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Impact of Sea Life with Plastic Pollution 塑料污染对海洋生物的影响
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.21.8.310
Chiranjeevi Sirikonda
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引用次数: 0
Brief Note on Environmental Pollution 环境污染简介
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.323
Shelby Boden
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引用次数: 0
Editorial Note on Toxic Chemicals & Its Effects 关于有毒化学品及其影响的社论注释
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.297
Chiranjeevi Sirikonda
The toxic chemicals are the material that can be toxic or cause health effects, they can not quickly break down in the atmosphere, they can build up small organisms' tissues, they can travel up through the food chain.Chemicals can be harmful because they can damage us as they reach or touch the body, posing a danger to human health. For example, nitrogen and sulphur oxide pollution from vehicles cause acid rain, killing fish and other aquatic species in rivers and lakes.
有毒化学物质是有毒或对健康造成影响的物质,它们不能在大气中迅速分解,它们可以形成小生物的组织,它们可以通过食物链向上传播。化学物质可能是有害的,因为当它们到达或接触人体时,会对我们造成伤害,对人体健康构成威胁。例如,车辆排放的氮和硫氧化物污染会导致酸雨,杀死河流和湖泊中的鱼类和其他水生物种。
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引用次数: 0
Observation of Mercury Species Concentration in Atmospheric Deposition in Niigata City in Japan 日本新泻市大气中汞种浓度的观测
Pub Date : 2021-01-01 DOI: 10.5985/JEC.31.55
Takashi Ono, Tomohiro Kobayashi, Aya Matsuzaki, Seiichi Tanahashi, H. Yagoh
Mercury concentrations in the atmospheric deposits were measured from April 2017 to April 2020 in Niigata City. As a result, total mercury concentration in the weighted average precipitation was 5.7±3.6 ng/L for total mercury, 2.8± 3.0 ng/L for dissolved, and 2.9±2.0 ng/L for particulate. A high concentration of dissolved mercury was observed in June 2017, suggesting an increase in the concentration of gaseous oxidized mercury in the atmosphere. In addition, Asian dust was observed when the concentration of particulate mercury and the concentration of particulate matter increased, which may have affected the concentration of mercury. The amount of atmospheric deposition increased in winter when there was much rainfall and snow, and the concentration of dissolved mercury tended to increase.
2017年4月至2020年4月,对新泻市大气沉积物中的汞浓度进行了测量。结果表明,加权平均降水中总汞浓度为5.7±3.6 ng/L,溶解汞浓度为2.8±3.0 ng/L,颗粒物汞浓度为2.9±2.0 ng/L。2017年6月观测到高浓度的溶解汞,表明大气中气态氧化汞的浓度有所增加。此外,当颗粒汞浓度和颗粒物浓度增加时,观察到亚洲粉尘,这可能影响了汞的浓度。冬季多雨雪期大气沉降量增加,溶解汞浓度有增加的趋势。
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引用次数: 0
Editorial on Exposure to Benzene and Its Causes 关于接触苯及其原因的社论
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.334
Fenx Jie
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引用次数: 0
Determination of Poly(oxyethylene)alkyl ether in Environmental Water 环境水中聚氧乙烯烷基醚的测定
Pub Date : 2021-01-01 DOI: 10.5985/JEC.31.9
R. Tahara, Seiki Igarashi, H. Mikami
A simultaneous analysis method for poly(oxyethylene)alkyl ethers (AEs) in environmental water was developed using solid phase extraction-liquid chromatography-tandem mass spectrometry (LC / MS / MS). The target substances were those with an alkyl group that had 9 – 15 carbon atoms and an ethylene oxide molar addition of 1 – 15 (C 9 - 15 EO 1 - 15 ). The elec-trospray ionization technique was used in the LC / MS / MS measurement. The method detection limit (MDL) of C 12 EOns, which is the main component of the AEs, ranged from 0 . 00043 μ g / L for C 12 EO 8 to 0 . 0052 μ g / L for C 12 EO 1 , with the total MDL being 0 . 020 μ g / L. The method quantification limit (MQL) ranged from 0 . 0011 μ g / L for C 12 EO 8 to 0 . 013 μ g / L for C 12 EO 1 , with the total MQL being 0 . 052 μ g / L. The total MDL and MQL of C 9 - 15 EO 1 - 15 were 0 . 14 μ g / L and 0 . 36 μ g / L respectively. Tokoro River water samples were analyzed using this method. In 15 surveys, the concentration of AEs ranged from 0 . 0080 μ g / L to 1 . 2 μ g / L, and C 12 EOns were the main substances in all samples. The distribution of the number of EO additional moles of C 12 EOns differed depending on the sample. This is thought to be because of the dif-ferent uses of the discharged AE products.
