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PARTISIPASI ORANG TUA SMKN 1 NURUSSALAM “STAYHOME” COVID-19 SELAMA BELAJAR DIRUMAH SAJA 家长参与smkn1 NURUSSALAM COVID-19在家里学习
Pub Date : 2020-10-31 DOI: 10.3314/JES.V6I2.1112
M. Nasir
ABSTRAK Partisipasi orang tua memberikan pengaruh terhadap pembelajaran dirumah selama “STAYHOME” covid -19 untuk belajar dirumah. Dampak pandemi Virus Corona (Virus-19) kini mulai sudah merambah ke dunia pendidikan sangat menggangu aktifitas pembelajaran peserta didik. Hasi hasil kajian yang dilakukan terhadap siswa SMKN 1 Nurussalam dapat di berikan simpulan partisipasi orang tua SMKN 1 Nurussalam“Stayhome” covid-19 selama belajar dirumah saja cukup baik yaitu secara kuantitatif persentase diperoleh angka sebesar  72,92%. Sedangkan untuk faktor hambatan orang tua selama wabah covid-19 ini ialah faktor waktu untuk anak yang mau berkonsultasi atau bertanya hanya 6 orang atau 33,3% yang menyatakan tidak sibuk, 7 orang atau 38,9% dari responden menyatakan kadang-kadang sibuk dan 5 orang responden atau 27,8% menjawab sangat sibuk hal ini di karenakan orang tua di berkaitan erat dengan masalah ekonomi serta faktor ketidak tahuan orang tua materi pembelajaran mengetahui hasil belajar anaknya yang memuaskan dari 18 responden hanya 9 orang atau 50,0% yang menyatakan selalu menasehatinya 4 orang atau 22,2% dari responden menyatakan kadang-kadang menesehati terhadap hasil belajar dan 5 orang responden atau 27,8% menjawab tidak pernah. Ketidaktahuan tentang pembelajaran menjadi pemhambat pembelajaran selama covid 19 bagi siswa selam ini. Kata kunci : Partisipasi, Orang Tua, Guru, Covid-19.
在covid -19的“宅在家”学习期间,家长参与影响在家学习。日冕病毒大流行的影响现在已经渗透到教育领域,严重干扰学习者的学习活动。学生smkn1 Nurussalam可以总结家长参与smkn1 Nurussalam covi在家学习时的“Stayhome”covid-19的总结。至于父母在covid-19流行期间的障碍因素,这是一个时间因素,只有6个人或33.3%的孩子说他们不太忙,7人或38,9%的受访者表示有时忙,5人受访者或27,8%回答很忙,这在经济密切相关的问题,因为父母和父母的无知因素的学习结果发现孩子学习材料满足18的受访者中,只有9人或50,0%宣布总是4人或22,2%经验丰富的受访者表示对学习结果和5人有时menesehati受访者或27.8%的人回答从来没有。在19年的学习过程中,对学习的无知变成了学生的学习障碍。关键词:参与,家长,老师,Covid-19。
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引用次数: 0
PROJECT BASED LEARNING PUPUK ORGANIK CAIR DI KELAS XI ATPH SMK NEGERI 1 LOKOP DAPAT MENINGKATKAN HASIL PERTANIAN MASYARAKAT SETEMPAT
Pub Date : 2020-10-31 DOI: 10.3314/JES.V6I2.1114
Ita Masyitha
ABSTRAK Kelangkaan pupuk anorganik di pasaran merupakan salah satu faktor merosotnya hasil pertanian di daerah sekitaran SMK Negeri 1 Lokop. Sehingga penulis yang mengajar di sekolah dengan jurusan Agribisnis Tanaman Pangan dan Hortikultura, mencoba mencari solusi melalui peserta didik dengan menggunakan pembelajaran Project Based Learning. Penulis membuat artikel ini untuk mengetahui dampak pembelajaran Project Based Learning berupa Pupuk Organik Cair (POC) pada peserta didik kelas XI ATPH 1 SMK Negeri 1 Lokop pada khususnya dan masyarakat setempat pada umumnya. Pada pembelajaran tersebut penulis dapat melihat data, bahwa penggunaan pupuk organik cair dapat meningkatkan hasil pertanian petani setempat. Data tersebut menunjukkan kenaikan hasil pertanian pada desa X sebelum menggunakan pupuk organik cair, hasil panen padinya adalah 13-14 kaleng/rante, setelah menggunakan pupuk organik cair maka hasil panen padinya meningkat menjadi 18-20,5 kaleng/rante, jika dipersentase maka akan didapat kenaikan 38%-44%. Selanjutnya hasil dari desa Y sebelum menggunakan pupuk organik cair, hasil panen padinya adalah 10-11 kaleng/rante, setelah menggunakan pupuk organik cair maka hasil panen padinya meningkat menjadi 17-19 kaleng/rante, jika dipersentasekan maka akan didapat kenaikan 70%-80%. Dari data di atas sangat jelas perbedaan yang sangat signifikan antara penggunaan pupuk anorganik dan pupuk organic. Hal ini menunjukkan bahwa para peserta didik mampu menerapkan ilmu yang mereka dapat di sekolah kepada masyarakat setempat, khususnya orang tua mereka. Pembelajaran melalui Project Based Learning sangat berdampak langsung dengan masyarakat setempat. Hal ini terlihat dari data yang didapat penulis. Kata kunci: Pupuk organic cair; project based learning; hasil pertanian .
