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Characterization of microplastics in soil, leachate and groundwater at a municipal landfill in Rayong Province, Thailand 泰国罗勇府一个城市垃圾填埋场的土壤、沥滤液和地下水中微塑料的特征。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-11-01 DOI: 10.1016/j.jconhyd.2024.104455
Wanlapa Wisitthammasri , Phatchareeporn Promduang , Srilert Chotpantarat
Recent years have witnessed a dramatic increase in global plastic production, leading to heightened concerns over microplastics (MPs) contamination as a significant environmental challenge. MP particles are ubiquitously distributed across both continental and marine ecosystems. Given the paucity of research on MPs in Thailand, particularly regarding MPs contamination in terrestrial environments, this study focused on investigating the distribution and characteristics of MPs in a landfill area. We collected 15 soil samples, 2 leachate samples, and 7 groundwater samples from both inside and outside a municipal landfill situated in the urbanized coastal region of Rayong Province. Our findings revealed variability in MPs concentration across different sample types. In soil, the MP count ranged from 240 to 26,100 pieces per kg of dry soil, 58.71 % of all sample sizes are lower than 0.5 mm. Similarly, the size found in the leachate sample, and the average MP in the leachate samples was 139 pieces per liter of MPs. The groundwater samples showed a fluctuation in MPs count from 18 to 94 pieces per liter, and the size of MPs ranged mostly from 0.5 to 1 mm. The predominant forms of MPs identified were sheets, followed by fragments, fibers, and granules. According to μ-FTIR analysis, the majority of the MPs were composed of polyethylene and polypropylene, commonly used in plastic packaging and ropes. The observed high concentrations and extensive distribution of MP contamination underscore the urgency for further studies and effective management strategies to mitigate the adverse impacts of this pollution on various organisms and ecosystems.
近年来,全球塑料产量急剧增加,导致人们更加关注微塑料(MPs)污染这一重大环境挑战。微塑料颗粒在大陆和海洋生态系统中无处不在。鉴于泰国有关 MPs 的研究很少,特别是有关陆地环境中 MPs 污染的研究,本研究重点调查了垃圾填埋场中 MPs 的分布和特征。我们从罗勇府城市化沿海地区的一个市政垃圾填埋场内外采集了 15 份土壤样本、2 份沥滤液样本和 7 份地下水样本。我们的研究结果表明,不同类型的样本中 MPs 的浓度存在差异。在土壤中,每公斤干土中的 MP 数量从 240 到 26,100 不等,58.71% 的样本尺寸小于 0.5 毫米。同样,在沥滤液样本中也发现了这种尺寸,沥滤液样本中的 MP 平均值为每升 139 粒。地下水样本中的 MPs 数量从每升 18 个到 94 个不等,MPs 的大小大多在 0.5 毫米到 1 毫米之间。经鉴定,主要的 MPs 形态是片状,其次是碎片、纤维和颗粒。根据μ-傅立叶变换红外分析,大多数 MPs 由聚乙烯和聚丙烯组成,常用于塑料包装和绳索。观察到的 MP 污染物浓度高、分布广,突出表明迫切需要进一步研究和制定有效的管理策略,以减轻这种污染对各种生物和生态系统的不利影响。
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引用次数: 0
A semi-probabilistic Bayesian method to identify the number and location of potential sources in 3D unconfined aquifer using limited observed concentration 利用有限的观测浓度,采用半概率贝叶斯方法确定三维无约束含水层中潜在污染源的数量和位置。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-22 DOI: 10.1016/j.jconhyd.2024.104447
Bandaru Goutham Rajeev Gandhi , Rajib Kumar Bhattacharjya
Source identification of a contaminant has always been challenging for accurately modeling groundwater transport. Source identification problems are classified into several parts, such as identifying the location of contamination, the strength of contamination, the time the contaminant is introduced into the groundwater, and the duration of its activity. Identifying the sources considering all the parts as variables increases the computational complexity. Reducing the number of variables in source identification problems is necessary for a swift solution through optimization approaches. The most challenging variable in source identification modeling is the location of contamination, as it is a discrete variable for almost all the numerical solutions of groundwater models. In this research study, we have created a methodology to narrow the location of contamination from a random distribution throughout the aquifer to a reasonable number of probable locations. Although methods to identify the location of contamination were devised earlier, we have attempted an approach of combining a particle tracking approach with Bayesian method of updating the probabilities as a novel approach, where the observation data is limited. We have considered the aquifer parameters and observation well data and devised a method with a Lagrangian approach to particle movement to identify the potential source locations. We have refined the source locations to a narrower probability distribution using the Bayesian method of updating the probability through new information of refined grid space. We have tested the models to identify the potential sources with different hypothetical problems and identified the sources in advective dominant transport with an average probability of 0.53, diffusion dominant transport with an average probability of 0.62, heterogenous soils with an average probability of 0.99, anisotropic aquifer with an average probability of 0.91, and aquifer with irregular boundary with an average probability of 0.96 to identify the location nearest to the actual contaminant source. The results are satisfactory in identifying the number of potential sources with an accuracy of 88 % (15 identified out of 17 sources with a probability greater than 0.4) and their locations in the aquifer with a probability of 0.223 for exact location identification. The probability of finding a source nearest to the actual location is 0.745 at an average distance of 11.6 m from the actual source location.
