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Editorial Note on Heavy Metals 关于重金属的社论注释
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.324
B. Sundaram
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引用次数: 0
Easy Analytical Methods for the Environmental Analysis 环境分析的简易分析方法
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.298
Chiranjeevi Sirikonda
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引用次数: 0
Editorial Note on How to Prevent Air Pollution 《如何防止空气污染》编者按
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.296
Chiranjeevi Sirikonda
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引用次数: 0
Estimation Accuracy of Annual Average Value of Atmospheric Concentration by Measurement Cycle and Frequency 利用测量周期和频率估算大气浓度年平均值的精度
Pub Date : 2021-01-01 DOI: 10.5985/JEC.31.64
Chieko Nudejima, J. Hoshi, Mika Kato, T. Kameya
In this study, we analyzed the estimation accuracy of the annual average value of 16 volatile organic compounds (VOCs) in the atmosphere according to the measurement frequency. As the analysis data, VOCs continuous monitoring data that has been observed hourly for 3 years at 6 points in Tokyo was used. In the case of 24 -hours sampling, the coefficient of variation (CV) of the annual average value in the 30 -days cycle to accurate annual average was 0 . 25 on average 16 substances. On the other hand, when the measuring day of the week is fixed, as in the case of the 7 -days cycle, there were substances that had a significantly higher CV. Especially for trichloroethylene and dichloromethane, it was higher than that in the 30 -days cycle. It was considered that this is influenced by the concentration fluctuation due to industrial and / or traffic activities, and it was speculated that if the measuring day of the week was fixed even once a month, the accuracy of the annual average value would decrease. In the monthly monitoring, the CV of the annual average value for one-week sampling was smaller than for the 24 -hours sampling. It was estimated that the monitoring 4 times per year with one-week sampling was the same level or less than the CV of the monitoring 12 times per year with the 24 -hours sampling. The annual average value by 1 -week sampling of 4 times per year was as accurate as the value obtained by 24 -hours sampling of 12 times per year that was commonly performed in Japan.
在本研究中,我们分析了大气中16种挥发性有机化合物(VOCs)的年平均值根据测量频率的估算精度。分析数据采用东京6个点连续3年逐小时监测的VOCs数据。在24小时采样的情况下,30天周期内的年平均值与精确年平均值的变异系数(CV)为0。25种,平均16种物质。另一方面,当一周的测量日固定时,如在7天周期的情况下,有物质具有显著更高的CV。特别是对三氯乙烯和二氯甲烷,高于30 d周期。认为这是受工业和/或交通活动引起的浓度波动的影响,并推测如果一周的测量日固定下来,即使每月一次,年平均值的准确性也会下降。在月度监测中,1周采样的年平均值CV小于24小时采样的年平均值CV。估计每年监测4次,每周一次采样与每年监测12次,24小时采样的CV相同或更低。每年4次的1周采样的年平均值与日本通常每年12次的24小时采样所获得的值一样准确。
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引用次数: 0
Benzotriazole UV Stabilizer Contamination of in the Rivers and the Atmosphere of Hyogo Prefecture 兵库县河流和大气中苯并三唑类紫外线稳定剂污染状况
Pub Date : 2021-01-01 DOI: 10.5985/JEC.31.30
Ryosuke Yoshiki, Yuki Haga, T. Yamasaki, A. Nakagoshi, Katsuya Yamamoto, C. Matsumura, Kazuo Fujimori
The concentrations of benzotriazole UV stabilizers (BUVSs) in water bodies and the atmosphere were analyzed in Hyogo, Japan. Only UV-326 was detected in the water at four sites in the Hokkesantanigawa-River system, with a maximum concentration of 2,800 ng/L. BUVSs were detected in most of the analyzed sediment samples, with UV-326 as the dominant compound, followed by UV-327, UV-328, and UV-320. Based on these observations, BUVSs appear to accumulate more readily in sediments than in water because of their strong hydrophobicity. BUVSs were detected in all the analyzed atmospheric samples, and similar to the water and sediment samples, UV-326 was the dominant compound. These results suggest that the production and usage of UV-326 in Hyogo Prefecture are greater than those of other BUVSs. To the best of our knowledge, this is the first study that reports the presence of four BUVS substances (UV-320, UV-326, UV-327, and UV-328) in the atmosphere.
