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PREPARATION AND CHARACTERIZATION OF MESOPOROUS CERIUM OXIDE FOR TOXIC AS(V) REMOVAL: PERFORMANCE AND MECHANISTIC STUDIE 介孔氧化铈的制备及性能研究
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-06-14 DOI: 10.3846/jeelm.2022.16749
U. Sahu, Sandip Mandal, S. Sahu, Narayan Gouda, R. Patel
In the present work, the adsorption of carcinogenic pentavalent arsenic (As(V)) from an aqueous solution was studied using mesoporous cerium oxide (MCO). The MCO was synthesized in the precipitation process and confirmed by FT-IR, SEM-EDX, XRD, and BET instrumental techniques. Batch adsorption showed that 95% of As(V) was removed in the optimum conditions of 0.60 g/L adsorbent dose, 10 mg/L initial concentration, time 30 min, and pH 3. Pseudo-secondorder kinetics and the Langmuir isotherm model were fitted to the experimental data. The MCO had a high surface area of 191.97 m2/g and a maximum adsorption capacity of 58.25 mg/g at pH 3. MCO could be able to remove 88% and 82% in the first and second cycles after being desorbed with 0.1 M NaOH solution. The Zeta potential and FTIR studies suggested that electrostatic attraction and ligand exchange mechanisms were responsible for As(V) adsorption.
在本工作中,使用介孔氧化铈(MCO)研究了致癌五价砷(As(V))从水溶液中的吸附。在沉淀过程中合成了MCO,并通过FT-IR、SEM-EDX、XRD和BET仪器技术进行了证实。分批吸附实验表明,在吸附剂用量为0.60g/L、初始浓度为10mg/L、时间为30min、pH为3的最佳条件下,As(V)的去除率为95%。拟二阶动力学和Langmuir等温线模型与实验数据进行了拟合。MCO在pH 3下具有191.97m2/g的高表面积和58.25mg/g的最大吸附容量。MCO在用0.1M NaOH溶液解吸后,在第一次和第二次循环中可以去除88%和82%。Zeta电位和FTIR研究表明,静电吸引和配体交换机制是As(V)吸附的原因。
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引用次数: 1
GREEN SYNTHESIS OF IRON-OXIDE NANOPARTICLES USING SCRAP IRON AS PRECURSOR FOR THE REMOVAL OF PB (II) FROM AQUEOUS MEDIUM 以废铁为前驱体绿色合成氧化铁纳米颗粒去除水介质中的铅(ii)
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-06-14 DOI: 10.3846/jeelm.2022.16747
Mohd Taqui, Snehamayee Das, T. Kamilya, Sandip Mondal, Surabhi Chaudhuri
In the present study, low-cost, environmentally friendly, single-step, high productive novel Iron-oxide nanoparticles (NPs) were prepared from scrap iron using a green synthesis method to remove Pb (II) from aqueous solution. The characterization of synthesized nanoparticles was conducted by UV-vis spectroscopy. The crystalline structure and the phase change were clarified by XRD. FE-SEM was done to know the morphology of iron oxide nanoparticles, and the average surface area of 46.856 m2/g was found by the BET surface area analyzer. The XRD plot shows that the obtained magnetite Fe3O4 combines FeO and Fe2O3 as the synthesis was conducted in the open atmosphere. The SEM images confirm the formation of iron oxide nanoparticles with a size of 31 nm. The removal efficiency of the adsorbent was carried out by optimizing the different operational parameters like pH, time, adsorbent dosage, initial concentration of metal ion, contact time by batch studies. The obtained pHzpc (pH 5.7) value indicates that the adsorption process will be favorable at higher pH. The maximum removal efficiency and uptake capacity of lead were 98% and 68.07 mg/g, respectively. Adsorption data obtained were analyzed with Langmuir and Freundlich isotherm equations. The equilibrium data are fitted by Langmuir isotherm in a superior way than that of Freundlich isotherm. The results show that homogeneous adsorption of the metal ion favors heterogeneous adsorption. The maximum adsorption capacity of iron oxide NPs was calculated through Langmuir isotherm was Qmax (68.07) mg/g. Moreover, the adsorption of metal ions with time was also analyzed with the pseudo 1st and pseudo 2nd kinetic equations. The kinetic data are fitted more in the pseudo 2nd order reaction. Adsorption capacity calculated through pseudo 2nd order equation was qe (51.81) mg/g. This literature verifies that NPs synthesized from scrap iron as precursors prove to be an attractive option for removing heavy metals.