要准确模拟地下水的迁移,污染物的来源识别一直是个难题。污染源识别问题分为几个部分,如识别污染位置、污染强度、污染物进入地下水的时间及其活动持续时间。将所有部分都视为变量来识别污染源会增加计算的复杂性。要想通过优化方法快速解决问题,就必须减少污染源识别问题中的变量数量。污染源识别建模中最具挑战性的变量是污染位置,因为它是几乎所有地下水模型数值解法中的离散变量。在这项研究中,我们创建了一种方法,将污染位置从整个含水层的随机分布缩小到合理数量的可能位置。虽然确定污染位置的方法早有设计,但在观测数据有限的情况下,我们尝试将粒子跟踪方法与更新概率的贝叶斯方法相结合,作为一种新方法。我们考虑了含水层参数和观测井数据,设计了一种采用拉格朗日粒子运动方法来确定潜在污染源位置的方法。我们利用贝叶斯方法,通过细化网格空间的新信息更新概率,将水源位置细化为较窄的概率分布。我们用不同的假设问题测试了识别潜在污染源的模型,在平流主导传输中识别污染源的平均概率为 0.53,在扩散主导传输中识别污染源的平均概率为 0.62,在异质土壤中识别污染源的平均概率为 0.99,在各向异性含水层中识别污染源的平均概率为 0.91,在不规则边界含水层中识别污染源的平均概率为 0.96,从而识别出距离实际污染源最近的位置。在确定潜在污染源数量方面,结果令人满意,准确率为 88%(17 个污染源中确定了 15 个,概率大于 0.4),在含水层中确定污染源位置的准确概率为 0.223。在距离实际水源位置平均 11.6 米的地方,找到最接近实际位置的水源的概率为 0.745。
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引用次数: 0
Microplastics in wastewater plants: A review of sources, characteristics, distribution and removal technologies 污水处理厂中的微塑料:来源、特征、分布和去除技术综述。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-22 DOI: 10.1016/j.jconhyd.2024.104448
Zhihao Hu, Yongjun Sun, Jun Zhou, Wenquan Sun, Kinjal J. Shah
Microplastics (MPs) are widespread in everyday life, and since wastewater treatment plants (WWTPs) serve as an important route for MPs to enter natural water bodies, a thorough understanding of the distribution and removal of MPs in wastewater treatment plants is of great importance. This article provides a comprehensive overview of the measured distribution of MPs and the current status of their removal in wastewater treatment plants. The main sources of MPs in wastewater treatment plants are personal care products in domestic wastewater, textile clothing and industrial wastewater made from plastics, textile factories and the friction of road tires. The MPs that entered the sewage treatment plant were predominantly in the form of fibers, fragments, granular MPs and other types of MPs. The size of MPs is divided into three categories: <0.5 mm, 0.5–1 mm and 1–5 mm. At all treatment stages in wastewater plants, 56.8–88.4 % of MPs are removed in primary treatment, but the primary sedimentation and degreasing stages remove most MPs. The efficiency of the activated sludge process for secondary treatment is inconsistent and is generally between 42.1 and 99.2 %. The coagulation, filtration and disinfection stages of tertiary treatment all have some MPs removal capacity. In addition, novel removal technologies are also described, such as modified filtration technology, membrane separation technology, electroflocculation, sol-gel and photocatalysis. These novel removal technologies can further limit the entry of microplastics into natural water bodies through sewage treatment plants and improved sewage treatment processes help reduce the risk of MPs entering the natural environment through sewage treatment plants. This article will provide reference for the distribution and removal of microplastics in various levels of WWTPs.
微塑料(MPs)广泛存在于日常生活中,而污水处理厂(WWTPs)是微塑料进入自然水体的重要途径,因此全面了解污水处理厂中微塑料的分布和去除情况具有重要意义。本文全面概述了污水处理厂中 MPs 的测量分布和去除现状。污水处理厂中 MPs 的主要来源是生活污水中的个人护理产品、纺织服装以及由塑料、纺织厂和公路轮胎摩擦产生的工业废水。进入污水处理厂的 MPs 主要以纤维、碎片、颗粒状 MPs 和其他类型 MPs 的形式存在。根据 MPs 的大小可分为三类:
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引用次数: 0
Patterns of spatiotemporal variations in the hydrochemistry and controlling factors of bedrock aquifers in the northern region of the Linhuan mining area 临环矿区北部地区基岩含水层水化学时空变化规律及控制因素。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-22 DOI: 10.1016/j.jconhyd.2024.104450
Miao Zhang , Luwang Chen , Xiaowei Hou , Yongsheng Hu , Jie Zhang , Jun Li , Xiaoxi Yin , Xiaoping Shi , Xinyue Cai
Systematically studying the hydrochemical evolution of bedrock groundwater in mining areas during mining process is crucial for effective groundwater resource management and coal mine production. The spatiotemporal characteristics and hydrochemical evolution patterns of the Permian fractured sandstone aquifer (PA) and the Carboniferous Taiyuan Formation limestone aquifer (CTA), both of which are directly associated with coal mining in the northern Linhuan mining area, China, were investigated using multivariate statistical analyses, hydrochemical graphical methods, ion ratio analysis, and a conceptual model. 72 groundwater samples, collected before and after mining, were classified into four groups by hierarchical cluster analysis (HCA). Principal component analysis (PCA) and ion ratio analysis indicated that water-rock interactions involve mineral dissolution (carbonates, gypsum, dolomite, silicates), cation exchange, and common ion effects. Hydrochemical evolution is influenced by bedrock paleotopography, aquifer hydraulic conductivity, and mining drainage. Paletopographic differences significantly influence water-rock interactions and spatial variability in hydrochemistry, with ion concentrations in groundwater increasing as paleotopographic elevation decreases. The pattern of hydraulic conductivity reflects the control exerted by variations in aquifer characteristics on mineral dissolution, leading to minor changes in hydrochemical characteristics. Mining activities disrupt the aquifer's reducing environment, resulting in a significant increase in groundwater SO42− concentration. These findings provide insights and a solid theoretical foundation for studying the hydrochemical variations patterns of groundwater and these control mechanisms in the hidden coal fields of North China.