对日本兵库县水体和大气中苯并三唑类紫外线稳定剂(BUVSs)的浓度进行了分析。在北克桑塔尼加河水系的4个地点仅检测到UV-326,最高浓度为2,800 ng/L。大部分沉积物样品中均检测到BUVSs,以UV-326为优势化合物,其次为UV-327、UV-328和UV-320。基于这些观察,由于BUVSs具有很强的疏水性,它们在沉积物中比在水中更容易积聚。在所有分析的大气样品中都检测到BUVSs,并且与水和沉积物样品相似,UV-326是主要化合物。这些结果表明,兵库县UV-326的产量和使用量大于其他buvs。据我们所知,这是首次报道大气中存在四种BUVS物质(UV-320、UV-326、UV-327和UV-328)的研究。
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引用次数: 0
Low-Cost Materials for the Removal of Contaminants of Emerging Pollutants 用于去除新兴污染物的低成本材料
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.319
Sowmya Sakinala
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引用次数: 0
Physiological Analysis and Contamination of Heavy Metal Contents in Vegetables and Fruits Irrigated with Wastewater 废水灌溉蔬菜水果重金属含量的生理分析及污染
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.292
Swati Singh Ch, Amar Singh Rana, M. Ibrahim
The following research work has been undertaken to examine the presence of heavy metals i.e., lead (Pb), Cadmium (Cd), Copper (Cu), Iron (Fe), Cobalt (Co) in some selected vegetables and fruits supplied in the local market. The process used to determine heavy metals is Atomic Absorption Spectrometer. Iron concentration in spinach, tomato, cauliflower and lady finger showed higher ranges which were exceeding the permissible limits. Cauliflower and spinach were within the limits specified. The pH value, ascorbic concentration and moisture content significantly decreased after oven drying of vegetables and fruits. However, the Total Soluble Solids (TSS) and ash content significantly increased after oven drying as compared with fresh vegetables and fruits. The present research data revealed that the fresh and oven dried vegetables such as Spinach, Cauliflower, Lady finger and Tomato contains 0.13-1.50%, 0.25-2.32%, 0.26-2.52% and 0.19-3.13% Titratable acidity respectively. Similarly, fresh and oven dried Guava Titratable acidity was highest 0.27 and 1.92 as compared with Water melon and Mango. The reduction in acidity may be due to catabolic activities in fruit cells and increased in pH. The pH value of vegetables and fruits dropped after oven drying. Similarly, ascorbic concentration and moisture content significantly decreased after oven drying as compared to fresh vegetables and fruits. However, the Total Soluble solids (TSS) and ash content significantly increased after oven drying as compared with fresh vegetables and fruits. Overall, from the following study we can conclude that vegetables and fruits were found to be contaminated by heavy toxic metals. Regular monitoring is required because these toxic metals will damage human body as well disturb our food chain. The main objective to conduct this study is to monitor the heavy metal toxicity and provide some recommendation, which in future will assure food safety and human health.