市场上无机肥料的缺乏是该国SMK 1地区农业产量下降的一个因素。因此,在以作物和园艺为基础的农业专业教师的学校任教的作家,试图通过学习者通过学习者的学习计划来寻求解决方案。在研究中,作者可以看到数据,使用液体有机肥料可以提高当地农民的产量。数据显示,X村的农产品在使用液体有机肥之前增加了13-14罐/rante,在使用液体有机肥后,收获会增加到18- 20.5罐/rante,如果稀释,增长率会上升38%-44%。Y村在使用液体有机肥料之前的产量是10-11罐从上面的数据来看,无机肥料和有机肥料的使用存在显著差异。这表明学习者能够向当地社区,尤其是他们的父母运用他们在学校学到的知识。通过项目基础学习学习对当地社区产生了直接的影响。这可以从作者获得的数据中看出。关键词:液体有机肥;基于学习的项目;农产品。
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引用次数: 0
PENGEMBANGAN LEMBAR KERJA PESERTA DIDIK (LKPD) INDUSTRI KECIL BERORIENTASI KEWIRAUSAHAAN UNTUK SMK NEGERI 1 BIREUEN 小型创业创业公司开发计划书1 BIREUEN
Pub Date : 2020-10-31 DOI: 10.3314/JES.V6I2.1047
Safrianas Safrianas
ABSTRAK Penelitian ini bertujuan untuk menghasilkan lembar kerja peserta didik (LKPD) Industri kecil berorientasi kewirausahaan, dan mengetahui kelayakan LKPD untuk pembelajaran. Penelitian ini merupakan penelitian pengembangan yang mengacu pada model pengembangan Borg & Gall. Prosedur dalam penelitian pengembangan ini terdiri dari empat tahap, yaitu tahap pendahuluan. perencanaan, pengembangan, dan evaluasi produk. Evaluasi produk dilakukan oleh teman sejawat, ahli materi dan media, serta guru kimia untuk mendapatkan masukan dan penilaian mengenai kualitas LKPD. Instrumen pengumpulan data yang digunakan berupa lembar validasi produk. Hasil penelitian menunjukkan bahwa LKPD Industri kecil berorientasi kewirausahaan dengan kategori sangat baik, sehingga LKPD yang dikembangkan layak digunakan dalam pembelajaran.
本研究旨在创建一个面向创业的小行业的学习者工作表,并了解学习的可行性。本研究是一种参考博格和加尔发展模式的开发开发研究。开发研究的程序包括四个阶段,也就是初步阶段。计划、开发和产品评估。产品评估是由同事、媒体专家和化学教师进行的,以获得对产品质量的输入和评估。用于产品验证表的数据收集工具。研究结果表明,这是一个非常具有创业精神的小行业,因此开发的这些项目值得学习。
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引用次数: 0
MENINGKATKAN KOMPETENSI PESERTA DIDIK MELALUI MODEL PEMBELAJARAN TEACHING FACTORY DALAM MATA PELAJARAN PRODUKTIF SMK DI ACEH TIMUR
Pub Date : 2020-10-31 DOI: 10.3314/JES.V6I2.1050
A. Akmaluddin
ABSTRAK Penelitian ini bertujuan untuk.mengidentifikasi dan mengembangkan model teaching factory  manajemen pada smk melalui serangkaian test dan validasi terhadap model dengan pendekatan riset dan pengembangan. Model manajemen teaching factory pada smk merupakan sebuah konsep yg menggabungkan pendekatan manajemen pembelajaran competency based training (pelatihan berabasis kopetensi) dan production based training (pelatihan berbasis produksi) pada lingkungan yg sebenarnya sehingga proses pencapaian kopetensi atau kecakapan hidup sesuai dg standar pekerjaan lulusan (siswa yg lulus) pada dunia industri. Secara khusus, penelitian ini bertujuan untuk merumuskan rancangan model manajemen pengembangan teaching factory smk. Untuk mencapai tujuan diatas yg menggunakan riset dan pengembangan, melalui riset  tahap awal, rancangan pengembangan model, percobaan dan validasi. Tahap penelitian awal di rencanakan seperti tahap berikut: kajian kepustakaan/ pengumpulan data lapangan dan deskripsi serta analisis penemuan data (factual), yaitu: 1).penjelasan karakteristik smk dengan standar indikator performa yg dapat dijabarkan sebagai isi dari pengembangan teaching factory, 2) Penjelasan karakteristik potensi pengembangan kelompok manajemen model teaching factory sebagai sebuah hasil pencapaian kelompok untuk mengembangkan dan menerapkan model manajemen tefa untuk smk 3) Mendsekripsikan karakteristik stakeholders yg potensial untuk mendukung pengembangan dan penerapan model manajemen tefa, dan 4) persiapan dari model manajemen tefa untuk smk unggul dan inofatif. Rancangan ujicoba dilakukan pada kelompok skala terbatas. Kemudian model tersebut di sandingkan dengan kelompok hasil pencapaian untuk mengembangkan dan menerapkan model tefa pada smk untuk menentukan apakah model yg dikembangkan dapat di terapkan secara tepat. Analisis data pada kajian ini, tahap awal kajian, dan data temuan atau fakta tentang program productive learning yg diterapkan dijelaskan dalam bentuk presentasi data, dan kemudian dianalisis (interpretasikan) secara kualitatif. Proses dan hasil pengembangan rancangan dilakukan dalam analisis kelompok sebaya dan penilaian oleh tim ahli.dan hasil percobaan dipresentasikan juga dalam bentuk data sama seperti rancangan (keterpakaian) dianalisa secara kualitatif. Model manajemen teaching factory yg dikembangkan akan dapat di terapkan pada manajemen teaching factory smk dan memberikan panduan untuk pengelola teaching factory ( kepala sekolah, guru, mitra industri) dan dapat menghasilkan kontribusi yg konstruktif dalam kemitraan antara smk dengan industri. Kata kunci: Teaching Factory (TEFA), Competency Based Training (CBT) dan Production Based Training (PBT)