在本研究中,以废铁为原料,采用绿色合成方法制备了低成本、环保、单步、高产的新型氧化铁纳米颗粒(NP),以去除水溶液中的Pb(II)。用紫外-可见光谱法对合成的纳米颗粒进行了表征。通过XRD对其晶体结构和相变进行了分析。进行FE-SEM以了解氧化铁纳米颗粒的形态,并且通过BET表面积分析仪发现平均表面积为46.856m2/g。XRD图显示,当在开放气氛中进行合成时,所获得的磁铁矿Fe3O4结合了FeO和Fe2O3。SEM图像证实了尺寸为31nm的氧化铁纳米颗粒的形成。通过分批研究,优化不同的操作参数,如pH、时间、吸附剂用量、金属离子的初始浓度、接触时间,以提高吸附剂的去除效率。所获得的pHzpc(pH5.7)值表明,在较高的pH下,吸附过程将是有利的。铅的最大去除率和吸收能力分别为98%和68.07mg/g。用Langmuir和Freundlich等温线方程对获得的吸附数据进行分析。Langmuir等温线拟合平衡数据的方法优于Freundlich等温线。结果表明,金属离子的均相吸附有利于非均相吸附。通过Langmuir等温线计算出氧化铁纳米粒子的最大吸附量为Qmax(68.07)mg/g。此外,还用伪一阶和伪二阶动力学方程分析了金属离子随时间的吸附。动力学数据更多地拟合在拟二阶反应中。通过拟二阶方程计算的吸附容量为qe(51.81)mg/g。该文献证实,以废铁为前体合成的纳米颗粒被证明是去除重金属的一种有吸引力的选择。
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引用次数: 4
IN-SITU REMEDIATION OF HEAVY METAL CONTAMINATED SITES THROUGH MECHANICAL STABILIZATION USING INDUSTRIAL WASTE PRODUCTS 利用工业废弃物进行机械稳定的重金属污染场地原位修复
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-06-08 DOI: 10.3846/jeelm.2022.17077
R. Raja, S. Pal, A. Karmakar
The present study aimed to assess the stabilization performance of fly ash, blast furnace slag and quick lime for heavy metals in contaminated soil at a landfill site at Kolkata, West Bengal, India. The physical properties and strength parameters of the contaminated soil substantially increased after additives application. Moreover, the heavy metal concentrations in the leachate of the polluted soil were found almost nil after optimum blending of the additives mechanically with the soil and post-curing for 7 days. The numerical modeling studies were also carried out using PLAXISTM 3D software to ascertain the improvement of safety factor and deformation caused at the foundation level of an embankment constructed on such stabilized soil. The vertical displacement of the embankment founded on stabilized soil reduced from 194.3 to 136.3 mm and the safety factor of the embankment slope (1 V:1.5 H) increased from 2.5 to 3.2 under drained condition.
