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Detoxification of Heavy Metals from Leafy Edible Vegetables by Agricultural Waste: Apricot Pit Shell 农业废弃物对叶菜可食蔬菜中重金属的解毒作用:杏核壳
Pub Date : 2018-01-01 DOI: 10.4172/2161-0525.1000548
Bita Tavakoli-Hosseinabady, P. Ziarati, E. Ballali, K. Umachandran
Soil contamination by heavy metals, though restricted to surface horizons, based on soil texture are occluded, organically complexed, modified and specifically adsorbed based on anthropogenic sources, resulted in toxicity ramification on human health, has been in vogue as a serious environmental problem for last few decades. A laboratory study was planned due to reduction of Lead, Cadmium and Nickel toxicity by a low-cost soil amendment. Apricot (Prunus armeniaca L.) pit shell an abundant and low cost natural resource in Iran was used to adsorbing some heavy metals from contaminated soil of vegetable farmlands. Different adsorption parameters like adsorbent dose, particle size of adsorbent and time of growing vegetable were studied. Composite soil sample were collected from four randomized farmland locations at three agricultural fields (each one more than 10 hectares), in Yazd county in Yazd Province. Cultivated Leafy vegetables were grown under controlled similar physical conditions, including pH, light and demonized watering. Leaves, roots and soil samples were examined, analyses and studied, at various frequencies for heavy metals.
土壤重金属污染虽然局限于表层,但基于土壤的质地,在人为源的基础上被遮挡、有机络合、修饰和特异性吸附,对人体健康产生毒性影响,是近几十年来作为一个严重的环境问题而流行起来的。由于一种低成本的土壤改良剂降低铅、镉和镍的毒性,计划进行实验室研究。利用伊朗丰富的低成本天然资源杏核壳吸附蔬菜农田污染土壤中的部分重金属。研究了吸附剂用量、吸附剂粒径、蔬菜生长时间等不同的吸附参数。在亚兹德省亚兹德县的三个农田(每个农田超过10公顷)的四个随机农田地点收集了复合土壤样本。叶菜在类似的物理条件下种植,包括pH值、光照和妖魔化的浇水。对树叶、根和土壤样本进行了不同频率的重金属检测、分析和研究。
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引用次数: 23
Synthesis and Performance of Iron Oxide-Based Ceramsite in a Biotrickling Filter for Nitrogen Oxides Removal 生物滴滤池中氧化铁基陶粒的合成及性能研究
Pub Date : 2018-01-01 DOI: 10.4172/2161-0525.1000534
Li Han, Z. Nan, Guo Ze, Fan Jing, Wu Dafu, H. Shaobin
A novel medium containing iron oxide-based porous ceramsite (modified ceramsite) and commercial ceramsite was used in two bench-scale biotrickling filter for nitrogen oxides removal to evaluate the performance of the modified ceramaite. In this study, we adopted the method of surface coating by choosing FeCl3·6H2O as modifier. Under the calcination time was 4 h at the temperature of 500°C, the modified filler presented excellent adsorption for microbial growth and the mass dry weight of biofilm reached a peak of 1.28 mg/g. Results showed that the density increased by 17% and porosity increased by about 15%, and the isoelectric point PI increased more than 4 times, while the surface pH value reduced to 3.46. The surface of pH is much lower than the isoelectric point, to ensure that its surface is electropositive, besides, the modified ceramsite had a more rough surface compared with ceramsite and changed the two-dimensional rough surface into three-dimensional surface. It only took 8 days for the biotrickling filter to start up with the modified ceramsite while the commercial ceramsite was about 22 days, which greatly shortened the start-up period. Packing with the modified filler, the NO removal performance stayed quite stable and efficient, the removal efficiency of NO did not apparently decrease under high inlet concentration of NO and basically maintained an average value of 92.8% during the whole operation period of treatment. While the commercial ceramsite presented an obvious removal decrease comparing with the modified, especially with the high NO inlet concentration of above 1600 mg/m3 and the removal efficiency was less than 80%. The iron oxide-based ceramsite proved to have the capability for improving the performance of the biofilter for NO removal. Furthermore, the fall off of the surface coating is not obvious under the experimental condition and the property of the coating is relatively stable in a long period of operation. Thus, our findings support the modified filler of iron oxide-based ceramsite as a material for use in filter media in in a biotrickling filter for pollutant gas removal.