系统研究矿区基岩地下水在开采过程中的水化学演变规律,对于有效管理地下水资源和煤矿生产至关重要。本研究采用多元统计分析、水化学图解法、离子比值分析和概念模型,研究了中国临环北部矿区与煤炭开采直接相关的二叠系断裂砂岩含水层(PA)和石炭系太原地层石灰岩含水层(CTA)的时空特征和水化学演化规律。通过层次聚类分析(HCA)将采矿前后采集的 72 个地下水样本分为四组。主成分分析(PCA)和离子比率分析表明,水与岩石的相互作用涉及矿物溶解(碳酸盐、石膏、白云石、硅酸盐)、阳离子交换和常见离子效应。水化学演变受基岩古地形、含水层导水性和采矿排水的影响。古地形差异极大地影响了水与岩石的相互作用以及水化学的空间变化,地下水中的离子浓度随着古地形标高的降低而增加。水力传导模式反映了含水层特征的变化对矿物溶解的控制,从而导致水化学特征的微小变化。采矿活动破坏了含水层的还原环境,导致地下水 SO42- 浓度显著增加。这些发现为研究华北隐伏煤田地下水的水化学变化规律及其控制机制提供了启示和坚实的理论基础。
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引用次数: 0
Determining the evaporation and evolution of surface water in a large catchment using isotopes and multiple models 利用同位素和多种模型确定大型集水区地表水的蒸发和演变。
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-16 DOI: 10.1016/j.jconhyd.2024.104446
Xiang Dong , Xing Chen , Fazhi Xie , Liugen Zheng , Zihan Zhang , Xinyi Fu , Tianqi Ma
The evolution and formation mechanisms of chemical components in surface water can reflect changes in the geological background of a basin and the extent of human interference. The Yangtze River basin is the largest water source area in China, yet its main ion sources and formation mechanisms are not fully understood. This study uses a combination of hydrochemistry, stable isotopes (δ18O, δD), the Craig-Gordon model, and the APCS-MLR model to quantitatively assess the water source replenishment and evaporation intensity of surface water in the Yangtze River. The study reveals the primary ion sources and controlling factors of surface water in the Yangtze River. The results show that the hydrochemical type in the upstream is mainly HCO3-Ca2+ and Na+-K+, while in the midstream and downstream it is primarily HCO3-Ca2+ and SO42−-Ca2+. The evolution of hydrochemical types is mainly controlled by rock weathering and human inputs. The surface water sources in the Yangtze River are directly replenished by precipitation, with the evaporation ratio in the upstream (0.66) being higher than in the midstream (0.63) and downstream (0.47). The lc-excess in the upstream (−0.32 ‰) is lower than in the midstream (1.21 ‰) and downstream (−0.27 ‰), indicating more intense evaporation in the upstream. The hydrochemical composition of the Yangtze River surface water mainly comes from geological factors (80.5 %), industrial factors (11.1 %), agricultural factors (6.4 %), and unknown factors (2.0 %). This study enhances the understanding of the chemical composition, water source replenishment, ion sources, and evolution mechanisms of the Yangtze River surface water, providing a basis for maintaining water quality and sustainable development in the Yangtze River basin.
地表水中化学成分的演变和形成机制可以反映流域地质背景的变化和人为干扰的程度。长江流域是中国最大的水源区,但其主要离子源和形成机制尚未完全清楚。本研究结合水化学、稳定同位素(δ18O、δD)、Craig-Gordon 模型和 APCS-MLR 模型,对长江地表水的水源补给和蒸发强度进行了定量评估。研究揭示了长江地表水的主要离子源和控制因子。结果表明,上游水化学类型主要为 HCO3--Ca2+和 Na+-K+,中下游主要为 HCO3--Ca2+和 SO42--Ca2+。水化学类型的演变主要受岩石风化和人为输入的控制。长江地表水源由降水直接补充,上游蒸发比(0.66)高于中游(0.63)和下游(0.47)。上游的 lc-过量(-0.32‰)低于中游(1.21‰)和下游(-0.27‰),表明上游的蒸发更为强烈。长江地表水的水化学组成主要来自地质因素(80.5%)、工业因素(11.1%)、农业因素(6.4%)和未知因素(2.0%)。该研究加深了人们对长江地表水化学成分、水源补给、离子来源和演变机理的认识,为保持长江流域水质和可持续发展提供了依据。
{"title":"Determining the evaporation and evolution of surface water in a large catchment using isotopes and multiple models","authors":"Xiang Dong ,&nbsp;Xing Chen ,&nbsp;Fazhi Xie ,&nbsp;Liugen Zheng ,&nbsp;Zihan Zhang ,&nbsp;Xinyi Fu ,&nbsp;Tianqi Ma","doi":"10.1016/j.jconhyd.2024.104446","DOIUrl":"10.1016/j.jconhyd.2024.104446","url":null,"abstract":"<div><div>The evolution and formation mechanisms of chemical components in surface water can reflect changes in the geological background of a basin and the extent of human interference. The Yangtze River basin is the largest water source area in China, yet its main ion sources and formation mechanisms are not fully understood. This study uses a combination of hydrochemistry, stable isotopes (δ<sup>18</sup>O, δD), the Craig-Gordon model, and the APCS-MLR model to quantitatively assess the water source replenishment and evaporation intensity of surface water in the Yangtze River. The study reveals the primary ion sources and controlling factors of surface water in the Yangtze River. The results show that the hydrochemical type in the upstream is mainly HCO<sub>3</sub><sup>−</sup>-Ca<sup>2+</sup> and Na<sup>+</sup>-K<sup>+</sup>, while in the midstream and downstream it is primarily HCO<sub>3</sub><sup>−</sup>-Ca<sup>2+</sup> and SO<sub>4</sub><sup>2−</sup>-Ca<sup>2+</sup>. The evolution of hydrochemical types is mainly controlled by rock weathering and human inputs. The surface water sources in the Yangtze River are directly replenished by precipitation, with the evaporation ratio in the upstream (0.66) being higher than in the midstream (0.63) and downstream (0.47). The lc-excess in the upstream (−0.32 ‰) is lower than in the midstream (1.21 ‰) and downstream (−0.27 ‰), indicating more intense evaporation in the upstream. The hydrochemical composition of the Yangtze River surface water mainly comes from geological factors (80.5 %), industrial factors (11.1 %), agricultural factors (6.4 %), and unknown factors (2.0 %). This study enhances the understanding of the chemical composition, water source replenishment, ion sources, and evolution mechanisms of the Yangtze River surface water, providing a basis for maintaining water quality and sustainable development in the Yangtze River basin.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"267 ","pages":"Article 104446"},"PeriodicalIF":3.5,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142501313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Feasibility evaluation of a blended cover with activated carbon for in-situ stabilization of DDT in sediment 用活性炭混合覆盖物就地稳定沉积物中滴滴涕的可行性评估