本研究旨在评估粉煤灰、高炉矿渣和生石灰对印度西孟加拉邦加尔各答某垃圾填埋场污染土壤中重金属的稳定性能。添加添加剂后,污染土壤的物理性质和强度参数均有明显提高。与土壤机械调配最佳添加剂,养护7 d后,污染土壤渗滤液中重金属含量基本为零。利用PLAXISTM 3D软件进行了数值模拟研究,以确定在这种稳定土上施工的路堤的安全系数和地基变形的改善情况。排水条件下,稳定土路基竖向位移由194.3 mm减小到136.3 mm,路基边坡安全系数(1 V:1.5 H)由2.5提高到3.2。
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引用次数: 0
TRENDS AND PERFORMANCES OF THE ALGAL BIOFUEL: A BIBLIOMETRIC APPROACH 藻类生物燃料的发展趋势和性能&文献计量法
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-06-06 DOI: 10.3846/jeelm.2022.16746
Conghao Gao, Huaijia Xin, Shu Yang, Zhuo Li, Shulin Liu, Bin Xu, Tianyang Zhang, S. Dutta, Yulin Tang
The paper systematically presents a survey of the literature on algal biofuel by a bibliometric assessment. Based on 10,201 articles extracted from the Science Citation Index Expanded database during 1980–2019, a knowledge-generating system about algal biofuel has been established through analysis of publication performance, social networks, citations analysis and keywords analysis. Annual publication output in algal biofuel research has rapidly increased, particularly over the past decade. “Bioresource Technology” is the most outstanding journal when all analysis indices have been taken into account. The USA ranks 1st with 2,151 publications and has a high supremacy in international research collaborations. Through the analysis of keywords, the research trends of algae biofuel in algae selection, cultivation, harvesting, extraction, conversion and bioproducts are reviewed. The future of algal biofuel is quite promising, however, for its commercial production, several technical challenges like large-scale algal biomass production, cheap harvesting technology, etc. have to be met a-priori.
本文通过文献计量学的方法对藻类生物燃料的文献进行了系统的综述。基于1980-2019年间从科学引文索引扩展数据库中提取的10201篇文章,通过对出版物绩效、社交网络、引文分析和关键词分析,建立了藻类生物燃料的知识生成系统。藻类生物燃料研究的年度出版物产量迅速增加,特别是在过去十年中。综合所有分析指标,《生物资源技术》是最优秀的期刊。美国以2151份出版物位居第一,在国际研究合作中占据绝对优势。通过关键词分析,综述了藻类生物燃料在藻类选择、培养、收获、提取、转化和生物制品等方面的研究进展。藻类生物燃料的未来是非常有希望的,然而,对于其商业生产来说,必须事先应对一些技术挑战,如大规模藻类生物质生产、廉价的收获技术等。
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引用次数: 1
SUSTAINABLE ENERGY-EFFICIENT CONVERSION OF WASTE TEA LEAVES TO REDUCING SUGAR: OPTIMIZATION AND LIFE-CYCLE ENVIRONMENTAL IMPACT ASSESSMENT 废茶叶可持续节能转化为还原糖:优化及全生命周期环境影响评价
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-05-31 DOI: 10.3846/jeelm.2022.16744
R. Chakraborty, Oindrila Roy
Innovative protocols involving energy-proficient pretreatment of waste tea leaves (WTL) for preparation of cellulose and its subsequent photocatalytic hydrolysis (PH) for production of total reducing sugar (TRS) have been reported. The WTL was subjected to alkali pretreatment (60 °C, 1 h) followed by bleaching (employing peracetic acid, 65 °C, 2 h) in a quartz halogen irradiated batch reactor (QHIBR) for efficient separations of lignin and hemicellulose fractions to produce WTL derived cellulose fiber (WTLDCF; 94.5% cellulose). Consequent PH of WTLDCF in QHIBR using combination of Amberlyst-15 and nano-TiO2 catalysts was optimized (parameters: 40 min, 70 °C, 1:30 WTLDCF to water weight ratio and 5 wt. % catalyst concentration) employing Taguchi design that provided maximum 68.25% TRS yield. The QHIBR demonstrated faster hydrolysis and superior energy-efficiency over conventional reactor owing to quartz halogen irradiation. Life cycle assessment indicated an acceptable global warming potential of 2.215 kg CO2 equivalent; thus, establishing an energy-efficient environmentally sustainable WTL valorization process.
