染指数(PI)显示污染水平的变化,排名金属有限公司的订单> >铬>镉>锰> Hg >镍>铅>铜>锌、>铬>镍>汞>镉>有限公司>锰>铜>锌>铅、和Hg >镍> >有限公司>铜> Cd >锰>锌> Pb,分别。然而,根据风险评估,斯瓦特河水体中个体金属污染总体低于生态风险阈值(ERI < 110)。其中,Cr、Mn、Co、Ni、Cu、Zn、As、Cd、Hg、Pb的慢性每日摄入量(cdi)、危害商(HQs)、危害指数(HIs)、癌症风险(CRs)和总癌症风险(TCRs)与每日河流饮水量和皮肤接触的关系表明,长期暴露于未经处理的河流水可能对居民造成致癌和非致癌的健康风险。
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引用次数: 0
From brushite to hydroxylapatite: A study on phosphate mineral transformation and the fate of oxytetracycline 从刷石到羟基磷灰石:磷矿物转化与土霉素命运的研究。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2025.104497
Jianan Guo, Lina Chen, Xinying Zhang, Changmin Jin, Yue Cui
Livestock manure, a common fertilizer in Chinese agriculture, can lead to environmental contamination and potential health risks due to elevated antibiotic and phosphorus levels. Importantly, the high phosphorus levels initiates transformations of phosphate minerals in soils, especially calcareous soils. These variations in phosphate mineralogy can significantly impact the migration and fate of antibiotics within the soil. However, the impact of the transformation process, particularly involving the metastable phase brushite (DCPD), on the fate of antibiotics remains unclear. In this study, we synthesized DCPD and hydroxylapatite (HAP) and examined their transformation process to assess their removal capacity and investigate the migration and fate of oxytetracycline (OTC). The findings reveal that HAP exhibits a maximum immobilization capacity for OTC of 20.10 mg/g, surpassing that of DCPD by 2.56 times (7.86 mg/g). This disparity in immobilization capacity between DCPD and HAP leads to a redistribution of OTC between the solid and liquid phases during the transformation process. Notably, the introduction of OTC also inhibits the transformation process, potentially impacting the fate of other potentially harmful elements. The study highlights that the transformation process of calcium phosphorus minerals has a significant impact on the mobility and fate of antibiotics in soil, which aids in better management and mitigation of the environmental risks associated with fertilizer application.
禽畜粪便是中国农业中常见的肥料,由于抗生素和磷含量的升高,会导致环境污染和潜在的健康风险。重要的是,高含量的磷会引发土壤(尤其是石灰性土壤)中磷酸盐矿物的转化。磷酸盐矿物学的这些变化会对土壤中抗生素的迁移和归宿产生重大影响。然而,转化过程对抗生素归宿的影响,尤其是涉及到易变相刷状石(DCPD)的转化过程对抗生素归宿的影响仍不清楚。在本研究中,我们合成了 DCPD 和羟基磷灰石 (HAP),并考察了它们的转化过程,以评估它们的去除能力,并研究土霉素 (OTC) 的迁移和归宿。研究结果表明,HAP 对 OTC 的最大固定能力为 20.10 毫克/克,是 DCPD 的 2.56 倍(7.86 毫克/克)。DCPD 和 HAP 在固定能力上的差异导致 OTC 在转化过程中在固相和液相之间重新分布。值得注意的是,引入 OTC 还会抑制转化过程,从而可能影响其他潜在有害元素的去向。该研究强调,磷钙矿物的转化过程对土壤中抗生素的流动性和归宿有重大影响,这有助于更好地管理和减轻与施肥相关的环境风险。
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引用次数: 0
Influence of wettability on water retention curves in unconsolidated porous media 疏松多孔介质中润湿性对保水曲线的影响
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2025-02-01 DOI: 10.1016/j.jconhyd.2025.104502
Gerhard Schäfer , Kevin Hernandez Perez , Panav Hulsurkar , Magda Ibrahim Youssif , François Lehmann , Mohammad Piri
Controlled laboratory experiments were carried out using the hanging column method. Prior to the experiments, three uniform silica sands, which were originally water-wet, were aged in contact with crude oil until they were moderately oil-wet. Five fractionally wet sands were obtained by mixing the water-wet sands with oil-wet sands containing 25, 50 and 75 vol% oil-wet sands. A total of 11 tests formed the basis for the present study. The measured water retention curves showed that the capillary pressure heads were greatly reduced in sands that were oil-wet or fractionally wet. Changes in the wettability of the sands also affected their irreducible water saturation: The higher the proportion of oil-wet sand in the sand mixtures, the lower the irreducible water saturation. To