采用含氧化铁基多孔陶粒(改性陶粒)和商品陶粒的新型介质,对改性陶粒的脱氮性能进行了评价。在本研究中,我们选用FeCl3·6H2O作为改性剂,采用表面涂层的方法。在500℃下焙烧4 h时,改性填料对微生物的吸附效果良好,生物膜的质量干重达到1.28 mg/g的峰值。结果表明,密度提高了17%,孔隙率提高了15%左右,等电点PI提高了4倍以上,而表面pH值降至3.46。表面pH值远低于等电点,以保证其表面具有正电性,并且改性陶粒的表面比陶粒更粗糙,将二维粗糙表面变为三维粗糙表面。改性陶粒的生物滴滤器启动时间仅为8天,而商用陶粒的启动时间约为22天,大大缩短了启动时间。经改性填料填料填料处理后,对NO的去除率保持了相当稳定和高效,在高进口NO浓度下,对NO的去除率没有明显下降,在整个处理运行期内基本保持在92.8%的平均值。与改性陶粒相比,工业陶粒的去除率明显下降,特别是NO进口浓度高达1600 mg/m3以上,去除率低于80%。氧化铁基陶粒被证明具有提高生物滤池去除NO性能的能力。此外,在实验条件下,表面涂层脱落不明显,涂层性能在长时间运行中相对稳定。因此,我们的研究结果支持氧化铁基陶粒改性填料作为过滤介质的材料,用于去除污染气体的生物滴滤器。
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引用次数: 0
Comparison Study of Toxicity Kohl and Black Stone Hair Dye 科尔和黑石染发剂毒性比较研究
Pub Date : 2018-01-01 DOI: 10.4172/2161-0525.1000539
A. Shihata
Background: Kohl has been known and used traditionally as eye cosmetic for women and babies. Kohl is a gray or black eye cosmetic used in middle east, India, Pakistan, and some parts of Africa. There are different forms of commercially available preparation: stone powder finger rods, or pencils. Black hair dye is widely used in Upper Egypt, traditionally know as "stone hair dye". Many cases of toxicity and mortality either due to accidental or deliberate ingestion of hair dyes were reported in Egypt and other countries. Objective: To determination the elements in Kohl and Hair Dye from market and comparison these elements in liver and kidney of two women reported in Upper Egypt. Toxicity of Kohl due to Lead, Aluminum, Zinc, and some other metals. While black stone is a traditional hair dye popularly used in the third world as a deep black coloration substance and cheap. Unfortunately, many persons use it as a criminal tool for homicide or suicide. (P-Phenylenediamine PPD) may cause severe dermatitis, gastritis, renal failure, convulsions, and coma in humans. So that (PPD) and other nitro aromatic compounds the main toxic ingredient of hair dye so that it's very dangerous transdermal and the concentration of Lead, Aluminum, Zinc, and some other metals is lower than in Black hair dye. This research was studied that in two cases (human) has died. *Corresponding author: Ahmed Shihata, Forensic Medicine Authority, Assuit University, Egypt, Tel: +201091449737; E-mail: ahmed_shihata_7@yahoo.com Received November 09, 2017; Accepted December 20, 2017; Published January 02, 2018 Citation: Shihata A (2018) Comparison Study of Toxicity Kohl and Black Stone Hair Dye. J Environ Anal Toxicol 8: 539. doi: 10.4172/2161-0525.1000539 Copyright: © 2018 Shihata A. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Citation: Shihata A (2018) Comparison Study of Toxicity Kohl and Black Stone Hair Dye. J Environ Anal Toxicol 7: 539. doi: 10.4172/2161-0525.1000539