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-15 DOI: 10.1016/j.jconhyd.2024.104445
Yeo-Myoung Cho, Brooke J. Pauken, Anna E. Tovkach, Oliver B. Fringer, Stephen G. Monismith, Richard G. Luthy
Activated carbon (AC) sediment amendment is an in-situ remediation technology in which the applied AC immobilizes organic contaminant flux from sediments, thereby reducing contaminant bioavailability and associated risks. While various studies have demonstrated the feasibility of in-situ AC treatment, hesitation to apply this technology exists due to limited experience under field-specific scour conditions and hydrodynamic forces. To address this concern, we conducted a feasibility study for an AC-blended cover at the Lauritzen Channel of the United Heckathorn Superfund Site in Richmond, California, United States, which was contaminated with dichlorodiphenyltrichloroethane and its metabolites (DDx) as well as dieldrin. Vessel activities causing sediment disturbance were identified as key factors for remedy selection. A blended cover with AC and coarse materials was designed to withstand varied hydrodynamic conditions and AC stability was tested in a current flume. The cover comprised medium-size gravel (D50 = 15 mm, D90 = 19 mm) with 4 % granular AC by weight. Flume erosion studies showed minimal AC loss (1–2 % of total AC) under shear forces of 9–31 Pa, which was equivalent to or exceeded the estimated worst-case erosional conditions in the channel induced by a hypothetical, stationary tugboat propelling at high power thrust. The treatability performance of the engineered blended cover design was evaluated through mesocosm studies using site sediment and various cover options. Post-treatment assessments on days 5 and 145 showed rapid reductions in freely dissolved (Cfree) DDx and dieldrin in the blended cover layers and surface water. For example, by day 145, Cfree DDx was reduced by over 98 %, meeting US EPA remedial goals for the site. It is concluded that the combination of both stability and performance testing demonstrates that an engineered blended cover-AC design would be a feasible remedial option at the site, and that this testing approach can be applied to evaluate in-situ treatment in other sediment cleanup activities.
活性炭(AC)沉积物改良是一种原位修复技术,应用活性炭可固定沉积物中的有机污染物通量,从而降低污染物的生物利用率和相关风险。虽然各种研究都证明了原位活性碳处理的可行性,但由于在现场特定冲刷条件和水动力作用下的经验有限,人们对应用这种技术还存在犹豫。为了解决这一问题,我们在美国加利福尼亚州里士满的 United Heckathorn 超级基金遗址的劳瑞岑水道进行了 AC 混合覆盖的可行性研究,该水道受到二氯二苯三氯乙烷及其代谢物(DDx)以及狄氏剂的污染。造成沉积物扰动的船只活动被认为是选择补救措施的关键因素。设计了一种含有 AC 和粗粒材料的混合覆盖层,以承受不同的水动力条件,并在水流槽中测试了 AC 的稳定性。覆盖层由中等大小的砾石(D50 = 15 毫米,D90 = 19 毫米)和 4% 的颗粒状 AC(按重量计)组成。水槽侵蚀研究表明,在 9-31 Pa 的剪切力作用下,AC 损失极小(占 AC 总量的 1-2%),这相当于或超过了假定的静止拖船以大功率推力推进时在河道中造成的最坏侵蚀条件。通过使用现场沉积物和各种盖板方案进行中型宇宙研究,对工程混合盖板设计的可处理性进行了评估。第 5 天和第 145 天的处理后评估显示,混合覆盖层和地表水中自由溶解(不含游离碳)的 DDx 和狄氏剂迅速减少。例如,到第 145 天,不含 C 的 DDx 减少了 98% 以上,达到了美国环保局为该场地制定的补救目标。结论是,稳定性和性能测试的结合表明,工程混合覆盖层-AC 设计是该场址可行的补救方案,而且这种测试方法可用于评估其他沉积物清理活动中的原位处理。
{"title":"Feasibility evaluation of a blended cover with activated carbon for in-situ stabilization of DDT in sediment","authors":"Yeo-Myoung Cho,&nbsp;Brooke J. Pauken,&nbsp;Anna E. Tovkach,&nbsp;Oliver B. Fringer,&nbsp;Stephen G. Monismith,&nbsp;Richard G. Luthy","doi":"10.1016/j.jconhyd.2024.104445","DOIUrl":"10.1016/j.jconhyd.2024.104445","url":null,"abstract":"<div><div>Activated carbon (AC) sediment amendment is an in-situ remediation technology in which the applied AC immobilizes organic contaminant flux from sediments, thereby reducing contaminant bioavailability and associated risks. While various studies have demonstrated the feasibility of in-situ AC treatment, hesitation to apply this technology exists due to limited experience under field-specific scour conditions and hydrodynamic forces. To address this concern, we conducted a feasibility study for an AC-blended cover at the Lauritzen Channel of the United Heckathorn Superfund Site in Richmond, California, United States, which was contaminated with dichlorodiphenyltrichloroethane and its metabolites (DDx) as well as dieldrin. Vessel activities causing sediment disturbance were identified as key factors for remedy selection. A blended cover with AC and coarse materials was designed to withstand varied hydrodynamic conditions and AC stability was tested in a current flume. The cover comprised medium-size gravel (D<sub>50</sub> = 15 mm, D<sub>90</sub> = 19 mm) with 4 % granular AC by weight. Flume erosion studies showed minimal AC loss (1–2 % of total AC) under shear forces of 9–31 Pa, which was equivalent to or exceeded the estimated worst-case erosional conditions in the channel induced by a hypothetical, stationary tugboat propelling at high power thrust. The treatability performance of the engineered blended cover design was evaluated through mesocosm studies using site sediment and various cover options. Post-treatment assessments on days 5 and 145 showed rapid reductions in freely dissolved (C<sub>free</sub>) DDx and dieldrin in the blended cover layers and surface water. For example, by day 145, C<sub>free</sub> DDx was reduced by over 98 %, meeting US EPA remedial goals for the site. It is concluded that the combination of both stability and performance testing demonstrates that an engineered blended cover-AC design would be a feasible remedial option at the site, and that this testing approach can be applied to evaluate in-situ treatment in other sediment cleanup activities.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"267 ","pages":"Article 104445"},"PeriodicalIF":3.5,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142446447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of humic acid on iron (oxyhydr)oxide transport in the presence of phosphate in saturated porous media 饱和多孔介质中磷酸盐存在时腐植酸对铁(氧氢)氧化物迁移的影响