本研究的目的是抽象的。通过研究和开发方法对这些模型进行一系列测试和验证,确定并开发smk上的教学工厂管理模式。smk的教学工厂管理模式是一个概念,它将现有的环境竞争基础学习管理方法和生产基础培训方法结合起来,使重复或能力的进程符合工业界毕业生的标准。具体来说,本研究旨在制定教学工厂smk开发管理模式的设计方案。通过早期研究、模型开发设计、实验和验证来实现上述目标。初步研究阶段如下:实地数据收集研究及描述及数据发现分析(事实):1)。smk特征的解释标准的性能指标可以作为教书工厂发展的内容,2)描述特征解释模型管理小组开发的潜力教书厂作为一个开发小组的成就和结果应用tefa管理模型来smk 3) Mendsekripsikan stakeholders特征支持开发和应用的潜在tefa管理模型,4)为smk的卓越和创新管理模式做好准备。试验计划在小组规模有限的情况下进行。然后将该模型与成就小组联系起来,以开发和应用tefa模型到smk,以确定开发的模型是否可以得到适当的应用。对本研究的数据分析,在本研究的早期阶段,以及应用的生产学习计划的发现或事实数据分析以数据展示的形式被解释,然后以定性的方式分析。设计过程和结果是在专家团队的同行分析和评估中进行的。实验结果也以设计形式呈现,设计形式分析性质。开发的茶正工厂管理模式将能够应用到茶正厂的smk管理中,并为茶正厂的经理(校长、教师、工业伙伴)提供指导,并能够在smk与行业之间的合作关系中产生建设性贡献。关键词:Teaching Factory (TEFA)、基础培训(CBT)和基础培训生产(PBT)
{"title":"MENINGKATKAN KOMPETENSI PESERTA DIDIK MELALUI MODEL PEMBELAJARAN TEACHING FACTORY DALAM MATA PELAJARAN PRODUKTIF SMK DI ACEH TIMUR","authors":"A. Akmaluddin","doi":"10.3314/JES.V6I2.1050","DOIUrl":"https://doi.org/10.3314/JES.V6I2.1050","url":null,"abstract":"ABSTRAK Penelitian ini bertujuan untuk.mengidentifikasi dan mengembangkan model teaching factory  manajemen pada smk melalui serangkaian test dan validasi terhadap model dengan pendekatan riset dan pengembangan. Model manajemen teaching factory pada smk merupakan sebuah konsep yg menggabungkan pendekatan manajemen pembelajaran competency based training (pelatihan berabasis kopetensi) dan production based training (pelatihan berbasis produksi) pada lingkungan yg sebenarnya sehingga proses pencapaian kopetensi atau kecakapan hidup sesuai dg standar pekerjaan lulusan (siswa yg lulus) pada dunia industri. Secara khusus, penelitian ini bertujuan untuk merumuskan rancangan model manajemen pengembangan teaching factory smk. Untuk mencapai tujuan diatas yg menggunakan riset dan pengembangan, melalui riset  tahap awal, rancangan pengembangan model, percobaan dan validasi. Tahap penelitian awal di rencanakan seperti tahap berikut: kajian kepustakaan/ pengumpulan data lapangan dan deskripsi serta analisis penemuan data (factual), yaitu: 1).penjelasan karakteristik smk dengan standar indikator performa yg dapat dijabarkan sebagai isi dari pengembangan teaching factory, 2) Penjelasan karakteristik potensi pengembangan kelompok manajemen model teaching factory sebagai sebuah hasil pencapaian kelompok untuk mengembangkan dan menerapkan model manajemen tefa untuk smk 3) Mendsekripsikan karakteristik stakeholders yg potensial untuk mendukung pengembangan dan penerapan model manajemen tefa, dan 4) persiapan dari model manajemen tefa untuk smk unggul dan inofatif. Rancangan ujicoba dilakukan pada kelompok skala terbatas. Kemudian model tersebut di sandingkan dengan kelompok hasil pencapaian untuk mengembangkan dan menerapkan model tefa pada smk untuk menentukan apakah model yg dikembangkan dapat di terapkan secara tepat. Analisis data pada kajian ini, tahap awal kajian, dan data temuan atau fakta tentang program productive learning yg diterapkan dijelaskan dalam bentuk presentasi data, dan kemudian dianalisis (interpretasikan) secara kualitatif. Proses dan hasil pengembangan rancangan dilakukan dalam analisis kelompok sebaya dan penilaian oleh tim ahli.dan hasil percobaan dipresentasikan juga dalam bentuk data sama seperti rancangan (keterpakaian) dianalisa secara kualitatif. Model manajemen teaching factory yg dikembangkan akan dapat di terapkan pada manajemen teaching factory smk dan memberikan panduan untuk pengelola teaching factory ( kepala sekolah, guru, mitra industri) dan dapat menghasilkan kontribusi yg konstruktif dalam kemitraan antara smk dengan industri. Kata kunci: Teaching Factory (TEFA), Competency Based Training (CBT) dan Production Based Training (PBT)","PeriodicalId":15610,"journal":{"name":"Journal of Education Science","volume":"4 1","pages":"46-54"},"PeriodicalIF":0.0,"publicationDate":"2020-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86631019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MENINGKATKAN KETERAMPILAN GENERIK SAINS DAN KEJUJURAN SISWA MELALUI MODEL KOOPERATIF BERBASIS BUDAYA ACEH 通过以亚齐文化为基础的合作模式提高学生的一般科学技能和诚实