建立了固相萃取-液相色谱-串联质谱(LC / MS / MS)同时分析环境水中聚氧乙烯烷基醚(AEs)的方法。目标物质是具有9 - 15个碳原子的烷基和环氧乙烷摩尔加成为1 - 15 (c9 - 15 EO 1 - 15)的物质。LC / MS / MS测量采用电喷雾电离技术。作为ae主要成分的c12eons的方法检出限(MDL)范围为0。00043 μ g / L, c12eo 8 ~ 0。c12eo1的检测浓度为0052 μ g / L,总MDL为0。方法定量限(MQL)为0。0011 μ g / L, c12eo 8 ~ 0。c12eo1的浓度为013 μ g / L,总MQL为0。c9 - 15eo 1 - 15的总MDL和MQL分别为0。14 μ g / L;分别为36 μ g / L。用该方法对东野河水样进行了分析。在15次调查中,ae的浓度范围为0。0080 μ g / L至1。2 μ g / L,以c12eons为主。c12eons的EO附加摩尔数分布随样品的不同而不同。这被认为是由于排放的AE产品的不同用途。
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引用次数: 0
Study of Pollution Sources of Zinc in Lake Shinji Based on Zinc Isotope Ratio in Sediment 基于沉积物锌同位素比值的真鸡湖锌污染源研究
Pub Date : 2021-01-01 DOI: 10.5985/jec.31.106
M. Sakata, Kenta Ito, T. Ohno, Kenji Kusunoki
In Lake Shinji, an increase in Zn concentration has been observed in the upper layer of sediment after about 1970. The clarifying of the pollution sources of Zn in the lake is important for assessing the impact of Zn transported from the China continent on the aquatic environment in Japan. In this study, to obtain knowledge on the pollution sources of Zn in Lake Shinji, we measured the δZn of a sediment core. Moreover, we measured the δZn of aerosols collected in Hirado City, Nagasaki Prefecture, which has been strongly affected by air pollutants from the China continent. It was difficult to explain the δZn values (+0.11±0.14 (2σ) ‰) of anthropogenic Zn, which were estimated from the Zn concentration and δZn in the sediment core, on the basis of the contribution of aerosols with negative δZn values (-0.08±0.20 (2σ) ‰). In contrast, the δZn values (+0.05–0.08‰; literature data) of treated water from sewage treatment plants and runoff on receiving water in urban areas were similar to those of anthropogenic Zn in the lake. These suggest that Zn pollution in Lake Shinji is primarily attributable to the discharge of effluent such as treated water from sewage treatment plants and runoff on receiving water in urban areas; thus, the contribution of Zn from the China continent is small. This may be attributable to the release of large amounts of Zn into the environment, because Zn is used in large quantities in various products.