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-11 DOI: 10.1016/j.jconhyd.2024.104444
Tufail Shah , Kang Zhao , Yingjie Yin , Jianying Shang
The subsurface flow of particular phosphate (P) has been recently regarded as a vital P transport path. Humic acid (HA) and P usually coexist in the natural environment and show a strong affinity to iron (Fe) (oxyhydr)oxide. The impact of P and HA on Fe (oxyhydr)oxide stability and transport is critical for evaluating the vertical transport of particular P and biogeochemical processes of Fe and P. This study investigated the effect of inorganic (IP) and organic (OP) phosphate on the stability and transport of ferrihydrite and goethite with HA through stability tests and column experiments. The adsorption of IP or OP on Fe (oxyhydr)oxide enhanced the stability and transport of Fe (oxyhydr)oxide, and OP showed a stronger enhancement than IP due to its stronger binding capacity and more negative surface. Compared with ferrihydrite, goethite had fewer adsorption sites for IP or OP and showed strong stability and transport at low IP (50 μM) or OP (10 μM) concentration. HA decreased IP or OP adsorption on Fe (oxyhydr)oxide through competition adsorption and electrostatic repulsion. The formed ternary phosphate-Fe (oxyhydr)oxide-HA complex showed a more negative surface and strong stability and transport. Our findings provide direct insights into the distinct role of IP and OP on Fe (oxyhydr)oxide stability and transport in the presence of HA, which provides essential information for evaluating the transport of particular Fe (oxyhydr)oxide-facilitated P in soils and subsurface environments rich in iron, phosphate, and dissolved carbon.
最近,特定磷酸盐(P)的地下流动被视为重要的 P 运输途径。腐殖酸(HA)和磷通常共存于自然环境中,并与氧化铁(Fe)有很强的亲和力。本研究通过稳定性测试和柱实验研究了无机磷酸盐(IP)和有机磷酸盐(OP)对含有 HA 的铁水石和鹅铁矿的稳定性和迁移的影响。IP或OP对氧化铁的吸附增强了氧化铁的稳定性和迁移性,其中OP因其更强的结合能力和更负的表面而比IP表现出更强的增强作用。与无水亚铁相比,网纹石对 IP 或 OP 的吸附位点较少,在低浓度 IP(50 μM)或 OP(10 μM)时表现出较强的稳定性和迁移性。HA 通过竞争吸附和静电排斥作用减少了 IP 或 OP 在氧化铁上的吸附。形成的三元磷酸盐-铁(氧氢)氧化物-HA 复合物显示出更负的表面,具有很强的稳定性和迁移性。我们的研究结果直接揭示了 IP 和 OP 在 HA 存在时对氧化铁稳定性和迁移的不同作用,这为评估特定氧化铁促进的磷在富含铁、磷酸盐和溶解碳的土壤和地下环境中的迁移提供了重要信息。
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引用次数: 0
Time-lapse dielectric properties monitoring of the flow cell during DNAPL contamination and remediation processes by full-waveform inversion of GPR data using particle swarm optimization: A laboratory study 利用粒子群优化技术对 GPR 数据进行全波形反演,在 DNAPL 污染和修复过程中对流动池的介电特性进行延时监测:实验室研究
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-10 DOI: 10.1016/j.jconhyd.2024.104443
İsmail Kaplanvural , Ertan Pekşen , Nihat Hakan Akyol , Doğukan Durdağ
This study presents the monitoring of the contamination and remediation processes of an aquifer system using the ground-penetrating radar (GPR) method. To achieve this, periodic GPR measurements were performed on a flow cell, which was established to simulate aquifer contamination and remediation scenarios. The exterior of the flow cell was made of plexiglas, and a small hole was created at the top center to inject Dense Non-aqueous Phase Liquid (DNAPL) contamination. To study contaminant distribution and remediation processes, DNAPL Trichloroethylene (TCE) was used as the groundwater contaminant. Methyl-beta-cyclodextrin (MCD) was used as remediation agent. The interior of the flow cell was packed with two different sand grain size distributions: low permeability sand along the bottom and a higher permeability sand along the top. Common offset GPR measurements were performed along the top plane of the flow cell. The GPR measurements were conducted periodically over a total duration of 66 days, encompassing the phases prior to injecting DNAPL TCE, after injection of DNAPL TCE, and during the remediation process using MCD. Time-lapse GPR data were analyzed using 1D and 2D plots. In addition, to evaluate and monitor the contamination and remediation processes within the flow cell, central traces of the time-lapse GPR dataset were inverted by full-waveform inversion to estimate the dielectric properties of the layers and the depth by Particle Swarm Optimization (PSO). To utilize PSO, a forward model calculation using 1D finite difference in time domain adapted to PSO algorithm to generate theoretical GPR traces to compare the theoretical model GPR traces to the measured GPR traces as a “goodness of fit” metric. The electrical conductivity, relative dielectric permittivity, relative magnetic permeability, and depth of the layer were estimated by PSO of the GPR data. The results of the inversion process indicated a significant change in the estimated electrical conductivity values for the post TCE DNAPL contamination stage and the remediation stage. In addition, to support the inversion results, contaminant mass removal was quantified using moment analysis from dissolved-phase contaminant concentrations collected from the flow cell over time. According to the mass recovery calculation by moment analysis, which was collected via an outlet from the flow cell, approximately 38 % of the injected DNAPL TCE mass was removed by enhanced dissolution from the representative aquifer domain of the flow cell during the remediation stage of the experiment.