quantify the characteristics of the measured water retention curves, the Van Genuchten model was used. The two optimized parameters seem to indicate a general trend: The higher the volume fraction of oil-wet sand, the higher is α and the lower is n. For the three unaged sands and the aged medium-sized sand, it was found that each of the two branches of the measured retention curves can be suitably scaled to a unique curve if, in addition to the petrophysical parameters (intrinsic permeability, porosity, surface tension, gas-water contact angle), the irreducible residual water saturation and the residual air saturation are taken into account. To quantify the observed deviations of the other two aged sands from the unified Leverett J-function, a theoretical fit function was used to match the experimental data of the three unaged sands. The experimental data sets for P2040ag and P100ag were found to be overestimated overall by the fit function. However, when the petrophysical parameters of the unaged sands were used instead of the actual measured parameters, the individual experimental Leverett J-functions came closer to the uniform J-curve. Based on this, it could be concluded that the apparent differences in pore structure between aged and unaged sands in addition to wettability, expressed by the cosine of the contact angle, may have contributed to a further reduction in the capillary pressure plateaus of the aged sands, which was particularly visible and significant in the P2040 and P100 sand. Using the measured static contact angles for two-phase gas-oil and oil-water systems and the measured interfacial tensions when the porous medium is either water-wet or moderately oil-wet, it was shown that the Bartell-Osterhof equation overestimates the measured gas-water contact angles. Reasonable agreement was achieved when a calibrated roughness factor of the solid surface was considered in the Young's contact angle.
采用悬挂柱法进行了室内对照试验。在实验之前,三种均匀的硅砂,最初是水湿的,在与原油接触中老化,直到它们具有适度的油湿性。将水湿砂与含油量分别为25%、50%和75%的油湿砂混合,得到5种分湿砂。共有11项测试构成了本研究的基础。实测的保水曲线表明,在油湿或部分湿砂中,毛管压力头大大降低。砂体润湿性的变化也影响其不可还原水饱和度:油湿砂在砂体混合物中的比例越高,其不可还原水饱和度越低。为了量化所测保水曲线的特征,采用了Van Genuchten模型。这两个优化后的参数似乎表明了一个总体趋势:油湿砂体积分数越大,α值越高,n值越低。对于3种未老化砂和中等老化砂,除了考虑岩石物性参数(固有渗透率、孔隙度、表面张力、气水接触角)外,考虑不可还原残余水饱和度和残余气饱和度,所测截留曲线的两个分支都可以适当地缩放成一条独特的曲线。为了量化观测到的另外两种老化砂与统一的Leverett j函数的偏差,采用理论拟合函数对三种未老化砂的实验数据进行拟合。通过拟合函数发现P2040ag和P100ag的实验数据集总体上被高估。然而,当使用未老化砂岩的岩石物性参数代替实际测量参数时,单个实验Leverett j函数更接近均匀的j曲线。由此可以得出结论,老化砂与未老化砂在孔隙结构上的明显差异以及以接触角余弦值表示的润湿性可能是导致老化砂毛管压力高原进一步降低的原因,这在P2040和P100砂中尤为明显和显著。利用实测的气-油-油-水两相体系的静态接触角,以及孔隙介质为水湿或中度油湿时实测的界面张力,表明Bartell-Osterhof方程高估了实测的气-水接触角。当在杨氏接触角中考虑固体表面的校准粗糙度因子时,获得了合理的一致性。
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引用次数: 0
Use of process-based coupled ecological-hydrodynamic models to support lake water ecosystem service protection planning at the regional scale 基于过程的耦合生态水动力模型在区域尺度上支持湖泊生态系统服务保护规划
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-26 DOI: 10.1016/j.jconhyd.2024.104469
Andrea Fenocchi , Nicolò Pella , Diego Copetti , Fabio Buzzi , Daniele Magni , Nico Salmaso , Claudia Dresti
Protection plans of lake waters are based on ecological and/or chemical targets, often simplified in terms of total phosphorus (TP) concentrations, customarily the depth-averaged ones at spring mixing for temperate environments. These target lake TP concentrations are then commonly employed to determine target external loading through reverse use of Vollenweider-OECD-type steady-state empirical models. Such models are also adopted in their direct form to estimate lake TP concentrations following hypothetical external load reductions. However, such approaches suffer from extreme parameterisation and often give inaccurate