1970年前后,真嗣湖上层沉积物中Zn浓度有所增加。澄清湖中锌的污染源对评价中国大陆运锌对日本水生环境的影响具有重要意义。为了了解真鸡湖Zn的污染源,我们测量了沉积物岩心的δZn。此外,我们还测量了长崎县平户市气溶胶的δZn,该地区受到中国大陆空气污染物的强烈影响。在负δZn值(-0.08±0.20 (2σ)‰)气溶胶贡献的基础上,难以解释由沉积物芯中Zn浓度和δZn估算的人为Zn δZn值(+0.11±0.14 (2σ)‰)。δZn值(+0.05 ~ 0.08‰;(文献数据)污水处理厂处理后的水和城市地区接收水的径流与湖泊中人为锌的情况相似。这些结果表明,真次湖的锌污染主要是由于污水处理厂的废水和城市地区的接收水径流排放所致;因此,来自中国大陆的Zn的贡献较小。这可能是由于大量锌被释放到环境中,因为锌在各种产品中大量使用。
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引用次数: 0
Estimating the Stock Amount of Chemical Substance in Factories and Business Establishments Prepared for Disasters and Accidents 工厂和企业为应对灾害和事故而准备的化学物质库存量估算
Pub Date : 2021-01-01 DOI: 10.5985/jec.31.98
Satoshi Nakamura, Yusuke Tawa, K. Noro, Y. Yabuki
In preparation for the leakage of chemical substances from factories and business establishments caused by disasters and accidents, it is desirable for each local government to grasp the daily stock amount of chemical substances in advance. This time, the technique to estimate the stock amount of chemical substances in factories and business establishments from PRTR notification data was examined. Using existing survey data by the Ministry of the Environment, the relationship between the annual handling amount of chemical substances in factories and business establishments and the stock amount on the first day of the fiscal year and the end of the fiscal year was analyzed, and it was found that the stock amount was about 3 . 9 to 5 . 4% of the handling amount (about 2 weeks to 20 days). We have developed a method to estimate the handling amount from the release and transfer amount of PRTR notification data, and it seems that the estimation of the stock amount becomes possible by combining with this technique.
为了防备因灾害和事故造成的工厂和商业场所的化学物质泄漏,每个地方政府都应该提前掌握化学物质的每日库存数量。这一次,研究了从PRTR通报数据估计工厂和商业机构化学物质存量的技术。利用环境部现有的调查数据,分析了工厂和营业场所的化学物质年处理量与会计年度第一天和会计年度结束时的库存量之间的关系,发现库存量约为3。朝九晚五。处理量的4%(约2周至20天)。我们开发了一种从PRTR通知数据的释放和转移量来估计处理量的方法,结合该技术估计库存量似乎成为可能。
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引用次数: 0
Simultaneous Determination of Ammonia and Humic Acid in Natural Water by Chemiluminescence with Hypobromites 次溴酸盐化学发光法同时测定天然水中氨和腐植酸
Pub Date : 2021-01-01 DOI: 10.5985/jec.31.91
T. Dang, T. Shiba, A. Kosugi, M. Okunaga, Matsui Kazuhiko, Y. Fujii, N. Takenaka
A simultaneous determination method for ammonia and humic acid in water based on the chemiluminescence method was developed. Ammonia was separated by a porous Teflon tube (in a double tube), and separated ammonia was reacted with hypobromite to produce chemiluminescence. By using the synergistic enhancement effect of humic acid for the chemiluminescence, a detection limit for ammonia of 0 . 41 μ mol dm −3 was obtained without any interference from other compounds. Humic acid in the remaining solution coming out from the double tube also reacts with hypobromite to produce chemiluminescence. Ammonia interfered with this chemiluminescence, but the effect was saturated at ammonia concentrations higher than 1 mmol dm −3 . The slope for the calibration graph of humic acid was not affected by ammonia concentration, but the value of the intercept for humic acid increased depending on ammonia concentration. There-fore, if the ammonia concentration is known, the humic acid concentration can be determined. The detection limit for humic acid was 1 . 1 ppb. The present method was applied to the measurement of natural water, and the results obtained by the present method were consistent with those obtained by ion chromatography for ammonia and another reported chemiluminescence method using N-bromosuccinimide for humic acid.
