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Comparison of an industrial- and a laboratory-scale furnace for analysis of hydrocarbon intumescent coating performance 用于分析碳氢化合物膨胀涂层性能的工业炉与实验室炉的比较
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-04-13 DOI: 10.1177/0734904120902852
Ying Zeng, C. Weinell, K. Dam‐Johansen, L. Ring, S. Kiil
Due to increasing demands for fire protection in high-risk environments, such as petrochemical processes and offshore platforms, so-called hydrocarbon intumescent coatings are increasingly used to protect structural steel in the event of a hydrocarbon fire. For these coatings, the fire-resistance performance is typically evaluated in a series of costly experiments with industrial-scale (i.e. 1–10 m3) furnaces, programmed to follow a standard hydrocarbon fire test curve. In this work, we propose a laboratory-scale furnace for coating evaluation, which can simulate the conditions of a typical hydrocarbon fire curve, that is, the standard UL 1709. In a case study with five hydrocarbon intumescent coating formulations, the correlation between the laboratory- and the industrial-scale furnace was investigated and a good agreement was found for the temperature progression of the coated steel plates. The physical and chemical properties of the intumescent coating chars were also similar for the two furnaces. In summary, the low-cost, time-efficient laboratory-scale furnace can provide reliable screening of hydrocarbon intumescent coatings and is recommended as a complementary tool for industrial fire tests.
由于在石化过程和海上平台等高风险环境中对消防的需求不断增加,在发生碳氢化合物火灾时,越来越多地使用所谓的碳氢化合物膨胀型涂料来保护结构钢。对于这些涂层,耐火性能通常在一系列工业规模的昂贵实验中进行评估(即1-10 m3)炉,编程为遵循标准碳氢化合物燃烧测试曲线。在这项工作中,我们提出了一种实验室规模的涂层评估炉,它可以模拟典型的碳氢化合物火灾曲线的条件,即标准UL 1709。在一个使用五种碳氢化合物膨胀型涂料配方的案例研究中,研究了实验室规模的熔炉和工业规模的熔炉之间的相关性,发现涂层钢板的温度变化非常一致。两种炉的膨胀型涂料焦的物理和化学性质也相似。总之,低成本、省时的实验室规模的熔炉可以提供碳氢化合物膨胀型涂层的可靠筛选,并被推荐为工业防火测试的补充工具。
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引用次数: 16
Poly(diallyldimethylammonium) and polyphosphate polyelectrolyte complex as flame retardant for char-forming epoxy resins 聚(二烯丙基二甲基铵)和聚磷酸盐聚电解质复合物用作成炭环氧树脂的阻燃剂
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-20 DOI: 10.1177/0734904120911722
Lichen Zhang, Deqi Yi, Jian-wei Hao
The flame retardant poly(diallyldimethylammonium) and polyphosphate polyelectrolyte complex and the curing agent m-Phenylenediamine were blended into diglycidyl ether of bisphenol A (DGEBA)-type epoxy resin to prepare flame-retardant epoxy resin thermosets. The effects of poly(diallyldimethylammonium) and polyphosphate on fire retardancy and thermal degradation behavior of epoxy resins (EP)/poly(diallyldimethylammonium) and polyphosphate composites were tested by Limiting Oxygen Index, UL-94, cone calorimeter tests, and thermogravimetric analysis and compared with pure EP. The results showed that the Limiting Oxygen Index value of EP/poly(diallyldimethylammonium) and polyphosphate composite could reach 31.9%, and UL-94 V-0 rating at 10 wt% poly(diallyldimethylammonium) and polyphosphate loading. Meanwhile the cone calorimetry peak heat release rate and total heat release were reduced up to 55.2% and 21.8%, respectively; smoke production rate and total smoke production were also declined significantly, compared with those of pure epoxy resins. Poly(diallyldimethylammonium) and polyphosphate played a very good flame-retardant effect on epoxy resins.