背景:眼影粉一直被认为是女性和婴儿的眼部化妆品。眼影粉是一种灰色或黑色的眼部化妆品,在中东、印度、巴基斯坦和非洲部分地区使用。有不同形式的商业准备:石粉指棒,或铅笔。黑色染发剂在上埃及广泛使用,传统上被称为“石头染发剂”。在埃及和其他国家报告了许多因意外或故意摄入染发剂而中毒和死亡的病例。目的:测定上埃及地区两名妇女的肝脏和肾脏中染发剂和染发剂的元素含量。由于铅、铝、锌和其他一些金属的毒性。而黑石是一种传统的染发剂,在第三世界广泛使用,作为一种深黑色的着色物质,价格便宜。不幸的是,许多人把它作为杀人或自杀的犯罪工具。(对苯二胺PPD)可引起严重的皮炎、胃炎、肾衰竭、惊厥和昏迷。所以(PPD)和其他硝基芳香族化合物是染发剂的主要有毒成分所以它是非常危险的透皮的铅,铝,锌和其他一些金属的浓度低于黑色染发剂。本研究经研究发现,有2例(人)已死亡。*通讯作者:Ahmed Shihata,埃及Assuit大学法医管理局,电话:+201091449737;邮箱:ahmed_shihata_7@yahoo.com 2017年11月09日收稿;2017年12月20日录用;引用本文:Shihata A (2018) Kohl和Black Stone染发剂毒性的比较研究。[J]环境与环境杂志,8(5):539。doi: 10.4172/2161-0525.1000539版权:©2018 Shihata A.这是一篇根据知识共享署名许可条款发布的开放获取文章,允许在任何媒体上不受限制地使用、分发和复制,前提是注明原作者和来源。引用本文:Shihata A (2018) Kohl和Black Stone染发剂毒性的比较研究。[J]中华毒物学杂志,2007,27(5):539。doi: 10.4172 / 2161 - 0525.1000539
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引用次数: 2
Determination of Pesticide Residues by GC-MS in Commercialized Mint Samples 商品薄荷样品中农药残留的气相色谱-质谱法测定
Pub Date : 2018-01-01 DOI: 10.4172/2161-0525.1000572
M. Jbilou, K. Laarej, R. Alami, A. Bouklouze, Y. Cherrah, A. E. Yadini, M. E. Faouzi
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引用次数: 0
Short-Term Exposure to Haze Air Pollution Induces Acute Airway Inflammation and Lung Function Reduction in Healthy Adult Subjects 短期暴露于雾霾空气污染可引起健康成人急性气道炎症和肺功能下降
Pub Date : 2018-01-01 DOI: 10.4172/2161-0525.1000555
Haibin Li, Yanqin Liu, S. Yao, Yuefei Jin, Yixin Luo, Wenyang Li, Chengyu Song, Chong Liu, Ziye Wang, Weidong Wu
Haze air pollution with high levels of PM has frequently took place in many areas of China in the past few years. However, the health effect of shirt-term exposure to haze air pollution has not been thoroughly characterized. This study aimed to determine the acute effect of haze exposure on respiratory system of healthy adult subjects, specifically on airways and lung function. Thirty healthy adult subjects were recruited and airway inflammation and lung function alterations examined under control and haze air pollution (157.33 μg/m for mean concentration of PM ) conditions, respectively. Airway inflammation was assessed by sputum induction while lung function was measured using spirometry. It was shown that 24-h exposure to haze air pollution could increase the levels of inflammatory mediators including interleukin-6 (IL-6), IL-8, and tumor necrotic factor-α (TNF-α), as well as the percentages of eosinophils, neutrophils, and lymphocytes in the sputum (<0.05). In contrast, the proportion of macrophages in the sputum from haze-exposed subjects decreased significantly (<0.05). In addition, short-term exposure to haze could decrease forced vital capacity (FVC), forced expiratory volume in the first second (FEV ), vital capacity (VC), and maximum voluntary ventilation (MVV), but not FEV1/FVC. In summary, short-term exposure of healthy adult subjects to haze air pollution induces airway inflammation and lung function impairment.