本研究介绍了利用探地雷达(GPR)方法监测含水层系统的污染和修复过程。为此,对一个流动池进行了定期的 GPR 测量,该流动池是为模拟含水层污染和修复情况而建立的。流动池的外部由有机玻璃制成,顶部中心有一个小孔,用于注入致密非水相液体(DNAPL)污染。为了研究污染物的分布和修复过程,使用 DNAPL 三氯乙烯(TCE)作为地下水污染物。甲基-beta-环糊精 (MCD) 用作修复剂。流动池内部填充了两种不同粒度的沙子:底部为低渗透性沙子,顶部为高渗透性沙子。沿流动池顶部平面进行了普通偏移 GPR 测量。GPR 测量在总共 66 天的时间内定期进行,包括注入 DNAPL TCE 之前、注入 DNAPL TCE 之后以及使用 MCD 进行修复过程中的各个阶段。使用一维和二维图对延时 GPR 数据进行了分析。此外,为了评估和监测流动池内的污染和修复过程,还对延时 GPR 数据集的中心轨迹进行了全波形反演,以通过粒子群优化(PSO)估算各层的介电性质和深度。为了利用 PSO,使用适应 PSO 算法的时域一维有限差分进行前向模型计算,生成理论 GPR 曲线,将理论模型 GPR 曲线与测量的 GPR 曲线进行比较,作为 "拟合度 "指标。通过对 GPR 数据进行 PSO,估算了导电率、相对介电常数、相对磁导率和地层深度。反演过程的结果表明,三氯乙烷 DNAPL 污染后阶段和修复阶段的估计电导率值发生了显著变化。此外,为了支持反演结果,还使用矩分析法对从流动池中收集到的溶解相污染物浓度随时间变化的情况进行了量化。根据通过流动池出口收集的矩分析质量回收计算,在实验的修复阶段,注入的 DNAPL TCE 质量约有 38% 通过流动池代表性含水层区域的强化溶解而去除。
{"title":"Time-lapse dielectric properties monitoring of the flow cell during DNAPL contamination and remediation processes by full-waveform inversion of GPR data using particle swarm optimization: A laboratory study","authors":"İsmail Kaplanvural ,&nbsp;Ertan Pekşen ,&nbsp;Nihat Hakan Akyol ,&nbsp;Doğukan Durdağ","doi":"10.1016/j.jconhyd.2024.104443","DOIUrl":"10.1016/j.jconhyd.2024.104443","url":null,"abstract":"<div><div>This study presents the monitoring of the contamination and remediation processes of an aquifer system using the ground-penetrating radar (GPR) method. To achieve this, periodic GPR measurements were performed on a flow cell, which was established to simulate aquifer contamination and remediation scenarios. The exterior of the flow cell was made of plexiglas, and a small hole was created at the top center to inject Dense Non-aqueous Phase Liquid (DNAPL) contamination. To study contaminant distribution and remediation processes, DNAPL Trichloroethylene (TCE) was used as the groundwater contaminant. Methyl-beta-cyclodextrin (MCD) was used as remediation agent. The interior of the flow cell was packed with two different sand grain size distributions: low permeability sand along the bottom and a higher permeability sand along the top. Common offset GPR measurements were performed along the top plane of the flow cell. The GPR measurements were conducted periodically over a total duration of 66 days, encompassing the phases prior to injecting DNAPL TCE, after injection of DNAPL TCE, and during the remediation process using MCD. Time-lapse GPR data were analyzed using 1D and 2D plots. In addition, to evaluate and monitor the contamination and remediation processes within the flow cell, central traces of the time-lapse GPR dataset were inverted by full-waveform inversion to estimate the dielectric properties of the layers and the depth by Particle Swarm Optimization (PSO). To utilize PSO, a forward model calculation using 1D finite difference in time domain adapted to PSO algorithm to generate theoretical GPR traces to compare the theoretical model GPR traces to the measured GPR traces as a “goodness of fit” metric. The electrical conductivity, relative dielectric permittivity, relative magnetic permeability, and depth of the layer were estimated by PSO of the GPR data. The results of the inversion process indicated a significant change in the estimated electrical conductivity values for the post TCE DNAPL contamination stage and the remediation stage. In addition, to support the inversion results, contaminant mass removal was quantified using moment analysis from dissolved-phase contaminant concentrations collected from the flow cell over time. According to the mass recovery calculation by moment analysis, which was collected via an outlet from the flow cell, approximately 38 % of the injected DNAPL TCE mass was removed by enhanced dissolution from the representative aquifer domain of the flow cell during the remediation stage of the experiment.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"267 ","pages":"Article 104443"},"PeriodicalIF":3.5,"publicationDate":"2024-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
How uncertainty in calibration data affects the modeling of non-point source pollutant loads in baseflow 校准数据的不确定性如何影响基流中非点源污染物负荷的建模
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-09 DOI: 10.1016/j.jconhyd.2024.104441
Shuai Chen , Wei Qin , Tong Cui , Jingling Qian , Jiazhong Zheng