将阻燃剂聚二烯丙基二甲基铵和聚磷酸盐聚电解质配合物与固化剂间苯二胺共混到双酚A型环氧树脂二缩水甘油醚中,制备阻燃环氧树脂热固性树脂。通过极限氧指数、UL-94、锥形量热计和热重分析测试了聚二烯丙基二甲基铵和聚磷酸盐对环氧树脂(EP)/聚二烯丙基二甲基铵和多磷酸盐复合材料的阻燃性和热降解行为的影响,并与纯EP进行了比较。结果表明,EP/聚二烯丙基二甲基铵和聚磷酸盐复合材料的极限氧指数可达到31.9%,UL-94V-0等级为10 wt%的聚(二烯丙基二甲基铵)和多磷酸盐负载。同时锥形量热法的峰值放热率和总放热率分别降低了55.2%和21.8%;与纯环氧树脂相比,发烟率和总发烟量也显著下降。聚二烯丙基二甲基铵和聚磷酸盐对环氧树脂具有很好的阻燃效果。
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引用次数: 5
Soot production modelling for operational computational fluid dynamics fire simulations 用于操作计算流体动力学火灾模拟的煤烟产生建模
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-01 DOI: 10.1177/0734904120905579
O. Marino, F. Muñoz, W. Jahn
With the aim of minimising the losses produced by fire accidents, fire engineering applies physics and engineering principles to preserve the integrity of people, environment and infrastructure. Fire modelling is complex due to the interaction between chemistry, heat transfer and fluid dynamics. Commercially available simulation tools necessarily simplify this complexity, excluding less fundamental processes, such as soot production. By not including this compound in the simulations, the interactions of radiation heat transfer, fire propagation and toxicity must be approximated based on input parameters that are often not well defined. In this work, two semi-empirical soot models are incorporated in the fire dynamics simulator. The models are compared against experimental data. For the operational viability in large-scale scenarios, a correction factor for the local variables is proposed as a function of the cell size, achieving good agreement with experimental data in terms of the amount of soot generated.
为了最大限度地减少火灾事故造成的损失,消防工程应用物理和工程原理来保护人员、环境和基础设施的完整性。由于化学、传热和流体动力学之间的相互作用,火灾建模是复杂的。商业上可用的模拟工具必然会简化这种复杂性,不包括不太基本的过程,如烟尘生产。通过在模拟中不包括这种化合物,辐射传热、火灾传播和毒性的相互作用必须基于通常没有很好定义的输入参数来近似。在这项工作中,两个半经验烟灰模型被纳入火灾动力学模拟器。将模型与实验数据进行了比较。对于大规模场景中的操作可行性,提出了局部变量的校正因子作为单元大小的函数,在产生的烟尘量方面与实验数据达成了良好的一致性。
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引用次数: 0
Numerical study of fire resistance of stainless steel circular hollow section columns 不锈钢圆形空心截面柱耐火性能的数值研究
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-01 DOI: 10.1177/0734904119888823
F. Arrais, N. Lopes, P. Real
Stainless steel has countless desirable characteristics for a structural material. Although initially more expensive than conventional carbon steel, stainless steel structures can be competitive due to their smaller need for fire protection material and lower life-cycle cost, thus contributing to a more sustainable construction. The most common stainless steel groups used in structural applications are the austenitic, ferritic and austenitic–ferritic (also known as Duplex grades). This work presents a numerical study on the behaviour of stainless steel circular hollow section members under axial compression at elevated temperatures, with different cross-section slenderness. The numerically obtained ultimate load-bearing capacities are compared with simplified calculation formulae from Eurocode 3 for columns under fire situation. A parametric study, considering different stainless steel grades from the aforementioned groups, cross-sectional classes and slendernesses, is here presented for different elevated temperatures. The numerical analyses were performed with the finite element programme SAFIR, with material and geometric non-linear analysis considering imperfections. Comparisons between the numerical results and the Eurocode 3 rules demonstrated that a specific design approach must be developed for stainless steel columns under fire situation.