results. Process-based coupled ecological-hydrodynamic models offer a much wider flexibility and produce an extensive set of information, solving many of the issues of Vollenweider-OECD-type models. However, their application has been up to now restricted to single lakes due to calibration effort and data availability burdens. To overcome these obstacles, in this study we developed a simplified application of the process-based coupled model QWET over 9 lakes in Northern Italy, making use of the ParSAC automatic calibration tool and feeding the models only with general data available from public monitoring. QWET models were calibrated over past observations, simulating nutrient reduction scenarios for the near-future decades. The advantages over traditionally employed models for lake water protection planning at the regional scale were hence identified through a practical application, determining the strengths and limits of the herein-adopted simplified process-based approach over lakes with different features. Obtained results were also analysed considering the specific case study.
湖泊水域的保护计划以生态和/或化学目标为基础,通常简化为总磷(TP)浓度,通常是温带环境春季混合时的深度平均浓度。这些目标湖泊总磷浓度通常通过反向使用vollenweider - oecd型稳态经验模型来确定目标外部负荷。这些模型也被直接用于估算假设外部负荷减少后的湖泊总磷浓度。然而,这种方法受到极端参数化的影响,常常给出不准确的结果。基于过程的耦合生态-水动力模型提供了更大的灵活性,并产生了广泛的信息集,解决了vollenweider - oecd型模型的许多问题。然而,由于校准工作和数据可用性负担,到目前为止,它们的应用仅限于单个湖泊。为了克服这些障碍,在这项研究中,我们开发了一个基于过程的耦合模型QWET在意大利北部9个湖泊的简化应用,利用ParSAC自动校准工具,并仅为模型提供来自公共监测的一般数据。QWET模型是根据过去的观测校准的,模拟了近未来几十年的营养减少情景。通过实际应用,确定了区域尺度上湖泊水体保护规划相对于传统模型的优势,确定了本文采用的基于简化过程的方法在不同湖泊特征上的优势和局限性。结合具体案例,对所得结果进行了分析。
{"title":"Use of process-based coupled ecological-hydrodynamic models to support lake water ecosystem service protection planning at the regional scale","authors":"Andrea Fenocchi ,&nbsp;Nicolò Pella ,&nbsp;Diego Copetti ,&nbsp;Fabio Buzzi ,&nbsp;Daniele Magni ,&nbsp;Nico Salmaso ,&nbsp;Claudia Dresti","doi":"10.1016/j.jconhyd.2024.104469","DOIUrl":"10.1016/j.jconhyd.2024.104469","url":null,"abstract":"<div><div>Protection plans of lake waters are based on ecological and/or chemical targets, often simplified in terms of total phosphorus (<em>TP</em>) concentrations, customarily the depth-averaged ones at spring mixing for temperate environments. These target lake <em>TP</em> concentrations are then commonly employed to determine target external loading through reverse use of Vollenweider-OECD-type steady-state empirical models. Such models are also adopted in their direct form to estimate lake <em>TP</em> concentrations following hypothetical external load reductions. However, such approaches suffer from extreme parameterisation and often give inaccurate results. Process-based coupled ecological-hydrodynamic models offer a much wider flexibility and produce an extensive set of information, solving many of the issues of Vollenweider-OECD-type models. However, their application has been up to now restricted to single lakes due to calibration effort and data availability burdens. To overcome these obstacles, in this study we developed a simplified application of the process-based coupled model QWET over 9 lakes in Northern Italy, making use of the ParSAC automatic calibration tool and feeding the models only with general data available from public monitoring. QWET models were calibrated over past observations, simulating nutrient reduction scenarios for the near-future decades. The advantages over traditionally employed models for lake water protection planning at the regional scale were hence identified through a practical application, determining the strengths and limits of the herein-adopted simplified process-based approach over lakes with different features. Obtained results were also analysed considering the specific case study.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104469"},"PeriodicalIF":3.5,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746711","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential health, environmental implication of microplastics: A review on its detection 微塑料对健康、环境的潜在影响:微塑料检测研究进展