Pub Date : 2020-10-31 DOI: 10.3314/JES.V6I2.1049
Fitri Handayani, Z. Zulfahmi, Nelliraharti Nelliraharti
Abstract The purpose of this study is (1) to improve generic science skills through an Aceh-based cooperative culture model on physics material. (2) Increase the honesty of students in the learning process through a cooperative culture based in Aceh. (3) To improve students' understanding of culture. The sample of this study was taken 1 (one) class. The research sample was applied to students of class XI IPA 1 Kutacane 1, Bambel sub-district, Aceh Tenggara district, which consisted of 37 students. Classes will be applied to learning through Acehnese culture-based cooperative learning models. Data collection techniques through generic science skill observation sheets are expressed in the number of mean values, and N-Gain values. Data processing to measure student honesty is to calculate the percentage of each indicator of student honesty questionnaire. Student response data were obtained using the student response questionnaire. The results of the study enhance students' generic science skills through a cooperative model based on Aceh culture physical material with a normal gain of 0.72 in the high category. Honesty students are obtained using an honest questionnaire, the openness of teachers and students in the learning process can improve students' sense of honesty. The positive response of students reaches 90.8%.
摘要本研究的目的是:(1)通过基于亚齐省的物理材料合作培养模式来提高学生的通用科学技能。(2)通过亚齐的合作文化,提高学生在学习过程中的诚实度。(3)提高学生对文化的理解。本研究的样本为1(1)班。课程将通过基于亚齐文化的合作学习模式应用于学习。通过通用科学技能观察表的数据收集技术以平均值的数量和n -增益值表示。测量学生诚信的数据处理是计算学生诚信问卷各指标的百分比。学生反应数据采用学生反应问卷获得。研究结果表明,基于亚齐文化物理材料的合作模式提高了学生的一般科学技能,高类别的正常增益为0.72。诚实学生是通过诚实问卷获得的,师生在学习过程中的开放性可以提高学生的诚实意识。学生的积极反应达到90.8%。
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引用次数: 0
AEPRD: An Enhanced Algorithm for Predicting Results of Orthodontic Operations AEPRD:一种预测正畸手术结果的改进算法
Pub Date : 2020-10-10 DOI: 10.33899/EDUSJ.2020.127785.1094
Al Abd Alazeez, A. Thaher
The face is the most critical component which is clear on first sight for an individual. Soft tissue of the face alongside the fundamental dentoskeletal tissues portrays the facial attributes of a person. Social affirmation, mental well-being, and self-esteem of an individual are related to physical appearance. The impression of a charming face is generally passionate with ethnicity, age, sexual orientation, culture, and character influencing ordinary facial attributes. Strikingly, facial properties are regularly packed in profile. Orthodontic assurance and treatment orchestrating are continuously being established on profiles rather than basically on Angle's concept of molar relationship. It was seen that particular skeletal exact guidelines, proportion of constitution of the soft tissue, and facial solid position can affect the assessment of the profile. One of the uncommon challenges in orthodontics is the treatment orchestrating and the leading body of orthognathic careful cases. These cases require a mix of both orthodontics and orthognathic medical procedure to accomplish an even impediment, appropriate function, and agreeable facial feel. It is obvious in the literature that there are three main types of malocclusions: Class I which includes people who have a normal bite, Class II which includes people who have an overbite, and Class III which includes people who have an underbite. Early analysis of malocclusion is exceptionally helpful to get legitimate straight teeth. Thus, in this paper we built up a straightforward PC supported system using image processing techniques that could help foreseeing teeth impediment. In other words, we take an image of an individual and order it into one of the three primary types: Class I, Class II, and Class III and predict the post-treatments of Class II and Class III. This study gives information which can be used in treatment orchestrating by authorities, for instance, orthodontists, prosthodontists, plastic specialists, and maxillofacial experts, who have the ability to change the soft tissue facial characteristics.