作为一种结构材料,不锈钢具有无数令人满意的特性。虽然最初比传统的碳钢更昂贵,但不锈钢结构由于对防火材料的需求更小,生命周期成本更低,因此具有竞争力,从而有助于更可持续的建筑。在结构应用中最常用的不锈钢组是奥氏体,铁素体和奥氏体-铁素体(也称为双相牌号)。本文对不同截面长细比的不锈钢圆空心截面构件在高温下的轴压性能进行了数值研究。数值计算得到的极限承载能力与欧洲规范3中柱在火灾情况下的简化计算公式进行了比较。一个参数化的研究,考虑了不同的不锈钢等级,从上述组,横截面等级和细长度,在这里提出了不同的高温。数值分析采用SAFIR有限元程序进行,考虑了材料和几何非线性分析的缺陷。数值计算结果与欧洲规范3的比较表明,对于火灾情况下的不锈钢柱,必须制定具体的设计方法。
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引用次数: 8
A reappraisal of the nominal curvature method in the fire design of reinforced concrete columns 钢筋混凝土柱防火设计中标称曲率法的再评价
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-01 DOI: 10.1177/0734904119895436
P. Bamonte
A reappraisal of the method based on nominal curvature for designing reinforced concrete columns in fire is proposed, with the focus on the validation of an alternative and widely accepted way of applying the method, which differs from the current provisions of EN 1992-1-2. To this end, a systematic comparison between experimental and numerical results is carried out on a database consisting of 74 columns tested in different laboratories. The comparison shows that the method based on nominal curvature yields conservative estimates of the time to failure. Moreover, the numerical results obtained are reasonably close to those obtained by means of finite element analysis. By contrast, if the method is applied in combination with the simplified methods introduced in EN 1992-1-2, the numerical results are not conservative, with a significant overestimation of the bearing capacity of the columns, and of the time to failure, mainly because of the overestimation of the stiffness by the simplified methods.
建议对基于标称曲率的火灾中钢筋混凝土柱设计方法进行重新评估,重点是验证一种替代且广泛接受的应用方法,该方法不同于EN 1992-1-2的现行规定。为此,在由74个在不同实验室测试的柱组成的数据库中,对实验结果和数值结果进行了系统的比较。比较表明,基于标称曲率的方法对失效时间进行了保守估计。此外,所获得的数值结果与有限元分析结果相当接近。相比之下,如果将该方法与EN 1992-1-2中引入的简化方法结合使用,则数值结果并不保守,主要是由于简化方法高估了刚度,因此对柱的承载力和失效时间的估计明显过高。
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引用次数: 2
Fire behaviour of ecological soil–cement blocks with waste incorporation: Experimental and numerical analysis 掺入废弃物的生态土壤-水泥砌块的火灾行为:实验和数值分析
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-01 DOI: 10.1177/0734904119893921
D. Ferreira, Eduarda Luso, M. L. Cruz, L. Mesquita, Guilherme Gontijo
The main goal of this study is to assess the behaviour of soil–cement blocks with incorporation of organic wastes. The problem of waste accumulation exists worldwide and has become a concern in today’s society, leading to enormous environmental damage. One of the possibilities for reducing their environmental impact is the reuse of these wastes in new materials. However, incorporating waste changes the mechanical, physical and thermal properties of the new material. In order to evaluate the potential use of waste in blocks composition, laboratory tests were conducted and the results were analysed. This article presents the fire behaviour of ecological soil–cement blocks with waste incorporation. Therefore, an experimental programme was performed using samples of wall panel with soil–cement blocks. The wall specimen under fire conditions was also analysed by a non-linear transient finite element numerical model, in time and temperature domains, and the numerical and experimental temperature fields were compared.