本署进行了以下的研究工作,以检查在本港市场供应的一些选定蔬菜和水果中是否含有重金属,即铅(Pb)、镉(Cd)、铜(Cu)、铁(Fe)和钴(Co)。测定重金属的方法是原子吸收光谱仪。菠菜、番茄、花椰菜和凤尾菜的铁含量超标。花椰菜和菠菜都在规定的限量之内。蔬菜和水果经烘箱干燥后,pH值、抗坏血药浓度和水分含量显著降低。但与新鲜蔬菜和水果相比,烘箱干燥后的总可溶性固形物(TSS)和灰分含量显著增加。本研究结果表明,新鲜蔬菜菠菜、花椰菜、凤手莲和番茄的可滴定酸度分别为0.13-1.50%、0.25-2.32%、0.26-2.52%和0.19-3.13%。与西瓜和芒果相比,新鲜和干燥番石榴的可滴定酸度最高,分别为0.27和1.92。酸度的降低可能是由于水果细胞的分解代谢活动和pH值的增加。烘箱干燥后蔬菜和水果的pH值下降。同样,与新鲜蔬菜和水果相比,烘箱干燥后的抗坏血药浓度和水分含量显著降低。但与新鲜蔬菜和水果相比,烘箱干燥后的总可溶性固形物(TSS)和灰分含量显著增加。总的来说,从下面的研究中我们可以得出结论,蔬菜和水果被重金属污染了。因为这些有毒金属会损害人体,也会扰乱我们的食物链,所以需要定期监测。本研究的主要目的是监测重金属的毒性,为今后的食品安全和人体健康提供建议。
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引用次数: 1
Editorial Note on Environmental Soil Chemistry 环境土壤化学编者按
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.294
Chiranjeevi Sirikonda
Soil chemistry is the analysis of the distribution of the elements and their compounds between the three main phases that form the soil, solid, liquid, and gaseous phases and within them. We aim to understand and predict how positively charged ions are dispersed between the solid and liquid phases by observing cation exchange reactions. Cation exchange is an important and unifying principle in soil science because it affects the flocculation and dispersion of soils and suspended sediments, the availability and transport of nutrient and contaminant cations, and the regulation of soil acidity. The first systemic studies of cation exchange reactions in soils are credited to J.T. Way. Way determined that equal quantities of Ca2+ were extracted from soils when leached with NH4+, K+, and Na+, based on H.S. Thompson's observation that CaSO4 was leached out when (NH4)2SO4 was applied to soil columns. Since then, a significant amount of work has been done to apply the cation exchange concept to model the availability of nutrient ions in soils, particularly the exchange of K+, NH4+, and Ca2+. The degree of colloid dispersion, and thus the formation of soil crusts and soil hydraulic conductivity, is directly affected by the relative concentration of sodium on soil surfaces. Na2+-Ca2+ exchange concepts have since been used to reclaim and control saline-sodic soils. The effects of sodium and solution composition, pH, ionic strength, and mineralogy on soil dispersive properties have made significant progress. The effects of acid rain and other anthropogenic inputs on soil acidification have been studied using aluminum–calcium exchange reactions. As evidenced by the numerous research articles published on the topic, cation exchange reactions have been, and continue to be, an active field of soil chemistry research. Several outstanding reviews are available, including those with background information, experimental methods, and cation exchange kinetic aspects. In soils, cation exchange occurs as a result of two general phenomena that are easily identified and comprehended. Second, most soils have a net negative charge, except for the very acid and extremely weathered ones. Second, they are electrically neutral in all normal macroscopic environments. As salts are applied to the soil by natural mineral weathering or decomposition processes of organic matter, some fraction of the added ions accumulate in the interfacial region and displace a charge-equivalent amount of ions from the interfacial region into the soil solution in irrigation water as a fertiliser, acid rain, or other anthropogenic input. When applied to a system as varied and heterogeneous as the soil, the simplicity of these principles belies the difficulty of the cation exchange process.