创新方案涉及废茶叶预处理(WTL)制备纤维素及其随后的光催化水解(PH)生产总还原糖(TRS)。WTL经碱预处理(60℃,1 h),再经过氧乙酸漂白(65℃,2 h),在石英卤素辐照间歇式反应器(QHIBR)中有效分离木质素和半纤维素组分,生产WTL衍生纤维素纤维(WTLDCF;94.5%纤维素)。采用田口设计优化了Amberlyst-15和纳米tio2复合催化剂QHIBR中WTLDCF的PH(参数:40 min, 70°C, 1:30 WTLDCF与水的重量比,5 wt. %的催化剂浓度),TRS收率最高为68.25%。由于石英卤素辐照,QHIBR比传统反应器具有更快的水解速度和更高的能效。生命周期评估表明,可接受的全球变暖潜势为2.215 kg CO2当量;从而建立一个节能、环保、可持续的WTL增值过程。
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引用次数: 0
SIMULTANEOUS SOLAR PHOTO-DEGRADATION OF PVC-FE-DOPED ZNO-NANOCOMPOSITE FLAKES AND METHYLENE BLUE DYE IN WATER PVC-FE掺杂ZNO-纳米复合薄片与亚甲基蓝染料在水中的同时光降解
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-05-25 DOI: 10.3846/jeelm.2022.16743
A. Roy, S. Chakrabarti, S. Maitra
Simultaneous solar photocatalytic decolorization of Methlene Blue (MB) dye and degradation of polymer nanocomposite film in water has been attempted in the present work. The film immobilized iron (Fe)-doped zinc oxide (ZnO) nanoparticles (NPs) in polyvinyl chloride (PVC) matrix. This reduced the cost of separation of nanoparticles from treated water. Doped NPs were prepared sonochemically using zinc acetylacetonate (0.95 mmol) and ferric acetylacetonate (0.05 mmol) precursors in aqueous ethanol medium. XRD, UV-vis spectroscopy, FESEM and EDX were used for characterizing nanoparticles whereas the film was characterized by SEM. During the process, the film also reduced in weight. Degradation of both the dye and the polymer followed pseudo-first order kinetics. About 28% of the initial concentration of dye and about 5.04% of the initial weight of the PVC-film were decreased in the process after a run time of 3 h 45 minutes.
本工作尝试同时对亚甲基蓝(MB)染料进行太阳能光催化脱色,并在水中降解聚合物纳米复合膜。将掺铁氧化锌纳米粒子(NP)薄膜固定在聚氯乙烯(PVC)基体中。这降低了从处理过的水中分离纳米颗粒的成本。使用乙酰丙酮锌(0.95mmol)和乙酰丙酮铁(0.05mmol)前体在含水乙醇介质中超声化学制备掺杂的NP。XRD、UV-vis光谱、FESEM和EDX用于表征纳米颗粒,而SEM则对薄膜进行了表征。在这一过程中,薄膜的重量也有所减轻。染料和聚合物的降解都遵循伪一级动力学。在3小时45分钟的运行时间后,染料的初始浓度的约28%和PVC膜的初始重量的约5.04%在该过程中降低。
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引用次数: 2
PYROLYSIS KINETICS OF KEYBOARD PLASTIC WASTE USING THERMOGRAVIMETRIC ANALYSER TO ASSESS ITS ENERGY POTENTIAL 用热重分析仪评估键盘塑料垃圾的热解动力学
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-05-25 DOI: 10.3846/jeelm.2022.16742
A. K. Panda, Satyanarayan Patnaik, Sachin Kumar
In this paper, the kinetic parameters of discarded computer keyboard plastic waste are estimated using thermogravimetric analysis (TGA) with four different non-isothermal kinetic models at a wide range of heating rates 5, 10, 15, 20, 40, 60 and 100 °C/min. The gross calorific value of waste computer keyboard plastic is 38.96 MJ/Kg. FT-IR analysis confirms the presence of alcohol, phenol, ether, ester, carboxylic acid, aromatic, and alkene compounds in keyboard plastic waste. The average values of activation energy are calculated as 158.1668, 198.883, 193.612, and 197.765 kJmol−1 from Kissinger, Friedman, FWO, and Coats-Redfern methods, respectively. The kinetic data obtained in this work would be useful for accurate prediction of reaction behaviour and in the design of efficient commercial process for the conversion of such plastic wastes to energy.