脸是最重要的组成部分,对一个人来说,第一眼就能看清楚。面部软组织与基本的牙骨组织一起描绘了一个人的面部特征。一个人的社会肯定、心理健康和自尊都与外表有关。一张迷人的脸给人的印象通常会受到种族、年龄、性取向、文化和性格等因素的影响。引人注目的是,面部特征通常集中在侧面。正畸保证和治疗协调不断建立在侧面,而不是基本的角度的磨牙关系的概念。可见,特定的骨骼精确指导、软组织构成比例和面部立体位置会影响轮廓的评估。一个不常见的挑战,在正畸治疗编排和领导机构的正畸细心的情况下。这些病例需要混合正畸和正颌医疗程序来实现均匀的障碍,适当的功能和宜人的面部感觉。在文献中很明显,有三种主要类型的错咬合:第一类包括正常咬合的人,第二类包括覆盖咬合的人,第三类包括下咬合的人。对错牙合的早期分析对矫正牙齿非常有帮助。因此,在本文中,我们建立了一个简单的PC支持的系统,使用图像处理技术,可以帮助预测牙齿障碍。换句话说,我们取一个个体的图像,并将其分为三类:第一类、第二类和第三类,并预测第二类和第三类的后处理。本研究提供的信息可用于当局的治疗协调,例如,正畸医生、修复医生、整形专家和颌面专家,他们有能力改变软组织面部特征。
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引用次数: 2
Isolation and Diagnosis of Rhizobium Bacteria Isolated from The Root Nodules of Leguminous Plants and Studying Their Plasmid Content. 豆科植物根瘤根瘤菌的分离诊断及其质粒含量研究。
Pub Date : 2020-10-04 DOI: 10.33899/EDUSJ.2020.127846.1098
Wissam Jihad Alubidy, Mohammed Al-shakarchi
The study included thirty-six isolates of rhizobia bacteria were isolated from the nodules located on the roots of nine types of leguminous family plants that were planted in four areas of the city of Mosul for the winter agricultural season for the year 2020-2019, where they studied the phenotypic and agricultural characteristics of the isolated bacteria in addition to a study of resistance and sensitivity to the isolates of rhizobia bacteria. The study included ten antibiotics, and resistance ratios differed between isolates groups, where the highest resistance rate for residual bacteria isolates was 100% for Nystatin and Amoxicillin, and the lowest resistance was for Tetracycline and Streptomycin, as it reached 22.2%. As for the rest of the antibiotics, there is a difference between that . As for heavy metal salts, all the isolates of rhizobia bacteria under study were resistant to both CdCl2 chloride and CoCl2 cobalt by 100%, while their resistance to nickel chloride NiCl2 was 77.7% and the lowest resistance to heavy metal was mercury chloride HgCl2, reaching 33.3%. The plasmid DNA content was described for the studied isolates, as the results showed that there are two types of plasmid DNA bundles, the first type close to large-scale gel drilling called Mega plasmid represents symbiotic plasmids that carry the genes of contract formation and nitrogen fixation and the second type moves far from the gel drilling and they are sizes small equal representing non-symbiotic plasmids.