Baseflow is a major transport pathway for non-point source (NPS) pollutants. Watershed water quality (WWQ) models calibrated by low-quality data may produce misleading predictions of baseflow NPS pollutant loads, resulting in poor management decisions. We evaluated how models of the baseflow nitrate loads in the Huron River basin, southwest of Lake Erie, were affected by uncertainty in the calibration data. Based on a five-year time series of daily streamflow, nitrate concentration, and specific conductance, two sets of “observed” baseflow nitrate load data that include uncertainty were estimated using various tracer-based and non-tracer-based hydrograph separation methods, in conjunction with assumptions regarding baseflow nitrate concentrations. We calibrated the Soil and Water Assessment Tool plus (SWAT+) model with the two “observed” data sets and used the Generalized Likelihood Uncertainty Estimation (GLUE) approach to quantify parameter and predictive uncertainties. The results showed that baseflow accounted for 26 %–34 % of the mean annual total streamflow (11.8 m3/s) and 8 %–37 % of the mean annual total nitrate load (14.3 kg·ha−1·year−1) in the Huron River basin. The baseflow and nitrate load estimates from the non-tracer-based methods resembled those from the tracer-based method but had greater uncertainty. The posterior parameter distributions, as well as the weighted means and 90 % prediction intervals of the simulated baseflow nitrate loads, exhibited minimal variation when different calibration data sets for SWAT+ and different threshold likelihood values for GLUE were used. Our analysis emphasizes the necessity of calibrating WWQ models with baseflow pollutant loads/concentrations when addressing water quality issues related to baseflow. It also demonstrates the feasibility of utilizing multiple non-tracer-based hydrograph separation methods to estimate baseflow NPS pollutant loads. These non-tracer-based methods offer a simplicity and broader applicability compared to tracer-based methods. This study has provided insights into how calibration data uncertainty impacts the modeling of NPS pollution in baseflow and highlights the practical value of non-tracer-based hydrograph separation methods.
基流是非点源 (NPS) 污染物的主要迁移途径。根据低质量数据校准的流域水质 (WWQ) 模型可能会对基流非点源污染物负荷产生误导性预测,从而导致管理决策失误。我们评估了伊利湖西南部休伦河流域的基流硝酸盐负荷模型如何受到校准数据不确定性的影响。根据日溪流、硝酸盐浓度和比导的五年时间序列,使用各种基于示踪剂和非基于示踪剂的水文图分离方法,结合有关基流硝酸盐浓度的假设,估算了两组包含不确定性的 "观测 "基流硝酸盐负荷数据。我们用两组 "观测 "数据校准了水土评估工具+(SWAT+)模型,并使用广义似然不确定性估计(GLUE)方法量化了参数和预测的不确定性。结果表明,基流占休伦河流域年均总流量(11.8 立方米/秒)的 26%-34%,占年均总硝酸盐负荷(14.3 千克-公顷-1-年-1)的 8%-37%。非示踪剂方法得出的基流和硝酸盐负荷估算值与示踪剂方法得出的估算值相似,但不确定性更大。当 SWAT+ 使用不同的校准数据集和 GLUE 使用不同的阈值似然值时,后验参数分布以及模拟基流硝酸盐负荷的加权平均值和 90% 预测区间的变化极小。我们的分析强调,在解决与基流有关的水质问题时,必须用基流污染物负荷/浓度校准水质模型。它还证明了利用多种非示踪剂水文图分离方法估算基流 NPS 污染物负荷的可行性。与基于示踪剂的方法相比,这些非示踪剂方法简单易用,适用范围更广。这项研究深入探讨了校准数据的不确定性如何影响基流中的核动力源污染建模,并强调了非示踪剂水文图分离法的实用价值。
{"title":"How uncertainty in calibration data affects the modeling of non-point source pollutant loads in baseflow","authors":"Shuai Chen ,&nbsp;Wei Qin ,&nbsp;Tong Cui ,&nbsp;Jingling Qian ,&nbsp;Jiazhong Zheng","doi":"10.1016/j.jconhyd.2024.104441","DOIUrl":"10.1016/j.jconhyd.2024.104441","url":null,"abstract":"<div><div>Baseflow is a major transport pathway for non-point source (NPS) pollutants. Watershed water quality (WWQ) models calibrated by low-quality data may produce misleading predictions of baseflow NPS pollutant loads, resulting in poor management decisions. We evaluated how models of the baseflow nitrate loads in the Huron River basin, southwest of Lake Erie, were affected by uncertainty in the calibration data. Based on a five-year time series of daily streamflow, nitrate concentration, and specific conductance, two sets of “observed” baseflow nitrate load data that include uncertainty were estimated using various tracer-based and non-tracer-based hydrograph separation methods, in conjunction with assumptions regarding baseflow nitrate concentrations. We calibrated the Soil and Water Assessment Tool plus (SWAT+) model with the two “observed” data sets and used the Generalized Likelihood Uncertainty Estimation (GLUE) approach to quantify parameter and predictive uncertainties. The results showed that baseflow accounted for 26 %–34 % of the mean annual total streamflow (11.8 m<sup>3</sup>/s) and 8 %–37 % of the mean annual total nitrate load (14.3 kg·ha<sup>−1</sup>·year<sup>−1</sup>) in the Huron River basin. The baseflow and nitrate load estimates from the non-tracer-based methods resembled those from the tracer-based method but had greater uncertainty. The posterior parameter distributions, as well as the weighted means and 90 % prediction intervals of the simulated baseflow nitrate loads, exhibited minimal variation when different calibration data sets for SWAT+ and different threshold likelihood values for GLUE were used. Our analysis emphasizes the necessity of calibrating WWQ models with baseflow pollutant loads/concentrations when addressing water quality issues related to baseflow. It also demonstrates the feasibility of utilizing multiple non-tracer-based hydrograph separation methods to estimate baseflow NPS pollutant loads. These non-tracer-based methods offer a simplicity and broader applicability compared to tracer-based methods. This study has provided insights into how calibration data uncertainty impacts the modeling of NPS pollution in baseflow and highlights the practical value of non-tracer-based hydrograph separation methods.