在5、10、15、20、40、60和100°C/min的加热速率下,采用热重分析(TGA)方法对废弃计算机键盘塑料废弃物的动力学参数进行了估算。废旧电脑键盘塑料的总热值为38.96 MJ/Kg。FT-IR分析证实在键盘塑料废料中存在酒精、苯酚、醚、酯、羧酸、芳香和烯烃化合物。用Kissinger、Friedman、FWO和Coats-Redfern方法计算得到的活化能平均值分别为158.1668、198.883、193.612和197.765 kJmol−1。在这项工作中获得的动力学数据将有助于准确预测反应行为和设计有效的商业过程,将这些塑料废物转化为能源。
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引用次数: 0
TECHNICAL AND ENVIRONMENTAL PERFORMANCE ASSESSMENT OF THE IRANIAN POWER PLANTS: A SEMI-DISPOSAL DEA APPROACH 伊朗发电厂技术与环境绩效评估:半处置DEA方法
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-05-23 DOI: 10.3846/jeelm.2022.16740
Masod Mokari, M. Ghiyasi, Ali Emami Meybodi
One of the most important issues is to achieve maximum production of energy from a particular energy source, which ensures the complete protection of the environment. The current paper as the first application of flexible and powerful semi-disposability approach, performs an empirical technical and environmental efficiency analysis for 39 natural gas and gasoline power plants, including governmental and private property, during the years 2011–2016. Different scenarios for environmental analysis, namely, weak disposability, strong disposability and semi-disposability with different returns to scale assumptions are performed in the analysis. The primary results of multivariate assessment based on constant returns to the scale shows that 7 power plants with state ownership and 8 power plants with private ownership were among the most efficient power plants from the technical-environmental perspective. Parametric and non-parametric tests are performed and the result shows better performance of private power plants compared with governmental power plants.
最重要的问题之一是实现从特定能源中最大限度地生产能源,这确保了环境的完全保护。本文作为灵活而强大的半可处置性方法的首次应用,对2011-2016年期间39家天然气和汽油发电厂(包括政府和私人财产)进行了经验技术和环境效率分析。分析中采用了不同的环境分析情景,即弱可弃置性、强可弃置性和半可弃置性,并采用不同的规模收益假设。基于规模不变收益的多变量评价初步结果显示,7家国有电厂和8家民营电厂在技术-环境角度上效率最高。进行了参数和非参数测试,结果表明民营电厂的性能优于政府电厂。
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引用次数: 0
CORRIGENDUM: BIOREMEDIATION OF CHROMIUM (VI) BY A MICROBIAL CONSORTIUM ISOLATED FROM TANNERY EFFLUENTS AND THEIR POTENTIAL INDUSTRIAL APPLICATION 勘误:从制革废水中分离出的微生物联合体对铬的生物修复及其潜在的工业应用
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-05-16 DOI: 10.3846/jeelm.2022.16521
Arghyadeep Bhattacharjee, R. Chaudhuri, Priyanshu Pandey, A. Mitra
Arghyadeep Bhattacharjee, Rajarshi Chaudhuri, Priyanshu Pandey, Arup Kumar Mitra, authors of the article “Bioremediation of chromium (VI) by a microbial consortium isolated from tannery effluents and their potential industrial application”, published in Journal of Environmental Engineering and Landscape Management, 29(4), 418–429, https://doi.org/10.3846/jeelm.2021.15762 inform that 423 p. is a minor misinformation in the legend of Figure 4: Figure 4. Observation of Keratinase activity of the isolates. Graphical representation showing the amount of keratin activity by the microorganisms which were determined by the concentration of the vanillin degraded per ml of the crude enzyme. Y-axis indicates the enzymatic activity expressed in U/ml and X-axis denotes the test isolates. Data (n = 3) illustrated in the bar diagram as mean +SD. ***p < 0.0001 as determined by One-way ANOVA (IS1 to IS4 represents the isolates; BSA: Bovine Serum Albumin) The correct legend is: Figure 4. Observation of Keratinase activity of the isolates. Graphical representation showing the amount of keratin activity by the microorganisms. Y-axis indicates the enzymatic activity expressed in U/ml and X-axis denotes the test isolates. Data (n = 3) illustrated in the bar diagram as mean +SD. ***p < 0.0001 as determined by One-way ANOVA (IS1 to IS4 represents the isolates) The authors regret the error.