该研究包括从2020-2019年冬季农业季节种植在摩苏尔市四个地区的九种豆科植物根部的根瘤中分离出的36株根瘤菌,除了研究对根瘤菌分离物的抗性和敏感性外,他们还研究了分离细菌的表型和农业特征。本研究共纳入10种抗生素,不同菌株组间的耐药率不同,残留菌分离株对制霉菌素和阿莫西林的耐药率最高,为100%,对四环素和链霉素的耐药率最低,为22.2%。至于其他抗生素,它们之间是有区别的。在重金属盐方面,所研究的根瘤菌菌株对CdCl2氯化物和CoCl2钴的抗性均为100%,对氯化镍NiCl2的抗性为77.7%,对氯化汞HgCl2的抗性最低,为33.3%。对所研究分离物的质粒DNA含量进行了描述,结果表明,质粒DNA束有两种类型,第一种类型的质粒DNA束靠近大规模凝胶钻孔,称为Mega质粒,代表共生质粒,携带收缩形成和固氮基因;第二种类型的质粒远离凝胶钻孔,大小不等,代表非共生质粒。
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引用次数: 2
Synthesis of New 3-Substituted Quinazolin-4(3H)-one Compounds Via Linking of Some Five-Membered Ring Heterocyclic Moieties With Quinazolin-4(3H)-one Nucleus 喹唑啉-4(3H)- 1核与一些五元环杂环基团连接合成新的3-取代喹唑啉-4(3H)- 1化合物
Pub Date : 2020-10-04 DOI: 10.33899/EDUSJ.2020.127904.1101
Rand Arshad Saad-Aldeen, M. Al-iraqi
In this research new compounds containing quinazolin-4(3H)-one nucleus linked to heterocyclic moieties were synthesized using ethyl (4'-oxoquinazolin-3'-yl) acetate (2) as a synthon. This compound was synthesized via 4-quinazolinone's (1) reaction with ethyl chloroacetate in the existence of K2CO3 as a base and acetone as a solvent. The ethyl α-(4'-oxoquinazolin-3'-yl) acetate (2) was converted to the corresponding hydrazide through its reaction with hydrazine hydrate (85 %). Compound (3) was reacted with two of acyl chlorides to synthesize the diacyl hydrazine compounds (4,5). The compound (5) was cyclized to the corresponding 1,3,4-oxadiazole (6) in presence of phosphorous oxychloride. The formyl derivative (7) of the hydrazide (3) was synthesized via its reaction with formic acid and consequently cyclized by phosphorous oxychloride to the corresponding 1,3,4-oxadiazole (8). The hydrazide (3) was also converted to the thiosemicarbazide derivative (9) by its reaction with ammonium thiocyanate under acidic conditions. Whereas other substituted thiosemicarbazide derivatives (10-12) were synthesized by the reaction of hydrazide (3) with organic isothiocyanate compounds. The resultant compounds (11, 12) were cyclized under basic conditions (4% sodium hydroxide solution) to give 1,3,4-triazole-2-thiole derivatives (13,14), whereas the cyclization of compounds (10-12) was performed under the acidic medium (conc. H2SO4) to give 2substituted amino-1,3,4-thiadiazoles (15-17). On the other side, the hydrazide's (3) reaction with isocyanate compounds affords the semicarbazide compounds (18,19). These compounds were cyclized under the basic condition to afford 1,3,4-triazol-2-ol compounds (20,21). The structures of the synthesized compounds were corroborated depending on the physical and spectral data. keywords: quinazolinone; oxadiazole; thiadiazole; triazole; carbohydrazide. تابكرم ريضحت 3 نيلوزانيوك ضوعم -(3H)4طبر ربع ةديدج نوا ريغ ةقلحلا ةيسامخ عيماجملا ضعب نيلوزانيوكلا ةاون عم ةسناجتملا -(3H)4نوا 1 * و يقا رعلا دمحا دمحم 2 نيدلادعس دشرا دنر 1 * قا رعلا ,لصوملا ,لصوملا ةعماج ,مولعلا ةيلك ,ءايميكلا مسق 2 ا رعلا ,لصوملا ,لصوملا ةعماج ,تانبلل ةيبرتلا ةيلك ,ءايميكلا مسق ق Journal of Education and Science (ISSN 1812-125X), Vol: 30, No: 1, 2021 (158-172) Downloaded from https://edusj.mosuljournals.com/ 159 ةصلاخلا ي ت نيلوزانيوكلا ةاون ىلع يوتحت ةديدج تابكرم ريضحت ثحبلا نمض -(3H)4مادختساب ةسناجتم ريغ ةيقلح عيماجمب ةطبترم نوأ α ( -'4 نيلوزانيوكوسكوا -3'ةيلوا ةًدام ليثلأا تلاخ)لي ًً (2) نيلوزانيوكلا لعافت ربع بكرملا اذه رضح . -(3H)4نوأ (1) عم ةًدعاق مويساتوبلا تانوبراك دوجوب ليثلأا تلاخ ورولك و .اًبيذم نوتيسلاا ـلا بكرم لِّ وحُ α ( -'4 نيلوزانيوكوسكوا -3'ليثلأا تلاخ)لي لباقملا ديزا رديهلا ىلا (3) يئاملا نيزا رديهلا عم هلعافت للاخ نم (85%) . ديزا رديهلا مدختسا (3) ةديدج ةعومجم ريضحتل ةيلوا ةًدام نم ةاون ةنمضتملا تابكرملا نيلوزانيوكلا -(3H)4نوأ ديزا رديهلا ل ِّ خداُ .ةسناجتم ريغ ةيقلح عيماجمب ةطبترملا (3) يبكرم عم لًاعافت نيزا رديه ليسأ يئانثلا يبكرم ريضحتل ليسلأ