</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"267 ","pages":"Article 104441"},"PeriodicalIF":3.5,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142437720","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Occurrence and visual characterization of microplastics from Mahakam River at Tenggarong City, Indonesia 印度尼西亚登加龙市马哈卡姆河中微塑料的出现和目测特征
IF 3.5 3区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Pub Date : 2024-10-09 DOI: 10.1016/j.jconhyd.2024.104440
Yudi Sukmono , Tony Hadibarata , Risky Ayu Kristanti , Abhishek Singh , Dunia A. Al Farraj , Mohamed S. Elshikh
Indonesia generates approximately 7.8 million tons of plastic waste annually, which 4.9 million tons is mismanaged. Presently, there is significant concern on microplastics (MPs) pollution in aquatic environment. The research on the prevalence of MPs in river systems are comparatively lower than the studies conducted on marine systems. The primary goal of this research was to look into the prevalence of MPs in the river water of Mahakam of Tenggarong City, Indonesia. To adequately represent this area, a meticulous selection method was used to find five separate sampling locations, with two stations at each location, positioned 200 m apart on opposite sides of the river. According to the study's findings, MPs has been observed in the range of 19.2 ± 1.8 to 58.5 ± 3.5 particles/l. Based on the MPs type, fragments (43.4 %) were the most common type of MPs found in water samples. Furthermore, 44.6 % of the MPs had size smaller than 1000 μm. The prevalent hues observed in the water samples were transparent and black, composing 75.6 % of overall formation. The determination of microplastic polymers employed Attenuated Total Reflection-Fourier Transform Infrared (ATR-FTIR) spectroscopy, revealing the presence of various type, such as polyethylene (PE) and polypropylene (PP).
印度尼西亚每年产生约 780 万吨塑料垃圾,其中 490 万吨管理不善。目前,水生环境中的微塑料(MPs)污染问题备受关注。与海洋系统的研究相比,河流系统中微塑料的研究相对较少。本研究的主要目标是调查印度尼西亚腾加龙市马哈卡姆河水中 MPs 的流行情况。为了充分代表这一地区,研究人员采用了细致的选择方法,在河对岸相距 200 米的地方分别找到五个采样点,每个采样点设两个站点。根据研究结果,观察到的 MPs 在 19.2 ± 1.8 至 58.5 ± 3.5 微粒/升之间。根据 MPs 类型,碎片(43.4%)是水样中最常见的 MPs 类型。此外,44.6%的 MPs 尺寸小于 1000 微米。在水样中观察到的主要色调是透明和黑色,占总色调的 75.6%。微塑料聚合物的测定采用了衰减全反射-傅立叶变换红外光谱法(ATR-FTIR),结果显示存在各种类型的微塑料聚合物,如聚乙烯(PE)和聚丙烯(PP)。
{"title":"Occurrence and visual characterization of microplastics from Mahakam River at Tenggarong City, Indonesia","authors":"Yudi Sukmono ,&nbsp;Tony Hadibarata ,&nbsp;Risky Ayu Kristanti ,&nbsp;Abhishek Singh ,&nbsp;Dunia A. Al Farraj ,&nbsp;Mohamed S. Elshikh","doi":"10.1016/j.jconhyd.2024.104440","DOIUrl":"10.1016/j.jconhyd.2024.104440","url":null,"abstract":"<div><div>Indonesia generates approximately 7.8 million tons of plastic waste annually, which 4.9 million tons is mismanaged. Presently, there is significant concern on microplastics (MPs) pollution in aquatic environment. The research on the prevalence of MPs in river systems are comparatively lower than the studies conducted on marine systems. The primary goal of this research was to look into the prevalence of MPs in the river water of Mahakam of Tenggarong City, Indonesia. To adequately represent this area, a meticulous selection method was used to find five separate sampling locations, with two stations at each location, positioned 200 m apart on opposite sides of the river. According to the study's findings, MPs has been observed in the range of 19.2 ± 1.8 to 58.5 ± 3.5 particles/l. Based on the MPs type, fragments (43.4 %) were the most common type of MPs found in water samples. Furthermore, 44.6 % of the MPs had size smaller than 1000 μm. The prevalent hues observed in the water samples were transparent and black, composing 75.6 % of overall formation. The determination of microplastic polymers employed Attenuated Total Reflection-Fourier Transform Infrared (ATR-FTIR) spectroscopy, revealing the presence of various type, such as polyethylene (PE) and polypropylene (PP).</div></div>","PeriodicalId":15530,"journal":{"name":"Journal of contaminant hydrology","volume":"267 ","pages":"Article 104440"},"PeriodicalIF":3.5,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142417644","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Journal of contaminant hydrology
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