土壤化学是对构成土壤的三个主要相——固、液、气相之间及其内部元素及其化合物分布的分析。我们的目的是通过观察阳离子交换反应来了解和预测带正电的离子是如何在固液相之间分散的。阳离子交换是土壤科学中一个重要而统一的原理,因为它影响土壤和悬浮沉积物的絮凝和分散,营养物和污染物阳离子的有效性和运输,以及土壤酸度的调节。对土壤中阳离子交换反应的第一个系统研究归功于J.T. Way。根据H.S. Thompson的观察,当(NH4)2SO4应用于土壤柱时,CaSO4被浸出,Way确定当NH4+, K+和Na+浸出时,从土壤中提取出等量的Ca2+。从那时起,大量的工作已经完成了应用阳离子交换概念来模拟土壤中营养离子的有效性,特别是K+, NH4+和Ca2+的交换。土壤表面钠的相对浓度直接影响胶体的分散程度,从而影响土壤结皮的形成和土壤的水力导电性。Na2+-Ca2+交换概念已被用于盐碱地的开垦和控制。钠和溶液组成、pH、离子强度和矿物学对土壤分散性的影响已取得重大进展。利用铝钙交换反应研究了酸雨和其他人为输入对土壤酸化的影响。正如发表在该主题上的大量研究文章所证明的那样,阳离子交换反应一直是并将继续是土壤化学研究的一个活跃领域。一些优秀的评论,包括背景信息,实验方法和阳离子交换动力学方面。在土壤中,阳离子交换是由于两种容易识别和理解的一般现象而发生的。其次,大多数土壤都带净负电荷,除了酸性很强和风化非常严重的土壤。其次,它们在所有正常的宏观环境中都是电中性的。当盐通过自然矿物风化作用或有机物分解作用作用于土壤时,部分添加的离子在界面区域积累,并从界面区域取代电荷等量的离子进入灌溉水中的土壤溶液中,作为肥料、酸雨或其他人为输入。当应用于像土壤这样变化多端的系统时,这些原理的简单性掩盖了阳离子交换过程的困难。
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引用次数: 0
Microplastics and their Role as a Sorbed Chemical 微塑料及其作为吸附化学物质的作用
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.320
Pawan Tarade
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引用次数: 0
Multiple Reuse of Electrocoagulation Treated Reactive Dyeing Wash-Off: Colorimetric Properties and Water Saving 电混凝处理的活性染色水洗渣的多次回用:比色性能及节水性能
Pub Date : 2021-01-01 DOI: 10.37421/2380-2391.2021.8.330
Nabeela Firdous, I. Shaikh, S. Islam, F. Arooj
Dyeing wash-off operations in textile industries quite water intensive resulting into the generation of highly polluted wastewater. This study evaluated the treatment efficiency of electrocoagulation process to decolorize the synthetic effluent of CI Reactive Yellow 145 and then, the treated effluent was reused for 08 subsequent wash-off cycles of textile dyeing. The process parameters (Electrolysis time, applied current density and pH) were optimized and the maximum colour removal efficiency (98%) was achieved at pH 7, 10 minutes treatment time and current density of 90 A/m2. The fabric quality was assessed in terms of Colour difference and wash fastness properties. The Colour difference values of all dyed fabric samples up to 8 reuse cycles were ranged 0.38 to 0.85 which is industrially acceptable quality limit (ΔEcmc < 1). The wash fastness and Colour strength properties were also comparable to that of conventionally washed off fabric samples. However, an increase in pH, COD, TDS and turbidity was observed after every reuse but it did not deteriorate the quality of dyeing. This approach of reuse of electrocoagulation treated dye wash-off liquor up to 8 cycles provides a sustainable solution for textile industry.
纺织工业的印染洗涤作业耗水量很大,产生了高污染的废水。本研究评价了电絮凝法对CI活性黄145合成出水的脱色处理效果,并将处理后的出水回用于随后的08次纺织染色水洗循环。优化了工艺参数(电解时间、施加电流密度和pH),在pH为7、处理时间为10分钟、电流密度为90 A/m2时,去色效率最高(98%)。织物质量是根据色差和洗涤牢度进行评定的。所有染色织物样品的色差值在8次重复使用周期内的范围为0.38至0.85,这是工业上可接受的质量限制(ΔEcmc < 1)。洗涤牢度和颜色强度性能也与常规水洗的织物样品相当。每次重复使用后,pH值、COD、TDS和浊度均有所升高,但不影响染色质量。该方法可重复利用经电凝处理的染料洗涤液达8次循环,为纺织工业提供了可持续的解决方案。
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引用次数: 1
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Journal of environmental analytical chemistry
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