近年来,中国多地频繁出现高浓度PM的雾霾空气污染。然而,长期暴露于雾霾空气污染对健康的影响尚未得到彻底的表征。本研究旨在确定雾霾暴露对健康成人呼吸系统的急性影响,特别是对气道和肺功能的影响。招募30名健康成人受试者,分别在控制和雾霾空气污染(PM平均浓度为157.33 μg/m)条件下检测气道炎症和肺功能变化。痰诱导法评价气道炎症,肺活量法测定肺功能。结果表明,24 h雾霾空气污染可使痰中炎症介质白细胞介素-6 (IL-6)、IL-8、肿瘤坏死因子-α (TNF-α)水平升高,嗜酸性粒细胞、中性粒细胞、淋巴细胞比例升高(<0.05)。相比之下,雾霾暴露组痰中巨噬细胞比例明显降低(<0.05)。此外,短时间暴露在雾霾环境中会降低用力肺活量(FVC)、第一秒用力呼气量(FEV)、肺活量(VC)和最大自主通气量(MVV),但不会降低FEV1/FVC。综上所述,健康成人短期暴露于雾霾空气污染中会引起气道炎症和肺功能损伤。
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引用次数: 1
Biologically Essential and Non-Essential Elements Causing Toxicity in Environment 在环境中引起毒性的生物必需元素和非必需元素
Pub Date : 2018-01-01 DOI: 10.4172/2161-0525.1000557
S. L. Bansal, S. Asthana
This paper encompasses the toxicity of abundant and trace elements present on the earth. Generally, the less abundant elements are more toxic. But even the biologically essential elements become toxic above a critical concentration. The synergistic influence of a metal on toxicity of another is also discussed for mercury selenium and zinc-cadmium pairs. A general observation is made that for biologically important elements a single oxidation states are considerably more toxic. It is known that some elements viz., C, H, O, Na, K, N, P, S, Mg, Ca, Cl are major essentials for life and B, F, Si, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Se, Mo, Sn and I are the trace elements essential for life. Cr (III) for example is essential for glucose and lipid metabolism, Mn(II) is a co-factor in a number of enzymatic reactions, Fe has major role in haemoglobin formation, Co(II) is a component of vit. B12, NI(II) has been found to be essential for mammals and Mo is an important co-factor for xanthine oxidase and aldehyde oxidase as a consequence of its different oxidation states. A minimum concentration of these elements is essential for proper growth of body, but beyond certain level of concentration these elements also become toxic. The threshold concentration is comparatively higher for the compounds of metals which have some biological function but for other metals (Pb, Cd, Hg, As, Sb etc) the tolerance limit is very low. These metals get accumulated in body because they are not biodegradable.