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-22 DOI: 10.1016/j.jconhyd.2024.104467
Bhawana Yadav , Payal Gupta , Vinay Kumar , Mridul Umesh , Deepak Sharma , Jithin Thomas , Suraj Kumar Bhagat
Microplastic contamination of terrestrial and aquatic environment has gained immense research attention due to their potential ecotoxicity and biomagnification property when enterer into food chain. Heterogenous nature of microplastics coupled with their ability to combine with other emerging pollutants have increased the severity of this crisis. Existing detection methods often fails to accurately quantify the amount of microplastic components present in environmental and biological samples. Thus, a great deal of research gap always exists in our current understanding about microplastics including the limitations in screening, detection and mitigation. This review work presents a comprehensive out look on the impact of microplastics on both terrestrial and aquatic environment. Furthermore, an in-depth discussion on various microplastic detection techniques recently used for microplastic quantification along with their significance and limitations is summarised in this review. The review also elaborates various physical, chemical and biological methods used for the mitigation of microplastics from environmental samples.
由于微塑料进入食物链后具有潜在的生态毒性和生物放大特性,陆地和水生环境的微塑料污染受到了广泛的关注。微塑料的异质性以及它们与其他新出现的污染物结合的能力增加了这场危机的严重性。现有的检测方法往往不能准确地量化环境和生物样品中存在的微塑料成分的数量。因此,我们目前对微塑料的认识一直存在很大的研究空白,包括在筛选、检测和缓解方面的局限性。本文综述了微塑料对陆地和水生环境的影响。此外,本文还深入讨论了近年来用于微塑料定量的各种微塑料检测技术及其意义和局限性。该报告还阐述了用于减少环境样品中微塑料的各种物理、化学和生物方法。
{"title":"Potential health, environmental implication of microplastics: A review on its detection","authors":"Bhawana Yadav ,&nbsp;Payal Gupta ,&nbsp;Vinay Kumar ,&nbsp;Mridul Umesh ,&nbsp;Deepak Sharma ,&nbsp;Jithin Thomas ,&nbsp;Suraj Kumar Bhagat","doi":"10.1016/j.jconhyd.2024.104467","DOIUrl":"10.1016/j.jconhyd.2024.104467","url":null,"abstract":"<div><div>Microplastic contamination of terrestrial and aquatic environment has gained immense research attention due to their potential ecotoxicity and biomagnification property when enterer into food chain. Heterogenous nature of microplastics coupled with their ability to combine with other emerging pollutants have increased the severity of this crisis. Existing detection methods often fails to accurately quantify the amount of microplastic components present in environmental and biological samples. Thus, a great deal of research gap always exists in our current understanding about microplastics including the limitations in screening, detection and mitigation. This review work presents a comprehensive out look on the impact of microplastics on both terrestrial and aquatic environment. Furthermore, an in-depth discussion on various microplastic detection techniques recently used for microplastic quantification along with their significance and limitations is summarised in this review. The review also elaborates various physical, chemical and biological methods used for the mitigation of microplastics from environmental samples.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"268 ","pages":"Article 104467"},"PeriodicalIF":3.5,"publicationDate":"2024-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142746710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of contaminant hydrology
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