本研究的主要目标是评估掺入有机废物的土壤-水泥块的性能。垃圾堆积问题在世界范围内都存在,并已成为当今社会关注的问题,导致了巨大的环境破坏。减少其对环境影响的可能性之一是将这些废物重新用于新材料中。然而,加入废物会改变新材料的机械、物理和热性能。为了评估废物在砌块组成中的潜在用途,进行了实验室测试并对结果进行了分析。本文介绍了掺入废弃物的生态土-水泥砌块的火灾行为。因此,使用带有土壤-水泥块的墙板样品进行了实验程序。采用非线性瞬态有限元数值模型,在时间域和温度域对火灾工况下的墙体试件进行了分析,并对数值温度场和实验温度场进行了比较。
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引用次数: 3
Preface 前言
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-01 DOI: 10.1177/0734904120914194
P. Piloto, A. Morgan
Evident from this definition, or from any of its variants that one can find in the growing literature on the subject, are two characteristic aspects. The first one being that such a risk takes place at a much larger scale than that of an individual institution. The second one being that it eventually spreads to the real economy outside the financial system through various “leakage” mechanisms, of which the last crisis has given some examples: liquidity shrinkage, fire sale of assets, drop in market value of derivatives. . . This type of risk, long confined to the monetary market, has spread widely in the recent past, culminating in the subprime crisis of 2008. The understanding and control of systemic risk has therefore become an extremely important societal and economic question. Such problems are now extensively being studied by people from disciplines like economics, finance and physics. The contributions by physicists are relatively new. The Econophys-Kolkata VI conference, the 6th event in this series of international conferences, held during October 21–25 last year, was dedicated to address and discuss extensively these issues and the recent developments. Like the last event in the series, this one was also organized jointly by the École Centrale Paris and the Saha Institute of Nuclear Physics, and was held at the Saha Institute of Nuclear Physics, Kolkata. This proceedings volume contains the written versions of most of the talks and seminars delivered by distinguished experts from all over the world, participating in the meeting, and accepted after refereeing. For some completeness in the cases of one or two important topics (like in the case Many-agent Games), some reviews, by experts who could not attend, were invited and incorporated in this volume.
从这个定义中,或者从人们可以在不断增长的关于这个主题的文献中找到的任何变体中,可以看出有两个特征方面。第一个是,这种风险发生的规模比单个机构大得多。第二种是它最终通过各种“泄漏”机制扩散到金融体系之外的实体经济,上一次危机给出了一些例子:流动性萎缩、资产贱卖、衍生品市值下跌。这种长期局限于货币市场的风险在最近广泛蔓延,最终导致了2008年的次贷危机。因此,对系统性风险的理解和控制已成为一个极其重要的社会和经济问题。经济学、金融学和物理学等学科的人们现在正在广泛研究这些问题。物理学家的贡献相对较新。去年10月21日至25日举行的加尔各答第六次经济会议是这一系列国际会议中的第六次会议,旨在广泛讨论这些问题和最近的发展。与该系列的最后一次活动一样,这次活动也是由巴黎中央大学和萨哈核物理研究所联合组织的,在加尔各答萨哈核物理学研究所举行。本议事录收录了来自世界各地的杰出专家参加会议并在裁判后接受的大多数演讲和研讨会的书面版本。为了在一到两个重要主题的情况下(如多代理游戏)获得一些完整性,邀请了一些无法出席的专家进行的评论,并将其纳入本卷。
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引用次数: 0
Numerical model to predict the effect of wood density in wood–steel–wood connections with and without passive protection under fire 有和无被动防护时木-钢-木连接中木材密度影响的数值模型
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-01 DOI: 10.1177/0734904119884706
E. Fonseca, Lino D. S. Silva, P. Leite
The main objective of this work is to present a numerical model to predict the effect of wood density in unprotected wood connections with an internal steel plate (wood–steel–wood), when comparing with the same connections using passive protection with gypsum plasterboard, submitted to fire conditions. Wood–steel–wood connections are made of four wood members, two on each side, with an internal steel plate that connects the pieces using steel dowel fasteners. First, analytical methodologies according to Eurocode 5 part 1-1 were used to design the connections at room temperature. After that, to predict the fire exposure and the connection ability, a numerical model was performed which permits to compare the fire resistance in wood–steel–wood connections without and with passive protection following the Eurocode 5 part 1-2. Results of the temperature and the wood char layer depth were compared using three different wood densities. The evolution of the charring rate was calculated in different locations of the connections and compared with the analytical value proposed by the Eurocode 5 part 1-2.