本文论述了地球上存在的丰富元素和微量元素的毒性。一般来说,含量越少的元素毒性越大。但是,即使是生物上必需的元素,超过临界浓度也会有毒。还讨论了一种金属对另一种金属对汞、硒和锌镉对毒性的协同影响。一般观察表明,对于重要的生物学元素,单一氧化态的毒性要大得多。已知C、H、O、Na、K、N、P、S、Mg、Ca、Cl等元素是生命必需的主要元素,B、F、Si、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Se、Mo、Sn、I等是生命必需的微量元素。例如,铬(III)是葡萄糖和脂质代谢所必需的,锰(II)是许多酶促反应的辅助因子,铁在血红蛋白形成中起主要作用,钴(II)是维生素的组成部分。已发现B12、NI(II)对哺乳动物是必需的,Mo是黄嘌呤氧化酶和醛氧化酶的重要辅助因子,由于其不同的氧化状态。这些元素的最低浓度是身体正常生长所必需的,但超过一定的浓度,这些元素也会中毒。对具有一定生物功能的金属化合物的阈值浓度相对较高,而对其他金属(铅、镉、汞、砷、锑等)的容忍极限很低。这些金属不能生物降解,所以会在体内积累。
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引用次数: 24
Carbon Sorbent of Destructive Type Based on Wood Biochar for Removal of Oil Pollution 基于木质生物炭的破坏性碳吸附剂去除油类污染
Pub Date : 2018-01-01 DOI: 10.4172/2161-0525.1000576
Khokhlov Andrii Viktorovich, Khokhlova Lyudmila Iosiphovna
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引用次数: 2
TCR-Vβ8 as Alternative to Animal Testing for Quantifying Active SEE tcr - v - β8作为定量活性SEE的替代动物试验
Pub Date : 2017-12-22 DOI: 10.4172/2161-0525.1000527
R. Rasooly, P. Do, Xiaohua He, Bradley J. Hernlem
Staphylococcal food poisoning is a result of ingestion of Staphylococcal enterotoxins (SEs) produced by the bacterium Staphylococcus aureus. SEs cause gastroenteritis and also cause activation of T cells and massive cytokine release. A current method for the detection of active SEs relies on its emetic effect on monkeys or kittens. However this costly procedure has low sensitivity and raises ethical concerns. This present study overcomes the limitations of such bioassays by providing an alternative method based on the alteration of TCR Vβ8 protein levels expressed on Jurkat T cell-line. We demonstrated that increasing concentrations of SEE, the causative agent in foodborne outbreaks in France, UK and USA, reduced TCR Vβ8 protein levels in a dose dependent manner and similarly alters the luciferase gene expression under the regulation of nuclear factor of T-cell activation (NFAT). Unlike previous studies that show accessory cells are not required for T cell activation by SEA or SEB, this present study demonstrated that accessory cells are required for T cell activation by SEE and SEE has greater affinity for the accessory cells than the Jurkat T cell. It is advantageous to use fixed dead cells where possible to reduce cell culture work. In this study we show that fixed accessory cells lacking any metabolic function without processing can present intact SEE and consequently alter TCR Vβ8 levels and the reporter gene expression.
葡萄球菌性食物中毒是由于摄入了由金黄色葡萄球菌产生的葡萄球菌性肠毒素(SEs)。SEs会引起胃肠炎,也会引起T细胞的激活和大量细胞因子的释放。目前检测活性se的方法依赖于它对猴子或小猫的催吐作用。然而,这种昂贵的程序灵敏度低,并引起道德问题。本研究通过提供一种基于Jurkat T细胞系上表达的TCR Vβ8蛋白水平改变的替代方法,克服了这种生物测定的局限性。我们证明,在法国、英国和美国食源性暴发的致病菌SEE浓度的增加,以剂量依赖的方式降低了TCR Vβ8蛋白水平,并在t细胞活化核因子(NFAT)的调节下类似地改变了荧光素酶基因的表达。与先前的研究表明SEA或SEB激活T细胞不需要辅助细胞不同,本研究表明SEE激活T细胞需要辅助细胞,并且SEE对辅助细胞的亲和力比Jurkat T细胞更强。在可能的情况下,使用固定的死细胞以减少细胞培养工作是有利的。在这项研究中,我们发现缺乏任何代谢功能而未经加工的固定附属细胞可以呈现完整的SEE,从而改变TCR Vβ8水平和报告基因表达。
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引用次数: 3
Characterization of ZrO 2 Nano Particles Prepared by Glycothermal Method and their Efficiency as Adsorbent of As(III) and As(V) from Waste Water 糖热法制备zro2纳米颗粒的表征及其对废水中as (III)和as (V)的吸附剂性能
Pub Date : 2017-11-27 DOI: 10.4172/2161-0525.1000532
B. Al‐Farhan
In this studied ZrO2 nano particles are prepared by glycothermal method. Characterization of the prepared nano particle was done using XRD, TEM and SEM. According to the obtained results, ZrO2 nano particles prepared by glycothermal method are mainly t-ZrO2 phase with tetragonal shape with an average size in the range of 30-50 nm. The formation of t-ZrO2 as the main phase of zirconium nano particles could be related to the presence of sodium hydroxide in the generation step. The removal efficiency of ZrO2 nano particles for adsorbing As(III) and As(V) from waste water is studied. The efficiency of removal is significantly increased with increasing the dose of zirconia nano particles till 0.5 g/L. This related to increasing in the active site which are available for the removal of arsenic species by increasing the dose of the nano particles. For both As(III) and As(V), the removal efficiency increased by decreasing pH value of the solution and increasing the contact time.