此外,它们被认为是许多天然生物碱的基本组成部分[19,20]。另一方面,除了喹唑啉-4(3H)-外,还有许多杂环核如1,3,4-恶二唑、1,3,4-噻二唑和1,3,4-三唑具有重要的生物学意义[21-23]。由于喹唑啉-4(3H)- 1衍生物的生物学重要性日益提高,以α-(4′-氧喹唑啉-3-基)乙酸乙酯为合成体,通过一系列中间体将喹唑啉-4(3H)- 1核与3位杂环连接,合成了新的喹唑啉-4(3H)- 1化合物。
{"title":"Synthesis of New 3-Substituted Quinazolin-4(3H)-one Compounds Via Linking of Some Five-Membered Ring Heterocyclic Moieties With Quinazolin-4(3H)-one Nucleus","authors":"Rand Arshad Saad-Aldeen, M. Al-iraqi","doi":"10.33899/EDUSJ.2020.127904.1101","DOIUrl":"https://doi.org/10.33899/EDUSJ.2020.127904.1101","url":null,"abstract":"In this research new compounds containing quinazolin-4(3H)-one nucleus linked to heterocyclic moieties were synthesized using ethyl (4'-oxoquinazolin-3'-yl) acetate (2) as a synthon. This compound was synthesized via 4-quinazolinone's (1) reaction with ethyl chloroacetate in the existence of K2CO3 as a base and acetone as a solvent. The ethyl α-(4'-oxoquinazolin-3'-yl) acetate (2) was converted to the corresponding hydrazide through its reaction with hydrazine hydrate (85 %). Compound (3) was reacted with two of acyl chlorides to synthesize the diacyl hydrazine compounds (4,5). The compound (5) was cyclized to the corresponding 1,3,4-oxadiazole (6) in presence of phosphorous oxychloride. The formyl derivative (7) of the hydrazide (3) was synthesized via its reaction with formic acid and consequently cyclized by phosphorous oxychloride to the corresponding 1,3,4-oxadiazole (8). The hydrazide (3) was also converted to the thiosemicarbazide derivative (9) by its reaction with ammonium thiocyanate under acidic conditions. Whereas other substituted thiosemicarbazide derivatives (10-12) were synthesized by the reaction of hydrazide (3) with organic isothiocyanate compounds. The resultant compounds (11, 12) were cyclized under basic conditions (4% sodium hydroxide solution) to give 1,3,4-triazole-2-thiole derivatives (13,14), whereas the cyclization of compounds (10-12) was performed under the acidic medium (conc. H2SO4) to give 2substituted amino-1,3,4-thiadiazoles (15-17). On the other side, the hydrazide's (3) reaction with isocyanate compounds affords the semicarbazide compounds (18,19). These compounds were cyclized under the basic condition to afford 1,3,4-triazol-2-ol compounds (20,21). The structures of the synthesized compounds were corroborated depending on the physical and spectral data. keywords: quinazolinone; oxadiazole; thiadiazole; triazole; carbohydrazide. تابكرم ريضحت 3 نيلوزانيوك ضوعم -(3H)4طبر ربع ةديدج نوا ريغ ةقلحلا ةيسامخ عيماجملا ضعب نيلوزانيوكلا ةاون عم ةسناجتملا -(3H)4نوا 1 * و يقا رعلا دمحا دمحم 2 نيدلادعس دشرا دنر 1 * قا رعلا ,لصوملا ,لصوملا ةعماج ,مولعلا ةيلك ,ءايميكلا مسق 2 ا رعلا ,لصوملا ,لصوملا ةعماج ,تانبلل ةيبرتلا ةيلك ,ءايميكلا مسق ق Journal of Education and Science (ISSN 1812-125X), Vol: 30, No: 1, 2021 (158-172) Downloaded from https://edusj.mosuljournals.com/ 159 ةصلاخلا ي ت نيلوزانيوكلا ةاون ىلع يوتحت ةديدج تابكرم ريضحت ثحبلا نمض -(3H)4مادختساب ةسناجتم ريغ ةيقلح عيماجمب ةطبترم نوأ α ( -'4 نيلوزانيوكوسكوا -3'ةيلوا ةًدام ليثلأا تلاخ)لي ًً (2) نيلوزانيوكلا لعافت ربع بكرملا اذه رضح . -(3H)4نوأ (1) عم ةًدعاق مويساتوبلا تانوبراك دوجوب ليثلأا تلاخ ورولك و .اًبيذم نوتيسلاا ـلا بكرم لِّ وحُ α ( -'4 نيلوزانيوكوسكوا -3'ليثلأا تلاخ)لي لباقملا ديزا رديهلا ىلا (3) يئاملا نيزا رديهلا عم هلعافت للاخ نم (85%) . ديزا رديهلا مدختسا (3) ةديدج ةعومجم ريضحتل ةيلوا ةًدام نم ةاون ةنمضتملا تابكرملا نيلوزانيوكلا -(3H)4نوأ ديزا رديهلا ل ِّ خداُ .ةسناجتم ريغ ةيقلح عيماجمب ةطبترملا (3) يبكرم عم لًاعافت نيزا رديه ليسأ يئانثلا يبكرم ريضحتل ليسلأ","PeriodicalId":15610,"journal":{"name":"Journal of Education Science","volume":"63 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80496081","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