arghydeep Bhattacharjee, Rajarshi Chaudhuri, Priyanshu Pandey, Arup Kumar Mitra,发表在《环境工程与景观管理杂志》29(4),418-429,https://doi.org/10.3846/jeelm.2021.15762上的文章“从制革厂废水中分离的微生物群落对铬(VI)的生物修复及其潜在的工业应用”的作者指出,423 p.是图4传说中的一个小错误信息:图4。分离菌株角朊酶活性的观察。图表显示了微生物角蛋白活性的数量,这是由每毫升粗酶降解的香兰素的浓度决定的。y轴为酶活性(U/ml), x轴为分离株。数据(n = 3)在柱状图中表示为平均值+SD。***经单因素方差分析,p < 0.0001 (IS1 ~ IS4代表分离株;BSA:牛血清白蛋白)正确的图示为:图4。分离菌株角朊酶活性的观察。图示显示微生物的角蛋白活性。y轴为酶活性(U/ml), x轴为分离株。数据(n = 3)在柱状图中表示为平均值+SD。***p < 0.0001,经单因素方差分析(IS1至IS4为分离株),作者对错误表示遗憾。
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引用次数: 2
MODIFICATION OF NATURAL OIL SORBENT FOR IMPROVEMENT OF HYDROPHOBICITY 改性天然吸油剂提高疏水性
IF 1.3 4区 环境科学与生态学 Q3 Environmental Science Pub Date : 2022-05-16 DOI: 10.3846/jeelm.2022.16958
V. Vaišis, Eglė Anužytė, D. Paliulis, Jolita Bradulienė
A sorbent made of natural materials (moss) was selected for the sorption of diesel from the surface of the water. The sorbent was modified to increase its hydrophobic–oleophilic characteristics. Typical natural organic sorbent from moss was selected and modified in three different ways: processed with hot water (80 °C and 100 °C), mercerized and coated with oil–water (10% and 50%). Water, diesel sorption capacity, and oil retention tests were performed. Tests showed that simple treatment with hot water and alkali can change surface properties and improve sorption capacity. Modification with hot water at 80 °C enhanced sorbents’ oil sorption capacity and showed the best results but meanwhile, this method readily increased hydrophilicity. This method of sorbent treatment could not be applied in cases where sorbents are used to clean oil spills from water surfaces. Meanwhile, better sorption results would be obtained in cases where cleaning operations take place on soil and other solid surfaces.
选择了一种由天然材料(苔藓)制成的吸附剂来吸附水表面的柴油。对吸附剂进行了改性,以提高其疏水-亲油特性。从苔藓中选择典型的天然有机吸附剂,并以三种不同的方式进行改性:热水处理(80°C和100°C)、丝光处理和油-水涂层(10%和50%)。进行了水、柴油吸附能力和保油试验。试验表明,热水和碱的简单处理可以改变表面性质,提高吸附能力。80°C热水改性提高了吸附剂的吸油能力,效果最好,但同时也容易增加亲水性。这种吸附剂处理方法不能应用于吸附剂用于清洁水面漏油的情况。同时,在对土壤和其他固体表面进行清洁操作的情况下,将获得更好的吸附结果。
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引用次数: 0
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Journal of Environmental Engineering and Landscape Management
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