本研究采用糖热法制备ZrO2纳米颗粒。采用XRD、TEM和SEM对制备的纳米颗粒进行了表征。结果表明,糖热法制备的ZrO2纳米颗粒主要为t-ZrO2相,呈四边形,平均粒径在30 ~ 50 nm之间。t-ZrO2作为锆纳米颗粒的主相的形成可能与生成过程中氢氧化钠的存在有关。研究了ZrO2纳米颗粒对废水中As(III)和As(V)的去除效果。随着氧化锆纳米颗粒投加量的增加,去除率显著提高至0.5 g/L。这与通过增加纳米粒子的剂量来去除砷的活性位点的增加有关。对于As(III)和As(V),随着溶液pH值的降低和接触时间的延长,去除效率均有所提高。
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引用次数: 4
Groundwater Assessment through an Integrated Approach Using GIS and Electrical Resistivity Technique: A Case Study from the Bullom Group of Sediments in Sierra Leone 利用GIS和电阻率技术综合评价地下水:以塞拉利昂Bullom组沉积物为例
Pub Date : 2017-11-10 DOI: 10.4172/2161-0525.1000523
Yaguba Jalloh, M. Thomsa, K. Sasaki
Electrical Resistivity in conjunction with Geographic Information System (GIS) techniques have been widely used in groundwater resource management. In this research, Vertical Electric Sounding (VES), an Electrical Resistivity method, was integrated with GIS to delineate geo-electric characteristics and evaluate groundwater potential of the Bullom group of sediments in Sierra Leone. For this assessment, a total of 5 vertical electrical sounding stations were established within the site. The Schlumberger electrode configuration and the expanding procedure were used for data acquisition. The VES curves generated were interpreted using partial curve matching. The depth sounding interpretation results were used to generate geo-electric sections from which the aquifer was delineated. The aquifer revealed four subsurface layers which comprises of sandy topsoil, clayey sand which acts as aquitard and sandy gravel (confine aquifer) that serves as a source of portable water in the study area. A GIS model was then developed to locate the suitable groundwater prospective zones which reveals the average depth to groundwater to be between 10 m to 30 m. This research concluded that the boreholes were sited in high conductivity zones in VES layers 1, 2, 3 and 4 as they contain probable aquifers with good yield.
电阻率与地理信息系统(GIS)技术的结合已广泛应用于地下水资源管理。在这项研究中,将电阻率法垂直电测深(VES)与GIS相结合,描绘了塞拉利昂Bullom组沉积物的地电特征并评估了地下水潜力。本次评估共在场址内建立了5个垂直电测深站。采用斯伦贝谢电极配置和扩展程序进行数据采集。利用部分曲线匹配的方法对生成的VES曲线进行解释。利用测深解释结果生成地电剖面,据此圈定了含水层。该含水层揭示了四个亚表层,包括沙质表土、作为含水层的粘土砂和作为研究区域可移动水源的沙质砾石(限制含水层)。然后开发了一个GIS模型来定位合适的地下水远景区,该模型显示地下水的平均深度在10米至30米之间。研究结果表明,该井位于地震探测系统1、2、3和4层的高导电性区域,可能含有高产含水层。
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引用次数: 0
期刊
Journal of Environmental and Analytical Toxicology
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