preparation of palladium Catalyst from bauxite ore and using for kerosene treatment 铝土矿制备钯催化剂及其在煤油处理中的应用
Pub Date : 2020-09-21 DOI: 10.33899/EDUSJ.2020.127951.1103
W. Saeed, Qaidar Salim
The research was aimed to used bauxite ore that has a high aluminum minerals which available in AlHussainiyat near al-Anbar district as a source of alumina which it used as a catalyst support after being loaded with palladium metal , The components of both bauxite ore and prepared catalyst were studied by X-ray diffraction and fluorescence as well as thermogravimetric analysis (TGA) of the prepared catalyst , After this the catalyst was used in the treatment of kerosene which is distilled at (150-260C) under different conditions of the (temperature , reaction time and the ratio of catalyst) to know the optimal reaction conditions that determid by measuring the (FTIR) and chemical analysis. The optimal conditions: temperature was (250C), reaction time was (2hours) and the catalyst ratio was (2%) .The catalyst appeard the ability to dehydrogenation reaction and reforming to form olefinic and aromatic compounds. The research also included the study of n-paraffins separated from kerosene samples that were treating in different temperatures (150,200,250C ) using (HNMR).The results showed the ability of the catalyst towards catalytic cracking and converting n-paraffins to iso-paraffins .
本研究的目的是利用al-Anbar地区附近AlHussainiyat的高铝矿物铝土矿作为氧化铝的来源,并在负载钯金属后用作催化剂载体。用x射线衍射和荧光以及热重分析(TGA)研究了铝土矿和制备的催化剂的成分。然后将催化剂用于处理(150 ~ 260℃)蒸馏煤油,在不同的(温度、反应时间和催化剂配比)条件下,通过红外光谱(FTIR)测量和化学分析确定最佳反应条件。最佳反应条件为温度(250℃)、反应时间(2h)、催化剂配比(2%),催化剂表现出脱氢反应和重整生成烯烃和芳香族化合物的能力。该研究还包括从煤油样品中分离出的正石蜡的研究,这些煤油样品在不同的温度(150、200、250℃)下使用核磁共振(HNMR)进行处理。结果表明,该催化剂具有催化裂解和正石蜡制异石蜡的能力。
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引用次数: 0
Adopting Text Similarity Methods and Cloud Computing to Build a College Chatbot Model 采用文本相似度方法和云计算构建高校聊天机器人模型
Pub Date : 2020-09-08 DOI: 10.33899/EDUSJ.2020.127244.1079
Zaid Mundher, Wissam Khalf Khater, Laith Mohammed Ganeem
A chatbot is a computer program which is designed to interact with users and answer questions. Nowadays, chatbots are one of the most common systems that are used in many fields and by different companies to achieve different tasks. Cloud computing is gaining increasing interest. A myriad of fields and applications have been developed based on cloud computing. In this paper, a college chatbot was developed and implemented to assist students to interact with their college and ask questions related to faculty, activities, exams, admission, amongst other tasks. Text similarity algorithms were adopted to achieve the proposed system. More specifically, cosine similarity and jaccard similarity algorithms were used to find the closest question in the dataset. Firebase real-time database, which is one of the Google cloud services, was used as a connector channel between users and the chatbot server. Experiments were conducted to evaluate the performance of cosine similarity and jaccard similarity methods, and to compare the results of both. In addition, real-time database was also evaluated as a chatbot connecter channel.
聊天机器人是一种设计用来与用户互动并回答问题的计算机程序。如今,聊天机器人是最常见的系统之一,被用于许多领域和不同的公司来完成不同的任务。云计算正获得越来越多的兴趣。无数的领域和应用都是基于云计算开发的。在本文中,开发并实现了一个大学聊天机器人,以帮助学生与他们的学院互动,并提出与教师,活动,考试,入学等任务相关的问题。采用文本相似度算法实现了该系统。更具体地说,余弦相似度和jaccard相似度算法用于在数据集中找到最接近的问题。Firebase实时数据库是Google云服务之一,被用作用户和聊天机器人服务器之间的连接通道。通过实验对余弦相似度法和雅克相似度法的性能进行了评价,并对两者的结果进行了比较。此外,还对实时数据库作为聊天机器人的连接通道进行了评价。
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引用次数: 0
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Journal of Education Science
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