这项工作的主要目的是提出一个数值模型,当与使用石膏板被动保护的相同连接进行比较时,预测具有内部钢板(木-钢-木)的无保护木连接中的木材密度对火灾条件的影响。木-钢-木连接由四个木构件组成,每侧两个,内部钢板使用钢钉紧固件连接构件。首先,根据欧洲规范5第1-1部分的分析方法用于在室温下设计连接。之后,为了预测火灾暴露和连接能力,根据欧洲规范5第1-2部分,进行了一个数值模型,该模型可以比较没有和有被动保护的木-钢-木连接的耐火性。使用三种不同的木材密度比较了温度和木材焦层深度的结果。计算了连接件不同位置的炭化率演变,并与欧洲规范第5部分第1-2部分提出的分析值进行了比较。
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引用次数: 9
Fire resistance of composite non-load bearing light steel framing walls 复合非承重轻钢框架墙的耐火性能
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-03-01 DOI: 10.1177/0734904119900931
Seddik M Khetata, P. Piloto, Ana BR Gavilán
The light steel frame walls are mostly used for non-load bearing applications. The light steel framed walls are made with studs and tracks that require fire protection, normally achieved by single plasterboard, by composite protection layers or by insulation of the cavity. The partition walls are fire rated to resist by integrity and insulation. Seven small-scale specimens were tested to define the fire resistance of non-load bearing light steel frame walls made with different materials. All tests were validated using two-dimensional numerical models, based on the finite-element method, the finite-volume method and hybrid finite-element method. A good agreement was achieved between the numerical and the experimental results from fire tests. The fire resistance increases with the number of studs and also with the thickness of the protection layers. The hybrid finite-element method solution method looks to be the best approximation model to predict fire resistance.
轻钢框架墙主要用于非承重应用。轻钢框架墙由需要防火的立柱和轨道制成,通常通过单层石膏板、复合保护层或空腔隔热来实现。隔墙通过完整性和绝缘性达到防火等级。测试了七个小规模样本,以确定由不同材料制成的非承重轻钢框架墙的耐火性。基于有限元法、有限体积法和混合有限元法,使用二维数值模型对所有试验进行了验证。数值计算结果与火灾试验结果吻合较好。耐火性随着螺柱的数量以及保护层的厚度而增加。混合有限元解法是预测耐火极限的最佳近似模型。
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引用次数: 14
Flame-retardant hybrid materials based on expandable polystyrene beads 基于可膨胀聚苯乙烯微珠的阻燃复合材料
IF 1.9 4区 工程技术 Q2 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2020-02-28 DOI: 10.1177/0734904119899851
J. Reuter, T. Standau, V. Altstädt, M. Döring
A highly efficient flame-retardant hybrid foam material combining expandable polystyrene foam beads and a waterborne resin equipped with inorganic flame retardants is described. The resin and the inorganic fillers were varied, and the different compositions were investigated in small burner and cone calorimeter tests. The burning time during the small burner test decreases from >60 s for neat expandable polystyrene to 0 s for optimized hybrid specimens. The peak of the heat release rate decreases from 661.0 kW/m2 for neat expandable polystyrene to 121.36 kW/m2 for a hybrid composition of 1:1:1 (expandable polystyrene:aluminum hydroxide:phenol formaldehyde resin). The hybrid materials containing inorganic flame retardants are burning slower and release heat and smoke more constantly at significantly lower rates. Furthermore, a continuous network of the cured thermoset is shown, which leads to embedded expandable polystyrene beads. The flame-retardant thermoset protects the expandable polystyrene from fire and leads to a material with high dimensional stability and efficient flame retardancy.
介绍了一种由可膨胀聚苯乙烯泡沫珠和无机阻燃剂的水性树脂组成的高效阻燃杂化泡沫材料。通过小型燃烧器和锥形量热仪试验,研究了树脂和无机填料的不同组成。在小燃烧器试验中,燃烧时间从纯可膨胀聚苯乙烯的60秒减少到优化混合试样的60秒。当聚苯乙烯:氢氧化铝:酚醛树脂为1:1:1时,热释放率峰值从纯聚苯乙烯的661.0 kW/m2降至121.36 kW/m2。含有无机阻燃剂的杂化材料燃烧更慢,释放热量和烟雾的速率更低。此外,显示了固化热固性的连续网络,这导致嵌入可膨胀的聚苯乙烯珠。阻燃热固性保护可膨胀聚苯乙烯免受火灾,并导致材料具有高尺寸稳定性和高效阻燃性。
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引用次数: 4
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Journal of Fire Sciences
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