建立了化学发光法同时测定水中氨和腐植酸的方法。氨用多孔聚四氟乙烯管(双管)分离,分离后的氨与次溴酸盐反应产生化学发光。利用腐植酸对化学发光的协同增强作用,对氨的检出限为0。在不受其他化合物干扰的情况下,得到41 μ mol dm−3。从双管流出的剩余溶液中的腐植酸也与次溴酸盐反应产生化学发光。氨干扰了这种化学发光,但当氨浓度高于1 mmol dm−3时,这种影响达到饱和。腐植酸校准图的斜率不受氨浓度的影响,但其截距值随氨浓度的增加而增大。因此,如果知道氨的浓度,就可以确定腐植酸的浓度。腐植酸的检出限为1。1磅。将该方法应用于天然水的测定,所得结果与离子色谱法测定氨的结果和另一种用n -溴代琥珀酰亚胺测定腐植酸的化学发光方法的结果一致。
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引用次数: 0
Heavy Metals Toxicity and the Environment Protection 重金属毒性与环境保护
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.326
O. Meena
Pollution of environment is one of the most horrible ecological crisis to which we are subjected today. One of the main sources of pollution in the environments is metallic compounds. Metals and metalloids have long been mined and used in numerous applications. This has led to a significant increase of metal pollutions. Metals can accumulate in all environmental matrices at either high or trace levels of concentration. Heavy metals are naturally occurring elements that have a high atomic weight and a density. Therefore amount of various kinds of metals are present in soil, plants, air, lakes, animals, oceanic regions, even in foodstuffs and human beings. Their widespread distribution, especially heavy metals, became serious problems because of their toxicities for animals, human health and the environment. Their toxicity of heavy metals depends on several factors including the dose, route of exposure and chemical species, as well as the age, gender, genetics and nutritional status of exposed individuals. Because of their high degree of toxicity, lead, cadmium, chromium, zinc, nickel, arsenic and mercury rank among the priority metals that are of public health significance. Metals generally enter in the ecosystem in a relatively non-toxic form and generally become intrinsic components of the environment in such a way that it is difficult to remove them from the environment. Some of them are converted into toxic forms through the environmental reactions involving various micro-organisms and non-biological pathways. For example, methylated compounds like dimethyl mercury, (CH3)2Hg, are more toxic than their inorganic forms. In the present investigation more attention has been given to heavy metals like lead, cadmium, nickel and zinc. Although, the term “heavy metals” refer to any metallic element that has a relatively high density and is toxic or poisonous at low concentrations. Examples of heavy metals include Pb, Cd, Hg, As, Cr and Ti etc. This review provides an analysis of their environmental occurrence, production and use, potential for human exposure and molecular mechanisms of toxicity, genotoxicity and carcinogenicity.
环境污染是当今人类面临的最严重的生态危机之一。金属化合物是环境污染的主要来源之一。金属和类金属长期以来一直被开采并在许多应用中使用。这导致了金属污染的显著增加。金属可以在所有环境基质中以高浓度或微量浓度积累。重金属是自然产生的元素,具有较高的原子量和密度。因此,在土壤、植物、空气、湖泊、动物、海洋中,甚至在食品和人体中,都存在着大量的各种金属。它们的广泛分布,特别是重金属,因其对动物、人类健康和环境的毒性而成为严重问题。它们对重金属的毒性取决于若干因素,包括剂量、接触途径和化学物质种类,以及接触者的年龄、性别、遗传和营养状况。由于其高度毒性,铅、镉、铬、锌、镍、砷和汞被列为对公共卫生具有重要意义的优先金属。金属一般以相对无毒的形式进入生态系统,一般成为环境的固有组成部分,很难从环境中去除。其中一些通过涉及各种微生物和非生物途径的环境反应转化为有毒形式。例如,甲基化的化合物,如二甲基汞,(CH3)2Hg,比它们的无机形式更有毒。目前对铅、镉、镍、锌等重金属的研究较多。不过,“重金属”一词指的是密度相对较高、浓度较低时有毒或有毒的任何金属元素。重金属的例子包括Pb、Cd、Hg、As、Cr和Ti等。本文综述了它们的环境发生、生产和使用、人体暴露潜力以及毒性、遗传毒性和致癌性的分子机制。
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Journal of environmental analytical chemistry
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